by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 18MAR24
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-275-QC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-275-QC, ADV-275-BK, ADV-275-QC-0, ADV-275-BK-0, ADV-275-QC-2, ADV-275-BK-2,
ADV-275-QC-4, ADV-275-BK-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-275-QC-2024a
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Germ cell mutagenicity, Category 2
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H341 Suspected of causing genetic defects
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts, fumes, gas, mists, vapors or spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
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ADV-275-QC HARDENER
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P308 + P313 IF exposed or concerned: Get medical advice/attention
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Isophoronediamine, reaction products with phenol and formaldehyde 25265-17-2 7-30
Polyoxypropylenediamine 9046-10-0 10-30
Benzyl alcohol
100-51-6 10-30
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 7-13
Isophoronediamine 2855-13-2 7-30
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 5-10
Hydroxybenzene 108-95-2 5-10
Synthetic amorphous, pyrogenic silica 112945-52-5 5-10
Benzene-1,3-dimethanamine 1477-55-0 1-5
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Diethylenetriamine 111-40-0 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call a physician/doctor if symptoms develop and
persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, hight-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
PRO-SET
ADV-275-QC HARDENER
Page 3 of 7 Last Revised: 18MAR24
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation. Do not breathe vapors or mists from
heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy
resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and
emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Isophoronediamine, reaction products with
phenol and formaldehyde
25265-17-2 No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 No data available
Benzyl alcohol
100-51-6 10 ppm TWA (WEEL)
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available
Isophoronediamine 2855-13-2 No data available
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Hydroxybenzene 108-95-2 ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Polymer of epichlorohydrin / bisphenol A and 31326-29-1 No data available
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diethylenetriamine
Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Blue.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.04
BULK DENSITY.................................................................................. 8.67 lbs./gal. (1.04kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-175-QC/ADV-275-QC ......................................................... 9.43 0.08
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to
occur in a drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, aldehydes,
nitrosamines.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Isophoronediamine, reaction products with phenol
and formaldehyde
25265-17-2
No data available
(reference IPD)
No data available
(reference IPD)
No data available
(reference IPD)
Polyoxypropylenediamine 9046-10-0 2855 mg/kg 2980 mg/kg >0.74 mg/L 8h vapor
Benzyl alcohol
100-51-6
1620 mg/kg
No data available
>4.18 mg/l
4h aerosol
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available No data available No data available
Isophoronediamine 2855-13-2 1030 mg/kg >2000 mg/kg >5.01 mg/l dust/mist
4h
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available No data available No data available
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 1620 mg/kg No data available No data available
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
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Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data this product does not
meet classification criteria.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the uncured state, this product may be harmful to aquatic life
with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Isophoronediamine, reaction products with phenol and
formaldehyde
25265-17-2
No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Benzyl alcohol
100-51-6
No data available
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Hydroxybenzene 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available
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Diethylenetriamine 111-40-0 No data available
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): ………….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the Health and Physical Classifications in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
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COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Propylene oxide
75-56-9 < 0.0018%
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Update to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ 18MAR24
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-275-QC-2024a
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-275-NC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-275-NC, ADV-275-NC-0, ADV-275-NC-1, ADV-275-NC-2, ADV-275-NC-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-275-NC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Germ cell mutagenicity, Category 2
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H341 Suspected of causing genetic defects
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts, fumes, gas, mists, vapors or spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention
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ADV-275-NC HARDENER
Page 2 of 7 Last Revised: 12SEP22
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Isophoronediamine, reaction products with phenol and formaldehyde 25265-17-2 7-30
Polyoxypropylenediamine 9046-10-0 10-30
Benzyl alcohol
100-51-6 10-30
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 7-13
Isophoronediamine 2855-13-2 7-30
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 5-10
Hydroxybenzene 108-95-2 5-10
Synthetic amorphous, pyrogenic silica 112945-52-5 5-10
Benzene-1,3-dimethanamine 1477-55-0 1-5
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Diethylenetriamine 111-40-0 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call a physician/doctor if symptoms develop and
persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, high-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURE S: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
PRO-SET
ADV-275-NC HARDENER
Page 3 of 7 Last Revised: 12SEP22
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation. Do not breathe vapors or mists from
heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy
resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and
emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Isophoronediamine, reaction products with
phenol and formaldehyde
25265-17-2 No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 No data available
Benzyl alcohol
100-51-6 10 ppm TWA (WEEL)
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available
Isophoronediamine 2855-13-2 No data available
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Hydroxybenzene 108-95-2 ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available
Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
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ADV-275-NC HARDENER
Page 4 of 7 Last Revised: 12SEP22
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.04
BULK DENSITY.................................................................................. 8.67 lbs./gal. (1.04kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-175-NC/ADV-275-NC ......................................................... 9.43 0.08
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to
occur in a drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, aldehydes,
nitrosamines.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Isophoronediamine, reaction products with phenol
and formaldehyde
25265-17-2
No data available
(reference IPD)
No data available
(reference IPD)
No data available
(reference IPD)
Polyoxypropylenediamine 9046-10-0 2855 mg/kg 2980 mg/kg >0.74 mg/L 8h vapor
Benzyl alcohol
100-51-6
1620 mg/kg
No data available
>4.18 mg/l
4h aerosol
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available No data available No data available
Isophoronediamine 2855-13-2 1030 mg/kg >2000 mg/kg >5.01 mg/l dust/mist
4h
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available No data available No data available
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 1620 mg/kg No data available No data available
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
PRO-SET
ADV-275-NC HARDENER
Page 5 of 7 Last Revised: 12SEP22
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data this product does not
meet classification criteria.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Isophoronediamine, reaction products with phenol and
formaldehyde
25265-17-2
No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Benzyl alcohol
100-51-6
No data available
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Hydroxybenzene 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available
Diethylenetriamine 111-40-0 No data available
13. DISPOSAL CONSIDERATIONS
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ADV-275-NC HARDENER
Page 6 of 7 Last Revised: 12SEP22
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): ………….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Immediate, Delayed.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
PRO-SET
ADV-275-NC HARDENER
Page 7 of 7 Last Revised: 12SEP22
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Propylene oxide
75-56-9 < 0.0018%
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Update to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-275-NC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 08SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-273-QC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-273-QC, ADV-273-QC-0, ADV-273-QC-1, ADV-273-QC-2, ADV-273-QC-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-273-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Respiratory sensitizer, Category 1
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Germ cell mutagenicity, Category 2
Reproductive toxicity, Category 2
Specific target organ toxicity single exposure, Category 3
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts/fumes/gas/mists/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 In case of inadequate ventilation wear respiratory protection
Response
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ADV-273-QC HARDENER
Page 2 of 8 Last Revised: 08SEP22
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention or advice
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Triethylenetetramine, reaction products with phenol and formaldehyde 32610-77-8 10-30
Benzyl alcohol 100-51-6 10-30
“Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, ether with
2,2-bis(hydroxymethyl)-1,3-propanediol (4:1), 2-hydroxy-3-mercaptopropyl ether”
72244-98-5 10-30
Triethylenetetramine 112-24-3 1-7
Fatty acids, C18-unsat’d., dimerms, reaction products with 1-
piperazineethanamine and tall oil
206565-89-1 5-10
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 3-7
Synthetic amorphous, pyrogenic silica 112945-52-5 5-10
2-Piperazin-1-yiethylamine 140-31-8 5-10
Hydroxybenzene 108-95-2 1-10
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Polyoxypropylenediamine 9046-10-0 1-10
4-tert-butylphenol 98-54-4 1-10
Benzene-1,3-dimethanamine 1477-55-0 1-5
Diethylenetriamine 111-40-0 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI).
Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present
at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system. May cause allergy, asthma symptoms or breathing
difficulties if inhaled. Serious effects may be delayed following exposure. RESPONSE: Remove to fresh air if effects occur and keep comfortable
for breathing. Immediately call a POISON CONTROL CENTER or doctor if symptoms develop and persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
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5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, hight-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in a cool, dry and well-ventilated place away from high temperatures
and moisture. Keep container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Do not handle until all safety precautions have been read and understood.
Use only with adequate ventilation. Do not breathe vapors or mists from heated material. Avoid exposure to concentrated vapors. Avoid skin and
eye contact. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses,
can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing. Persons with a history of skin sensitization problems may need to avoid using this
product entirely.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard. Persons with a history of asthma, allergies or chronic or
recurrent respiratory disease should not be employed in any process in which this product is used.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Triethylenetetramine, reaction products with
phenol and formaldehyde
32610-77-8
No data available
Benzyl alcohol 100-51-6 10 ppm TWA (WEEL)
“Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-
.omega.-hydroxy-, ether with 2,2-
bis(hydroxymethyl)-1,3-propanediol (4:1), 2-
hydroxy-3-mercaptopropyl ether”
72244-98-5 No data available
Triethylenetetramine 112-24-3 AIHA WEEL: 1 ppm ; 6 mg/ m
3
; Absorbed via skin
Fatty acids, C18-unsat’d., dimerms, reaction 206565-89-1 No data available
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products with 1-piperazineethanamine and tall oil
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5
No data available
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
2-Piperazin-1-yiethylamine 140-31-8 No data available
Hydroxybenzene 108-95-2 ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available (reference Diethylenetriamine)
Polyoxypropylenediamine 9046-10-0 No data available
4-tert-butylphenol 98-54-4 No data available
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Blue.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 11.2
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.05
BULK DENSITY.................................................................................. 8.75 lbs./gal. (1.05kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-175 / ADV-273 .................................................................... 8.65 0.07
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a
drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid heating or processing at temperatures greater than 120
F (48
C).
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, carbon monoxide, carbon dioxide, volatile amines,
ammonia, nitric acid, aldehydes, nitrosamines.
11. TOXICOLOGICAL INFORMATION
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Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Triethylenetetramine, reaction products with
phenol and formaldehyde
32610-77-8
No data available No data available No data available
Benzyl alcohol
100-51-6
1620 mg/kg
No data available
>4.18 mg/l
4h aerosol
“Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-
.omega.-hydroxy-, ether with 2,2-
bis(hydroxymethyl)-1,3-propanediol (4:1), 2-
hydroxy-3-mercaptopropyl ether”
72244-98-5 No data available No data available No data available
Triethylenetetramine 112-24-3 1716 mg/kg 1465 mg/kg No data
Fatty acids, C18-unsat’d., dimerms, reaction
products with 1-piperazineethanamine and tall oil
206565-89-1
No data available
No data available
No data available
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5
No data available
No data available
No data available
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
2-Piperazin-1-yiethylamine 140-31-8 2097 mg/kg 866 mg/kg No data
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
1620 mg/kg
No data available
No data available
Polyoxypropylenediamine 9046-10-0 3069 mg/kg ATE 3170 mg/kg ATE >0.74
4-tert-butylphenol 98-54-4 >2000 mg/kg No data available No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough. May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Category 1. A component in this product is reported to cause
allergy, asthma symptoms or breathing difficulties if inhaled. Serious effects may be delayed following exposure.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Category 2. This product contains a substance that is suspected of
damaging fertility of the unborn child.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Category 3. This product contains a substance that may cause respiratory if
inhaled.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.
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CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Triethylenetetramine, reaction products with phenol and
formaldehyde
32610-77-8
Aquatic Chronic Cat. 3
Benzyl alcohol
100-51-6
No data available
“Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-
hydroxy-, ether with 2,2-bis(hydroxymethyl)-1,3-propanediol
(4:1), 2-hydroxy-3-mercaptopropyl ether”
72244-98-5 No data available
Triethylenetetramine 112-24-3 Aquatic Chronic Cat. 3
Fatty acids, C18-unsat’d., dimerms, reaction products with
1-piperazineethanamine and tall oil
206565-89-1
Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5
Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
2-Piperazin-1-yiethylamine 140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Hydroxybenzene
108-95-2
Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
4-tert-butylphenol 98-54-4 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 1
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Diethylenetriamine 111-40-0 No data available
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Triethylenetetramine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Triethylenetetramine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Triethylenetetramine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
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TECHNICAL SHIPPING NAME: …………………………………………………. Triethylenetetramine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS (or REACH) No data on CAS# 57214-10-5. All other ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) No data on CAS# 206565-89-1. All other ingredients are listed or otherwise compliant.
Australia AICS No data on CAS# 206565-89-1. All other ingredients are listed or otherwise compliant.
Japan ENCS No data on CAS# 206565-89-1. All other ingredients are listed or otherwise compliant.
South Korea KECI No data on CAS# 206565-89-1. All other ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS No data on CAS# 57214-10-5 and 206565-89-1. All other ingredients are listed or
otherwise compliant.
US EPA TSCA Requirements: ………………………………………………….. Reference a TSCA SNUR for CAS# 206565-89-1.
