80ESG215Q_SDS.pdf

by | Sep 27, 2025

Page 1/11
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/26/2019 Reviewed on 10/26/2019
49.1.7
1 Identification
Product identifier
Trade name: ESG 215 Resin
Article number:I215188
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Eye Irrit. 2B H320 Causes eye irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) US

Page 2/11
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/26/2019 Reviewed on 10/26/2019
Trade name: ESG 215 Resin
(Contd. of page 1)
49.1.7
Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
Hydroxyphenylethane Triglycidyl Ether
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane
Hazard statements
Harmful if swallowed or in contact with skin.
Causes skin and eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / protective clothing.
If swallowed: Call a poison center/doctor if you feel unwell.
Rinse mouth.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
1
1
0
Health = 1
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
1
1
0
Health = 1
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 3)
US

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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/26/2019 Reviewed on 10/26/2019
Trade name: ESG 215 Resin
(Contd. of page 2)
49.1.7
vPvB:Not applicable.
* 3 Composition/information on ingredients
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 25- 50%
CAS: 87093-13-8 Hydroxyphenylethane Triglycidyl Ether 20-<25% CAS: 17557-23-2 EINECS: 241-536-7 1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane 5-<10% * 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixtureNo further relevant information available. Advice for firefighters Protective equipment:Wear self-contained respiratory protective device. (Contd. on page 4) US Page 4/11 Safety Data Sheet acc. to OSHA HCS Printing date 10/26/2019 Reviewed on 10/26/2019 Trade name: ESG 215 Resin (Contd. of page 3) 49.1.7 Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency proceduresNot required. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m PAC-2: 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m PAC-3: 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m * 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires:No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. US (Contd. on page 5) Page 5/11 Safety Data Sheet acc. to OSHA HCS Printing date 10/26/2019 Reviewed on 10/26/2019 Trade name: ESG 215 Resin (Contd. of page 4) 49.1.7 * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles US (Contd. on page 6) Page 6/11 Safety Data Sheet acc. to OSHA HCS Printing date 10/26/2019 Reviewed on 10/26/2019 Trade name: ESG 215 Resin (Contd. of page 5) 49.1.7 * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Pasty Color: Black Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:Undetermined. Flash point: 94 C (201.2 F) Flammability (solid, gaseous):Not applicable. Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure: Not determined. Density at 20 C (68 F): 1.46 g/cm (12.18 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 0.3 % VOC content: 0.00 % 0.0 g/l / 0.00 lb/gal Solids content: 33.2 % (Contd. on page 7) US Page 7/11 Safety Data Sheet acc. to OSHA HCS Printing date 10/26/2019 Reviewed on 10/26/2019 Trade name: ESG 215 Resin (Contd. of page 6) 49.1.7 Other information No further relevant information available. * 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin:Irritant to skin and mucous membranes. on the eye:Irritating effect. Sensitization:Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) None of the ingredients is listed. NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. (Contd. on page 8) US Page 8/11 Safety Data Sheet acc. to OSHA HCS Printing date 10/26/2019 Reviewed on 10/26/2019 Trade name: ESG 215 Resin (Contd. of page 7) 49.1.7 Ecotoxical effects: Remark:Toxic for fish Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT not regulated IMDG, IATA UN3082 UN proper shipping name DOT not regulated IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin), MARINE POLLUTANT IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin) Transport hazard class(es) DOT Class not regulated (Contd. on page 9) US Page 9/11 Safety Data Sheet acc. to OSHA HCS Printing date 10/26/2019 Reviewed on 10/26/2019 Trade name: ESG 215 Resin (Contd. of page 8) 49.1.7 IMDG, IATA Class 9 Miscellaneous dangerous substances and articles Label 9 Packing group DOT not regulated IMDG, IATA III Environmental hazards: Product contains environmentally hazardous substances: Epoxy Resin Marine pollutant: Yes Symbol (fish and tree) Special marking (IATA): Symbol (fish and tree) Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 90 EMS Number: F-A,S-F Stowage Category A Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN), 9, III * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): None of the ingredients is listed. (Contd. on page 10) US Page 10/11 Safety Data Sheet acc. to OSHA HCS Printing date 10/26/2019 Reviewed on 10/26/2019 Trade name: ESG 215 Resin (Contd. of page 9) 49.1.7 TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) 87093-13-8 Hydroxyphenylethane Triglycidyl Ether Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants None of the ingredients is listed. Proposition 65 Chemicals known to cause cancer: 1317-65-3 Calcium Carbonate 14808-60-7 Quartz (SiO2) Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS07GHS09 Signal wordWarning Hazard-determining components of labeling: Reaction Product of Bisphenol A and Epichlorohydrin Hydroxyphenylethane Triglycidyl Ether 1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane (Contd. on page 11) US Page 11/11 Safety Data Sheet acc. to OSHA HCS Printing date 10/26/2019 Reviewed on 10/26/2019 Trade name: ESG 215 Resin (Contd. of page 10) 49.1.7 Hazard statements Harmful if swallowed or in contact with skin. Causes skin and eye irritation. May cause an allergic skin reaction. Toxic to aquatic life with long lasting effects. Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Avoid release to the environment. Wear protective gloves / protective clothing. If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision10/26/2019 / 4 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Acute Tox. 4: Acute toxicity Category 4 Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Irrit. 