80655711_SDS.pdf
80655697_SDS.pdf
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
1 / 12
SECTION 1. IDENTIFICATION
Product name : SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Company name : Sika Corporation
201 Polito Avenue
Lyndhurst, NJ 07071
USA
www.sikausa.com
Telephone : (201) 933-8800
Telefax : (201) 804-1076
E-mail address : ehs@sika-corp.com
Emergency telephone : CHEMTREC: 800-424-9300
INTERNATIONAL: +1-703-527-3887
Recommended use of the
chemical and restrictions on
use
: For further information, refer to product data sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Acute toxicity (Oral)
: Category 4
Acute toxicity (Inhalation)
: Category 3
Acute toxicity (Dermal)
: Category 3
Skin corrosion
: Category 1B
Serious eye damage
: Category 1
Skin sensitization
: Category 1
Specific target organ toxicity
– repeated exposure
: Category 2 (Adrenal gland, Kidney, Liver, Heart, Blood)
GHS label elements
Hazard pictograms
:
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
2 / 12
Signal Word
: Danger
Hazard Statements
: H302 Harmful if swallowed.
H311 + H331 Toxic in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H373 May cause damage to organs (Adrenal gland, Kidney,
Liver, Heart, Blood) through prolonged or repeated exposure.
Precautionary Statements
:
Prevention:
P260 Do not breathe mist or vapors.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/ doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P314 Get medical advice/ attention if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P361 + P364 Take off immediately all contaminated clothing and
wash it before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Additional Labeling
There are no ingredients with unknown acute toxicity used in a mixture at a concentration >= 1%.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
3 / 12
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
Components
Chemical name CAS-No. Classification Concentra-
tion (% w/w)
2,2′-dimethyl-
4,4’methylenebis(cyclohexylamine)
6864-37-5 Acute Tox. 4; H302
Acute Tox. 2; H330
Acute Tox. 3; H311
Skin Corr. 1A; H314
Eye Dam. 1; H318
STOT RE 2; H373
>= 50 – < 70
Isophoronediamine 2855-13-2 Acute Tox. 4; H302
Skin Corr. 1B; H314
Eye Dam. 1; H318
Skin Sens. 1A; H317
>= 50 – < 70
Actual concentration is withheld as a trade secret
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.
Symptoms of poisoning may appear several hours later.
If inhaled : Move to fresh air.
Consult a physician after significant exposure.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficul-
ty.
Take victim immediately to hospital.
In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
4 / 12
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
Most important symptoms
and effects, both acute and
delayed
: Health injuries may be delayed.
corrosive effects
sensitizing effects
Gastrointestinal discomfort
Respiratory disorder
Allergic reactions
Headache
Dermatitis
Skin disorders
Harmful if swallowed.
Toxic in contact with skin or if inhaled.
May cause an allergic skin reaction.
Causes serious eye damage.
May cause damage to organs through prolonged or repeated
exposure.
Causes severe burns.
Notes to physician : Treat symptomatically.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment
for fire-fighters
: In the event of fire, wear self-contained breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
gency procedures
: Use personal protective equipment.
Deny access to unprotected persons.
Environmental precautions
: Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform respective authorities.
Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for
containment and cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
5 / 12
Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on protection against
fire and explosion
: Normal measures for preventive fire protection.
Advice on safe handling : Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitization problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Provide sufficient air exchange and/or exhaust in work rooms.
Follow standard hygiene measures when handling chemical
products.
Conditions for safe storage : Prevent unauthorized access.
Store in original container.
Keep in a well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Store in accordance with local regulations.
Materials to avoid : Explosives
Oxidizing agents
Poisonous gases
Dangerous when wet
Flammable solids
Organic peroxides
Poisonous liquids
Spontaneously Combustible Substances
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Contains no substances with occupational exposure limit values.
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use pro-
cess enclosures, local exhaust ventilation or other engineer-
ing controls to keep worker exposure below any recommend-
ed or statutory limits.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
6 / 12
Personal protective equipment
Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is nec-
essary.
Eye protection : Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary.
Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.
Hygiene measures : Avoid contact with skin, eyes and clothing.
Wash hands before breaks and immediately after handling
the product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Wash thoroughly after handling.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : light yellow
Odor : ammoniacal
Odor Threshold : No data available
pH : Not applicable
Melting point/range / Freezing
point
: No data available
Boiling point/boiling range
: 1,855 F / 1,013 C
Flash point : 234 F / 112 C
(Method: closed cup)
Evaporation rate : No data available
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
7 / 12
Flammability (solid, gas)
: No data available
Upper explosion limit / Upper
flammability limit
: No data available
Lower explosion limit / Lower
flammability limit
: No data available
Vapor pressure : 0.02 hpa
Relative vapor density : No data available
Density : 0.91 g/cm3 (68 F / 20 C)
Solubility(ies)
Water solubility : soluble
Solubility in other solvents : No data available
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : No data available
Decomposition temperature : No data available
Viscosity
Viscosity, dynamic : No data available
Viscosity, kinematic : > 20.5 mm2/s (104 F / 40 C)
Explosive properties : No data available
Oxidizing properties : No data available
Volatile organic compounds
(VOC) content
: Not applicable
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : The product is chemically stable.
Possibility of hazardous reac-
tions
: Stable under recommended storage conditions.
Conditions to avoid : No data available
Incompatible materials : No data available
Hazardous decomposition
products
: No decomposition if stored and applied as directed.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
8 / 12
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Harmful if swallowed.
Toxic in contact with skin or if inhaled.
Components:
2,2′-dimethyl-4,4’methylenebis(cyclohexylamine):
Acute oral toxicity : LD50 Oral (Rat): 320 – 460 mg/kg
Acute inhalation toxicity : LC50 (Rat): 0.42 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity : LD50 Dermal (Rabbit): 201 – 400 mg/kg
Isophoronediamine:
Acute oral toxicity : LD50 Oral (Rat): 1,030 mg/kg
Acute inhalation toxicity : LC50 (Rat): > 10 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity : LD50 (Rabbit): > 2,000 – 5,000 mg/kg
Skin corrosion/irritation
Causes severe burns.
Product:
Method : In Vitro Membrane Barrier Test Method for Skin Corrosion –
CORROSITEX
Result : Corrosive after 3 minutes to 1 hour of exposure
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization
Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
9 / 12
Carcinogenicity
Not classified based on available information.
IARC Not applicable
OSHA Not applicable
NTP Not applicable
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
May cause damage to organs (Adrenal gland, Kidney, Liver, Heart, Blood) through prolonged or re-
peated exposure.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
Aspiration toxicity
Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
Isophoronediamine:
Toxicity to algae/aquatic
plants
: ErC50 (Desmodesmus subspicatus (green algae)): > 10 – 100
mg/l
NOEC (Desmodesmus subspicatus (green algae)): 1.5 mg/l
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological infor-
mation
: Do not empty into drains; dispose of this material and its con-
tainer in a safe way.
Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.
Toxic to aquatic organisms, may cause long-term adverse
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
10 / 12
effects in the aquatic environment.
May be harmful to the environment if released in large quanti-
ties.
Water polluting material.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental protection and waste disposal legislation and any regional
local authority requirements.
Contaminated packaging : Empty containers should be taken to an approved waste han-
dling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR
UN/ID No. : UN 2927
Proper shipping name : Toxic liquid, corrosive, organic, n.o.s.
(2,2′-dimethyl-4,4′-methylenebis(cyclohexylamine))
Class : 6.1
Subsidiary risk : 8
Packing group : II
Labels : Toxic, Corrosive
Packing instruction (cargo
aircraft)
: 660
Packing instruction (passen-
ger aircraft)
: 653
IMDG-Code
UN number : UN 2927
Proper shipping name : TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.
(2,2′-dimethyl-4,4′-methylenebis(cyclohexylamine))
Class : 6.1
Subsidiary risk : 8
Packing group : II
Labels : 6.1 (8)
EmS Code : F-A, S-B
Marine pollutant : yes
Domestic regulation
49 CFR
UN/ID/NA number : UN 2927
Proper shipping name : Toxic liquids, corrosive, organic, n.o.s.
