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BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/23/2019
10/23/2019 EN (English US) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : BLACK QUICK LEVELING TOPCOAT
CAS-No. : mixture
Product code : 602-079
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
Recommended use : Coatings and paints, thinners, paint removers
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 2 H225 Highly flammable liquid and vapour
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Carcinogenicity Category 2 H351 Suspected of causing cancer
Reproductive toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific target organ toxicity (single exposure) Category 1 H370 Causes damage to organs
Specific target organ toxicity (single exposure) Category 3 H335 May cause respiratory irritation
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the aquatic environment – Acute Hazard Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H370 – Causes damage to organs
H372 – Causes damage to organs through prolonged or repeated exposure
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 2/12
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, spray, vapors.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash exposed areas. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P307+P311 – If exposed: Call a poison center/doctor
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center or doctor if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see none listed on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and federal regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS US classification
styrene, inhibited
(CAS-No.) 100-42-5 <= 34 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
talc
(CAS-No.) 14807-96-6 <= 16 Carc. 2, H351
methanol
(CAS-No.) 67-56-1 <= 4 Flam. Liq. 2, H225
Acute Tox. 3 (Oral), H301
Acute Tox. 3 (Inhalation), H331
STOT SE 1, H370
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.8 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 3/12
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. Call a POISON CENTER or
doctor/physician if you feel unwell. Call a poison center/doctor/physician if you feel unwell.
Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction
on this label). If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation. Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. No open flames, no sparks, and no
smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 4/12
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Notify authorities if product enters sewers or public waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapor. No open flames. No smoking. Use only non-
sparking tools. Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Use only outdoors or in a well-ventilated area. Do not breathe
dust/fume/gas/mist/vapors/spray. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Ground/bond container and receiving equipment. Take
precautionary measures against static discharge. Flammable vapors may accumulate in the
container. Use explosion-proof equipment. Avoid contact with skin and eyes. Avoid breathing
dust/fume/gas/mist/vapors/spray. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing before
reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat,
drink or smoke when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof
place. Keep container tightly closed. Store locked up. Store in a well-ventilated place. Keep
cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
methanol (67-56-1)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 250 ppm
talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 5/12
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask. Wear respiratory protection.
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Black
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 64.4 C
Flash point : 12 – 16 C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.2
Specific gravity / density : 9.67
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 6/12
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below. Highly flammable liquid and vapour.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive vapor-
air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of
ignition.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg body weight
ATE US (dermal) 5010 mg/kg body weight
ATE US (gases) 2770 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
methanol (67-56-1)
LD50 oral rat 1187 – 2769 mg/kg body weight (BASF test, Rat, Male / female, Weight of evidence, Aqueous
solution, Oral, 7 day(s))
LD50 dermal rabbit 17100 mg/kg (Rabbit, Inconclusive, insufficient data, Dermal)
LC50 inhalation rat (mg/l) 128.2 mg/l air (BASF test, 4 h, Rat, Male / female, Experimental value, Inhalation (vapours))
ATE US (oral) 100 mg/kg body weight
ATE US (dermal) 17100 mg/kg body weight
ATE US (gases) 700 ppmV/4h
ATE US (vapors) 3 mg/l/4h
ATE US (dust, mist) 0.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 7/12
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : Causes damage to organs. May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methanol (67-56-1)
STOT-single exposure Causes damage to organs.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation. Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
methanol (67-56-1)
LC50 fish 1 15400 mg/l (EPA 660/3 – 75/009, 96 h, Lepomis macrochirus, Flow-through system, Fresh
water, Experimental value, Lethal)
EC50 Daphnia 1 18260 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 96 h, Daphnia magna, Semi-
static system, Fresh water, Experimental value, Locomotor effect)
ErC50 (algae) 22000 mg/l (OECD 201: Alga, Growth Inhibition Test, 96 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 8/12
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
12.2. Persistence and degradability
BLACK QUICK LEVELING TOPCOAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
methanol (67-56-1)
Persistence and degradability Readily biodegradable in the soil. Readily biodegradable in water.
Biochemical oxygen demand (BOD)
0.6 – 1.12 g O /g substance
Chemical oxygen demand (COD)
1.42 g O /g substance
ThOD
1.5 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
12.3. Bioaccumulative potential
BLACK QUICK LEVELING TOPCOAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
methanol (67-56-1)
BCF fish 1 1 - 4.5 (72 h, Cyprinus carpio, Static system, Fresh water, Experimental value)
Log Pow -0.77 (Experimental value)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
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Safety Data Sheet
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methanol (67-56-1)
Surface tension 0.023 N/m (20 C)
Log Koc 0.088 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable. Flammable vapors
may accumulate in the container.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
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10/23/2019 EN (English US) 10/12
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Not applicable
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methanol (67-56-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 5000 lb
SARA Section 311/312 Hazard Classes Fire hazard
Delayed (chronic) health hazard
Immediate (acute) health hazard
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 11/12
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
methanol (67-56-1)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
methanol (67-56-1)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
No Yes No No
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methanol(67-56-1) U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania -
RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/23/2019
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
BLACK QUICK LEVELING TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/23/2019 EN (English US) 12/12
Full text of H-phrases:
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H301 Toxic if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H331 Toxic if inhaled
H332 Harmful if inhaled
H335 May cause respiratory irritation
H351 Suspected of causing cancer
H361 Suspected of damaging fertility or the unborn child
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 08/26/2019
08/27/2019 EN (English US) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : BLACK HI-GLOSS COATING
CAS-No. : mixture
Product code : 602-021
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 2 H225 Highly flammable liquid and vapour
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Carcinogenicity Category 2 H351 Suspected of causing cancer
Reproductive toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific target organ toxicity (single exposure) Category 3 H335 May cause respiratory irritation
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the aquatic environment – Acute Hazard Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 2/12
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, spray, vapors.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash exposed areas. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center or doctor if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see none listed on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and federal regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS US classification
styrene, inhibited
(CAS-No.) 100-42-5 <= 33 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
talc
(CAS-No.) 14807-96-6 <= 15 Carc. 2, H351
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 10 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.8 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 3/12
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction
on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 4/12
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Wash
hands and other exposed areas with mild soap and water before eating, drinking or smoking
and when leaving work. Provide good ventilation in process area to prevent formation of vapor.
No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special instructions
before use. Do not handle until all safety precautions have been read and understood.
Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof
place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 5/12
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Black
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 14 – 16 C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : <=
Specific gravity / density : 1.1
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive vapor-
air mixture.
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 6/12
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg body weight
ATE US (dermal) 5010 mg/kg body weight
ATE US (gases) 2770 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg body weight
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 7/12
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
12.2. Persistence and degradability
BLACK HI-GLOSS COATING (mixture)
Persistence and degradability Not established.
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 8/12
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
ThOD
2.44 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
12.3. Bioaccumulative potential
BLACK HI-GLOSS COATING (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 9/12
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 10/12
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 11/12
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 08/26/2019
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-phrases:
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H351 Suspected of causing cancer
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
BLACK HI-GLOSS COATING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/27/2019 EN (English US) 12/12
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 12/18/2018
12/18/2018 EN (English US) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixtures
Trade name : BLACK SUPER TOOLING
CAS-No. : mixture
Product code : 602-001
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 3
H226 Flammable liquid and vapor
Skin corrosion/irritation
Category 2
H315 Causes skin irritation
Serious eye damage/eye
irritation Category 2A
H319 Causes serious eye irritation
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
Precautionary statements (GHS-US) : P210 – Keep away from heat;hot surfaces;open flames. – No smoking
P233 – Keep container tightly closed
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P264 – Wash exposed area. thoroughly after handling
P280 – Wear eye protection;protective clothing
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 2/11
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P235 – Store in a well-ventilated place. Keep cool
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin
(CAS-No.) TRADE SECRET <= 47 Not classified
styrene, inhibited
(CAS-No.) 100-42-5 <= 43.5 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 4 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.5 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: Get medical advice/attention. Specific treatment (see ... on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects : May cause genetic defects. May cause cancer.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 3/11
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. No open flames. No smoking. Take precautionary measures against static discharge.
Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing
dust/fume/gas/mist/vapors/spray. Obtain special instructions before use. Do not handle until all
safety precautions have been read and understood. Eliminate all ignition sources if safe to do
so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 4/11
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIH ACGIH STEL (ppm) 40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm (Methyl ethyl ketone (MEK); USA; Time-
weighted average exposure limit 8 h; TLV - Adopted
Value)
ACGIH ACGIH STEL (ppm) 300 ppm (Methyl ethyl ketone (MEK); USA; Short time
value; TLV - Adopted Value)
Unsaturated Polyester Resin (TRADE SECRET)
Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves
Eye protection:
Chemical goggles or safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Black
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : >= 64.4 C
Flash point : >= -6.67 C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Flammable liquid and vapor.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : <= 1.1
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 5/11
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapor. May form flammable/explosive vapor-air
mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000.000 mg/kg body weight
ATE US (dermal) 2820.000 mg/kg body weight
ATE US (gases) 2770.000 ppmV/4h
ATE US (vapors) 12.000 mg/l/4h
ATE US (dust, mist) 1.500 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129.000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 6/11
Carcinogenicity : Not classified.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status 3 – Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure : Not classified
Specific target organ toxicity repeated
exposure
: Not classified
Aspiration hazard : Not classified
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
EC50 Daphnia 1 308 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna;
Static system; Fresh water; Experimental value)
LC50 fish 2 2993 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Static
system; Fresh water; Experimental value)
12.2. Persistence and degradability
BLACK SUPER TOOLING (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 7/11
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
ThOD
2.44 g O /g substance
BOD (% of ThOD) > 0.5 (5 days; Literature study)
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
BLACK SUPER TOOLING (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (BCF)
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
Log Koc Koc,352; Estimated value; log Koc; 2.55; Estimated value
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc Koc,34; Calculated value
Ecology - soil Slightly harmful to plants.
12.5. Other adverse effects
Effect on the global warming : No known effects from this product.
GWPmix comment : No known effects from this product.
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 8/11
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1263 Paint, 3, II
UN-No.(DOT) : UN1263
Proper Shipping Name (DOT) : Paint
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to
5 L (1.3 gallons).
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used
provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous
material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the
MAWP.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 128
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport document description : UN1263
UN-No. (TDG) : UN1263
Transport by sea
Transport document description (IMDG) : UN 1263 PAINT, 3, II
UN-No. (IMDG) : 1263
Proper Shipping Name (IMDG) : PAINT
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Limited quantities (IMDG) : 5 L
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 9/11
Air transport
Transport document description (IATA) : UN 1263 Paint, 3, II
UN-No. (IATA) : 1263
Proper Shipping Name (IATA) : Paint
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporing requirements of the United States SARA Section 313
CERCLA RQ 5000 lb
Unsaturated Polyester Resin (TRADE SECRET)
Not listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
Unsaturated Polyester Resin (TRADE SECRET)
Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
Yes No No No 0.1 g/day
BLACK SUPER TOOLING
Safety Data Sheet
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styrene, inhibited (100-42-5)
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone (78-93-3)
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
Revision date : 12/18/2018
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-phrases:
---
---
H225 Highly flammable liquid and vapor
---
---
H226 Flammable liquid and vapor
---
---
H315 Causes skin irritation
---
---
H317 May cause an allergic skin reaction
---
---
H319 Causes serious eye irritation
---
---
H332 Harmful if inhaled
---
---
H335 May cause respiratory irritation
---
---
H336 May cause drowsiness or dizziness
---
---
H351 Suspected of causing cancer
---
---
H361 Suspected of damaging fertility or the unborn child
---
---
H372 Causes damage to organs through prolonged or repeated exposure
---
---
H400 Very toxic to aquatic life
---
---
H411 Toxic to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 11/11
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 12/18/2018
12/18/2018 EN (English US) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixtures
Trade name : BLACK SUPER TOOLING
CAS-No. : mixture
Product code : 602-001
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 3
H226 Flammable liquid and vapor
Skin corrosion/irritation
Category 2
H315 Causes skin irritation
Serious eye damage/eye
irritation Category 2A
H319 Causes serious eye irritation
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02
GHS07
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
Precautionary statements (GHS-US) : P210 – Keep away from heat;hot surfaces;open flames. – No smoking
P233 – Keep container tightly closed
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P264 – Wash exposed area. thoroughly after handling
P280 – Wear eye protection;protective clothing
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
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Safety Data Sheet
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P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P235 – Store in a well-ventilated place. Keep cool
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin
(CAS-No.) TRADE SECRET <= 47 Not classified
styrene, inhibited
(CAS-No.) 100-42-5 <= 43.5 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 4 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.5 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: Get medical advice/attention. Specific treatment (see ... on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects : May cause genetic defects. May cause cancer.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
BLACK SUPER TOOLING
Safety Data Sheet
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12/18/2018 EN (English US) 3/11
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. No open flames. No smoking. Take precautionary measures against static discharge.
Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing
dust/fume/gas/mist/vapors/spray. Obtain special instructions before use. Do not handle until all
safety precautions have been read and understood. Eliminate all ignition sources if safe to do
so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 4/11
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIH ACGIH STEL (ppm) 40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm (Methyl ethyl ketone (MEK); USA; Time-
weighted average exposure limit 8 h; TLV - Adopted
Value)
ACGIH ACGIH STEL (ppm) 300 ppm (Methyl ethyl ketone (MEK); USA; Short time
value; TLV - Adopted Value)
Unsaturated Polyester Resin (TRADE SECRET)
Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves
Eye protection:
Chemical goggles or safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Black
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : >= 64.4 C
Flash point : >= -6.67 C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Flammable liquid and vapor.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : <= 1.1
BLACK SUPER TOOLING
Safety Data Sheet
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Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapor. May form flammable/explosive vapor-air
mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat 2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000.000 mg/kg body weight
ATE US (dermal) 2820.000 mg/kg body weight
ATE US (gases) 2770.000 ppmV/4h
ATE US (vapors) 12.000 mg/l/4h
ATE US (dust, mist) 1.500 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129.000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
BLACK SUPER TOOLING
Safety Data Sheet
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Carcinogenicity : Not classified.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status 3 – Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure : Not classified
Specific target organ toxicity repeated
exposure
: Not classified
Aspiration hazard : Not classified
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
EC50 Daphnia 1 308 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna;
Static system; Fresh water; Experimental value)
LC50 fish 2 2993 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Static
system; Fresh water; Experimental value)
12.2. Persistence and degradability
BLACK SUPER TOOLING (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 7/11
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
ThOD
2.44 g O /g substance
BOD (% of ThOD) > 0.5 (5 days; Literature study)
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
BLACK SUPER TOOLING (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (BCF)
Log Pow 2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (19 C)
Log Koc Koc,352; Estimated value; log Koc; 2.55; Estimated value
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc Koc,34; Calculated value
Ecology - soil Slightly harmful to plants.
12.5. Other adverse effects
Effect on the global warming : No known effects from this product.
GWPmix comment : No known effects from this product.
