by | Sep 27, 2025
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)Page 1
SECTION 1: Identification
1.1. Identification
Product form :MixturesTrade name :BLACK VINYL ESTER REPAIR PUTTYCAS-No. :mixtureProduct code :1802-007Formula :na
1.2. Recommended use and restrictions on use
Use of the substance/mixture :MOLD REPAIR PUTTY
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number :ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 2
H225 Highly flammable liquid and vaporSkin corrosion/irritation
Category 2
H315 Causes skin irritationSerious eye damage/eye
irritation Category 2A
H319 Causes serious eye irritationCarcinogenicity Category 2H351 Suspected of causing cancerReproductive toxicity
Category 2
H361 Suspected of damaging fertility or the unborn childSpecific target organ
toxicity (single exposure)
Category 3
H335 May cause respiratory irritationSpecific target organ
toxicity (repeated exposure)
Category 1
H372 Causes damage to organs through prolonged or repeated exposure
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02GHS07GHS08
Signal word (GHS-US) :DangerHazard statements (GHS-US) :H225 – Highly flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)2/11 H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) :P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
NameProduct identifier%GHS-US classificationUnsaturated VINYL ESTER Resin(CAS-No.) TRADE SECRET<= 34Not classifiedstyrene, inhibited(CAS-No.) 100-42-5<= 28Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
talc(CAS-No.) 14807-96-6<= 24Not classifiedmethyl ethyl ketone(CAS-No.) 78-93-3<= 2Flam. Liq. 2, H225
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate(CAS-No.) 136-52-7<= 0.5Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)3/11
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general :Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation :Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact :Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention.
Specific treatment (see seek medical attention. on this label).
First-aid measures after eye contact :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects :May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.Unsuitable extinguishing media :Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard :Highly flammable liquid and vapor.Explosion hazard :May form flammable/explosive vapor-air mixture.Reactivity :No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting :Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures :Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1.For non-emergency personnel
Protective equipment :Gloves. Protective goggles. Protective clothing.Emergency procedures :Evacuate unnecessary personnel.
6.1.2.For emergency responders
Protective equipment :Equip cleanup crew with proper protection.Emergency procedures :Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment :Dam up the liquid spill. Contain released product, pump into suitable containers.
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)4/11Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed :Handle empty containers with care because residual vapors are flammable.Precautions for safe handling :Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a
well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so.
Hygiene measures :Wash HANDS thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures :Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions :Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products :Strong bases. Strong acids.Incompatible materials :Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)ACGIHACGIH TWA (ppm)20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
methyl ethyl ketone (78-93-3)ACGIHACGIH TWA (ppm)200 ppm (Methyl ethyl ketone (MEK); USA; Time-
weighted average exposure limit 8 h; TLV - Adopted
Value)
ACGIHACGIH STEL (ppm)300 ppm (Methyl ethyl ketone (MEK); USA; Short time
value; TLV - Adopted Value)
cobalt(II) 2-ethylhexanoate (136-52-7)Not applicableUnsaturated VINYL ESTER Resin (TRADE SECRET)Not applicabletalc (14807-96-6)ACGIHACGIH TWA (mg/m )2 mg/m (Talc (containing no asbestos fibers); USA;
Time-weighted average exposure limit 8 h; TLV -
Adopted Value; Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica; Talc (containing asbestos fibers); 0.1
fibers/cm ; USA; Time-weighted average exposure
limit 8 h; TLV - Adopted Value; Respirable fibers:
length > 5 m; aspect ratio 3:1, as determined by the
membrane filter method at 400-450X magnification (4-
mm objective), using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls :Ensure exposure is below occupational exposure limits (where available).
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)5/11
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:Avoid all unnecessary exposure.
Hand protection:Wear protective glovesEye protection:Chemical goggles or safety glassesSkin and body protection:Wear suitable protective clothing
Respiratory protection:Wear appropriate mask
Other information:Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state :Liquid
Color :Black
Odor :characteristic
Odor threshold :No data available
pH :No data available
Melting point :No data available
Freezing point :No data available
Boiling point :>= 64.4 C
Flash point :>= -6.67 C
Relative evaporation rate (butyl acetate=1) :No data available
Flammability (solid, gas) :Highly flammable liquid and vapor.
Vapor pressure :No data available
Relative vapor density at 20 C :No data available
Relative density :No data available
Specific gravity / density :1.4Solubility :No data available
Log Pow :No data available
Auto-ignition temperature :No data available
Decomposition temperature :No data available
Viscosity, kinematic :No data available
Viscosity, dynamic :No data available
Explosion limits :No data available
Explosive properties :No data available
Oxidizing properties :No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2.Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture.
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)6/11
10.3.Possibility of hazardous reactions
Not established.
10.4.Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5.Incompatible materials
Strong acids. Strong bases.
10.6.Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1.Information on toxicological effects
Acute toxicity :Not classifiedstyrene, inhibited (100-42-5)LD50 oral rat5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)LD50 dermal rat2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit5010 mg/kg (Rabbit; Literature study)LC50 inhalation rat (mg/l)12 mg/l/4h (Rat; Literature study)LC50 inhalation rat (ppm)2770 ppm/4h (Rat; Literature study)ATE US (oral)5000.000 mg/kg body weightATE US (dermal)2820.000 mg/kg body weightATE US (gases)2770.000 ppmV/4hATE US (vapors)12.000 mg/l/4hATE US (dust, mist)1.500 mg/l/4hmethyl ethyl ketone (78-93-3)ATE US (oral)2737.000 mg/kg body weightATE US (dermal)6480.000 mg/kg body weightATE US (gases)11300.000 ppmV/4hATE US (vapors)34.000 mg/l/4hATE US (dust, mist)34.000 mg/l/4hcobalt(II) 2-ethylhexanoate (136-52-7)LD50 oral rat3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat> 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)ATE US (oral)3129.000 mg/kg body weightSkin corrosion/irritation :Causes skin irritation.Serious eye damage/irritation :Causes serious eye irritation.Respiratory or skin sensitization :Not classifiedGerm cell mutagenicity :Not classifiedCarcinogenicity :Suspected of causing cancer.styrene, inhibited (100-42-5)IARC group2B – Possibly carcinogenic to humanscobalt(II) 2-ethylhexanoate (136-52-7)IARC group2B – Possibly carcinogenic to humanstalc (14807-96-6)IARC group3 – Not classifiableReproductive toxicity :Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure:May cause respiratory irritation.
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)7/11Specific target organ toxicity repeated
exposure
:Causes damage to organs through prolonged or repeated exposure.Aspiration hazard :Not classifiedPotential Adverse human health effects and
symptoms
:Harmful if inhaled.Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
SECTION 12: Ecological information
12.1.Toxicity
methyl ethyl ketone (78-93-3)EC50 Daphnia 1308 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna;
Static system; Fresh water; Experimental value)
LC50 fish 22993 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Static
system; Fresh water; Experimental value)
cobalt(II) 2-ethylhexanoate (136-52-7)LC50 fish 146.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 10.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)LC50 fish 254.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 20.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)Threshold limit algae 1144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 232.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
talc (14807-96-6)LC50 fish 1> 100 g/l (LC50; 24 h; Brachydanio rerio)
12.2.Persistence and degradability
BLACK VINYL ESTER REPAIR PUTTY (mixture)Persistence and degradabilityNot established.styrene, inhibited (100-42-5)Persistence and degradabilityReadily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD)0.42methyl ethyl ketone (78-93-3)Persistence and degradabilityReadily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
ThOD
2.44 g O /g substance
BOD (% of ThOD)> 0.5 (5 days; Literature study)cobalt(II) 2-ethylhexanoate (136-52-7)Persistence and degradabilityReadily biodegradable in water. No (test)data on mobility of the substance available.Unsaturated VINYL ESTER Resin (TRADE SECRET)Persistence and degradabilityNot established.
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)8/11talc (14807-96-6)Persistence and degradabilityBiodegradability: not applicable.Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
12.3.Bioaccumulative potential
BLACK VINYL ESTER REPAIR PUTTY (mixture)Bioaccumulative potentialNot established.styrene, inhibited (100-42-5)BCF fish 135.5 (BCF)Log Pow2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500). Not established.methyl ethyl ketone (78-93-3)Log Pow0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potentialLow potential for bioaccumulation (Log Kow < 4). Not established.cobalt(II) 2-ethylhexanoate (136-52-7)BCF fish 11.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500).Unsaturated VINYL ESTER Resin (TRADE SECRET)Bioaccumulative potentialNot established.
12.4.Mobility in soil
styrene, inhibited (100-42-5)Surface tension0.032 N/m (19 C)Log KocKoc,352; Estimated value; log Koc; 2.55; Estimated valuemethyl ethyl ketone (78-93-3)Surface tension0.024 N/m (20 C)Log KocKoc,34; Calculated valueEcology - soilSlightly harmful to plants.cobalt(II) 2-ethylhexanoate (136-52-7)Surface tension0.064 N/m (20 C; 1 g/l)
12.5.Other adverse effects
Effect on the global warming :No known effects from this product.GWPmix comment :No known effects from this product.Other information :Avoid release to the environment.