Canada WHMIS Confidential Business Information (CBI): …….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Triethylenetetramine
112-14-3 PA, MA,
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
2-Piperazin-1-yiethylamine
140-31-8 MA, PA, NJ
4-tert-butylphenol
98-54-4 PA, NJ
16. OTHER INFORMATION
REASON FOR ISSUE:……………………………………………………………… Changes to Section 1.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. September 8, 2022
SUPERSEDES DATE: ……………………………………………………………… January 14, 2022
SDS VERSION: ………………………………………………………………………. ADV-273-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
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HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
2
by | Sep 27, 2025
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 06/01/2015 Revision date: 05/12/2017 Version: ADV-273-NC-2017a
05/12/2017 EN (English) Page 1
SECTION 1: Identification
Identification
Product form : Mixtures
Product name : PRO-SET ADV-273-NC HARDENER
Product code : ADV-273-NC, ADV-273-NC-0, ADV-273-NC-2, ADV-273-NC-4
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy adhesive resins
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 888-377-6738 or 989-684-7286
www.prosetepoxy.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Acute Tox. 4 (Oral)
Acute Tox. 4 (Inhalation)
Skin Corr. 1B
Eye Dam. 1
Resp. Sens. 1
Skin Sens. 1
Muta. 2
Repr. 2
STOT SE 3
STOT RE 2
Aquatic Acute 2
Aquatic Chronic 2
Label elements
Hazard pictograms (GHS) :
GHS05
GHS07
GHS08
GHS09
Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed or if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma
symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing genetic defects. Suspected of damaging fertility
or the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquatic life with long
lasting effects
Precautionary statements (GHS)
:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust, fume, gas,
mist, vapours, spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-
ventilated area. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves,
protective clothing, eye protection, face protection. [In case of inadequate ventilation] wear respiratory protection. If swallowed: rinse mouth. Do
NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person
to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Immediately call a poison center/doctor. If skin irritation or rash
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 2/10
occurs: Get medical advice/attention. If experiencing respiratory symptoms: Call a poison center/doctor. Take off contaminated clothing and wash it
before reuse. Collect spillage. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container to
hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation
Other hazards
No additional information available
Unknown acute toxicity
No additional information available
SECTION 3: Composition/information on ingredients
Substance
Not applicable
Mixtures
Name Product identifier %
Formaldehyde, polymer with N,N’-bis(2-aminoethyl)-1,2-ethanediamine and phenol
(CAS No) 32610-77-8 10 – 40
Benzyl alcohol
(CAS No) 100-51-6 10 – 40
Mercaptan-terminated polymer (Non-hazarddous)
(CAS No) Not available 10 – 40
Triethylenetetramine
(CAS No) 112-24-3 1 – 15
Alicylic aliphatic polyamine
(CAS No) Trade Secret 1 – 10
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine)
(CAS No) 57214-10-5 1 – 10
Silica, amorphous, fumed, crystalline-free
(CAS No) 112945-52-5 1 – 10
1-Piperazineethanamine
(CAS No) 140-31-8 1 – 10
Phenol
(CAS No) 108-95-2 1 – 10
Diethylenetriamine-bisphenol A-epichlorohydrin polymer
(CAS No) 31326-29-1 1 – 10
Alkyletheramine
(CAS No) Trade Secret 1 – 10
Alkylphenol
(CAS No) Trade Secret 1 – 10
1,3-Benzenedimethanamine
(CAS No) 1477-55-0 1 – 5
Diethylenetriamine
(CAS No) 111-40-0 0.1 – 2
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold. Refer to Section 15 for additional information regarding this CBI claim.
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Immediately call a POISON CENTER or
doctor/physician.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 3/10
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Nitrogen oxides.
Amines. Ammonia. Nitric acid. Aldehydes. Nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions.
Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it
can ignite the sawdust.
Reactivity : No dangerous reaction known under conditions of normal use.
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA). Use water spray or fog for cooling exposed containers.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available
Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
Methods and material for containment and cleaning up
For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or other combustible
absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Do not swallow. Handle and open container with care. Use only outdoors or in a well-ventilated
area. Do not get in eyes, on skin, or on clothing. Do not breathe dust, fume, gas, mist, vapours,
spray. Do not eat, drink or smoke when using this product. Use personal protective equipment
as required. When mixed with epoxy resin this product causes an exothermic reaction, which in
large masses, can produce enough heat to damage or ignite surrounding materials and emit
fumes and vapors that vary widely in composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Do not eat, drink or smoke when using this product. Contaminated work clothing should not be
allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep locked up and out of reach of children. Keep container tightly closed. Keep only in the
original container in a cool, well-ventilated place. Protect from moisture. Storage temperature :
40 F (4 C) – 90 F (32 C).
SECTION 8: Exposure controls/personal protection
Control parameters
Formaldehyde, polymer with N,N’-bis(2-aminoethyl)-1,2-ethanediamine and phenol (32610-77-8)
Not applicable
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 4/10
Benzyl alcohol (100-51-6)
AIHA WEEL TWA (ppm) 10 ppm
Mercaptan-terminated polymer (Non-hazarddous) (Not available)
Not applicable
Triethylenetetramine (112-24-3)
AIHA WEEL TWA (mg/m ) 6 mg/m (Absorbed via skin)
AIHA WEEL TWA (ppm) 1 ppm
Alicylic aliphatic polyamine (Trade Secret)
Not applicable
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (57214-10-5)
Not applicable
Silica, amorphous, fumed, crystalline-free (112945-52-5)
ACGIH ACGIH TWA (mg/m ) 10 mg/m (Inhalable)
3 mg/m (Respirable)
OSHA OSHA PEL (TWA) (mg/m ) 6 mg/m (Amorphous silica)
15 mg/m (Total dust)
5 mg/m (Respirable)
1-Piperazineethanamine (140-31-8)
Not applicable
Phenol (108-95-2)
ACGIH ACGIH TWA (mg/m ) 19 mg/m
ACGIH ACGIH TWA (ppm) 5 ppm
OSHA OSHA PEL (TWA) (mg/m ) 19 mg/m
OSHA OSHA PEL (TWA) (ppm) 5 ppm
IDLH US IDLH (ppm) 250 ppm
NIOSH NIOSH REL (TWA) (mg/m ) 19 mg/m
NIOSH NIOSH REL (TWA) (ppm) 5 ppm
NIOSH NIOSH REL (ceiling) (mg/m ) 60 mg/m
NIOSH NIOSH REL (ceiling) (ppm) 15.6 ppm
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
Not applicable
Alkyletheramine (Trade Secret)
Not applicable
Alkylphenol (Trade Secret)
Not applicable
1,3-Benzenedimethanamine (1477-55-0)
ACGIH ACGIH Ceiling (mg/m ) 0.1 mg/m
NIOSH NIOSH REL (ceiling) (mg/m ) 0.1 mg/m
Diethylenetriamine (111-40-0)
ACGIH ACGIH TWA (ppm) 1 ppm
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 5/10
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Gel
Colour : Colourless
Odour : Ammonia
Odour threshold : No data available
pH : 11.2
Melting point : No data available
Freezing point : No data available
Boiling point : > 400 F (204 C) (estimated based on similar product)
Flash point : > 200 F (93 C) (estimated based similar product)
)
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Not flammable
Vapour pressure : < 1 mm Hg (estimated based on ingredient data)
Relative vapour density at 20 C : No data available
Relative density : 1.05
Solubility : No data available
Partition coefficient n-octanol/water : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
Other information
VOC content : 8.65 g/l (0.07 lb/gal)
Bulk density : 8.75 lb/gal (1.05kg/L)
SECTION 10: Stability and reactivity
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an epoxy resin will cause irreversible polymerization with significant heat
buildup and pressure.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Acids. Oxidizing materials. Halogenated compounds.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon. Nitrogen oxides. Amines. Ammonia. Nitric
acid. Aldehydes. Nitrosamines.
