90000000113_SDS.pdf
* O D V V ) D E U L F
Not available.
Solid.
GHS product identifier
Other means of
identification
Product type
Section 1. Identification
:
:
Relevant identified uses of the substance or mixture and uses advised against
SAFETY DATA SHEET
* O D V V ) D E U L F
Product use :Glass fibres
Area of application :Professional applications.
vS0nPd0fnnndPS0o9F2tEmergency telephone
number (with hours of
operation)
Supplier/Manufacturer
e-mail address of person
responsible for this SDS
:
Product code :
Section 2. Hazards identification
Classification of the
substance or mixture
:
Signal word :No signal word.
Hazard statements :No known significant effects or critical hazards.
Precautionary statements
Prevention :Not applicable.
Response :Not applicable.
Storage :Not applicable.
Disposal :Not applicable.
GHS label elements
OSHA/HCS status :While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the
safe handling and proper use of the product. This SDS should be retained and available
for employees and other users of this product.
Hazards not otherwise
classified
:None known.
Not classified.
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 1/11
United States
Not available.
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Website: www. V D H U W H [.com
:
:
:
* O D V V ) D E U L F
Section 3. Composition/information on ingredients
titanium dioxide – 1 13463-67-7
Ingredient name CAS number%
Other means of
identification
:Not available.
Substance/mixture :Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Other names
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Wash out mouth with water. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 2/11
United States
* O D V V ) D E U L F
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
In case of fire, use water spray (fog), foam, dry chemical or CO .
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Prevent entry into sewers, water courses, basements
or confined areas. Vacuum or sweep up material and place in a designated, labeled
waste container. Dispose of via a licensed waste disposal contractor. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Vacuum or sweep up material and place in a
designated, labeled waste container. Dispose of via a licensed waste disposal
contractor.Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8).:
Precautions for safe handling
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 3/11
United States
* O D V V ) D E U L F
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store between the following temperatures: 20 to 25 C (68 to 77 F). Store in accordance
with local regulations. Store in original container protected from direct sunlight in a dry,
cool and well-ventilated area, away from incompatible materials (see Section 10) and
food and drink. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage.
Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before
handling or use.
:
:
titanium dioxide OSHA PEL (United States, 5/2018).
TWA: 15 mg/m 8 hours. Form: Total dust
ACGIH TLV (United States, 1/2022).
TWA: 2.5 mg/m 8 hours. Form: respirable fraction,
finescale particles
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. 4 – 8 hours (breakthrough time): Protective/insulated gloves. If applicable
Rubber gloves. Butyl gloves. Neoprene gloves./ polychloroprene gloves. Nitrile gloves.
(>=0.5 mm)
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Recommended: Protective hand cream
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 4/11
United States
* O D V V ) D E U L F
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Relative density
Solid.
Not available.
Not available.
Characteristic.Odor
pH
According to specificationColor
Evaporation rate Not available.
Not available.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
SADT Not available.:
Decomposition temperature:Not available.
Viscosity Not applicable.:
Flow time (ISO 2431) :Not available.
Density Not available.:
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Flash point Not applicable.:
Boiling point, initial boiling
point, and boiling range
:Not available.
Vapor pressure
Relative vapor density Not applicable.
Not applicable.:
:
Flammability :Not available.
Lower and upper explosion
limit/flammability limit
:Not applicable.
Auto-ignition temperature Not applicable.
Not applicable.Partition coefficient: n-
octanol/water
:
:
Miscible with water :No.
Particle characteristics
Median particle size :Not available.
Other information
Solubility(ies) :Media Result
hot water Not soluble
cold water Not soluble
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 5/11
United States
* O D V V ) D E U L F
Section 9. Physical and chemical properties
Physical/chemical
properties comments
:No additional information.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous polymerization will not occur.
No specific data.
Section 11. Toxicological information
Acute toxicity
titanium dioxide LC50 Inhalation Dusts and mistsRat – Male,
Female
5.09 mg/l 4 hours
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Conclusion/Summary :Not available.
Mutagenicity
Conclusion/Summary :Not available.
Teratogenicity
Conclusion/Summary :Not available.
Reproductive toxicity
Conclusion/Summary :Not available.
Irritation/Corrosion
titanium dioxide Skin – Mild irritant Human – 72 hours 300
ug I
–
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
titanium dioxide – 2B –
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 6/11
United States
* O D V V ) D E U L F
Section 11. Toxicological information
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Reproductive toxicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Numerical measures of toxicity
Aspiration hazard
Not available.
:Routes of entry anticipated: Oral, Dermal, Inhalation, Eyes.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Acute toxicity estimates
Product/ingredient name
titanium dioxide N/A N/A N/A N/A 5.09
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm) Inhalation
(vapors)
(mg/l) Inhalation
(dusts and
mists) (mg/
l)
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 7/11
United States
* O D V V ) D E U L F
Section 11. Toxicological information
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
titanium dioxide Acute LC50 3 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia – Neonate
48 hours
Acute LC50 6.5 mg/l Fresh water Daphnia – Daphnia pulex –
Neonate
48 hours
Acute LC50 >1000000 g/l Marine waterFish – Fundulus heteroclitus96 hours
Product/ingredient name SpeciesResult Exposure
Conclusion/Summary :Not available.
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:Disposal methods
Section 14. Transport information
–
–
–
–
–
Not regulated.
–
Not regulated. Not regulated.
DOT Classification IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 8/11
United States
* O D V V ) D E U L F
Section 14. Transport information
– – -Packing group
Environmental
hazards
Special precautions for user
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
Additional information
Transport in bulk according
to IMO instruments
:Not available.
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: FIBROUS GLASSMassachusetts
:
:
SARA 313
California Prop. 65
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs) :Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :None of the components are listed.
New Jersey :None of the components are listed.
Pennsylvania :None of the components are listed.
State regulations
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
Not applicable.
SARA 311/312
Classification :Not applicable.
titanium dioxide 1 CARCINOGENICITY – Category 2
Name % Classification
Composition/information on ingredients
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 9/11
United States
* O D V V ) D E U L F
Section 15. Regulatory information
International regulations
WARNING: This product can expose you to Titanium dioxide, which is known to the State of California to cause
cancer. For more information go to www.P65Warnings.ca.gov.
Titanium dioxide – –
Ingredient name No significant risk levelMaximum acceptable dosage
level
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Not listed.
Section 16. Other information
History
Date of issue/Date of
revision
Date of previous issue
:
:
11/29/2022
No previous validation
Hazardous Material Information System (U.S.A.)
0
0
0
National Fire Protection Association (U.S.A.)
Health Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
/0
0
0
Special hazards
Procedure used to derive the classification
Classification Justification
Not classified.
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 10/11
United States
* O D V V ) D E U L F
Section 16. Other information
Chemical Check GmbH
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
:
:
References :HCS (U.S.A.)- Hazard Communication Standard
International transport regulations
Key to abbreviations :
1
ATE = Acute Toxicity Estimate
AMP = Acceptable maximum peak above the acceptable ceiling concentration for an
8-hr shift
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
UN = United Nations
Indicates information that has changed from previously issued version.
Date of issue/Date of revision :11/29/2022Date of previous issue :No previous validationVersion:1 11/11
United States
90000000042_SDS.pdf
SAFETY DATA SHEET
1. Identification
TR-309 & 307 Rubbing CompoundProduct identifier
Other means of identification
309, 307Product code
Polish.Recommended use
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Manufacturer/Supplier
11022 Vulcan StreetAddress
South Gate, CA 90280-0893 United States
(562) 923-5438Telephone:
CHEMTREC: (800) 424-9300Emergency
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Not classified.Physical hazards
Category 1Skin corrosion/irritationHealth hazards
Category 1Serious eye damage/eye irritation
Category 1ACarcinogenicity
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 2 (Lung)Specific target organ toxicity, repeated
exposure
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes severe skin burns and eye damage. May cause cancer. May cause respiratory irritation.
May cause damage to organs (Lung) through prolonged or repeated exposure.
Precautionary statement
Prevention Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Wear protective
gloves/protective clothing/eye protection/face protection. Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Use only outdoors or in
a well-ventilated area.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a
poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 1 / 8
3. Composition/information on ingredients
Mixtures
7732-18-5 35 – 40Water
CAS number %Chemical name
64742-96-7 30 – 35Solvent Naphtha (petroleum),
Heavy Aliphatic
14808-60-7 15 – 20Quartz
61790-12-3 5 – 10Tall Oil, Fatty Acids
141-43-5 1 – 52-Aminoethanol
8002-09-3 1 – 5Pine Oil
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Burning pain and severe corrosive skin damage. Causes permanent skin damage (scarring).
Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision. Permanent eye damage including blindness could result. Ingestion may produce
burns to the lips, oral cavity, upper airway, esophagus and possibly the digestive tract. May cause
respiratory irritation. Coughing. Wheezing. Difficulty in breathing. Shortness of breath. Prolonged
exposure may cause chronic effects. Causes digestive tract burns.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
General information
5. Fire-fighting measures
Alcohol resistant foam. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Fire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to heat with water spray and remove container, if no risk
is involved. Use standard firefighting procedures and consider the hazards of other involved
materials.
Fire fighting
equipment/instructions
Material will burn in a fire.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-20182 / 8
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid
prolonged exposure. Should be handled in closed systems, if possible. Use only in well-ventilated
areas. Wear appropriate personal protective equipment. Observe good industrial hygiene
practices.
Precautions for safe handling
Store locked up. Keep away from heat and sources of ignition. Store in original tightly closed
container. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
FormValueComponents Type
PEL 6 mg/m32-Aminoethanol (CAS
141-43-5)
3 ppm
PEL 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
PEL 400 mg/m3Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
100 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)
FormValueComponents Type
TWA 0.1 mg/m3 Respirable.Quartz (CAS 14808-60-7)
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values
FormValueComponents Type
STEL 6 ppm2-Aminoethanol (CAS
141-43-5)
TWA 3 ppm
TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7)
TWA 200 mg/m3 Non-aerosol.Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
US. NIOSH: Pocket Guide to Chemical Hazards
FormValueComponents Type
STEL 15 mg/m32-Aminoethanol (CAS
141-43-5)
6 ppm
TWA 8 mg/m3
3 ppm
TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
No biological exposure limits noted for the ingredient(s).Biological limit values
Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica
should be monitored and controlled. Occupational Exposure Limits are not relevant to the current
physical form of the product.
Exposure guidelines
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 3 / 8
US ACGIH Threshold Limit Values: Skin designation
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS
64742-96-7)
Can be absorbed through the skin.
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles) and a face shield.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.
Contact glove manufacturer for specific information.
Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Solid.Physical state
Paste.Form
Not available.Color
Not available.Odor
Odor threshold Not available.
pH Not applicable.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
Not available.
Flash point > 140.0 F (> 60.0 C) (Estimated)
Evaporation rate Not applicable.
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Other information
Not explosive.Explosive properties
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 4 / 8
Not oxidizing.Oxidizing properties
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizers, strong acids, and strong bases. Amines.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
Nitrogen oxides.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns.
Symptoms related to the
physical, chemical and
toxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result. May cause respiratory irritation. Coughing. Discomfort in the chest.
Shortness of breath. Causes digestive tract burns. Prolonged exposure may cause chronic
effects.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsComponents Species
Quartz (CAS 14808-60-7)
Inhalation
Chronic
LOEC Human 0.0563 mg/m3
Causes severe skin burns and eye damage.Skin corrosion/irritation
Causes serious eye damage.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity May cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause respiratory irritation.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (Lung) through prolonged or repeated exposure.
Aspiration hazard Due to the physical form of the product it is not expected to be an aspiration hazard.
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 5 / 8
Chronic effects May cause damage to organs through prolonged or repeated exposure. May be harmful if
absorbed through skin. Prolonged exposure may cause chronic effects.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Further information Symptoms may be delayed. May be absorbed through the skin.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of any ingredients in the mixture. Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Aminoethanol (CAS 141-43-5) -1.31
No data available for this product.Mobility in soil
Other adverse effects Substantial amounts of the product may lead to a local change in acidity in small water systems
which may have adverse effects on aquatic organisms.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN2491UN number
Ethanolamine solutionsUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB3, T4, TP1Special provisions
154Packaging exceptions
203Packaging non bulk
241Packaging bulk
IATA
UN2491UN number
Ethanolamine solutionUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoEnvironmental hazards
8LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 6 / 8
IMDG
UN2491UN number
ETHANOLAMINE SOLUTIONUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
NoMarine pollutant
Environmental hazards
F-A, S-BEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
lung effects
immune system effects
kidney effects
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK – Substance List
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
2-Aminoethanol (CAS 141-43-5)
Pine Oil (CAS 8002-09-3)
Quartz (CAS 14808-60-7)
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS 64742-96-7)
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 7 / 8
US. Pennsylvania Worker and Community Right-to-Know Law
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. Rhode Island RTK
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
California Proposition 65
This product can expose you to Quartz, which is known to the State of California to cause cancer.
For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 – CRT: Listed date/Carcinogenic substance
Quartz (CAS 14808-60-7) Listed: October 1, 1988
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Quartz (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI) YesTaiwan
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
03-September-2018Issue date
-Revision date
Version # 01
NFPA ratings
03
1
List of abbreviations PEL: Permissible Exposure Limit.
STEL: Short-Term Exposure Limit.
TWA: Time Weighted Average Value.
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 8 / 8
90000000041_SDS.pdf
SAFETY DATA SHEET
NOROX
MEKP-9H DDDD RED
Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023
1 / 28
SECTION 1. IDENTIFICATION
Trade name
: NOROX
MEKP-9H DDDD RED
Manufacturer or supplier’s details
Company name of supplier
: United Initiators, Inc.
Address
: 555 Garden Street
Elyria OH 44035 USA
Telephone
: +1-440-323-3112
Telefax
: +1-440-323-2659
Emergency telephone
: CHEMTREC US (24h): +1-800-424-9300
CHEMTREC WORLD (24h): +1-703-527-3887
E-mail address of person
responsible for the SDS
: cs-initiators.nafta@united-in.com
Recommended use of the chemical and restrictions on use
Recommended use
: polymerization initiators
Curing chemical
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Flammable liquids
: Category 4
Organic peroxides
: Type D
Acute toxicity (Oral)
: Category 4
Acute toxicity (Inhalation)
: Category 4
Skin corrosion
: Category 1B
Serious eye damage
: Category 1
Reproductive toxicity
: Category 2
Short-term (acute) aquatic
hazard
: Category 2
GHS label elements
SAFETY DATA SHEET
NOROX
MEKP-9H DDDD RED
Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023
2 / 28
Hazard pictograms
:
Signal Word
: Danger
Hazard Statements
: H227 Combustible liquid.
H242 Heating may cause a fire.
H302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H361 Suspected of damaging fertility or the unborn child.
H401 Toxic to aquatic life.
Precautionary Statements
:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P220 Keep/Store away from clothing/ strong acids, bases,
heavy metal salts and other reducing substances /combustible
materials.
P234 Keep only in original container.
P261 Avoid breathing mist or vapors.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/ doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use water spray, alcohol-resistant
foam, dry chemical or carbon dioxide to extinguish.
SAFETY DATA SHEET
NOROX
MEKP-9H DDDD RED
Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023
3 / 28
Storage:
P405 Store locked up.
P410 Protect from sunlight.
P411 + P235 Store at temperatures not exceeding < 100 F/ <
38 C. Keep cool.
P420 Store away from other materials.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Chemical nature
: Organic Peroxide
Liquid mixture
Components
Chemical name CAS-No. Concentration (% w/w)
dimethyl phthalate 131-11-3
>= 40 – < 45
2-Butanone, peroxide 1338-23-4
>= 35 – < 40
Trimethylpentanediol isobutyrate 6846-50-0
>= 15 – < 20
Butanone 78-93-3
>= 1 – < 5
Hydrogen peroxide 7722-84-1
>= 1 – < 5
2-Naphthalenol, 1-[2-[4-(2-
phenyldiazenyl)phenyl]diazenyl]-, ar-
heptyl ar',ar''-Me derivs.
92257-31-3
>= 0.1 – < 1
Actual concentration is withheld as a trade secret
SECTION 4. FIRST AID MEASURES
General advice
: Take off contaminated clothing and shoes immediately.
Call a physician immediately.
Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and seek medical
advice.
Move out of dangerous area.
Show this material safety data sheet to the doctor in
attendance.
Do not leave the victim unattended.
SAFETY DATA SHEET
NOROX
MEKP-9H DDDD RED
Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023
4 / 28
Symptoms of poisoning may appear several hours later.
If inhaled
: Administer oxygen if breathing is difficult or cyanosis is
observed.
Call a physician immediately.
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Respiratory tract burning possible if aerosols are inhaled.
Call a physician or poison control center immediately.
If unconscious, place in recovery position and seek medical
advice.
Keep respiratory tract clear.
In case of skin contact
: If symptoms persist, call a physician.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with
difficulty.
In case of contact, immediately flush skin with plenty of water
for at least 15 minutes while removing contaminated clothing
and shoes.
Wash contaminated clothing before re-use.
If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact
: Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
: Call a physician immediately.
Rinse mouth thoroughly with water.
Keep respiratory tract clear.
Do NOT induce vomiting.
If symptoms persist, call a physician.
Most important symptoms
and effects, both acute and
delayed
: Harmful if swallowed or if inhaled.
Causes serious eye damage.
Suspected of damaging fertility or the unborn child.
Causes severe burns.
