by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 08SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-175-QC
APPLICABLE PRODUCT CODES: ………………. ADV-175-QC, ADV-175-QC-0, ADV-175-QC-1, ADV-175-QC-2, ADV-175-QC-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-175-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 65-85
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 3-7
PRO-SET
ADV-175-QC
Page 2 of 6 Last Revised: 08SEP22
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 1-5
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERA TURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTION S: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
PRO-SET
ADV-175-QC
Page 3 of 6 Last Revised: 08SEP22
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIV E MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8
No data available.
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 No data available.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Yellow.
ODOR: …………………………………………………………………………………… Mild.
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C)
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8 >15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 17100 mg/kg >4500 mg/kg No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
PRO-SET
ADV-175-QC
Page 4 of 6 Last Revised: 08SEP22
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Not classified.
PRO-SET
ADV-175-QC
Page 5 of 6 Last Revised: 08SEP22
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis-
17557-23-2
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADATDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC Not determined.
US EPA TSCA Requirements: ..................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): ........ No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the Health and Physical Classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
PRO-SET
ADV-175-QC
Page 6 of 6 Last Revised: 08SEP22
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Change in Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 8, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-175-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-175-NC
APPLICABLE PRODUCT CODES: ………………. ADV-175-NC, ADV-175-NC-0, ADV-175-NC-1, ADV-175-NC-2, ADV-175-NC-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-175-NC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 65-85
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 3-7
PRO-SET
ADV-175-NC
Page 2 of 6 Last Revised: 12SEP22
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 1-5
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max. ): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
PRO-SET
ADV-175-NC
Page 3 of 6 Last Revised: 12SEP22
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8
No data available.
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 No data available.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C)
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, 25085-99-8 >15,000 mg/kg >23,000 mg/kg No data
PRO-SET
ADV-175-NC
Page 4 of 6 Last Revised: 12SEP22
polymers (rat) (rabbit)
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 17100 mg/kg >4500 mg/kg No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
PRO-SET
ADV-175-NC
Page 5 of 6 Last Revised: 12SEP22
Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5
Not classified.
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis-
17557-23-2
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC Not determined.
US EPA TSCA Requirements: ..................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): ........ No data available
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
PRO-SET
ADV-175-NC
Page 6 of 6 Last Revised: 12SEP22
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Change to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-175-NC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 08SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-175-QC
APPLICABLE PRODUCT CODES: ………………. ADV-175-QC, ADV-175-QC-0, ADV-175-QC-1, ADV-175-QC-2, ADV-175-QC-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-175-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 65-85
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 3-7
PRO-SET
ADV-175-QC
Page 2 of 6 Last Revised: 08SEP22
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 1-5
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERA TURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTION S: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
PRO-SET
ADV-175-QC
Page 3 of 6 Last Revised: 08SEP22
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIV E MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8
No data available.
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 No data available.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Yellow.
ODOR: …………………………………………………………………………………… Mild.
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C)
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8 >15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 17100 mg/kg >4500 mg/kg No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
PRO-SET
ADV-175-QC
Page 4 of 6 Last Revised: 08SEP22
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Not classified.
PRO-SET
ADV-175-QC
Page 5 of 6 Last Revised: 08SEP22
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis-
17557-23-2
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADATDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC Not determined.
US EPA TSCA Requirements: ..................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): ........ No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the Health and Physical Classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
PRO-SET
ADV-175-QC
Page 6 of 6 Last Revised: 08SEP22
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Change in Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 8, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-175-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-175-NC
APPLICABLE PRODUCT CODES: ………………. ADV-175-NC, ADV-175-NC-0, ADV-175-NC-1, ADV-175-NC-2, ADV-175-NC-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-175-NC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 65-85
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 3-7
PRO-SET
ADV-175-NC
Page 2 of 6 Last Revised: 12SEP22
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 1-5
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max. ): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
PRO-SET
ADV-175-NC
Page 3 of 6 Last Revised: 12SEP22
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8
No data available.