2B: Serious eye damage/eye irritation Category 2B Skin Sens. 1: Skin sensitisation Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2 * Data compared to the previous version altered. US Page 1/13 Safety Data Sheet acc. to OSHA HCS Printing date 05/11/2020 Reviewed on 05/11/2020 51.0.8 1 Identification Product identifier Trade name: ESG 215 Hardener Article number:I215189 Application of the substance / the mixtureEpoxy hardener Details of the supplier of the safety data sheet Sika Advanced Resins, US EHS Department Manufacturer/Supplier: Supplier's Name: Sika Advanced Resins, US Headquarters: 30800 Stephenson Hwy Madison Heights, MI 48071 USA advancedresins.ehs@us.sika.com Information department:Product safety department Emergency telephone number: During normal opening times: +1 (248) 588-2270 CHEMTREC 24-hour Emergency: +1 (800) 424-9300 * 2 Hazard(s) identification Classification of the substance or mixture GHS06 Skull and crossbones Acute Tox. 2 H330 Fatal if inhaled. GHS08 Health hazard STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS05 Corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. GHS07 Acute Tox. 4 H302 Harmful if swallowed. (Contd. on page 2) US Page 2/13 Safety Data Sheet acc. to OSHA HCS Printing date 05/11/2020 Reviewed on 05/11/2020 Trade name: ESG 215 Hardener (Contd. of page 1) 51.0.8 Acute Tox. 4 H312 Harmful in contact with skin. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. Label elements GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05GHS06GHS07GHS08 Signal wordDanger Hazard-determining components of labeling: 2,2'-iminodiethylamine diethylmethylbenzenediamine 1-methylimidazole m-phenylenebis(methylamine) Hazard statements Harmful if swallowed or in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment is urgent (see on this label). Take off contaminated clothing and wash it before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0 - 4) 3 1 0 Health = 3 Fire = 1 Reactivity = 0 (Contd. on page 3) US Page 3/13 Safety Data Sheet acc. to OSHA HCS Printing date 05/11/2020 Reviewed on 05/11/2020 Trade name: ESG 215 Hardener (Contd. of page 2) 51.0.8 HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *3 1 0 Health = *3 Fire = 1 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. * 3 Composition/information on ingredients Chemical characterization: Mixtures Description:Mixture of the substances listed below with nonhazardous additions. Dangerous components: CAS: 111-40-0 EINECS: 203-865-4 2,2'-iminodiethylamine 20-50% CAS: 68479-98-1 EINECS: 270-877-4 diethylmethylbenzenediamine 20-50% CAS: 616-47-7 EINECS: 210-484-7 1-methylimidazole 10-20% CAS: 1477-55-0 EINECS: 216-032-5 m-phenylenebis(methylamine) 1-<2.5% * 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Remove breathing apparatus only after contaminated clothing have been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. After inhalation: Supply fresh air or oxygen; call for doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Immediately call a doctor. Drink copious amounts of water and provide fresh air. Immediately call a doctor. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 05/11/2020 Reviewed on 05/11/2020 Trade name: ESG 215 Hardener (Contd. of page 3) 51.0.8 Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment: Mouth respiratory protective device. Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 111-40-0 2,2'-iminodiethylamine 3 ppm 616-47-7 1-methylimidazole 2.3 mg/m PAC-2: 111-40-0 2,2'-iminodiethylamine 8.5 ppm 616-47-7 1-methylimidazole 25 mg/m (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 05/11/2020 Reviewed on 05/11/2020 Trade name: ESG 215 Hardener (Contd. of page 4) 51.0.8 PAC-3: 111-40-0 2,2'-iminodiethylamine 51 ppm 616-47-7 1-methylimidazole 150 mg/m * 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires:Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 111-40-0 2,2'-iminodiethylamine REL Long-term value: 4 mg/m , 1 ppm Skin TLV Long-term value: 4.2 mg/m , 1 ppm Skin Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 05/11/2020 Reviewed on 05/11/2020 Trade name: ESG 215 Hardener (Contd. of page 5) 51.0.8 Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Amber colored Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:198 C (388.4 F) Flash point: 105 C (221 F) Flammability (solid, gaseous):Not applicable. (Contd. on page 7) US Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 05/11/2020 Reviewed on 05/11/2020 Trade name: ESG 215 Hardener (Contd. of page 6) 51.0.8 Ignition temperature: 325 C (617 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: 1 Vol % Upper: 10 Vol % Vapor pressure at 20 C (68 F):0.5 hPa (0.4 mm Hg) Density at 20 C (68 F): 1.01 g/cm (8.43 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Fully miscible. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: VOC content: 0.00 % 0.0 g/l / 0.00 lb/gal Solids content: 0.0 % Other information No further relevant information available. * 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide US (Contd. on page 8) Page 8/13 Safety Data Sheet acc. to OSHA HCS Printing date 05/11/2020 Reviewed on 05/11/2020 Trade name: ESG 215 Hardener (Contd. of page 7) 51.0.8 * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: 111-40-0 2,2'-iminodiethylamine Oral LD50 1,553 mg/kg (rat) Dermal LD50 1,045 mg/kg (rabbit) 68479-98-1 diethylmethylbenzenediamine Oral LD50 738 mg/kg (rat) Dermal LD50 >2,000 mg/kg (rat)
616-47-7 1-methylimidazole
Oral LD50 1,400 mg/kg (mouse)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Toxic
Harmful
Corrosive
Irritant
Very toxic
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
(Contd. on page 9) US

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Trade name: ESG 215 Hardener
(Contd. of page 8)
51.0.8
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
Recommended cleansing agent:Water, if necessary with cleansing agents.
* 14 Transport information
UN-Number
DOT NA2735
IMDG, IATA UN2735
UN proper shipping name
DOT Amines, liquid, corrosive, n.o.s. (Diethylenetriamine, m-
phenylenebis(methylamine))
IMDG A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(DIETHYLENETRIAMINE, m-phenylenebis(methylamine)),
MARINE POLLUTANT
IATA A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(DIETHYLENETRIAMINE, m-phenylenebis(methylamine))
(Contd. on page 10)
US

