by | Sep 27, 2025
Page 1/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
50.0
1 Identification
Product identifier
Trade name: TCC102 Hardener
Article number:I070102
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
Repr. 1B H360 May damage fertility or the unborn child.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
(Contd. on page 2)
US
Page 2/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 1)
50.0
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3,6-diazaoctanethylenediamin
2,2′-iminodiethylamine
bisphenol A
4-nonylphenol, branched
butyl glycidyl ether
Hazard statements
Harmful if swallowed.
Toxic if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
May damage fertility or the unborn child.
May cause respiratory irritation.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
(Contd. on page 3)
US
Page 3/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 2)
50.0
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 25- 50%
CAS: 84852-15-3
EINECS: 284-325-5
4-nonylphenol, branched 10-20%
CAS: 80-05-7
EINECS: 201-245-8
bisphenol A 10-<20%
CAS: 111-40-0
EINECS: 203-865-4
2,2'-iminodiethylamine 10-<20%
CAS: 2426-08-6
EINECS: 219-376-4
butyl glycidyl ether 0.1-<1%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
(Contd. on page 4)
US
Page 4/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 3)
50.0
Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
(Contd. on page 5)
US
Page 5/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 4)
50.0
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
84852-15-3 4-nonylphenol, branched 3.9 mg/m
80-05-7 bisphenol A 15 mg/m
111-40-0 2,2'-iminodiethylamine 3 ppm
2426-08-6 butyl glycidyl ether 9 ppm
PAC-2:
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
84852-15-3 4-nonylphenol, branched 43 mg/m
80-05-7 bisphenol A 110 mg/m
111-40-0 2,2'-iminodiethylamine 8.5 ppm
2426-08-6 butyl glycidyl ether 580 ppm
PAC-3:
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
84852-15-3 4-nonylphenol, branched 260 mg/m
80-05-7 bisphenol A 650 mg/m
111-40-0 2,2'-iminodiethylamine 51 ppm
2426-08-6 butyl glycidyl ether 3,500 ppm
7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
US
(Contd. on page 6)
Page 6/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 5)
50.0
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
111-40-0 2,2'-iminodiethylamine
REL Long-term value: 4 mg/m , 1 ppm
Skin
TLV Long-term value: 4.2 mg/m , 1 ppm
Skin
2426-08-6 butyl glycidyl ether
PEL Long-term value: 270 mg/m , 50 ppm
REL Ceiling limit value: 30 mg/m , 5.6 ppm
*15-min
TLV Long-term value: 16 mg/m , 3 ppm
Skin; DSEN
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
(Contd. on page 7)
US
Page 7/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 6)
50.0
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Amber colored
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:207.1 C (404.8 F)
Flash point: 122 C (251.6 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 325 C (617 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 1 Vol %
Upper: 10 Vol %
(Contd. on page 8)
US
Page 8/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 7)
50.0
Vapor pressure at 20 C (68 F):0.5 hPa (0.4 mm Hg)
Density at 20 C (68 F): 1.02 g/cm (8.51 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 11.1 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:
Aldehyde
Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
(Contd. on page 9)
US
Page 9/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 8)
50.0
80-05-7 bisphenol A
Oral LD50 3,250 mg/kg (rat)
Dermal LD50 3,000 mg/kg (rabbit)
111-40-0 2,2'-iminodiethylamine
Oral LD50 1,553 mg/kg (rat)
Dermal LD50 1,045 mg/kg (rabbit)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Toxic
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
(Contd. on page 10)
US
Page 10/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 9)
50.0
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT NA2735
IMDG, IATA UN2735
UN proper shipping name
DOT Amines, liquid, corrosive, n.o.s. (Triethylenetetramine,
Diethylenetriamine)
IMDG A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE), MARINE
POLLUTANT
IATA A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
(Contd. on page 11)
US
Page 11/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 10)
50.0
Label 8
IMDG
Class 8 Corrosive substances
Label 8
IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards: Product contains environmentally hazardous substances: 4-
nonylphenol, branched
Marine pollutant: Yes
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Segregation Code SG35 Stow "separated from" SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 1L
(Contd. on page 12)
US
Page 12/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 11)
50.0
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": U N 2 7 3 5 A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE), 8, II,
ENVIRONMENTALLY HAZARDOUS
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
84852-15-3 4-nonylphenol, branched
80-05-7 bisphenol A
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
80-05-7 bisphenol A
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
(Contd. on page 13)
US
Page 13/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 12)
50.0
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3,6-diazaoctanethylenediamin
2,2'-iminodiethylamine
bisphenol A
4-nonylphenol, branched
butyl glycidyl ether
Hazard statements
Harmful if swallowed.
Toxic if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
May damage fertility or the unborn child.
May cause respiratory irritation.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 14)
US
Page 14/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 13)
50.0
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision09/11/2018 / 4
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Acute Tox. 3: Acute toxicity Category 3
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
Repr. 1B: Reproductive toxicity Category 1B
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
Aquatic Acute 2: Hazardous to the aquatic environment - acute aquatic hazard Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
US
by | Sep 27, 2025
Page 1/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
50.0
1 Identification
Product identifier
Trade name: TCC102 Hardener
Article number:I070102
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
Repr. 1B H360 May damage fertility or the unborn child.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
(Contd. on page 2)
US
Page 2/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 1)
50.0
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3,6-diazaoctanethylenediamin
2,2′-iminodiethylamine
bisphenol A
4-nonylphenol, branched
butyl glycidyl ether
Hazard statements
Harmful if swallowed.
Toxic if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
May damage fertility or the unborn child.
May cause respiratory irritation.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
(Contd. on page 3)
US
Page 3/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 2)
50.0
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 25- 50%
CAS: 84852-15-3
EINECS: 284-325-5
4-nonylphenol, branched 10-20%
CAS: 80-05-7
EINECS: 201-245-8
bisphenol A 10-<20%
CAS: 111-40-0
EINECS: 203-865-4
2,2'-iminodiethylamine 10-<20%
CAS: 2426-08-6
EINECS: 219-376-4
butyl glycidyl ether 0.1-<1%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
(Contd. on page 4)
US
Page 4/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 3)
50.0
Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
(Contd. on page 5)
US
Page 5/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 4)
50.0
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
84852-15-3 4-nonylphenol, branched 3.9 mg/m
80-05-7 bisphenol A 15 mg/m
111-40-0 2,2'-iminodiethylamine 3 ppm
2426-08-6 butyl glycidyl ether 9 ppm
PAC-2:
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
84852-15-3 4-nonylphenol, branched 43 mg/m
80-05-7 bisphenol A 110 mg/m
111-40-0 2,2'-iminodiethylamine 8.5 ppm
2426-08-6 butyl glycidyl ether 580 ppm
PAC-3:
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
84852-15-3 4-nonylphenol, branched 260 mg/m
80-05-7 bisphenol A 650 mg/m
111-40-0 2,2'-iminodiethylamine 51 ppm
2426-08-6 butyl glycidyl ether 3,500 ppm
7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
US
(Contd. on page 6)
Page 6/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 5)
50.0
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
111-40-0 2,2'-iminodiethylamine
REL Long-term value: 4 mg/m , 1 ppm
Skin
TLV Long-term value: 4.2 mg/m , 1 ppm
Skin
2426-08-6 butyl glycidyl ether
PEL Long-term value: 270 mg/m , 50 ppm
REL Ceiling limit value: 30 mg/m , 5.6 ppm
*15-min
TLV Long-term value: 16 mg/m , 3 ppm
Skin; DSEN
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
(Contd. on page 7)
US
Page 7/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 6)
50.0
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Amber colored
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:207.1 C (404.8 F)
Flash point: 122 C (251.6 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 325 C (617 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 1 Vol %
Upper: 10 Vol %
(Contd. on page 8)
US
Page 8/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 7)
50.0
Vapor pressure at 20 C (68 F):0.5 hPa (0.4 mm Hg)
Density at 20 C (68 F): 1.02 g/cm (8.51 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 11.1 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:
Aldehyde
Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
(Contd. on page 9)
US
Page 9/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 8)
50.0
80-05-7 bisphenol A
Oral LD50 3,250 mg/kg (rat)
Dermal LD50 3,000 mg/kg (rabbit)
111-40-0 2,2'-iminodiethylamine
Oral LD50 1,553 mg/kg (rat)
Dermal LD50 1,045 mg/kg (rabbit)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Toxic
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
(Contd. on page 10)
US
Page 10/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 9)
50.0
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT NA2735
IMDG, IATA UN2735
UN proper shipping name
DOT Amines, liquid, corrosive, n.o.s. (Triethylenetetramine,
Diethylenetriamine)
IMDG A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE), MARINE
POLLUTANT
IATA A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
(Contd. on page 11)
US
Page 11/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 10)
50.0
Label 8
IMDG
Class 8 Corrosive substances
Label 8
IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards: Product contains environmentally hazardous substances: 4-
nonylphenol, branched
Marine pollutant: Yes
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Segregation Code SG35 Stow "separated from" SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 1L
(Contd. on page 12)
US
Page 12/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 11)
50.0
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": U N 2 7 3 5 A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE), 8, II,
ENVIRONMENTALLY HAZARDOUS
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
84852-15-3 4-nonylphenol, branched
80-05-7 bisphenol A
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
80-05-7 bisphenol A
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
(Contd. on page 13)
US
Page 13/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 12)
50.0
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3,6-diazaoctanethylenediamin
2,2'-iminodiethylamine
bisphenol A
4-nonylphenol, branched
butyl glycidyl ether
Hazard statements
Harmful if swallowed.