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 8/11
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1263 Paint, 3, II
UN-No.(DOT) : UN1263
Proper Shipping Name (DOT) : Paint
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packaging may be increased to
5 L (1.3 gallons).
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used
provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous
material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the
MAWP.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 128
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport document description : UN1263
UN-No. (TDG) : UN1263
Transport by sea
Transport document description (IMDG) : UN 1263 PAINT, 3, II
UN-No. (IMDG) : 1263
Proper Shipping Name (IMDG) : PAINT
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Limited quantities (IMDG) : 5 L
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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Air transport
Transport document description (IATA) : UN 1263 Paint, 3, II
UN-No. (IATA) : 1263
Proper Shipping Name (IATA) : Paint
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporing requirements of the United States SARA Section 313
CERCLA RQ 5000 lb
Unsaturated Polyester Resin (TRADE SECRET)
Not listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
Unsaturated Polyester Resin (TRADE SECRET)
Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
Yes No No No 0.1 g/day
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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styrene, inhibited (100-42-5)
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone (78-93-3)
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
Revision date : 12/18/2018
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-phrases:
---
---
H225 Highly flammable liquid and vapor
---
---
H226 Flammable liquid and vapor
---
---
H315 Causes skin irritation
---
---
H317 May cause an allergic skin reaction
---
---
H319 Causes serious eye irritation
---
---
H332 Harmful if inhaled
---
---
H335 May cause respiratory irritation
---
---
H336 May cause drowsiness or dizziness
---
---
H351 Suspected of causing cancer
---
---
H361 Suspected of damaging fertility or the unborn child
---
---
H372 Causes damage to organs through prolonged or repeated exposure
---
---
H400 Very toxic to aquatic life
---
---
H411 Toxic to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
BLACK SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/18/2018 EN (English US) 11/11
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)Page 1
SECTION 1: Identification
1.1. Identification
Product form :MixturesTrade name :CLEAR URETHANE SEALER PART ACAS-No. :mixtureProduct code :5604-002AFormula :na
1.2. Recommended use and restrictions on use
Use of the substance/mixture :COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number :ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 3
H226 Flammable liquid and vaporCarcinogenicity Category 2H351 Suspected of causing cancerReproductive toxicity
Category 2
H361 Suspected of damaging fertility or the unborn childSpecific target organ
toxicity (single exposure)
Category 3
H336 May cause drowsiness or dizzinessSpecific target organ
toxicity (repeated exposure)
Category 1
H372 Causes damage to organs through prolonged or repeated exposure
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02GHS07GHS08
Signal word (GHS-US) :DangerHazard statements (GHS-US) :H226 – Flammable liquid and vapor
H336 – May cause drowsiness or dizziness
H351 – Suspected of causing cancer
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) :P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)2/11 P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, fume, mist, spray, vapors
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P308+P313 – If exposed or concerned: Get medical advice/attention
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to in accordance with local, state, and federal regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
NameProduct identifier%GHS-US classificationn-butyl acetate(CAS-No.) 123-86-4<= 38Flam. Liq. 3, H226
STOT SE 3, H336
Saturated Polyester Resin(CAS-No.) TRADE SECRET<= 25Not classified2-methoxy-1-methylethyl acetate(CAS-No.) 108-65-6<= 23Not classifiedProprietary Resin(CAS-No.) TRADE SECRET<= 15Not classifiedacetone(CAS-No.) 67-64-1<= 12Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
styrene, inhibited(CAS-No.) 100-42-5<= 3Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general :Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation :Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention.
Specific treatment (see seek medical attention. on this label). Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
First-aid measures after eye contact :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if
pain, blinking or redness persists.
First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects :May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause drowsiness or dizziness.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.Unsuitable extinguishing media :Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard :Highly flammable liquid and vapor. Flammable liquid and vapor.Explosion hazard :May form flammable/explosive vapor-air mixture.Reactivity :No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting :Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures :Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1.For non-emergency personnel
Protective equipment :Gloves. Protective goggles. Protective clothing.Emergency procedures :Evacuate unnecessary personnel.
6.1.2.For emergency responders
Protective equipment :Equip cleanup crew with proper protection. Avoid breathing dust/fume/gas/mist/vapors/spray.Emergency procedures :Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment :Dam up the liquid spill. Contain released product, pump into suitable containers.Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed :Handle empty containers with care because residual vapors are flammable.Precautions for safe handling :Eliminate all ignition sources if safe to do so. Wash hands and other exposed areas with mild
soap and water before eating, drinking or smoking and when leaving work. Provide good
ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take
precautionary measures against static discharge. Use only non-sparking tools. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-
ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray.
Hygiene measures :Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly
after handling.
CLEAR URETHANE SEALER PART A
Safety Data Sheet
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7.2. Conditions for safe storage, including any incompatibilities
Technical measures :Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/
equipment.
Storage conditions :Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away
from : Keep container tightly closed.
Incompatible products :Strong bases. Strong acids.Incompatible materials :Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)ACGIHACGIH TWA (ppm)20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
Proprietary Resin (TRADE SECRET)Not applicablen-butyl acetate (123-86-4)ACGIHACGIH TWA (ppm)150 ppm (n-Butyl acetate; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)200 ppm (n-Butyl acetate; USA; Short time value; TLV
- Adopted Value)
Saturated Polyester Resin (TRADE SECRET)Not applicableacetone (67-64-1)ACGIHACGIH TWA (ppm)500 ppm (Acetone; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)750 ppm (Acetone; USA; Short time value; TLV -
Adopted Value)
2-methoxy-1-methylethyl acetate (108-65-6)Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls :Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:Avoid all unnecessary exposure.
Hand protection:Wear protective glovesEye protection:Chemical goggles or safety glassesSkin and body protection:Wear suitable protective clothing
Respiratory protection:Where exposure through inhalation may occur
from use, respiratory protection equipment is
recommended
CLEAR URETHANE SEALER PART A
Safety Data Sheet
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04/13/2018EN (English US)5/11
Other information:Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state :Liquid
Color :clear
Odor :characteristic
Odor threshold :No data available
pH :No data available
Melting point :No data available
Freezing point :No data available
Boiling point :>= 56.1 C
Flash point :>= -20 C
Relative evaporation rate (butyl acetate=1) :No data available
Flammability (solid, gas) :Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure :No data available
Relative vapor density at 20 C :No data available
Relative density :No data available
Specific gravity / density :1Solubility :No data available
Log Pow :No data available
Auto-ignition temperature :No data available
Decomposition temperature :No data available
Viscosity, kinematic :No data available
Viscosity, dynamic :No data available
Explosion limits :No data available
Explosive properties :No data available
Oxidizing properties :No data available
9.2. Other information
VOC content :<= 572 g/l
SECTION 10: Stability and reactivity
10.1.Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2.Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.
10.3.Possibility of hazardous reactions
Not established.
10.4.Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5.Incompatible materials
Strong acids. Strong bases.
