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1 Identification
Product identifier
Trade name: PFR-405 Resin
Article number:I026031
Application of the substance / the mixturePolyester resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS02GHS08
Signal wordDanger
Hazard-determining components of labeling:
Phosphate Ester
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If experiencing respiratory symptoms: Call a poison center/doctor.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
2
0
Health = 2
Fire = 2
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
2
0
Health = *2
Fire = 2
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
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vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25013-15-4
EINECS: 246-562-2
Vinyl toluene 10-20%
Phosphate Ester 1-5%
CAS: 64-17-5
EINECS: 200-578-6
ethanol 1-5%
CAS: 91-99-6 N,N-Bishydroxyethyl-m-toluidine 0.1-1%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
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* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
64-17-5 ethanol 1,800 ppm
PAC-2:
64-17-5 ethanol 3300* ppm
PAC-3:
64-17-5 ethanol 15000* ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away – Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
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Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
25013-15-4 Vinyl toluene
PEL Long-term value: 480 mg/m , 100 ppm
REL Long-term value: 480 mg/m , 100 ppm
TLV Short-term value: 483 mg/m , 100 ppm
Long-term value: 242 mg/m , 50 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
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Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Thixotropic Paste
Color: Light yellow
Odor: Aromatic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:170 C (338 F)
Flash point: 53 C (127.4 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 494 C (921.2 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Explosion limits:
Lower: 1.1 Vol %
Upper: 5.2 Vol %
Vapor pressure at 20 C (68 F):1.5 hPa (1.1 mm Hg)
Density at 20 C (68 F): 1 g/cm (8.35 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
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Viscosity:
Dynamic at 20 C (68 F): 40,000 mPas
Kinematic: Not determined.
Solvent content:
Organic solvents: 19.6 %
Water: 0.0 %
VOC content: 19.62 %
196.3 g/l / 1.64 lb/gal
Solids content: 54.2 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
21645-51-2 aluminium hydroxide
Oral LD50 >2,000 mg/kg (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through inhalation.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
25013-15-4 Vinyl toluene 3
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64-17-5 ethanol 1
13463-67-7 titanium dioxide 2B
7631-86-9 silicon dioxide, chemically prepared 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, IMDG, IATA UN1866
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UN proper shipping name
DOT Resin solution
IMDG RESIN SOLUTION (1,4-dihydroxybenzene), MARINE POLLUTANT
IATA RESIN SOLUTION
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG
Class 3 Flammable liquids
Label 3
IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: 1,4-
dihydroxybenzene
Marine pollutant: Yes
Yes
Symbol (fish and tree)
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): 30
EMS Number: F-E,S-E
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
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Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: UN 1866 RESIN SOLUTION, 3, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
108-10-1 4-methylpentan-2-one
Proposition 65
Chemicals known to cause cancer:
13463-67-7 titanium dioxide
108-10-1 4-methylpentan-2-one
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
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Chemicals known to cause developmental toxicity:
64-17-5 ethanol
108-10-1 4-methylpentan-2-one
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
25013-15-4 Vinyl toluene A4
64-17-5 ethanol A3
NIOSH-Ca (National Institute for Occupational Safety and Health)
13463-67-7 titanium dioxide
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS08
Signal wordDanger
Hazard-determining components of labeling:
Phosphate Ester
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If experiencing respiratory symptoms: Call a poison center/doctor.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
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16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision01/09/2020 / 11
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flam. Liq. 3: Flammable liquids Category 3
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Resp. Sens. 1: Respiratory sensitisation Category 1
* Data compared to the previous version altered.
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49.1.7
1 Identification
Product identifier
Trade name: AL 2020 Resin
Article number:I026020
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
Phosphate Ester
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
[In case of inadequate ventilation] wear respiratory protection.
If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
1
0
Health = *2
Fire = 1
Reactivity = 0
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49.1.7
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 50-100%
Phosphate Ester 20-50%
CAS: 2425-79-8
EINECS: 219-371-7
1,4-bis(2,3-epoxypropoxy)butane 5-<10%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
1-5%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
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49.1.7
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 16 mg/m
PAC-2:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 170 mg/m
PAC-3:
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 220 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
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49.1.7
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
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49.1.7
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light amber
Odor: uncharacteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:266 C (510.8 F)
Flash point: 112 C (233.6 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.18 g/cm (9.85 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
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49.1.7
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin)
(Contd. on page 9)
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Transport hazard class(es)
DOT
Class not regulated
Label -
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: Epoxy
Resin
Marine pollutant: Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN), 9, III
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
Phosphate Ester
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
[In case of inadequate ventilation] wear respiratory protection.
If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/12/2019 / 2
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
(Contd. on page 12)
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49.1.7
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Resp. Sens. 1: Respiratory sensitisation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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1 Identification
Product identifier
Trade name: AL 2022 Hardener
Article number:I026018
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier's Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Tox. 3 H311 Toxic in contact with skin.
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
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GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
2,2'-dimethyl-4,4'methylenebis(cyclohexylamine)
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Trimethylolpropane poly(oxypropylene)triamine
Hazard statements
Harmful if swallowed.
Toxic in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment is urgent (see on this label).