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Trade name: ESG 215 Hardener
(Contd. of page 9)
51.0.8
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG
Class 8 Corrosive substances
Label 8
IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards: Product contains environmentally hazardous substances:
diethylmethylbenzenediamine, Epoxy phenol novolac resin
Marine pollutant: Yes
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Hazard identification number (Kemler code):80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Segregation Code SG35 Stow “separated from” SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
(Contd. on page 11)
US

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Trade name: ESG 215 Hardener
(Contd. of page 10)
51.0.8
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN “Model Regulation”: U N 2 7 3 5 A M I N E S , L I Q U I D , CO R R O S I V E , N. O .S .
( D I E T H Y L E N E T R I A M I N E , M –
PHENYLENEBIS(METHYLAMINE)), 8, II, ENVIRONMENTALLY
HAZARDOUS
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
(Contd. on page 12)
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Trade name: ESG 215 Hardener
(Contd. of page 11)
51.0.8
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
2,2′-iminodiethylamine
diethylmethylbenzenediamine
1-methylimidazole
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed or in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
(Contd. on page 13)
US

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Trade name: ESG 215 Hardener
(Contd. of page 12)
51.0.8
Specific treatment is urgent (see on this label).
Take off contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision05/11/2020 / 4
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Acute Tox. 2: Acute toxicity Category 2
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
* Data compared to the previous version altered.
US

80ES707-H_SDS.pdf

by | Sep 27, 2025

Page 1/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 02/05/2020 Reviewed on 02/05/2020
50. 0
1 Identification
Product identifier
Trade name: SP707 Hardener
Article number:I500889-6
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Repr. 1B H360F May damage fertility.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
(Contd. on page 2)
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Trade name: SP707 Hardener
(Contd. of page 1)
50. 0
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Flam. Liq. 4 H227 Combustible liquid.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
2,2′-iminodiethylamine
Aromatic amine epoxy adduct – trade secret
bisphenol A
1-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
Hazard statements
Combustible liquid.
Harmful if swallowed.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May damage fertility.
May cause respiratory irritation.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Keep away from flames and hot surfaces. No smoking.
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment is urgent (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 3)
US

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Trade name: SP707 Hardener
(Contd. of page 2)
50. 0
Classification system:
NFPA ratings (scale 0 – 4)
3
2
0
Health = 3
Fire = 2
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
2
0
Health = *3
Fire = 2
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
Aromatic amine epoxy adduct – trade secret 25- 50%
CAS: 111-40-0
EINECS: 203-865-4
2,2′-iminodiethylamine 20-50%
CAS: 80-05-7
EINECS: 201-245-8
bisphenol A 20%
CAS: 616-47-7
EINECS: 210-484-7
1-methylimidazole 5%
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 1-<2.5% 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Remove breathing apparatus only after contaminated clothing have been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 3) 50. 0 After inhalation: Supply fresh air or oxygen; call for doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Immediately call a doctor. Drink copious amounts of water and provide fresh air. Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment: Mouth respiratory protective device. Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Environmental precautions:Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 4) 50. 0 Protective Action Criteria for Chemicals PAC-1: 111-40-0 2,2'-iminodiethylamine 3 ppm 80-05-7 bisphenol A 15 mg/m 616-47-7 1-methylimidazole 2.3 mg/m PAC-2: 111-40-0 2,2'-iminodiethylamine 8.5 ppm 80-05-7 bisphenol A 110 mg/m 616-47-7 1-methylimidazole 25 mg/m PAC-3: 111-40-0 2,2'-iminodiethylamine 51 ppm 80-05-7 bisphenol A 650 mg/m 616-47-7 1-methylimidazole 150 mg/m 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 5) 50. 