SECTION 13: Disposal considerations
13.1.Disposal methods
Product/Packaging disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information :Handle empty containers with care because residual vapors are flammable.Ecology - waste materials :Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Proper Shipping Name (DOT) :RESIN SOLUTION
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)9/11Class (DOT) :3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120Packing group (DOT) :II - Medium DangerHazard labels (DOT) :3 - Flammable liquidOther information :No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) :UN 1866 RESIN SOLUTION, 3, IIUN-No. (IMDG) :1866Proper Shipping Name (IMDG) :RESIN SOLUTIONClass (IMDG) :3 - Flammable liquidsPacking group (IMDG) :II - substances presenting medium danger
Air transport
Transport document description (IATA) :UN 1866 RESIN SOLUTION, 3, IIUN-No. (IATA) :1866Proper Shipping Name (IATA) :RESIN SOLUTIONClass (IATA) :3 - Flammable LiquidsPacking group (IATA) :II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)CERCLA RQ1000 lbSARA Section 311/312 Hazard ClassesImmediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)CERCLA RQ5000 lbtalc (14807-96-6)Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
No additional information available
talc (14807-96-6)Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)10/11styrene, inhibited (100-42-5)Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
NoNoNoNo0.1 g/daystyrene, inhibited (100-42-5)U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
talc (14807-96-6)U.S. - New Jersey - Right to Know Hazardous Substance List
SECTION 16: Other information
Data sources :REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information :None.Full text of H-phrases:---
---
H225Highly flammable liquid and vapor---
---
H226Flammable liquid and vapor---
---
H315Causes skin irritation---
---
H317May cause an allergic skin reaction---
---
H319Causes serious eye irritation---
---
H332Harmful if inhaled---
---
H335May cause respiratory irritation---
---
H336May cause drowsiness or dizziness---
---
H351Suspected of causing cancer---
---
H361Suspected of damaging fertility or the unborn child---
---
H372Causes damage to organs through prolonged or repeated exposure---
---
H400Very toxic to aquatic life---
---
H411Toxic to aquatic life with long lasting effectsNFPA health hazard :2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard :3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity :2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
BLACK VINYL ESTER REPAIR PUTTY
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)11/11Hazard RatingHealth :2 Moderate Hazard - Temporary or minor injury may occurFlammability :3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical :1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
:HPersonal protection H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)Page 1
SECTION 1: Identification
1.1. Identification
Product form :MixturesTrade name :CLEAR VINYL ESTER SEALERCAS-No. :mixtureProduct code :1800AFormula :na
1.2. Recommended use and restrictions on use
Use of the substance/mixture :COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number :ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 3
H226 Flammable liquid and vaporAcute toxicity
(inhalation:vapour)
Category 4
H332 Harmful if inhaledSkin corrosion/irritation
Category 2
H315 Causes skin irritationSerious eye damage/eye
irritation Category 2A
H319 Causes serious eye irritationCarcinogenicity Category 2H351 Suspected of causing cancerReproductive toxicity
Category 2
H361 Suspected of damaging fertility or the unborn childSpecific target organ
toxicity (single exposure)
Category 3
H335 May cause respiratory irritationSpecific target organ
toxicity (repeated exposure)
Category 1
H372 Causes damage to organs through prolonged or repeated exposure
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02GHS07GHS08
Signal word (GHS-US) :DangerHazard statements (GHS-US) :H226 – Flammable liquid and vapor
H315 – Causes skin irritation
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)2/10 H319 – Causes serious eye irritation
H332 – Harmful if inhaled
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) :P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust/fume/gas/mist/vapors/spray
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray
P264 – Wash exposed area. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell
P321 – Specific treatment (see none listed. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to in accordance with local, state, and federal regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
NameProduct identifier%GHS-US classificationstyrene, inhibited(CAS-No.) 100-42-5<= 62Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Unsaturated VINYL ESTER Resin(CAS-No.) TRADE SECRET<= 33Not classifiedacetone(CAS-No.) 67-64-1<= 5Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate(CAS-No.) 136-52-7<= 0.5Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)3/10
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general :Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation :Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention.
Specific treatment (see seek medical attention. on this label).
First-aid measures after eye contact :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects :May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.Unsuitable extinguishing media :Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard :Highly flammable liquid and vapor. Flammable liquid and vapor.Explosion hazard :May form flammable/explosive vapor-air mixture.Reactivity :No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting :Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures :Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1.For non-emergency personnel
Protective equipment :Gloves. Protective goggles. Protective clothing.Emergency procedures :Evacuate unnecessary personnel.
6.1.2.For emergency responders
Protective equipment :Equip cleanup crew with proper protection.Emergency procedures :Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment :Dam up the liquid spill. Contain released product, pump into suitable containers.
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)4/10Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed :Handle empty containers with care because residual vapors are flammable.Precautions for safe handling :Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a
well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so. Take precautionary measures against
static discharge. Do not breathe dust/fume/gas/mist/vapors/spray.
Hygiene measures :Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures :Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions :Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products :Strong bases. Strong acids.Incompatible materials :Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)ACGIHACGIH TWA (ppm)20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
Unsaturated VINYL ESTER Resin (TRADE SECRET)Not applicablecobalt(II) 2-ethylhexanoate (136-52-7)Not applicableacetone (67-64-1)ACGIHACGIH TWA (ppm)500 ppm (Acetone; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)750 ppm (Acetone; USA; Short time value; TLV -
Adopted Value)
8.2. Appropriate engineering controls
Appropriate engineering controls :Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:Avoid all unnecessary exposure.
Hand protection:Wear protective glovesEye protection:Chemical goggles or safety glassesSkin and body protection:
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)5/10
Wear suitable protective clothing
Respiratory protection:Wear appropriate mask
Other information:Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state :Liquid
Color :clear
Odor :characteristic
Odor threshold :No data available
pH :No data available
Melting point :No data available
Freezing point :No data available
Boiling point :>= 56.1 – 146 C
Flash point :>= -20 C
Relative evaporation rate (butyl acetate=1) :No data available
Flammability (solid, gas) :Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure :No data available
Relative vapor density at 20 C :No data available
Relative density :No data available
Specific gravity / density :1.1Solubility :No data available
Log Pow :No data available
Auto-ignition temperature :No data available
Decomposition temperature :No data available
Viscosity, kinematic :No data available
Viscosity, dynamic :No data available
Explosion limits :No data available
Explosive properties :No data available
Oxidizing properties :No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2.Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3.Possibility of hazardous reactions
Not established.
10.4.Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5.Incompatible materials
Strong acids. Strong bases.
10.6.Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)6/10
SECTION 11: Toxicological information
11.1.Information on toxicological effects
Acute toxicity :Inhalation:vapour: Harmful if inhaled.CLEAR VINYL ESTER SEALER (mixture)ATE US (vapors)11.000 mg/l/4hstyrene, inhibited (100-42-5)LD50 oral rat5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)LD50 dermal rat2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit5010 mg/kg (Rabbit; Literature study)LC50 inhalation rat (mg/l)12 mg/l/4h (Rat; Literature study)LC50 inhalation rat (ppm)2770 ppm/4h (Rat; Literature study)ATE US (oral)5000.000 mg/kg body weightATE US (dermal)2820.000 mg/kg body weightATE US (gases)2770.000 ppmV/4hATE US (vapors)12.000 mg/l/4hATE US (dust, mist)1.500 mg/l/4hcobalt(II) 2-ethylhexanoate (136-52-7)LD50 oral rat3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat> 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)ATE US (oral)3129.000 mg/kg body weightacetone (67-64-1)LD50 oral rat5800 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value)LD50 dermal rabbit20000 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >7426 mg/kg
bodyweight; Rabbit; Weight of evidence)
LC50 inhalation rat (mg/l)71 mg/l/4h (Rat; Experimental value; 76 mg/l/4h; Rat; Experimental value)LC50 inhalation rat (ppm)30000 ppm/4h (Rat; Experimental value)ATE US (oral)5800.000 mg/kg body weightATE US (dermal)20000.000 mg/kg body weightATE US (gases)30000.000 ppmV/4hATE US (vapors)71.000 mg/l/4hATE US (dust, mist)71.000 mg/l/4hSkin corrosion/irritation :Causes skin irritation.Serious eye damage/irritation :Causes serious eye irritation.Respiratory or skin sensitization :Not classifiedGerm cell mutagenicity :Not classifiedCarcinogenicity :Suspected of causing cancer.styrene, inhibited (100-42-5)IARC group2B – Possibly carcinogenic to humanscobalt(II) 2-ethylhexanoate (136-52-7)IARC group2B – Possibly carcinogenic to humansReproductive toxicity :Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure:May cause respiratory irritation.Specific target organ toxicity repeated
exposure
:Causes damage to organs through prolonged or repeated exposure.Aspiration hazard :Not classifiedPotential Adverse human health effects and
symptoms
:Harmful if inhaled. Based on available data, the classification criteria are not met.