Protection of first-aiders
: First Aid responders should pay attention to self-protection
and use the recommended protective clothing
Notes to physician
: Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
SAFETY DATA SHEET
NOROX
MEKP-9H DDDD RED
Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023
5 / 28
Suitable extinguishing media
: Water spray jet
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during fire
fighting
: Risk of explosion if heated under confinement.
Possible emission of gaseous decomposition products may
lead to a dangerous pressure build-up.
Avoid confinement.
Contact with incompatible materials or exposure to
temperatures exceeding SADT may result in a self-
accelerating decomposition reaction with release of flammable
vapors which may auto-ignite.
The product burns violently.
Flash back possible over considerable distance.
Do not allow run-off from fire fighting to enter drains or water
courses.
Vapors may form explosive mixtures with air.
The product will float on water and can be reignited on surface
water.
Cool closed containers exposed to fire with water spray.
Specific extinguishing meth-
ods
: Do not use a solid water stream as it may scatter and spread
fire.
Remove undamaged containers from fire area if it is safe to do
so.
Use water spray to cool unopened containers.
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Use a water spray to cool fully closed containers.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment
for fire-fighters
: Wear self-contained breathing apparatus for firefighting if
necessary.
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
gency procedures
: Follow safe handling advice and personal protective
equipment recommendations.
Beware of vapors accumulating to form explosive
concentrations. Vapors can accumulate in low areas.
Use personal protective equipment.
SAFETY DATA SHEET
NOROX
MEKP-9H DDDD RED
Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023
6 / 28
Remove all sources of ignition.
Never return spills in original containers for re-use.
Treat recovered material as described in the section "Disposal
considerations".
Environmental precautions
: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
: Contact with incompatible substances can cause
decomposition at or below SADT.
Clear spills immediately.
Suppress (knock down) gases/vapors/mists with a water spray
jet.
To clean the floor and all objects contaminated by this
material, use plenty of water.
Soak up with inert absorbent material.
Isolate waste and do not reuse.
Non-sparking tools should be used.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
SECTION 7. HANDLING AND STORAGE
Technical measures
: See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Advice on protection against
fire and explosion
: Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors).
Keep away from heat and sources of ignition.
Use only explosion-proof equipment.
Keep away from open flames, hot surfaces and sources of
ignition.
Keep away from combustible material.
Do not spray on a naked flame or any incandescent material.
Advice on safe handling
: Open drum carefully as content may be under pressure.
Protect from contamination.
Do not swallow.
Do not breathe vapors/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
Avoid formation of aerosol.
Take precautionary measures against static discharges.
Never return any product to the container from which it was
originally removed.
Provide sufficient air exchange and/or exhaust in work rooms.
SAFETY DATA SHEET
NOROX
MEKP-9H DDDD RED
Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023
7 / 28
Avoid confinement.
Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
Smoking, eating and drinking should be prohibited in the
application area.
Wash thoroughly after handling.
For personal protection see section 8.
Conditions for safe storage
: Store in original container.
Keep containers tightly closed in a cool, well-ventilated place.
Store in cool place.
Keep in a well-ventilated place.
Contamination may result in dangerous pressure increases -
closed containers may rupture.
Observe label precautions.
Store in accordance with the particular national regulations.
Avoid impurities (e.g. rust, dust, ash), risk of decomposition.
Electrical installations / working materials must comply with
the technological safety standards.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Materials to avoid
: Keep away from strong acids, bases, heavy metal salts and
other reducing substances.
Recommended storage tem-
perature
: < 100 F
< 38 C
Further information on stor-
age stability
: No decomposition if stored normally.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis
dimethyl phthalate 131-11-3 TWA 5 mg/m3 ACGIH
TWA 5 mg/m3 NIOSH REL
TWA 5 mg/m3 OSHA Z-1
TWA 5 mg/m3 OSHA P0
2-Butanone, peroxide 1338-23-4 C 0.2 ppm ACGIH
C 0.2 ppm
1.5 mg/m3
NIOSH REL
C 0.7 ppm
5 mg/m3
OSHA P0
Butanone 78-93-3 TWA 200 ppm ACGIH
STEL 300 ppm ACGIH
SAFETY DATA SHEET
NOROX
MEKP-9H DDDD RED
Version
1.1
Revision Date:
06/14/2023
SDS Number:
600000001059
Date of last issue: 06/02/2023
Date of first issue: 06/02/2023
8 / 28
TWA 200 ppm
590 mg/m3
NIOSH REL
ST 300 ppm
885 mg/m3
NIOSH REL
TWA 200 ppm
590 mg/m3
OSHA Z-1
TWA 200 ppm
590 mg/m3
OSHA P0
STEL 300 ppm
885 mg/m3
OSHA P0
Hydrogen peroxide 7722-84-1 TWA 1 ppm ACGIH
TWA 1 ppm
1.4 mg/m3
NIOSH REL
TWA 1 ppm
1.4 mg/m3
OSHA Z-1
TWA 1 ppm
1.4 mg/m3
OSHA P0
Biological occupational exposure limits
Components CAS-No. Control
parameters
Biological
specimen
Sam-
pling
time
Permissible
concentra-
tion
Basis
Butanone 78-93-3 methyl ethyl
ketone
Urine End of
shift (As
soon as
possible
after
exposure
ceases)
2 mg/l ACGIH
BEI
Engineering measures : Minimize workplace exposure concentrations.
Personal protective equipment
Respiratory protection
: In the case of dust or aerosol formation use respirator with an
approved filter.
Filter type
: ABEK-filter
Use NIOSH approved respiratory protection.
Hand protection
Material : butyl-rubber
Break through time : <= 480 min
Glove thickness : 0.5 mm
Material : Nitrile rubber
Break through time : < 30 min
Glove thickness : 0.4 mm
Remarks : The data about break through time/strength of material are
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standard values! The exact break through time/strength of
material has to be obtained from the producer of the
protective glove. Choose gloves to protect hands against
chemicals depending on the concentration and quantity of the
hazardous substance and specific to place of work.
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection
: Ensure that eyewash stations and safety showers are close
to the workstation location.
Please follow all applicable local/national requirements when
selecting protective measures for a specific workplace.
Always wear eye protection when the potential for inadvertent
eye contact with the product cannot be excluded.
Tightly fitting safety goggles
Please wear suitable protective goggles. Also wear face
protection if there is a splash hazard.
Skin and body protection
: Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Additional body garments should be used based upon the
task being performed (e.g., sleevelets, apron, gauntlets,
disposable suits) to avoid exposed skin surfaces.
Wear as appropriate:
Flame retardant antistatic protective clothing.
Protective measures
: The type of protective equipment must be selected according
to the concentration and amount of the dangerous substance
at the specific workplace.
Hygiene measures
: Avoid contact with skin, eyes and clothing.
Keep away from food and drink.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and immediately after handling
the product.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: liquid
Color
: red
Odor
: slight
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Odor Threshold
: not determined
pH
: Not applicable
Melting point/range
: No data available
Boiling point/boiling range
: not determined
Flash point
: > 76 C
Flammability (solid, gas)
: Not applicable
Upper explosion limit / Upper
flammability limit
: No data available
Lower explosion limit / Lower
flammability limit
: No data available
Vapor pressure
: No data available
Relative vapor density
: > 1
Density
: 1.1 g/cm3
Solubility(ies)
Water solubility
: slightly soluble
Partition coefficient: n-
octanol/water
: No data available
Self-Accelerating decomposi-
tion temperature (SADT)
: ca. 60 C
SADT-Self Accelerating Decomposition Temperature. Lowest
temperature at which the tested package size will undergo a
self-accelerating decomposition reaction.
Viscosity
Viscosity, dynamic
: No data available
Viscosity, kinematic
: not determined
Oxidizing properties
: The substance or mixture is not classified as oxidizing.
Organic peroxide
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: Stable under recommended storage conditions.
Heating may cause a fire or explosion.
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Chemical stability
: Stable under recommended storage conditions.
No decomposition if stored normally.
Possibility of hazardous reac-
tions
: Vapors may form explosive mixture with air.
Conditions to avoid
: Protect from contamination.
Heat, flames and sparks.
Avoid confinement.
Incompatible materials
: Accelerators, strong acids and bases, heavy metals and
heavy metal salts, reducing agents
Hazardous decomposition
products
: Irritant, caustic, flammable, noxious/toxic gases and vapours
can develop in the case of fire and decomposition
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Harmful if swallowed or if inhaled.
Product:
Acute oral toxicity
: Acute toxicity estimate: 1,372 mg/kg
Method: Calculation method
Acute inhalation toxicity
: Acute toxicity estimate: 4.17 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute dermal toxicity
: Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method
Components:
dimethyl phthalate:
Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
: (Rat): > 10.4 mg/l
Exposure time: 6 h
Test atmosphere: vapor
Remarks: No mortality observed at this dose.