0 111-40-0 2,2'-iminodiethylamine REL Long-term value: 4 mg/m , 1 ppm Skin TLV Long-term value: 4.2 mg/m , 1 ppm Skin Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles US (Contd. on page 7) Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 6) 50. 0 * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Amber colored Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:198 C (388.4 F) Flash point: 92 C (197.6 F) Flammability (solid, gaseous):Not applicable. Ignition temperature: 325 C (617 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Not determined. Explosion limits: Lower: 1 Vol % Upper: 10 Vol % Vapor pressure at 20 C (68 F):0.5 hPa (0.4 mm Hg) Density at 20 C (68 F): 1.05 g/cm (8.76 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: VOC content: 0.00 % 0.0 g/l / 0.00 lb/gal Solids content: 20.0 % (Contd. on page 8) US Page 8/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 7) 50. 0 Other information No further relevant information available. 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD50 910 mg/kg (rat) Dermal LD50 2,000 mg/kg (rabbit) 111-40-0 2,2'-iminodiethylamine Oral LD50 1,553 mg/kg (rat) Dermal LD50 1,045 mg/kg (rabbit) 80-05-7 bisphenol A Oral LD50 3,250 mg/kg (rat) Dermal LD50 3,000 mg/kg (rabbit) 616-47-7 1-methylimidazole Oral LD50 1,400 mg/kg (mouse) Primary irritant effect: on the skin:Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Strong irritant with the danger of severe eye injury. Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Toxic Harmful Corrosive (Contd. on page 9) US Page 9/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 8) 50. 0 Irritant Very toxic Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. Carcinogenic categories IARC (International Agency for Research on Cancer) None of the ingredients is listed. NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. * 12 Ecological information Toxicity Aquatic toxicity: 48 hr EC50 172 mg/l (Fish) 96 hr LC50 100 mg/l (Fish) 72 or 96 hr ErC50 29.5 mg/l (Algea) Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Danger to drinking water if even small quantities leak into the ground. Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. on page 10) US Page 10/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 9) 50. 0 Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT, IMDG, IATA UN2922 UN proper shipping name DOT Corrosive liquids, toxic, n.o.s. (Diethylenetriamine, 1- methylimidazole) IMDG, IATA CORROSIVE LIQUID, TOXIC, N.O.S. (DIETHYLENETRIAMINE, 1-methylimidazole) Transport hazard class(es) DOT Class 8 Corrosive substances Label 8, 6.1 IMDG Class 8 Corrosive substances Label 8/6.1 IATA Class 8 Corrosive substances Label 8 (6.1) Packing group DOT, IMDG, IATA II Environmental hazards: Marine pollutant: No (Contd. on page 11) US Page 11/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 10) 50. 0 Special precautions for user Warning: Corrosive substances Danger code (Kemler): 86 EMS Number: F-A,S-B Segregation groups Alkalis Stowage Category B Stowage Code SW2 Clear of living quarters. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN "Model Regulation": UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. (DIETHYLENETRIAMINE, 1-METHYLIMIDAZOLE), 8 (6.1), II * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): 80-05-7 bisphenol A TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants None of the ingredients is listed. (Contd. on page 12) US Page 12/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 11) 50. 0 Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: 80-05-7 bisphenol A Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05GHS06GHS07GHS08 Signal wordDanger Hazard-determining components of labeling: 2,2'-iminodiethylamine Aromatic amine epoxy adduct - trade secret bisphenol A 1-methylimidazole 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- Hazard statements Combustible liquid. Harmful if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May damage fertility. (Contd. on page 13) US Page 13/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 12) 50. 0 May cause respiratory irritation. Precautionary statements Keep away from flames and hot surfaces. No smoking. Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment is urgent (see on this label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision02/05/2020 / 5 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 4: Flammable liquids Category 4 Acute Tox. 4: Acute toxicity Category 4 Acute Tox. 2: Acute toxicity Category 2 Skin Corr. 1B: Skin corrosion/irritation Category 1B Eye Dam. 1: Serious eye damage/eye irritation Category 1 Resp. Sens. 1: Respiratory sensitisation Category 1 Skin Sens. 1: Skin sensitisation Category 1 Repr. 1B: Reproductive toxicity Category 1B STOT SE 3: Specific target organ toxicity (single exposure) Category 3 * Data compared to the previous version altered. US

