by | Sep 27, 2025
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
1 / 13
SECTION 1. IDENTIFICATION
Product name :
SikaBiresin AP017 (Formerly P 17) Part A
Company name : Sika Corporation
201 Polito Avenue
Lyndhurst, NJ 07071
USA
www.sikausa.com
Telephone :
(201) 933-8800
Telefax : (201) 804-1076
E-mail address : ehs
@sika-corp.com
Emergency telephone : CHEMTREC: 800-424-9300
INTERNATIONAL: +1-703-527-3887
Recommended use of the
chemical and restrictions on
use
: For further information, refer to product data sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Flammable liquids
: Category 3
Skin irritation
: Category 2
Eye irritation
: Category 2A
Carcinogenicity (Inhalation)
: Category 1A
GHS label elements
Hazard pictograms
:
Signal Word
: Danger
Hazard Statements
: H226 Flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H350 May cause cancer by inhalation.
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
2 / 13
Precautionary Statements
:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equip-
ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P332 + P313 If skin irritation occurs: Get medical advice/ atten-
tion.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Additional Labeling
There are no ingredients with unknown acute toxicity used in a mixture at a concentration >= 1%.
Other hazards
None known.
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
3 / 13
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
Components
Chemical name CAS-No. Classification Concentra-
tion (% w/w)
Talc 14807-96-6 >= 50 – < 70
vinyltoluene 25013-15-4 Flam. Liq. 3; H226
Acute Tox. 4; H332
Skin Irrit. 2; H315
Eye Irrit. 2A; H319
Asp. Tox. 1; H304
>= 10 – < 20
barium sulfate 7727-43-7 >= 1 – < 5
Quartz (SiO2) >5 m 14808-60-7 Carc. 1A; H350
STOT RE 1; H372
STOT SE 3; H335
>= 0.1 – < 1
Actual concentration is withheld as a trade secret
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.
If inhaled : Move to fresh air.
Consult a physician after significant exposure.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.
In case of eye contact : Immediately flush eye(s) with plenty of water.
Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Obtain medical attention.
Most important symptoms
and effects, both acute and
delayed
: Causes skin irritation.
Causes serious eye irritation.
May cause cancer by inhalation.
irritant effects
Excessive lachrymation
Er
ythema
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
4 / 13
Dermatitis
Notes to physician : Treat symptomatically.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: Water
Further information : Use water spray to cool unopened containers.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment
for fire-fighters
: In the event of fire, wear self-contained breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
gency procedures
: Use personal protective equipment.
Remove all sources of ignition.
Deny access to unprotected persons.
Beware of vapors accumulating to form explosive concentra-
tions. Vapors can accumulate in low areas.
Environmental precautions
: Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for
containment and cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
SECTION 7. HANDLING AND STORAGE
Advice on protection against
fire and explosion
: Use explosion-proof equipment.
Keep away from heat/ sparks/ open flames/ hot surfaces. No
smoking.
Take precautionary measures against electrostatic discharg-
es.
Advice on safe handling : Do not breathe vapors or spray mist.
Avoid exceeding the given occupational exposure limits (see
section 8
).
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
5 / 13
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Take precautionary measures against static discharge.
Open drum carefully as content may be under pressure.
Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors).
Follow standard hygiene measures when handling chemical
products.
Conditions for safe storage : Store in original container.
Keep in a well-ventilated place.
Observe label precautions.
Store in accordance with local regulations.