Toxic if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
May damage fertility or the unborn child.
May cause respiratory irritation.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 14)
US
Page 14/14
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/04/2020 Reviewed on 09/11/2018
Trade name: TCC102 Hardener
(Contd. of page 13)
50.0
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision09/11/2018 / 4
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Acute Tox. 3: Acute toxicity Category 3
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
Repr. 1B: Reproductive toxicity Category 1B
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
Aquatic Acute 2: Hazardous to the aquatic environment - acute aquatic hazard Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
US
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
INDEX
80TC1611
80TC1611-F
80TC1611-G
80TC1611-Q
SAFETY DATA SHEET
Date Prepared : 04/15/2015
SDS No : TC-1611 PART A
TC-1611 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-1611 PART A
GENERAL USE: Epoxy resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Exclamation
mark
Environment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see on this label).
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
Page 1 of 8
P362: Take off contaminated clothing and wash before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Black paste-like with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. Causes eye and skin irritation. May cause allergic skin
reaction. May be harmful if swallowed. Use in well ventilated areas.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation. May cause an allergic skin reaction.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing skin conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Barium sulfate 30 – 607727-43-7
Epoxy phenol novolac resin 15 – 4028064-14-4
Glycidyl ether, Aliphatic, Modifier 1 – 514228-73-0
Carbon Black 1 – 51333-86-4
Silica, Amorphous 0.5 – 1.57631-86-9
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, aldehydes, hydrocarbons, and phenolics.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
Page 2 of 8
TC-1611 PART A
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 8
TC-1611 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Barium sulfate
TWA NE
[1]
15T,5R
[1]
NE 10 NE
[2]
10T,5R
[2]
STEL NE NE NE NE NE NE
Epoxy phenol novolac resin
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Glycidyl ether, Aliphatic, Modifier
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Carbon Black
TWA NE 3.5 NE 3.5 NE
[2]
3.5
[2]
STEL NE NE NE NE NE NE
Silica, Amorphous
TWA
20
mppcf
[4]
80
%SiO2
[4]
NE
10 Total
Dust
NE
[2]
6
[2]
STEL NE NE NE NE NE NE
Footnotes:
1. T = Total, R = Respirable
2. NIOSH REL, T = Total, R = Respirable
3. NIOSH REL
4. Mineral Dusts
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Paste-like
ODOR: Slight
COLOR: Black
pH: Not Established
PERCENT VOLATILE: 0.07
Page 4 of 8
TC-1611 PART A
FLASH POINT AND METHOD: > 93.3 C (200 F) Closed Cup
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Insoluble
SPECIFIC GRAVITY: 1.85 (water=1) at 25 C (77 F)
VISCOSITY: Paste-like
(VOC): < 1.300 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS POLYMERIZATION: Product can undergo hazardous polymerization. This product will autopolymerize at very high
temperatures.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures and sources of ignition.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, aldehydes, and phenolics.
INCOMPATIBLE MATERIALS: Strong acids, bases, oxidizing agents, and amines.
11. TOXICOLOGICAL INFORMATION
ACUTE
Chemical Name ORAL LD50 DERMAL LD50
INHALATION
LC
50
Barium sulfate Not Established Not Established Not Established
Epoxy phenol novolac resin > 2000 mg/kg > 2000 mg/kg Not Established
Glycidyl ether, Aliphatic, Modifier 2450 mg/kg 2500 mg/kg Not Established
Carbon Black > 8000 g/kg Not Established Not Established
Silica, Amorphous Not Established Not Established Not Established
CARCINOGENICITY
Chemical Name
IARC
Status
Carbon Black 2B
Silica, Amorphous 3
IARC: This product contains substances that are classified as carcinogens to humans.
IRRITATION: Causes eye and skin irritation.
SENSITIZATION: May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
Page 5 of 8
TC-1611 PART A
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Epoxy phenol novolac resin
PRIMARY HAZARD CLASS/DIVISION: 9
UN/NA NUMBER: UN3082
PACKING GROUP: III
NAERG: 171
LABEL: Class 9 (miscellaneous hazardous materials)
MARINE POLLUTANT #1: Yes
OTHER SHIPPING INFORMATION: Only regulated for bulk and vessel shipments, per 49CFR171.4 (c) Exceptions. Except when all or
part of the transportation is by vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk
packagings transported by motor vehicle, rail car, or aircraft.
ROAD AND RAIL (ADR/RID)
PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (Epoxy phenol novolac resin)
UN NUMBER: UN3082
HAZARD CLASS: 9
PACKING GROUP: III
LABEL: Class 9 (miscellaneous hazardous materials)
AIR (ICAO/IATA)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Epoxy phenol novolac resin
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
ERG: 9L
LABEL: Class 9 (miscellaneous hazardous materials)
NOTE: Only regulated for bulk and vessel shipments, per 49CFR171.4 (c) Exceptions. Except when all or part of the transportation is by
vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk packagings transported by motor vehicle,
rail car, or aircraft.
VESSEL (IMO/IMDG)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL NAME: Epoxy phenol novolac resin
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
EmS: F-A, S-F
MARINE POLLUTANT #1: Yes
Page 6 of 8
TC-1611 PART A
LABEL: Class 9 (miscellaneous hazardous materials)
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Carbon Black 1 – 5 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
D2A – Very
Toxic
D2B – Toxic
WHMIS CLASSIFICATION
Class D2A: Poisonous and infectious material (Very toxic).
Class D2B: Poisonous and infectious material (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D2A – Chronic toxicity
D2A – Carcinogenicity
D2B – Mutagenicity
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
Page 7 of 8
TC-1611 PART A
REASON FOR ISSUE: Revised format
Date Prepared: 04/15/2015
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 8 of 8
TC-1611 PART A
SAFETY DATA SHEET
Date Prepared : 04/15/2015
SDS No : TC-1611 PART B
TC-1611 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-1611 PART B
GENERAL USE: Epoxy curing agent
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 4
Acute Toxicity (Dermal), Category 4
Skin Corrosion, Category 1
Serious Eye Damage, Category 1
Skin Sensitization, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Exclamation
mark
CorrosionEnvironment
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
Page 1 of 8
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see on this label).
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P391: Collect spillage.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Amber liquid with an ammoniacal odor.
IMMEDIATE CONCERNS: Corrosive. Causes eye and skin burns. Causes respiratory tract irritation. May cause allergic skin reaction.
May be harmful if absorbed through skin. Contains material that may cause target organ damage, based on animal data. Do not breathe
vapor or mist. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until
ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Causes eye burns. May cause blindness. Severe eye irritation.
SKIN: Causes severe skin burns. May cause an allergic skin reaction.
INGESTION: Harmful if swallowed. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus
and the stomach.
INHALATION: May be harmful if inhaled. May cause respiratory tract irritation.
CARCINOGENICITY: This product contains ingredients that are considered to be probable or suspected human carcinogens.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye and skin conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
TARGET ORGAN STATEMENT: Contains material which may cause damage to the following organs: skin, eyes, respiratory system,
reproductive system, kidney, and liver.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Tetraethylenepentamine 30 – 60112-57-2
2-piperazin-1-ylethylamine 15 – 40140-31-8
Diethyltoluenediamine (DETDA) 7 – 1368479-98-1
2-Ethyl-4-methylimidazole 1 – 5931-36-2
Diethylenetriamine (DETA) 0.1 – 1111-40-0
1h-imidazole, 5-methyl- 0.1 – 1822-36-6
4. FIRST AID MEASURES
Page 2 of 8
TC-1611 PART B
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention immediately. Wash
clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
CHRONIC EFFECTS: Prolonged contact may result in chemical burns and permanent damage. May cause allergic skin reaction.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
GENERAL HAZARD: May generate ammonia gas. May generate nitrogen oxide gases. Incomplete combustion may form carbon monoxide.