10.6.Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1.Information on toxicological effects
Acute toxicity :Not classified
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)6/11styrene, inhibited (100-42-5)LD50 oral rat5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)LD50 dermal rat2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit5010 mg/kg (Rabbit; Literature study)LC50 inhalation rat (mg/l)12 mg/l/4h (Rat; Literature study)LC50 inhalation rat (ppm)2770 ppm/4h (Rat; Literature study)ATE US (oral)5000.000 mg/kg body weightATE US (dermal)2820.000 mg/kg body weightATE US (gases)2770.000 ppmV/4hATE US (vapors)12.000 mg/l/4hATE US (dust, mist)1.500 mg/l/4hn-butyl acetate (123-86-4)LD50 oral rat10770 mg/kg (Rat; Equivalent or similar to OECD 423; Experimental value; 12789 mg/kg; Rat;
Equivalent or similar to OECD 423; Experimental value; 10760 mg/kg bodyweight; Rat)
LD50 dermal rabbit> 17600 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >14112
mg/kg bodyweight; Rabbit)
ATE US (oral)10770.000 mg/kg body weightacetone (67-64-1)LD50 oral rat5800 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value)LD50 dermal rabbit20000 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >7426 mg/kg
bodyweight; Rabbit; Weight of evidence)
LC50 inhalation rat (mg/l)71 mg/l/4h (Rat; Experimental value; 76 mg/l/4h; Rat; Experimental value)LC50 inhalation rat (ppm)30000 ppm/4h (Rat; Experimental value)ATE US (oral)5800.000 mg/kg body weightATE US (dermal)20000.000 mg/kg body weightATE US (gases)30000.000 ppmV/4hATE US (vapors)71.000 mg/l/4hATE US (dust, mist)71.000 mg/l/4h2-methoxy-1-methylethyl acetate (108-65-6)LD50 oral rat6190 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value)LD50 dermal rat> 2000 mg/kg (Rat; Experimental value; Equivalent or similar to OECD 402)LD50 dermal rabbit> 2000 mg/kg body weight (Rabbit; Experimental value; Equivalent or similar to OECD 402)Skin corrosion/irritation :Not classifiedSerious eye damage/irritation :Not classifiedRespiratory or skin sensitization :Not classifiedGerm cell mutagenicity :Not classifiedCarcinogenicity :Suspected of causing cancer.styrene, inhibited (100-42-5)IARC group2B – Possibly carcinogenic to humansReproductive toxicity :Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure:May cause drowsiness or dizziness.Specific target organ toxicity repeated
exposure
:Causes damage to organs through prolonged or repeated exposure.Aspiration hazard :Not classifiedPotential Adverse human health effects and
symptoms
:Harmful if inhaled. Based on available data, the classification criteria are not met.Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause drowsiness or dizziness.
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)7/11Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
SECTION 12: Ecological information
12.1.Toxicity
n-butyl acetate (123-86-4)LC50 fish 118 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-
through system; Fresh water; Experimental value)
acetone (67-64-1)LC50 fish 25540 mg/l (LC50; EU Method C.1; 96 h; Salmo gairdneri; Static system; Fresh water;
Experimental value)
EC50 Daphnia 212600 mg/l (LC50; Other; 48 h; Daphnia magna; Static system; Fresh water; Experimental
value)
2-methoxy-1-methylethyl acetate (108-65-6)EC50 Daphnia 1380 mg/l (EC50; Equivalent or similar to OECD 202; 48 h; Daphnia magna; Static system;
Fresh water; Experimental value)
LC50 fish 2100 – 180 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Oncorhynchus mykiss;
Static system; Fresh water; Experimental value)
Threshold limit algae 1>= 1000 mg/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 96 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Experimental value)
Threshold limit algae 2> 1000 mg/l (EC50; OECD 201: Alga, Growth Inhibition Test; 96 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Experimental value)
12.2.Persistence and degradability
CLEAR URETHANE SEALER PART A (mixture)Persistence and degradabilityNot established.styrene, inhibited (100-42-5)Persistence and degradabilityReadily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD)0.42Proprietary Resin (TRADE SECRET)Persistence and degradabilityNot established.n-butyl acetate (123-86-4)Persistence and degradabilityReadily biodegradable in water. Biodegradable in the soil. Not established.Biochemical oxygen demand (BOD)
0.15 – 0.5 g O /g substance
Chemical oxygen demand (COD)
2.32 g O /g substance
ThOD
2.21 g O /g substance
Saturated Polyester Resin (TRADE SECRET)Persistence and degradabilityNot established.acetone (67-64-1)Persistence and degradabilityReadily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available.
Biochemical oxygen demand (BOD)
1.43 g O /g substance
Chemical oxygen demand (COD)
1.92 g O /g substance
ThOD
2.2 g O /g substance
BOD (% of ThOD)0.872 (20 days; Literature study)2-methoxy-1-methylethyl acetate (108-65-6)Persistence and degradabilityReadily biodegradable in water. Readily biodegradable in the soil. Low potential for adsorption
in soil.
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)8/11
12.3.Bioaccumulative potentialCLEAR URETHANE SEALER PART A (mixture)Bioaccumulative potentialNot established.styrene, inhibited (100-42-5)BCF fish 135.5 (BCF)Log Pow2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500). Not established.Proprietary Resin (TRADE SECRET)Bioaccumulative potentialNot established.n-butyl acetate (123-86-4)BCF fish 114 (BCF)Log Pow2.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method; 25
C)
Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500). Not established.Saturated Polyester Resin (TRADE SECRET)Bioaccumulative potentialNot established.acetone (67-64-1)BCF fish 10.69 (BCF)BCF other aquatic organisms 13 (BCF; BCFWIN)Log Pow-0.24 (Test data)Bioaccumulative potentialNot bioaccumulative.2-methoxy-1-methylethyl acetate (108-65-6)Log Pow1.2 (Experimental value; Equivalent or similar to OECD 117; 20 C; 0.36; Experimental value;
OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method; 25 C)
Bioaccumulative potentialLow potential for bioaccumulation (Log Kow < 4).
12.4.Mobility in soil
styrene, inhibited (100-42-5)Surface tension0.032 N/m (19 C)Log KocKoc,352; Estimated value; log Koc; 2.55; Estimated valuen-butyl acetate (123-86-4)Surface tension0.0613 N/m (20 C; 1 g/l)Log Koclog Koc,SRC PCKOCWIN v2.0; 1.268 - 1.844; QSARacetone (67-64-1)Surface tension0.0237 N/m2-methoxy-1-methylethyl acetate (108-65-6)Surface tension0.0294 N/m (20 C; 100 vol %)Log Koclog Koc,0.264; QSAR
12.5.Other adverse effects
Effect on the global warming :No known effects from this product.GWPmix comment :No known effects from this product.Other information :Avoid release to the environment.
SECTION 13: Disposal considerations
13.1.Disposal methods
Product/Packaging disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Additional information :Handle empty containers with care because residual vapors are flammable.Ecology - waste materials :Avoid release to the environment.
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)9/11
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Proper Shipping Name (DOT) :PAINTClass (DOT) :3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120Packing group (DOT) :II - Medium DangerHazard labels (DOT) :3 - Flammable liquidOther information :No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) :UN 1263 paint, 3, IIUN-No. (IMDG) :1263Proper Shipping Name (IMDG) :paintClass (IMDG) :3 - Flammable liquidsPacking group (IMDG) :II - substances presenting medium danger
Air transport
Transport document description (IATA) :UN 1263 paint, 3, IIUN-No. (IATA) :1263Proper Shipping Name (IATA) :paintClass (IATA) :3 - Flammable LiquidsPacking group (IATA) :II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)CERCLA RQ1000 lbSARA Section 311/312 Hazard ClassesImmediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
n-butyl acetate (123-86-4)CERCLA RQ5000 lbSARA Section 311/312 Hazard ClassesImmediate (acute) health hazard
Delayed (chronic) health hazard
Fire hazard
acetone (67-64-1)Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporing requirements of the United States SARA Section 313
CERCLA RQ5000 lb
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)10/11
15.2. International regulations
CANADA
No additional information available
acetone (67-64-1)Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
NoNoNoNo0.1 g/daystyrene, inhibited (100-42-5)U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
acetone (67-64-1)U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
Other information :None.Full text of H-phrases:---
---
H225Highly flammable liquid and vapor---
---
H226Flammable liquid and vapor---
---
H315Causes skin irritation---
---
H319Causes serious eye irritation---
---
H332Harmful if inhaled---
---
H335May cause respiratory irritation---
---
H336May cause drowsiness or dizziness---
---
H351Suspected of causing cancer---
---
H361Suspected of damaging fertility or the unborn child---
---
H372Causes damage to organs through prolonged or repeated exposure
CLEAR URETHANE SEALER PART A
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)11/11NFPA health hazard :2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard :3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity :2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard RatingHealth :2 Moderate Hazard - Temporary or minor injury may occurFlammability :3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical :1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
:HPersonal protection H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 07/24/2023
07/24/2023 EN (English US) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : Durakote Marine Bright Silver
CAS-No. : mixture
Product code : 315-020M
Formula : N/A
Other means of identification : Unsaturated Polyester Resin Gel Coat
1.2. Recommended use and restrictions on use
Use of the substance/mixture : Coatings
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 3 H226 Flammable liquid and vapor
Acute toxicity (inhalation:vapor) Category 4 H332 Harmful if inhaled
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Reproductive toxicity Category 1B H360 May damage fertility or the unborn child
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the aquatic environment – Acute Hazard Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H332 – Harmful if inhaled
H360 – May damage fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment.