(2,2′-dimethyl-4,4’methylenebis(cyclohexylamine))
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin CH128-4 (formerly EL-336-LPL) Part B
Revision Date 09/13/2023
Print Date 09/13/2023
11 / 12
Class : 6.1
Subsidiary risk : 8
Packing group : II
Labels : TOXIC, CORROSIVE
ERG Code : 154
Marine pollutant : no
DOT: As per 49 CFR 171.4, Non- bulk materials (<119 Gal) are exempt from being classified as a Marine Pollutant. IMDG: For Limited Quantity special provisions reference IMDG Code Chapter 3.4 Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. SECTION 15. REGULATORY INFORMATION TSCA list : All chemical substances in this product are either listed as ac- tive on the TSCA Inventory or are in compliance with a TSCA Inventory exemption. No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Acute toxicity (any route of exposure) Respiratory or skin sensitization Specific target organ toxicity (single or repeated exposure) Skin corrosion or irritation Serious eye damage or eye irritation SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). Safety Data Sheet according to OSHA 1910.1200 Hazard Communication Standard SikaBiresin CH128-4 (formerly EL-336-LPL) Part B Revision Date 09/13/2023 Print Date 09/13/2023 12 / 12 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. SECTION 16. OTHER INFORMATION Full text of other abbreviations Notes to Reader The information contained in this Safety Data Sheet applies only to the actual Sika Corporation ("Sika") product identified and described herein. This information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material, product or process. All of the information set forth herein is based on technical data re- garding the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's current Product Data Sheet, product label and Safety Data Sheet for each Sika product, which are available at web site and/or telephone number listed in Section 1 of this SDS. SIKA MAKES NO WARRA NTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRING E ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS. All sales of Sika products are subject to its current terms and conditions of sale available at www.sikausa.com or 201- 933-8800. Revision Date 09/13/2023 100000035506 US / Z8
80655226_SDS.pdf
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Safety Data Sheet
acc. to OSHA HCS
Printing date 03/03/2020 Reviewed on 03/03/2020
50. 0
1 Identification
Product identifier
Trade name: ESG 215 T Hardener
Article number:I215689
Application of the substance / the mixtureEpoxy hardener
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
(Contd. on page 2)
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Trade name: ESG 215 T Hardener
(Contd. of page 1)
50. 0
Acute Tox. 4 H312 Harmful in contact with skin.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
2,2′-iminodiethylamine
diethylmethylbenzenediamine
1-methylimidazole
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed or in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment is urgent (see on this label).
Take off contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
(Contd. on page 3)
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Trade name: ESG 215 T Hardener
(Contd. of page 2)
50. 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 111-40-0
EINECS: 203-865-4
2,2′-iminodiethylamine 20-50%
CAS: 68479-98-1
EINECS: 270-877-4
diethylmethylbenzenediamine 20-50%
CAS: 616-47-7
EINECS: 210-484-7
1-methylimidazole 10-20%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 1-<2.5%
* 4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
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Trade name: ESG 215 T Hardener
(Contd. of page 3)
50. 0
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
111-40-0 2,2'-iminodiethylamine 3 ppm
616-47-7 1-methylimidazole 2.3 mg/m
PAC-2:
111-40-0 2,2'-iminodiethylamine 8.5 ppm
616-47-7 1-methylimidazole 25 mg/m
PAC-3:
111-40-0 2,2'-iminodiethylamine 51 ppm
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Trade name: ESG 215 T Hardener
(Contd. of page 4)
50. 0
616-47-7 1-methylimidazole 150 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
111-40-0 2,2'-iminodiethylamine
REL Long-term value: 4 mg/m , 1 ppm
Skin
TLV Long-term value: 4.2 mg/m , 1 ppm
Skin
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
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Trade name: ESG 215 T Hardener
(Contd. of page 5)
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Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Amber colored
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:198 C (388.4 F)
Flash point: 105 C (221 F)
Flammability (solid, gaseous):Not applicable.
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Ignition temperature: 325 C (617 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 1 Vol %
Upper: 10 Vol %
Vapor pressure at 20 C (68 F):0.5 hPa (0.4 mm Hg)
Density at 20 C (68 F): 1.06 g/cm (8.85 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic at 20 C (68 F): 150,000 mPas
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 4.7 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
111-40-0 2,2'-iminodiethylamine
Oral LD50 1,553 mg/kg (rat)
Dermal LD50 1,045 mg/kg (rabbit)
68479-98-1 diethylmethylbenzenediamine
Oral LD50 738 mg/kg (rat)
Dermal LD50 >2,000 mg/kg (rat)
616-47-7 1-methylimidazole
Oral LD50 1,400 mg/kg (mouse)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Toxic
Harmful
Corrosive
Irritant
Very toxic
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
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Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT NA2735
IMDG, IATA UN2735
UN proper shipping name
DOT Amines, liquid, corrosive, n.o.s. (Diethylenetriamine, m-
phenylenebis(methylamine))
IMDG AMINES, LIQUID, CORROSIVE, N.O.S.
(DIETHYLENETRIAMINE, m-phenylenebis(methylamine)),
MARINE POLLUTANT
IATA AMINES, LIQUID, CORROSIVE, N.O.S.
(DIETHYLENETRIAMINE, m-phenylenebis(methylamine))
(Contd. on page 10)
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Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG
Class 8 Corrosive substances
Label 8
IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards: Product contains environmentally hazardous substances:
diethylmethylbenzenediamine, Epoxy phenol novolac resin
Marine pollutant: Yes
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Segregation Code SG35 Stow “separated from” SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
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Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN “Model Regulation”: UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S.
(DIETHYLENETRIAMINE, M-
PHENYLENEBIS(METHYLAMINE)), 8, II, ENVIRONMENTALLY
HAZARDOUS
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
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Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
2,2′-iminodiethylamine
diethylmethylbenzenediamine
1-methylimidazole
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed or in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
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Specific treatment is urgent (see on this label).
Take off contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision03/03/2020 / 5
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Acute Tox. 2: Acute toxicity Category 2
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
* Data compared to the previous version altered.
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* 1 Identification
Product identifier
Trade name: SikaBiresin CH94-6 (L143 SLOW HARD)
Article number:I025959-4
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
4-tert-butylphenol
Polyoxypropylenediamine
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
(Contd. on page 3)
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 9046-10-0 Polyoxypropylenediamine 20-50%
CAS: 2855-13-2
EINECS: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamine 25- 50%
CAS: 25513-64-8
EINECS: 247-134-8
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 3-<5%
CAS: 98-54-4
EINECS: 202-679-0
4-tert-butylphenol 1-<3%
CAS: 1477-55-0
EINECS: 216-032-5
m-phenylenebis(methylamine) 1-<2.5%
CAS: 2579-20-6
EINECS: 219-941-5
1,3-Cyclohexanedimethanamine 1-5%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
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Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
9046-10-0 Polyoxypropylenediamine 4.8 mg/m
98-54-4 4-tert-butylphenol 1.5 mg/m
PAC-2:
9046-10-0 Polyoxypropylenediamine 53 mg/m
98-54-4 4-tert-butylphenol 40 mg/m
PAC-3:
9046-10-0 Polyoxypropylenediamine 320 mg/m
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98-54-4 4-tert-butylphenol 240 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
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The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light amber
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:232 C (449.6 F)
Flash point: 110 C (230 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 510 C (950 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 0.7 Vol %
Upper: 5 Vol %
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Vapor pressure: Not determined.
Density at 20 C (68 F): 0.92 g/cm (7.68 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Fully miscible.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 3.5 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
9046-10-0 Polyoxypropylenediamine
Oral LD50 2,855 mg/kg (rabbit)
Dermal LD50 2,980 mg/kg (rabbit)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Oral LD50 1,030 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rat)
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Primary irritant effect:
on the skin:Strong caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:
9046-10-0 Polyoxypropylenediamine
48 hr EC50 80 mg/l (daphnia)
96 hr LC50 772 mg/l (Fish)
72 or 96 hr ErC50 15 mg/l (Algea)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
96 hr LC50 110 mg/l (Fish)
NOEC 3 mg/l (daphnia)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
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Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
Recommended cleansing agent:Water, if necessary with cleansing agents.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1760
UN proper shipping name
DOT Corrosive liquids, n.o.s. (Polyoxypropylenediamine,
Isophoronediamine)
IMDG CORROSIVE LIQUID, N.O.S. (Polyoxypropylenediamine,
ISOPHORONEDIAMINE), MARINE POLLUTANT
IATA CORROSIVE LIQUID, N.O.S. (Polyoxypropylenediamine,
ISOPHORONEDIAMINE)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG
Class 8 Corrosive substances
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Label 8
IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances:
Polyoxypropylenediamine
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Hazard identification number (Kemler code):80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": U N 1 7 6 0 C O R R O S I V E L I Q U I D , N . O . S .