Downwind personnel must be evacuated. Burning of material produces obnoxious and toxic fumes.
EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, or limestone powder.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammonia, aldehydes,
nitrosamine, and chlorine.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Do not use sodium nitrite or other nitorsating agents in formulations containing this product. Suspected cancer causing
nitrosamines could be formed. Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area.
Handle and use in a manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 8
TC-1611 PART B
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Tetraethylenepentamine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
2-piperazin-1-ylethylamine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Diethyltoluenediamine (DETDA)
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
2-Ethyl-4-methylimidazole
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Diethylenetriamine (DETA)
TWA NE NE 1 NE 1
[1]
4
[1]
STEL NE NE NE NE NE NE
1h-imidazole, 5-methyl-
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Footnotes:
1. NIOSH REL (skin)
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Ammoniacal
COLOR: Amber
pH: Alkaline
FLASH POINT AND METHOD: > 100 C (212 F) Closed Cup
VAPOR PRESSURE: Not Established
Page 4 of 8
TC-1611 PART B
VAPOR DENSITY: Not Established
BOILING POINT: > 132.2 C (270 F)
SOLUBILITY IN WATER: Moderately soluble
SPECIFIC GRAVITY: 0.98 (water=1) at 25 C (77 F)
VISCOSITY #1: 60 Centipoise at 25 C (77 F)
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: No data available
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with peroxide may resulting violent decomposition of peroxide possibly creating
an explosion. CAUTION! N-Nitrosamines, many of which are known to be potent carcinogens, may be formed when the product comes in
contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammonia, aldehydes,
nitrosamine, and chlorine.
INCOMPATIBLE MATERIALS: Sodium hypochlorite, organic acids, mineral acids, oxidizing agents, and nitrous acid.
11. TOXICOLOGICAL INFORMATION
ACUTE
Chemical Name ORAL LD50 DERMAL LD50
INHALATION
LC
50
Tetraethylenepentamine 2140 mg/kg > 660 mg/kg Not Established
2-piperazin-1-ylethylamine Not Established Not Established Not Established
Diethyltoluenediamine (DETDA) 738 mg/kg > 2000 mg/kg Not Established
2-Ethyl-4-methylimidazole 1000 mg/kg > 400 mg/kg Not Established
Diethylenetriamine (DETA) Not Established Not Established> 0.07 mg/l (4 h)
1h-imidazole, 5-methyl- Not Established Not Established Not Established
CHRONIC: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
CARCINOGENICITY
Chemical Name
IARC
Status
1h-imidazole, 5-methyl- 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
IRRITATION: Causes severe eye and skin irritation.
CORROSIVITY: Corrosive to the eyes and skin.
SENSITIZATION: May cause sensitization by skin contact.
TARGET ORGANS: Contains material which may cause damage to the following organs: skin, eyes, respiratory system, reproductive system,
kidney, and liver.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
Page 5 of 8
TC-1611 PART B
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Corrosive liquids, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
PRIMARY HAZARD CLASS/DIVISION: 8
UN/NA NUMBER: UN1760
PACKING GROUP: III
NAERG: 154
LABEL: Corrosive
ROAD AND RAIL (ADR/RID)
PROPER SHIPPING NAME: Corrosive liquid, n.o.s. (tetraethylenepentamine solution)
UN NUMBER: UN1760
HAZARD CLASS: 8
PACKING GROUP: III
LABEL: Corrosive
AIR (ICAO/IATA)
SHIPPING NAME: Corrosive liquid, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
UN/NA NUMBER: UN1760
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
ERG: 8L
LABEL: Corrosive
VESSEL (IMO/IMDG)
SHIPPING NAME: Corrosive liquid, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
UN/NA NUMBER: UN1760
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
EmS: F-A, S-B
MARINE POLLUTANT #1: Yes
LABEL: Corrosive
15. REGULATORY INFORMATION
Page 6 of 8
TC-1611 PART B
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains diethyltoluenediamine (DETDA) (CAS No: 68479-98-1) which is subject to TSCA
12(b), Section 4 export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
1h-imidazole, 5-methyl- 0.1 – 1 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
D2B – ToxicE – Corrosive
WHMIS CLASSIFICATION
Class D2B: Poisonous and infectious material (Toxic).
Class E: Corrosive material
WHMIS HEALTH EFFECTS CRITERIA
D2B – Eye irritation
D2B – Skin Sensitization
E – Corrosive to Skin
E – TDG Class 8 – corrosive substance
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revised format
Date Prepared: 04/15/2015
Page 7 of 8
TC-1611 PART B
HMIS RATING
HEALTH * 3
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
3 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 8 of 8
TC-1611 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 3/18/2014
MSDS No : TC-1604 PART A
TC-1604 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-1604 PART A
GENERAL USE: Epoxy resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Mutagenicity, Category 1
Carcinogenicity, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Exclamation
mark
Health hazardEnvironment
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H340: May cause genetic defects.
H350: May cause cancer.
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
Page 1 of 8
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P321: Specific treatment (see on this label).
P362: Take off contaminated clothing and wash before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P314: Get medical advice/attention if you feel unwell.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P391: Collect spillage.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: White viscous liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. Causes eye and skin irritation. Can cause allergic skin
reaction. May be harmful if swallowed. Use in well ventilated areas.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation. May cause an allergic skin reaction.
INGESTION: May be harmful if swallowed.
INHALATION: May result in respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing skin conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Phenol, 4,4′-(1-methylethylidene)bis, polymer with (chloromethyl)oxirane 60 – 10025068-38-6
Calcium Carbonate (limestone) 10 – 301317-65-3
2,3-epoxypropyl O-tolyl Ether 5 – 102210-79-9
Furfuryl Alcohol 1 – 5 98-00-0
Titanium oxide (TiO2) 1 – 513463-67-7
Silica, Crystalline < 0.114808-60-7
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
Page 2 of 8
TC-1604 PART A
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or alcohol foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 8
TC-1604 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Phenol, 4,4'-(1-methylethylidene)bis, polymer with
(chloromethyl)oxirane
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Calcium Carbonate (limestone)
TWA NE
[1]
15T 5R
[1]
NE 10 NE NE
STEL NE NE NE NE NE NE
2,3-epoxypropyl O-tolyl Ether
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Furfuryl Alcohol
TWA 50 200 10 40 10 40
STEL NE NE 15 60 15 60
Titanium oxide (TiO2)
TWA NE
15 Total
Dust
NE 10 NE NE
STEL NE NE NE NE NE NE
Silica, Crystalline
TWA250 mppcf 10 NE 0.025 NE
[2]
0.05
[2]
STEL NE NE NE NE NE NE
OSHA TABLE COMMENTS:
1. T = Total, R = Respirable
2. NIOSH REL
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: White
pH: Not Established
Page 4 of 8
TC-1604 PART A
PERCENT VOLATILE: 0.22
FLASHPOINT AND METHOD: > 125 C (257 F) Closed Cup
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Practically insoluble
SPECIFIC GRAVITY: 1.28 (water=1) at 25 C (77 F)
VISCOSITY: 8500 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 2.820 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: No data available.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Strong oxidizing agents, strong alkalies, and strong acids.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Phenol, 4,4'-(1-methylethylidene)bis, polymer with (chloromethyl)oxirane 30000 mg/kg > 1200 mg/kg Not Established
Calcium Carbonate (limestone) Not Established Not Established Not Established
2,3-epoxypropyl O-tolyl Ether > 2000 mg/kg Not Established 1220 ppm
Furfuryl Alcohol 177 mg/kg 3825 ml/kg Not Established
Titanium oxide (TiO2) > 10000 mg/kg> 10000 mg/kg > 6.82 mg/l
Silica, Crystalline Not Established Not Established Not Established
CHRONIC EFFECTS: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
CARCINOGENICITY
Chemical Name NTP Status
IARC
Status
Titanium oxide (TiO2) 2B
Silica, Crystalline 1 1
IARC: This product contains substances that are classified as carcinogens to humans.
IRRITATION: Causes eye and skin irritation.