80ES707-G_SDS.pdf

by | Sep 27, 2025

Page 1/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/10/2019 Reviewed on 10/10/2019
49.1.7
1 Identification
Product identifier
Trade name: SP707 Resin
Article number:I229088-1
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Water-react. 3 H261 In contact with water releases flammable gas.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Eye Irrit. 2B H320 Causes eye irritation.
(Contd. on page 2)
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Trade name: SP707 Resin
(Contd. of page 1)
49.1.7
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane
Hazard statements
In contact with water releases flammable gas.
Harmful if swallowed or in contact with skin.
Causes skin and eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Handle under inert gas. Protect from moisture.
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
Rinse mouth.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
1
0
2
W
Health = 1
Fire = 0
Reactivity = 2
The substance demonstrates unusual reactivity with water.
(Contd. on page 3)
US

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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/10/2019 Reviewed on 10/10/2019
Trade name: SP707 Resin
(Contd. of page 2)
49.1.7
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
1
0
2
Health = 1
Fire = 0
Reactivity = 2
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 1675-54-3
EINECS: 216-823-5
bis[4-(2,3-epoxypropoxy)phenyl]propane 25- 50%
CAS: 28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
10-20%
CAS: 17557-23-2
EINECS: 241-536-7
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane 5-<10% CAS: 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1-5% CAS: 872-50-4 EINECS: 212-828-1 N-methyl-2-pyrrolidone 0.1-1% 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 3) 49.1.7 Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixtureNo further relevant information available. Advice for firefighters Protective equipment:Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 39 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 30 mg/m 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 120 mg/m 872-50-4 N-methyl-2-pyrrolidone 30 ppm PAC-2: 1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 430 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 330 mg/m 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1,300 mg/m (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 4) 49.1.7 872-50-4 N-methyl-2-pyrrolidone 32 ppm PAC-3: 1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 2,600 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 2,000 mg/m 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 7,900 mg/m 872-50-4 N-methyl-2-pyrrolidone 190 ppm 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires:Keep ignition sources away - Do not smoke. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Specific end use(s)No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 872-50-4 N-methyl-2-pyrrolidone TLV BEI WEEL Long-term value: 10 ppm Skin (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 5) 49.1.7 Ingredients with biological limit values: 872-50-4 N-methyl-2-pyrrolidone BEI 100 mg/L Medium: urine Time: end of shift Parameter: 5-Hydroxy-N-methyl-2-pyrrolidone Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles US (Contd. on page 7) Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 6) 49.1.7 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Thixotropic Paste Color: Grey Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:201 C (393.8 F) Flash point: Not applicable. Flammability (solid, gaseous):Not applicable. Ignition temperature: 400 C (752 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Not determined. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure: Not determined. Density at 20 C (68 F): 1.75 g/cm (14.6 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 0.2 % VOC content: 0.20 % 3.6 g/l / 0.03 lb/gal Solids content: 39.3 % (Contd. on page 8) US Page 8/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 7) 49.1.7 Other information No further relevant information available. * 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsContact with water releases flammable gases. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD50 4,500 mg/kg (rat) Primary irritant effect: on the skin:Irritant to skin and mucous membranes. on the eye:Irritating effect. Sensitization:Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) 1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 3 NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradabilityNo further relevant information available. (Contd. on page 9) US Page 9/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 8) 49.1.7 Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Ecotoxical effects: Remark:Toxic for fish Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. 14 Transport information UN-Number DOT not regulated IMDG, IATA UN3082 UN proper shipping name DOT not regulated IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin, DGEBA Monomer), MARINE POLLUTANT IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin, DGEBA Monomer) (Contd. on page 10) US Page 10/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 9) 49.1.7 Transport hazard class(es) DOT Class not regulated IMDG, IATA Class 9 Miscellaneous dangerous substances and articles Label 9 Packing group DOT not regulated IMDG, IATA III Environmental hazards: Product contains environmentally hazardous substances: Epoxy phenol novolac resin Marine pollutant: Yes Symbol (fish and tree) Special marking (IATA): Symbol (fish and tree) Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 423 EMS Number: F-A,S-F Stowage Category A Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN, DGEBA MONOMER), 9, III US (Contd. on page 11) Page 11/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 10) 49.1.7 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): 7429-90-5 aluminum powder (stabilised) 872-50-4 N-methyl-2-pyrrolidone TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants None of the ingredients is listed. Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: 872-50-4 N-methyl-2-pyrrolidone Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 12) US Page 12/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 11) 49.1.7 Hazard pictograms GHS02GHS07GHS09 Signal wordWarning Hazard-determining components of labeling: bis[4-(2,3-epoxypropoxy)phenyl]propane 1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane Hazard statements In contact with water releases flammable gas. Harmful if swallowed or in contact with skin. Causes skin and eye irritation. May cause an allergic skin reaction. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statements Handle under inert gas. Protect from moisture. Avoid breathing dust/fume/gas/mist/vapors/spray Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision10/10/2019 / 5 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) (Contd. on page 13) US Page 13/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 12) 49.1.7 LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit BEI: Biological Exposure Limit Water-react. 3: Substances and mixtures which in contact with water emit flammable gases Category 3 Acute Tox. 4: Acute toxicity Category 4 Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Irrit. 2B: Serious eye damage/eye irritation Category 2B Skin Sens. 1: Skin sensitisation Category 1 Aquatic Acute 2: Hazardous to the aquatic environment - acute aquatic hazard Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2 * Data compared to the previous version altered. US Page 1/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 50. 