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 No data available.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C)
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.16
BULK DENSITY………………………………………………………………………. 9.67 lbs./gal. (1.16 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, 25085-99-8 >15,000 mg/kg >23,000 mg/kg No data
PRO-SET
ADV-175-NC
Page 4 of 6 Last Revised: 12SEP22
polymers (rat) (rabbit)
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 17100 mg/kg >4500 mg/kg No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
PRO-SET
ADV-175-NC
Page 5 of 6 Last Revised: 12SEP22
Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5
Not classified.
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis-
17557-23-2
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC Not determined.
US EPA TSCA Requirements: ..................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): ........ No data available
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
PRO-SET
ADV-175-NC
Page 6 of 6 Last Revised: 12SEP22
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Change to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-175-NC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-175-BK
APPLICABLE PRODUCT CODES: ………………. ADV-175-BK, ADV-175-BK-0, ADV-175-BK-1, ADV-175-BK-2, ADV-175-BK-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Pigmented adhesive resin for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-175-BK-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 65-85
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 3-7
PRO-SET
ADV-175-BK
Page 2 of 7 Last Revised: 12SEP22
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 1-5
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI).
Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present
at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
PRO-SET
ADV-175-BK
Page 3 of 7 Last Revised: 12SEP22
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
This product contains Carbon Black (<1% by weight), which is listed by IARC as a Group 2B possibly carcinogenic to humans by IARC. No
significant inhalation exposure is expected to occur during use of products in which Carbon Black is present in a liquid dispersion or when bound
to other materials, such as in cured epoxies. Risk of overexposure depends on actual concentration in the formula and duration and level of
exposure to dust from sanding or similar machining operations of solidified product. When sanding or machining solidified product and creating an
airborne dust that may contain carbon black, consider the use of appropriate respiratory protection, such as a N95 particulate filter or greater. Use
and select a respirator according the guidelines established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ......................................... Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ............................................. Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8
No data available.
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 No data available.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 No data available.
Oxirane, 2,2'[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ............................................................................. Gel.
COLOR: ............................................................................................. Black.
ODOR: ................................................................................................ Mild.
ODOR THRESHOLD: ......................................................................... No data available
pH ....................................................................................................... No data available
MELTING POINT / FREEZING POINT ................................................ No data available
BOILING POINT (760mm/Hg): ........................................................... > 400 F (204
C)
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.14
BULK DENSITY………………………………………………………………………. 9.50 lbs./gal. (1.14 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... No data mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
PRO-SET
ADV-175-BK
Page 4 of 7 Last Revised: 12SEP22
DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to thermal decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPO INT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8 >15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 17100 mg/kg >4500 mg/kg No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2
4500 mg/kg
>2000 mg/kg
No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
This product contains cresyl glycidyl ether (<1.0% by weight) which has shown mutagenic effects in in vitro tests. Literature Ames Tests showed
that o-cresyl glycidyl ether was a direct-acting mutagen in strains TA 1535 and TA 100, but was not mutagenic in TA 98. In an unscheduled DNA
synthesis assay, o-cresyl glycidyl ether produced significant increases in unscheduled DNA synthesis at 10 and 100 ppm. At 1000 ppm, o-cresyl
glycidyl ether produced a marked reduction in unscheduled DNA synthesis due to its cytotoxic effects. In a host-mediated micronucleus test in
mice, o-cresyl glycidyl ether was found not to be genotoxic.
CARCINOGENICITY: .......................................................................... Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
A two-year dermal study in mice produced skin tumors at doses greater than 1.87 mg Neopentyl Glycol Diglycidyl Ether per mouse per week
(Holland, 1981).
This product contains Carbon Black, which is listed by IARC as a Group 2B possibly carcinogenic to humans by IARC. No significant inhalation
exposure is expected to occur during use of products in which Carbon Black is present in a liquid dispersion or bound to other materials, such as
in epoxies. Risk of overexposure depends on actual concentration in the formula and duration and level of exposure to dust from sanding or
similar machining operations. Refer to Section 8 respiratory protection information and Section 11 for toxicology information.