SENSITIZATION: May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
Page 5 of 8
TC-1604 PART A
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND
PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Bisphenol A epoxy resin
PRIMARY HAZARD CLASS/DIVISION: 9
UN/NA NUMBER: UN3082
PACKING GROUP: III
ERG CODE: 171
LABEL: Class 9 (miscellaneous hazardous materials)
MARINE POLLUTANT #1: Yes
NOTE: Only regulated for bulk and vessel shipments, per 49CFR171.4 (c) Exceptions. Except when all or part of the transportation is by
vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk packagings transported by motor vehicle,
rail car, or aircraft.
AIR (ICAO/IATA)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Bisphenol A epoxy resin
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
ERG CODE: 9L
LABEL: Class 9 (miscellaneous hazardous materials)
NOTE: Only regulated for bulk and vessel shipments, per 49CFR171.4 (c) Exceptions. Except when all or part of the transportation is by
vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk packagings transported by motor vehicle,
rail car, or aircraft.
VESSEL (IMO/IMDG)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL NAME: Bisphenol A epoxy resin
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
EmS: F-A, S-F
MARINE POLLUTANT #1: Yes
LABEL: Class 9 (miscellaneous hazardous materials)
15. REGULATORY INFORMATION
Page 6 of 8
TC-1604 PART A
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
D2A – Very
Toxic
D2B – Toxic
WHMIS CLASSIFICATION
Class D2A: Poisonous and infectious material (Very toxic).
Class D2B: Poisonous and infectious material (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D2A – Carcinogenicity
D2B – Eye irritation
D2B – Skin Sensitization
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revised format
Page 7 of 8
TC-1604 PART A
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 8 of 8
TC-1604 PART A
SAFETY DATA SHEET
Date Issued : 3/18/2014
MSDS No : TC-1604 PART B
TC-1604 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-1604 PART B
GENERAL USE: Epoxy curing agent
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 4
Acute Toxicity (Dermal), Category 4
Skin Corrosion, Category 1
Eye Corrosion, Category 1
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Reproductive Toxicity, Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
Physical:
Flammable Liquids, Category 4
GHS LABEL
CorrosionHealth hazardEnvironment
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H227: Combustible liquid.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects.
H361: Suspected of damaging fertility or the unborn child .
PRECAUTIONARY STATEMENT(S)
Page 1 of 8
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P285: In case of inadequate ventilation wear respiratory protection.
P273: Avoid release to the environment.
Response:
P370+P378: In case of fire: Use alcohol resistant foam, carbon dioxide, dry chemical, dry sand, water spray (fog), or limestone powder
for extinction. Do not use water jet.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P321: Specific treatment (see on this label).
P363: Wash contaminated clothing before reuse.
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P391: Collect spillage.
Storage:
P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber liquid with an ammoniacal odor.
IMMEDIATE CONCERNS: Combustible liquid. Keep away from heat, sparks, and flame. Corrosive to eyes and skin. Causes burns. May
be harmful if absorbed through skin or if swallowed. Irritating to the respiratory system. Do not breathe vapor or mist. Do not ingest. Do
not get in eyes or on skin or clothing. Contains material that may target organ damage, based on animal data. Use only with adequate
ventilation. Keep container tightly closed and sealed untill ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Causes eye burns. May cause blindness. Severe eye irritation.
SKIN: Causes skin burns, severe irritation and possible allergic reaction.
INGESTION: Harmful if swallowed. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus
and the stomach.
INHALATION: Irritating to respiratory system.
CARCINOGENICITY: Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of
exposure.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
TARGET ORGANS: Contains material which may cause damage to the following organs: kidneys, liver, central nervous system (CNS).
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Page 2 of 8
TC-1604 PART B
Chemical Name Wt.% CAS
Tetraethylenepentamine 60 – 100112-57-2
Triethanolamine 10 – 30102-71-6
Piperazine 3 – 7 110-85-0
2-piperazin-1-ylethylamine 1 – 5 140-31-8
Ethanol, 2, 2′-iminobis- < 0.1 111-42-2
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention immediately. Wash
clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
CHRONIC TOXICITY
CHRONIC EFFECTS: Prolonged contact may result in chemical burns and permanent damage. May cause allergic skin reaction.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
GENERAL HAZARD: May generate ammonia gas. May generate nitrogen oxide gases. Incomplete combustion may form carbon monoxide.
Downwind personnel must be evacuated. Burning of material produces obnoxious and toxic fumes.
EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, water spray (fog), or limestone powder. Do not
use water jet.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammonia, and nitrosamine.
EXPLOSION HAZARDS: Temperatures at or above the flash point could generate combustible mixtures. Avoid all ignition sources. "Empty"
containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FL AME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES O F
IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEAT H. Empty drums should be completely drained, properly bunged and
promptly returned to a drum reconditioner, or properly disposed of.
FIRE FIGHTING PROCEDURES: Remove containers from the fire area if possible. Do not release runoff from fire control methods to
sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Eliminate sources of ignition. Evacuate the area. Clean-up should only be performed by trained personnel. People dealing
with a major spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers
or waterways. Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Do not use
combustible materials such as saw dust. Use only spark resistant and explosion proof recovery devices. Shovel into open-top drums or plastic
bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of
residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
Page 3 of 8
TC-1604 PART B
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Combustible liquid. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid
breathing vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Do not use sodium nitrite or other nitorsating agents in formulations containing this product. Suspected cancer causing
nitrosamines could be formed. Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area.
Handle and use in a manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat in the original or similar container. Avoid sources of ignition
and incompatible materials. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Avoid
unnecessary contact.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Tetraethylenepentamine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Triethanolamine
TWA NE NE NE 5 NE NE
STEL NE NE NE NE NE NE
Piperazine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
2-piperazin-1-ylethylamine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Ethanol, 2, 2'-iminobis-
TWA NE NE NE NE 3
[1]
15
[1]
STEL NE NE NE NE NE NE
OSHA TABLE COMMENTS:
1. NIOSH REL
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Page 4 of 8
TC-1604 PART B
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Ammoniacal
COLOR: Amber
pH: Alkaline
PERCENT VOLATILE: 6.93
FLASHPOINT AND METHOD: > 90 C (194 F) Closed Cup
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Soluble
SPECIFIC GRAVITY: 1.02 (water=1) at 25 C (77 F)
VISCOSITY: Not Established
VOC (Volatile Organic Compound): < 70.700 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures and sources of ignition.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with peroxide may resulting violent decomposition of peroxide possibly creating
an explosion. CAUTION! N-Nitrosamines, many of which are known to be potent carcinogens, may be formed when the product comes in
contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammonia, and
nitrosamine.
INCOMPATIBLE MATERIALS: Sodium hypochlorite, organic acids, mineral acids, peroxides, oxidizing agents, nitrous acid, and other
nitrosating agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Tetraethylenepentamine 2140 mg/kg > 660 mg/kg Not Established
Triethanolamine Not Established Not Established Not Established
Piperazine Not Established Not Established Not Established
2-piperazin-1-ylethylamine Not Established Not Established Not Established
Ethanol, 2, 2′-iminobis-
700 to 2800
mg/kg
> 5000 mg/kg Not Established
CHRONIC EFFECTS: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when
Page 5 of 8
TC-1604 PART B
subsequently exposed to very low levels.
CARCINOGENICITY
Chemical Name
IARC
Status
Triethanolamine 3
Ethanol, 2, 2′-iminobis- 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
IRRITATION: Causes severe eye and skin irritation.
CORROSIVITY: Corrosive to the eyes and skin.
SENSITIZATION: May cause sensitization by skin contact.
REPRODUCTIVE EFFECTS: Suspected of damaging fertility. Suspected of damaging the unborn child.
TARGET ORGANS: Contains material which may cause damage to the following organs: kidneys, liver, central nervous system (CNS).