Take off immediately all contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
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49.1.7
Classification system:
NFPA ratings (scale 0 - 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 2855-13-2
EINECS: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamine 25- 50%
CAS: 6864-37-5
EINECS: 229-962-1
2,2'-dimethyl-4,4'methylenebis(cyclohexylamine) 25- 50%
CAS: 39423-51-3 Trimethylolpropane poly(oxypropylene)triamine 20-<25%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
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After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
6864-37-5 2,2'-dimethyl-4,4'methylenebis(cyclohexylamine) 0.28 mg/m
39423-51-3 Trimethylolpropane poly(oxypropylene)triamine 30 mg/m
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PAC-2:
6864-37-5 2,2'-dimethyl-4,4'methylenebis(cyclohexylamine) 3.1 mg/m
39423-51-3 Trimethylolpropane poly(oxypropylene)triamine 330 mg/m
PAC-3:
6864-37-5 2,2'-dimethyl-4,4'methylenebis(cyclohexylamine) 19 mg/m
39423-51-3 Trimethylolpropane poly(oxypropylene)triamine 2,000 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
(Contd. on page 6)
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Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Colorless
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:1,013 C (1,855.4 F)
Flash point: 110 C (230 F)
Flammability (solid, gaseous):Not applicable.
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49.1.7
Ignition temperature: 275 C (527 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 0.5 Vol %
Upper: 2.8 Vol %
Vapor pressure at 20 C (68 F):6.8 hPa (5.1 mm Hg)
Density at 20 C (68 F): 0.93 g/cm (7.76 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Oral LD50 1,030 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rat)
6864-37-5 2,2'-dimethyl-4,4'methylenebis(cyclohexylamine)
Oral LD50 320-460 mg/kg (rat)
Dermal LD50 200-400 mg/kg (rabbit)
Inhalative LC50/4 h 0.42 mg/l (rat) (Test Guideline 402)
39423-51-3 Trimethylolpropane poly(oxypropylene)triamine
Oral LD50 <2,000 mg/kg (rat)
Dermal LD50 >1,000 mg/kg (rat)
Primary irritant effect:
on the skin:Strong caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Toxic
Harmful
Corrosive
Irritant
Very toxic
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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* 12 Ecological information
Toxicity
Aquatic toxicity:
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
96 hr LC50 110 mg/l (Fish)
NOEC 3 mg/l (daphnia)
6864-37-5 2,2′-dimethyl-4,4’methylenebis(cyclohexylamine)
48 hr EC50 15.2 mg/l (daphnia)
96 hr LC50 45 mg/l (Fish)
39423-51-3 Trimethylolpropane poly(oxypropylene)triamine
48 hr EC50 (static) 13 mg/l (daphnia)
72 or 96 hr ErC50 (static) 4.4 mg/l (Algea)
NOEC (static) 1 mg/l (Algea)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
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Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN2922
UN proper shipping name
DOT Corrosive liquids, toxic, n.o.s. (Cycloaliphatic Amine)
IMDG CORROSIVE LIQUID, TOXIC, N.O.S. (Cycloaliphatic Amine,
Propoxylated Triamine), MARINE POLLUTANT
IATA CORROSIVE LIQUID, TOXIC, N.O.S. (Cycloaliphatic Amine)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8, 6.1
IMDG
Class 8 Corrosive substances
Label 8/6.1
IATA
Class 8 Corrosive substances
Label 8 (6.1)
Packing group
DOT, IMDG, IATA II
Environmental hazards: Product contains environmentally hazardous substances:
Propoxylated Triamine
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Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 886
EMS Number: F-A,S-B
Stowage Category B
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 0.5 L
On cargo aircraft only: 2.5 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 0
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
UN “Model Regulation”: U N 2 9 2 2 C O R R O S I V E L I Q U I D , T O X I C , N . O . S .
(CYCLOALIPHATIC AMINE), 8 (6.1), II, ENVIRONMENTALLY
HAZARDOUS
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
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Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
2,2′-dimethyl-4,4’methylenebis(cyclohexylamine)
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Trimethylolpropane poly(oxypropylene)triamine
Hazard statements
Harmful if swallowed.
Toxic in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
(Contd. on page 13)
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Trade name: AL 2022 Hardener
(Contd. of page 12)
49.1.7
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment is urgent (see on this label).
Take off immediately all contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/08/2019 / 3
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Acute Tox. 3: Acute toxicity Category 3
Acute Tox. 2: Acute toxicity Category 2
Skin Corr. 1A: Skin corrosion/irritation Category 1A
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
Aquatic Acute 3: Hazardous to the aquatic environment – acute aquatic hazard Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment – long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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1 Identification
Product identifier
Trade name:TCC-6072 PART A ISO
Article number:I024707-2
Application of the substance / the mixturePolyurethane resin
Details of the supplier of the safety data sheetSikaAxson US – EHS Department
Manufacturer/Supplier:
Company Name: Axson Technologies US, Inc.-SikaAxson
Headquarters:
31200 Stephenson Hwy
Madison Heights, MI 48071
USA
Manufacturing Site:
1611 Hults Drive
Eaton Rapids, MI 48827
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Resp. Sens. 1H334May cause allergy or asthma symptoms or breathing difficulties if inhaled.
STOT RE 2H373May cause damage to organs through prolonged or repeated exposure.
GHS07
Acute Tox. 4H332Harmful if inhaled.
Skin Irrit. 2H315Causes skin irritation.
Eye Irrit. 2AH319Causes serious eye irritation.
Skin Sens. 1H317May cause an allergic skin reaction.