0 1 Identification Product identifier Trade name: SP707 Hardener Article number:I500889-6 Application of the substance / the mixtureEpoxy curing agent Details of the supplier of the safety data sheet Sika Advanced Resins, US EHS Department Manufacturer/Supplier: Supplier's Name: Sika Advanced Resins, US Headquarters: 30800 Stephenson Hwy Madison Heights, MI 48071 USA advancedresins.ehs@us.sika.com Information department:Product safety department Emergency telephone number: During normal opening times: +1 (248) 588-2270 CHEMTREC 24-hour Emergency: +1 (800) 424-9300 * 2 Hazard(s) identification Classification of the substance or mixture GHS06 Skull and crossbones Acute Tox. 2 H330 Fatal if inhaled. GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Repr. 1B H360F May damage fertility. GHS05 Corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. GHS07 (Contd. on page 2) US Page 2/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 1) 50. 0 Acute Tox. 4 H302 Harmful if swallowed. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. Flam. Liq. 4 H227 Combustible liquid. Label elements GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05GHS06GHS07GHS08 Signal wordDanger Hazard-determining components of labeling: 2,2'-iminodiethylamine Aromatic amine epoxy adduct - trade secret bisphenol A 1-methylimidazole 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- Hazard statements Combustible liquid. Harmful if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May damage fertility. May cause respiratory irritation. Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Keep away from flames and hot surfaces. No smoking. Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment is urgent (see on this label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. on page 3) US Page 3/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 2) 50. 0 Classification system: NFPA ratings (scale 0 - 4) 3 2 0 Health = 3 Fire = 2 Reactivity = 0 HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *3 2 0 Health = *3 Fire = 2 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. * 3 Composition/information on ingredients Chemical characterization: Mixtures Description:Mixture of the substances listed below with nonhazardous additions. Dangerous components: Aromatic amine epoxy adduct - trade secret 25- 50% CAS: 111-40-0 EINECS: 203-865-4 2,2'-iminodiethylamine 20-50% CAS: 80-05-7 EINECS: 201-245-8 bisphenol A 20% CAS: 616-47-7 EINECS: 210-484-7 1-methylimidazole 5% CAS: 25513-64-8 EINECS: 247-134-8 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 1-<2.5% 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Remove breathing apparatus only after contaminated clothing have been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 3) 50. 0 After inhalation: Supply fresh air or oxygen; call for doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Immediately call a doctor. Drink copious amounts of water and provide fresh air. Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment: Mouth respiratory protective device. Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Environmental precautions:Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 4) 50. 0 Protective Action Criteria for Chemicals PAC-1: 111-40-0 2,2'-iminodiethylamine 3 ppm 80-05-7 bisphenol A 15 mg/m 616-47-7 1-methylimidazole 2.3 mg/m PAC-2: 111-40-0 2,2'-iminodiethylamine 8.5 ppm 80-05-7 bisphenol A 110 mg/m 616-47-7 1-methylimidazole 25 mg/m PAC-3: 111-40-0 2,2'-iminodiethylamine 51 ppm 80-05-7 bisphenol A 650 mg/m 616-47-7 1-methylimidazole 150 mg/m 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 5) 50. 0 111-40-0 2,2'-iminodiethylamine REL Long-term value: 4 mg/m , 1 ppm Skin TLV Long-term value: 4.2 mg/m , 1 ppm Skin Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles US (Contd. on page 7) Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 6) 50. 0 * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Amber colored Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:198 C (388.4 F) Flash point: 92 C (197.6 F) Flammability (solid, gaseous):Not applicable. Ignition temperature: 325 C (617 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Not determined. Explosion limits: Lower: 1 Vol % Upper: 10 Vol % Vapor pressure at 20 C (68 F):0.5 hPa (0.4 mm Hg) Density at 20 C (68 F): 1.05 g/cm (8.76 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: VOC content: 0.00 % 0.0 g/l / 0.00 lb/gal Solids content: 20.0 % (Contd. on page 8) US Page 8/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 7) 50. 0 Other information No further relevant information available. 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD50 910 mg/kg (rat) Dermal LD50 2,000 mg/kg (rabbit) 111-40-0 2,2'-iminodiethylamine Oral LD50 1,553 mg/kg (rat) Dermal LD50 1,045 mg/kg (rabbit) 80-05-7 bisphenol A Oral LD50 3,250 mg/kg (rat) Dermal LD50 3,000 mg/kg (rabbit) 616-47-7 1-methylimidazole Oral LD50 1,400 mg/kg (mouse) Primary irritant effect: on the skin:Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Strong irritant with the danger of severe eye injury. Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Toxic Harmful Corrosive (Contd. on page 9) US Page 9/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 8) 50. 0 Irritant Very toxic Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. Carcinogenic categories IARC (International Agency for Research on Cancer) None of the ingredients is listed. NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. * 12 Ecological information Toxicity Aquatic toxicity: 48 hr EC50 172 mg/l (Fish) 96 hr LC50 100 mg/l (Fish) 72 or 96 hr ErC50 29.5 mg/l (Algea) Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Danger to drinking water if even small quantities leak into the ground. Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. on page 10) US Page 10/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 9) 50. 0 Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT, IMDG, IATA UN2922 UN proper shipping name DOT Corrosive liquids, toxic, n.o.s. (Diethylenetriamine, 1- methylimidazole) IMDG, IATA CORROSIVE LIQUID, TOXIC, N.O.S. (DIETHYLENETRIAMINE, 1-methylimidazole) Transport hazard class(es) DOT Class 8 Corrosive substances Label 8, 6.1 IMDG Class 8 Corrosive substances Label 8/6.1 IATA Class 8 Corrosive substances Label 8 (6.1) Packing group DOT, IMDG, IATA II Environmental hazards: Marine pollutant: No (Contd. on page 11) US Page 11/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 10) 50. 0 Special precautions for user Warning: Corrosive substances Danger code (Kemler): 86 EMS Number: F-A,S-B Segregation groups Alkalis Stowage Category B Stowage Code SW2 Clear of living quarters. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN "Model Regulation": UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. (DIETHYLENETRIAMINE, 1-METHYLIMIDAZOLE), 8 (6.1), II * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): 80-05-7 bisphenol A TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants None of the ingredients is listed. (Contd. on page 12) US Page 12/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 11) 50. 0 Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: 80-05-7 bisphenol A Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05GHS06GHS07GHS08 Signal wordDanger Hazard-determining components of labeling: 2,2'-iminodiethylamine Aromatic amine epoxy adduct - trade secret bisphenol A 1-methylimidazole 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- Hazard statements Combustible liquid. Harmful if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May damage fertility. (Contd. on page 13) US Page 13/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 12) 50. 0 May cause respiratory irritation. Precautionary statements Keep away from flames and hot surfaces. No smoking. Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment is urgent (see on this label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision02/05/2020 / 5 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 4: Flammable liquids Category 4 Acute Tox. 4: Acute toxicity Category 4 Acute Tox. 2: Acute toxicity Category 2 Skin Corr. 1B: Skin corrosion/irritation Category 1B Eye Dam. 1: Serious eye damage/eye irritation Category 1 Resp. Sens. 1: Respiratory sensitisation Category 1 Skin Sens. 1: Skin sensitisation Category 1 Repr. 1B: Reproductive toxicity Category 1B STOT SE 3: Specific target organ toxicity (single exposure) Category 3 * Data compared to the previous version altered. US