Study: Species: Rat, Route: Inhalation, Duration: 2 years, Target Organ: Lungs, Effect: Inflammation, fibrosis, tumors. Note: Tumors in the rat lung
are considered to be related to lung overload rather than to a specific chemical effect of the carbon black itself in the lung. These effects in rats
have been reported in many studies in other poorly soluble inorganic particles and appear to be rat specific (ILSI, 2000). Tumors have not been
observed in other species (Ex. mouse, hamster) for carbon black or other poorly soluble particles under similar circumstances and study
conditions.
PRO-SET
ADV-175-BK
Page 5 of 7 Last Revised: 12SEP22
In 2006, IARC re-affirmed its 1995 finding that there is inadequate evidence from human health studies to assess whether carbon black causes
cancer in humans. IARC concluded that there is sufficient evidence in animal studies for the carcinogenicity of carbon black. IARC s overall
assessment is that carbon black is possibly carcinogenic to humans (Group 2B) . This conclusion was based on IARC s guideline s, which
generally require such a classification if one species exhibits carcinogenicity in two or more animal studies (IARC, 2010). ACHIG classifies Carbon
Black as a confirmed animal carcinogen with unknown relevance to humans (Category A3).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2
Oxirane, Mono[(C12-14-alkyloxy)methyl] Derivs. 68609-97-2 Not classified.
Synthetic Amorphous, Pyrogenic Silica 112945-52-5
Not classified.
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis-
17557-23-2
Not classified.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3077.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3077.
PRO-SET
ADV-175-BK
Page 6 of 7 Last Revised: 12SEP22
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC Not determined.
US EPA TSCA Requirements: ..................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): ........ No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the Health and Physical Classifications in Section 2.
Subject to Section 313 ................................................................ No data available.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
Carbon black
1333-86-4 <1%
1, 2
CA, NJ, MA, PA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
2.
Carbon black, (airborne, unbound particles of respirable size) is a substance listed under California Proposition 65. As present in this product,
carbon black does not meet that listing criteria, as it is both bound in a liquid dispersion and therefore not respirable.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Change to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-175-BK-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
2 1
1
PRO-SET
ADV-175-BK
Page 7 of 7 Last Revised: 12SEP22
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 0
3
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
PRO-SET LAM-237 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 05/25/2016 Revision date: 01/25/2019 Version: LAM-237 -2019a
01/25/2019 EN (English) Page 1
SECTION 1: Identification
Identification
Product form : Mixtures
Product name : PRO-SET LAM-237 Hardener
Product code : LAM-237, LAM-237-1, LAM-237-2, LAM-237-3, LAM-237-4, LAM-237-5, LAM-237-6
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy resins
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 888-377-6738 or 989-684-7286
www.prosetepoxy.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Acute Tox. 4 (Oral)
Acute Tox. 4 (Dermal)
Acute Tox. 4 (Inhalation)
Skin Corr. 1B
Eye Dam. 1
Skin Sens. 1
STOT RE 2
Asp. Tox. 1
Aquatic Acute 2
Aquatic Chronic 2
Label elements
Hazard pictograms (GHS) :
GHS05
GHS07
GHS08
GHS09
Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed, in contact with skin or if inhaled. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage.
May cause an allergic skin reaction. May cause damage to organs through prolonged or repeated exposure if swallowed. Toxic to aquatic life. Toxic
to aquatic life with long lasting effects
Precautionary statements (GHS)
:
Do not breathe dust, fume, gas, mist, vapours, spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the
environment. Wear protective gloves, protective clothing, eye protection, face protection. If swallowed: rinse mouth. Do NOT induce vomiting. If on
skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep
comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. IF exposed or concerned: Get medical attention/advice. Immediately call a poison center/doctor. If skin irritation or rash occurs: Get medical
advice/attention. Take off contaminated clothing and wash it before reuse. Collect spillage. Store locked up. Dispose of contents/container to
hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation
PRO-SET LAM-237 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 2/8
Other hazards
No additional information available
Unknown acute toxicity
No additional information available
SECTION 3: Composition/information on ingredients
Substance
Not applicable
Mixtures
Name Product identifier HPR %
Propylene glycol diamine, 2-amino-, diether with Propylene
(CAS No) 9046-10-0 10 – 30
Isophorone diamine
(CAS No) 2855-13-2 10 – 30
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-(2-aminomethylethoxy)-, ether with 2-
ethyl-2-(hydroxymethyl)-1,3-propanediol (3:1)
(CAS No) 39423-51-3 10 – 30
Formaldehyde, polymer with benzenamine, hydrogenated
(CAS No) 135108-88-2 7 – 30
Cyclohexanamine, 4,4′-methylenebis-
(CAS No) 1761-71-3 5 – 13
1,3-Propanediamine, N,N”-1,2-ethanediylbis-
(CAS No) 10563-26-5 1 – 5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Immediately call a POISON CENTER or
doctor/physician.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Harmful if inhaled. May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. This product may be aspirated into the lungs and cause chemical pneumonitis.