STOT SE 3H335May cause respiratory irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2)
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Hazard pictograms
GHS07
GHS08
Signal wordDanger
Hazard-determining components of labeling:
4,4′-methylenediphenyl diisocyanate
methylenediphenyl diisocyanate
Homopolymer of methylenediphenyl diisocyanate
Hazard statements
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
[In case of inadequate ventilation] wear respiratory protection.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
0
0
Health = 2
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
0
0
Health = *2
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 3)
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vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 101-68-8
EINECS: 202-966-0
4,4′-methylenediphenyl diisocyanate 20-50%
CAS: 26447-40-5
EINECS: 247-714-0
methylenediphenyl diisocyanate 5-<10%
CAS: 25686-28-6Homopolymer of methylenediphenyl diisocyanate 0.1-<1%
4 First-aid measures
Description of first aid measures
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
Nitrogen oxides (NOx)
Hydrogen cyanide (HCN)
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
(Contd. on page 4)
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Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
101-68-84,4'-methylenediphenyl diisocyanate 0.45 mg/m
26447-40-5methylenediphenyl diisocyanate 29 mg/m
78-83-1butanol 150 ppm
98-88-4benzoyl chloride 0.3 ppm
98-82-8cumene 50 ppm
1330-20-7xylene 130 ppm
100-41-4ethylbenzene 33 ppm
PAC-2:
101-68-84,4'-methylenediphenyl diisocyanate 5 mg/m
26447-40-5methylenediphenyl diisocyanate 40 mg/m
78-83-1butanol 1,300 ppm
98-88-4benzoyl chloride 5 ppm
98-82-8cumene 300 ppm
1330-20-7xylene 920* ppm
100-41-4ethylbenzene 1100* ppm
PAC-3:
101-68-84,4'-methylenediphenyl diisocyanate 55 mg/m
26447-40-5methylenediphenyl diisocyanate 240 mg/m
78-83-1butanol 8000* ppm
98-88-4benzoyl chloride 20 ppm
98-82-8cumene 730 ppm
1330-20-7xylene 2500* ppm
100-41-4ethylbenzene 1800* ppm
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7 Handling and storage
Handling:
Precautions for safe handlingEnsure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
101-68-84,4'-methylenediphenyl diisocyanate
PELCeiling limit value: 0.2 mg/m , 0.02 ppm
RELLong-term value: 0.05 mg/m , 0.005 ppm
Ceiling limit value: 0.2* mg/m , 0.02* ppm
*10-min
TLVLong-term value: 0.051 mg/m , 0.005 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
(Contd. on page 6)
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Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Amber colored
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 208 C (406.4 F)
Flash point: Not applicable.
Flammability (solid, gaseous): Not applicable.
Ignition temperature: 520 C (968 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 0.4 Vol %
Upper: 0.0 Vol %
Vapor pressure at 20 C (68 F): 0.1 hPa (0.1 mm Hg)
Density at 20 C (68 F): 1.17 g/cm (9.76 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
(Contd. on page 7)
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Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.4 %
VOC content: 0.40 %
4.7 g/l / 0.04 lb/gl
Solids content: 27.1 %
Other information No further relevant information available.
10Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactions
Violent reactions with -NHx, -OH and -SH- groups.
In the presence of water or humidity gas (CO2) is porduced and/or uncontrolled polymerization, possibly leading
to internal pressure rises and consequent risk of container breach.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:
?
Nitrogen oxides
Carbon monoxide and carbon dioxide
(possible HCN)
11Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
101-68-84,4'-methylenediphenyl diisocyanate
Oral LD502,200 mg/kg (mouse)
DermalLD50>9,400 mg/kg (rabbit)
InhalativeLC50/4 h2 mg/l (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
(Contd. on page 8)
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Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
101-68-84,4′-methylenediphenyl diisocyanate 3
98-88-4benzoyl chloride 2A
98-82-8cumene 2B
1330-20-7xylene 3
100-41-4ethylbenzene 2B
NTP (National Toxicology Program)
98-82-8cumene R
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
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14Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
15Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
101-68-84,4′-methylenediphenyl diisocyanate
TSCA (Toxic Substances Control Act) (Substances not listed):
All ingredients are listed.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
98-82-8cumene
100-41-4ethylbenzene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
(Contd. on page 10)
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Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
101-68-84,4′-methylenediphenyl diisocyanate D, CBD
98-82-8cumene D, CBD
1330-20-7xylene I
100-41-4ethylbenzene D
TLV (Threshold Limit Value established by ACGIH)
98-88-4benzoyl chloride A4
1330-20-7xylene A4
100-41-4ethylbenzene A3
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07
GHS08
Signal wordDanger
Hazard-determining components of labeling:
4,4′-methylenediphenyl diisocyanate
methylenediphenyl diisocyanate
Homopolymer of methylenediphenyl diisocyanate
Hazard statements
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
[In case of inadequate ventilation] wear respiratory protection.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
(Contd. on page 11)
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Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision05/23/2018 / 6
Abbreviations and acronyms:
ADR: Accord europ en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Resp. Sens. 1: Respiratory sensitisation Category 1
Skin Sens. 1: Skin sensitisation Category 1
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
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1 Identification
Product identifier
Trade name:TCC-6072 PART B POLYOL
Article number:I025826-1
Application of the substance / the mixturePolyurethane resin
Details of the supplier of the safety data sheetSikaAxson US – EHS Department
Manufacturer/Supplier:
Company Name: Axson Technologies US, Inc.-SikaAxson
Headquarters:
31200 Stephenson Hwy
Madison Heights, MI 48071
USA
Manufacturing Site:
1611 Hults Drive
Eaton Rapids, MI 48827
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
The product is not classified, according to the Globally Harmonized System (GHS).
Label elements
GHS label elementsVoid
Hazard pictogramsVoid
Signal wordVoid
Hazard statementsVoid
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
In case of inadequate ventilation wear respiratory protection.
Classification system:
NFPA ratings (scale 0 – 4)
0
1
0
Health = 0
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
1
1
0
Health = 1
Fire = 1
Reactivity = 0
(Contd. on page 2)
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25791-96-2
NLP: 500-044-5
Poly[oxy(methyl-1,2-ethanediyl)],.alpha.,.alpha.’,.alpha’-1,2,3-
propanetriyltris[.omega.-hydroxy-
20-50%
CAS: 110-63-4
EINECS: 203-786-5
butane-1,4-diol 5-<10%
4 First-aid measures
Description of first aid measures
General information:No special measures required.