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 2/10
P241 – Use explosion-proof electrical, lighting, ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, fume, mist, spray, vapors.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash EXPOSED AREA. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water.
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center or doctor if you feel unwell.
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see SEEK MEDICAL AID. on this label).
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS..
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS US classification
styrene, inhibited
(CAS-No.) 100-42-5 <= 33 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
STOT RE 1, H372
Aquatic Acute 2, H401
ALUMINUM PIGMENT
(CAS-No.) Proprietary <= 15 Flam. Sol. 2, H228
Acute Tox. 4 (Inhalation), H332
Eye Irrit. 2, H319
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.3 Eye Irrit. 2, H319
Skin Sens. 1, H317
Repr. 1B, H360
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 3/10
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention.
Specific treatment (see seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 4/10
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapor. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Eliminate all ignition sources if safe to do so.
Take precautionary measures against static discharge.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
ALUMINUM PIGMENT (Proprietary)
Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 5/10
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Silver
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 293 F
Flash point : >= 87 F
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.24
Density : 1.24 kg/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
VOC content : <= 403 g/l VOC is based on 100% evaporation of monomers
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 6/10
Acute toxicity (inhalation) : Harmful if inhaled.
ATE US (vapors) 11 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 Inhalation – Rat 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 Inhalation – Rat [ppm] 2770 ppm/4h (Rat; Literature study)
ATE US (gases) 4500 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight
ALUMINUM PIGMENT (Proprietary)
ATE US (gases) 4500 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : May damage fertility or the unborn child.
STOT-single exposure : Not classified
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : Dangerous for the environment. Harmful to aquatic life.
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 7/10
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
12.2. Persistence and degradability
Durakote Marine Bright Silver (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
ALUMINUM PIGMENT (Proprietary)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Durakote Marine Bright Silver (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
ALUMINUM PIGMENT (Proprietary)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 8/10
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Sewage disposal recommendations : Do not discharge into drains.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site..
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, III
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : III - Minor Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the
bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a
flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this
subchapter are applicable.
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids
with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table
2 for UN2672).
T2 - 1.5 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 60 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 220 L
DOT Vessel Stowage Location : A - The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 9/10
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, III
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : III - substances presenting low danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, III
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
ALUMINUM PIGMENT (Proprietary)
Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
Durakote Marine Bright Silver
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
07/24/2023 EN (English US) 10/10
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 07/24/2023
Other information : None.
Full text of H-phrases:
H226 Flammable liquid and vapor
H228 Flammable solid
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H360 May damage fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 11/11/2024
11/11/2024 (Date of issue) EN (English US) 1/14
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : DURATEC VINYL ESTR FED STD 33446 TAN
CAS-No. : mixture
Product code : 1911-045
Formula : N/A
1.2. Recommended use and restrictions on use
Use of the substance/mixture : coatings
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 3 H226 Flammable liquid and vapor
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Reproductive toxicity Category 1B H360 May damage fertility or the unborn child
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated
exposure
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 2/14
H360 – May damage fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment.
P241 – Use explosion-proof electrical, lighting, ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapors, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash EXPOSED AREA. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P272 – Contaminated work clothing must not be allowed out of the workplace.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water.
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see SEEK MEDICAL AID. on this label).
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS..
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 3/14
3.2. Mixtures
Name Product identifier % GHS US classification
styrene, inhibited CAS-No.: 100-42-5 41 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation:vapour),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Repr. 2, H361
STOT RE 1, H372
Aquatic Chronic 3, H412
cobalt(II) 2-ethylhexanoate CAS-No.: 136-52-7 0.3 Eye Irrit. 2, H319
Skin Sens. 1, H317
Repr. 1B, H360
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs:
Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this
label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 4/14
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapor. Flammable liquid and vapor.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Eliminate all ignition sources if safe to do so. Wash hands and other exposed areas with mild
soap and water before eating, drinking or smoking and when leaving work. Provide good
ventilation in process area to prevent formation of vapor. No open flames. No smoking. Take
precautionary measures against static discharge. Use only non-sparking tools. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-
ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment.
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 5/14
Storage conditions : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away
from : Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
DURATEC VINYL ESTR FED STD 33446 TAN (mixture)
No additional information available
styrene, inhibited (100-42-5)
USA – ACGIH – Occupational Exposure Limits
ACGIH OEL TWA [ppm] 20 ppm
ACGIH OEL STEL [ppm] 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
No additional information available
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Personal protective equipment symbol(s):
Other information:
Do not eat, drink or smoke during use.
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 6/14
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : TAN
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 275 F
Flash point : 86 F
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.08
Specific gravity / density : 1.08 kg/l
Solubility : No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
VOC content : 435 g/l VOC is based on 100 % evaporation of monomers.
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapor. Not established. Flammable liquid and
vapor. May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 7/14
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 Inhalation – Rat 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 Inhalation – Rat [ppm] 2770 ppm/4h (Rat; Literature study)
ATE US (vapors) 11 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
styrene, inhibited (100-42-5)
pH Not applicable
cobalt(II) 2-ethylhexanoate (136-52-7)
pH 6.8 (4.03 %; 20 C)
Serious eye damage/irritation : Causes serious eye irritation.
styrene, inhibited (100-42-5)
pH Not applicable
cobalt(II) 2-ethylhexanoate (136-52-7)
pH 6.8 (4.03 %; 20 C)
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : May damage fertility or the unborn child.
Specific target organ toxicity single exposure : Not classified
Specific target organ toxicity repeated exposure : Causes damage to organs through prolonged or repeated exposure.
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 8/14
styrene, inhibited (100-42-5)
Specific target organ toxicity repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
styrene, inhibited (100-42-5)
Viscosity, kinematic 0.8 mm /s
Potential Adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : Dangerous for the environment. Harmful to aquatic life.
styrene, inhibited (100-42-5)
LC50 – Fish [1] 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 – Crustacea [1] 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 algae 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 – Fish [1] 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 – Crustacea [1] 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 – Fish [2] 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water; Read-
across)
EC50 – Crustacea [2] 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit – Algae [1] 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit – Algae [2] 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
12.2. Persistence and degradability
DURATEC VINYL ESTR FED STD 33446 TAN (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 9/14
styrene, inhibited (100-42-5)
Chemical oxygen demand (COD) 2.8 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
12.3. Bioaccumulative potential
DURATEC VINYL ESTR FED STD 33446 TAN (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF – Fish [1] 35.5 (Carassius auratus, Literature study)
Partition coefficient n-octanol/water (Log Pow) 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF - Fish [1] 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Organic Carbon Normalized Adsorption Coefficient
(Log Koc)
2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Sewage disposal recommendations : Do not discharge into drains.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 10/14
SECTION 14: Transport information
In accordance with DOT / TDG / IMDG / IATA
14.1. UN number
DOT NA No : UN1866
UN-No. (TDG) : UN1866
UN-No. (IMDG) : 1866
UN-No. (IATA) : 1866
14.2. UN proper shipping name
Proper Shipping Name (DOT) : Resin solution
Proper Shipping Name (TDG) : RESIN SOLUTION
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
14.3. Transport hazard class(es)
DOT
Transport hazard class(es) (DOT) : 3
Hazard labels (DOT) : 3
TDG
Transport hazard class(es) (TDG) : 3
Hazard labels (TDG) : 3
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
14.4. Packing group
Packing group (DOT) : III
Packing group (TDG) : III
Packing group (IMDG) : III
Packing group (IATA) : III
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 11/14
14.5. Environmental hazards
Other information : No supplementary information available.