Materials to avoid : Explosives
Oxidizing agents
Poisonous gases
Poisonous liquids
SECTION 8. EXPOSURE CONTRO LS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis
Talc 14807-96-6 TWA (Dust) 20 Million parti-
cles per cubic foot
OSHA Z-3
TWA (respir-
able dust
fraction
)
2 mg/m3 OSHA P0
TWA (Res-
pirable par-
ticulate mat-
ter
)
2 mg/m3 ACGIH
PEL (respir-
able)
0.05 mg/m3 OSHA CARC
vinyltoluene 25013-15-4 TW A 10 ppm ACGIH
TWA 100 ppm
480 mg/m3
OSHA Z-1
TWA 100 ppm
480 mg/m3
OSHA P0
barium sulfate 7727-43-7 TWA (Inhal-
able particu-
late matter)
5 mg/m3 ACGIH
TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA (respir- 5 mg/m3 OSHA Z-1
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
6 / 13
able fraction)
TWA (Total
dust)
10 mg/m3 OSHA P0
TWA (respir-
able dust
fraction)
5 mg/m3 OSHA P0
Quartz (SiO2) >5 m 14808-60-7 TWA (Res-
pirable par-
ticulate mat-
ter
)
0.025 mg/m3 ACGIH
TWA (Res-
pirable dust)
0.05 mg/m3 OSHA Z-1
TWA (respir-
able)
10 mg/m3 /
%SiO2+2
OSHA Z-3
TWA (respir-
able)
250 mppcf /
%SiO2+5
OSHA Z-3
TWA (respir-
able dust
fraction)
0.1 mg/m3 OSHA P0
TWA (Res-
pirable par-
ticulate mat-
ter
)
0.025 mg/m3
(Silica)
ACGIH
PEL (respir-
able)
0.05 mg/m3 OSHA CARC
TWA (respir-
able dust
fraction
)
0.1 mg/m3 OSHA P0
TWA (Res-
pirable par-
ticulate mat-
ter)
0.025 mg/m3 ACGIH
TWA (Res-
pirable par-
ticulate mat-
ter)
0.025 mg/m3
(Silica)
ACGIH
The above constituents are the only constituents of the product which have a PEL, TLV or other rec-
ommended exposure limit. At this time, the other constituents have no known exposure limits.
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use pro-
cess enclosures, local exhaust ventilation or other engineer-
ing controls to keep worker exposure below any recommend-
ed or statutory limits.
The engineering controls also need to keep gas, vapor or
dust concentrations below an
y lower explosive limits.
Personal protective equipment
Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
7 / 13
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.
Eye protection : Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary.
Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.
Hygiene measures : Avoid contact with skin, eyes and clothing.
Wash hands before breaks and immediately after handling
the product.
Remove respiratory and skin/eye protection only after vapors
have been cleared from the area.
Remove contaminated clothing and protective equipment
before entering eating areas.
Wash thoroughly after handling.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : paste
Color : various
Odor : pungent
Odor Threshold : No data available
pH : Not applicable
Melting point/range / Freezing
point
: No data available
Boiling point/boiling range
: 338 F / 170 C
Flash point : ca. 127 F / 53 C
(Method: closed cup)
Evaporation rate : No data available
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
8 / 13
Flammability (solid, gas)
: No data available
Upper explosion limit / Upper
flammability limit
: No data available
Lower explosion limit / Lower
flammability limit
: No data available
Vapor pressure : 2 hpa
Relative vapor density : No data available
Density : 1.59 – 2.13 g/cm3 (68 F / 20 C)
Solubility(ies)
Water solubility : soluble
Solubility in other solvents : No data available
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : No data available
Decomposition temperature : No data available
Viscosity
Viscosity, dynamic : No data available
Viscosity, kinematic : > 20.5 mm2/s (104 F / 40 C)
Explosive properties : No data available
Oxidizing properties : No data available
Volatile organic compounds
(VOC) content
: 8 g/l
Part A + Valspar Cream Hardener BPO Part B Combined.
8 g/l
Part A + AP017 Reducer Part A + Valspar Cream Hardener
BPO Part B Combined.
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : The product is chemically stable.
Possibility of hazardous reac-
tions
: Stable under recommended storage conditions.
Vapors may form explosive mixture with air.
Conditions to avoid : Heat, flames and sparks.
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
9 / 13
Incompatible materials : No data available
Hazardous decomposition
products
: No decomposition if stored and applied as directed.
SECTION 11. TOXICOLOGICAL INFORMATION
Not classified due to lack of data.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitization
Skin sensitization
Not classified due to lack of data.
Respiratory sensitization
Not classified due to lack of data.
Germ cell mutagenicity
Not classified due to lack of data.
Carcinogenicity
May cause cancer by inhalation.
IARC Group 1: Carcinogenic to humans
Quartz (SiO2) 14808-60-7
(Silica dust, crystalline)
Group 2B: Possibly carcinogenic to humans
Titanium dioxide (> 10 m) 13463-67-7
OSHA OSHA specifically regulated carcinogen
Talc (Mg3H2(SiO3)4) 14807-96-6
(crystalline silica)
OSHA specifically regulated carcinogen
Quartz (SiO2) 14808-60-7
(crystalline silica)
NTP Known to be human carcinogen
Quartz (SiO2) 14808-60-7
(Silica, Crystalline (Respirable Size))
Reproductive toxicity
Not classified due to lack of data.