(POLYOXYPROPYLENEDIAMINE, ISOPHORONEDIAMINE), 8,
III, ENVIRONMENTALLY HAZARDOUS
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
75-56-9 propylene oxide
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 12)
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Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
4-tert-butylphenol
Polyoxypropylenediamine
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
m-phenylenebis(methylamine)
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision05/09/2020 / 1
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
(Contd. on page 13)
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NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Corr. 1A: Skin corrosion/irritation Category 1A
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Repr. 2: Reproductive toxicity Category 2
* Data compared to the previous version altered.
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* 1 Identification
Product identifier
Trade name: SikaBiresin CR94 (L140 Resin)
Article number:I026106-2
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Muta. 1B H340 May cause genetic defects.
Carc. 1B H350 May cause cancer.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) US
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Hazard pictograms
GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Stoddard solvent
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause genetic defects.
May cause cancer.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
1
0
Health = *2
Fire = 1
Reactivity = 0
(Contd. on page 3)
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 1675-54-3
EINECS: 216-823-5
bis[4-(2,3-epoxypropoxy)phenyl]propane 25- 50%
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 20-50%
CAS: 2425-79-8
EINECS: 219-371-7
1,4-bis(2,3-epoxypropoxy)butane 5-<10%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether 5-<10%
CAS: 8052-41-3
EINECS: 232-489-3
Stoddard solvent 0.1-1%
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
(Contd. on page 4)
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Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 39 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 16 mg/m
8052-41-3 Stoddard solvent 300 mg/m
PAC-2:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 430 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 170 mg/m
8052-41-3 Stoddard solvent 1,800 mg/m
PAC-3:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 2,600 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 220 mg/m
8052-41-3 Stoddard solvent 29500** mg/m
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* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
8052-41-3 Stoddard solvent
PEL Long-term value: 2900 mg/m , 500 ppm
REL Long-term value: 350 mg/m
Ceiling limit value: 1800* mg/m
*15-min
TLV Long-term value: 525 mg/m , 100 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 6)
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Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Off-white
Odor: Light
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:>200 C (>392 F)
Flash point: 112 C (233.6 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
(Contd. on page 7)
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Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.13 g/cm (9.43 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Fully miscible.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic at 20 C (68 F): 6,000-8,000 mPas
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.2 %
VOC content: 0.06 %
0.7 g/l / 0.01 lb/gal
Solids content: 0.8 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
(Contd. on page 8)
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Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
The product can cause inheritable damage.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
(Contd. on page 9)
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Recommended cleansing agent:Water, if necessary with cleansing agents.
* 14 Transport information
UN-Number
DOT NA3082
IMDG, IATA UN3082
UN proper shipping name
DOT Environmentally hazardous substance, liquid, n.o.s. (Epoxy Resin,
Epoxy phenol novolac resin)
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin, Epoxy phenol novolac resin), MARINE
POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin, Epoxy phenol novolac resin)
Transport hazard class(es)
DOT, IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT, IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: Epoxy
phenol novolac resin, Epoxy Resin
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Hazard identification number (Kemler code):90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
(Contd. on page 10)
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Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: No limit
On cargo aircraft only: No limit
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN, EPOXY PHENOL NOVOLAC
RESIN), 9, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
(Contd. on page 11)
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Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Stoddard solvent
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause genetic defects.
May cause cancer.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
(Contd. on page 12)
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Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:
Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision05/09/2020 / 1
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Muta. 1B: Germ cell mutagenicity Category 1B
Carc. 1B: Carcinogenicity Category 1B
* Data compared to the previous version altered.
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I ldentiJication
Product identifier
Trade name:F100 Medium Blue Polvol
Article number : I 02 2 7 2 9
Application of the substance / the mixture Polyurethane resin
Details of the supplier of the safety datu sheet
Sika Advanced Resins, US
EHS Department
M a nufa ctur e r/S upp lier :
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
a dv an c e dr e s in s. ehs
@us.
s ika. c o m
I nfo rm atio n dep artm e nt : P r o du ct s afety d ep ar t m en t
E m er ge ncy telep hone nam b er :
During normal opening times: + I (248) 588-2270
CHEMTREC 24-hour Emergency: +I (800) 424-9300
2 Hazard.(s) identffication
*
6;’:::::::’:::::^***
Carc. 2 H351 Suspected ofcausing cancer.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. I H304 May befatal if swallowed and enters airways-
Aquatic Acute 3 H402 Harmful to aquatic life.
Aquatic Chronic 3 H4I2 Harmful to aquatic liJb with long lasting elJ’ects-
Label elements
GHS tubet elements The product is clussified und labeled according to the Clobally Harmonized System (GHS).
Hazard pietograms
GHSOS
Signal word Danger
(Contd. on page 2)
US
o
BUILOING TRUST
Safety Data Sheet
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Page 2/13
Reviewerl on 0l /06/2020
P rintin g date 0 I /0 6/2 02 0
*
Trade nume: F|00 Medium Blue PolYol
Hazard-determining components of labeling:
Diis opropyl naphthalene
Blue reactive pigment
Solvent naphtha (petroleum), heavy arom.
ethylbenzene
Hazard statements
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
May befatal if swallowed and enters airways.
Harmful to aquatic life.
Harmful to aquatic life with long lastittg fficts.
Precautionary statem ents
Avoid breathing dus t/fu me/gas /mis t/v ap o rs /spray
Obtain special instructions before use-
D o not bre ath e dus t/fum e/ gas /mis t/v ap ors/s pray.
Avoid release to the environment.
Iy’ear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor.
Do NOT induce vomiting.
IF exposed or concerned: Get medicul udvice/uttentiott.
Get medical advice/attention if you.feel unwell.
Store locked up.
Dispose of coitents/contdinel in accortlurrce with local/regional/national/intemational regulations.
Classification system:
NFPA ratings (scale 0 – 4)
Health:0
Fire : l
Reactivity:0
HMlS-ratings (scale 0 – 4)
Health: 0
Fire: l
Reactittitlt :
0
Other hazards
Resalts of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
C hem ical c haracterizatio n : M ixt u re s
Description: Mixture of the substances listed below with nonhazardous additions.
(Contd. ofpage l)
(Contd. on page 3)
REACTTVTTYE
3 C omposition/inform utio non ingredients
US
BUILOIN6 TRUST
Printing datc 0 I /06/2020
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Page 3/1 3
Reviewed on 0l/06/2020
Trade nsme: F100 Medium Blue PolYol
Personal precautions, protective equipment and emergency procedures Mount respiratory protective device.
(Contd. on page 4)
{<
(Contd. ofpage 2)
Dangerous components:
cAS: 38640-62-9 Diis opropyl naphthalene s-t0%
cAS:25214-63-5 Alkoxylated amine
>5-<10t%
CAS:64742-94-5
EINECS:265-198-5
Solvent naphtha (petroleum), heavy arom' r-5%
Blue reactive pigment r-5%
cAS:9t-20-3
EINECS: 202-049-5
naphthalene 4.25-
(Jndetermincd.
290 “C (554’F)
Flammability (solid, gaseous): Not applicable’
D e co mp ositio n temq erstare : Not determined.
Product is not selJigniting
Auto igniting:
Danger of explosion: Product does not present an explosion hazard
Explosion limits
Lower:
Upper:
Not determined.
Not determined.
Not determined.
Vapor pressure:
Density at 20
oC
(68 “I):
Relative density
Vapor density
Evoporotion rate
1.64 g/cm’ (l 3.69 lbJgul)
Not determined.
Not determined.
Not determined.
Soluhility in / Miscibility with
lYater: Not miscible or dfficult to mix.
Partitiott coefficient (n-octanolhuatcr) : Not determined
l/iscosity:
Dynamic: Not determined.
(Contd. on page 7)
TJS
BUILNING TRUST
Pri n t i n.g dn te 0 I /06/2 020
Safe$ Datu Sheet
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Page 7/l 3
Rcvictcd on 0I/06/2020
Trade name: F100 Medium Blue Polyol
(Contd. ofpage 6)
Kinematic: Not determined.
Solvent content:
Organic solvents:
VOC content:
0.6 %
0.59 %
9.7 g/l / 0.08 lb/gal
Solids content:
Other information
66.0 %
No further
relevant information available.
10 Stability and renctivity
Reactivity No further
relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications
Possibility of hazardous reactions No dangerous reactions knowtt.
Conditions to avoid No.further relevant information available.
Incompatible materials: No further
relevant information available.
Hazardous decomposition products: Carbon monoxide and carbort dioxide
*
I nfo rm ation on toxico logic al effe cts
Acute toxicity:
I 1 Toxicological information
LD/LC|| values that are relevantfor classiJication
Oral LD5O 743 mg/kg (rat)
Primary irritant
on the skin: No ititant effect.
on the eye: No irritating ffict.