80ES707-F_SDS.pdf

by | Sep 27, 2025

Page 1/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/10/2019 Reviewed on 10/10/2019
49.1.7
1 Identification
Product identifier
Trade name: SP707 Resin
Article number:I229088-1
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Water-react. 3 H261 In contact with water releases flammable gas.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Eye Irrit. 2B H320 Causes eye irritation.
(Contd. on page 2)
US

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Safety Data Sheet
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Trade name: SP707 Resin
(Contd. of page 1)
49.1.7
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane
Hazard statements
In contact with water releases flammable gas.
Harmful if swallowed or in contact with skin.
Causes skin and eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Handle under inert gas. Protect from moisture.
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
Rinse mouth.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
1
0
2
W
Health = 1
Fire = 0
Reactivity = 2
The substance demonstrates unusual reactivity with water.
(Contd. on page 3)
US

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Trade name: SP707 Resin
(Contd. of page 2)
49.1.7
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
1
0
2
Health = 1
Fire = 0
Reactivity = 2
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 1675-54-3
EINECS: 216-823-5
bis[4-(2,3-epoxypropoxy)phenyl]propane 25- 50%
CAS: 28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
10-20%
CAS: 17557-23-2
EINECS: 241-536-7
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane 5-<10% CAS: 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1-5% CAS: 872-50-4 EINECS: 212-828-1 N-methyl-2-pyrrolidone 0.1-1% 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 3) 49.1.7 Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixtureNo further relevant information available. Advice for firefighters Protective equipment:Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 39 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 30 mg/m 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 120 mg/m 872-50-4 N-methyl-2-pyrrolidone 30 ppm PAC-2: 1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 430 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 330 mg/m 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 1,300 mg/m (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 4) 49.1.7 872-50-4 N-methyl-2-pyrrolidone 32 ppm PAC-3: 1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 2,600 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 2,000 mg/m 67762-90-7 Silicones and siloxanes, dimethyl-, reaction products with silica 7,900 mg/m 872-50-4 N-methyl-2-pyrrolidone 190 ppm 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires:Keep ignition sources away - Do not smoke. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Specific end use(s)No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 872-50-4 N-methyl-2-pyrrolidone TLV BEI WEEL Long-term value: 10 ppm Skin (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 5) 49.1.7 Ingredients with biological limit values: 872-50-4 N-methyl-2-pyrrolidone BEI 100 mg/L Medium: urine Time: end of shift Parameter: 5-Hydroxy-N-methyl-2-pyrrolidone Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles US (Contd. on page 7) Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 6) 49.1.7 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Thixotropic Paste Color: Grey Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:201 C (393.8 F) Flash point: Not applicable. Flammability (solid, gaseous):Not applicable. Ignition temperature: 400 C (752 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Not determined. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure: Not determined. Density at 20 C (68 F): 1.75 g/cm (14.6 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 0.2 % VOC content: 0.20 % 3.6 g/l / 0.03 lb/gal Solids content: 39.3 % (Contd. on page 8) US Page 8/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 7) 49.1.7 Other information No further relevant information available. * 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsContact with water releases flammable gases. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD50 4,500 mg/kg (rat) Primary irritant effect: on the skin:Irritant to skin and mucous membranes. on the eye:Irritating effect. Sensitization:Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) 1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 3 NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradabilityNo further relevant information available. (Contd. on page 9) US Page 9/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 8) 49.1.7 Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Ecotoxical effects: Remark:Toxic for fish Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. 14 Transport information UN-Number DOT not regulated IMDG, IATA UN3082 UN proper shipping name DOT not regulated IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin, DGEBA Monomer), MARINE POLLUTANT IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin, DGEBA Monomer) (Contd. on page 10) US Page 10/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 9) 49.1.7 Transport hazard class(es) DOT Class not regulated IMDG, IATA Class 9 Miscellaneous dangerous substances and articles Label 9 Packing group DOT not regulated IMDG, IATA III Environmental hazards: Product contains environmentally hazardous substances: Epoxy phenol novolac resin Marine pollutant: Yes Symbol (fish and tree) Special marking (IATA): Symbol (fish and tree) Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 423 EMS Number: F-A,S-F Stowage Category A Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN, DGEBA MONOMER), 9, III US (Contd. on page 11) Page 11/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 10) 49.1.7 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): 7429-90-5 aluminum powder (stabilised) 872-50-4 N-methyl-2-pyrrolidone TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants None of the ingredients is listed. Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: 872-50-4 N-methyl-2-pyrrolidone Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 12) US Page 12/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 11) 49.1.7 Hazard pictograms GHS02GHS07GHS09 Signal wordWarning Hazard-determining components of labeling: bis[4-(2,3-epoxypropoxy)phenyl]propane 1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane Hazard statements In contact with water releases flammable gas. Harmful if swallowed or in contact with skin. Causes skin and eye irritation. May cause an allergic skin reaction. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statements Handle under inert gas. Protect from moisture. Avoid breathing dust/fume/gas/mist/vapors/spray Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision10/10/2019 / 5 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) (Contd. on page 13) US Page 13/13 Safety Data Sheet acc. to OSHA HCS Printing date 10/10/2019 Reviewed on 10/10/2019 Trade name: SP707 Resin (Contd. of page 12) 49.1.7 LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit BEI: Biological Exposure Limit Water-react. 3: Substances and mixtures which in contact with water emit flammable gases Category 3 Acute Tox. 4: Acute toxicity Category 4 Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Irrit. 2B: Serious eye damage/eye irritation Category 2B Skin Sens. 1: Skin sensitisation Category 1 Aquatic Acute 2: Hazardous to the aquatic environment - acute aquatic hazard Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2 * Data compared to the previous version altered. US Page 1/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 50. 