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)7/10Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
SECTION 12: Ecological information
12.1.Toxicity
cobalt(II) 2-ethylhexanoate (136-52-7)LC50 fish 146.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 10.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)LC50 fish 254.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 20.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)Threshold limit algae 1144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 232.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
acetone (67-64-1)LC50 fish 25540 mg/l (LC50; EU Method C.1; 96 h; Salmo gairdneri; Static system; Fresh water;
Experimental value)
EC50 Daphnia 212600 mg/l (LC50; Other; 48 h; Daphnia magna; Static system; Fresh water; Experimental
value)
12.2.Persistence and degradability
CLEAR VINYL ESTER SEALER (mixture)Persistence and degradabilityNot established.styrene, inhibited (100-42-5)Persistence and degradabilityReadily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD)0.42Unsaturated VINYL ESTER Resin (TRADE SECRET)Persistence and degradabilityNot established.cobalt(II) 2-ethylhexanoate (136-52-7)Persistence and degradabilityReadily biodegradable in water. No (test)data on mobility of the substance available.acetone (67-64-1)Persistence and degradabilityReadily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available.
Biochemical oxygen demand (BOD)
1.43 g O /g substance
Chemical oxygen demand (COD)
1.92 g O /g substance
ThOD
2.2 g O /g substance
BOD (% of ThOD)0.872 (20 days; Literature study)
12.3.Bioaccumulative potential
CLEAR VINYL ESTER SEALER (mixture)Bioaccumulative potentialNot established.styrene, inhibited (100-42-5)BCF fish 135.5 (BCF)Log Pow2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500). Not established.
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)8/10Unsaturated VINYL ESTER Resin (TRADE SECRET)Bioaccumulative potentialNot established.cobalt(II) 2-ethylhexanoate (136-52-7)BCF fish 11.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500).acetone (67-64-1)BCF fish 10.69 (BCF)BCF other aquatic organisms 13 (BCF; BCFWIN)Log Pow-0.24 (Test data)Bioaccumulative potentialNot bioaccumulative.
12.4.Mobility in soil
styrene, inhibited (100-42-5)Surface tension0.032 N/m (19 C)Log KocKoc,352; Estimated value; log Koc; 2.55; Estimated valuecobalt(II) 2-ethylhexanoate (136-52-7)Surface tension0.064 N/m (20 C; 1 g/l)acetone (67-64-1)Surface tension0.0237 N/m
12.5.Other adverse effects
Effect on the global warming :No known effects from this product.GWPmix comment :No known effects from this product.Other information :Avoid release to the environment.
SECTION 13: Disposal considerations
13.1.Disposal methods
Product/Packaging disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information :Handle empty containers with care because residual vapors are flammable.Ecology - waste materials :Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Proper Shipping Name (DOT) :PAINTClass (DOT) :3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120Packing group (DOT) :II - Medium DangerHazard labels (DOT) :3 - Flammable liquidOther information :No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) :UN 1263 paint, 3, IIUN-No. (IMDG) :1263
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)9/10Proper Shipping Name (IMDG) :paintClass (IMDG) :3 - Flammable liquidsPacking group (IMDG) :II - substances presenting medium danger
Air transport
Transport document description (IATA) :UN 1263 paint, 3, IIUN-No. (IATA) :1263Proper Shipping Name (IATA) :paintClass (IATA) :3 - Flammable LiquidsPacking group (IATA) :II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)CERCLA RQ1000 lbSARA Section 311/312 Hazard ClassesImmediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
acetone (67-64-1)Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporing requirements of the United States SARA Section 313
CERCLA RQ5000 lb
15.2. International regulations
CANADA
No additional information available
acetone (67-64-1)Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
NoNoNoNo0.1 g/daystyrene, inhibited (100-42-5)U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
CLEAR VINYL ESTER SEALER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/11/2018EN (English US)10/10acetone (67-64-1)U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
Other information :None.Full text of H-phrases:---
---
H225Highly flammable liquid and vapor---
---
H226Flammable liquid and vapor---
---
H315Causes skin irritation---
---
H317May cause an allergic skin reaction---
---
H319Causes serious eye irritation---
---
H332Harmful if inhaled---
---
H335May cause respiratory irritation---
---
H336May cause drowsiness or dizziness---
---
H351Suspected of causing cancer---
---
H361Suspected of damaging fertility or the unborn child---
---
H372Causes damage to organs through prolonged or repeated exposure---
---
H400Very toxic to aquatic life---
---
H411Toxic to aquatic life with long lasting effectsNFPA health hazard :2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard :3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity :2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard RatingHealth :2 Moderate Hazard - Temporary or minor injury may occurFlammability :3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical :1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
:HPersonal protection H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 11/21/2019
11/21/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : VINYL ESTER FAIRING PRIMER
CAS-No. : mixture
Product code : 1799-052
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H336 – May cause drowsiness or dizziness.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
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11/21/2019 EN (English) 2/13
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, fume, mist, spray, vapours.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
styrene, inhibited
(CAS-No.) 100-42-5 <= 27 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
talc
(CAS-No.) 14807-96-6 <= 24 Carc. 2, H351
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 14 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 13 Carc. 2, H351
Aquatic Acute 3, H402
2-propanol
(CAS-No.) 67-63-0 <= 2 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
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Name Product identifier % GHS-US classification
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Eliminate all ignition sources if safe to do so. Do
not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
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talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Grey Blue
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : No data available
Relative density : 0.9
Density : 8 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
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Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapour. May form
flammable/explosive vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation. May cause drowsiness or dizziness.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
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SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
VINYL ESTER FAIRING PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
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methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
VINYL ESTER FAIRING PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
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titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
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DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
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11/21/2019 EN (English) 12/13
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 11/21/2019
Other information : None.
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 13/13
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 11/21/2019
11/21/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : VINYL ESTER FAIRING PRIMER
CAS-No. : mixture
Product code : 1799-052
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H336 – May cause drowsiness or dizziness.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
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Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, fume, mist, spray, vapours.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
styrene, inhibited
(CAS-No.) 100-42-5 <= 27 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
talc
(CAS-No.) 14807-96-6 <= 24 Carc. 2, H351
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 14 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 13 Carc. 2, H351
Aquatic Acute 3, H402
2-propanol
(CAS-No.) 67-63-0 <= 2 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
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Name Product identifier % GHS-US classification
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
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Safety Data Sheet
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Eliminate all ignition sources if safe to do so. Do
not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
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talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Grey Blue
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : No data available
Relative density : 0.9
Density : 8 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
VINYL ESTER FAIRING PRIMER
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Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapour. May form
flammable/explosive vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation. May cause drowsiness or dizziness.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
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SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
VINYL ESTER FAIRING PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 9/13
methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
VINYL ESTER FAIRING PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 10/13
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 11/13
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 12/13
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 11/21/2019
Other information : None.
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 13/13
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Revision date: 8/23/2019
8/23/2019
EN (English US) 1/18
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : GREY VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1799-006
Type of product : Coating
Formula : na
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : COATING
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixtures: SDS < 2015 : Show CLP information + DPD classification in
section 2.1
Flammable liquids Category 2 H225
Acute toxicity (inhalation:vapour) Category 4 H332
Skin corrosion/irritation Category 2 H315
Serious eye damage/eye irritation Category 2 H319
Germ cell mutagenicity Category 1B H340
Carcinogenicity Category 1B H350
Reproductive toxicity Category 2 H361
Specific target organ toxicity (repeated exposure) Category 1 H372
Hazardous to the aquatic environment - Chronic Hazard Category 3 H412
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 2/18
2.2. Label elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : Danger
Hazardous ingredients : styrene, inhibited; Solvent Naptha Petroleum Aliphatic
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H340 - May cause genetic defects.
H350 - May cause cancer.
H361 - Suspected of damaging fertility or the unborn child.
H372 - Causes damage to organs through prolonged or repeated exposure.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P233 - Keep container tightly closed.
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof equipment.
P260 - Do not breathe dust, mist, vapors, fume.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water .
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P312 - Call a POISON CENTRE or doctor if you feel unwell.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder, foam to
extinguish.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
EUH phrases : EUH208 - Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic
reaction.
2.3. Other hazards
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according
to Directive 67/548/EEC
Classification
according to
Regulation (EC) No.