May be fatal if swallowed and enters airways. May cause burns or irritation of the linings of the
mouth, throat, and gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, nitrogen oxides,
amines, ammonia, nitric acid, cyanides, aldehydes, nitrosamines. When mixed with sawdust,
wood chips, or other cellulosic material, spontaneous combustion can occur under certain
conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly
enough, it can ignite the sawdust.
PRO-SET LAM-237 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 3/8
Reactivity : No dangerous reaction known under conditions of normal use.
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available
Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
Methods and material for containment and cleaning up
For containment : Stop leak if safe to do so. Contain and/or absorb spill with inert material (e.g. sand, vermiculite),
then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use
appropriate Personal Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or
other combustible absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust, fume, gas, mist, vapours,
spray. Do not swallow. Handle and open container with care. Use only outdoors or in a well-
ventilated area. Do not eat, drink or smoke when using this product. When mixed with epoxy
resin this product causes an exothermic reaction, which in large masses, can produce enough
heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in
composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in a dry, cool and well-
ventilated place. Protect from moisture. Storage temperature : 40 F (4 C) – 90 F (32 C).
SECTION 8: Exposure controls/personal protection
Control parameters
Propylene glycol diamine, 2-amino-, diether with Propylene (9046-10-0)
Not applicable
Isophorone diamine (2855-13-2)
Not applicable
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-(2-aminomethylethoxy)-, ether with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol
(3:1) (39423-51-3)
Not applicable
Formaldehyde, polymer with benzenamine, hydrogenated (135108-88-2)
Not applicable
Cyclohexanamine, 4,4′-methylenebis- (1761-71-3)
Not applicable
1,3-Propanediamine, N,N”-1,2-ethanediylbis- (10563-26-5)
Not applicable
PRO-SET LAM-237 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 4/8
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : No data available
Colour : Colourless
Odour : Ammonia
Odour threshold : No data available
pH : 12.2
Melting point : No data available
Freezing point : No data available
Boiling point : > 400 F (204 C) estimated based on similar product
Flash point : > 200 F (93 C) estimated based similar product.
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Not flammable
Vapour pressure : < 1 mm Hg @ 20 C / 68 F (estimated based on ingredient data).
Relative vapour density at 20 C : No data available
Relative density : 0.95
Solubility : No data available
Partition coefficient n-octanol/water : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : 12.9 mm /s @ 40 C / 104 F
Viscosity, dynamic : No data available
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
Other information
VOC content : LAM-125 / LAM-237: 3.13 g/L (0.03 lbs/gal); LAM-135 / LAM-237: 0.93 g/L (0.01 lbs/gal); LAM-
145 / LAM-237: 1.58 g/L (0.01 lbs/gal)
Bulk density : 7.92 lb/gal (0.95 kg/L)
SECTION 10: Stability and reactivity
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an epoxy resin will cause irreversible polymerization with significant heat
buildup and pressure.
Conditions to avoid : Heat. Incompatible materials.
PRO-SET LAM-237 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 5/8
Incompatible materials : Acids. Oxidizing materials. Halogenated compounds.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon, nitrogen oxides, amines, ammonia, nitric
acid, cyanides, aldehydes, nitrosamines.