SECTION 11: Toxicological information
Information on toxicological effects
Benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 6/10
Benzyl alcohol (100-51-6)
LC50 inhalation rat > 4.18 mg/l/4h
Triethylenetetramine (112-24-3)
LD50 oral rat 1716 mg/kg
LD50 dermal rabbit 1465 mg/kg
Silica, amorphous, fumed, crystalline-free (112945-52-5)
LD50 oral rat > 5000 mg/kg
LD50 dermal rabbit > 2000 mg/kg
1-Piperazineethanamine (140-31-8)
LD50 oral rat 2097 mg/kg
LD50 dermal rabbit 866 mg/kg
Phenol (108-95-2)
LD50 oral rat 317 mg/kg
LD50 dermal rabbit 630 mg/kg (Solid)
LC50 inhalation rat 0.9 mg/l/8h (Solid)
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
LD50 oral rat 1620 mg/kg
1,3-Benzenedimethanamine (1477-55-0)
LD50 oral rat 980 mg/kg
LD50 dermal rabbit 2000 mg/kg
LC50 inhalation rat 1.34 mg/l/4h
Diethylenetriamine (111-40-0)
LD50 oral rat 1080 mg/kg
LD50 dermal rabbit 1090 mg/kg
LC50 inhalation rat 0.07 – 0.3 mg/l/4h
Acute toxicity (oral) : Harmful if swallowed.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Harmful if inhaled.
Skin corrosion/irritation : Causes severe skin burns.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction.
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : Not classified.
Silica, amorphous, fumed, crystalline-free (112945-52-5)
IARC group 3 – Not classifiable
Phenol (108-95-2)
IARC group 3 – Not classifiable
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified.
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Harmful if swallowed.
Symptoms/injuries after inhalation : Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 7/10
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
SECTION 12: Ecological information
Toxicity
Ecology – general : Toxic to aquatic life with long lasting effects.
Benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 1 23 mg/l (Exposure time: 48 h – Species: water flea)
LC50 fish 2 10 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])
Triethylenetetramine (112-24-3)
LC50 fish 1 570 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
EC50 Daphnia 1 31.1 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 495 mg/l (Exposure time: 96 h – Species: Pimephales promelas)
1-Piperazineethanamine (140-31-8)
LC50 fish 1 1950 – 2460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 32 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 > 1000 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
Phenol (108-95-2)
LC50 fish 1 11.9 – 50.5 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 4.24 – 10.7 mg/l (Exposure time: 48 h – Species: Daphnia magna [Static])
LC50 fish 2 20.5 – 25.6 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 2 10.2 – 15.5 mg/l (Exposure time: 48 h – Species: Daphnia magna)
Diethylenetriamine (111-40-0)
LC50 fish 1 248 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [static])
EC50 Daphnia 1 16 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 1014 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
Persistence and degradability
PRO-SET ADV-273-NC HARDENER
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET ADV-273-NC HARDENER
Bioaccumulative potential Not established.
Benzyl alcohol (100-51-6)
Partition coefficient n-octanol/water 1.1
Triethylenetetramine (112-24-3)
BCF fish 1 (no bioaccumulation expected)
Partition coefficient n-octanol/water -1.4
1-Piperazineethanamine (140-31-8)
BCF fish 1 (no bioaccumulation expected)
Partition coefficient n-octanol/water -1.48
Phenol (108-95-2)
BCF fish 1 (no significant bioaccumulation)
Partition coefficient n-octanol/water 1.5
Diethylenetriamine (111-40-0)
BCF fish 1 0.3 – 1.7
Partition coefficient n-octanol/water -1.3
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 8/10
Mobility in soil
PRO-SET ADV-273-NC HARDENER
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Name Product identifier Ecotoxicity Classification Information
Formaldehyde, polymer with N,N’-bis(2-aminoethyl)-1,2-ethanediamine and phenol
(CAS No) 32610-77-8 Aquatic Chronic Cat. 3
Benzyl alcohol
(CAS No) 100-51-6 No data available
Mercaptan-terminated polymer (Non-hazarddous)
(CAS No) Trade Secret No data available
Triethylenetetramine
(CAS No) 112-24-3 Aquatic Chronic Cat. 3
Alicylic aliphatic polyamine
(CAS No) Trade Secret No data available
Formaldehyde, oligomeric reaction products with phenol and m-
phenylenebis(methylamine)
(CAS No) 57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Silica, amorphous, fumed, crystalline-free
(CAS No) 112945-52-5 No data available
1-Piperazineethanamine
(CAS No) 140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Phenol
(CAS No) 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Diethylenetriamine-bisphenol A-epichlorohydrin polymer
(CAS No) 31326-29-1 No data available
Alkyletheramine
(CAS No) Trade Secret No data available
Alkylphenol
(CAS No) Trade Secret Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
1,3-Benzenedimethanamine
(CAS No) 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Diethylenetriamine
(CAS No) 111-40-0 No data available
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT and TDG
UN-No.(DOT/TDG) : UN3259
Proper Shipping Name (DOT/TDG) : Polyamines, solid, corrosive n.o.s. (Triethylenetetramine)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : III
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 3259
Proper Shipping Name (IMDG) : POLYAMINES, SOLID, CORROSIVE, N.O.S . (Triethylenetetramine)
Class (IMDG) : 8
Packing group (IMDG) : III
EmS Number : F-A, S-B
Marine pollutant : Yes
Transport by air
In accordance with IATA
UN-No. (IATA) : 3259
Proper Shipping Name (IATA) : Polyamines, solid, corrosive, n.o.s. (Triethylenetetramine)
Class (IATA) : 8
Packing group (IATA) : III
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 9/10
Marine pollutant : Yes
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Formaldehyde, polymer with N,N’-bis(2-aminoethyl)-1,2-ethanediamine and phenol (32610-77-8)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (57214-10-5)
EPA TSCA Regulatory Flag P – P – indicates a commenced PMN substance.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Phenol (108-95-2)
Listed on the United States SARA Section 302
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 302 Threshold Planning
Quantity (TPQ)
500 – 10000 lb
SARA Section 313 – Emission Reporting 1 %
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Canada WHMIS Confidential Business Information (CBI): The HMIRA number issued for this CBI claim is #11231. The date of filing is 2017-04-26
International regulations
No additional information available
US State regulations
California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm
Benzyl alcohol (100-51-6)
U.S. – Pennsylvania – RTK (Right to Know) List
Triethylenetetramine (112-24-3)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
1-Piperazineethanamine (140-31-8)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
Phenol (108-95-2)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – Pennsylvania – RTK (Right to Know) List
1,3-Benzenedimethanamine (1477-55-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 10/10
Diethylenetriamine (111-40-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
SECTION 16: Other information
Date of issue : 06/01/2015
Revision date : 05/12/2017
Other information : None.
NFPA health hazard : 3
NFPA fire hazard : 1
NFPA reactivity : 0
HMIS III Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 08SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-176-QC
APPLICABLE PRODUCT CODE S: ………………. ADV-176-QC, ADV-176-QC-0, ADV-176-QC-1, ADV-176-QC-2, ADV-176-QC-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-176-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 45-70
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 10-30
PRO-SET
ADV-176-QC
Page 2 of 6 Last Revised: 08SEP22
Epoxy-CTBN rubber adduct 68610-73-1 7-30
Glass oxide, spheres 65997-17-3 1-5
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS:………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash skin and hands thoroughly after
handling. Launder contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken
when curing product in large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can
produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
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ADV-176-QC
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depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
This product contains glass oxide, non-fibrous spheres. No significant exposure is expected to occur during use of products in which these
spheres are present in a liquid dispersion or bound to other materials, such as in epoxies. Risk of overexposure by way of inhalation depends on
actual concentration in the formula and duration and level of exposure to airborne particulate generated from sanding or similar machining
operations.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
Epoxy-CTBN rubber adduct 68610-73-1 No data available.