1272/2008 [CLP]
talc (CAS-No.) 14807-96-6
(EC-No.) 238-877-9
(REACH-no) No data
available
<= 31.5 Not classified Not classified
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 3/18
styrene, inhibited (CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
<= 25 R10
Xn; R20
Xi; R36/38
Flam. Liq. 3, H226
Repr. 2, H361d
STOT RE 1, H372
Acute Tox. 4 (Inhalation),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
methyl ethyl ketone (CAS-No.) 78-93-3
(EC-No.) 201-159-0
(EC Index-No.) 606-002-00-3
(REACH-no) 01-2119457290-
43
<= 5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide (CAS-No.) 13463-67-7
(EC-No.) 236-675-5
(REACH-no) 01-2119489379-
17
<= 4 Not classified Not classified
Solvent Naptha Petroleum Aliphatic (CAS-No.) 64742-89-8
(REACH-no) 01-2119471306-
40
<= 2 Not classified Muta. 1B, H340
Carc. 1B, H350
Asp. Tox. 1, H304
n-butyl acetate (CAS-No.) 123-86-4
(EC-No.) 204-658-1
(EC Index-No.) 607-025-00-1
(REACH-no) 01-2119485493-
29
<= 1 R10
R66
R67
Flam. Liq. 3, H226
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7
(EC-No.) 205-250-6
(REACH-no) 01-2119524678-
29
<= 0.5 Repr.Cat.3; R62
R43
N; R50/53
Skin Sens. 1, H317
Repr. 2, H361f
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
2-propanol (CAS-No.) 67-63-0
(EC-No.) 200-661-7
(EC Index-No.) 603-117-00-0
(REACH-no) 01-2119457558-
25
<= 0.5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
isobutyl acetate (CAS-No.) 110-19-0
(EC-No.) 203-745-1
(EC Index-No.) 607-026-00-7
(REACH-no) 01-2119488971-
22
<= 0.5 Not classified Flam. Liq. 2, H225
Specific concentration limits:
Name Product identifier Specific concentration limits:
DSD/DPD
Specific concentration
limits: CLP
styrene, inhibited
(CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
(12.5 =< C < 100) Xi;R36/38
(12.5 =< C < 100) Xn;R20
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing.
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first
aid instruction on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 4/18
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged
exposure through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour. Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew
with proper protection. For further information refer to section 8: "Exposure
controls/personal protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Take precautionary measures against static
discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work. Provide good ventilation in process area to prevent formation of vapor. No
open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke
when using this product. Always wash hands after handling the product.
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7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in
fireproof place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
Belgium Limit value (mg/m ) 108 mg/m
Belgium Limit value (ppm) 25 ppm
Belgium Short time value (mg/m ) 216 mg/m
Belgium Short time value (ppm) 50 ppm
France VME (mg/m ) 100 mg/m
France VME (ppm) 23.3 ppm
France VLE (mg/m ) 200 mg/m
France VLE (ppm) 46.6 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 430 mg/m
United Kingdom WEL TWA (ppm) 100 ppm
United Kingdom WEL STEL (mg/m ) 1080 mg/m
United Kingdom WEL STEL (ppm) 250 ppm
USA - ACGIH ACGIH TWA (ppm) 20 ppm
USA - ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 0.1 mg/m Cobalt compounds (as Co); United Kingdom;
Time-weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
methyl ethyl ketone (78-93-3)
EU IOELV TWA (mg/m ) 600 mg/m
EU IOELV TWA (ppm) 200 ppm
EU IOELV STEL (mg/m ) 900 mg/m
EU IOELV STEL (ppm) 300 ppm
Belgium Limit value (mg/m ) 600 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 900 mg/m
Belgium Short time value (ppm) 300 ppm
France VME (mg/m ) 600 mg/m
France VME (ppm) 200 ppm
France VLE (mg/m ) 900 mg/m
France VLE (ppm) 300 ppm
Germany TRGS 910 Acceptable concentration notes
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methyl ethyl ketone (78-93-3)
Netherlands Grenswaarde TGG 8H (mg/m ) 590 mg/m
Netherlands Grenswaarde TGG 8H (ppm) 197 ppm
Netherlands Grenswaarde TGG 15MIN (mg/m ) 900 mg/m
Netherlands Grenswaarde TGG 15MIN (ppm) 300 ppm
United Kingdom WEL TWA (mg/m ) 600 mg/m
United Kingdom WEL TWA (ppm) 200 ppm
United Kingdom WEL STEL (mg/m ) 899 mg/m
United Kingdom WEL STEL (ppm) 300 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
Belgium Limit value (mg/m ) 10 mg/m
France VME (mg/m ) 10 mg/m
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 10 mg/m
4 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 10 mg/m
n-butyl acetate (123-86-4)
Belgium Limit value (mg/m ) 723 mg/m (Ac tate de n-butyle; Belgium; Time-
weighted average exposure limit 8 h)
Belgium Limit value (ppm) 150 ppm (Ac tate de n-butyle; Belgium; Time-weighted
average exposure limit 8 h)
Belgium Short time value (mg/m ) 964 mg/m (Ac tate de n-butyle; Belgium; Short time
value)
Belgium Short time value (ppm) 200 ppm (Ac tate de n-butyle; Belgium; Short time
value)
France VME (mg/m ) 710 mg/m (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VME (ppm) 150 ppm (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VLE (mg/m ) 940 mg/m (Ac tate de n-butyle; France; Short time
value; VL: Valeur non r glementaire indicative)
France VLE (ppm) 200 ppm (Ac tate de n-butyle; France; Short time value;
VL: Valeur non r glementaire indicative)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m Butyl acetate; United Kingdom; Time-
weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
United Kingdom WEL TWA (ppm) 150 ppm Butyl acetate; United Kingdom; Time-weighted
average exposure limit 8 h; Workplace exposure limit
(EH40/2005)
United Kingdom WEL STEL (mg/m ) 966 mg/m Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
United Kingdom WEL STEL (ppm) 200 ppm Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
USA - ACGIH ACGIH TWA (ppm) 150 ppm (n-Butyl acetate; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value)
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n-butyl acetate (123-86-4)
USA - ACGIH ACGIH STEL (ppm) 200 ppm (n-Butyl acetate; USA; Short time value; TLV -
Adopted Value)
isobutyl acetate (110-19-0)
Belgium Limit value (mg/m ) 238 mg/m
Belgium Limit value (ppm) 50 ppm
Belgium Short time value (mg/m ) 712 mg/m
Belgium Short time value (ppm) 150 ppm
France VME (mg/m ) 710 mg/m
France VME (ppm) 150 ppm
France VLE (mg/m ) 940 mg/m
France VLE (ppm) 200 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m
United Kingdom WEL TWA (ppm) 150 ppm
United Kingdom WEL STEL (mg/m ) 903 mg/m
United Kingdom WEL STEL (ppm) 187 ppm
USA - ACGIH ACGIH TWA (ppm) 150 ppm
2-propanol (67-63-0)
Belgium Limit value (mg/m ) 500 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 1000 mg/m
Belgium Short time value (ppm) 400 ppm
France VLE (mg/m ) 980 mg/m
France VLE (ppm) 400 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 999 mg/m
United Kingdom WEL TWA (ppm) 400 ppm
United Kingdom WEL STEL (mg/m ) 1250 mg/m
United Kingdom WEL STEL (ppm) 500 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 400 ppm
talc (14807-96-6)
Belgium Limit value (mg/m ) 2 mg/m
Germany TRGS 910 Acceptable concentration notes
Netherlands Grenswaarde TGG 8H (mg/m ) 0.25 mg/m (respirabel)
United Kingdom WEL TWA (mg/m ) 1 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for particulate
matter containing no asbestos and < 1% crystalline
silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
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8.2. Exposure controls
Appropriate engineering controls:
Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station.
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Environmental exposure controls:
Avoid release to the environment.
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Gray.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour,Highly flammable liquid and vapour
Vapor pressure : No data available
Relative vapor density at 20 C : <
Relative density : <=
Specific gravity / density : 1.4
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. Highly flammable liquid and vapour.
May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
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10.4. Conditions to avoid
Overheating. Heat. Sparks. Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
ATE CLP (vapors) 11 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg body weight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure,
Rat, Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
n-butyl acetate (123-86-4)
LD50 oral rat 10770 mg/kg (Rat; Equivalent or similar to OECD 423; Experimental value; 12789 mg/kg;
Rat; Equivalent or similar to OECD 423; Experimental value; 10760 mg/kg bodyweight;
Rat)
LD50 dermal rabbit > 17600 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >14112
mg/kg bodyweight; Rabbit)
isobutyl acetate (110-19-0)
LD50 oral rat 13413 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male, Experimental
value, Oral, 014 day(s))
LD50 dermal rabbit > 17400 mg/kg body weight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male,
Experimental value, Dermal, 14 day(s))
LC50 inhalation rat (mg/l) > 30 mg/l (EPA OTS 798.6050, 6 h, Rat, Male / female, Read-across, Inhalation
(vapours), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Experimental value,
Oral, 14 day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value,
Dermal, 14 day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental
value, Inhalation (vapours), 14 day(s))
Skin corrosion/irritation : Causes skin irritation.
Additional information : Causes skin irritation
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable,2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : Not classified
Additional information : May cause respiratory irritation
Based on available data, the classification criteria are not met
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Additional information : Causes damage to organs through prolonged or repeated exposure
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Aquatic acute : Not classified
Aquatic chronic : Harmful to aquatic life with long lasting effects.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
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cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella
subcapitata, Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static
system, Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
n-butyl acetate (123-86-4)
LC50 fish 1 18 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-
through system; Fresh water; Experimental value)
isobutyl acetate (110-19-0)
LC50 fish 1 16.6 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 24.6 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Semi-static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 397 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
GREY VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD) 2.8 g O /g substance
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ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 2.03 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD) Not applicable (inorganic)
ThOD Not applicable (inorganic)
n-butyl acetate (123-86-4)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established.
Biochemical oxygen demand (BOD) 0.15 – 0.5 g O /g substance
Chemical oxygen demand (COD) 2.32 g O /g substance
ThOD 2.21 g O /g substance
isobutyl acetate (110-19-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Not
established.