STOT-single exposure
Not classified due to lack of data.
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
10 / 13
STOT-repeated exposure
Not classified due to lack of data.
Aspiration toxicity
Not classified due to lack of data.
Further information
Product:
Remarks : Titanium dioxide (13463-67-7)
In lifetime inhalation studies of rats, airborne respirable-size
titanium dioxide particles have shown to cause an increase in
lung tumors at concentrations associated with substantial
particle lung burdens and consequential pulmonary overload
and inflammation. The potential for these adverse health ef-
fects appears to be closely related to the particle size and the
amount of the exposed surface area that comes into contact
with the lung. However, tests with other laboratory animals
such as mice and hamsters, indicate that rats are significantly
more susceptible to the pulmonary overload and inflammation
that causes lung cancer. Epidemiological studies do not sug-
gest an increased risk of cancer in humans from occupational
exposure to titanium dioxide. Titanium dioxide has been char-
acterized by IARC as possibly carcinogenic to humans (Group
2B) through inhalation (not ingestion). It has not been charac-
terized as a potential carcino
gen by either NTP or OSHA.
Quartz (14808-60-7): This classification is relevant when ex-
posed to Quartz (silicon dioxide) in dust or powder form only,
including cured product that is subject to sanding, grinding,
cutting, or other surface preparation activities.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological infor-
mation
: Do not empty into drains; dispose of this material and its con-
tainer in a safe way.
Avoid dispersal of spilled material and runoff and contact with
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
11 / 13
soil, waterways, drains and sewers.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.
Contaminated packaging : Empty containers should be taken to an approved waste han-
dling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR
UN/ID No. : UN 1866
Proper shipping name : Resin solution
Class : 3
Packing group : III
Labels : Flammable Liquids
Packing instruction (cargo
aircraft
)
: 366
Packing instruction (passen-
ger aircraft)
: 355
IMDG-Code
UN number : UN 1866
Proper shipping name : RESIN SOLUTION
Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-E
Marine pollutant : no
Domestic regulation
49 CFR
UN/ID/NA number : UN 1866
Proper shipping name : Resin solution
Class : 3
Packing group : III
Labels : FLAMMABLE LIQUID
ERG Code : 127
Marine pollutant : no
DOT: As per 49CFR 173.150 (f) Combustible Liquid Exception, Material is Not Regulated.
IMDG: For Limited Quantity special provisions reference IMDG Code Chapter 3.4
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
12 / 13
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based
upon the properties of the unpackaged material as it is described within this Safety Data Sheet.
Transportation classifications may vary by mode of transportation, package sizes, and variations in
regional or country regulations.
SECTION 15. REGULATORY INFORMATION
TSCA list : All chemical substances in this product are either listed as ac-
tive on the TSCA Inventory or are in compliance with a TSCA
Inventory exemption.
No substances are subject to a Significant New Use Rule.
The following substance(s) is/are subject to TSCA 12(b) export notification requirements:
vinyltoluene 25013-15-4
CERCLA Reportable Quantity
Listed substances in the product are at low enough levels to not be expected to exceed the RQ
SARA 304 Extremely Hazardous Substances Reportable Quantity
Listed substances in the product are at low enough levels to not be expected to exceed the RQ
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards
: Flammable (gases, aerosols, liquids, or solids)
Carcinogenicity
Skin corrosion or irritation
Serious eye damage or eye irritation
SARA 313
: This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air
Act Section 112 (40 CFR 61).
California Prop. 65
WARNING: This product can expose you to chemicals including Talc, which is known to the State of
California to cause cancer, and methanol, which is known to the State of California to cause birth
defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
SECTION 16. OTHER INFORMATION
Full text of other abbreviations
ACGIH : USA. ACGIH Threshold Limit Values (TLV)
Safety Data Sheet
according to the OSHA Hazard Communication Standard
SikaBiresin AP017 (Formerly P 17) Part A
Revision Date 03/21/2024
Print Date 03/21/2024
13 / 13
OSHA CARC : OSHA Specifically Regulated Chemicals/Carcinogens
OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated
values)
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) – Table Z-1 Lim-
its for Air Contaminants
OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) – Table Z-3 Min-
eral Dusts
ACGIH / TWA : 8-hour, time-weighted average
OSHA CARC / PEL : Permissible exposure limit (PEL)
OSHA P0 / TWA : 8-hour time weighted average
OSHA Z-1 / TWA : 8-hour time weighted average
OSHA Z-3 / TWA : 8-hour time weighted average
Notes to Reader
The information contained in this Safety Data Sheet applies only to the actual Sika Corporation
(“Sika”) product identified and described herein. This information is not intended to address, nor
does it address the use or application of the identified Sika product in combination with any other
material, product or process. All of the information set forth herein is based on technical data re-
garding the identified product that Sika believes to be reliable as of the date hereof. Prior to each
use of any Sika product, the user must always read and follow the warnings and instructions on
the product’s current Product Data Sheet, product label and Safety Data Sheet for each Sika
product, which are available at web site and/or telephone number listed in Section 1 of this SDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY
ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONS EQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRO DUCT IN A MANNER TO INFRINGE ON ANY
PATENT OR ANY OTHER INTELLECTUAL PR OPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sikausa.com or 201-933-8800.