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND
PROPER SHIPPING NAME: Corrosive liquids, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
PRIMARY HAZARD CLASS/DIVISION: 8
UN/NA NUMBER: UN1760
PACKING GROUP: III
ERG CODE: 154
LABEL: Corrosive
AIR (ICAO/IATA)
SHIPPING NAME: Corrosive liquid, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
UN/NA NUMBER: UN1760
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
ERG CODE: 8L
LABEL: Corrosive
Page 6 of 8
TC-1604 PART B
VESSEL (IMO/IMDG)
SHIPPING NAME: Corrosive liquid, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
UN/NA NUMBER: UN1760
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
EmS: F-A, S-B
MARINE POLLUTANT #1: Yes
LABEL: Corrosive
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Ethanol, 2, 2′-iminobis- < 0.1100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Ethanol, 2, 2'-iminobis- < 0.1 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
Combustible
Liquid
WHMIS CLASSIFICATION
Class B3: Combustible liquid
Page 7 of 8
TC-1604 PART B
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revised format
HMIS RATING
HEALTH * 3
FLAMMABILITY 2
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
2
3 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 8 of 8
TC-1604 PART B
by | Sep 27, 2025
ENTERPRISES
SAFETY DATA SHEET
TC.157O PART A
Page
‘l
ot /
Date Issued : 0211312014
SDS No : TC-1570 PART A
Date Revised : 0V 1312020
Revision No :2WB
r. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-l570 PART A
GENERAL USE: Epoxy resin
MANTJFACTURER
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, C492780
Emergency Phone: (114) 73+8450
24 HR. EMERGENCY TELF-PHONE NI.]MBERS
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCl# 2820
2. HA ZARDS IDENTIFICATION
GHS CI.ASSIFICATIONS
Health:
Skin Irritation, Category 2
Serious Eye Damage Category I
Skin Sensitization, Category I
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS I-ABEL
CorrosionExclamation Environment
mark
SIGNAL WORD: DANGER
HAZARD STATEMEITS
H315: Causes skin irritation.
H318: Causes serious eye damage.
H3l7:.May cause an allergic skinreaction.
H411 : Toxic to aquatic life with long lasting effects.
PRE CAU TI ONARY STATWI ENTS
Prevention:
P2 6 I : Av oi d breathi ng dust/fu me/gas/mi st/v ap ours /spray.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wearprotective glovesfurotective clothing/eye protection/face protection.
P213: Avoid release to the environment.
Response:
P3A+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin initation orrashoccurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P35 1+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do
Continue rinsing.
t
I
Page2oI /
TC.157O PART A
P3 I 0 : Immediately call a POI SON CENTER/d octor/physici an.
P39l : Collect spillage.
Disposal:
P501 : Dispose of contents/container in accordance with local/regional/national/international regulations
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.Vo CAS
Barium sulfate 40-707727-43-1
2,2′-[( 1-methylethylidene)bis(4, I -phenyleneoxymethylene)] bisoxirane 10- 30 1615-54-3
Titanium dioxi de (IiO2) 3-7 13463-61-1
Oxirane, 2,2′ -11,4-butanediylbis(oxym ethylene) lbis-
1-5 2425-79-8
4. FIRST AID MEASURBS
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anyttring by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breatlring, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by nained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGIITING MEAST]RES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires’
6. ACCIDENTAL RELEASE MEASURF^S
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Eliminate all sources of ignition. Ensure adequate
ventilation. Use personal protective equipment. Dike and contain spill. Prevent product from entering drains or waterways. Absorb with non-
combustible material (such as sand, earth, diatomaceous earth, orvermiculite) and transferto a containerfor disposal according to
locaVnation al regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDIJRES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. IIANDLING AND STORAGE
GENERAL PROCED{.IRES: Avoid contact wit}r eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaVmanufacnrring techniques and practices’
Page 3 ot /
TC-1570 PART A
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from lieezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80’F (l 8 -21′ C)
SHELF LIFE: l2 months from date of shipment under manufacturers recommended storage conditions.
8. E)POSURE CONTROLS / PERSONAL PROTECTION
osHA HAZARDOUS COMPONENTS (29 CFR19r0.r200)
EXPOSURE LIMITS
Chemical Name Type ppm mdm3
TWA
_ tll151 5p ttl
OSTIA PEL
STEL
TWA 10
ACGIH TLV
STEL
NIOSH IDLH
_ tll191 5p ttlTWA
Barium sulfate
NIOSH REL STEL
TWA
OSHA PEL
STEL
TWA
ACGIH TLV
STEL
TWA
2,2′-[( 1-methylethylidene)bis(4, l-phenyleneoxymethylene)] bisoxirane
NIOSH REL
STEL
TWA
l2l
15
t2l
OSHA PEL
STEL
TWA 10
ACGIH TLV
STEL
TWA
Titanium dioxide (IiO2)
NIOSH REL
STEL
TWA
OSIIA PEL
STEL
TWA
ACGIH TLV
STEL
TWA
Oxirane, 2,2′ -ft,4 -btttwrediylbis(oxymethylene)lbis-
MOSH REL
STEL
Footnotes:
1. T = Total dust, R = Respirable fraction
2. Total dust
EXPOSURE G
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels
below recommended exposure limits.
PERSONA L PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
Page 4 ol /
TC.157O PART A
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wem nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and s election. Observe OSHA regulations for respirator use (29 CFR 19 I 0.1 34).
PROTECTfVE CLOTHING: Protective clothing should be selected and used in accordance with’Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower’
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEIVIICAL PROPERTTES
PHYSICAL STATE: Paste-LiKe
ODOR: Slight
COLOR: White
pH: No data available
FLASH POINT AID METHOD: > 200″C (392″F) Pensky-Martens CC
VAPORPRESSURE: No data available
VAPORDENSITY: No data available
BOILING POINT: No data available
SOLLJBILITY IN WATER: Insoluble
SPECIFIC GRAVITY:2.1 (water=l) at25oC Q1″n
VISCOSITY #1: 160000 Centipoise at25″C Q1’m
(VOC): Nil
10. STABILITY AND REACTTVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure
CONDITIONS TO AVOID: No data available
POSSIBILITYOF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INC OMPATIBLE MATERIALS: Oxidizing agents
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LDso DERMAL LDsO INHALATIONLCM
Barium sulfate No data availableNo data available No data available
2,2′ -f(l-methylethylidene)bis(4, 1-
pheny len eoxymethylene) lbi soxirane
> 5000 mglkg Rat> 2000 mg/kg Rabbit13.M mg/l Rat (4 h)
Titanium dioxide (IiO2) > 10000 mglkg Rat No data available> 6.82mgfl Rat (4 h)
Oxirane, 2,2′ -11,4-bttanediylbis(oxymethylene)lbis- 1410 mg/kg Rat> 2l5O mg/kgRabbit No data available
SKIN CORROSION/IRRITATION: Causes skin initation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious ey e dama ge.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by skin contacl
Page 5 ol /
TC.157O PART A
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name
IARC Status
2,2′-[( 1-methylethylidene)bis(4,1-phenyleneoxymettrylene)]bisoxirane
J
Titanium dioxide (Ti02) 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
EI{VIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may causelong-term adverse effecs in the aquatic environment.
Avoid release to the environment.
BIOACCUMUI-ATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CIIELICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISpOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable producs via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authorityrequirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Environmentally hazmdous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Bisphenol A epoxy resin
PRIMARY HAZARD CLASSiDIVISION : 9
UN/NANUMBER: tlN3082
PACKINGGROI.]P: Itr
NAERG:171
LABEL: Class 9 (miscellaneous hazardous materials)
MARINE POLLUTANT #1: Yes
OTHER SHIPPING INFORMATION : Only regulated for bulk and vessel shipments, per 49CFR 17 1.4 (c) Exceptions. Except when all or
part of the transportation is by vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk
packagings tansported by motor vehicle, rail car, or aircraft’
AIR (ICAO/IATA)
SHIPPING NAME: Environmentally hazardous substance, liquid, n’o’s. (See Note)
TECHMCAL NAME: Bisphenol A epoxy resin
LINNANUMBER: UN3082
PRIMARY HAZARD CLASS/DMSION: 9
PACKING GROUP: Itr
ERG:9L
LABEL: Class 9 (miscellaneous hazardous materials)
Page b oI /
TC.Is7O PART A
NOTE: Orrly regulatecl fbr bulk and vessel shipments, per 49CFR 17 L4 (c) Exceptions. Except when all or piu’t of the transportation is by
vessel. the requirements ol’this subchaptel specific to marine pollutants do not apply to non-bulk packagings tlansported by rnotor vehicle,
lail car. ol aircrali.
VESSIiI, (IMO/IMDG)
SHIPPI NG NA ME : Envi lonnren tally hazar dous substance, I iq uid, n.o. s.
TECHNICAI NAME: Bisphenol A epoxy resin
UN/NA NUMtsIlR: LlN3082
PRIMARY HAZARD CI,ASS/DIVISION: 9
PACKING GIIOUP: I]I
EnS: F-A, S-F
MARINE POLLUTANT #1: Yes
LAIIEL: Clnss 9 (rniscellaneous hazardous materials)
r5. REGT]LATORY INFORMATION
UNI’|I’D STA’TES
SARA TITLE III (SI]PERFUND AMENDMENTS AND REAUTHORI ZATION A CT)
3lll3l2 HEALTH HAZARDS: Referto Section 2forhazard clzssification.