ThOD 2.2 g O /g substance
BOD (% of ThOD) 0.6
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not
established.
Biochemical oxygen demand (BOD) 1.19 g O /g substance
Chemical oxygen demand (COD) 2.23 g O /g substance
ThOD 2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Persistence and degradability May cause long-term adverse effects in the environment.
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12.3. Bioaccumulative potential
GREY VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
40 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
n-butyl acetate (123-86-4)
BCF fish 1 14 (BCF)
Log Pow 2.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method;
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
isobutyl acetate (110-19-0)
Log Pow 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
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methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
n-butyl acetate (123-86-4)
Surface tension 0.0613 N/m (20 C; 1 g/l)
Log Koc log Koc,SRC PCKOCWIN v2.0; 1.268 - 1.844; QSAR
isobutyl acetate (110-19-0)
Surface tension 62.5 mN/m (20 C, 1 g/l, OECD 115: Surface Tension of Aqueous Solutions)
Log Koc 1.193 - 1.844 (log Koc, SRC PCKOCWIN v2.0, QSAR)
Ecology - soil Highly mobile in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Results of PBT and vPvB assessment
Component
styrene, inhibited (100-42-5) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
methyl ethyl ketone (78-93-3) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
titanium(IV) oxide (13463-67-7) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
2-propanol (67-63-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
isobutyl acetate (110-19-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
12.6. Other adverse effects
Additional information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : UN 1866
UN-No. (IMDG) : UN 1866
UN-No. (IATA) : UN 1866
UN-No. (ADN) : Not applicable
UN-No. (RID) : UN 1866
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Safety Data Sheet
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8/23/2019
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14.2. UN proper shipping name
Proper Shipping Name (ADR) : paint
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : UN 1866 paint, 3, II, (D/E)
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
Transport document description (IATA) : UN 1866 Resin solution, 3, II
Transport document description (RID) : UN 1866 , 3
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 3
Hazard labels (ADR) : 3
:
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
:
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
:
ADN
Transport hazard class(es) (ADN) : Not applicable
RID
Transport hazard class(es) (RID) : 3
Hazard labels (RID) : 3
:
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
GREY VINYL ESTER PRIMER
Safety Data Sheet
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8/23/2019
EN (English US) 16/18
14.6. Special precautions for user
Overland transport
Classification code (ADR) : F1
Special provision (ADR) : 163, 640C, 650
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E2
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC : 3YE
Transport by sea
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-E
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3
ERG code (IATA) : 3L
Inland waterway transport
No data available
Rail transport
No data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
Contains no substance subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012
concerning the export and import of hazardous chemicals.
Substance(s) are not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic
pollutants and amending Directive 79/117/EEC.
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15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : isobutyl acetate is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Ontwikkeling
: styrene, inhibited is listed
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids
must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with
the product
The requirements from the Danish Working Environment Authorities regarding work with
carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labeling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard Category 1
Asp. Tox. 1 Aspiration hazard Category 1
Carc. 1B Carcinogenicity Category 1B
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Flam. Liq. 2 Flammable liquids Category 2
Flam. Liq. 3 Flammable liquids Category 3
Muta. 1B Germ cell mutagenicity Category 1B
Repr. 2 Reproductive toxicity Category 2
Repr. 2 Reproductive toxicity Category 2
Skin Irrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization, Category 1
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
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H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
EUH208 Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic reaction
R10 Flammable
R11 Highly flammable
R20 Harmful by inhalation
R36/38 Irritating to eyes and skin
R43 May cause sensitization by skin contact
R45 May cause cancer
R46 May cause heritable genetic damage
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 Possible risk of impaired fertility
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapors may cause drowsiness and dizziness
F Highly flammable
N Dangerous for the environment
Xi Irritant
Xn Harmful
SDS EU (REACH Annex II)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed
or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations
or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Revision date: 8/23/2019
8/23/2019
EN (English US) 1/18
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : GREY VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1799-006
Type of product : Coating
Formula : na
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : COATING
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixtures: SDS < 2015 : Show CLP information + DPD classification in
section 2.1
Flammable liquids Category 2 H225
Acute toxicity (inhalation:vapour) Category 4 H332
Skin corrosion/irritation Category 2 H315
Serious eye damage/eye irritation Category 2 H319
Germ cell mutagenicity Category 1B H340
Carcinogenicity Category 1B H350
Reproductive toxicity Category 2 H361
Specific target organ toxicity (repeated exposure) Category 1 H372
Hazardous to the aquatic environment - Chronic Hazard Category 3 H412
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
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2.2. Label elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : Danger
Hazardous ingredients : styrene, inhibited; Solvent Naptha Petroleum Aliphatic
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H340 - May cause genetic defects.
H350 - May cause cancer.
H361 - Suspected of damaging fertility or the unborn child.
H372 - Causes damage to organs through prolonged or repeated exposure.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P233 - Keep container tightly closed.
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof equipment.
P260 - Do not breathe dust, mist, vapors, fume.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water .
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P312 - Call a POISON CENTRE or doctor if you feel unwell.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder, foam to
extinguish.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
EUH phrases : EUH208 - Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic
reaction.
2.3. Other hazards
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according
to Directive 67/548/EEC
Classification
according to
Regulation (EC) No.
1272/2008 [CLP]
talc (CAS-No.) 14807-96-6
(EC-No.) 238-877-9
(REACH-no) No data
available
<= 31.5 Not classified Not classified
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styrene, inhibited (CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
<= 25 R10
Xn; R20
Xi; R36/38
Flam. Liq. 3, H226
Repr. 2, H361d
STOT RE 1, H372
Acute Tox. 4 (Inhalation),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
methyl ethyl ketone (CAS-No.) 78-93-3
(EC-No.) 201-159-0
(EC Index-No.) 606-002-00-3
(REACH-no) 01-2119457290-
43
<= 5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide (CAS-No.) 13463-67-7
(EC-No.) 236-675-5
(REACH-no) 01-2119489379-
17
<= 4 Not classified Not classified
Solvent Naptha Petroleum Aliphatic (CAS-No.) 64742-89-8
(REACH-no) 01-2119471306-
40
<= 2 Not classified Muta. 1B, H340
Carc. 1B, H350
Asp. Tox. 1, H304
n-butyl acetate (CAS-No.) 123-86-4
(EC-No.) 204-658-1
(EC Index-No.) 607-025-00-1
(REACH-no) 01-2119485493-
29
<= 1 R10
R66
R67
Flam. Liq. 3, H226
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7
(EC-No.) 205-250-6
(REACH-no) 01-2119524678-
29
<= 0.5 Repr.Cat.3; R62
R43
N; R50/53
Skin Sens. 1, H317
Repr. 2, H361f
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
2-propanol (CAS-No.) 67-63-0
(EC-No.) 200-661-7
(EC Index-No.) 603-117-00-0
(REACH-no) 01-2119457558-
25
<= 0.5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
isobutyl acetate (CAS-No.) 110-19-0
(EC-No.) 203-745-1
(EC Index-No.) 607-026-00-7
(REACH-no) 01-2119488971-
22
<= 0.5 Not classified Flam. Liq. 2, H225
Specific concentration limits:
Name Product identifier Specific concentration limits:
DSD/DPD
Specific concentration
limits: CLP
styrene, inhibited
(CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
(12.5 =< C < 100) Xi;R36/38
(12.5 =< C < 100) Xn;R20
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing.
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first
aid instruction on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
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4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged
exposure through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour. Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew
with proper protection. For further information refer to section 8: "Exposure
controls/personal protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Take precautionary measures against static
discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work. Provide good ventilation in process area to prevent formation of vapor. No
open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke
when using this product. Always wash hands after handling the product.