After inhalation:Supply fresh air; consult doctor in case of complaints.
After skin contact:Generally the product does not irritate the skin.
After eye contact:Rinse opened eye for several minutes under running water.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:No special measures required.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Reference to other sections
See Section 7 for information on safe handling.
(Contd. on page 3)
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See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
9082-00-2Glycerol, propylene oxide, ethylene oxide polymer 30 mg/m
102-60-31,1',1'',1'''-ethylenedinitrilotetrapropan-2-ol 34 mg/m
110-63-4butane-1,4-diol 4.7 mg/m
78-83-1butanol 150 ppm
280-57-9triethylenediamine 5.1 mg/m
98-82-8cumene 50 ppm
100-41-4ethylbenzene 33 ppm
1330-20-7xylene 130 ppm
PAC-2:
9082-00-2Glycerol, propylene oxide, ethylene oxide polymer 330 mg/m
102-60-31,1',1'',1'''-ethylenedinitrilotetrapropan-2-ol 370 mg/m
110-63-4butane-1,4-diol 52 mg/m
78-83-1butanol 1,300 ppm
280-57-9triethylenediamine 56 mg/m
98-82-8cumene 300 ppm
100-41-4ethylbenzene 1100* ppm
1330-20-7xylene 920* ppm
PAC-3:
9082-00-2Glycerol, propylene oxide, ethylene oxide polymer 2,000 mg/m
102-60-31,1',1'',1'''-ethylenedinitrilotetrapropan-2-ol 2,200 mg/m
110-63-4butane-1,4-diol 640 mg/m
78-83-1butanol 8000* ppm
280-57-9triethylenediamine 340 mg/m
98-82-8cumene 730 ppm
100-41-4ethylbenzene 1800* ppm
1330-20-7xylene 2500* ppm
7 Handling and storage
Handling:
Precautions for safe handlingNo special measures required.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:None.
(Contd. on page 4)
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Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Breathing equipment:Not required.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:Goggles recommended during refilling.
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Off-white
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 101 C (213.8 F)
Flash point: >94 C (>201.2 F)
Flammability (solid, gaseous): Not applicable.
(Contd. on page 5)
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Ignition temperature: 290 C (554 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.06 g/cm (8.85 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 9.7 %
VOC content: 9.69 %
103.0 g/l / 0.86 lb/gl
Solids content: 3.7 %
Other information No further relevant information available.
10Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:
?
Carbon monoxide and carbon dioxide
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11Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
25791-96-2Poly[oxy(methyl-1,2-ethanediyl)],.alpha.,.alpha.’,.alpha’-1,2,3-propanetriyltris[.omega.-hydroxy-
OralLD501,002.5 mg/kg (rat)
DermalLD50>2,000 mg/kg (rat)
Primary irritant effect:
on the skin:No irritant effect.
on the eye:No irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product is not subject to classification according to internally approved calculation methods for
preparations:
When used and handled according to specifications, the product does not have any harmful effects according to
our experience and the information provided to us.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1318-02-1zeolites 3
98-82-8cumene 2B
100-41-4ethylbenzene 2B
1330-20-7xylene 3
NTP (National Toxicology Program)
98-82-8cumene R
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:Not known to be hazardous to water.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
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13Disposal considerations
Waste treatment methods
Recommendation:Smaller quantities can be disposed of with household waste.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14Transport information
UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
15Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act) (Substances not listed):
All ingredients are listed.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
(Contd. on page 8)
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Proposition 65
Chemicals known to cause cancer:
98-82-8cumene
100-41-4ethylbenzene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
98-82-8cumene D, CBD
100-41-4ethylbenzene D
1330-20-7xylene I
TLV (Threshold Limit Value established by ACGIH)
100-41-4ethylbenzene A3
1330-20-7xylene A4
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsVoid
Hazard pictogramsVoid
Signal wordVoid
Hazard statementsVoid
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision05/23/2018 / 2
Abbreviations and acronyms:
ADR: Accord europ en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
(Contd. on page 9)
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LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
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1 Identification
Product identifier
Trade name: ProInfusion Resin
Article number:I025953
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS09
(Contd. on page 2)
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Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
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3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 1675-54-3
EINECS: 216-823-5
bis[4-(2,3-epoxypropoxy)phenyl]propane 25- 50%
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 25- 50%
CAS: 2425-79-8
EINECS: 219-371-7
1,4-bis(2,3-epoxypropoxy)butane 5-<10%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether 5-<10%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
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* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 39 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 16 mg/m
PAC-2:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 430 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 170 mg/m
PAC-3:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 2,600 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 220 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
(Contd. on page 5)
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Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 6)
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Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Translucent
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:266 C (510.8 F)
Flash point: 112 C (233.6 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.15 g/cm (9.6 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
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Kinematic: Not determined.