3f3 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section
313 ol Title III o1’the Superf’und Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CI’RCI,A (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION,ANDLIABILITY ACT)
CERCLA REGIILATORY: This product does not contain any substances regulated as a hazar dous sttbstance under the Comprehensive
Envilonmental Response Compensation and Liability Act (CERCI-A) (40 CFR 302).
TSCA (TOXIC STJBSIhNCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject toTSCA Section l2(b) export notification.
TSCA STATUS: This product orits components are listed inorexempt liom theTSCA inventory requirements.
CLEAN AIR ACT
Chemical Name WtVo CAS
Epichlorohydrin 1 06-89-8
OCC UPATIONA L S AFETY AND HEA LTH ADMINISTRATION (OSHA
)
29 CFR1910.1I9—PROCF^SS SAFETYMANAGEMENTOF HIGHLYHAZARDOUS CHEMICAIf: None of the chemicals in
this product are considered highly hazat dous by OSHA.
CALIFORNIA PROPOSITION 65: A WARNING: This product can expose you to chemicals including [see table below], which is [are]
known [o the Stateof California to cause cancerand birth defecls or other reproductive harm. Formore information, go to
www.P65Wan.rin gs.ca.gov.
Chemical Name WLVo Listed
Titaniu n.r dioxide (Ti02) o Cancer
Epichlorohyddn
o Cancer
o Male Reproductive
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM): This product ha.s been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMFSTIC SUBSTANCE LIST (INVENTORY): All components in this product arc listed in ol exempted frorn the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GIINERAL COMMENTS: No data available
Page / ot /
TC.157O PART A
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revis ed z 021 1 312020
REVISION SUMMARY: This SDS replaces the02/l5D0l7 SDS.
HMISRATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without wan’anty, expressed ol implied, except that is accurate to the best
knowledge of BJB Enterprises,Inc. The dataon this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
XPERSONAL PROTECTION
HEALTH
FLAillMAI}ILITY
BTB
ENTERPRISES
SAFETY DATA SHEET
TC-1570 PART B
Page 1 ot /
Date Issued :0AB/2014
SDS No : TC-1570 PART B
Date Revised : 0A 13/2020
Revision No :2
1. PRODUCT AND COMPANY IDEIYTIFICATION
PRODUCT NAME: TC-I570 PART B
GENERAL USE: Epoxy curing agent
MANUFACTURER
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CAgn80
Emergency Phone: (114) 73+U50
24 HR. EMERGENCY TELEPHONE N{.]MBERS
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 4
Acute Toxicity ( Inhalation), Category 2
Skin Corrosion, Category I
Serious Eye Damage Category 1
Skin Sensitization, Category I
Reproductive Toxicity, Category I
Target Organ Toxicity (Single exposure), Category 3
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS I-ABEL
Skull and
crossbones
Corrosion Healthhazard Environment
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H302: Harmful if swallowed.
H330: Fatal if inhaled.
H3 14: Causes severe skin burns and eye damage.
H3 17: May cause an allergic skin reaction.
H360: May damage fertility or the unbom child.
H335: May cause respiratory irritation.
H4l I : Toxic to aquatic life with long lasting effects.
PRECAUTI ONARY STATEMENTS
Prevention:
P201 : Obtain special instructions before use.
PZA: Do not handle until all safety precautions have been read and understood.
P2 60 : Do n ot breath e du st/fu me/gas/mist/vapours/spr ay.
P27l: Use only outdoors or in a well-ventilated area.
lLs
Page:2oI /
TC-1570 PART B
PZM: ln case of inadequate ventilation wear respiratory protection.
P264 : Wash thoroughly aft er h andling.
P2l0: Do not eat, drink or smoke when using this product.
P212: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P301+P33GFP331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
p303+p361+p353: IFON SKIN (orhair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P363: Wash contaminated clothing before reuse.
P304+P340: IF INHALED: Remove person to fiesh air and keep comfortable for breathing.
p305+p35
1+p338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P3 10 : Immediately call a POISON CENTER/doctor/physician.
P308+P31 3: IF exposed or concerned: Getmedical advice/ attention’
P391 : Collect spillage.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501 : Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
WITo CAS
Polyamine adduct
30- 60Proprietary
1,2-Eth anediamine, N- (2- aminoethyl)-
l5 –
,10 I1140-0
4,4′ -Isopropyli den edipheno I l0- 30 80-05-7
4. FIRST AID MEASURE.S
EyES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical advice/attention.
SKIN: Immediately wash skin with soap andplenty of water. Remove contaminated clothing. Getmedical attention immediately. Wash
clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHAI-ATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrqstoccurs, provide artificial respiration or
oxygen by ftained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or alcohol-resistant foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide nitrogen oxides, nitric acid, ammoni4 aldehydes,
nitrosamine, and chlorine.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EeUIpMENT: Firefighrers should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
Page 3 ot /
TC.1570 PART B
SPLL AND LEAK PROCEDURBS: Evacuate unnecessary personnel from the spill area. Eliminate all sources of ignition. Ensure adequate
ventilation. Use personal protective equipment. Dike and contain spill. Prevent product from entering drains or waterways. Absorb with non-
combustible material (such as sand, earth, diatomaceous earth, orvermiculite) and transferto a containerfor disposal according to
I ocaVnational regulations.
EI{VIR ONM EN TAL PRECA UTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS forpersonal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLINGANDSTORAGE
GENERAL PROCEDURES: Avoid contract with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaVmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated placg away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from fieezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80’F (1 8 -n’ C)
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
8. E)(POSURE CONTROLS / PERSONAL PROTECTION
Page 4 ol /
TC-1570 PART B
osHA HAZARDOUS COMPONENTS (29 CFRl910.1200)
EXPOSURE LIMITS
ppm -d-tChemical Name Type
TWA
STEL
OSHA PEL
TWA
ACGIHTLV
STEL
TWA
NIOSH REL
STEL
Polyamine adduct
TWA 1 4
OSHA PEL
STEL
ITWA
ACGIH TLV
STEL
4 tllTWA I tl1
NIOSH REL
STEL
1,2-Ethanedi amine, N- (2- aminoethyl)-
TWA
OSIIA PEL
STEL
TWA
STEL
ACGIH TLV
TWA
STEL
4,4′ -Isopropyli d en edipheno I
MOSH REL
Footnotes:
l. Skin
ENGIIYEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
b elow recom mended exposure limits.
PERSONAL PROTECTTVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor carffidge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTfVE CLOTHING: Protective clothing should be selected and used in accordance with’Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIEMC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PITYSICAL AND CHEIVIICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
Page 5 ot /
TC.157O PART B
ODOR: Irritating
COLOR: Light yellow
pH: Alkaline
FLASH POINT AND METHOD: 110’C (230″F)
VAPORPRESSLJRE: No data available
VAPOR DEI{SITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Soluble
SPECIFIC GRAVITY: 1.08 (water=l) at25″C (11″D
VISCOSITY #1:3500 Centipoise at25″C (71’n
(VOC): Nil
10. STABILITY AND REACTTVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: No data available
POSSIBILITY OF IIAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammoni4 aldehydes,
nitrosamine, and chlorine.
INCOMPATIBLE MATERIALS: Sodium hypochlorite, organic acids, mineral acids, oxidizing agents, and nitrous acid.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LDso DERMAL LDsO INHALATIONLCsO
Polyamine adduct No data available No data available No data available
1,2-Ethanediamine, N-(2-aminoethyl)- 1080 mg/kg Rat 1090 mg/kg Rabbit 0.3 mg/l Rat (4 h)
4,4′ -Isopropylidenediphenol > 2000 mg/kg Rat 64ffimlkg Rabbit l70mglm3 Rat (6 h)
SKIN CORROSION/IRRITATION: Causes severe skin burns.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye damage.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by skin contacl
GERM CELL MUTAGENICITY: No data available
REPRODUCTM TOXICITY: May damage fertility orthe unbom child.
STOT-SINGLE E)POSURE: May cause respiratory irritation.
STOT-REPEATED E)POSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENMRONMENITAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may causelong-term adverse effects in the aquatic environment.
Avoid release to the environment.