Glass oxide, spheres 65997-17-3 Particulate Not Otherwise Regulated; 15 mg/m3
total dust; 5 mg/m3 respirable
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Yellow.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
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11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
Epoxy-CTBN rubber adduct 68610-73-1 ATE >2000 mg/kg ATE >2000 mg/kg No data
Glass oxide, spheres 65997-17-3
No data
No data
No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSIT IZATION: ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Does not meet acute aquatic toxicity requirements.
CHRONIC AQUATIC TOXICITY: ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
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MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 Not classified.
Epoxy-CTBN rubber adduct 68610-73-1
Aquatic Chronic Cat. 2
Glass oxide, spheres 65997-17-3 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 68610-73-1 listed on NDSL only. All other ingredients are DSL listed
or otherwise compliant.
Australia AICS No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
Japan ENCS Not determined.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC Not determined.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
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US EPA TSCA Requirements: ..................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): ........ No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the Health and Physical classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Changes to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 8, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-176-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 06/24/2016 Revision date: 05/12/2017 Version: ADV-276-QC-2017a
05/12/2017 EN (English) Page 1
SECTION 1: Identification
Identification
Product form : Mixtures
Product name : PRO-SET ADV-276-QC HARDENER
Product code : ADV-276-QC, ADV-276-QC-0, ADV-276-QC-2, ADV-276-QC-4
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy adhesive resins
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 888-377-6738 or 989-684-7286
www.prosetepoxy.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Acute Tox. 4 (Oral)
Acute Tox. 4 (Inhalation)
Skin Corr. 1B
Eye Dam. 1
Resp. Sens. 1
Skin Sens. 1
Muta. 2
Repr. 2
STOT SE 3
STOT RE 2
Aquatic Acute 2
Aquatic Chronic 2
Label elements
Hazard pictograms (GHS) :
GHS05
GHS07
GHS08
GHS09
Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed or if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma
symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing genetic defects. Suspected of damaging fertility
or the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquatic life with long
lasting effects
Precautionary statements (GHS)
:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust, fume, gas,
mist, vapours, spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-
ventilated area. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves,
protective clothing, eye protection, face protection. [In case of inadequate ventilation] wear respiratory protection. If swallowed: rinse mouth. Do
NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person
to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Immediately call a poison center/doctor. Wash contaminated
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 2/10
clothing before reuse. Collect spillage. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container
to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation
Other hazards
No additional information available
Unknown acute toxicity
No additional information available
SECTION 3: Composition/information on ingredients
Substance
Not applicable
Mixtures
Name Product identifier %
Formaldehyde, polymer with 5-amino-1,3,3-trimethylcyclohexanemethanamine and phenol
(CAS No) 25265-17-2 5 – 40
Propylene glycol diamine, 2-amino-, diether with Propylene
(CAS No) 9046-10-0 10 – 40
2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-
piperazinyl)ethyl]amino]butyl-terminated
(CAS No) 68683-29-4 10 – 40
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine)
(CAS No) 57214-10-5 10 – 40
Isophorone diamine
(CAS No) 2855-13-2 1 – 15
Alicylic aliphatic polyamine
(CAS No) Trade Secret 1 – 10
Phenol
(CAS No) 108-95-2 1 – 10
Silica, amorphous, fumed, crystalline-free
(CAS No) 112945-52-5 1 – 10
Glass, oxide, chemicals
(CAS No) 65997-17-3 1 – 10
Alkyletheramine
(CAS No) Trade Secret 1 – 10
1,3-Benzenedimethanamine
(CAS No) 1477-55-0 1 – 5
Diethylenetriamine-bisphenol A-epichlorohydrin polymer
(CAS No) 31326-29-1 1 – 5
Diethylenetriamine
(CAS No) 111-40-0 0.1 – 1.5
1-Piperazineethanamine
(CAS No) 140-31-8 0.1 – 1.5
Alkylphenol
(CAS No) Trade Secret 0.1 – 1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold. Refer to Section 15 for additional information regarding this CBI claim.
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Immediately call a POISON CENTER or
doctor/physician.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 3/10
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Nitrogen oxides.
Amines. Ammonia. Nitric acid. Aldehydes. Nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions.
Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it
can ignite the sawdust.
Reactivity : No dangerous reaction known under conditions of normal use.
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA). Use water spray or fog for cooling exposed containers.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available
Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
Methods and material for containment and cleaning up
For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or other combustible
absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust, fume, gas, mist, vapours,
spray. Do not swallow. Handle and open container with care. When using do not eat, drink or
smoke. Use only outdoors or in a well-ventilated area. Use personal protective equipment as
required. When mixed with epoxy resin this product causes an exothermic reaction, which in
large masses, can produce enough heat to damage or ignite surrounding materials and emit
fumes and vapors that vary widely in composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Do not eat, drink or smoke when using this product. Contaminated work clothing should not be
allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Keep only in the original
container in a cool, well-ventilated place. Protect from moisture. Storage temperature : 40 F
(4 C) – 90 F (32 C).
SECTION 8: Exposure controls/personal protection
Control parameters
Formaldehyde, polymer with 5-amino-1,3,3-trimethylcyclohexanemethanamine and phenol (25265-17-2)
Not applicable
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 4/10
Propylene glycol diamine, 2-amino-, diether with Propylene (9046-10-0)
Not applicable
2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated (68683-29-4)
Not applicable
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (57214-10-5)
Not applicable
Isophorone diamine (2855-13-2)
Not applicable
Alicylic aliphatic polyamine (Trade Secret)
Not applicable
Phenol (108-95-2)
ACGIH ACGIH TWA (mg/m ) 19 mg/m
ACGIH ACGIH TWA (ppm) 5 ppm
OSHA OSHA PEL (TWA) (mg/m ) 19 mg/m
OSHA OSHA PEL (TWA) (ppm) 5 ppm
IDLH US IDLH (ppm) 250 ppm
NIOSH NIOSH REL (TWA) (mg/m ) 19 mg/m
NIOSH NIOSH REL (TWA) (ppm) 5 ppm
NIOSH NIOSH REL (ceiling) (mg/m ) 60 mg/m
NIOSH NIOSH REL (ceiling) (ppm) 15.6 ppm
Silica, amorphous, fumed, crystalline-free (112945-52-5)
ACGIH ACGIH TWA (mg/m ) 10 mg/m (Inhalable)
3 mg/m (Respirable)
OSHA OSHA PEL (TWA) (mg/m ) 6 mg/m (Amorphous silica)
15 mg/m (Total dust)
5 mg/m (Respirable)
Glass, oxide, chemicals (65997-17-3)
ACGIH ACGIH TWA (mg/m ) 10 mg/m (Inhalable)
3 mg/m (Respirable)
OSHA OSHA PEL (TWA) (mg/m ) 15 mg/m (Total dust)
5 mg/m (Respirable)
Alkyletheramine (Trade Secret)
Not applicable
1,3-Benzenedimethanamine (1477-55-0)
ACGIH ACGIH Ceiling (mg/m ) 0.1 mg/m
NIOSH NIOSH REL (ceiling) (mg/m ) 0.1 mg/m
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
Not applicable
Diethylenetriamine (111-40-0)
ACGIH ACGIH TWA (ppm) 1 ppm
1-Piperazineethanamine (140-31-8)
Not applicable
Alkylphenol (Trade Secret)
Not applicable
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 5/10
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Gel
Colour : Blue
Odour : Ammonia
Odour threshold : No data available
pH : 10-12.5 (estimated based on ingredient data)
Melting point : No data available
Freezing point : No data available
Boiling point : > 400 F (204 C) (estimated based on similar product)
Flash point : > 200 F (93 C) (estimated based similar product)
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Non flammable.