Acute dermal toxicity
: LD50 (Rabbit): > 12,000 mg/kg
2-Butanone, peroxide:
Acute oral toxicity
: Acute toxicity estimate: 500 mg/kg
Method: Expert judgment
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Acute inhalation toxicity
: Acute toxicity estimate: 1.5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Expert judgment
Assessment: The component/mixture is moderately toxic after
short term inhalation.
Remarks: Based on data from similar materials
Acute dermal toxicity
: Acute toxicity estimate: 2,500 mg/kg
Method: Expert judgment
Trimethylpentanediol isobutyrate:
Acute oral toxicity
: LD50 (Rat): > 2,000 mg/kg
Method: Expert judgment
Assessment: The substance or mixture has no acute oral tox-
icity
Acute inhalation toxicity
: LCLo (Rat): > 0.12 mg/l
Exposure time: 6 h
Test atmosphere: vapor
Method: Expert judgment
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: No mortality observed at this dose.
Acute dermal toxicity
: LD50 (Guinea pig): > 2,000 mg/kg
Method: Expert judgment
Assessment: The substance or mixture has no acute dermal
toxicity
Butanone:
Acute oral toxicity
: LD50 (Rat): 2,193 mg/kg
Method: OECD Test Guideline 423
Acute inhalation toxicity
: Remarks: No data available
Acute dermal toxicity
: LD50 (Rabbit): > 5,000 mg/kg
Method: OECD Test Guideline 402
Remarks: Based on available data, the classification criteria
are not met.
Hydrogen peroxide:
Acute oral toxicity
: Acute toxicity estimate: 500.0 mg/kg
Method: Converted acute toxicity point estimate
Assessment: The component/mixture is moderately toxic after
single ingestion.
Acute inhalation toxicity
: LC50 (Rat): > 0.17 mg/l
Exposure time: 4 h
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Test atmosphere: dust/mist
Assessment: The component/mixture is moderately toxic after
short term inhalation.
Remarks: Based on harmonised classification in EU regulation
1272/2008, Annex VI
Acute dermal toxicity
: LD50 (Rabbit): > 6,500 mg/kg
2-Naphthalenol, 1-[2-[4-(2-phenyldiazenyl)phenyl]diazenyl]-, ar-heptyl ar’,ar”-Me derivs.:
Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation
Causes severe burns.
Product:
Remarks : Extremely corrosive and destructive to tissue.
Components:
dimethyl phthalate:
Species : Rabbit
Method : Draize Test
Result : No skin irritation
2-Butanone, peroxide:
Species : Rabbit
Result : Causes burns.
Trimethylpentanediol isobutyrate:
Species : Guinea pig
Exposure time : 24 h
Result : No skin irritation
Remarks : Based on available data, the classification criteria are not met.
Butanone:
Species : Rabbit
Assessment : Repeated exposure may cause skin dryness or cracking.
Method : OECD Test Guideline 404
Result : No skin irritation
Hydrogen peroxide:
Result : Corrosive after 3 minutes or less of exposure
Remarks : Extremely corrosive and destructive to tissue.
2-Naphthalenol, 1-[2-[4-(2-phenyldiazenyl)phenyl]diazenyl]-, ar-heptyl ar’,ar”-Me derivs.:
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Result : No skin irritation
Serious eye damage/eye irritation
Causes serious eye damage.
Product:
Remarks : May cause irreversible eye damage.
Components:
dimethyl phthalate:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405
2-Butanone, peroxide:
Result : Irreversible effects on the eye
Trimethylpentanediol isobutyrate:
Species : Rabbit
Result : No eye irritation
Exposure time : 24 h
Butanone:
Species : Rabbit
Result : Eye irritation
Method : OECD Test Guideline 405
Hydrogen peroxide:
Result : Irreversible effects on the eye
Remarks : May cause irreversible eye damage.
Respiratory or skin sensitization
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Components:
dimethyl phthalate:
Species : Mouse
Method : OECD Test Guideline 429
Result : Does not cause skin sensitization.
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2-Butanone, peroxide:
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Does not cause skin sensitization.
Assessment : Harmful if swallowed., Harmful if inhaled.
Trimethylpentanediol isobutyrate:
Species : Guinea pig
Result : Does not cause skin sensitization.
Butanone:
Routes of exposure : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Does not cause skin sensitization.
Germ cell mutagenicity
Not classified based on available information.
Components:
dimethyl phthalate:
Genotoxicity in vitro
: Method: OECD Test Guideline 471
Result: negative
Method: OECD Test Guideline 473
Result: negative
Method: OECD Test Guideline 476
Result: positive
Genotoxicity in vivo
: Test Type: Chromosomal aberration
Species: Rat
Application Route: Intraperitoneal
Result: negative
Test Type: Micronucleus test
Species: Mouse
Application Route: Intraperitoneal injection
Result: negative
2-Butanone, peroxide:
Genotoxicity in vitro
: Method: OECD Test Guideline 473
Result: negative
Method: OECD Test Guideline 471
Result: negative
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Method: OECD Test Guideline 476
Result: negative
Trimethylpentanediol isobutyrate:
Genotoxicity in vitro
: Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative
Test Type: Ames test
Method: Regulation (EC) No. 440/2008, Annex, B.13/14
(Ames test)
Result: negative
Test Type: Chromosome aberration test in vitro
Method: OECD Test Guideline 473
Result: negative
Butanone:
Genotoxicity in vitro
: Method: OECD Test Guideline 471
Result: negative
Method: OECD Test Guideline 476
Result: negative
Method: OECD Test Guideline 473
Result: negative
Genotoxicity in vivo
: Species: Mouse
Application Route: Intraperitoneal
Method: OECD Test Guideline 474
Result: negative
Hydrogen peroxide:
Genotoxicity in vitro
: Test Type: Ames test
Result: negative
Genotoxicity in vivo
: Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Result: negative
Carcinogenicity
Not classified based on available information.
Components:
dimethyl phthalate:
Species : Rat
Application Route : Skin contact
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Method : OECD Test Guideline 451
Result : negative
Remarks : Based on data from similar materials
2-Butanone, peroxide:
Remarks : This information is not available.
Hydrogen peroxide:
Carcinogenicity – Assess-
ment
: Carcinogenicity classification not possible from current data.
IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Suspected of damaging fertility or the unborn child.
Components:
dimethyl phthalate:
Effects on fertility
: Species: Rat
Application Route: oral (gavage)
Method: OECD Test Guideline 440
Result: negative
Effects on fetal development
: Species: Rat
Application Route: Ingestion
General Toxicity Maternal: NOAEL: 840 mg/kg body weight
Developmental Toxicity: NOAEL: 3,570 mg/kg body weight
Method: OECD Test Guideline 414
2-Butanone, peroxide:
Effects on fertility
: Species: Rat
Application Route: oral (gavage)
General Toxicity Parent: NOAEL: 50 mg/kg body weight
Method: OECD Test Guideline 421
Result: negative
Trimethylpentanediol isobutyrate:
Effects on fetal development
: Test Type: One-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 414
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Result: negative
Reproductive toxicity – As-
sessment
: Suspected of damaging fertility or the unborn child., Some
evidence of adverse effects on sexual function and fertility,
and/or on development, based on animal experiments.
Butanone:
Effects on fertility
: Species: Rat
Application Route: oral (drinking water)
General Toxicity Parent: NOAEL: 10,000 mg/l
General Toxicity F1: NOAEL: 10,000 mg/l
Method: OECD Test Guideline 416
Remarks: Based on data from similar materials
Species: Rat
Application Route: oral (drinking water)
General Toxicity Parent: LOAEL: 20,000 mg/l
Method: OECD Test Guideline 416
Remarks: Based on data from similar materials
Effects on fetal development
: Species: Rat
Application Route: Inhalation
General Toxicity Maternal: NOAEC: ca. 1,002 mg/kg body
weight
Teratogenicity: NOAEC Parent: ca. 1,002 mg/kg body weight
Method: OECD Test Guideline 414
Result: negative
2-Naphthalenol, 1-[2-[4-(2-phenyldiazenyl)phenyl]diazenyl]-, ar-heptyl ar’,ar”-Me derivs.:
Reproductive toxicity – As-
sessment
: Some evidence of adverse effects on sexual function and
fertility, and/or on development, based on animal experiments.
STOT-single exposure
Not classified based on available information.
Components:
Butanone:
Assessment : May cause drowsiness or dizziness.
Hydrogen peroxide:
Assessment : May cause respiratory irritation.
STOT-repeated exposure
Not classified based on available information.
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Repeated dose toxicity
Components:
dimethyl phthalate:
Species : Rat
NOAEL : 770 mg/kg
Application Route : Oral
Exposure time : 16 w
Method : OECD Test Guideline 408
2-Butanone, peroxide:
Species : Rat
NOAEL : 200 mg/kg
Application Route : oral (gavage)
Exposure time : 28 d
Method : OECD Test Guideline 407
Repeated dose toxicity –
Assessment
: Harmful if swallowed., Harmful if inhaled.