Solvent content:
Organic solvents: 0.1 %
VOC content: 0.08 %
0.9 g/l / 0.01 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin)
(Contd. on page 9)
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Transport hazard class(es)
DOT
Class not regulated
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: Epoxy
Resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN), 9, III
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 11)
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Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision01/09/2020 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
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NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
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1 Identification
Product identifier
Trade name: ProInfusion Slow Hardener
Article number:I025959
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier's Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
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Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
4-tert-butylphenol
Polyoxypropylenediamine
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
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HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 9046-10-0 Polyoxypropylenediamine 25- 50%
CAS: 2855-13-2
EINECS: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamine 25- 50%
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 3-<5%
CAS: 98-54-4
EINECS: 202-679-0
4-tert-butylphenol 1-<3%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 1-<2.5%
CAS: 2579-20-6
EINECS: 219-941-5
1,3-Cyclohexanedimethanamine 1-5%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
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Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
9046-10-0 Polyoxypropylenediamine 4.8 mg/m
98-54-4 4-tert-butylphenol 1.5 mg/m
PAC-2:
9046-10-0 Polyoxypropylenediamine 53 mg/m
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98-54-4 4-tert-butylphenol 40 mg/m
PAC-3:
9046-10-0 Polyoxypropylenediamine 320 mg/m
98-54-4 4-tert-butylphenol 240 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
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Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light amber
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:232 C (449.6 F)
Flash point: 110 C (230 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 510 C (950 F)
Decomposition temperature: Not determined.
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Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 0.7 Vol %
Upper: 5 Vol %
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.92 g/cm (7.68 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 3.5 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
9046-10-0 Polyoxypropylenediamine
Oral LD50 2,855 mg/kg (rabbit)
Dermal LD50 2,980 mg/kg (rabbit)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Oral LD50 1,030 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rat)
Primary irritant effect:
on the skin:Strong caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
9046-10-0 Polyoxypropylenediamine
48 hr EC50 80 mg/l (daphnia)
96 hr LC50 772 mg/l (Fish)
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72 or 96 hr ErC50 15 mg/l (Algea)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
96 hr LC50 110 mg/l (Fish)
NOEC 3 mg/l (daphnia)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1760
UN proper shipping name
DOT Co rr o sive liq u id s, n .o .s . (P o lyo xyp ro p yle n ed ia m in e,
Isophoronediamine)
IMDG CORROSIVE LIQUID, N.O.S. (Polyoxypropylenediamine,
ISOPHORONEDIAMINE), MARINE POLLUTANT
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IATA CORROSIVE LIQUID, N.O.S. (Polyoxypropylenediamine,
ISOPHORONEDIAMINE)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG
Class 8 Corrosive substances
Label 8
IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances:
Polyoxypropylenediamine
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
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Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": U N 1 7 6 0 C O R R O S I V E L I Q U I D , N . O . S .
(POLYOXYPROPYLENEDIAMINE, ISOPHORONEDIAMINE), 8,
III, ENVIRONMENTALLY HAZARDOUS
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
75-56-9 propylene oxide
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
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Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
4-tert-butylphenol
Polyoxypropylenediamine
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
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Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision01/22/2020 / 8
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Corr. 1A: Skin corrosion/irritation Category 1A
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Repr. 2: Reproductive toxicity Category 2
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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1 Identification
Product identifier
Trade name: ProInfusion Resin
Article number:I025953
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS09
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Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
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3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 1675-54-3
EINECS: 216-823-5
bis[4-(2,3-epoxypropoxy)phenyl]propane 25- 50%
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 25- 50%
CAS: 2425-79-8
EINECS: 219-371-7
1,4-bis(2,3-epoxypropoxy)butane 5-<10%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether 5-<10%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
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* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 39 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 16 mg/m
PAC-2:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 430 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 170 mg/m
PAC-3:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 2,600 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 220 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
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Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
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Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Translucent
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:266 C (510.8 F)
Flash point: 112 C (233.6 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.15 g/cm (9.6 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
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Kinematic: Not determined.
Solvent content:
Organic solvents: 0.1 %
VOC content: 0.08 %
0.9 g/l / 0.01 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin)
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Transport hazard class(es)
DOT
Class not regulated
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: Epoxy
Resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN), 9, III
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision01/09/2020 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
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NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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1 Identification
Product identifier
Trade name: ProInfusion Fast Hardener
Article number:I025956
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier's Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
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Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
m-phenylenebis(methylamine)
4-tert-butylphenol
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Hazard statements
Harmful if swallowed or if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 25- 50%
CAS: 98-54-4
EINECS: 202-679-0
4-tert-butylphenol 10-20%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 10-20%
CAS: 2579-20-6
EINECS: 219-941-5
1,3-Cyclohexanedimethanamine 10-20%
CAS: 2855-13-2
EINECS: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamine 10-20%
CAS: 90-72-2
EINECS: 202-013-9
2,4,6-tris(dimethylaminomethyl)phenol 1-5%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
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Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
98-54-4 4-tert-butylphenol 1.5 mg/m
90-72-2 2,4,6-tris(dimethylaminomethyl)phenol 6.5 mg/m
PAC-2:
98-54-4 4-tert-butylphenol 40 mg/m
90-72-2 2,4,6-tris(dimethylaminomethyl)phenol 72 mg/m
(Contd. on page 5)
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PAC-3:
98-54-4 4-tert-butylphenol 240 mg/m
90-72-2 2,4,6-tris(dimethylaminomethyl)phenol 430 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 6)
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Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light amber
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:>200 C (>392 F)
Flash point: 110 C (230 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 510 C (950 F)
Decomposition temperature: Not determined.