14.6. Special precautions for user
DOT
UN-No.(DOT) : UN1866
DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the
bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a
flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this
subchapter are applicable.
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief
devices are authorized on DOT 57 portable tanks.
IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids
with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table
2 for UN2672).
T2 - 1.5 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail (49
CFR 173.27)
: 60 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 220 L
DOT Vessel Stowage Location : A - The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel.
TDG
UN-No. (TDG) : UN1866
Explosive Limit and Limited Quantity Index : 5 L
Excepted quantities (TDG) : E1
Passenger Carrying Road Vehicle or Passenger
Carrying Railway Vehicle Index
: 60 L
Emergency Response Guide (ERG) Number : 127
IMDG
Special provision (IMDG) : 223, 955
Packing instructions (IMDG) : P001, LP01
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T2
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS
EmS-No. (Spillage) : S-E - SPILLAGE SCHEDULE Echo - FLAMMABLE LIQUIDS, FLOATING ON WATER
Stowage category (IMDG) : A
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
IATA
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y344
PCA limited quantity max net quantity (IATA) : 10L
PCA packing instructions (IATA) : 355
PCA max net quantity (IATA) : 60L
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 12/14
CAO packing instructions (IATA) : 366
CAO max net quantity (IATA) : 220L
Special provision (IATA) : A3
ERG code (IATA) : 3L
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. US Federal regulations
Commercial status of components according to the United States Environmental Protection Agency s Toxic Substances Control Act (TSCA):
Name CAS-No. Listing Commercial
status
Flags
styrene, inhibited 100-42-5 Present Active
cobalt(II) 2-ethylhexanoate 136-52-7 Present Active
styrene, inhibited (100-42-5)
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 13/14
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity
-Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
-Male
No significant risk
level (NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know Hazardous
Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Other information : None.
Full text of H-phrases
H226 Flammable liquid and vapor
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H360 May damage fertility or the unborn child
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary
incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can
be ignited under almost all ambient temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change at elevated
temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature conditions.
Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well
as liquids with flash points between 73 F and 100 F. (Classes IB IC)
DURATEC TAN VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2024 (Date of issue) EN (English US) 14/14
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo hazardous
polymerization in the absence of inhibitors.
Personal protection : H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
Safety Data Sheet (SDS), USA
by | Sep 27, 2025
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 12/31/2019
12/31/2019 EN (English US) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : ORANGE VINYL ESTER TOPCOAT
CAS-No. : mixture
Product code : 1908-045
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Flammable liquids Category 3 H226 Flammable liquid and vapour
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Reproductive toxicity Category 2 H361 Suspected of damaging fertility or the unborn child
Specific target organ toxicity (single exposure) Category 3 H335 May cause respiratory irritation
Specific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated exposure
Hazardous to the aquatic environment – Acute Hazard Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H226 – Flammable liquid and vapour
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 2/10
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, spray, vapors.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash EXPOSED AREA. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
P302+P352 – If on skin: Wash with plenty of water
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center or doctor if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see none llisted on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local.state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS US classification
styrene, inhibited
(CAS-No.) 100-42-5 <= 41 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 3/10
First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction
on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : May cause genetic defects. Suspected of damaging fertility or the unborn child. Causes
damage to organs.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 4/10
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapor. No open flames. No smoking. Take precautionary
measures against static discharge. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special instructions
before use. Do not handle until all safety precautions have been read and understood.
Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 5/10
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : orange
Odor : characteristic
Odor threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : 146.1 ( 64) C
Flash point : 30 - 34 C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Flammable liquid and vapour.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 1.1
Specific gravity / density : 9 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. May form flammable/explosive vapor-air
mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 6/10
styrene, inhibited (100-42-5)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg body weight
ATE US (dermal) 5010 mg/kg body weight
ATE US (gases) 2770 ppmV/4h
ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : May cause genetic defects. Suspected of damaging fertility or the unborn child. Causes
damage to organs.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 7/10
styrene, inhibited (100-42-5)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
12.2. Persistence and degradability
ORANGE VINYL ESTER TOPCOAT (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
12.3. Bioaccumulative potential
ORANGE VINYL ESTER TOPCOAT (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 8/10
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, III
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : III - Minor Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the
bulk packaging requirements of 173.241 of this subchapter are applicable. If the material has a
flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this
subchapter are applicable.
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids
with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table
2 for UN2672).
T2 - 1.5 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 60 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 220 L
DOT Vessel Stowage Location : A - The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Not applicable
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, III
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : III - substances presenting low danger
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 9/10
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, III
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
ORANGE VINYL ESTER TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
12/31/2019 EN (English US) 10/10
Revision date : 12/31/2019
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-phrases:
H226 Flammable liquid and vapour
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation
H351 Suspected of causing cancer
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)Page 1
SECTION 1: Identification
1.1. Identification
Product form :MixturesTrade name :CLEAR VINYL ESTER HI-GLOSS TOPCOATCAS-No. :mixtureProduct code :1904-045Formula :na
1.2. Recommended use and restrictions on use
Use of the substance/mixture :TOOLING TOPCOAT
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number :ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 3
H226 Flammable liquid and vaporSkin corrosion/irritation
Category 2
H315 Causes skin irritationSerious eye damage/eye
irritation Category 2A
H319 Causes serious eye irritationCarcinogenicity Category 2H351 Suspected of causing cancerReproductive toxicity
Category 2
H361 Suspected of damaging fertility or the unborn childSpecific target organ
toxicity (single exposure)
Category 3
H335 May cause respiratory irritationSpecific target organ
toxicity (repeated exposure)
Category 1
H372 Causes damage to organs (hearing sense) through prolonged or repeated exposure
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02GHS07GHS08
Signal word (GHS-US) :DangerHazard statements (GHS-US) :H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
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Safety Data Sheet
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04/13/2018EN (English US)2/9 H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs (hearing sense) through prolonged or repeated exposure
Precautionary statements (GHS-US) :P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, mist, fume, spray, vapors
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
NameProduct identifier%GHS-US classificationUnsaturated VINYL ESTER Resin(CAS-No.) TRADE SECRET<= 59.5Not classifiedstyrene, inhibited(CAS-No.) 100-42-5<= 40Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
cobalt(II) 2-ethylhexanoate(CAS-No.) 136-52-7<= 0.5Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general :Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)3/9First-aid measures after inhalation :Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention.
Specific treatment (see seek medical attention. on this label).
First-aid measures after eye contact :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects :May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.Unsuitable extinguishing media :Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard :Highly flammable liquid and vapor. Flammable liquid and vapor.Explosion hazard :May form flammable/explosive vapor-air mixture.Reactivity :No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting :Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures :Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1.For non-emergency personnel
Protective equipment :Gloves. Protective goggles. Protective clothing.Emergency procedures :Evacuate unnecessary personnel.
6.1.2.For emergency responders
Protective equipment :Equip cleanup crew with proper protection.Emergency procedures :Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment :Dam up the liquid spill. Contain released product, pump into suitable containers.Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
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SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed :Handle empty containers with care because residual vapors are flammable.Precautions for safe handling :Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a
well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so. Take precautionary measures against
static discharge. Do not breathe dust/fume/gas/mist/vapors/spray.
Hygiene measures :Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures :Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions :Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products :Strong bases. Strong acids.Incompatible materials :Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)ACGIHACGIH TWA (ppm)20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
cobalt(II) 2-ethylhexanoate (136-52-7)Not applicableUnsaturated VINYL ESTER Resin (TRADE SECRET)Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls :Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:Avoid all unnecessary exposure.