Hydrogen peroxide:
Species : Mouse
Application Route : Ingestion
Exposure time : 90 d
Symptoms : No adverse effects.
Aspiration toxicity
Not classified based on available information.
Components:
dimethyl phthalate:
No aspiration toxicity classification
Trimethylpentanediol isobutyrate:
Not classified due to data which are conclusive although insufficient for classification.
Further information
Product:
Remarks : No data available
Components:
dimethyl phthalate:
Remarks : No data available
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Trimethylpentanediol isobutyrate:
Remarks : No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
dimethyl phthalate:
Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): 39 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
: LC50 (Daphnia magna (Water flea)): > 52 mg/l
Exposure time: 48 h
Toxicity to algae/aquatic
plants
: EC50 (Desmodesmus subspicatus (green algae)): 260 mg/l
Exposure time: 72 h
Toxicity to fish (Chronic tox-
icity)
: NOEC (Oncorhynchus mykiss (rainbow trout)): 11 mg/l
Exposure time: 102 d
Method: OECD Test Guideline 210
LOEC (Oncorhynchus mykiss (rainbow trout)): 24 mg/l
Exposure time: 102 d
Method: OECD Test Guideline 210
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)
: NOEC (Daphnia magna (Water flea)): 9.6 mg/l
Exposure time: 21 d
LOEC (Daphnia magna (Water flea)): 23 mg/l
Exposure time: 21 d
Toxicity to microorganisms
: EC50: 4,100 mg/l
Exposure time: 0.5 h
Method: OECD Test Guideline 209
2-Butanone, peroxide:
Toxicity to fish
: LC50 (Poecilia reticulata (guppy)): 44.2 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
NOEC (Poecilia reticulata (guppy)): 18 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 39 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202
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NOEC (Daphnia magna (Water flea)): 26.7 mg/l
Method: OECD Test Guideline 202
Toxicity to algae/aquatic
plants
: EC50 (Pseudokirchneriella subcapitata (green algae)): 5.6
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
NOEC (Pseudokirchneriella subcapitata (green algae)): 2.1
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Toxicity to microorganisms
: EC50 (Bacteria): 48 mg/l
Exposure time: 0.5 h
Method: OECD Test Guideline 209
Trimethylpentanediol isobutyrate:
Toxicity to fish
: NOEC (Fish): >= 6 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia): >= 1.46 mg/l
Exposure time: 48 h
NOEC (Daphnia): 0.7 mg/l
Exposure time: 21 d
Toxicity to algae/aquatic
plants
: EC50 (Chlorella pyrenoidosa): > 7.49 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)
: LOEC (Daphnia magna (Water flea)): 0.7 mg/l
Exposure time: 21 d
Ecotoxicology Assessment
Acute aquatic toxicity
: This product has no known ecotoxicological effects.
Chronic aquatic toxicity
: Harmful to aquatic life with long lasting effects.
Butanone:
Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): 2,993 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 308 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202
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Toxicity to algae/aquatic
plants
: EC50 (Pseudokirchneriella subcapitata (green algae)): 2,029
mg/l
Exposure time: 96 h
Method: OECD Test Guideline 201
Toxicity to microorganisms
: NOEC (Pseudomonas putida): 1,150 mg/l
Exposure time: 16 h
Method: DIN 38 412 Part 8
Hydrogen peroxide:
Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): 16.4 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
: LC50 (Daphnia pulex (Water flea)): 2.4 mg/l
Exposure time: 48 h
Toxicity to algae/aquatic
plants
: EC50 (Skeletonema costatum (marine diatom)): 1.38 mg/l
Exposure time: 72 h
NOEC (Skeletonema costatum (marine diatom)): 0.63 mg/l
Exposure time: 72 h
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)
: NOEC (Daphnia magna (Water flea)): 0.63 mg/l
Exposure time: 21 d
Persistence and degradability
Components:
dimethyl phthalate:
Biodegradability
: Result: Readily biodegradable.
Method: OECD Test Guideline 301E
2-Butanone, peroxide:
Biodegradability
: Result: Readily biodegradable.
Method: OECD Test Guideline 301D
Trimethylpentanediol isobutyrate:
Biodegradability
: Result: rapidly biodegradable
Exposure time: 28 d
Method: OECD Test Guideline 301B
Butanone:
Biodegradability
: Result: Readily biodegradable.
Method: OECD Test Guideline 301D
SAFETY DATA SHEET
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SDS Number:
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Hydrogen peroxide:
Biodegradability
: Result: Readily biodegradable.
Bioaccumulative potential
Components:
dimethyl phthalate:
Bioaccumulation
: Bioconcentration factor (BCF): 57
Method: OECD Test Guideline 305
Partition coefficient: n-
octanol/water
: log Pow: 1.54
2-Butanone, peroxide:
Partition coefficient: n-
octanol/water
: log Pow: < 0.3 (25 C / 25 C) Trimethylpentanediol isobutyrate: Bioaccumulation : Species: Fish Bioconcentration factor (BCF): 1.95 Partition coefficient: n- octanol/water : log Pow: 4.91 (25 C / 25 C) Butanone: Partition coefficient: n- octanol/water : log Pow: 0.3 (40 C / 40 C) Hydrogen peroxide: Partition coefficient: n- octanol/water : log Pow: -1.57 Remarks: Calculation Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro- tection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufac- tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological infor- mation : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 24 / 28 Toxic to aquatic life. Components: dimethyl phthalate: Additional ecological infor- mation : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of wastes in an approved waste disposal facility. The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Contaminated packaging : Dispose of in accordance with local regulations. Clean container with water. Dispose of contents/ container to an approved waste disposal plant. Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG UN number : UN 3105 Proper shipping name : ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE(S) ) Class : 5.2 Packing group : Not assigned by regulation Labels : 5.2 IATA-DGR UN/ID No. : UN 3105 Proper shipping name : Organic peroxide type D, liquid (Methyl ethyl ketone peroxide(s)) Class : 5.2 Packing group : Not assigned by regulation Labels : Organic Peroxides, Keep Away From Heat Packing instruction (cargo aircraft) : 570 Packing instruction (passen- ger aircraft) : 570 SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 25 / 28 IMDG-Code UN number : UN 3105 Proper shipping name : ORGANIC PEROXIDE TYPE D, LIQUID (METHYL ETHYL KETONE PEROXIDE(S) ) Class : 5.2 Packing group : Not assigned by regulation Labels : 5.2 EmS Code : F-J, S-R Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : UN 3105 Proper shipping name : Organic peroxide type D, liquid (Methyl ethyl ketone peroxide(s), <=45%) Class : 5.2 Packing group : Not assigned by regulation Labels : ORGANIC PEROXIDE ERG Code : 145 Marine pollutant : no Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) 2-Butanone, peroxide 1338-23-4 10 28 SARA 304 Extremely Hazardous Substances Reportable Quantity Listed substances in the product are at low enough levels to not be expected to exceed the RQ SARA 302 Extremely Hazardous Substances Threshold Planning Quantity Components CAS-No. Component TPQ (lbs) Hydrogen peroxide 7722-84-1 1000 SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids) Organic peroxides Acute toxicity (any route of exposure) Reproductive toxicity Skin corrosion or irritation Serious eye damage or eye irritation SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 26 / 28 SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: dimethyl phthalate 131-11-3 Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR 61): dimethyl phthalate 131-11-3 This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermedi- ate or Final VOC's (40 CFR 60.489): Butanone 78-93-3 Clean Water Act This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section 307 dimethyl phthalate 131-11-3 This product contains the following priority pollutants related to the U.S. Clean Water Act: dimethyl phthalate 131-11-3 The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta- ble 116.4A: Xylene 1330-20-7 ethylbenzene 100-41-4 The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: Xylene 1330-20-7 ethylbenzene 100-41-4 California Prop. 65 WARNING: This product can expose you to chemicals including ethylbenzene, which is/are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. International Regulations The ingredients of this product are reported in the following inventories: TCSI (TW) : On the inventory, or in compliance with the inventory TSCA (US) : All substances listed as active on the TSCA inventory DSL (CA) : All components of this product are on the Canadian DSL KECI (KR) : On the inventory, or in compliance with the inventory PICCS (PH) : On the inventory, or in compliance with the inventory IECSC (CN) : On the inventory, or in compliance with the inventory SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 27 / 28 TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. SECTION 16. OTHER INFORMATION Further information This material safety datasheet only contains information relating to safety and does not replace any product information or product specification. These safety instructions also apply to empty packaging which may still contain product residues. The hazards on the label also apply to residues in the container. Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 06/14/2023 Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated values) OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit ACGIH / C : Ceiling limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday NIOSH REL / C : Ceiling value not be exceeded at any time. OSHA P0 / TWA : 8-hour time weighted average OSHA P0 / STEL : Short-term exposure limit OSHA P0 / C : Ceiling limit OSHA Z-1 / TWA : 8-hour time weighted average AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub- stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz- SAFETY DATA SHEET NOROX MEKP-9H DDDD RED Version 1.1 Revision Date: 06/14/2023 SDS Number: 600000001059 Date of last issue: 06/02/2023 Date of first issue: 06/02/2023 28 / 28 ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys- tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza- tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi- cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre- vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth- erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub- stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti- tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern- ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend- ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8
90000000023_SDS.pdf
SAFETY DATA SHEET
1. Identification
TR-309 & 307 Rubbing CompoundProduct identifier
Other means of identification
309, 307Product code
Polish.Recommended use
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Manufacturer/Supplier
11022 Vulcan StreetAddress
South Gate, CA 90280-0893 United States
(562) 923-5438Telephone:
CHEMTREC: (800) 424-9300Emergency
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Not classified.Physical hazards
Category 1Skin corrosion/irritationHealth hazards
Category 1Serious eye damage/eye irritation
Category 1ACarcinogenicity
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 2 (Lung)Specific target organ toxicity, repeated
exposure
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes severe skin burns and eye damage. May cause cancer. May cause respiratory irritation.