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Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.92 g/cm (7.68 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 35.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
25513-64-8 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
Oral LD50 900 mg/kg (rat)
98-54-4 4-tert-butylphenol
Oral LD50 2,951 mg/kg (rat)
Dermal LD50 2,288 mg/kg (rabbit)
1477-55-0 m-phenylenebis(methylamine)
Oral LD50 1,040 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Inhalative LC50/4 h 2.4 mg/l (rat)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Oral LD50 1,030 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rat)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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12 Ecological information
Toxicity
Aquatic toxicity:
25513-64-8 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
72 or 96 hr ErC50 43.5 mg/l (Algea)
NOEC 16 mg/l (Algea)
98-54-4 4-tert-butylphenol
48 hr EC50 3.4 mg/l (daphnia)
96 hr LC50 4.71 mg/l (Fathead minnow)
1477-55-0 m-phenylenebis(methylamine)
72 or 96 hr ErC50 12 mg/l (Chaetogammarus marinus)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
96 hr LC50 110 mg/l (Fish)
NOEC 3 mg/l (daphnia)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
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* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1760
UN proper shipping name
DOT Corrosive liquids, n.o.s. (m-phenylenebis(methylamine),
Trimethylhexamethylenediamines)
IMDG, IATA CORROSIVE LIQUID, N.O.S. (m-phenylenebis(methylamine),
TRIMETHYLHEXAMETHYLENEDIAMINES)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA III
Environmental hazards: Not applicable.
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
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IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: U N 1 7 6 0 C O R R O S I V E L I Q U I D , N . O . S . ( M –
P H E N Y L E N E B I S ( M E T H Y L A M I N E ) ,
TRIMETHYLHEXAMETHYLENEDIAMINES), 8, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
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Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
m-phenylenebis(methylamine)
4-tert-butylphenol
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Hazard statements
Harmful if swallowed or if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
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Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision01/22/2020 / 4
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Repr. 2: Reproductive toxicity Category 2
Aquatic Acute 3: Hazardous to the aquatic environment – acute aquatic hazard Category 3
* Data compared to the previous version altered.
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1 Identification
Product identifier
Trade name: ProInfusion Resin
Article number:I025953
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS09
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Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
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3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 1675-54-3
EINECS: 216-823-5
bis[4-(2,3-epoxypropoxy)phenyl]propane 25- 50%
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 25- 50%
CAS: 2425-79-8
EINECS: 219-371-7
1,4-bis(2,3-epoxypropoxy)butane 5-<10%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether 5-<10%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
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* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 39 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 16 mg/m
PAC-2:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 430 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 170 mg/m
PAC-3:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 2,600 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 220 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
(Contd. on page 5)
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Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 6)
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Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Translucent
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:266 C (510.8 F)
Flash point: 112 C (233.6 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.15 g/cm (9.6 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
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Kinematic: Not determined.
Solvent content:
Organic solvents: 0.1 %
VOC content: 0.08 %
0.9 g/l / 0.01 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin)
(Contd. on page 9)
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Transport hazard class(es)
DOT
Class not regulated
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: Epoxy
Resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN), 9, III
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 11)
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Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision01/09/2020 / 6
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
(Contd. on page 12)
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NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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1 Identification
Product identifier
Trade name: ProInfusion Med Hardener
Article number:I025962
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier's Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
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Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
4-tert-butylphenol
Polyoxypropylenediamine
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
(Contd. on page 3)
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HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 9046-10-0 Polyoxypropylenediamine 25- 50%
CAS: 2855-13-2
EINECS: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamine 25- 50%
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 10-20 %
CAS: 98-54-4
EINECS: 202-679-0
4-tert-butylphenol 5-<10%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 5-10%
CAS: 2579-20-6
EINECS: 219-941-5
1,3-Cyclohexanedimethanamine 5-10%
CAS: 90-72-2
EINECS: 202-013-9
2,4,6-tris(dimethylaminomethyl)phenol 1-5%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
(Contd. on page 4)
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After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
9046-10-0 Polyoxypropylenediamine 4.8 mg/m
98-54-4 4-tert-butylphenol 1.5 mg/m
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90-72-2 2,4,6-tris(dimethylaminomethyl)phenol 6.5 mg/m
PAC-2:
9046-10-0 Polyoxypropylenediamine 53 mg/m
98-54-4 4-tert-butylphenol 40 mg/m
90-72-2 2,4,6-tris(dimethylaminomethyl)phenol 72 mg/m
PAC-3:
9046-10-0 Polyoxypropylenediamine 320 mg/m
98-54-4 4-tert-butylphenol 240 mg/m
90-72-2 2,4,6-tris(dimethylaminomethyl)phenol 430 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
(Contd. on page 6)
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Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light amber
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:>200 C (>392 F)
Flash point: 110 C (230 F)
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Flammability (solid, gaseous):Not applicable.
Ignition temperature: 510 C (950 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 0.7 Vol %
Upper: 5 Vol %
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.92 g/cm (7.68 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 12.8 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
9046-10-0 Polyoxypropylenediamine
Oral LD50 2,855 mg/kg (rabbit)
Dermal LD50 2,980 mg/kg (rabbit)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Oral LD50 1,030 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rat)
25513-64-8 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
Oral LD50 900 mg/kg (rat)
98-54-4 4-tert-butylphenol
Oral LD50 2,951 mg/kg (rat)
Dermal LD50 2,288 mg/kg (rabbit)
1477-55-0 m-phenylenebis(methylamine)
Oral LD50 1,040 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
Inhalative LC50/4 h 2.4 mg/l (rat)
Primary irritant effect:
on the skin:Strong caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
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OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:
9046-10-0 Polyoxypropylenediamine
48 hr EC50 80 mg/l (daphnia)
96 hr LC50 772 mg/l (Fish)
72 or 96 hr ErC50 15 mg/l (Algea)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
96 hr LC50 110 mg/l (Fish)
NOEC 3 mg/l (daphnia)
25513-64-8 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
72 or 96 hr ErC50 43.5 mg/l (Algea)
NOEC 16 mg/l (Algea)
98-54-4 4-tert-butylphenol
48 hr EC50 3.4 mg/l (daphnia)
96 hr LC50 4.71 mg/l (Fathead minnow)
1477-55-0 m-phenylenebis(methylamine)
72 or 96 hr ErC50 12 mg/l (Chaetogammarus marinus)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
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Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1760
UN proper shipping name
DOT Corrosive liquids, n.o.s. (Polyoxypropylenediamine, m-
phenylenebis(methylamine))
IMDG CORROSIVE LIQUID, N.O.S. (Polyoxypropylenediamine, m-
phenylenebis(methylamine)), MARINE POLLUTANT
IATA CORROSIVE LIQUID, N.O.S. (Polyoxypropylenediamine, m-
phenylenebis(methylamine))
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG
Class 8 Corrosive substances
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Label 8
IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances:
Polyoxypropylenediamine
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: U N 1 7 6 0 C O R R O S I V E L I Q U I D , N . O . S .