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7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in
fireproof place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
Belgium Limit value (mg/m ) 108 mg/m
Belgium Limit value (ppm) 25 ppm
Belgium Short time value (mg/m ) 216 mg/m
Belgium Short time value (ppm) 50 ppm
France VME (mg/m ) 100 mg/m
France VME (ppm) 23.3 ppm
France VLE (mg/m ) 200 mg/m
France VLE (ppm) 46.6 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 430 mg/m
United Kingdom WEL TWA (ppm) 100 ppm
United Kingdom WEL STEL (mg/m ) 1080 mg/m
United Kingdom WEL STEL (ppm) 250 ppm
USA - ACGIH ACGIH TWA (ppm) 20 ppm
USA - ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 0.1 mg/m Cobalt compounds (as Co); United Kingdom;
Time-weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
methyl ethyl ketone (78-93-3)
EU IOELV TWA (mg/m ) 600 mg/m
EU IOELV TWA (ppm) 200 ppm
EU IOELV STEL (mg/m ) 900 mg/m
EU IOELV STEL (ppm) 300 ppm
Belgium Limit value (mg/m ) 600 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 900 mg/m
Belgium Short time value (ppm) 300 ppm
France VME (mg/m ) 600 mg/m
France VME (ppm) 200 ppm
France VLE (mg/m ) 900 mg/m
France VLE (ppm) 300 ppm
Germany TRGS 910 Acceptable concentration notes
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methyl ethyl ketone (78-93-3)
Netherlands Grenswaarde TGG 8H (mg/m ) 590 mg/m
Netherlands Grenswaarde TGG 8H (ppm) 197 ppm
Netherlands Grenswaarde TGG 15MIN (mg/m ) 900 mg/m
Netherlands Grenswaarde TGG 15MIN (ppm) 300 ppm
United Kingdom WEL TWA (mg/m ) 600 mg/m
United Kingdom WEL TWA (ppm) 200 ppm
United Kingdom WEL STEL (mg/m ) 899 mg/m
United Kingdom WEL STEL (ppm) 300 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
Belgium Limit value (mg/m ) 10 mg/m
France VME (mg/m ) 10 mg/m
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 10 mg/m
4 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 10 mg/m
n-butyl acetate (123-86-4)
Belgium Limit value (mg/m ) 723 mg/m (Ac tate de n-butyle; Belgium; Time-
weighted average exposure limit 8 h)
Belgium Limit value (ppm) 150 ppm (Ac tate de n-butyle; Belgium; Time-weighted
average exposure limit 8 h)
Belgium Short time value (mg/m ) 964 mg/m (Ac tate de n-butyle; Belgium; Short time
value)
Belgium Short time value (ppm) 200 ppm (Ac tate de n-butyle; Belgium; Short time
value)
France VME (mg/m ) 710 mg/m (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VME (ppm) 150 ppm (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VLE (mg/m ) 940 mg/m (Ac tate de n-butyle; France; Short time
value; VL: Valeur non r glementaire indicative)
France VLE (ppm) 200 ppm (Ac tate de n-butyle; France; Short time value;
VL: Valeur non r glementaire indicative)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m Butyl acetate; United Kingdom; Time-
weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
United Kingdom WEL TWA (ppm) 150 ppm Butyl acetate; United Kingdom; Time-weighted
average exposure limit 8 h; Workplace exposure limit
(EH40/2005)
United Kingdom WEL STEL (mg/m ) 966 mg/m Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
United Kingdom WEL STEL (ppm) 200 ppm Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
USA - ACGIH ACGIH TWA (ppm) 150 ppm (n-Butyl acetate; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value)
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 7/18
n-butyl acetate (123-86-4)
USA - ACGIH ACGIH STEL (ppm) 200 ppm (n-Butyl acetate; USA; Short time value; TLV -
Adopted Value)
isobutyl acetate (110-19-0)
Belgium Limit value (mg/m ) 238 mg/m
Belgium Limit value (ppm) 50 ppm
Belgium Short time value (mg/m ) 712 mg/m
Belgium Short time value (ppm) 150 ppm
France VME (mg/m ) 710 mg/m
France VME (ppm) 150 ppm
France VLE (mg/m ) 940 mg/m
France VLE (ppm) 200 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m
United Kingdom WEL TWA (ppm) 150 ppm
United Kingdom WEL STEL (mg/m ) 903 mg/m
United Kingdom WEL STEL (ppm) 187 ppm
USA - ACGIH ACGIH TWA (ppm) 150 ppm
2-propanol (67-63-0)
Belgium Limit value (mg/m ) 500 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 1000 mg/m
Belgium Short time value (ppm) 400 ppm
France VLE (mg/m ) 980 mg/m
France VLE (ppm) 400 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 999 mg/m
United Kingdom WEL TWA (ppm) 400 ppm
United Kingdom WEL STEL (mg/m ) 1250 mg/m
United Kingdom WEL STEL (ppm) 500 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 400 ppm
talc (14807-96-6)
Belgium Limit value (mg/m ) 2 mg/m
Germany TRGS 910 Acceptable concentration notes
Netherlands Grenswaarde TGG 8H (mg/m ) 0.25 mg/m (respirabel)
United Kingdom WEL TWA (mg/m ) 1 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for particulate
matter containing no asbestos and < 1% crystalline
silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
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according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
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8.2. Exposure controls
Appropriate engineering controls:
Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station.
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Environmental exposure controls:
Avoid release to the environment.
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Gray.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour,Highly flammable liquid and vapour
Vapor pressure : No data available
Relative vapor density at 20 C : <
Relative density : <=
Specific gravity / density : 1.4
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. Highly flammable liquid and vapour.
May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
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10.4. Conditions to avoid
Overheating. Heat. Sparks. Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
ATE CLP (vapors) 11 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg body weight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure,
Rat, Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
n-butyl acetate (123-86-4)
LD50 oral rat 10770 mg/kg (Rat; Equivalent or similar to OECD 423; Experimental value; 12789 mg/kg;
Rat; Equivalent or similar to OECD 423; Experimental value; 10760 mg/kg bodyweight;
Rat)
LD50 dermal rabbit > 17600 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >14112
mg/kg bodyweight; Rabbit)
isobutyl acetate (110-19-0)
LD50 oral rat 13413 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male, Experimental
value, Oral, 014 day(s))
LD50 dermal rabbit > 17400 mg/kg body weight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male,
Experimental value, Dermal, 14 day(s))
LC50 inhalation rat (mg/l) > 30 mg/l (EPA OTS 798.6050, 6 h, Rat, Male / female, Read-across, Inhalation
(vapours), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Experimental value,
Oral, 14 day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value,
Dermal, 14 day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental
value, Inhalation (vapours), 14 day(s))
Skin corrosion/irritation : Causes skin irritation.
Additional information : Causes skin irritation
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable,2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : Not classified
Additional information : May cause respiratory irritation
Based on available data, the classification criteria are not met
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Additional information : Causes damage to organs through prolonged or repeated exposure
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Aquatic acute : Not classified
Aquatic chronic : Harmful to aquatic life with long lasting effects.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
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cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella
subcapitata, Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static
system, Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
n-butyl acetate (123-86-4)
LC50 fish 1 18 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-
through system; Fresh water; Experimental value)
isobutyl acetate (110-19-0)
LC50 fish 1 16.6 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 24.6 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Semi-static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 397 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
GREY VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD) 2.8 g O /g substance
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ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 2.03 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD) Not applicable (inorganic)
ThOD Not applicable (inorganic)
n-butyl acetate (123-86-4)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established.
Biochemical oxygen demand (BOD) 0.15 – 0.5 g O /g substance
Chemical oxygen demand (COD) 2.32 g O /g substance
ThOD 2.21 g O /g substance
isobutyl acetate (110-19-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Not
established.
ThOD 2.2 g O /g substance
BOD (% of ThOD) 0.6
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not
established.
Biochemical oxygen demand (BOD) 1.19 g O /g substance
Chemical oxygen demand (COD) 2.23 g O /g substance
ThOD 2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Persistence and degradability May cause long-term adverse effects in the environment.
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12.3. Bioaccumulative potential
GREY VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
40 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
n-butyl acetate (123-86-4)
BCF fish 1 14 (BCF)
Log Pow 2.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method;
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
isobutyl acetate (110-19-0)
Log Pow 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
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methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
n-butyl acetate (123-86-4)
Surface tension 0.0613 N/m (20 C; 1 g/l)
Log Koc log Koc,SRC PCKOCWIN v2.0; 1.268 - 1.844; QSAR
isobutyl acetate (110-19-0)
Surface tension 62.5 mN/m (20 C, 1 g/l, OECD 115: Surface Tension of Aqueous Solutions)
Log Koc 1.193 - 1.844 (log Koc, SRC PCKOCWIN v2.0, QSAR)
Ecology - soil Highly mobile in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Results of PBT and vPvB assessment
Component
styrene, inhibited (100-42-5) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
methyl ethyl ketone (78-93-3) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
titanium(IV) oxide (13463-67-7) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
2-propanol (67-63-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
isobutyl acetate (110-19-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
12.6. Other adverse effects
Additional information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : UN 1866
UN-No. (IMDG) : UN 1866
UN-No. (IATA) : UN 1866
UN-No. (ADN) : Not applicable
UN-No. (RID) : UN 1866
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14.2. UN proper shipping name
Proper Shipping Name (ADR) : paint
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : UN 1866 paint, 3, II, (D/E)
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
Transport document description (IATA) : UN 1866 Resin solution, 3, II
Transport document description (RID) : UN 1866 , 3
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 3
Hazard labels (ADR) : 3
:
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
:
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
:
ADN
Transport hazard class(es) (ADN) : Not applicable
RID
Transport hazard class(es) (RID) : 3
Hazard labels (RID) : 3
:
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
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14.6. Special precautions for user
Overland transport
Classification code (ADR) : F1
Special provision (ADR) : 163, 640C, 650
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E2
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC : 3YE
Transport by sea
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-E
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3
ERG code (IATA) : 3L
Inland waterway transport
No data available
Rail transport
No data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
Contains no substance subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012
concerning the export and import of hazardous chemicals.
Substance(s) are not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic
pollutants and amending Directive 79/117/EEC.