Revision Date 03/21/2024
100000056511
US / Z8
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
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Safety Data Sheet
acc. to OSHA HCS
Printing date 04/18/2019 Reviewed on 09/11/2018
49.0
1 Identification
Product identifier
Trade name: TCC5220A Resin
Article number:I079066
Application of the substance / the mixturePolyurethane resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) US
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Trade name: TCC5220A Resin
(Contd. of page 1)
49.0
Hazard pictograms
GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
diphenylmethanediisocyanate,isomeres and homologues
4,4′-methylenediphenyl diisocyanate
methylenediphenyl diisocyanate
Hazard statements
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
[In case of inadequate ventilation] wear respiratory protection.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
0
0
Health = 2
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
0
0
Health = *2
Fire = 0
Reactivity = 0
(Contd. on page 3)
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Trade name: TCC5220A Resin
(Contd. of page 2)
49.0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 50-100%
CAS: 101-68-8
EINECS: 202-966-0
4,4′-methylenediphenyl diisocyanate 20-50%
CAS: 26447-40-5
EINECS: 247-714-0
methylenediphenyl diisocyanate 1-<5%
CAS: 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1-5%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use fire fighting measures that suit the environment.
(Contd. on page 4)
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(Contd. of page 3)
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Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Nitrogen oxides (NOx)
Hydrogen cyanide (HCN)
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 0.15 mg/m
101-68-8 4,4'-methylenediphenyl diisocyanate 0.45 mg/m
26447-40-5 methylenediphenyl diisocyanate 29 mg/m
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 120 mg/m
PAC-2:
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 3.6 mg/m
101-68-8 4,4'-methylenediphenyl diisocyanate 5 mg/m
26447-40-5 methylenediphenyl diisocyanate 40 mg/m
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1,300 mg/m
PAC-3:
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 22 mg/m
101-68-8 4,4'-methylenediphenyl diisocyanate 55 mg/m
26447-40-5 methylenediphenyl diisocyanate 240 mg/m
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 7,900 mg/m
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7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
101-68-8 4,4'-methylenediphenyl diisocyanate
PEL Ceiling limit value: 0.2 mg/m , 0.02 ppm
REL Long-term value: 0.05 mg/m , 0.005 ppm
Ceiling limit value: 0.2* mg/m , 0.02* ppm
*10-min
TLV Long-term value: 0.051 mg/m , 0.005 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 6)
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Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light brown
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:190 C (374 F)
Flash point: Not applicable.
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 400 C (752 F)
Decomposition temperature: Not determined.
(Contd. on page 7)
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Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 0.4 Vol %
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.25 g/cm (10.43 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 90.9 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactions
Violent reactions with -NHx, -OH and -SH- groups.