( P O L Y O X Y P R O P Y L E N E D I A M I N E , M –
PHENYLENEBIS(METHYLAMINE)), 8, III, ENVIRONMENTALLY
HAZARDOUS
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
75-56-9 propylene oxide
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS05GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
4-tert-butylphenol
Polyoxypropylenediamine
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision01/22/2020 / 7
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
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ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Corr. 1A: Skin corrosion/irritation Category 1A
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Repr. 2: Reproductive toxicity Category 2
Aquatic Acute 3: Hazardous to the aquatic environment – acute aquatic hazard Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment – long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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1 Identification
Product identifier
Trade name: CP 15 Black – Paste
Article number:F025796
Application of the substance / the mixturePigment
Details of the supplier of the safety data sheetSikaAxson US – EHS Department
Manufacturer/Supplier:
Company Name: Axson Technologies US, Inc.-SikaAxson
Headquarters:
31200 Stephenson Hwy
Madison Heights, MI 48071
USA
Manufacturing Site:
1611 Hults Drive
Eaton Rapids, MI 48827
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
d~
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
d~
GHS07
Signal wordWarning
Hazard-determining components of labeling:
Polypropylene glycol
Hazard statements
Harmful if swallowed.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
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If swallowed: Call a poison center/doctor if you feel unwell.
Rinse mouth.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
1
1
0
Health = 1
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
1
1
0
Health = 1
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
25322-69-4 Polypropylene glycol 50-100%
4 First-aid measures
Description of first aid measures
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:Supply fresh air; consult doctor in case of complaints.
After skin contact:Generally the product does not irritate the skin.
After eye contact:Rinse opened eye for several minutes under running water.
After swallowing:Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
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Carbon monoxide (CO)
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional informationCollect contaminated fire fighting water separately. It must not enter the sewage system.
6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
25322-69-4 Polypropylene glycol 30 mg/m
1333-86-4 Carbon black 9 mg/m
PAC-2:
25322-69-4 Polypropylene glycol 330 mg/m
1333-86-4 Carbon black 99 mg/m
PAC-3:
25322-69-4 Polypropylene glycol 2,000 mg/m
1333-86-4 Carbon black 590 mg/m
7 Handling and storage
Handling:
Precautions for safe handlingNo special precautions are necessary if used correctly.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:None.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
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Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:Wash hands before breaks and at the end of work.
Breathing equipment:Not required.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:Goggles recommended during refilling.
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Viscous
Color: Black
Odor: Ether-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:Undetermined.
Flash point: 186 C (366.8 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature:
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.2 g/cm (10.01 lbs/gal)
(Contd. on page 5)
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Trade name: CP 15 Black – Paste
(Contd. of page 4)
46. 0
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gl
Solids content: 27.0 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:
Possible in traces.
Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
25322-69-4 Polypropylene glycol
Oral LD50 541 mg/kg (rat)
Dermal LD50 >10,000 mg/kg (rabbit)
Primary irritant effect:
on the skin:No irritant effect.
on the eye:No irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:Harmful
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1333-86-4 Carbon black 2B
(Contd. on page 6)
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(Contd. of page 5)
46. 0
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, IMDG, IATA not regulated
UN proper shipping name
DOT, IMDG, IATA not regulated
Transport hazard class(es)
DOT, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards: Not applicable.
(Contd. on page 7)
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(Contd. of page 6)
46. 0
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: not regulated
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act) (Substances not listed):
All ingredients are listed.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
1333-86-4 Carbon black
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
1333-86-4 Carbon black A4
NIOSH-Ca (National Institute for Occupational Safety and Health)
1333-86-4 Carbon black
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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(Contd. of page 7)
46. 0
Hazard pictograms
d~
GHS07
Signal wordWarning
Hazard-determining components of labeling:
Polypropylene glycol
Hazard statements
Harmful if swallowed.
Precautionary statements
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
If swallowed: Call a poison center/doctor if you feel unwell.