Sensitization: No sensitizing effects htown.
A dditio nal toxic olo gic al inform atio n :
The product shows the following dangers according to internally approved calculation -rrroit to,
(;:{r:.rr!r!ru!^!!’r,
3 8 64 0- 6 2-9 Diisopropyl n ap hth ale n e
Oral
Dermal
Inhalative
LD5O
LD5O
LC50/6 h (dynamic)
>4,000 mg/kg (rat)
>5.6 mg/l (ra) (Test Guideline 402)
000 mg/kg (mouse)
91-20-3 naphlhulene
LD5O
LD5O
490 mg/kg (ra)
5,000 mg/kg (ra)
Oral
Dermal
US
BUILIIING TRUST
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Rcviavcd on 0l/06/2020
*
Trade name: FI00 Medium Blue Polyol
Waste trcatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 9)
(Contd. of page 7)
Carcinogenic calegories
NTP (National Toxicology Program)
9 I -20-3naphthalene R
OSHA-Ca (Occupational Safety & Health Administration)
7 I -43-2benzene
IARC (International Agency for
Research on Cancer)
Zeo lit e (Crystal lin e a I umin o s ilic at e) 3
9 I -20-3naphthalene 2B
I 330-20-7xylene 3
I 2 E cological information
Aqaatic toxicity:
48ECsO
96 hr LC50
72 or 96 hr ErC50
3 naphthalene
mg/l (daphnia)
0.5 mg/l (Fish)
0.15 mg/l (Algea)
Toxicity
Persistence and degradability No rel ev ant information av ailab le.
Behavior in environmental systems :
B i o ac cu mul ativ e p ote n ti al N o
fu
r t h e r r e I e v a n t i nfo rmation av ail ab I e’
Mobiliry in soil No further
relevant information available.
Ecotoxical effects:
Remark: Harmful to fish
A d ditional e c olo gic al info r m ati o n :
General notes:
llater hazard class 2 (Self-asses.sment): hazardous for water
Do not allow product to rcuch ground water, wdter coutse ot sewage systent.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further
relevant information available.
I 3 Disposal conslderatlons
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Softty Duta Sheet
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Page 9/l j
Reviewed on 0l/06/2020
P t i n ti n g date 0 I /06/2020
Trade name: FI00 Medium Blue PolYol
(Contd. ofpage 8)
Uncleaned packagings:
Recommeidation: Disposal must be made according to official regulations.
*
1 4 Tr an sp ort inform atio n
UN-Number
DOT
IMDG,IATA
not regulated
uN3082
not regulated
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N. O. S. (Diis opropyl naph thal en e), MA N N E P O LLUTA NT
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID’
N. O. S. (Diis opropyl naphthalene)
IATA
UN proper shipping name
DOT
IMDG
not regulated
IMDG,IATA
CIass
Label
9 Miscellaneous dangerous substances and articles
9
Transport hazard class(es)
DOT
Class
Packing group
DOT
IMDG,IATA
not regulated
III
Environmental hazards :
hlarine pollutant:
Special marking (IATA)
Product contains environmentally hazardous substances
D ii s op r o py I n aph th al en e
Yes
Symbol (fish and tree)
Symbol (/ish and tree)
Speciol precautions for
user
EMS Number:
Stowage Category
Warning : Miscellaneous dangerous substances and articles
F-A,S-F
A
Tronsport in bulk according to Annex II of
MARPOLT3/78 antl the IBC Code Not applicable.
(Contd. on pagc l0)
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BUILNIN6 TRUST
Safe$ Datu Sheet
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Page l0/13
Reviewed on 01/06/2020
P rinting datc 0 I /0 6/2 02 0
Trade name: FI00 Medium Blue PolYol
(Contd. ofpage 9)
5L
Code: El
Maximum net quantity per inner packaging: j0
ml
Maximum net quantity per outer packaging: 1000 ml
T r an sp o t/A ddit io nal info r m at i o n :
IMDG
Limited quantities (LQ)
Excepted quantities (EQ)
UN 3OS2 ENVIRONMENTALLY HAZARDOUS SUBSTANCE’
LrQUrD, N.O.S. (DIISOPROPYL NAPHTHALENE), 9, III
UN “Model Regulation”:
I 5 Re ga lat o ry info rm atio n
*
Safety, health and environnrental regulations/legislation speciiic for
the substance or mkture
Sara
xylene
A
TSCA (Toxic SabstancesControl Act):
CalciumI37-65-3
A
Fibrous6s997-1 7-3
ACTII/E
Polyether35176-
CTIVE
Diisopropyl38640-62-9
ACTIVE
amme2s2 r 4-63-5
ACTIVE
64742-94-5 naphtha arom.
ACTIVE
e
CTIVE
Blue reactive pigmenl
naplfihalene9 I-20-3
A
I acid, l ester
ACTIYE
CTIYE
xyleneI 330-20-7
CTIVE
t I 1-46-62,
ACTIVE
I 47- I 4-8 ocyanine Blue
Section 355 (extremelY hazardoussubstances):
ingredients isNone
Section 313 (SpeciJic toxicchemical listings):
naphthalene91 -20-s
I 3i0-20-7
C’hemicals regulated by TSCA Section I2(b)
ingredients is listed.None
(Contd. on page
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Printing datc 0 I /06/2 02 0
Chemical regulated by TSCA 5(a)(2)rule:
ingredients is listed.None
Trade name: FI00 Medium Blue PolYol
(Contd. ofpage l0)
Proposition 65
Carcino genic categories
NIOSH-Ca Institute for Occupational Sofnty and Health)
GHS label elements The Product
is
Hazard pictograms
(GHS)
@
(Contd. on page 12)
Hazardous Air Pollutants
naphthalene9I
xyleneI s30-20-7
I 00-4 I -4 e
Chemicals known to cause cancer:
r 3 I 7-65-3 Carbonate
9 r -20-3
I 4808-60-7Quartz
100-41-4ethylbenzene
98-82-8cumene
benzene7-43-2
icals known to cause reproductive toxicity for fem
ales:
None of the ingredients is
Chcmicals known to csuse reprotluctive. toxicity for
males:
I -43-2benzene
Chemicals known to cuuse developmental toxicity:
7 1 -43-2benzene
I 08-88-3toluene
EPA (Environmental Protection Agency)
CBD
9 I -20-3
9 I -20-3
TLV (Threshold Limit Value established byACGIH)
e ingredients is listedNone
None ingredients is
Listed in CIYC Regulations
GHSOS
and to the Globally Harmon
rts
.:,
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Printing datc 0 I /06/2 02 0
Silfety Data Shee.t
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Page l2/13
Reviewed on UIi06/2020
Trade name: FI00 Medium Blue PolYol
(Contd. ofpage I l)
Signal word Danger
H azar d-d eterm i ning c o mp o nents of I ab elin g :
Diis opropy I naphthalene
Blue reactive pigment
Solvent naphtha (petroleum), heavy arom.
ethylbenzene
Hazard statements
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
May befatal if swallowed and enters airways.
Harmful to aquatic life.
Harmful to aquatic life with long lasting fficts.
Precautionary statements
Obtain special instructions before use.
Do not breathe dust/fume/gas/mist/vapors/spray.
Avoid release to the environment.
Ll/ear protective gloves/protective clothing/eye protection/fuce protection.
If swallowed: Immediately call a poison center/doctor.
Do NOT induce vomiting.
IF exposed ur cuncerned: Get medical advice/attentiott.
Get medical advice/attention if youfeel unwell’
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regttlatiotts
Chimical safety assessn ent: A Chemical Safety lsscssment has not been canied ottt.
16 Other information
This information is based on our present lcnowledge. However, this shall not constitute a guarantee
specffii productfeatures and shall not establish a legally valid contractual relationship.