0 1 Identification Product identifier Trade name: SP707 Hardener Article number:I500889-6 Application of the substance / the mixtureEpoxy curing agent Details of the supplier of the safety data sheet Sika Advanced Resins, US EHS Department Manufacturer/Supplier: Supplier's Name: Sika Advanced Resins, US Headquarters: 30800 Stephenson Hwy Madison Heights, MI 48071 USA advancedresins.ehs@us.sika.com Information department:Product safety department Emergency telephone number: During normal opening times: +1 (248) 588-2270 CHEMTREC 24-hour Emergency: +1 (800) 424-9300 * 2 Hazard(s) identification Classification of the substance or mixture GHS06 Skull and crossbones Acute Tox. 2 H330 Fatal if inhaled. GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Repr. 1B H360F May damage fertility. GHS05 Corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. GHS07 (Contd. on page 2) US Page 2/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 1) 50. 0 Acute Tox. 4 H302 Harmful if swallowed. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. Flam. Liq. 4 H227 Combustible liquid. Label elements GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05GHS06GHS07GHS08 Signal wordDanger Hazard-determining components of labeling: 2,2'-iminodiethylamine Aromatic amine epoxy adduct - trade secret bisphenol A 1-methylimidazole 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- Hazard statements Combustible liquid. Harmful if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May damage fertility. May cause respiratory irritation. Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Keep away from flames and hot surfaces. No smoking. Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment is urgent (see on this label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. on page 3) US Page 3/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 2) 50. 0 Classification system: NFPA ratings (scale 0 - 4) 3 2 0 Health = 3 Fire = 2 Reactivity = 0 HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *3 2 0 Health = *3 Fire = 2 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. * 3 Composition/information on ingredients Chemical characterization: Mixtures Description:Mixture of the substances listed below with nonhazardous additions. Dangerous components: Aromatic amine epoxy adduct - trade secret 25- 50% CAS: 111-40-0 EINECS: 203-865-4 2,2'-iminodiethylamine 20-50% CAS: 80-05-7 EINECS: 201-245-8 bisphenol A 20% CAS: 616-47-7 EINECS: 210-484-7 1-methylimidazole 5% CAS: 25513-64-8 EINECS: 247-134-8 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 1-<2.5% 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Remove breathing apparatus only after contaminated clothing have been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 3) 50. 0 After inhalation: Supply fresh air or oxygen; call for doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Immediately call a doctor. Drink copious amounts of water and provide fresh air. Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment: Mouth respiratory protective device. Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Environmental precautions:Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 4) 50. 0 Protective Action Criteria for Chemicals PAC-1: 111-40-0 2,2'-iminodiethylamine 3 ppm 80-05-7 bisphenol A 15 mg/m 616-47-7 1-methylimidazole 2.3 mg/m PAC-2: 111-40-0 2,2'-iminodiethylamine 8.5 ppm 80-05-7 bisphenol A 110 mg/m 616-47-7 1-methylimidazole 25 mg/m PAC-3: 111-40-0 2,2'-iminodiethylamine 51 ppm 80-05-7 bisphenol A 650 mg/m 616-47-7 1-methylimidazole 150 mg/m 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 5) 50. 0 111-40-0 2,2'-iminodiethylamine REL Long-term value: 4 mg/m , 1 ppm Skin TLV Long-term value: 4.2 mg/m , 1 ppm Skin Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles US (Contd. on page 7) Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 6) 50. 0 * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Amber colored Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:198 C (388.4 F) Flash point: 92 C (197.6 F) Flammability (solid, gaseous):Not applicable. Ignition temperature: 325 C (617 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Not determined. Explosion limits: Lower: 1 Vol % Upper: 10 Vol % Vapor pressure at 20 C (68 F):0.5 hPa (0.4 mm Hg) Density at 20 C (68 F): 1.05 g/cm (8.76 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: VOC content: 0.00 % 0.0 g/l / 0.00 lb/gal Solids content: 20.0 % (Contd. on page 8) US Page 8/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 7) 50. 0 Other information No further relevant information available. 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD50 910 mg/kg (rat) Dermal LD50 2,000 mg/kg (rabbit) 111-40-0 2,2'-iminodiethylamine Oral LD50 1,553 mg/kg (rat) Dermal LD50 1,045 mg/kg (rabbit) 80-05-7 bisphenol A Oral LD50 3,250 mg/kg (rat) Dermal LD50 3,000 mg/kg (rabbit) 616-47-7 1-methylimidazole Oral LD50 1,400 mg/kg (mouse) Primary irritant effect: on the skin:Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Strong irritant with the danger of severe eye injury. Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Toxic Harmful Corrosive (Contd. on page 9) US Page 9/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 8) 50. 0 Irritant Very toxic Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. Carcinogenic categories IARC (International Agency for Research on Cancer) None of the ingredients is listed. NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. * 12 Ecological information Toxicity Aquatic toxicity: 48 hr EC50 172 mg/l (Fish) 96 hr LC50 100 mg/l (Fish) 72 or 96 hr ErC50 29.5 mg/l (Algea) Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Danger to drinking water if even small quantities leak into the ground. Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. on page 10) US Page 10/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 9) 50. 0 Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT, IMDG, IATA UN2922 UN proper shipping name DOT Corrosive liquids, toxic, n.o.s. (Diethylenetriamine, 1- methylimidazole) IMDG, IATA CORROSIVE LIQUID, TOXIC, N.O.S. (DIETHYLENETRIAMINE, 1-methylimidazole) Transport hazard class(es) DOT Class 8 Corrosive substances Label 8, 6.1 IMDG Class 8 Corrosive substances Label 8/6.1 IATA Class 8 Corrosive substances Label 8 (6.1) Packing group DOT, IMDG, IATA II Environmental hazards: Marine pollutant: No (Contd. on page 11) US Page 11/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 10) 50. 0 Special precautions for user Warning: Corrosive substances Danger code (Kemler): 86 EMS Number: F-A,S-B Segregation groups Alkalis Stowage Category B Stowage Code SW2 Clear of living quarters. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN "Model Regulation": UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. (DIETHYLENETRIAMINE, 1-METHYLIMIDAZOLE), 8 (6.1), II * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): 80-05-7 bisphenol A TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants None of the ingredients is listed. (Contd. on page 12) US Page 12/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 11) 50. 0 Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: 80-05-7 bisphenol A Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05GHS06GHS07GHS08 Signal wordDanger Hazard-determining components of labeling: 2,2'-iminodiethylamine Aromatic amine epoxy adduct - trade secret bisphenol A 1-methylimidazole 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- Hazard statements Combustible liquid. Harmful if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May damage fertility. (Contd. on page 13) US Page 13/13 Safety Data Sheet acc. to OSHA HCS Printing date 02/05/2020 Reviewed on 02/05/2020 Trade name: SP707 Hardener (Contd. of page 12) 50. 0 May cause respiratory irritation. Precautionary statements Keep away from flames and hot surfaces. No smoking. Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment is urgent (see on this label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision02/05/2020 / 5 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 4: Flammable liquids Category 4 Acute Tox. 4: Acute toxicity Category 4 Acute Tox. 2: Acute toxicity Category 2 Skin Corr. 1B: Skin corrosion/irritation Category 1B Eye Dam. 1: Serious eye damage/eye irritation Category 1 Resp. Sens. 1: Respiratory sensitisation Category 1 Skin Sens. 1: Skin sensitisation Category 1 Repr. 1B: Reproductive toxicity Category 1B STOT SE 3: Specific target organ toxicity (single exposure) Category 3 * Data compared to the previous version altered. US