Hand protection:Wear protective glovesEye protection:Chemical goggles or safety glassesSkin and body protection:Wear suitable protective clothing
Respiratory protection:Wear appropriate mask
Other information:Do not eat, drink or smoke during use.
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state :Liquid
Color :Colourless to light yellow
Odor :characteristic
Odor threshold :No data available
pH :No data available
Melting point :No data available
Freezing point :No data available
Boiling point :146.1 ( 64) C
Flash point :32.2 (30 - 34) C
Relative evaporation rate (butyl acetate=1) :No data available
Flammability (solid, gas) :Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure :No data available
Relative vapor density at 20 C :No data available
Relative density : 1.1
Solubility :No data available
Log Pow :No data available
Auto-ignition temperature :No data available
Decomposition temperature :No data available
Viscosity, kinematic :No data available
Viscosity, dynamic :No data available
Explosion limits :No data available
Explosive properties :No data available
Oxidizing properties :No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2.Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3.Possibility of hazardous reactions
Not established.
10.4.Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5.Incompatible materials
Strong acids. Strong bases.
10.6.Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1.Information on toxicological effects
Acute toxicity :Not classifiedstyrene, inhibited (100-42-5)LD50 oral rat5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)LD50 dermal rat2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit5010 mg/kg (Rabbit; Literature study)
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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styrene, inhibited (100-42-5)
LC50 inhalation rat (mg/l)12 mg/l/4h (Rat; Literature study)LC50 inhalation rat (ppm)2770 ppm/4h (Rat; Literature study)ATE US (oral)5000.000 mg/kg body weightATE US (dermal)2820.000 mg/kg body weightATE US (gases)2770.000 ppmV/4hATE US (vapors)12.000 mg/l/4hATE US (dust, mist)1.500 mg/l/4hcobalt(II) 2-ethylhexanoate (136-52-7)LD50 oral rat3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat> 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)ATE US (oral)3129.000 mg/kg body weightSkin corrosion/irritation :Causes skin irritation.Serious eye damage/irritation :Causes serious eye irritation.Respiratory or skin sensitization :Not classifiedGerm cell mutagenicity :Not classifiedCarcinogenicity :Suspected of causing cancer.styrene, inhibited (100-42-5)IARC group2B – Possibly carcinogenic to humanscobalt(II) 2-ethylhexanoate (136-52-7)IARC group2B – Possibly carcinogenic to humansReproductive toxicity :Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure:May cause respiratory irritation.Specific target organ toxicity repeated
exposure
:Causes damage to organs (hearing sense) through prolonged or repeated exposure.Aspiration hazard :Not classifiedPotential Adverse human health effects and
symptoms
:Harmful if inhaled. Based on available data, the classification criteria are not met.Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
SECTION 12: Ecological information
12.1.Toxicity
cobalt(II) 2-ethylhexanoate (136-52-7)LC50 fish 146.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 10.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)LC50 fish 254.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 20.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)Threshold limit algae 1144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 232.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
12.2.Persistence and degradability
CLEAR VINYL ESTER HI-GLOSS TOPCOAT (mixture)Persistence and degradabilityNot established.
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)7/9styrene, inhibited (100-42-5)Persistence and degradabilityReadily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD)0.42cobalt(II) 2-ethylhexanoate (136-52-7)Persistence and degradabilityReadily biodegradable in water. No (test)data on mobility of the substance available.Unsaturated VINYL ESTER Resin (TRADE SECRET)Persistence and degradabilityNot established.
12.3.Bioaccumulative potential
CLEAR VINYL ESTER HI-GLOSS TOPCOAT (mixture)Bioaccumulative potentialNot established.styrene, inhibited (100-42-5)BCF fish 135.5 (BCF)Log Pow2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500). Not established.cobalt(II) 2-ethylhexanoate (136-52-7)BCF fish 11.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500).Unsaturated VINYL ESTER Resin (TRADE SECRET)Bioaccumulative potentialNot established.
12.4.Mobility in soil
styrene, inhibited (100-42-5)Surface tension0.032 N/m (19 C)Log KocKoc,352; Estimated value; log Koc; 2.55; Estimated valuecobalt(II) 2-ethylhexanoate (136-52-7)Surface tension0.064 N/m (20 C; 1 g/l)
12.5.Other adverse effects
Effect on the global warming :No known effects from this product.GWPmix comment :No known effects from this product.Other information :Avoid release to the environment.
SECTION 13: Disposal considerations
13.1.Disposal methods
Product/Packaging disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information :Handle empty containers with care because residual vapors are flammable.Ecology - waste materials :Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Proper Shipping Name (DOT) :RESIN SOLUTIONClass (DOT) :3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120Packing group (DOT) :III - Minor Danger
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)8/9Hazard labels (DOT) :3 - Flammable liquidOther information :No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) :UN 1866 RESIN SOLUTION, 3, IIIUN-No. (IMDG) :1866Proper Shipping Name (IMDG) :RESIN SOLUTIONClass (IMDG) :3 - Flammable liquidsPacking group (IMDG) :III - substances presenting low danger
Air transport
Transport document description (IATA) :UN 1866 RESIN SOLUTION, 3, IIIUN-No. (IATA) :1866Proper Shipping Name (IATA) :RESIN SOLUTIONClass (IATA) :3 - Flammable LiquidsPacking group (IATA) :III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)CERCLA RQ1000 lbSARA Section 311/312 Hazard ClassesImmediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
NoNoNoNo0.1 g/day
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)9/9styrene, inhibited (100-42-5)U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECTION 16: Other information
Other information :None.Full text of H-phrases:---
---
H226Flammable liquid and vapor---
---
H315Causes skin irritation---
---
H317May cause an allergic skin reaction---
---
H319Causes serious eye irritation---
---
H332Harmful if inhaled---
---
H335May cause respiratory irritation---
---
H351Suspected of causing cancer---
---
H361Suspected of damaging fertility or the unborn child---
---
H372Causes damage to organs through prolonged or repeated exposure---
---
H400Very toxic to aquatic life---
---
H411Toxic to aquatic life with long lasting effectsNFPA health hazard :2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard :3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity :2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard RatingHealth :2 Moderate Hazard - Temporary or minor injury may occurFlammability :3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical :1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
:HPersonal protection H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)Page 1
SECTION 1: Identification
1.1. Identification
Product form :MixturesTrade name :CLEAR VINYL ESTER HI-GLOSS TOPCOATCAS-No. :mixtureProduct code :1904-045Formula :na
1.2. Recommended use and restrictions on use
Use of the substance/mixture :TOOLING TOPCOAT
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number :ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 3
H226 Flammable liquid and vaporSkin corrosion/irritation
Category 2
H315 Causes skin irritationSerious eye damage/eye
irritation Category 2A
H319 Causes serious eye irritationCarcinogenicity Category 2H351 Suspected of causing cancerReproductive toxicity
Category 2
H361 Suspected of damaging fertility or the unborn childSpecific target organ
toxicity (single exposure)
Category 3
H335 May cause respiratory irritationSpecific target organ
toxicity (repeated exposure)
Category 1
H372 Causes damage to organs (hearing sense) through prolonged or repeated exposure
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02GHS07GHS08
Signal word (GHS-US) :DangerHazard statements (GHS-US) :H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)2/9 H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs (hearing sense) through prolonged or repeated exposure
Precautionary statements (GHS-US) :P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, mist, fume, spray, vapors
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
NameProduct identifier%GHS-US classificationUnsaturated VINYL ESTER Resin(CAS-No.) TRADE SECRET<= 59.5Not classifiedstyrene, inhibited(CAS-No.) 100-42-5<= 40Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
cobalt(II) 2-ethylhexanoate(CAS-No.) 136-52-7<= 0.5Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general :Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)3/9First-aid measures after inhalation :Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention.