Date ofpreparation / last revision 0l/06/2020 / 5
Ab breviation s an d acr o ny m s :
II(DG : Internalional Arsritime Code for
r-lon gerous Gnnd s
DOT: US Department of Transporlation
I AT,4 : Intarnational,4ir Transport .Association
ACGIH : American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercisl Chemical Substances
ELINCS: European List ofNotified Chemical Substances
CAS: Chemical Abstracts Serttice (division ofthe American Chemical Society)
NFPA: National I’ire Protection Association (USA)
HMIS: Hazardous Mateials Identification System (USA)
VOC: Volatile Organic Compounds (USA, !)U)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose. 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSII: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
for
any
(Contd. on page 13)
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Ssfe$ Datu Sheet
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Pinting date 0 I /06/2020
Reviewed on 01/06/2020
Trade nume: F100 Medium Blue PolYol
(Contd. ofpage 12)
PEL: Permissible Exposure Limit
Carc. 2 : Carcinogenicity – Category 2
STOT RE 2: SpeciJic target organ toxicity (repeated atposure) – Category 2
Asp. Tox. 1: Aspiration hazard –
Category I
Aquatic Acute 3: Hazardous to the aquatic environmenl – acute aquatic hazard – Calegory 3
Aquatic Chronic 3: Hazardous to thi aquatic environment – Iong-term aquatic hazard –
Category 3
*
Data compared to the previous version altered.
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I ldenffication
Product identifier
Trade name: Fl00 Part B ISO
Article number: 102 I 125
Application of the substance / the mkture Polyurethane resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
M anufactu r e r/S upp I i e r :
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 4807 l
USA
ehs-us@axson.com
I nfo rm ati o n d ep artm e n t : P r o du ct s afety d ep ar tm e n t
Em ergency telep hone num b er :
During normal opening times: + I (248) 588-2270
CHEMTREC 24-hour Emergencv: *l (800) 424-9300
2 Hazard.(s) idenffication
Classification of the substonce or mkture
@
GHS’B Heatth hazard
Resp. Sens. I
Carc. 2
STOT RE 2
H334 May cause allergy or asthma symptoms or breathing dfficulties if inhaled.
H35l Suspected ofcausing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
CHSOT
Acute Tox. 4 H332 Harnlful if inhaled.
Skin lrrit. 2 II3I5 Causes skin irritation.
Eye lrrit. 2A H3l9 Causes serious eye irritation.
Skin Sens. I H3 17 May cause an allergic skin reaction.
STOT SE 3 H3 j5
May cause rcspiratory irritation
Aquattc Acute 3 H402 Hurmful to uquatic life.
Label elements
GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2)
I
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Printing date 0I /06/2020
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Reviewed on 0l /06/21)20
!
‘I’rade
name: h’|00 Part B ISO
(Contd. ofpage l)
Hozard pictograms
GHSOT GHSO8
Signal word Danger
H azard-determining components of labeling:
diph enylmethane diis o cy anate,is omeres and homo lo gue s
4, 4′ – me thy lene dip heny I diis o cyana te
Diisopropyl naphthalene
Hazard statements
Harmful if inhaled.
Causes skin initation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing dfficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing cdncer.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Harm.ful to aquatic life.
Precautionary statem ents
Avoi d b re athin g dus t/fume/gas/mis thaporshpray
D o n o t b r e at h e du s t/fum e/ gas /mis t/v ap o rs /sp r ay.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case ofinadequate ventilationJ wear respiratory protection.
IF INHALED: Remove person tofresh air and keep comfortablefor breathing.
If in eyes: Rinse cautiously with waterfor several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if youfeel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
ILrash contanrinated clotldtrg before reuse.
Store locked up.
Dispose ofcontents/container in accordance with local/regional/national/international regulations.
ClassiJic ation system :
NFPA rutings (scale 0 – 4)
Health: 2
Fire : I
Reactivity :
0
HMlS-ratings (scale 0 – 4)
Health:
*2
Fire : I
Reactivity – 0
(Contd. on page 3)
REACTIVITY
HEALTH
FIRE
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*
Trade name: F100 Part B ISO
(Contd. ofpage 2)
Other hazards
Resalts of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
3 Composition/information on ingredients
Chemicul characterization : Mixtures
Description: Mixture of the substances listed below with nonhazardous additions
Dangerous components:
CAS:9016-87-9 dipheny lmethanediis o cy an ate,is omeres an d homo lo gues 10-20%
CAS: 101-68-8
EINECS: 202-966-0
4, 4′-methy I enedip heny I diis o cyanat e I0-20%
CAS: 38640-62-9 Diis opropyl naphthalene 5-10%
CAS: 64742-47-8
EINECS: 265-149-8
Kerosine – unspecified t-5%
CAS: 100-41-4
EINECS: 202-849-4
ethylbenzene 0.1-I%
Description oflirst aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical obsemation for at least 48 hours
after the accident.
After inhalation:
Supplyfresh air and to be sure callfor a doctor.
In case ofunconsciousness place patient stably in side positionfor transportation.
Afier skln corrtact: Immediutely wush with water and soap and rinse thoroughly.
After eve contact:
Rinse opened eye for
several minutes under running water. lf symptoms persist, consult a doctor.
After swallowing: If symptoms persist consult doctor.
I nform ation fo r do cto r :
triost important symp16^t ond effects, both ocutc and delayed No further
relevant information available.
Indication of any immediate medical attention anil special tteatment needed
No further
relevant information available.
US
4 First-aid measures
(Contd. on page 4)
BUILOING TRUST
Printing date 0 I /06/2 020
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Puge 4/l 4
Revieu,ed on 0 I /06/202 0
*
Trade name: F|00 Part B ISO
(Contd. ofpage 3)
Personal precautions, protcctivc cqaipment and emergency procedures Mount respi.ra.tory prote.ctive device.
E nv ir o n m e ntal p re cautio ns :
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case ofseepage into water course or sewage syste/n.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with tiquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item I 3.
Ensure adequ ate v entilati on.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section I j
Jbr
disposal information.
Protcctivo ,4ction Criteria for Chemicsls
5 Fire-Jighting measures
Extinguishing media
S uitable exting uis hin g age nts :
CO2, extinguishing powder or water spray. Fight largerfires with water spray.
Use fire fighting
measures that suit the environment.
Special hazards arisingfrom the suhstance or mixture
During heating or in case offire poisonous gases are produced.
Nitrogen oxides Q,{Ox)
Hydrogen cyanide (HCN)
Advice for fireftghters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional inform ation
Dispose offire debris and contaminated fire fighting
water in accordance with official regulations.
6 Accidental release ,neasures
PAC-|:
90r 6-87-9diphenylmethan ediis o cy anate,is omeres and homolo gu es 0.15 mg/m3
I 0 r -68-84, 4′ -methylenediphery I diis o qt anat e 0.45
38640-62-9Diisopropy I naphtha lene 5.6 mg/m’
100-41-4ethylbenzene 3j ppm
PAC-2:
e0 I 6-87-9diphenylmethan ediis o cy ana t e, is omeres and homo logues 3.6 mg/m’
I 0 1 -68-84, 4′ -methyl enedipheny I diis o cyanate 5 mg/m3
38640-62-9Diisopropyl naphthalene 61 mg/m3
on page
tts
ri
BUILDIN6 TRUST
Printing date 0 I /06/2 02 0
Sofrty Data Sheet
scc. to OSHA HCS
Pagc 5/14
Rewewed on 0lt’06/2020
,k
Trade name: h’|00 Part B ISO
of 4
I I 00* ppm
ethylbenzeneI 00-4 I -4
PAC-3:
22 mg/m’
dip henylmethan ediis o cy ana te, is omeres and homo lo gues901 6-87-9
55 mg/m’
r 0 I -68-84, 4′ -methyl enedipheny I diis o cy anat e
370 mg/m’
38640-62-9D ii s o p r o py I n aphth al en e
I 800* ppm
I 00-4 I -4ethylbenzene
Additional information about design of technical systems: Nofurther data; see item 7.
Control parameters
Components htith limit values that require monitoring at the workplace:
The foltowing
constituents are the only constituents of the product which have a P EL, TLV or other recommended
exposln’e linit.
At this time, the other constituents have no lorcwn exposure limits.
I 0 1 – 6 8- 8 4,4′ -m ethylene dip henyl diis o cy an ate
7 Handling and storage
Handling:
Precautions for
safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation
of aerosols.
Information about protection against explosions and fires:
Keep respiratory protective device available.
Conditions for
safe storage, including any incompatibilities
Storage:
Requirements to be met by Storerooms and receptacles: No special requirements.
Informatiort about storage in one contnton storagefacility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Spectfic end use(s) No further
relevant information available.