May cause damage to organs (Lung) through prolonged or repeated exposure.
Precautionary statement
Prevention Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Wear protective
gloves/protective clothing/eye protection/face protection. Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Use only outdoors or in
a well-ventilated area.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a
poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 1 / 8
3. Composition/information on ingredients
Mixtures
7732-18-5 35 – 40Water
CAS number %Chemical name
64742-96-7 30 – 35Solvent Naphtha (petroleum),
Heavy Aliphatic
14808-60-7 15 – 20Quartz
61790-12-3 5 – 10Tall Oil, Fatty Acids
141-43-5 1 – 52-Aminoethanol
8002-09-3 1 – 5Pine Oil
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Burning pain and severe corrosive skin damage. Causes permanent skin damage (scarring).
Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision. Permanent eye damage including blindness could result. Ingestion may produce
burns to the lips, oral cavity, upper airway, esophagus and possibly the digestive tract. May cause
respiratory irritation. Coughing. Wheezing. Difficulty in breathing. Shortness of breath. Prolonged
exposure may cause chronic effects. Causes digestive tract burns.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
General information
5. Fire-fighting measures
Alcohol resistant foam. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Fire may produce irritating, corrosive and/or toxic gases.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to heat with water spray and remove container, if no risk
is involved. Use standard firefighting procedures and consider the hazards of other involved
materials.
Fire fighting
equipment/instructions
Material will burn in a fire.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-20182 / 8
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid
prolonged exposure. Should be handled in closed systems, if possible. Use only in well-ventilated
areas. Wear appropriate personal protective equipment. Observe good industrial hygiene
practices.
Precautions for safe handling
Store locked up. Keep away from heat and sources of ignition. Store in original tightly closed
container. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
FormValueComponents Type
PEL 6 mg/m32-Aminoethanol (CAS
141-43-5)
3 ppm
PEL 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
PEL 400 mg/m3Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
100 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)
FormValueComponents Type
TWA 0.1 mg/m3 Respirable.Quartz (CAS 14808-60-7)
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values
FormValueComponents Type
STEL 6 ppm2-Aminoethanol (CAS
141-43-5)
TWA 3 ppm
TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7)
TWA 200 mg/m3 Non-aerosol.Solvent Naphtha
(petroleum), Heavy
Aliphatic (CAS 64742-96-7)
US. NIOSH: Pocket Guide to Chemical Hazards
FormValueComponents Type
STEL 15 mg/m32-Aminoethanol (CAS
141-43-5)
6 ppm
TWA 8 mg/m3
3 ppm
TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
No biological exposure limits noted for the ingredient(s).Biological limit values
Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica
should be monitored and controlled. Occupational Exposure Limits are not relevant to the current
physical form of the product.
Exposure guidelines
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 3 / 8
US ACGIH Threshold Limit Values: Skin designation
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS
64742-96-7)
Can be absorbed through the skin.
Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles) and a face shield.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.
Contact glove manufacturer for specific information.
Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Solid.Physical state
Paste.Form
Not available.Color
Not available.Odor
Odor threshold Not available.
pH Not applicable.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
Not available.
Flash point > 140.0 F (> 60.0 C) (Estimated)
Evaporation rate Not applicable.
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Other information
Not explosive.Explosive properties
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 4 / 8
Not oxidizing.Oxidizing properties
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
No dangerous reaction known under conditions of normal use.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizers, strong acids, and strong bases. Amines.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
Nitrogen oxides.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns.
Symptoms related to the
physical, chemical and
toxicological characteristics
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result. May cause respiratory irritation. Coughing. Discomfort in the chest.
Shortness of breath. Causes digestive tract burns. Prolonged exposure may cause chronic
effects.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsComponents Species
Quartz (CAS 14808-60-7)
Inhalation
Chronic
LOEC Human 0.0563 mg/m3
Causes severe skin burns and eye damage.Skin corrosion/irritation
Causes serious eye damage.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity May cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause respiratory irritation.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (Lung) through prolonged or repeated exposure.
Aspiration hazard Due to the physical form of the product it is not expected to be an aspiration hazard.
TR-309 & 307 Rubbing Compound SDS US
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Chronic effects May cause damage to organs through prolonged or repeated exposure. May be harmful if
absorbed through skin. Prolonged exposure may cause chronic effects.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Further information Symptoms may be delayed. May be absorbed through the skin.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of any ingredients in the mixture. Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Aminoethanol (CAS 141-43-5) -1.31
No data available for this product.Mobility in soil
Other adverse effects Substantial amounts of the product may lead to a local change in acidity in small water systems
which may have adverse effects on aquatic organisms.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN2491UN number
Ethanolamine solutionsUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB3, T4, TP1Special provisions
154Packaging exceptions
203Packaging non bulk
241Packaging bulk
IATA
UN2491UN number
Ethanolamine solutionUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
NoEnvironmental hazards
8LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 6 / 8
IMDG
UN2491UN number
ETHANOLAMINE SOLUTIONUN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
NoMarine pollutant
Environmental hazards
F-A, S-BEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
lung effects
immune system effects
kidney effects
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK – Substance List
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
2-Aminoethanol (CAS 141-43-5)
Pine Oil (CAS 8002-09-3)
Quartz (CAS 14808-60-7)
Solvent Naphtha (petroleum), Heavy Aliphatic (CAS 64742-96-7)
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 7 / 8
US. Pennsylvania Worker and Community Right-to-Know Law
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
US. Rhode Island RTK
2-Aminoethanol (CAS 141-43-5)
Quartz (CAS 14808-60-7)
California Proposition 65
This product can expose you to Quartz, which is known to the State of California to cause cancer.
For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 – CRT: Listed date/Carcinogenic substance
Quartz (CAS 14808-60-7) Listed: October 1, 1988
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Quartz (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI) YesTaiwan
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
03-September-2018Issue date
-Revision date
Version # 01
NFPA ratings
03
1
List of abbreviations PEL: Permissible Exposure Limit.
STEL: Short-Term Exposure Limit.
TWA: Time Weighted Average Value.
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
TR-309 & 307 Rubbing Compound SDS US
3627 Version #: 01 Revision date: – Issue date: 03-September-2018 8 / 8
90000000022_SDS.pdf
SAFETY DATA SHEET
Date issued : 05/15/2014
SDS number : SC-22
Date revised : 03/25/2024
Revision number : 3
SC-22
1. Identification
Product identifier: SC-22
Relevant identified uses: Plasticizer
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
This product does not meet the criteria for classification.
Label elements
Not Applicable
3. Composition/information on ingredients
Chemical name % w/w CAS No.
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 80 – 10068515-49-1
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Foam, carbon dioxide, dry chemical, or water fog.
Hazardous combustion products: Carbon monoxide and carbon dioxide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Page 1 of 5
Small spill: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear full
protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize small spills
with a decontaminant.
Large spill: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top drums or
plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of
residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes,
skin, and clothing. Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
Conditions for safe storage: Keep away from heat, sparks, open flames, or other sources of ignition. Store in a cool, dry place, away from
excessive heat, in original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent
contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection – hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection – other: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Colorless
Odor: Mild
pH: No data available
Initial boiling point and boiling range: > 250 C (482 F)
Flash point: 223.9 C (435 F) Pensky-Martens CC
Page 2 of 5
SC-22
Evaporation rate (n-butyl acetate = 1): < 0.01 (n-BuAc=1)
Vapor pressure: < 0.08 mmHg at 20 C (68 F)
Relative vapor density: > 1 (Air=1)
Relative density: 0.97 (water=1) at 20 C (68 F)
Solubility: Negligible
Dynamic viscosity: 130 Centistokes at 20 C (68 F)
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: Heat, flames, and ignition sources.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide and carbon dioxide.