Specific treatment (see seek medical attention. on this label).
First-aid measures after eye contact :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects :May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.Unsuitable extinguishing media :Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard :Highly flammable liquid and vapor. Flammable liquid and vapor.Explosion hazard :May form flammable/explosive vapor-air mixture.Reactivity :No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting :Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures :Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1.For non-emergency personnel
Protective equipment :Gloves. Protective goggles. Protective clothing.Emergency procedures :Evacuate unnecessary personnel.
6.1.2.For emergency responders
Protective equipment :Equip cleanup crew with proper protection.Emergency procedures :Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment :Dam up the liquid spill. Contain released product, pump into suitable containers.Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)4/9
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed :Handle empty containers with care because residual vapors are flammable.Precautions for safe handling :Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a
well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so. Take precautionary measures against
static discharge. Do not breathe dust/fume/gas/mist/vapors/spray.
Hygiene measures :Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures :Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions :Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products :Strong bases. Strong acids.Incompatible materials :Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)ACGIHACGIH TWA (ppm)20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
cobalt(II) 2-ethylhexanoate (136-52-7)Not applicableUnsaturated VINYL ESTER Resin (TRADE SECRET)Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls :Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:Avoid all unnecessary exposure.
Hand protection:Wear protective glovesEye protection:Chemical goggles or safety glassesSkin and body protection:Wear suitable protective clothing
Respiratory protection:Wear appropriate mask
Other information:Do not eat, drink or smoke during use.
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)5/9
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state :Liquid
Color :Colourless to light yellow
Odor :characteristic
Odor threshold :No data available
pH :No data available
Melting point :No data available
Freezing point :No data available
Boiling point :146.1 ( 64) C
Flash point :32.2 (30 - 34) C
Relative evaporation rate (butyl acetate=1) :No data available
Flammability (solid, gas) :Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure :No data available
Relative vapor density at 20 C :No data available
Relative density : 1.1
Solubility :No data available
Log Pow :No data available
Auto-ignition temperature :No data available
Decomposition temperature :No data available
Viscosity, kinematic :No data available
Viscosity, dynamic :No data available
Explosion limits :No data available
Explosive properties :No data available
Oxidizing properties :No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2.Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3.Possibility of hazardous reactions
Not established.
10.4.Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5.Incompatible materials
Strong acids. Strong bases.
10.6.Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1.Information on toxicological effects
Acute toxicity :Not classifiedstyrene, inhibited (100-42-5)LD50 oral rat5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)LD50 dermal rat2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit5010 mg/kg (Rabbit; Literature study)
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)6/9
styrene, inhibited (100-42-5)
LC50 inhalation rat (mg/l)12 mg/l/4h (Rat; Literature study)LC50 inhalation rat (ppm)2770 ppm/4h (Rat; Literature study)ATE US (oral)5000.000 mg/kg body weightATE US (dermal)2820.000 mg/kg body weightATE US (gases)2770.000 ppmV/4hATE US (vapors)12.000 mg/l/4hATE US (dust, mist)1.500 mg/l/4hcobalt(II) 2-ethylhexanoate (136-52-7)LD50 oral rat3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat> 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)ATE US (oral)3129.000 mg/kg body weightSkin corrosion/irritation :Causes skin irritation.Serious eye damage/irritation :Causes serious eye irritation.Respiratory or skin sensitization :Not classifiedGerm cell mutagenicity :Not classifiedCarcinogenicity :Suspected of causing cancer.styrene, inhibited (100-42-5)IARC group2B – Possibly carcinogenic to humanscobalt(II) 2-ethylhexanoate (136-52-7)IARC group2B – Possibly carcinogenic to humansReproductive toxicity :Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure:May cause respiratory irritation.Specific target organ toxicity repeated
exposure
:Causes damage to organs (hearing sense) through prolonged or repeated exposure.Aspiration hazard :Not classifiedPotential Adverse human health effects and
symptoms
:Harmful if inhaled. Based on available data, the classification criteria are not met.Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
SECTION 12: Ecological information
12.1.Toxicity
cobalt(II) 2-ethylhexanoate (136-52-7)LC50 fish 146.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 10.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)LC50 fish 254.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 20.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)Threshold limit algae 1144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 232.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
12.2.Persistence and degradability
CLEAR VINYL ESTER HI-GLOSS TOPCOAT (mixture)Persistence and degradabilityNot established.
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)7/9styrene, inhibited (100-42-5)Persistence and degradabilityReadily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD)0.42cobalt(II) 2-ethylhexanoate (136-52-7)Persistence and degradabilityReadily biodegradable in water. No (test)data on mobility of the substance available.Unsaturated VINYL ESTER Resin (TRADE SECRET)Persistence and degradabilityNot established.
12.3.Bioaccumulative potential
CLEAR VINYL ESTER HI-GLOSS TOPCOAT (mixture)Bioaccumulative potentialNot established.styrene, inhibited (100-42-5)BCF fish 135.5 (BCF)Log Pow2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500). Not established.cobalt(II) 2-ethylhexanoate (136-52-7)BCF fish 11.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500).Unsaturated VINYL ESTER Resin (TRADE SECRET)Bioaccumulative potentialNot established.
12.4.Mobility in soil
styrene, inhibited (100-42-5)Surface tension0.032 N/m (19 C)Log KocKoc,352; Estimated value; log Koc; 2.55; Estimated valuecobalt(II) 2-ethylhexanoate (136-52-7)Surface tension0.064 N/m (20 C; 1 g/l)
12.5.Other adverse effects
Effect on the global warming :No known effects from this product.GWPmix comment :No known effects from this product.Other information :Avoid release to the environment.
SECTION 13: Disposal considerations
13.1.Disposal methods
Product/Packaging disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information :Handle empty containers with care because residual vapors are flammable.Ecology - waste materials :Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Proper Shipping Name (DOT) :RESIN SOLUTIONClass (DOT) :3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120Packing group (DOT) :III - Minor Danger
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)8/9Hazard labels (DOT) :3 - Flammable liquidOther information :No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) :UN 1866 RESIN SOLUTION, 3, IIIUN-No. (IMDG) :1866Proper Shipping Name (IMDG) :RESIN SOLUTIONClass (IMDG) :3 - Flammable liquidsPacking group (IMDG) :III - substances presenting low danger
Air transport
Transport document description (IATA) :UN 1866 RESIN SOLUTION, 3, IIIUN-No. (IATA) :1866Proper Shipping Name (IATA) :RESIN SOLUTIONClass (IATA) :3 - Flammable LiquidsPacking group (IATA) :III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)CERCLA RQ1000 lbSARA Section 311/312 Hazard ClassesImmediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)Listed on EPA's Hazardous Air Pollutants (HAPS)
15.3. US State regulations
styrene, inhibited (100-42-5)U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
NoNoNoNo0.1 g/day
CLEAR VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)9/9styrene, inhibited (100-42-5)U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECTION 16: Other information
Other information :None.Full text of H-phrases:---
---
H226Flammable liquid and vapor---
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H315Causes skin irritation---
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H317May cause an allergic skin reaction---
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H319Causes serious eye irritation---
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H332Harmful if inhaled---
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H335May cause respiratory irritation---
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H351Suspected of causing cancer---
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H361Suspected of damaging fertility or the unborn child---
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H372Causes damage to organs through prolonged or repeated exposure---
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H400Very toxic to aquatic life---
---
H411Toxic to aquatic life with long lasting effectsNFPA health hazard :2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard :3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity :2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard RatingHealth :2 Moderate Hazard - Temporary or minor injury may occurFlammability :3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical :1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
:HPersonal protection H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