B IOACC UMULA TION/A CCUMULATION: No d ata avai lab le
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
Page 6 ot /
TC-1570 PART B
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authorityrequirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER S HIPPING NAM E: Di ethyl enetri am ine solu ti on
PRIMARY HAZARD CLASS/DIVISION: 8
UN/NA NUMBER: UN2079
PACKING GROUP: II
NAERG:154
LABEL: Corrosive
AIR (ICAO/IATA)
SHIPPING NA ME : Diethylenetri am ine solution
UN/NA NUMBER: UN2079
PRIMARY HAZARD CLASS/DIVISION : 8
PACKING GROTIP: II
ERG:8L
LABEL: Corrosive
vEssEL (rMo/rMDG)
SHIPPING NAME : Diethylenetriamine solution
UN/NA NUMBER: UN2079
PRIMARY IIAZARD CLASS/DIVISION : 8
PACKING GROT]P: II
EmS: F-A, S-B
LABEL: Corrosive
15. REGTJLATORY INFORMATION
TJNITEDSTATES
SARA TITLE III (ST]PE RFUND A MENDM ENTS AND REAUTHORI ZATION A CT)
3llBl2 HEALTH HAZARDS: Referto Section 2forhazard classification.
313 REPORTABLE INGREDBNTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title trI of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Pat 372:
EPCRA SECTI ON 313 STJPPLTER NOTIFICATION
Chemical Name wt.10CAS
4,4′ -Isopropyli den ediphenol 10- 3080-05-7
CERCLA (COMPREHENSIVE EIWIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGLILATORY: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCI-A) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject toTSCA Section l2(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCC UPATIONA L S AFETY AND HEA LTH A DMIN ISTRATION (OSHA )
29 CFRDr0.1I9—PROCESS SAFETY MANAGEMENT OF HIGHLY IIAZARDOUS CHEMICAIS: None of the chemicals in
Page / oI /
TC-1570 PART B
this prodttct are cotrsidered highly haza dous by OSHA.
CALIFORNIA PROPOSITION 65: A WARNING: This product cim expose you to chemicals including Isee table belowl, which is [arel
known to the State of Calil’ornia to caLrse birrh det’ects ol’ other reprodr”rctive halm. For morc infortnation, go to www.P65Warnings.ca.gov.
Chemical Name Wt.Vo Listed
4.4′-lsopropylidenediphenol r0- 30 oFemale Reproductive
OSHA HAZARD COMM. RULE: The conrenrs of the SDS comply with the OSHA Hazard Cornrnunication Standard 29 CFR 1910′ 1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SImSTANCE LIST (INVENTORY): All componerlts in this product are listed in or exen]pted from the Domestic
Substances List (DSL) or the Non-Domestic Sttbstances List (NDSL)’
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revis ed : 021 1 3/2020
REVISION SUMMARY: This SDS replaces the 02l152017 SDS
HMIS RATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTLRER DISCLAIMER: This informarion is fumished without wananty, expressed or implied, except that is accurate to ttre best
knowledge of BJB Enteryrises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc’
assumes no legal responsibility for use or reliance upon this data.
XPERSONAL PROTECTION
HEALTH
FLAMMABILITY
IE
E
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
Material Safety DataSheet
Page1of5 Spabond 340LV resin
1 Productandcompanyidentification
Material identification:Spabond 340LV Resin
Applicati onofthesubstance/pr eparation:Epoxyresinadhesive
Supplier/Manu facturer :Gurit(Canada)Inc
175,rueP ladeau
Magog,Qu bec,J1X7L1
Canada
Tel:+1819847-2182
Fortranspo rtation emergencie s,call:Chemt rec:1-800-424-9300orCanutec (Canada): 613-996-6666
Foradditional informati on:Health,Safety andEnvironm entdepartment
Email:christian.moreau@gur it.com
Dateofissue:15/04/10
2 Hazardsidentifi cation
Emergency overview : Viscousliquid material containsepoxyconstituent s.
Hazardous status: Thismaterial isclassified hazardous under OSHA29CFR1910.1200 andunder
theCanadianContro lledProductsRegulati ons
Warning statement : WARNING!
CAUSESEYEANDSKIN IRRITA TION
MAYCAUSE RESPIRATORY TRACT IRRITATION
MAYCAUSE SENSITIZA TION BYSKINCONTACT
Avoidcontact withskinandclothing. Donotbreathevapor,useonlywithadequate
ventilation.
Wash thoroughly whenappropriate
Potential acutehealth effects:Eyes:Irritanttoeyes
Skin:Irritant toskinandmucus membranes .
Inhalation: Maycauserespiratorytractirritation.
Ingestion: Maycauseillness.
Potential chronichealth effects:Prolonged skincontact cancausesensitization.
3 Composi tion/information oningredients
Description :Mixture ofthesubstanc eslistedbelow withnonhaz ardousadditions .
Chem icalname CASnumber %Conce ntration
Propane, 2,2-bis[p-(2,3-epoxypr opoxy)phenyl] -,polymers 25085 -99-8 60 100%
Alkyl (C12,C14)GlycidylEther 68609 -97-2 5 10%
1,4-Butanediol Diglycidy lEther 2425-79-8 5 10%
Phenol, polymer withformaldehyde, GlycidylEther 28064 -14-4 1 5%
Material Safety DataSheet
Page2of5 Spabond 340LV resin
4 Firstaidmeasures
Eyecontact: Rinse immediatelywithplenty ofwater.Ifsymptom spersist, consultadoctor.
Skincontact : Immediat elywashwithsoapandrinsethoroughly .Remove clothing soiledbytheproduct.
Ingestion: Donotinduce vomiting.Rinse outmouth anddrinkplentyofwater.Callformedical help.
Inhalation : Removeindividualtofreshair.Consult adoctor ifsymptomspersist.
6 Accide ntalreleas emeasures
Person alprecautions : Wearprotectiveclothing toavoidcontact witheyesandskin.
Environm entalprecaution s: Prevent materialfromenteringwaterways, sewerssurface orground water.
Measuresforcleaning up: Scoop upspilled material.
5 Fire-fighting measures
Suitableextinguishi ngmedia:Waterhaze,foam, fire-extinguishing powder, carbon dioxide.
Notsuitab leextinguishi ngmedia:Waterwithfulljet.
Special exposurehazards: Formation oftoxicgaseswilloccurduring overheating orincaseoffire.
Protective equipment : Wearfullyprotective suitwithselfcontained breathing apparatus
(SCBA)withaface-pieceoperatedinpositivepressure mode.
7 Handling andstorage
Handling: Wearappropriatepersonalprotection whenhandling. Avoidinhalationofvapors.
Storage: Storeinacool,dryplaceintightly closed receptacles. Keepawayfromheat.
Dateofissue:15/04/10
Material Safety DataSheet
Page3of5 Spabond 340LV resin
9 Physical andchemical properties
Physicalstate: Pasty
Color: Yellow
Odor: Characterist ic(slight)
Flash point: >101
o
C(>214
o
F)
Melting point: Notavailable
Boilingpoint: >200
o
C(>392
o
F)
Ignition temperature : 460
o
C(860
o
F);Product isnotself-igniting
Vapor pressure (20
o
C(68
o
F): 0.075mmHg
Relative density : Notdeterm ined
Solubili tyinwater: Notmiscible
8 Expos urecontrols andpersonalprotection
Componen tswithlimitvaluesthatrequire monitoring attheworkp lace:Noneestablished
Enginee ringmeasures:Useonlywithadequateventilation oruserespiratoryprotection.
General measu res: Keepproductawayfromfoodandbeverage s.
Washhands before eatingandwhenever appropriate .
Immediately remove allsoiled andcontaminated clothing .
Avoidcontact witheyesandskin.
Person alprotection equipments:Eyes:Wearsafetyglasses
Skin:Weargloves andprotecti veworkclothes
Suitablegloves:Nitrilerubber(NBR).Selection ofgloves should takeinconsidera tionthequalityaspect
(thickness,strength, etc.)whichvariesfrommanufactu rertomanufacturer .
Dateofissue:15/04/10
Material Safety DataSheet
Page4of5 Spabond 340LV resin
10 Stability andreactivity
Stabilityandreactivity :Thisproductisstable.
Dangerous reaction : Nodanger ousreactions known.
Incompatibility withothersubstances: Strongoxidizers, strong acidsandbases,amines.
Hazardous decomposition products: Decomposit ionproducts includebutarenotlimitedto:Carbon
monoxide, Carbon dioxideandtoxicpyrolysis product s.
12 Ecologi calinformation
General notes:Toxictosomeaquaticorganisms. Prevent material toreachground water, waterways or
sewagesystem.