Incompatible materials: Strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters,
C10-rich
> 10 g/kg Rat > 3.16 g/kg Rabbit > 0.13 mg/l Rat
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Notes: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Environmental data: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
Page 3 of 5
SC-22
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: None Known
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119—process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 80 – 100Developmental Toxicity
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
General comments: DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4.
In the U.S., there is no longer any restriction on the use of DIDP in toys intended for children and other child care articles [83 FR 3583, 16 CFR
PART 1307].
In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys and
child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
2005/84/EC].
16. Other information
Reason for issue: Revision
Date revised: 03/25/2024
Revision summary: This SDS replaces the 09/08/2020 SDS.
Page 4 of 5
SC-22
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
SC-22
90000000021_SDS.pdf
900000000219_SDS.pdf
900000000122_SDS.pdf
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 9/23/2024
9/23/2024 (Date of issue) EN (English US) 1/15
SECTION 1: Identification
1.1. Identification
Product form
Trade name
CAS-No.
Product code
Formula
Other means of identification
: Mixture
: Solid White Hi-Gloss Coating
: mixture
: 614-075
: N/A
: Unsaturated Polyester Resin Product
1.2. Recommended use and restrictions on use
Use of the substance/mixture : Coatings
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 2 H225 Highly flammable liquid and vapor
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Reproductive toxicity Category 1B H360 May damage fertility or the unborn child
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated
exposure
Hazardous to the aquatic environment – Acute Hazard Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapor
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 2/15
H319 – Causes serious eye irritation
H360 – May damage fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment.
P241 – Use explosion-proof electrical, lighting, ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapors, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash EXPOSED AREA. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P272 – Contaminated work clothing must not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water.
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see SEEK MEDICAL AID. on this label).
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS..
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 3/15
3.2. Mixtures
Name Product identifier % GHS US classification
styrene, inhibited CAS-No.: 100-42-5 25 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Carc. 2, H351
STOT RE 1, H372
Aquatic Acute 3, H402
methyl ethyl ketone CAS-No.: 78-93-3 2.5 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate CAS-No.: 136-52-7 0.3 Eye Irrit. 2, H319
Skin Sens. 1, H317
Repr. 1B, H360
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this
label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 4/15
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Eliminate all ignition sources if safe to do so. Wash hands and other exposed areas with mild
soap and water before eating, drinking or smoking and when leaving work. Provide good
ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take
precautionary measures against static discharge. Use only non-sparking tools. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-
ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray.
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 5/15
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment.
Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away
from : Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Solid White (mixture)
No additional information available
styrene, inhibited (100-42-5)
USA – ACGIH – Occupational Exposure Limits
ACGIH OEL TWA [ppm] 20 ppm
ACGIH OEL STEL [ppm] 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
No additional information available
methyl ethyl ketone (78-93-3)
USA – ACGIH – Occupational Exposure Limits
ACGIH OEL TWA [ppm] 200 ppm
ACGIH OEL STEL [ppm] 300 ppm
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 6/15
Personal protective equipment symbol(s):
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : White
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 175.1 F
Flash point : 16 F
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.28
Solubility : No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : Explosive under influence of a flame.
Oxidizing properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 7/15
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 Inhalation – Rat 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 Inhalation – Rat [ppm] 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg body weight
ATE US (dermal) 5010 mg/kg body weight
ATE US (gases) 2770 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
styrene, inhibited (100-42-5)
pH Not applicable
cobalt(II) 2-ethylhexanoate (136-52-7)
pH 6.8 (4.03 %; 20 C)
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 8/15
Serious eye damage/irritation : Causes serious eye irritation.
styrene, inhibited (100-42-5)
pH Not applicable
cobalt(II) 2-ethylhexanoate (136-52-7)
pH 6.8 (4.03 %; 20 C)
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : May damage fertility or the unborn child.
Specific target organ toxicity single exposure : Not classified
methyl ethyl ketone (78-93-3)
Specific target organ toxicity single exposure May cause drowsiness or dizziness.
Specific target organ toxicity repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
Specific target organ toxicity repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
styrene, inhibited (100-42-5)
Viscosity, kinematic 0.8 mm /s
methyl ethyl ketone (78-93-3)
Viscosity, kinematic 0.494 mm /s
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : Dangerous for the environment. Harmful to aquatic life.
styrene, inhibited (100-42-5)
LC50 – Fish [1] 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 9/15
styrene, inhibited (100-42-5)
EC50 – Crustacea [1] 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 algae 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 – Fish [1] 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 – Crustacea [1] 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 – Fish [2] 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water; Read-
across)
EC50 – Crustacea [2] 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit – Algae [1] 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit – Algae [2] 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 – Fish [1] 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 – Crustacea [1] 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 algae 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
12.2. Persistence and degradability
Solid White (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD) 2.8 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 2.03 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 10/15
12.3. Bioaccumulative potential
Solid White (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF – Fish [1] 35.5 (Carassius auratus, Literature study)
Partition coefficient n-octanol/water (Log Pow) 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF - Fish [1] 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Partition coefficient n-octanol/water (Log Pow) 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Organic Carbon Normalized Adsorption Coefficient
(Log Koc)
2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Organic Carbon Normalized Adsorption Coefficient
(Log Koc)
1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Sewage disposal recommendations : Do not discharge into drains.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 11/15
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with DOT / TDG / IMDG / IATA
14.1. UN number
DOT NA No : UN1866
UN-No. (TDG) : UN1866
UN-No. (IMDG) : 1866
UN-No. (IATA) : 1866
14.2. UN proper shipping name
Proper Shipping Name (DOT) : Resin solution
Proper Shipping Name (TDG) : RESIN SOLUTION
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
14.3. Transport hazard class(es)
DOT
Transport hazard class(es) (DOT) : 3
Hazard labels (DOT) : 3
TDG
Transport hazard class(es) (TDG) : 3
Hazard labels (TDG) : 3
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 12/15
14.4. Packing group
Packing group (DOT) : II
Packing group (TDG) : II
Packing group (IMDG) : II
Packing group (IATA) : II
14.5. Environmental hazards
Other information : No supplementary information available.
14.6. Special precautions for user
DOT
UN-No.(DOT) : UN1866
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to 5
L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in
173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief
devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail (49
CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
TDG
UN-No. (TDG) : UN1866
Explosive Limit and Limited Quantity Index : 5 L
Excepted quantities (TDG) : E2
Passenger Carrying Road Vehicle or Passenger
Carrying Railway Vehicle Index
: 5 L
Emergency Response Guide (ERG) Number : 127
IMDG
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 13/15
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS
EmS-No. (Spillage) : S-E - SPILLAGE SCHEDULE Echo - FLAMMABLE LIQUIDS, FLOATING ON WATER
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
IATA
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3
ERG code (IATA) : 3L
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. US Federal regulations
Commercial status of components according to the United States Environmental Protection Agency s Toxic Substances Control Act (TSCA):
Name CAS-No. Listing Commercial
status
Flags
styrene, inhibited 100-42-5 Present Active
cobalt(II) 2-ethylhexanoate 136-52-7 Present Active
methyl ethyl ketone 78-93-3 Present Active
styrene, inhibited (100-42-5)
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 14/15
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity
-Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
-Male
No significant risk
level (NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous
Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous
Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Other information : None.
Full text of H-phrases
H225 Highly flammable liquid and vapor
H226 Flammable liquid and vapor
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H351 Suspected of causing cancer
H360 May damage fertility or the unborn child
Solid White Hi-Gloss Coating
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
9/23/2024 (Date of issue) EN (English US) 15/15
Full text of H-phrases
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary
incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can
be ignited under almost all ambient temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change at elevated
temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature conditions.
Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well
as liquids with flash points between 73 F and 100 F. (Classes IB IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo hazardous
polymerization in the absence of inhibitors.
Personal protection : H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
Safety Data Sheet (SDS), USA
900000000106_SDS.pdf
SAFETY DATA SHEET (SDS)
METYX
Glass Fiber Fabric
1
/5 FR-04-2/13.04.2015
1. Identification of the Substance and Company/Undertaking
1.1. Trade Name: METYX Glass Fiber Fabrics
1.2. Chemical Name: Fiber Glass
1.3. Scope: Industrial applications
1.4. Supplier Details:
METYX, USA, Inc.
2504 Lowell Road Gastonia NC 28054
Tel.: +1 704 824 1030
Web: www.metyx.com
e-Mail: metyx@metyx.com
Emergency Phone number: + 704 239 5671
2. Composition/Information on Ingredients
Continuous filament glass fiber including synthetic threading yarn
Ingredient name CAS Number: %
Glass, oxide, chemicals 65997 17 3 >95
Organic Surface Binder/Sizing Not available <5
Continuous filament glass fiber is a glass product which is given a specific shape (filament) and dimension
(filament diameter). A surface treatment (sizing) is applied to the filament which are gathered to form a strand. The
sizing is a mixture of chemicals, i.e. film former, coupling agent and polymeric resin/emulsion. The sizing content
is usually less than or equal to 2%. Non crimp fabrics made with glass fibers are stitched with synthetic yarns.