8 Exposure controls/persona,l protection
TLI/
PEL
REL
Ceiling limit value: 0.2 mg/m3, 0.02 ppm
Long-term value: 0.05 mg/m3, 0.005 ppm
Ceiling limit value: 0.2* mg/m3, 0.02* ppm
*10-min
Long-term value: 0.05 I mg/m3, 0.005 ppm
100-41-4 ethylbenzene
PELLong-term value: 435 mg/m3, 100 ppm
on page
lIs
BUILDIf,I6 TRUST
Printirtg date 0 I /06/2 02 0
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Page 6/14
Reviewed on U l/Ub/2020
Trade name: FI00 Part B ISO
Additional information: The lists that were during the creation were as basis
Exposure contrcls
P erso nal protective equip m ent :
General protective and hygienic measures:
Ke ep aw ay
fr”onr fo
o d s tuffs, b ev cr a g c s an d
fe
e d.
Immediately remove ull soiled and contaninated clotlting.
Wash hands before breal 140 “C (>284 “F)
(Jndetermined.
t90 “c (374 “F)
Not applicable.
400 “c (752’F)
Flantm ab ility (s oli tl, g as e o u s) :
Ignition temperature:
D e c o mp o sitio n te mp e r ature Not determined.
Auto igniting: Product is not seffigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower:
Upper:
0.4 Vol %
Not determined.
Vapor pressure at 20 “C
(68 oF):
U hPa
Density at 20
oC
(68
“F):
Relative density
Vapor density
Evaporation rate
I .73 g/cm3 (1a.a4 lbs/gal)
Not determined.
Nut leternined.
Not determined.
Solubility in / Miscibility with
ll/ater: Not miscihle or dfficult to mix.
Partition c oeffi cient ( n -octanol/water) : Not determined.
(Contd. on page 8)
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tt
BUILIIING TRUST
Printing date 0 1 /06/2 02 0
Sof”A Datu Sheet
acc. to OSH,4 HCS
Page 8/l 4
Reviev,ed on 0 I /06/2020
Trade name: Fl00 Part B ISO
I nform ation on toxicological effe cts
Acute toxicity:
Primary iwitant effect:
on the skin: Irritant to skin and mucous membranes.
(Contd. on page 9)
(Contd. ofpage 7)
Viseosity:
Dynamic at 20
oC
(68 “F):
Kinematic at 40 “C
(104 “F):
200 mPas
100 mm’z/s
Solvent content:
Organic solvents:
VOC content:
0.6 %
0.57 %
9.9 g/l / 0.08 lb/gal
Solids content:
Other information
89.9 %
No further
relevant information available.
10 Stability and reaetivity
Reactivity No further
relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
P o ssibility of h azardo u s re actio ns
Violent reactions with -NHx, -OH and -SH- groups.
In the presence of water or humidity gas (CO2) is porduced and/or uncontrolled polymerization, possibly leading
to internal pressure rises and conscqucnt risk ofcontainer breach.
Conditions to avoid Nofurther relevant infonnation available.
Incompatible materials: No further
relevant information available.
H azar do us de c o mp o siti on pro du cts :
Nitrogen oxides
Carbon monoxide and carbon dioxide
(possible HCN)
I 1 Toxicolo gical inform atio n
LD/LC|| vulues thul are rclcvanlfor classiJicatiort:
I 0 1 – 6 8 – 8 4,4′-m ethylene dip henyl dii so cy an ate
Oral
Dermul
LD5O
LD5O
2,200 mg/kg (mouse)
>9,400 mg/kg (rabbit)
3 8 6 4 0- 6 2 -g Di isopropyl n ap hth ale ne
Oral
Dennal
Inhalative
LD5O
LD5O
LC50/6 h (dynamic)
>4,000 mg/kg (mouse)
>4,000 mg/kg (rat)
>5.6 mg/l (rat) (Test Guideline 402)
US
BUILUIN6 TRUST
Printing date 0 I /06/2020
SafeA Datu Sheet
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Puge 9/14
Revi euted on 0 I /06/2 02 0
Trade name: Fl00 Part B ISO
(Contd. ofpage 8)
on the eye: Irritating effect.
Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
Additional toxicological inform ation:
The product shows thefollowing dangers according to internally approved calculation methods for
preparations
Harmful
Irritant
Carcinogenic categories
NTP (National Toxicology Program)
None of the ingredients is
OSHA-Ca (Occupational Sqfety & Health Administration)
7 I -43-2benzene
IARC (International Agency for
Research on Cancer)
901 6-87-9 is omeres and homologues 3
r 0 I -68-84, 4′ -methylenedipheny I di is o cy an a t e 3
Zeolite (Crystalline aluminosilicate) 3
I 3463-67-7titanium dioxide 2B
I 330-20-7xylene
3
I 00-4 I -4ethylbenzene
2B
I 2 Ecological information
,t
Toxicity
Persistence and degradability relevant information avai
Behavior in environm ental systems :
Bioaccumulative potential No.further relevant information available.
Mobility in soil No further
relevant information available.
Additio nal eco logic al info rm atio n :
General notes:
Water hazard class I (Self-a,s,ses,sment): ‘slightly
hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water cou/se or sewage system.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
(Contd. on page l0)
Aquatic toxicity:
3 8 6 4 0- 6 2-9 Diisopropyl n ap hth ale ne
48 hr EC50
96 hr LC50
72 ur 96 hr ErC50
0.16 mg/l (daphnia)
0.5 mg/l (Fish)
0.15 rng/l (Algea)
US
BUILOINC TRUST
Printing date 0 I /06/2020
Snfety Dote Sheet
acc. to OSHA HCS
Page l0/14
Revie.wcrl on 0 I /06/202 0
Trade name: F|00 Part B ISO
(Contd. ofpage 9)
Other adverse effects No further
relevant information available.
1 3 Disposal considerations
ll/aste treatment m ethods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to fficial
regulations.
:t
I 4 Transport inform ation
UN-Number
DOT
IMDG,IATA
not regulated
uN3082
UN proper shipping name
DOT
IMDG
not regulated
ENVIRONMENT’ALLY HAZARDO US SUBSTANCE, LIQU]D,
N. O. S. (Diisopropyl naphthalene), MANNE POLLUTANT
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, L]QLUD,
N. O. S. (Diis opropyl naphthalen e)
IATA
Transport hazard class(es)
DOT
Class not regulated
IMDG,IATA
CIttss
Label
9 Miscellaneous dangerous substances and articles
9
Packing group
DOT
IMDG,IATA
not regulated
ilI
Environmental hazards :
Marine pollutant:
Special marking (IATA) :
Product contains environmentally hazardous substances
Diisopropyl naphthalene
Yes
Symbol (fish and tee)
Symbol (fish and tree)
(Contd. on page I I )
US
BL’ILilII’Jfi TRUST
P rinting date 0 I /0 6/2 0 2 0
Safe$ I)ats Sheet
scc- to OSHA HCS
Page I l/14
Hewewed on 0l/06/’2020
Trade name: FI00 Part B ISO
(Contd. ofpage l0)
Special prccautions for user
Danger code (Kemler):
EMS Number:
Stowage Category
Warning: Miscellaneous dangerous subslances and article.g
90
F-A,S-F
A
Transport in bulk according to Annex II of
MARPOLT3/78 and the IBC Code Not applicable
Tr an sp ort/A ddition al inform atio n :
IMDG
Limited quantities (LQ)
Excepted quantities (EQ)
5L
Code: EI
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulationt’ UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LrQUrD, N.O.S. (DIISOPROPYL NAPHTHALENE), 9, III
1 5 Regulatory inform atio n
i.
Safety, health snd environmental regulations/legislation speciJic for
the suhstance or mixture
Sara
Section 3 5 5 (extremely hazardous substances) :
None of the ingredients is listed.
on page I 2)
Section 313 (Specific toxic chemical listings):
90 r 6-87-9dip heny lmeth an ediis o cy anate, i s omeres and homolo gue s
I 0r -68-84, 4′ -methyl en ediphenyl diis o cy an ate
I 330-20-7xylene
I 00-4 I -4ethylbenzene
TSCA (Toxic Strbstsnces Control Act):
65997- I 7-3Fibrous Glass
diphenylm ethan ediis o cy anate,is om eres and homo I o gu es
ACTIVE
901 6-87-9 ACTIVE
I 0 r -68-84, 4′ -methylenedipheny I diis o cy anate ACTIVE
38640-62-9Diis opropyl naphthalene ACTIVE
Zeolite (Crystalline aluminosilicate) ACTIVE
64742-47-8Kerosine – unspecified ACTIVE
I 3463-67-7titanium dioxide ACTIVE
64742-94-5Solvent naphtha (petroleum), heavy arom. ACTIVE
6861 I-44-9Silane, dichlorodimet hy l-, reaction products with silic a ACTIVE
I 3 30-20-7xylene ACT]VE
US
BUILNING TRUST&
Printing date. 0 I /06/2020
Sofety Data Sheet
scc. to OSHA HCS
Page I2/14
Rcviewed on 0I/06/2020
Trade name: F100 Part B ISO
of
P o lyme thy I a I lry I s i I ox an e ACTIVE
I 00-4 I -4ethylbenzene ACTIVE
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule
None oJ’the ingredients is listed.