Vapour pressure : < 1 mm Hg (estimated based on ingredient data)
Relative vapour density at 20 C : No data available
Relative density : 1.04
Solubility : No data available
Partition coefficient n-octanol/water : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
Other information
VOC content : ADV-176 / ADV-276: 7.69 g/L (0.06 lb/gal); ADV-175 / ADV-276: 4.34 g/L (0.04 lb/gal)
Bulk density : 8.65 lb/gal (1.04 kg/L)
SECTION 10: Stability and reactivity
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an epoxy resin will cause irreversible polymerization with significant heat
buildup and pressure.
Conditions to avoid : Heat. Incompatible materials.
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 6/10
Incompatible materials : Acids. Oxidizing materials. Halogenated compounds.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon. Nitrogen oxides. Amines. Ammonia. Nitric
acid. Aldehydes. Nitrosamines.
SECTION 11: Toxicological information
Information on toxicological effects
Propylene glycol diamine, 2-amino-, diether with Propylene (9046-10-0)
LD50 oral rat 2855 mg/kg
LD50 dermal rabbit 2890 mg/kg
LC50 inhalation rat > 0.74 mg/l/8h
Isophorone diamine (2855-13-2)
LD50 oral rat 1030 mg/kg
LD50 dermal rabbit > 2000 mg/kg
LC50 inhalation rat > 5.01 mg/l/4h
Phenol (108-95-2)
LD50 oral rat 317 mg/kg
LD50 dermal rabbit 630 mg/kg
LC50 inhalation rat 0.9 mg/l/8h
Silica, amorphous, fumed, crystalline-free (112945-52-5)
LD50 oral rat > 5000 mg/kg
LD50 dermal rabbit > 2000 mg/kg
1,3-Benzenedimethanamine (1477-55-0)
LD50 oral rat 980 mg/kg
LD50 dermal rabbit 2000 mg/kg
LC50 inhalation rat 1.34 mg/l/4h
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
LD50 oral rat 1620 mg/kg
Diethylenetriamine (111-40-0)
LD50 oral rat 1080 mg/kg
LD50 dermal rabbit 1090 mg/kg
LC50 inhalation rat 0.07 – 0.3 mg/l/4h
1-Piperazineethanamine (140-31-8)
LD50 oral rat 2097 mg/kg
LD50 dermal rabbit 866 mg/kg
Acute toxicity (oral) : Harmful if swallowed.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Harmful if inhaled.
Skin corrosion/irritation : Causes severe skin burns.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction.
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : Not classified.
Phenol (108-95-2)
IARC group 3 – Not classifiable
Silica, amorphous, fumed, crystalline-free (112945-52-5)
IARC group 3 – Not classifiable
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 7/10
STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified.
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Harmful if swallowed.
Symptoms/injuries after inhalation : Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
SECTION 12: Ecological information
Toxicity
Ecology – general : Toxic to aquatic life with long lasting effects.
Isophorone diamine (2855-13-2)
EC50 Daphnia 1 14.6 – 21.5 mg/l (Exposure time: 48 h – Species: Daphnia magna [semi-static])
Phenol (108-95-2)
LC50 fish 1 11.9 – 50.5 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 4.24 – 10.7 mg/l (Exposure time: 48 h – Species: Daphnia magna [Static])
LC50 fish 2 20.5 – 25.6 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 2 10.2 – 15.5 mg/l (Exposure time: 48 h – Species: Daphnia magna)
Diethylenetriamine (111-40-0)
LC50 fish 1 248 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [static])
EC50 Daphnia 1 16 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 1014 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
1-Piperazineethanamine (140-31-8)
LC50 fish 1 1950 – 2460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 32 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 > 1000 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
Persistence and degradability
PRO-SET ADV-276-QC HARDENER
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET ADV-276-QC HARDENER
Bioaccumulative potential Not established.
Isophorone diamine (2855-13-2)
Partition coefficient n-octanol/water 0.79 (at 23 C)
Phenol (108-95-2)
BCF fish 1 (no significant bioaccumulation)
Partition coefficient n-octanol/water 1.5
Diethylenetriamine (111-40-0)
BCF fish 1 0.3 – 1.7
Partition coefficient n-octanol/water -1.3
1-Piperazineethanamine (140-31-8)
BCF fish 1 (no bioaccumulation expected)
Partition coefficient n-octanol/water -1.48
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 8/10
Mobility in soil
PRO-SET ADV-276-QC HARDENER
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Name Product identifier Ecotoxicity Classification Information
Formaldehyde, polymer with 5-amino-1,3,3-trimethylcyclohexanemethanamine and
phenol
(CAS No) 25265-17-2 No data available
Propylene glycol diamine, 2-amino-, diether with Propylene
(CAS No) 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-
piperazinyl)ethyl]amino]butyl-terminated
(CAS No) 68683-29-4 No data available
Formaldehyde, oligomeric reaction products with phenol and m-
phenylenebis(methylamine)
(CAS No) 57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Isophorone diamine
(CAS No) 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Alicylic aliphatic polyamine
(CAS No) Trade Secret No data available
Phenol
(CAS No) 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Silica, amorphous, fumed, crystalline-free
(CAS No) 112945-52-5 No data available
Glass, oxide, chemicals
(CAS No) 65997-17-3 No data available
Alkyletheramine
(CAS No) Trade Secret No data available
1,3-Benzenedimethanamine
(CAS No) 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Diethylenetriamine-bisphenol A-epichlorohydrin polymer
(CAS No) 31326-29-1 No data available
Diethylenetriamine
(CAS No) 111-40-0 No data available
1-Piperazineethanamine
(CAS No) 140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Alkylphenol
(CAS No) Trade Secret Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT and TDG
UN-No.(DOT/TDG) : UN3259
Proper Shipping Name (DOT/TDG) : Polyamines, solid, corrosive n.o.s. (Polyoxypropylenediamine)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : III
Marine pollutant : No
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 3259
Proper Shipping Name (IMDG) : POLYAMINES, SOLID, CORROSIVE, N.O.S . (Polyoxypropylenediamine)
Class (IMDG) : 8
Packing group (IMDG) : III
EmS Number : F-A, S-B
Marine pollutant : Yes
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 9/10
Transport by air
In accordance with IATA
UN-No. (IATA) : 3259
Proper Shipping Name (IATA) : Polyamines, solid, corrosive, n.o.s. (Polyoxypropylenediamine)
Class (IATA) : 8
Packing group (IATA) : III
Marine pollutant : Yes
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Formaldehyde, polymer with 5-amino-1,3,3-trimethylcyclohexanemethanamine and phenol (25265-17-2)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Propylene glycol diamine, 2-amino-, diether with Propylene (9046-10-0)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated (68683-29-4)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (57214-10-5)
EPA TSCA Regulatory Flag P – P – indicates a commenced PMN substance.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Phenol (108-95-2)
Listed on the United States SARA Section 302
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 302 Threshold Planning
Quantity (TPQ)
500 – 10000 lb
SARA Section 313 – Emission Reporting 1 %
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Propylene oxide (75-56-9)
Listed on the United States SARA Section 302
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 100 lb
SARA Section 302 Threshold Planning
Quantity (TPQ)
10000 lb
SARA Section 313 – Emission Reporting 0.1 %
Canada WHMIS Confidential Business Information (CBI): The HMIRA number issued for this CBI claim is #11234. The date of filing is 2017-04-26.