Rinse mouth.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision11/16/2017 / –
Abbreviations and acronyms:
ADR: Accord europ en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
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49.1.7
1 Identification
Product identifier
Trade name: APG 1750 S Orange Resin
Article number:I025505
Application of the substance / the mixtureSprayable polyester gel coat
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
(Contd. on page 2)
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49.1.7
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08GHS09
Signal wordWarning
Hazard-determining components of labeling:
methyl methacrylate
cobalt(II) 2-ethylhexanoate
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
2
0
Health = 2
Fire = 2
Reactivity = 0
(Contd. on page 3)
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49.1.7
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
2
0
Health = 2
Fire = 2
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25013-15-4
EINECS: 246-562-2
Vinyl toluene 25- 50%
CAS: 80-62-6
EINECS: 201-297-1
methyl methacrylate 1-5%
CAS: 136-52-7
EINECS: 205-250-6
cobalt(II) 2-ethylhexanoate 0.25-<1%
CAS: 91-99-6 N,N-Bishydroxyethyl-m-toluidine 0.1-1%
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
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(Contd. of page 3)
49.1.7
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
80-62-6 methyl methacrylate 17 ppm
PAC-2:
80-62-6 methyl methacrylate 120 ppm
PAC-3:
80-62-6 methyl methacrylate 570 ppm
7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
(Contd. on page 5)
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49.1.7
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
25013-15-4 Vinyl toluene
PEL Long-term value: 480 mg/m , 100 ppm
REL Long-term value: 480 mg/m , 100 ppm
TLV Short-term value: 483 mg/m , 100 ppm
Long-term value: 242 mg/m , 50 ppm
80-62-6 methyl methacrylate
PEL Long-term value: 410 mg/m , 100 ppm
REL Long-term value: 410 mg/m , 100 ppm
TLV Short-term value: 410 mg/m , 100 ppm
Long-term value: 205 mg/m , 50 ppm
DSEN
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 6)
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49.1.7
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Pasty
Color: Orange
Odor: Aromatic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:170 C (338 F)
Flash point: 50 C (122 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 494 C (921.2 F)
Decomposition temperature: Not determined.
(Contd. on page 7)
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49.1.7
Auto igniting: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Explosion limits:
Lower: 1.1 Vol %
Upper: 5.2 Vol %
Vapor pressure at 20 C (68 F):1 hPa (0.8 mm Hg)
Density at 20 C (68 F): 1.29 g/cm (10.77 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 28.4 %
VOC content: 32.58 %
420.3 g/l / 3.51 lb/gal
Solids content: 30.8 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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49.1.7
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
25013-15-4 Vinyl toluene 3
80-62-6 methyl methacrylate 3
64-17-5 ethanol 1
136-52-7 cobalt(II) 2-ethylhexanoate 2B
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
(Contd. on page 9)
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49.1.7
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1866
UN proper shipping name
DOT Resin solution
IMDG RESIN SOLUTION, MARINE POLLUTANT
IATA RESIN SOLUTION
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG
Class 3 Flammable liquids
Label 3
IATA
Class 3 Flammable liquids
(Contd. on page 10)
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49.1.7
Label 3
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Marine pollutant: Yes
Yes
Symbol (fish and tree)
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): III
EMS Number: F-E,S-E
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 1866 RESIN SOLUTION, 3, III, ENVIRONMENTALLY
HAZARDOUS
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
80-62-6 methyl methacrylate
136-52-7 cobalt(II) 2-ethylhexanoate
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
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49.1.7
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
80-62-6 methyl methacrylate
136-52-7 cobalt(II) 2-ethylhexanoate
108-10-1 4-methylpentan-2-one
Proposition 65
Chemicals known to cause cancer:
1317-65-3 Calcium Carbonate
14808-60-7 Quartz (SiO2)
108-10-1 4-methylpentan-2-one
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
64-17-5 ethanol
108-10-1 4-methylpentan-2-one
Carcinogenic categories
EPA (Environmental Protection Agency)
80-62-6 methyl methacrylate E, NL
TLV (Threshold Limit Value established by ACGIH)
25013-15-4 Vinyl toluene A4
80-62-6 methyl methacrylate A4
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08GHS09
Signal wordWarning
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49.1.7
Hazard-determining components of labeling:
methyl methacrylate
cobalt(II) 2-ethylhexanoate
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/24/2019 / 13
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
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49.1.7
Flam. Liq. 3: Flammable liquids Category 3
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
* Data compared to the previous version altered.
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49.1.7
1 Identification
Product identifier
Trade name: P17 SMCR Black
Article number:I017688
Application of the substance / the mixture
Polyester resin
Polyester filler
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS02GHS07
Signal wordWarning
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
2
0
Health = 2
Fire = 2
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
2
0
Health = 2
Fire = 2
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
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* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25013-15-4
EINECS: 246-562-2
Vinyl toluene 10-20%
CAS: 3077-12-1
EINECS: 221-359-1
2,2′-[(4-methylphenyl)imino]bisethanol 0.1-1%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
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Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
Handling:
Precautions for safe handlingNo special precautions are necessary if used correctly.
Information about protection against explosions and fires:
Keep ignition sources away – Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the remaining constituent has no known exposure limits.
25013-15-4 Vinyl toluene
PEL Long-term value: 480 mg/m , 100 ppm
REL Long-term value: 480 mg/m , 100 ppm
TLV Short-term value: 483 mg/m , 100 ppm
Long-term value: 242 mg/m , 50 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
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Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:Not required.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Fluid
Color: Black
Odor: Pungent
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:170 C (338 F)
Flash point: >55 C (>131 F)
Flammability (solid, gaseous):Not applicable.
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Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.58 g/cm (13.19 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 18.3 %
VOC content: 17.41 %
275.1 g/l / 2.30 lb/gal
Solids content: 49.4 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
14807-96-6 Talc (Mg3H2(SiO3)4) 3
25013-15-4 Vinyl toluene 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Harmful to fish
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
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13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, IMDG, IATA UN1866
UN proper shipping name
DOT Resin solution
IMDG, IATA RESIN SOLUTION
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Flammable liquids
EMS Number: F-E,S-E
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
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Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: UN 1866 RESIN SOLUTION, 3, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
108-10-1 4-methylpentan-2-one
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
64-17-5 ethanol
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108-10-1 4-methylpentan-2-one
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
25013-15-4 Vinyl toluene A4
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07
Signal wordWarning
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/12/2019 / 7
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
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DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flam. Liq. 3: Flammable liquids Category 3
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Aquatic Chronic 3: Hazardous to the aquatic environment – long-term aquatic hazard Category 3
* Data compared to the previous version altered.
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by | Sep 27, 2025