Hazardoas Air Pollutants
I 0 I -68-84, 4′-methylened iphenyl d i is ocya na t e
I 330-20-7xylene
I 00-4 I -4ethylbenzene
9 I -20-3naphthalene
Proposition 65
Chemicals known to cause csncer:
I 3463-67-7titanium dioxide
I 00-4 I -4ethylbenzene
9 r -20-3naphthalene
7 I -43-2benzene
Chemicals known lo cause rcproiluclive loxicity for femules:
None of the ingredients i.s listed.
Chemicals known to csuse reproductive toxicity for
males
7 I -43-2benzene
Chemiculs known to cause developmental toxicity:
7 I -43-2benzene
r 08-88-3toluene
Carcinogenic categories
EPA (Environm ental Protection Agency)
90r 6-87-9diphenylmethanediisocyanulc,isunrcrcs und lnrtulugucs CBD
I 01 -68-84, 4′ -methyl enediph eny I diis o cy an ate D, CBD
100-41-4ethylbenzene D
TLV (Threshold Limit Value established by ACGIH)
I 00-4 r -4ethylbenzene A3
NIOSH-Ca (National Institute for Occuputional Safety and Health)
I 3463-67-7titanium dioxide
is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page l3)
Listed in CIYC Regulations
None of the ingredients is listed
GHS label elements
US
BUILDINC TRUST
Printing date u I /u 6/2 u 2 u
So.fety Data Shee.t
occ. to OSHA HCS
Page I 3/14
R eviewerl. on
(
) I /0 6/ 2 0 2.
(
)
Trade name: F|00 Part B ISO
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specifc productfeatures and shall not establish a legally valid contractual relationship.
Date. ofpreporstion / lssl revision 0l /06/2020 / 5
Ab breviatio tts an d ac rony ms :
IMDG: hternational Maritine Codefor Dangetous Goods
DOT: US Department of Transporlation
IATA: International Air Transport Association
ACGIH: Arnerican Conference of Governmental Industrial Hygienists
(Contd. on page l4)
t
(Contd. ofpage 12)
Hazard pictograms
GHSOT GHSO8
Signal word Danger
Hazard-determining components of Iabeling:
dip h eny lm et hane dii s o cy anat e, is o meres and homo lo gues
4, 4′ -me t hy I e n e dip he ny I d iis o cy anate
Diis opropy I n aphthalene
Hazard statements
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing dfficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause rcspirator,, iftitation.
May cause damage to organs through prolonged or repeated exposure.
HarmJill to aquatic liJb.
Pre caution ary statem ents
D o n o t b r e a t h e d u s t /fr.m e /g a s /mi s t/v ap o rs /s pr ay.
Wear protective gloves/protective clothing/eye protection/face protection.
fin case of inadequate verxtilation| wear respiratory protection.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiottsly with waterfor several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poisott center/doctor if you feel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
LYash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical saJety assessment: A Chemical Sajbty Assessment has not been carried out.
16 Other information
US
BUILDING TRUST
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Safety Data Sheet
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Rewewed on 01/06/2020
Trade name: Fl00 Part B ISO
EINECS: European Inventory of Existing Commercial Chemical Substances
(Contd. ofpage 13)
CAS: Abstracts Service (division ofthe American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials ldentiJication System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NI OSH : National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
kEL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Acute Tox. 4: Acute toxicity –
Category 4
Skin lrrit, 2: Skin corrosion/irritation –
Category 2
Eye lrrit. 2A: Sertous eye damageleye irritation –
Category 2A
Resp. Sens, 1 : Respiratory sensitisation –
Category I
Skin Sens. I : Skin sensitisation –
Category I
Carc. 2: Carcinogenicily –
Category 2
STOT SE 3: SpeciJic target organ toxicity (single acposure) – Category 3
STOT RE 2: Specifc target organ toxicity (repeated exposure) –
Category 2
Aquatic Acute j:
Hazardous to the oquetic enrironment – acute dquatic hazard –
Category 3
*
Data compared to the prcvious version sltercd.
US
80607389_SDS.pdf
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Safety Data Sheet
acc. to OSHA HCS
Printing date 05/11/2020 Reviewed on 05/11/2020
51.0.8
* 1 Identification
Product identifier
Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
Article number:I025953-1
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07
Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Reaction Product of Bisphenol A and Epichlorohydrin
(Contd. on page 2)
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Safety Data Sheet
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Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
(Contd. of page 1)
51.0.8
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
(Contd. on page 3) US
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Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
(Contd. of page 2)
51.0.8
Dangerous components:
CAS: 1675-54-3
EINECS: 216-823-5
bis[4-(2,3-epoxypropoxy)phenyl]propane 25- 50%
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 20-50%
CAS: 2425-79-8
EINECS: 219-371-7
1,4-bis(2,3-epoxypropoxy)butane 5-<10%
CAS: 68609-97-2
EINECS: 271-846-8
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether 5-<10%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
(Contd. on page 4)
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Safety Data Sheet
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Printing date 05/11/2020 Reviewed on 05/11/2020
Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
(Contd. of page 3)
51.0.8
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 39 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 16 mg/m
PAC-2:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 430 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 170 mg/m
PAC-3:
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 2,600 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 220 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
(Contd. on page 5)
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Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
(Contd. of page 4)
51.0.8
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
US
(Contd. on page 6)
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Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
(Contd. of page 5)
51.0.8
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Translucent
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:266 C (510.8 F)
Flash point: 112 C (233.6 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.14 g/cm (9.51 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Fully miscible.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.1 %
VOC content: 0.08 %
0.9 g/l / 0.01 lb/gal
Solids content: 0.0 %
(Contd. on page 7)
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Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
(Contd. of page 6)
51.0.8
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1675-54-3 bis[4-(2,3-epoxypropoxy)phenyl]propane 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
(Contd. on page 8)
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Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
(Contd. of page 7)
51.0.8
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
Recommended cleansing agent:Water, if necessary with cleansing agents.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy Resin)
Transport hazard class(es)
DOT
Class not regulated
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
(Contd. on page 9)
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Trade name: SikaBiresin CR86 (PROINFUSION RESIN)
(Contd. of page 8)
51.0.8
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: Epoxy
Resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Hazard identification number (Kemler code):90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY RESIN), 9, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
(Contd. on page 10)
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Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07
Signal wordWarning
Hazard-determining components of labeling:
bis[4-(2,3-epoxypropoxy)phenyl]propane
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Alkyl C12-C14 Glycidyl Ether
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
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Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision05/11/2020 / 8
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
* Data compared to the previous version altered.
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* 1 Identification
Product identifier
Trade name: SikaBiresin CH138-10 (PROINFUSION HT HARD)
Article number:I025950-1
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Tox. 3 H311 Toxic in contact with skin.
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
(Contd. on page 2)
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GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
2,2′-dimethyl-4,4’methylenebis(cyclohexylamine)
3-aminomethyl-3,5,5-trimethylcyclohexylamine
2-ethyl-4-methylimidazole
Hazard statements
Harmful if swallowed.
Toxic in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment is urgent (see on this label).
Take off immediately all contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 3)
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Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
3
1
0
Health = 3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 6864-37-5
EINECS: 229-962-1
2,2′-dimethyl-4,4’methylenebis(cyclohexylamine) 50-1 00%
CAS: 2855-13-2
EINECS: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamine 10-20%
CAS: 931-36-2
EINECS: 213-234-5
2-ethyl-4-methylimidazole 1-5%
CAS: 822-36-6
EINECS: 212-497-3
4-methylimidazole 0.1-1%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
(Contd. on page 4)
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After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
6864-37-5 2,2′-dimethyl-4,4’methylenebis(cyclohexylamine) 0.28 mg/m
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822-36-6 4-methylimidazole 10 mg/m
PAC-2:
6864-37-5 2,2′-dimethyl-4,4’methylenebis(cyclohexylamine) 3.1 mg/m
822-36-6 4-methylimidazole 110 mg/m
PAC-3:
6864-37-5 2,2′-dimethyl-4,4’methylenebis(cyclohexylamine) 19 mg/m
822-36-6 4-methylimidazole 150 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
(Contd. on page 6)
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Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Amber colored
Odor: Ammonia-like
Odor threshold: Not determined.
pH-value at 20 C (68 F): 11
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:1,013 C (33.813 F)
Flash point: 140 C (284 F)
Flammability (solid, gaseous):Not applicable.