International regulations
No additional information available
PRO-SET ADV-276-QC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 10/10
US State regulations
California Proposition 65 – This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause
cancer, developmental and/or reproductive harm
Propylene oxide (75-56-9)
U.S. – California –
Proposition 65 –
Carcinogens List
U.S. – California –
Proposition 65 –
Developmental Toxicity
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Female
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Male
Non-significant risk
level (NSRL)
Yes No No No
Isophorone diamine (2855-13-2)
U.S. – New Jersey – Right to Know Hazardous Substance List
Phenol (108-95-2)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – Pennsylvania – RTK (Right to Know) List
1,3-Benzenedimethanamine (1477-55-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
Diethylenetriamine (111-40-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
1-Piperazineethanamine (140-31-8)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
Propylene oxide (75-56-9)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – Pennsylvania – RTK (Right to Know) – Special Hazardous Substances
U.S. – Pennsylvania – RTK (Right to Know) List
SECTION 16: Other information
Date of issue : 06/24/2016
Revision date : 05/12/2017
Other information : None.
NFPA health hazard : 3
NFPA fire hazard : 1
NFPA reactivity : 0
HMIS III Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-176-NC
APPLICABLE PRODUCT CODES: ………………. ADV-176-NC, ADV-176-NC-0, ADV-176-NC-1, ADV-176-NC-2, ADV-176-NC-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-176-NC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 45-70
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 10-30
PRO-SET
ADV-176-NC
Page 2 of 6 Last Revised: 12SEP22
Epoxy-CTBN rubber adduct 68610-73-1 7-30
Glass oxide, spheres 65997-17-3 1-5
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS:………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
PRO-SET
ADV-176-NC
Page 3 of 6 Last Revised: 12SEP22
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
This product contains glass oxide, non-fibrous spheres. No significant exposure is expected to occur during use of products in which these
spheres are present in a liquid dispersion or bound to other materials, such as in epoxies. Risk of overexposure by way of inhalation depends on
actual concentration in the formula and duration and level of exposure to airborne particulate generated from sanding or similar machining
operations.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIM ITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
Epoxy-CTBN rubber adduct 68610-73-1 No data available.
Glass oxide, spheres 65997-17-3 Particulate Not Otherwise Regulated; 15 mg/m3
total dust; 5 mg/m3 respirable
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
PRO-SET
ADV-176-NC
Page 4 of 6 Last Revised: 12SEP22
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
Epoxy-CTBN rubber adduct 68610-73-1 ATE >2000 mg/kg ATE >2000 mg/kg No data
Glass oxide, spheres 65997-17-3
No data
No data
No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Does not meet acute aquatic toxicity requirements.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
PRO-SET
ADV-176-NC
Page 5 of 6 Last Revised: 12SEP22
ADDITIONAL ECOTOXICITY INFORMATION: ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 Not classified.
Epoxy-CTBN rubber adduct 68610-73-1
Aquatic Chronic Cat. 2
Glass oxide, spheres 65997-17-3 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 68610-73-1 listed on NDSL only. All other ingredients are DSL listed
or otherwise compliant.
Australia AICS No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
Japan ENCS Not determined.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC Not determined.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
US EPA TSCA Requirements: ..................................................... No data available.
PRO-SET
ADV-176-NC
Page 6 of 6 Last Revised: 12SEP22
Canada WHMIS Confidential Business Information (CBI): ........ No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Changes to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-176-NC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 08SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-176-QC
APPLICABLE PRODUCT CODE S: ………………. ADV-176-QC, ADV-176-QC-0, ADV-176-QC-1, ADV-176-QC-2, ADV-176-QC-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-176-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 45-70
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 10-30
PRO-SET
ADV-176-QC
Page 2 of 6 Last Revised: 08SEP22
Epoxy-CTBN rubber adduct 68610-73-1 7-30
Glass oxide, spheres 65997-17-3 1-5
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS:………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash skin and hands thoroughly after
handling. Launder contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken
when curing product in large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can
produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
PRO-SET
ADV-176-QC
Page 3 of 6 Last Revised: 08SEP22
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
This product contains glass oxide, non-fibrous spheres. No significant exposure is expected to occur during use of products in which these
spheres are present in a liquid dispersion or bound to other materials, such as in epoxies. Risk of overexposure by way of inhalation depends on
actual concentration in the formula and duration and level of exposure to airborne particulate generated from sanding or similar machining
operations.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
Epoxy-CTBN rubber adduct 68610-73-1 No data available.
Glass oxide, spheres 65997-17-3 Particulate Not Otherwise Regulated; 15 mg/m3
total dust; 5 mg/m3 respirable
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Yellow.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
PRO-SET
ADV-176-QC
Page 4 of 6 Last Revised: 08SEP22
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
Epoxy-CTBN rubber adduct 68610-73-1 ATE >2000 mg/kg ATE >2000 mg/kg No data
Glass oxide, spheres 65997-17-3
No data
No data
No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSIT IZATION: ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Does not meet acute aquatic toxicity requirements.
CHRONIC AQUATIC TOXICITY: ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
PRO-SET
ADV-176-QC
Page 5 of 6 Last Revised: 08SEP22
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 Not classified.
Epoxy-CTBN rubber adduct 68610-73-1
Aquatic Chronic Cat. 2
Glass oxide, spheres 65997-17-3 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 68610-73-1 listed on NDSL only. All other ingredients are DSL listed
or otherwise compliant.
Australia AICS No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
Japan ENCS Not determined.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC Not determined.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
PRO-SET
ADV-176-QC
Page 6 of 6 Last Revised: 08SEP22
US EPA TSCA Requirements: ..................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): ........ No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the Health and Physical classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Changes to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 8, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-176-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-176-NC
APPLICABLE PRODUCT CODES: ………………. ADV-176-NC, ADV-176-NC-0, ADV-176-NC-1, ADV-176-NC-2, ADV-176-NC-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-176-NC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 45-70
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 10-30
PRO-SET
ADV-176-NC
Page 2 of 6 Last Revised: 12SEP22
Epoxy-CTBN rubber adduct 68610-73-1 7-30
Glass oxide, spheres 65997-17-3 1-5
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS:………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
PRO-SET
ADV-176-NC
Page 3 of 6 Last Revised: 12SEP22
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
This product contains glass oxide, non-fibrous spheres. No significant exposure is expected to occur during use of products in which these
spheres are present in a liquid dispersion or bound to other materials, such as in epoxies. Risk of overexposure by way of inhalation depends on
actual concentration in the formula and duration and level of exposure to airborne particulate generated from sanding or similar machining
operations.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIM ITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
Epoxy-CTBN rubber adduct 68610-73-1 No data available.