In the presence of water or humidity gas (CO2) is porduced and/or uncontrolled polymerization, possibly leading
to internal pressure rises and consequent risk of container breach.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:
Nitrogen oxides
Carbon monoxide and carbon dioxide
(possible HCN)
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11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral LD50 >5,000 mg/kg (rat)
Inhalative LC50/4 h 0.00049 mg/l (rat)
101-68-8 4,4′-methylenediphenyl diisocyanate
Oral LD50 2,200 mg/kg (mouse)
Dermal LD50 >9,400 mg/kg (rabbit)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 3
101-68-8 4,4′-methylenediphenyl diisocyanate 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
48 hr EC50 >1,000 mg/l (daphnia)
96 hr LC50 >1,000 mg/l (Fish)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
(Contd. on page 9)
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Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
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15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues
101-68-8 4,4′-methylenediphenyl diisocyanate
TSCA (Toxic Substances Control Act): (Substances not listed)
All ingredients are listed.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
101-68-8 4,4′-methylenediphenyl diisocyanate
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues CBD
101-68-8 4,4′-methylenediphenyl diisocyanate D, CBD
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 11)
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Hazard pictograms
GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
diphenylmethanediisocyanate,isomeres and homologues
4,4′-methylenediphenyl diisocyanate
methylenediphenyl diisocyanate
Hazard statements
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
[In case of inadequate ventilation] wear respiratory protection.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision09/11/2018 / 2
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
(Contd. on page 12)
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CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Resp. Sens. 1: Respiratory sensitisation Category 1
Skin Sens. 1: Skin sensitisation Category 1
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
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1 Identification
Product identifier
Trade name: TCC5220B Hardener
Article number:I079067
Application of the substance / the mixturePolyurethane resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
The product is not classified, according to the Globally Harmonized System (GHS).
Label elements
GHS label elementsVoid
Hazard pictogramsVoid
Signal wordVoid
Hazard statementsVoid
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
In case of inadequate ventilation wear respiratory protection.
Classification system:
NFPA ratings (scale 0 – 4)
0
1
0
Health = 0
Fire = 1
Reactivity = 0
(Contd. on page 2)
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HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
0
1
0
Health = 0
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1-5%
4 First-aid measures
Description of first aid measures
General information:No special measures required.
After inhalation:Supply fresh air; consult doctor in case of complaints.
After skin contact:Generally the product does not irritate the skin.
After eye contact:Rinse opened eye for several minutes under running water.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
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6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 120 mg/m
PAC-2:
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1,300 mg/m
PAC-3:
67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 7,900 mg/m
7 Handling and storage
Handling:
Precautions for safe handlingNo special measures required.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:None.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
(Contd. on page 4)
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Exposure controls
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Breathing equipment:Not required.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:Goggles recommended during refilling.
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Red
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:Undetermined.
Flash point: 104 C (219.2 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
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Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.07 g/cm (8.93 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 5.5 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:No irritant effect.
on the eye:No irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product is not subject to classification according to internally approved calculation methods for
preparations:
(Contd. on page 6)
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When used and handled according to specifications, the product does not have any harmful effects according to
our experience and the information provided to us.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1318-02-1 zeolites 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:Smaller quantities can be disposed of with household waste.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
(Contd. on page 7)
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UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act): (Substances not listed)
All ingredients are listed.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
(Contd. on page 8)
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Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsVoid
Hazard pictogramsVoid
Signal wordVoid
Hazard statementsVoid
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision09/11/2018 / 1
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
US
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* 1 Identification
Product identifier
Trade name: TCC410 Resin
Article number:I410088
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Manufacturer:
Sika Advanced Resins
30800 Stephenson Hwy
Madison Heights
MI 48071
USA
Information department:Product safety department
Emergency telephone number:
During normalopening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Carc. 1A H350 May cause cancer.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS08
Signal wordDanger
(Contd. on page 2)
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Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
Quartz (SiO2)
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Polyglycol
epichlorohydrin polymer
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause cancer.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin: Wash with plenty of water.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
1
0
Health = *2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 3)
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vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 20-50%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether 5-<10%
CAS: 41638-13-5 Polyglycol
epichlorohydrin polymer
1-5%
CAS: 14808-60-7
EINECS: 238-878-4
Quartz (SiO2) 0.1-1%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
(Contd. on page 4)
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Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
14808-60-7 Quartz (SiO2) 0.075 mg/m
PAC-2:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
14808-60-7 Quartz (SiO2) 33 mg/m
PAC-3:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
14808-60-7 Quartz (SiO2) 200 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
(Contd. on page 5)
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Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 6)
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Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Viscous
Color: Silver grey
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:2,500 C (36.500 F)
Flash point: 150 C (302 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 400 C (752 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.95 g/cm (16.27 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Fully miscible.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
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Kinematic: Not determined.