(Contd. on page 7)
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Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.94 g/cm (7.84 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Fully miscible.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 4.0 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
6864-37-5 2,2′-dimethyl-4,4’methylenebis(cyclohexylamine)
Oral LD50 320-460 mg/kg (rat)
Dermal LD50 200-400 mg/kg (rabbit)
Inhalative LC50/4 h 0.42 mg/l (rat) (Test Guideline 402)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Oral LD50 1,030 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rat)
931-36-2 2-ethyl-4-methylimidazole
Oral LD50 250 mg/kg (mouse)
1,000 mg/kg (rat)
Dermal LD50 >400 mg/kg (rabbit)
Primary irritant effect:
on the skin:Strong caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Toxic
Harmful
Corrosive
Irritant
Very toxic
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
822-36-6 4-methylimidazole 2B
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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* 12 Ecological information
Toxicity
Aquatic toxicity:
6864-37-5 2,2′-dimethyl-4,4’methylenebis(cyclohexylamine)
48 hr EC50 15.2 mg/l (daphnia)
96 hr LC50 45 mg/l (Fish)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
96 hr LC50 110 mg/l (Fish)
NOEC 3 mg/l (daphnia)
931-36-2 2-ethyl-4-methylimidazole
96 hr LC50 >46 mg/l (Fish)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
Recommended cleansing agent:Water, if necessary with cleansing agents.
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* 14 Transport information
UN-Number
DOT, IMDG, IATA UN2922
UN proper shipping name
DOT Corrosive liquids, toxic, n.o.s. (Cycloaliphatic Amine)
IMDG CORROSIVE LIQUID, TOXIC, N.O.S. (Cycloaliphatic Amine),
MARINE POLLUTANT
IATA CORROSIVE LIQUID, TOXIC, N.O.S. (Cycloaliphatic Amine)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8, 6.1
IMDG
Class 8 Corrosive substances
Label 8/6.1
IATA
Class 8 Corrosive substances
Label 8 (6.1)
Packing group
DOT, IMDG, IATA II
Environmental hazards: Product contains environmentally hazardous substances:
Cycloaliphatic Amine
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Hazard identification number (Kemler code):886
EMS Number: F-A,S-B
(Contd. on page 11)
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Stowage Category B
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 0.5 L
On cargo aircraft only: 2.5 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 0
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
UN “Model Regulation”: U N 2 9 2 2 C O R R O S I V E L I Q U I D , T O X I C , N . O . S .
(CYCLOALIPHATIC AMINE), 8 (6.1), II, ENVIRONMENTALLY
HAZARDOUS
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
822-36-6 4-methylimidazole
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Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
2,2′-dimethyl-4,4’methylenebis(cyclohexylamine)
3-aminomethyl-3,5,5-trimethylcyclohexylamine
2-ethyl-4-methylimidazole
Hazard statements
Harmful if swallowed.
Toxic in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
(Contd. on page 13)
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If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment is urgent (see on this label).
Take off immediately all contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision05/11/2020 / 8
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Acute Tox. 3: Acute toxicity Category 3
Acute Tox. 2: Acute toxicity Category 2
Skin Corr. 1A: Skin corrosion/irritation Category 1A
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
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* 1 Identification
Product identifier
Trade name: SikaBiresin AP014 (A) White
Article number:660963-2
Application of the substance / the mixturePolyester filler
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
advanced.resins.ehs@us.sika.com
Manufacturer/Supplier:
Manufacturer:
Sika Advanced Resins
30800 Stephenson Hwy
Madison Heights
MI 48071
USA
Information department:Product safety department
Emergency telephone number:
During normalopening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flammable Liquids 3 H226 Flammable liquid and vapor.
GHS08 Health hazard
Carcinogenicity 1B H350 May cause cancer. Route of ex posure: Inhalation.
Toxic to Reproduction 2 H361 Suspected of damaging fe rtility or the unborn child.
Specific Target Organ Toxicity – Repeated Exposure 1 H372 Causes damage to the hearing organs through
prolonged or repeated exposure.
GHS07
Skin Irritation 2 H315 Causes skin irritation.
Eye Irritation 2A H319 Causes serious eye irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS02GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
Styrene
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause cancer. Route of exposure: Inhalation.
Suspected of damaging fertility or the unborn child.
Causes damage to the hearing organs through prolonged or repeated exposure.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use CO2, powder or water spray to extinguish.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 3)
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Classification system:
NFPA ratings (scale 0 – 4)
2
3
0
Health = 2
Fire = 3
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
3
0
Health = *2
Fire = 3
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 100-42-5
EINECS: 202-851-5
Styrene 10-20%
* 4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
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* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
100-42-5 Styrene 20 ppm
PAC-2:
100-42-5 Styrene 130 ppm
PAC-3:
100-42-5 Styrene 1100* ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
(Contd. on page 5)
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Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away – Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
100-42-5 Styrene
ACGIH TLV Short-term value: 170 at 40 ppm mg/m
Long-term value: 85 at 20 ppm mg/m
OSHA PEL Long-term value: 100 ppm mg/m
Ceiling limit value: 200 ppm mg/m
PEL Long-term value: 100 ppm
Ceiling limit value: 200; 600* ppm
*5-min peak in any 3 hrs
REL Short-term value: 425 mg/m , 100 ppm
Long-term value: 215 mg/m , 50 ppm
TLV Short-term value: 20 ppm
Long-term value: 10 ppm
BEI, OTO, A3
Ingredients with biological limit values:
100-42-5 Styrene
BEI 400 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: Mandelic acid plus phenylglyoxylic acid (nonspecific)
40 g/L
Medium: urine
Time: end of shift
Parameter: Styrene
(Contd. on page 6)
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Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Pasty
Color: White
Odor: Pungent
Odor threshold: Not determined.
(Contd. on page 7)
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pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:145 C (293 F)
Flash point: 31 C (87.8 F)
Flammability (solid, gaseous):Flammable.
Auto igniting: 490 C (914 F)
Decomposition temperature: Not determined.
Ignition temperature: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Explosion limits:
Lower: 0.9 Vol %
Upper: 6.8 Vol %
Vapor pressure at 20 C (68 F):6 hPa (4.5 mm Hg)
Density at 20 C (68 F): 2.16 g/cm (18.03 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Fully miscible.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.3 %
Water: 0.0 %
VOC content: 14.76 %
319.5 g/l / 2.67 lb/gal
Solids content: 56.3 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
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Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
100-42-5 Styrene
Oral LD50 >2,000 mg/kg (rat)
Dermal LD50 >2,000 mg/kg (rat)
Inhalative LC50/4 h 11.8 mg/l (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
14807-96-6 Talc (Mg3H2(SiO3)4) 3
100-42-5 Styrene 2A
13463-67-7 titanium dioxide 2B
64-17-5 ethanol 1
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
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Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
Recommended cleansing agent:Water, if necessary with cleansing agents.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1866
UN proper shipping name
DOT Resin solution
IMDG, IATA RESIN SOLUTION
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids
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Label 3
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Flammable liquids
EMS Number: F-E,S-E
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: UN 1866 RESIN SOLUTION, 3, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
100-42-5 Styrene
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
100-42-5 Styrene
108-10-1 4-methylpentan-2-one
Proposition 65
Chemicals known to cause cancer:
100-42-5 Styrene
14808-60-7 Quartz (SiO2)
108-10-1 4-methylpentan-2-one
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
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Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
64-17-5 ethanol
108-10-1 4-methylpentan-2-one
Carcinogenic categories
NIOSH-Ca (National Institute for Occupational Safety and Health)
13463-67-7 titanium dioxide
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
Styrene
Hazard statements
Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause cancer. Route of exposure: Inhalation.
Suspected of damaging fertility or the unborn child.
Causes damage to the hearing organs through prolonged or repeated exposure.
Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
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If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use CO2, powder or water spray to extinguish.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:
Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Contact:
Date of preparation / last revision03/21/2023
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flammable Liquids 3: Flammable liquids Category 3
Skin Irritation 2: Skin corrosion/irritation Category 2
Eye Irritation 2A: Serious eye damage/eye irritation Category 2A
Carcinogenicity 1B: Carcinogenicity Category 1B
Toxic to Reproduction 2: Reproductive toxicity Category 2
Specific Target Organ Toxicity – Repeated Exposure 1: Specific target organ toxicity (repeated exposure) Category 1
* Data compared to the previous version altered.
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