Glass oxide, spheres 65997-17-3 Particulate Not Otherwise Regulated; 15 mg/m3
total dust; 5 mg/m3 respirable
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
PRO-SET
ADV-176-NC
Page 4 of 6 Last Revised: 12SEP22
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
Epoxy-CTBN rubber adduct 68610-73-1 ATE >2000 mg/kg ATE >2000 mg/kg No data
Glass oxide, spheres 65997-17-3
No data
No data
No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Does not meet acute aquatic toxicity requirements.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
PRO-SET
ADV-176-NC
Page 5 of 6 Last Revised: 12SEP22
ADDITIONAL ECOTOXICITY INFORMATION: ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 Not classified.
Epoxy-CTBN rubber adduct 68610-73-1
Aquatic Chronic Cat. 2
Glass oxide, spheres 65997-17-3 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 68610-73-1 listed on NDSL only. All other ingredients are DSL listed
or otherwise compliant.
Australia AICS No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
Japan ENCS Not determined.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC Not determined.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
US EPA TSCA Requirements: ..................................................... No data available.
PRO-SET
ADV-176-NC
Page 6 of 6 Last Revised: 12SEP22
Canada WHMIS Confidential Business Information (CBI): ........ No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Changes to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-176-NC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-176-BK
APPLICABLE PRODUCT CODES: ………………. ADV-176-BK, ADV-176-BK-0, ADV-176-BK-1, ADV-176-BK-2, ADV-176-BK-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-176-BK-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 30-60
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 15-40
PRO-SET
ADV-176-BK
Page 2 of 7 Last Revised: 12SEP22
Epoxy-CTBN rubber adduct 68610-73-1 7-30
Glass oxide, spheres 65997-17-3 1-5
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUT IONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTEC TION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
PRO-SET
ADV-176-BK
Page 3 of 7 Last Revised: 12SEP22
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
This product contains Carbon Black (<1% by weight), which is listed by IARC as a Group 2B possibly carcinogenic to humans by IARC. No
significant inhalation exposure is expected to occur during use of products in which Carbon Black is present in a liquid dispersion or when bound
to other materials, such as in cured epoxies. Risk of overexposure depends on actual concentration in the formula and duration and level of
exposure to dust from sanding or similar machining operations of solidified product. When sanding or machining solidified product and creating an
airborne dust that may contain carbon black, consider the use of appropriate respiratory protection, such as a N95 particulate filter, or greater.
This product contains glass oxide, non-fibrous spheres. No significant exposure is expected to occur during use of products in which these
spheres are present in a liquid dispersion or bound to other materials, such as in epoxies. Risk of overexposure by way of inhalation depends on
actual concentration in the formula and duration and level of exposure to airborne particulate generated from sanding or similar machining
operations. Use and select a respirator according the guidelines established in OSHA 1910.134 or other applicable respiratory protection
standard.
ADDITIONAL PROTECTIVE MEASURES: ......................................... Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ............................................. Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
No data available.
Oxirane, 2,2'[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
Epoxy-CTBN rubber adduct 68610-73-1 No data available.
Glass oxide, spheres 65997-17-3 Particulate Not Otherwise Regulated; 15 mg/m3
total dust; 5 mg/m3 respirable
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ............................................................................. Gel.
COLOR: ............................................................................................. Colorless.
ODOR: ................................................................................................ Mild.
ODOR THRESHOLD: ......................................................................... No data available
pH ....................................................................................................... No data available
MELTING POINT / FREEZING POINT ................................................ No data available
BOILING POINT (760mm/Hg): ........................................................... > 400 F (204
C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
PRO-SET
ADV-176-BK
Page 4 of 7 Last Revised: 12SEP22
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
Epoxy-CTBN rubber adduct 68610-73-1 ATE >2000 mg/kg ATE >2000 mg/kg No data
Glass oxide, spheres 65997-17-3
No data
No data
No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8 >15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
This product contains Carbon Black, which is listed by IARC as a Group 2B possibly carcinogenic to humans by IARC. No significant inhalation
exposure is expected to occur during use of products in which Carbon Black is present in a liquid dispersion or bound to other materials, such as
in epoxies. Risk of overexposure depends on actual concentration in the formula and duration and level of exposure to dust from sanding or
similar machining operations. Refer to Section 8 respiratory protection information and Section 11 for toxicology information.
PRO-SET
ADV-176-BK
Page 5 of 7 Last Revised: 12SEP22
Study: Species: Rat, Route: Inhalation, Duration: 2 years, Target Organ: Lungs, Effect: Inflammation, fibrosis, tumors. Note: Tumors in the rat lung
are considered to be related to lung overload rather than to a specific chemical effect of the carbon black itself in the lung. These effects in rats
have been reported in many studies in other poorly soluble inorganic particles and appear to be rat specific (ILSI, 2000). Tumors have not been
observed in other species (Ex. mouse, hamster) for carbon black or other poorly soluble particles under similar circumstances and study
conditions.
In 2006, IARC re-affirmed its 1995 finding that there is inadequate evidence from human health studies to assess whether carbon black causes
cancer in humans. IARC concluded that there is sufficient evidence in animal studies for the carcinogenicity of carbon black. IARC s overall
assessment is that carbon black is possibly carcinogenic to humans (Group 2B) . This conclusion was based on IARC s guideline s, which
generally require such a classification if one species exhibits carcinogenicity in two or more animal studies (IARC, 2010). ACHIG classifies Carbon
Black as a confirmed animal carcinogen with unknown relevance to humans (Category A3).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Does not meet acute aquatic toxicity requirements.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
Information
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 Not classified.
Epoxy-CTBN rubber adduct 68610-73-1 Aquatic Chronic Cat. 2
Glass oxide, spheres 65997-17-3 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Not classified.
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PRO-SET
ADV-176-BK
Page 6 of 7 Last Revised: 12SEP22
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 68610-73-1 listed on NDSL only. All other ingredients are DSL listed
or otherwise compliant.
Australia AICS No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
Japan ENCS Not determined.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC Not determined.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC No data on CAS# 68610-73-1. All other ingredients are listed or otherwise
compliant.
US EPA TSCA Requirements: ..................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): ........ No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
Carbon black
1333-86-4 <1%
1, 2
CA, NJ, MA, PA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
2.
Carbon black, (airborne, unbound particles of respirable size) is a substance listed under California Proposition 65. As present in this product,
carbon black does not meet that listing criteria, as it is both bound in a liquid dispersion and therefore not respirable.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Changes to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-176-BK-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
PRO-SET
ADV-176-BK
Page 7 of 7 Last Revised: 12SEP22
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
2