SECTION 11: Toxicological information
Information on toxicological effects
Propylene glycol diamine, 2-amino-, diether with Propylene (9046-10-0)
LD50 oral rat 2855 mg/kg
LD50 dermal rabbit 2890 mg/kg
LC50 inhalation rat > 0.74 mg/l/8h
Isophorone diamine (2855-13-2)
LD50 oral rat 1030 mg/kg
LD50 dermal rabbit > 2000 mg/kg
LC50 inhalation rat > 5.01 mg/l/4h
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-(2-aminomethylethoxy)-, ether with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol
(3:1) (39423-51-3)
LD50 oral rat 550 mg/kg
LD50 dermal rabbit > 1000 mg/kg
Cyclohexanamine, 4,4′-methylenebis- (1761-71-3)
LD50 oral rat 380 mg/kg
LD50 dermal rabbit > 1000 mg/kg
1,3-Propanediamine, N,N”-1,2-ethanediylbis- (10563-26-5)
LD50 oral rat 1200 mg/kg
LD50 dermal rabbit 190 – 210 mg/kg
Acute toxicity (oral) : Oral: Harmful if swallowed.
Acute toxicity (dermal) : Dermal: Harmful in contact with skin.
Acute toxicity (inhalation) : Inhalation: Harmful if inhaled.
Skin corrosion/irritation : Causes severe skin burns.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified.
Carcinogenicity : Not classified.
Reproductive toxicity : Not classified.
STOT-single exposure : Not classified.
STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure if swallowed.
Aspiration hazard : May be fatal if swallowed and enters airways.
PRO-SET LAM-237 Hardener
Viscosity, kinematic (calculated value) (40 C) 12.9 mm /s
Potential adverse human health effects and
symptoms
: Harmful in contact with skin. Harmful if inhaled. Harmful if swallowed.
Symptoms/injuries after inhalation : Harmful if inhaled. May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. This product may be aspirated into the lungs and cause chemical pneumonitis.
May be fatal if swallowed and enters airways. May cause burns or irritation of the linings of the
mouth, throat, and gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
PRO-SET LAM-237 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 6/8
SECTION 12: Ecological information
Toxicity
Ecology – general : Toxic to aquatic life with long lasting effects.
Isophorone diamine (2855-13-2)
EC50 Daphnia 1 14.6 – 21.5 mg/l (Exposure time: 48 h – Species: Daphnia magna [semi-static])
Persistence and degradability
PRO-SET LAM-237 Hardener
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET LAM-237 Hardener
Bioaccumulative potential Not established.
Isophorone diamine (2855-13-2)
Partition coefficient n-octanol/water 0.79 (at 23 C)
Cyclohexanamine, 4,4′-methylenebis- (1761-71-3)
Partition coefficient n-octanol/water 2.03
Mobility in soil
PRO-SET LAM-237 Hardener
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Ingredient CAS# Ecotoxicity Classification Information
Propylene glycol diamine, 2-amino-, diether with Propylene
9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Isophorone diamine
2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-(2-aminomethylethoxy)-, ether
with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (3:1)
39423-51-3 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
Formaldehyde, polymer with benzenamine, hydrogenated
135108-88-2 Not classified
Cyclohexanamine, 4,4′-methylenebis-
1761-71-3 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
1,3-Propanediamine, N,N”-1,2-ethanediylbis-
10563-26-5 Not classified
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT and TDG
UN-No.(DOT/TDG) : UN2735
Proper Shipping Name (DOT/TDG) : Polyamines, liquid, corrosive, n.o.s. (Propylene glycol diamine, 2-amino-, diether with Propylene)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : II
Marine pollutant : No
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 2735
Proper Shipping Name (IMDG) : POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Propylene glycol diamine, 2-amino-, diether
with Propylene)
PRO-SET LAM-237 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 7/8
Class (IMDG) : 8
Packing group (IMDG) : II
EmS number : F-A, S-B
Marine pollutant : Yes
Transport by sea
In accordance with IATA
UN-No. (IATA) : 2735
Proper Shipping Name (IATA) : Polyamines, liquid, corrosive, n.o.s. (Propylene glycol diamine, 2-amino-, diether with Propylene)
Class (IATA) : 8
Packing group (IATA) : II
Marine pollutant : Yes
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Propylene glycol diamine, 2-amino-, diether with Propylene (9046-10-0)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-(2-aminomethylethoxy)-, ether with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (3:1)