GREY VINYL ESTER PRIMER
Safety Data Sheet
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8/23/2019
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15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : isobutyl acetate is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Ontwikkeling
: styrene, inhibited is listed
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids
must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with
the product
The requirements from the Danish Working Environment Authorities regarding work with
carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labeling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard Category 1
Asp. Tox. 1 Aspiration hazard Category 1
Carc. 1B Carcinogenicity Category 1B
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Flam. Liq. 2 Flammable liquids Category 2
Flam. Liq. 3 Flammable liquids Category 3
Muta. 1B Germ cell mutagenicity Category 1B
Repr. 2 Reproductive toxicity Category 2
Repr. 2 Reproductive toxicity Category 2
Skin Irrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization, Category 1
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
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H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
EUH208 Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic reaction
R10 Flammable
R11 Highly flammable
R20 Harmful by inhalation
R36/38 Irritating to eyes and skin
R43 May cause sensitization by skin contact
R45 May cause cancer
R46 May cause heritable genetic damage
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 Possible risk of impaired fertility
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapors may cause drowsiness and dizziness
F Highly flammable
N Dangerous for the environment
Xi Irritant
Xn Harmful
SDS EU (REACH Annex II)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed
or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations
or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Revision date: 8/23/2019
8/23/2019
EN (English US) 1/18
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : GREY VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1799-006
Type of product : Coating
Formula : na
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : COATING
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixtures: SDS < 2015 : Show CLP information + DPD classification in
section 2.1
Flammable liquids Category 2 H225
Acute toxicity (inhalation:vapour) Category 4 H332
Skin corrosion/irritation Category 2 H315
Serious eye damage/eye irritation Category 2 H319
Germ cell mutagenicity Category 1B H340
Carcinogenicity Category 1B H350
Reproductive toxicity Category 2 H361
Specific target organ toxicity (repeated exposure) Category 1 H372
Hazardous to the aquatic environment - Chronic Hazard Category 3 H412
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
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2.2. Label elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : Danger
Hazardous ingredients : styrene, inhibited; Solvent Naptha Petroleum Aliphatic
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H340 - May cause genetic defects.
H350 - May cause cancer.
H361 - Suspected of damaging fertility or the unborn child.
H372 - Causes damage to organs through prolonged or repeated exposure.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P233 - Keep container tightly closed.
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof equipment.
P260 - Do not breathe dust, mist, vapors, fume.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water .
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P312 - Call a POISON CENTRE or doctor if you feel unwell.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder, foam to
extinguish.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
EUH phrases : EUH208 - Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic
reaction.
2.3. Other hazards
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according
to Directive 67/548/EEC
Classification
according to
Regulation (EC) No.
1272/2008 [CLP]
talc (CAS-No.) 14807-96-6
(EC-No.) 238-877-9
(REACH-no) No data
available
<= 31.5 Not classified Not classified
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styrene, inhibited (CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
<= 25 R10
Xn; R20
Xi; R36/38
Flam. Liq. 3, H226
Repr. 2, H361d
STOT RE 1, H372
Acute Tox. 4 (Inhalation),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
methyl ethyl ketone (CAS-No.) 78-93-3
(EC-No.) 201-159-0
(EC Index-No.) 606-002-00-3
(REACH-no) 01-2119457290-
43
<= 5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide (CAS-No.) 13463-67-7
(EC-No.) 236-675-5
(REACH-no) 01-2119489379-
17
<= 4 Not classified Not classified
Solvent Naptha Petroleum Aliphatic (CAS-No.) 64742-89-8
(REACH-no) 01-2119471306-
40
<= 2 Not classified Muta. 1B, H340
Carc. 1B, H350
Asp. Tox. 1, H304
n-butyl acetate (CAS-No.) 123-86-4
(EC-No.) 204-658-1
(EC Index-No.) 607-025-00-1
(REACH-no) 01-2119485493-
29
<= 1 R10
R66
R67
Flam. Liq. 3, H226
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7
(EC-No.) 205-250-6
(REACH-no) 01-2119524678-
29
<= 0.5 Repr.Cat.3; R62
R43
N; R50/53
Skin Sens. 1, H317
Repr. 2, H361f
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
2-propanol (CAS-No.) 67-63-0
(EC-No.) 200-661-7
(EC Index-No.) 603-117-00-0
(REACH-no) 01-2119457558-
25
<= 0.5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
isobutyl acetate (CAS-No.) 110-19-0
(EC-No.) 203-745-1
(EC Index-No.) 607-026-00-7
(REACH-no) 01-2119488971-
22
<= 0.5 Not classified Flam. Liq. 2, H225
Specific concentration limits:
Name Product identifier Specific concentration limits:
DSD/DPD
Specific concentration
limits: CLP
styrene, inhibited
(CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
(12.5 =< C < 100) Xi;R36/38
(12.5 =< C < 100) Xn;R20
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing.
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first
aid instruction on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
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4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged
exposure through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour. Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew
with proper protection. For further information refer to section 8: "Exposure
controls/personal protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Take precautionary measures against static
discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work. Provide good ventilation in process area to prevent formation of vapor. No
open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke
when using this product. Always wash hands after handling the product.
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7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in
fireproof place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
Belgium Limit value (mg/m ) 108 mg/m
Belgium Limit value (ppm) 25 ppm
Belgium Short time value (mg/m ) 216 mg/m
Belgium Short time value (ppm) 50 ppm
France VME (mg/m ) 100 mg/m
France VME (ppm) 23.3 ppm
France VLE (mg/m ) 200 mg/m
France VLE (ppm) 46.6 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 430 mg/m
United Kingdom WEL TWA (ppm) 100 ppm
United Kingdom WEL STEL (mg/m ) 1080 mg/m
United Kingdom WEL STEL (ppm) 250 ppm
USA - ACGIH ACGIH TWA (ppm) 20 ppm
USA - ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 0.1 mg/m Cobalt compounds (as Co); United Kingdom;
Time-weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
methyl ethyl ketone (78-93-3)
EU IOELV TWA (mg/m ) 600 mg/m
EU IOELV TWA (ppm) 200 ppm
EU IOELV STEL (mg/m ) 900 mg/m
EU IOELV STEL (ppm) 300 ppm
Belgium Limit value (mg/m ) 600 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 900 mg/m
Belgium Short time value (ppm) 300 ppm
France VME (mg/m ) 600 mg/m
France VME (ppm) 200 ppm
France VLE (mg/m ) 900 mg/m
France VLE (ppm) 300 ppm
Germany TRGS 910 Acceptable concentration notes
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methyl ethyl ketone (78-93-3)
Netherlands Grenswaarde TGG 8H (mg/m ) 590 mg/m
Netherlands Grenswaarde TGG 8H (ppm) 197 ppm
Netherlands Grenswaarde TGG 15MIN (mg/m ) 900 mg/m
Netherlands Grenswaarde TGG 15MIN (ppm) 300 ppm
United Kingdom WEL TWA (mg/m ) 600 mg/m
United Kingdom WEL TWA (ppm) 200 ppm
United Kingdom WEL STEL (mg/m ) 899 mg/m
United Kingdom WEL STEL (ppm) 300 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
Belgium Limit value (mg/m ) 10 mg/m
France VME (mg/m ) 10 mg/m
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 10 mg/m
4 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 10 mg/m
n-butyl acetate (123-86-4)
Belgium Limit value (mg/m ) 723 mg/m (Ac tate de n-butyle; Belgium; Time-
weighted average exposure limit 8 h)
Belgium Limit value (ppm) 150 ppm (Ac tate de n-butyle; Belgium; Time-weighted
average exposure limit 8 h)
Belgium Short time value (mg/m ) 964 mg/m (Ac tate de n-butyle; Belgium; Short time
value)
Belgium Short time value (ppm) 200 ppm (Ac tate de n-butyle; Belgium; Short time
value)
France VME (mg/m ) 710 mg/m (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VME (ppm) 150 ppm (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VLE (mg/m ) 940 mg/m (Ac tate de n-butyle; France; Short time
value; VL: Valeur non r glementaire indicative)
France VLE (ppm) 200 ppm (Ac tate de n-butyle; France; Short time value;
VL: Valeur non r glementaire indicative)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m Butyl acetate; United Kingdom; Time-
weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
United Kingdom WEL TWA (ppm) 150 ppm Butyl acetate; United Kingdom; Time-weighted
average exposure limit 8 h; Workplace exposure limit
(EH40/2005)
United Kingdom WEL STEL (mg/m ) 966 mg/m Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
United Kingdom WEL STEL (ppm) 200 ppm Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
USA - ACGIH ACGIH TWA (ppm) 150 ppm (n-Butyl acetate; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value)
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n-butyl acetate (123-86-4)
USA - ACGIH ACGIH STEL (ppm) 200 ppm (n-Butyl acetate; USA; Short time value; TLV -
Adopted Value)
isobutyl acetate (110-19-0)
Belgium Limit value (mg/m ) 238 mg/m
Belgium Limit value (ppm) 50 ppm
Belgium Short time value (mg/m ) 712 mg/m
Belgium Short time value (ppm) 150 ppm
France VME (mg/m ) 710 mg/m
France VME (ppm) 150 ppm
France VLE (mg/m ) 940 mg/m
France VLE (ppm) 200 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m
United Kingdom WEL TWA (ppm) 150 ppm
United Kingdom WEL STEL (mg/m ) 903 mg/m
United Kingdom WEL STEL (ppm) 187 ppm
USA - ACGIH ACGIH TWA (ppm) 150 ppm
2-propanol (67-63-0)
Belgium Limit value (mg/m ) 500 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 1000 mg/m
Belgium Short time value (ppm) 400 ppm
France VLE (mg/m ) 980 mg/m
France VLE (ppm) 400 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 999 mg/m
United Kingdom WEL TWA (ppm) 400 ppm
United Kingdom WEL STEL (mg/m ) 1250 mg/m
United Kingdom WEL STEL (ppm) 500 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 400 ppm
talc (14807-96-6)
Belgium Limit value (mg/m ) 2 mg/m
Germany TRGS 910 Acceptable concentration notes
Netherlands Grenswaarde TGG 8H (mg/m ) 0.25 mg/m (respirabel)
United Kingdom WEL TWA (mg/m ) 1 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for particulate
matter containing no asbestos and < 1% crystalline
silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
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8.2. Exposure controls
Appropriate engineering controls:
Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station.