Ecotoxicitydata:Notavailabl e
Persistence andbiodegrad ability:Notavailable
Mobility:Notavailab le
13 Disposalconsideration
Wastedispos al:Disposal mustbeinaccordance withapplicableFederal, Stateandlocalregulatio ns.
Remarks : Donotallowmaterialtoenterdrains, sewers orsurface water.
Dateofissue:15/04/10
11 Toxicol ogical information
Toxicolog icalinformation
Ingredient name Test Result Route /species
Propane, 2,2-bis[p-(2,3-poxypr opoxy) phenyl] -,polymers LD50 >5000mg/kg Oralrat
Alkyl (C12,C14)GlycidylEther LD50 >5000mg/kg Oralrat
1,4-Butanediol Diglycidy lEther LD50 >1000mg/kg Oralrat
Phenol, polymer withformaldehyde, GlycidylEther LD50 >5000mg/kg Oralrat
Acute toxicity: Irritanttoeyes.
Irritanttoskinandmucous membranes.
Maycauserespirator ytractirritation.
Maycauseillness ifingested.
Sensitization: Sensitization possiblethrough skincontact.
Mutagenic effects :Notavailable
Teratogenic effects :Notavailab le
Carcin ogeniceffects:Notlistedascarcinogenic byACGIH ,OSHA, IARC andNTP.
Material Safety DataSheet
Page5of5 Spabond 340LV resin
15 Regul atoryinformation
U.S.Federa lregulat ions:
TSCA :Allcomponen tslisted.
SARA 302;304;311/312;313:Noneoftheingredient listed.
U.S.Stateregulations :
California Proposition65:Noneoftheingredient listed.
Canadian regulatio ns:
DSL:Allcompone ntslisted
WHMI Sclassification :D2B-Toxicmaterials causing othereffects;
1
0
HEALTH
FLAMMABIL ITY
PHYSIC ALHAZARDS
HMIS-rating Hazar drating
0-Minimal
1-Slight
2-Moderat e
3-Serious
4-Extreme
NFPA-rating
2
1
0
Health
Flammability
Reactivity
*2
Regulatorystatus
(UN/IMDG/ IATA;DOT/TDG) :Notregulated fortransport
16 Other information
References: AINSIZ400.1,MSDS Standard,2004;
29CFR 1910.1200 OSHA Hazard Communication Standard ;
Controlledproducts regulations(DORS/88 -66)Canada.
Noticetothereader:
Tothebestofourknowle dge,theinformationcontained hereinisaccurate atthedateofitspublication.However ,
thisshallnotconstitu teaguarant eeforanyspecificproduct features andshallnotestablish alegallyvalid
contractualrelationshi p.Thedatarelatesonlytothespecificproduct designated anddoesnotrelatetouseofthe
productinanyprocess orincombination withanyothermaterial.
14 Transport information
Dateofissue:15/04/10
Page 1/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
D R
* 1 Identification of substance
Product details
Trade name: Spabond 340 Extra Slow Hardener
Application of the substance / the preparationEpoxy curing agent
Manufacturer/Supplier:
GURIT (UK) Ltd GURIT (Canada) Inc.
St. CROSS BUSINESS PARK 175, rue P ladeau
NEWPORT I.O.W. Magog (Qu bec)
PO30 5WU J1X 5G9
UNITED KINGDOM Canada
TEL:+44(0)1983 828000 T: +1 819 847 2182
FAX:+44(0)1983 828100 F: +1 819 847 2572
Information department:Product safety department.
Emergency information:Contact as above
* 2 Composition/Data on components
Chemical characterization
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
9046-10-0 Polyoxyalkyleneamine 25-50%
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 10-25%
100-51-6 Benzyl alcohol 2.5-10%
3 Hazards identification
Hazard description:
C Corrosive
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of the “General Classification guideline for
preparations of the EU” in the latest valid version.
Causes burns.
May cause sensitization by skin contact.
Classification system:
The classification was made according to the latest editions of international substances lists, and expanded
upon from company and literature data.
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
(Contd. on page 2)
USA
Page 2/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 1)
D R
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
3
1
0
Health = 3
Fire = 1
Reactivity = 0
4 First aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Immediately rinse with water.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Do not induce vomiting; immediately call for medical help.
A person vomiting while lying on their back should be turned onto their side.
Administer medicinal carbon
Rinse out mouth and then drink plenty of water.
5 Fire fighting measures
Suitable extinguishing agents:
Water haze
Foam
Fire-extinguishing powder
Carbon dioxide
For safety reasons unsuitable extinguishing agents:Water with full jet
Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Protective equipment:
Mount respiratory protective device.
Wear fully protective suit.
6 Accidental release measures
Person-related safety precautions:Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection:Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
Handling:
Information for safe handling:
Store in cool, dry place in tightly closed receptacles.
(Contd. on page 3)
USA
Page 3/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 2)
D R
Keep away from heat and direct sunlight.
Information about protection against explosions and fires:No special measures required.
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
8 Exposure controls and personal protection
Additional information about design of technical systems:No further data; see item 7.
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:Use suitable respiratory protective device in case of insufficient ventilation.
Protection of hands:
Protective gloves
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to
the application.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
For the permanent contact of a maximum of 15 minutes gloves made of the following materials are
suitable:
Nitrile rubber, NBR
Eye protection:Safety glasses
Body protection:Protective work clothing
9 Physical and chemical properties
General Information
Form: Pasty
Color: Blue
Odor: Amine-like
Change in condition
Melting point/Melting range:Undetermined.
(Contd. on page 4)
USA
Page 4/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 3)
D R
Boiling point/Boiling range:247 C (477 F)
Flash point: 117 C (243 F)
Ignition temperature: 240.0 C (464 F)
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Density at 20 C (68 F): 1.090 g/cm
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Viscosity:
Dynamic at 20 C (68 F): 260000 mPas
Solvent content:
Organic solvents: 0.0 %
Water: 0.0 %
Solids content: 17.0 %
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Dangerous reactionsNo dangerous reactions known.
Dangerous products of decomposition:Danger of toxic pyrolysis products.
11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
9046-10-0 Polyoxyalkyleneamine
Oral LD50 2855 mg/kg (rat)
Dermal LD50 2980 mg/kg (rab)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:Strong caustic effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
esophagus and stomach.
12 Ecological information
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
(Contd. on page 5)
USA
Page 5/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 4)
D R
Do not allow product to reach ground water, water course or sewage system.
* 13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:
Packagings that cannot be cleansed are to be disposed of in the same manner as the product.
14 Transport information
DOT regulations:
Hazard class: 8
Identification number: UN3259
Packing group: II
Proper shipping name (technical name):P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Label 8
Land transport ADR/RID (cross-border):
ADR/RID class: 8 Corrosive substances
Danger code (Kemler): 80
UN-Number: 3259
Packaging group: II
Description of goods: 32 59 PO L YAMINES , SO L ID, CO RRO S IVE , N.O . S.
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Maritime transport IMDG:
IMDG Class: 8
UN Number: 3259
Label 8
Packaging group: II
EMS Number: F-A,S-B
Marine pollutant: No
(Contd. on page 6)
USA
Page 6/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 5)
D R
Propper shipping name: P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 8
UN/ID Number: 3259
Label 8
Packaging group: II
Propper shipping name: P O L Y A M I N E S , S O L I D , C O R R O S I V E , N . O . S .
(Polyoxyalkyleneamine, ISOPHORONEDIAMINE)
* 15 Regulations
Sara
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Cancerogenity categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
IARC (International Agency for Research on Cancer)
7631-86-9 silicon dioxide, chemically prepared 3
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
(Contd. on page 7)
USA
Page 7/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/06/2008 Reviewed on 05/06/2008
Trade name: Spabond 340 Extra Slow Hardener
(Contd. of page 6)
D R
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
Hazard symbols:
C Corrosive
Hazard-determining components of labelling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Benzyl alcohol
Polyoxyalkyleneamine
Risk phrases:
Causes burns.
May cause sensitization by skin contact.
Safety phrases:
When using do not eat or drink.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After contact with skin, wash immediately with plenty of water
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately.
This material and its container must be disposed of as hazardous waste.
National regulations:
All components in this formulation are listed in the EPA TSCA chemical inventory. They comply with
applicable rules and orders of the regulations.
Technical instructions (air):
Class Share in %
II 3.9
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
* 16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Department issuing MSDS:Health, Safety & Environmental department.
Contact:SIMON RHODES
* Data compared to the previous version altered.
USA