(39423-51-3)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Formaldehyde, polymer with benzenamine, hydrogenated (135108-88-2)
EPA TSCA Regulatory Flag P – P – indicates a commenced PMN substance.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Propylene oxide (75-56-9)
Listed on the United States SARA Section 302
CERCLA RQ 100 lb
SARA Section 302 Threshold Planning Quantity (TPQ) 10000 lb
SARA Section 313 – Emission Reporting 0.1 %
International regulations
No additional information available
US State regulations
California Proposition 65 – This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer,
developmental and/or reproductive harm
Propylene oxide (75-56-9)
U.S. – California –
Proposition 65 –
Carcinogens List
U.S. – California –
Proposition 65 –
Developmental Toxicity
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Female
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Male
Non-significant risk
level (NSRL)
Yes No No No
Isophorone diamine (2855-13-2)
U.S. – New Jersey – Right to Know Hazardous Substance List
PRO-SET LAM-237 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 8/8
Propylene oxide (75-56-9)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – Pennsylvania – RTK (Right to Know) – Special Hazardous Substances
U.S. – Pennsylvania – RTK (Right to Know) List
SECTION 16: Other information
Date of issue : 05/25/2016
Revision date : 01/25/2019
Other information : None.
NFPA health hazard : 3
NFPA fire hazard : 1
NFPA reactivity : 0
HMIS III Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.
by | Sep 27, 2025
PRO-SET LAM-224 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 06/01/2015 Revision date: 01/25/2019 Version: LAM-224 -2019a
01/25/2019 EN (English) Page 1
SECTION 1: Identification
Identification
Product form : Mixtures
Product name : PRO-SET LAM-224 Hardener
Product code : LAM-224, LAM-224-1, LAM-224-2, LAM-224-3, LAM-224-4, LAM-224-5
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy resins
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 888-377-6738 or 989-684-7286
www.prosetepoxy.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Acute Tox. 4 (Dermal)
Acute Tox. 4 (Inhalation)
Skin Corr. 1B
Eye Dam. 1
Skin Sens. 1
Repr. 2
Aquatic Acute 1
Aquatic Chronic 1
Label elements
Hazard pictograms (GHS) :
GHS05
GHS07
GHS08
GHS09
Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful in contact with skin or if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Suspected of damaging
fertility or the unborn child. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.
Precautionary statements (GHS)
:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust, fume, gas,
mist, vapours, spray. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be
allowed out of the workplace. Avoid release to the environment. Wear protective gloves, protective clothing, eye protection, face protection. If
swallowed: rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Immediately call a poison
center/doctor. If skin irritation or rash occurs: Get medical attention/advice. Take off contaminated clothing and wash it before reuse. Collect
spillage. Store locked up. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national
and/or international regulation.
Other hazards
No additional information available
PRO-SET LAM-224 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 2/8
Unknown acute toxicity
No additional information available
SECTION 3: Composition/information on ingredients
Substance
Not applicable
Mixtures
Name Product identifier HPR %
1-Piperazineethanamine
(CAS No) 140-31-8 10 – 30
1,3-Benzenedimethanamine
(CAS No) 1477-55-0 10 – 30
4-tert-Butylphenol
(CAS No) 98-54-4 10 – 30
Trimethylhexamethylenediamine
(CAS No) 25620-58-0 10 – 30
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine)
(CAS No) 57214-10-5 10 – 30
1,3-Propanediamine, N,N”-1,2-ethanediylbis-
(CAS No) 10563-26-5 5 – 10
Phenol, 4-nonyl-, branched
(CAS No) 84852-15-3 0.1 – 1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold..
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Harmful if inhaled. May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : May be harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat,
and gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, nitrogen oxides,
amines, ammonia, nitric acid, cyanides, aldehydes, nitrosamines. When mixed with sawdust,
wood chips, or other cellulosic material, spontaneous combustion can occur under certain
conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly
enough, it can ignite the sawdust.
Reactivity : No dangerous reaction known under conditions of normal use.