Solvent content:
Organic solvents: 0.4 %
VOC content: 0.38 %
7.4 g/l / 0.06 lb/gal
Solids content: 61.5 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
14807-96-6 Talc (Mg3H2(SiO3)4) 3
14808-60-7 Quartz (SiO2) 1
NTP (National Toxicology Program)
14808-60-7 Quartz (SiO2) K
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
Recommended cleansing agent:Water, if necessary with cleansing agents.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin)
(Contd. on page 9)
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Transport hazard class(es)
DOT
Class not regulated
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards:
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN), 9, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
7429-90-5 aluminum powder (stabilised)
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
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Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
98-82-8 cumene
Proposition 65
Chemicals known to cause cancer:
1317-65-3 Calcium Carbonate
14808-60-7 Quartz (SiO2)
14808-60-7 Quartz (SiO2)
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value)
14808-60-7 Quartz (SiO2) A2
NIOSH-Ca (National Institute for Occupational Safety and Health)
14808-60-7 Quartz (SiO2)
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
Quartz (SiO2)
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Polyglycol
epichlorohydrin polymer
(Contd. on page 11)
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Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause cancer.
Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin: Wash with plenty of water.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:
Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Contact:
Date of preparation / last revision10/19/2021 / 4
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
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OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Carc. 1A: Carcinogenicity Category 1A
* Data compared to the previous version altered.
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49.1.7
1 Identification
Product identifier
Trade name: TCC230 Resin
Article number:I230088
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
(Contd. on page 2)
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49.1.7
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS08GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
2,3-epoxypropyl o-tolyl ether
4-nonylphenol, branched
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
(Contd. on page 3)
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49.1.7
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 50-100%
CAS: 2210-79-9
EINECS: 218-645-3
2,3-epoxypropyl o-tolyl ether 10%
CAS: 84852-15-3
EINECS: 284-325-5
4-nonylphenol, branched 1-<2.5%
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
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49.1.7
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
84852-15-3 4-nonylphenol, branched 3.9 mg/m
PAC-2:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
84852-15-3 4-nonylphenol, branched 43 mg/m
PAC-3:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
84852-15-3 4-nonylphenol, branched 260 mg/m
7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
(Contd. on page 5)
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49.1.7
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 6)
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49.1.7
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Viscous
Color: Whitish
Odor: uncharacteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:110 C (230 F)
Flash point: 105 C (221 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.13 g/cm (9.43 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
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Trade name: TCC230 Resin
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49.1.7
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.0 %
VOC content: 0.03 %
0.3 g/l / 0.00 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
US
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49.1.7
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, ADN not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT, ADN not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin, o-Cresyl glycidyl ether), MARINE
POLLUTANT
(Contd. on page 9)
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49.1.7
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin, o-Cresyl glycidyl ether)
Transport hazard class(es)
DOT, ADN
Class not regulated
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: 4-
nonylphenol, branched, Epoxy Resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Not applicable.
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": not regulated
US
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49.1.7
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
84852-15-3 4-nonylphenol, branched
TSCA (Toxic Substances Control Act):
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin ACTIVE
Alkylphenol Blocked Polyisocyanate *
2210-79-9 2,3-epoxypropyl o-tolyl ether ACTIVE
84852-15-3 4-nonylphenol, branched ACTIVE
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
1330-20-7 xylene
Proposition 65
Chemicals known to cause cancer:
100-41-4 ethylbenzene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
108-88-3 toluene
Carcinogenic categories
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 11)
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Hazard pictograms
GHS07GHS08GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
2,3-epoxypropyl o-tolyl ether
4-nonylphenol, branched
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision09/11/2018 / 2
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
(Contd. on page 12)
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49.1.7
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Muta. 2: Germ cell mutagenicity Category 2
Repr. 2: Reproductive toxicity Category 2
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
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49.1.7
1 Identification
Product identifier
Trade name: TCC 205 Resin
Article number:I820088-1
Application of the substance / the mixture
Epoxy resin
Epoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) US
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49.1.7
Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Bis(1,2,2,6,6-pentamethyl-4-piperidyl sebacate
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
(Contd. on page 3)
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 50-100%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
10-20%
CAS: 41556-26-7 Bis(1,2,2,6,6-pentamethyl-4-piperidyl sebacate 0.25-<1%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
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* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
PAC-2:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
PAC-3:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
(Contd. on page 5)
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49.1.7
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
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* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Whitish
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:Undetermined.