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Environmental exposure controls:
Avoid release to the environment.
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Gray.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour,Highly flammable liquid and vapour
Vapor pressure : No data available
Relative vapor density at 20 C : <
Relative density : <=
Specific gravity / density : 1.4
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. Highly flammable liquid and vapour.
May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 9/18
10.4. Conditions to avoid
Overheating. Heat. Sparks. Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
ATE CLP (vapors) 11 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg body weight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure,
Rat, Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
n-butyl acetate (123-86-4)
LD50 oral rat 10770 mg/kg (Rat; Equivalent or similar to OECD 423; Experimental value; 12789 mg/kg;
Rat; Equivalent or similar to OECD 423; Experimental value; 10760 mg/kg bodyweight;
Rat)
LD50 dermal rabbit > 17600 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >14112
mg/kg bodyweight; Rabbit)
isobutyl acetate (110-19-0)
LD50 oral rat 13413 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male, Experimental
value, Oral, 014 day(s))
LD50 dermal rabbit > 17400 mg/kg body weight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male,
Experimental value, Dermal, 14 day(s))
LC50 inhalation rat (mg/l) > 30 mg/l (EPA OTS 798.6050, 6 h, Rat, Male / female, Read-across, Inhalation
(vapours), 14 day(s))
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8/23/2019
EN (English US) 10/18
2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Experimental value,
Oral, 14 day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value,
Dermal, 14 day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental
value, Inhalation (vapours), 14 day(s))
Skin corrosion/irritation : Causes skin irritation.
Additional information : Causes skin irritation
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable,2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : Not classified
Additional information : May cause respiratory irritation
Based on available data, the classification criteria are not met
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Additional information : Causes damage to organs through prolonged or repeated exposure
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Aquatic acute : Not classified
Aquatic chronic : Harmful to aquatic life with long lasting effects.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
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Safety Data Sheet
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8/23/2019
EN (English US) 11/18
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella
subcapitata, Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static
system, Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
n-butyl acetate (123-86-4)
LC50 fish 1 18 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-
through system; Fresh water; Experimental value)
isobutyl acetate (110-19-0)
LC50 fish 1 16.6 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 24.6 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Semi-static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 397 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
GREY VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD) 2.8 g O /g substance
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ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 2.03 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD) Not applicable (inorganic)
ThOD Not applicable (inorganic)
n-butyl acetate (123-86-4)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established.
Biochemical oxygen demand (BOD) 0.15 – 0.5 g O /g substance
Chemical oxygen demand (COD) 2.32 g O /g substance
ThOD 2.21 g O /g substance
isobutyl acetate (110-19-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Not
established.
ThOD 2.2 g O /g substance
BOD (% of ThOD) 0.6
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not
established.
Biochemical oxygen demand (BOD) 1.19 g O /g substance
Chemical oxygen demand (COD) 2.23 g O /g substance
ThOD 2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Persistence and degradability May cause long-term adverse effects in the environment.
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8/23/2019
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12.3. Bioaccumulative potential
GREY VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
40 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
n-butyl acetate (123-86-4)
BCF fish 1 14 (BCF)
Log Pow 2.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method;
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
isobutyl acetate (110-19-0)
Log Pow 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 14/18
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
n-butyl acetate (123-86-4)
Surface tension 0.0613 N/m (20 C; 1 g/l)
Log Koc log Koc,SRC PCKOCWIN v2.0; 1.268 - 1.844; QSAR
isobutyl acetate (110-19-0)
Surface tension 62.5 mN/m (20 C, 1 g/l, OECD 115: Surface Tension of Aqueous Solutions)
Log Koc 1.193 - 1.844 (log Koc, SRC PCKOCWIN v2.0, QSAR)
Ecology - soil Highly mobile in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Results of PBT and vPvB assessment
Component
styrene, inhibited (100-42-5) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
methyl ethyl ketone (78-93-3) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
titanium(IV) oxide (13463-67-7) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
2-propanol (67-63-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
isobutyl acetate (110-19-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
12.6. Other adverse effects
Additional information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : UN 1866
UN-No. (IMDG) : UN 1866
UN-No. (IATA) : UN 1866
UN-No. (ADN) : Not applicable
UN-No. (RID) : UN 1866
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8/23/2019
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14.2. UN proper shipping name
Proper Shipping Name (ADR) : paint
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : UN 1866 paint, 3, II, (D/E)
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
Transport document description (IATA) : UN 1866 Resin solution, 3, II
Transport document description (RID) : UN 1866 , 3
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 3
Hazard labels (ADR) : 3
:
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
:
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
:
ADN
Transport hazard class(es) (ADN) : Not applicable
RID
Transport hazard class(es) (RID) : 3
Hazard labels (RID) : 3
:
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 16/18
14.6. Special precautions for user
Overland transport
Classification code (ADR) : F1
Special provision (ADR) : 163, 640C, 650
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E2
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC : 3YE
Transport by sea
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-E
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3
ERG code (IATA) : 3L
Inland waterway transport
No data available
Rail transport
No data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
Contains no substance subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012
concerning the export and import of hazardous chemicals.
Substance(s) are not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic
pollutants and amending Directive 79/117/EEC.
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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 17/18
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : isobutyl acetate is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Ontwikkeling
: styrene, inhibited is listed
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids
must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with
the product
The requirements from the Danish Working Environment Authorities regarding work with
carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labeling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard Category 1
Asp. Tox. 1 Aspiration hazard Category 1
Carc. 1B Carcinogenicity Category 1B
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Flam. Liq. 2 Flammable liquids Category 2
Flam. Liq. 3 Flammable liquids Category 3
Muta. 1B Germ cell mutagenicity Category 1B
Repr. 2 Reproductive toxicity Category 2
Repr. 2 Reproductive toxicity Category 2
Skin Irrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization, Category 1
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
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Safety Data Sheet
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H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
EUH208 Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic reaction
R10 Flammable
R11 Highly flammable
R20 Harmful by inhalation
R36/38 Irritating to eyes and skin
R43 May cause sensitization by skin contact
R45 May cause cancer
R46 May cause heritable genetic damage
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 Possible risk of impaired fertility
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapors may cause drowsiness and dizziness
F Highly flammable
N Dangerous for the environment
Xi Irritant
Xn Harmful
SDS EU (REACH Annex II)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed
or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations
or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : WHITE VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1794-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 35 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 26 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 6 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 5 Carc. 2, H351
Aquatic Acute 3, H402
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
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Name Product identifier % GHS-US classification
2-propanol
(CAS-No.) 67-63-0 <= 0.7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Allow
affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapours/spray. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
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talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : off white
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.34
Relative density : <=
Density : 11.15 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
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Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
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SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
WHITE VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
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methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
WHITE VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
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titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
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Safety Data Sheet
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10/10/2019 EN (English) 11/13
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
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CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 13/13
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : WHITE VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1794-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 35 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 26 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 6 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 5 Carc. 2, H351
Aquatic Acute 3, H402
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
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Safety Data Sheet
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Name Product identifier % GHS-US classification
2-propanol
(CAS-No.) 67-63-0 <= 0.7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Allow
affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapours/spray. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
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Safety Data Sheet
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talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : off white
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.34
Relative density : <=
Density : 11.15 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
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10/10/2019 EN (English) 6/13
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 8/13
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
WHITE VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 9/13
methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
WHITE VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 10/13
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 11/13
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 12/13
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 13/13
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : WHITE VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1794-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
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Safety Data Sheet
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 35 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 26 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 6 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 5 Carc. 2, H351
Aquatic Acute 3, H402
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
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Safety Data Sheet
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10/10/2019 EN (English) 3/13
Name Product identifier % GHS-US classification
2-propanol
(CAS-No.) 67-63-0 <= 0.7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Allow
affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapours/spray. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
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talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : off white
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.34
Relative density : <=
Density : 11.15 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
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Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
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SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
WHITE VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
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methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
WHITE VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
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titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
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DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
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CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
WHITE VINYL ESTER PRIMER
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10/10/2019 EN (English) 13/13
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