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
PRO-SET LAM-224 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 3/8
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available
Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
Methods and material for containment and cleaning up
For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or other combustible
absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Do not get in eyes, on skin, or on clothing. Do not breathe dust, fume,
gas, mist, vapours, spray. Do not swallow. Handle and open container with care. Use only
outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Use
personal protective equipment as required. When mixed with epoxy resin this product causes
an exothermic reaction, which in large masses, can produce enough heat to damage or ignite
surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in dry, cool, well-
ventilated area. Protect from moisture. Storage temperature : 40 F (4 C) – 90 F (32 C).
SECTION 8: Exposure controls/personal protection
Control parameters
1-Piperazineethanamine (140-31-8)
Not applicable
1,3-Benzenedimethanamine (1477-55-0)
ACGIH ACGIH Ceiling (mg/m ) 0.1 mg/m
NIOSH NIOSH REL (ceiling) (mg/m ) 0.1 mg/m
4-tert-Butylphenol (98-54-4)
Not applicable
Trimethylhexamethylenediamine (25620-58-0)
Not applicable
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (57214-10-5)
Not applicable
1,3-Propanediamine, N,N”-1,2-ethanediylbis- (10563-26-5)
Not applicable
Phenol, 4-nonyl-, branched (84852-15-3)
Not applicable
PRO-SET LAM-224 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 4/8
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of inadequate ventilation wear respiratory protection. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully
before eating or smoking. Handle according to established industrial hygiene and safety practices.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : No data available
Colour : Colourless
Odour : Ammonia
Odour threshold : No data available
pH : 11.4
Melting point : No data available
Freezing point : No data available
Boiling point : > 400 F (204 C) estimated based on similar product.
Flash point : > 200 F (93 C) estimated based similar product.
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Not flammable
Vapour pressure : < 1 mm Hg @ 20 C / 68 F (estimated based on ingredient data)
Relative vapour density at 20 C : No data available
Relative density : 1
Solubility : No data available
Partition coefficient n-octanol/water : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : 75 mm /s @ 20 C / 68 F
Viscosity, dynamic : No data available
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
Other information
VOC content : LAM-125 / LAM-224: 3.60 g/L (0.03 lbs/gal); LAM-135 / LAM-224: 1.66 g/L (0.01 (lbs/gal)
Bulk density : 8.34 lb/gal (1.00 kg/L)
SECTION 10: Stability and reactivity
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an epoxy resin will cause irreversible polymerization with significant heat
buildup and pressure.
Conditions to avoid : Heat. Incompatible materials.
PRO-SET LAM-224 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 5/8
Incompatible materials : Acids. Oxidizing materials. Halogenated compounds.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon, nitrogen oxides, amines, ammonia, nitric
acid, cyanides, aldehydes, nitrosamines, phenolics.
SECTION 11: Toxicological information
Information on toxicological effects
1-Piperazineethanamine (140-31-8)
LD50 oral rat 2097 mg/kg
LD50 dermal rabbit 866 mg/kg
1,3-Benzenedimethanamine (1477-55-0)
LD50 oral rat 980 mg/kg
LD50 dermal rabbit 2000 mg/kg
LC50 inhalation rat 1.34 mg/l/4h
4-tert-Butylphenol (98-54-4)
LD50 oral rat > 2000 mg/kg
LD50 dermal rat No data. Intraperitoneal mouse 78 mg/kg.
LC50 inhalation rat 5.6 mg/l Remarks: Nutritional and Metabolic: Weight loss or decreased weight gain
Trimethylhexamethylenediamine (25620-58-0)
LD50 oral rat 910 mg/kg
1,3-Propanediamine, N,N”-1,2-ethanediylbis- (10563-26-5)
LD50 oral rat 1200 mg/kg
LD50 dermal rabbit 190 – 210 mg/kg
Phenol, 4-nonyl-, branched (84852-15-3)
LD50 oral rat 1412 mg/kg
Acute toxicity (oral) : Not classified.
Acute toxicity (dermal) : Dermal: Harmful in contact with skin.
Acute toxicity (inhalation) : Inhalation: Harmful if inhaled.
Skin corrosion/irritation : Causes severe skin burns
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified.
Carcinogenicity : Not classified.