Flash point: 150 C (302 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.13 g/cm (9.43 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.7 %
VOC content: 0.70 %
7.9 g/l / 0.07 lb/gal
Solids content: 0.0 %
(Contd. on page 7)
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Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
(Contd. on page 8)
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Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin)
Transport hazard class(es)
DOT
Class not regulated
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49.1.7
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances:
Bis(1,2,2,6,6-pentamethyl-4-piperidyl sebacate, Epoxy Resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN), 9, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
95-63-6 1,2,4-trimethylbenzene
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TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
98-82-8 cumene
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Bis(1,2,2,6,6-pentamethyl-4-piperidyl sebacate
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Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/26/2019 / 4
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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49.1.7
1 Identification
Product identifier
Trade name: TCC 205 Resin
Article number:I820088-1
Application of the substance / the mixture
Epoxy resin
Epoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Bis(1,2,2,6,6-pentamethyl-4-piperidyl sebacate
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
(Contd. on page 3)
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 50-100%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
10-20%
CAS: 41556-26-7 Bis(1,2,2,6,6-pentamethyl-4-piperidyl sebacate 0.25-<1%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
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49.1.7
* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
PAC-2:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
PAC-3:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
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Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
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* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Whitish
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:Undetermined.
Flash point: 150 C (302 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.13 g/cm (9.43 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.7 %
VOC content: 0.70 %
7.9 g/l / 0.07 lb/gal
Solids content: 0.0 %
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49.1.7
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
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49.1.7
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin)
Transport hazard class(es)
DOT
Class not regulated
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IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances:
Bis(1,2,2,6,6-pentamethyl-4-piperidyl sebacate, Epoxy Resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN), 9, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
95-63-6 1,2,4-trimethylbenzene
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TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
98-82-8 cumene
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Bis(1,2,2,6,6-pentamethyl-4-piperidyl sebacate
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Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/26/2019 / 4
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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49.1.7
1 Identification
Product identifier
Trade name: TCC104 Hardener
Article number:R151378-2
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07
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Signal wordDanger
Hazard-determining components of labeling:
Teta, reaction products with propylene oxide
Polyoxylated Triethylenetetramine
3,6-diazaoctanethylenediamin
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
3
1
0
Health = 3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
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Dangerous components:
CAS: 26950-63-0 Teta, reaction products with propylene oxide
Polyoxylated Triethylenetetramine
50-100%
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 10-20%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
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Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
PAC-2:
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
PAC-3:
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the remaining constituent has no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
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Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Amber colored
Odor: Characteristic
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Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:~278 C (~532.4 F)
Flash point: 135 C (275 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 335 C (635 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 2 Vol %
Upper: 6.7 Vol %
Vapor pressure: Not determined.
Density at 20 C (68 F): 1 g/cm (8.35 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
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Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
(Contd. on page 8)
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49.1.7
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
US
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49.1.7
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 10)
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49.1.7
Hazard pictograms
GHS05GHS07
Signal wordDanger
Hazard-determining components of labeling:
Teta, reaction products with propylene oxide
Polyoxylated Triethylenetetramine
3,6-diazaoctanethylenediamin
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/12/2019 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
(Contd. on page 11)
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49.1.7
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
* Data compared to the previous version altered.
US
by | Sep 27, 2025
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49.1.7
1 Identification
Product identifier
Trade name: TCC104 Hardener
Article number:R151378-2
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07
(Contd. on page 2)
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Signal wordDanger
Hazard-determining components of labeling:
Teta, reaction products with propylene oxide
Polyoxylated Triethylenetetramine
3,6-diazaoctanethylenediamin
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
3
1
0
Health = 3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
(Contd. on page 3) US
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49.1.7
Dangerous components:
CAS: 26950-63-0 Teta, reaction products with propylene oxide
Polyoxylated Triethylenetetramine
50-100%
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 10-20%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
(Contd. on page 4)
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49.1.7
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
PAC-2:
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
PAC-3:
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the remaining constituent has no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
(Contd. on page 5) US
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49.1.7
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Amber colored
Odor: Characteristic
(Contd. on page 6)
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49.1.7
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:~278 C (~532.4 F)
Flash point: 135 C (275 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 335 C (635 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 2 Vol %
Upper: 6.7 Vol %
Vapor pressure: Not determined.
Density at 20 C (68 F): 1 g/cm (8.35 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
(Contd. on page 7)
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49.1.7
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
(Contd. on page 8)
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49.1.7
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
US
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 10)
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49.1.7
Hazard pictograms
GHS05GHS07
Signal wordDanger
Hazard-determining components of labeling:
Teta, reaction products with propylene oxide
Polyoxylated Triethylenetetramine
3,6-diazaoctanethylenediamin
Hazard statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/12/2019 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
(Contd. on page 11)
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PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
* Data compared to the previous version altered.
US