3. Hazards Identifications
The product is not classified as hazardous according to Regulation (EC) 1272/2008 as amended.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
Product definiton: Article . Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Under normal industrial conditions, product is not flammable and has stability.
3.1. Skin: Directly contact with skin may cause irritation, itching, rash, and swelling. Wear protective clothes.
3.2. Eye: May cause eye irritation, rash, pain. These symptoms may continue after stop working. This condition
may be temporary but may cause permanent influence as cornea. Wear safety glasses.
3.3. Respiratory: May cause respiratory problems. This may damage throat and lungs and cause cough. Wear
respiratory mask.
4. First Aid Measures
4.1. Inhalation: May cause respiratory problem. Move to fresh air. If symptoms persist, call physician.
SAFETY DATA SHEET (SDS)
METYX
Glass Fiber Fabric
2
/5 FR-04-2/13.04.2015
4.2. Skin Contact: If skin irritation does occur, remove contaminated clothing and wash off plenty of water min.
15 minutes without rubbing. Use a mild soap if possible. If symptoms persist, call physician.
4.3. Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes without
rubbing. If eye irritation persists, consult a specialist.
4.4. Ingestion: Gently wipe or rinse the inside of the mouth with water. Consult a physician if necessary.
4.5. Additional information: Mild hydrocortisone skin cream is helpful for skin irritation.
5. Fire Fighting Measures
5.1. Suitable Extinguishing Media: Water, carbon dioxide (CO2), foam, dry chemical. Extinguishing media for B
class fire may be used.
5.2. Special Protective Clothing: In case of big fires self-contained breathing apparatus must be used ad full
protective clothing must be worn.
5.3. Additional information: Only the packaging film, polyester yarn and glass sizing material are likely burn. Combustion
gases are basically carbon dioxide and water vapor. Formation of toxic gases is possible during heating or in case of fire.
There may be small quantities of carbon monoxide and other substances which make it necessary to use protective devices in
the event of a major fire. Fiberglass will not burn, but smoking of the product may occur at approximately 400 - 500 F
(approximately 200 - 260 C) due to decomposition of the surface binder.
Surface binders may decompose in a fire situation and release carbon monoxide, carbon dioxide and water. Additionally,
there are many chemicals that can evolve during any partial decomposition of chemical products. The amounts or identities
cannot be predicted and can differ in each situation.
6. Accidental Release Measures
6.1. Personal Precautions: Provide eyewash stations. Under normal industrial conditions, this product is not
flammable and has stability. See chapter 8.
6.2. Environmental Precautions: No special environmental precautions required.
6.3. Spill Cleanup Methods: NONE.
7. Handling & Storage
7.1. Usage Precautions: Wear appropriate personal protective equipment in case of direct contact with the product
(See section 8). Provide adequate ventilation. Prevent and/or minimize dust formation. Keep away heating
sources.
7.2. Storage Precautions: Keep product in its packaging until use to minimize potential dust generation. Store in
original package in a cool, dry place. Packing material must be prevented to damage during transporting and
carrying.
7.3. Special Usage: Vacuum clean, sweep or shovel carefully in order to prevent dust suspension.
SAFETY DATA SHEET (SDS)
METYX
Glass Fiber Fabric
3
/5 FR-04-2/13.04.2015
8. Exposure Control & Personal Protection
Continuous filament glass fibers are not respirable however certain mechanical processes might generate
airborne dust or fiber (See section 11).
8.1. Engineering Measures:
Occupational Exposure Limits (OEL)
Fiber Glass Continuous Filament (65997-17-3)
The American Conference of Governmental Hygienists has adopted a Threshold Limit Value (TLV) for fibrous
dust of 15mg/m (total) and 5mg/m (respirable). The Occupational Safety and Health Administration (OSHA)
does not prescribe a Permissible Exposure Limit (PEL) for fibrous glass but relies on the PEL-TWA s for
nuisance dust of 15mg/m (total) and 5mg/m (respirable).
Respirable fraction: 1 fiber/cc (related to respirable particulate with fiber-like dimensions (glass shards)
8.2. Respiratory Equipment: Provide adequate ventilation to ensure that the defined workplace exposure limit is
not exceeded. If use or application generates dust, use an appropriate respirator with a particulate filter.
8.3. Skin Protect: Skin irritation is known to occur chiefly at the pressure points such as around the neck, wrists,
and waist and between the fingers. Long-sleeved garments and long leggings are recommended to prevent irritation
Wear protective gloves (nitrile rubber, butyl rubber, PVC, Viton ).
8.4. Eye Protect: Wear safety glasses with side-shields.
8.5. Hygiene Considerations: Wash hands before breaks and immediately after handling the product
Avoid contact with skin, eyes and clothing
Avoid getting dust into boots and gloves through wrist bands and pant tucks
Remove and wash contaminated clothing before re-use
9. Physical & Chemical Specifications
9.1. Appear./Form/Odor: Solid, white, roll, odorless
9.2. Density: Glass: aprx. 2.6 g/cm
9.3. pH : not applicable
9.4. Viscosity: not applicable
9.5. Solubility: insoluble in water and oil
9.6. Vapor Pressure: not applicable
9.7. Flash Point: not applicable
9.8. Ignition Temp.: not applicable
9.9. Melting Point: Glass:~ 800-850 C,
9.10. Boiling Temp.: not applicable
9.11. Explosion Limits: not applicable
9.12. Thermal Decomposition: not applicable, see chapter 10
9.13. Other: Friction may cause static electricity
SAFETY DATA SHEET (SDS)
METYX
Glass Fiber Fabric
4
/5 FR-04-2/13.04.2015
10. Stability & Reactivity
10.1. Conditions to Avoid: High humidity and heat can affect product properties
10.2. Materials to Avoid: Moisture, strong oxidizing agents
10.3. Hazardous Decomposition Products: Long time high heat exposure can damage surface coating of product.
CO and NOx gasses can be released.
10.4 Possibility of hazardous reactions. Reacts with strong oxidizing agents, alkali, amines and acids
11. Toxicological Information
Glass fibers Short term effects:
Dusts and fibers may cause mechanical irritation to eyes and skin. The irritation disappears when the exposure
ceases. Mechanical irritation is not considered as a health hazard in the meaning of Regulation (EC) No 1272/2008
on hazardous substance. Continous filament glass fibers do not require a classification as an irritant (Xi) under the
Regulation (EC) No 1272/2008. Inhalation may cause coughing, nose and throat irritation and sneezing. High
exposures may cause difficult breathing, congestion and chest tightness.
Glass fibers Long term effects:
There are no known health effects from the long term use or contact with non-respirable continuous filament fibers.
Non-respirable fibers cannot reach the deep lung because they have a diameter of greater than 3.5 micrometers.
Fibers of this diameter cannot penetrate the narrow, bending passages of the human respiratory tract to reach the
lower regions of the lung and thus, have no possibility of causing serious pulmonary damage. Instead, they deposit
on the surfaces of the upper respiratory tract, nose, or pharynx. These fibers are then cleared through normal
physiological mechanisms.
Powder effects: When used and handled according to specifications, the product does not have any harmful effects
according to our experience and the information provided to us.
12. Ecological Information
12.1 Ecotoxicity: N/A
12.2 Mobility: N/A
12.3 Stability &Decomposition: N/A
12.4 Bioaccumulatetive: N/A
12.5 Other: N/A
13. Disposal Considerations
This product can be considered as immobile solid waste and disposed as solid waste. Glass fiber must be
destroyed depending on local regulations. The generation of waste should be avoided or minimised wherever possible.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements.
SAFETY DATA SHEET (SDS)
METYX
Glass Fiber Fabric
5
/5 FR-04-2/13.04.2015
If glass fiber involves any resin to form a composite structure (cured or half cured), disposing of this material
must do considering disposal consideration of the resin.
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
14. Transport Information
Not classified as dangerous in the meaning of transport regulations.
Not classified as a hazardous material with respect to transportation regulations (ADR for road,
RID for rail, IMDG for sea and ICAO/IATA for air transport).
15. Regulatory Information
This product is not hazardous according to
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 -
United Kingdom (UK). Annex XIV - List of substances subject to authorisation No SVHC's normally expected above 0.1%
w/w
The international Agency for Research on Cancer (IARC) in June, 1987 and in October, 2001, categorized
continuous filament fiber glass as not classifiable with respect to human carcinogenicity (Group 3). The evidence
from human, as well as, animal studies was evaluated by IARC as insufficient to classify continuous filament fiber
glass as a confirmed, probable or even possible cancer causing material.
16. Other Information
Full text of abbreviated H Statements: Not applicable.
Full text of classifications [CLP/GHS]: Not applicable.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Rev date.26.04.2018
DISCLAIMER
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text. Users assume full
responsibility for applying the appropriate safety measures when the product used.