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : Not classified.
STOT-repeated exposure : Not classified.
Aspiration hazard : Not classified.
PRO-SET LAM-224 Hardener
Viscosity, kinematic (calculated value) (20 C /
68 F)
75 mm /s
Potential adverse human health effects and
symptoms
: Harmful in contact with skin. Harmful if inhaled.
Symptoms/injuries after inhalation : Harmful if inhaled. May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : May be harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat,
and gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
PRO-SET LAM-224 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 6/8
SECTION 12: Ecological information
Toxicity
Ecology – general : Very toxic to aquatic life with long lasting effects.
1-Piperazineethanamine (140-31-8)
LC50 fish 1 1950 – 2460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 32 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 > 1000 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
4-tert-Butylphenol (98-54-4)
LC50 fish 1 4.71 – 5.62 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 3.9 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 6.9 mg/l (Exposure time: 96 h – Species: Cyprinus carpio [static])
EC50 Daphnia 2 3.4 – 4.5 mg/l (Exposure time: 48 h – Species: Daphnia magna [Static])
Phenol, 4-nonyl-, branched (84852-15-3)
LC50 fish 1 0.135 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 0.14 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 0.1351 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [flow-through])
Persistence and degradability
PRO-SET LAM-224 Hardener
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET LAM-224 Hardener
Bioaccumulative potential Not established.
1-Piperazineethanamine (140-31-8)
BCF fish 1 (no bioaccumulation expected)
Partition coefficient n-octanol/water -1.48
4-tert-Butylphenol (98-54-4)
BCF fish 1 34 – 240
Partition coefficient n-octanol/water 2.44
Trimethylhexamethylenediamine (25620-58-0)
Partition coefficient n-octanol/water 0.77 (at 23 C)
Phenol, 4-nonyl-, branched (84852-15-3)
BCF fish 1 271
Mobility in soil
PRO-SET LAM-224 Hardener
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Ingredient CAS# Ecotoxicity Classification Information
1-Piperazineethanamine
140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
1,3-Benzenedimethanamine
1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
4-tert-Butylphenol
98-54-4 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
Trimethylhexamethylenediamine
25620-58-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine)
57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
1,3-Propanediamine, N,N”-1,2-ethanediylbis-
10563-26-5 Not classified
Phenol, 4-nonyl-, branched
84852-15-3 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Other information : Avoid release to the environment.
PRO-SET LAM-224 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 7/8
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT and TDG
UN-No.(DOT/TDG) : UN2735
Proper Shipping Name (DOT/TDG) : Polyamines, liquid, corrosive, n.o.s. (1,3-Benzenedimethanamine)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : II
Marine Pollutant : No
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 2735
Proper Shipping Name (IMDG) : POLYAMINES, LIQUID, CORROSIVE, N.O.S. (1,3-Benzenedimethanamine)
Class (IMDG) : 8
Packing group (IMDG) : II
EmS Number : F-A, S-B
Marine pollutant : Yes
Transport by sea
In accordance with IATA
UN-No. (IATA) : 2735
Proper Shipping Name (IATA) : Polyamines, liquid, corrosive, n.o.s. (1,3-Benzenedimethanamine)
Class (IATA) : 8
Packing group (IATA) : II
Marine pollutant : Yes
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (57214-10-5)
EPA TSCA Regulatory Flag P – P – indicates a commenced PMN substance.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Phenol, 4-nonyl-, branched (84852-15-3)
Subject to reporting requirements of United States SARA Section 313
EPA TSCA Regulatory Flag SP – SP – indicates a substance that is identified in a proposed Significant New Uses Rule.
SARA Section 313 – Emission Reporting 1 %
International regulations
No additional information available
US State regulations
California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm
PRO-SET LAM-224 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 8/8
1-Piperazineethanamine (140-31-8)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
1,3-Benzenedimethanamine (1477-55-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
Trimethylhexamethylenediamine (25620-58-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
SECTION 16: Other information
Date of issue : 06/01/2015
Revision date : 01/25/2019
Other information : None.
NFPA health hazard : 3
NFPA fire hazard : 1
NFPA reactivity : 0
HMIS III Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.
