by | Sep 27, 2025
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Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
43.0
* 1 Identification
Product identifier
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
Relevant identified uses of the substance or mixture.Adhesive
Application of the substance / the mixtureAdhesives
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
Information department:Environment protection department.
Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) USA
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Safety Data Sheet
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Trade name: MP55300/MP55305/MP55315 Part A (Resin)
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Hazard pictograms
GHS02GHS05GHS07GHS08
Signal wordDanger
Hazard statements
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
May cause respiratory irritation.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dusts or mists.
Wear protective gloves / eye protection / face protection.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a POISON CENTER/doctor.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If swallowed: Rinse mouth. Do NOT induce vomiting.
In case of fire: Use for extinction: CO2, powder or water spray.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
3
2
Health = 2
Fire = 3
Reactivity = 2
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
PHYSICAL HAZARD
2
3
2
Health = 2
Fire = 3
Physical Hazard = 2
(Contd. on page 3)
USA
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Safety Data Sheet
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Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture
Hazardous components:
80-62-6 methyl methacrylate 25-50%
79-41-4 methacrylic acid 2.5-10%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Overexposure, remove to fresh air and seek medical attention.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Do not induce vomiting; immediately call for medical help.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Protective clothing and respiratory protective device.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
(Contd. on page 4)
USA
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See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location away from direct heat.
Information about storage in one common storage facility:Store away from oxidizing agents.
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
80-62-6 methyl methacrylate
PEL Long-term value: 410 mg/m , 100 ppm
REL Long-term value: 410 mg/m , 100 ppm
TLV Short-term value: 410 mg/m , 100 ppm
Long-term value: 205 mg/m , 50 ppm
DSEN
79-41-4 methacrylic acid
REL Long-term value: 70 mg/m , 20 ppm
Skin
TLV Long-term value: 70 mg/m , 20 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment (see listings below)
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
(Contd. on page 5)
USA
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Safety Data Sheet
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Trade name: MP55300/MP55305/MP55315 Part A (Resin)
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Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
Face protection (face shield)
Body protection:
Protective work clothing
Emergency showers and eye wash stations should be available.
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Off White
Odor: Characteristic
Odor threshold: Not determined.
pH-value at 20 C (68 F): 3.3
Change in condition
Melting point: Undetermined.
Boiling point: 101 C (214 F)
Flash point: 10 C (50 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 430 C (806 F)
Decomposition temperature: Not determined.
Auto igniting: Not determined.
Danger of explosion: Not determined.
Flammable limits:
Lower: 2.1 Vol %
Upper: 12.5 Vol %
Vapor pressure at 20 C (68 F):28 mm Hg
Specific gravity at 20 C (68 F):1 g/cm (8.345 lbs/gal)
(Contd. on page 6)
USA
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Safety Data Sheet
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Trade name: MP55300/MP55305/MP55315 Part A (Resin)
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Relative density Not determined.
Vapor density >1 at 20C
Evaporation rate 3
Solubility in / Miscibility with
Water: Insoluble
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.0 %
Solids content: Not available
Other information <20 grams/liter [mixed]
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoid
Heat, flames, sparks.
Avoid high temperatures. Avoid freezing.
Avoid oxygen free atmospheres or inert blanketing.
Incompatible materials:
Reacts with acids.
Reacts with oxidizing agents.
Reacts with alkalis (bases)
Halogens
Avoid contact with copper, brass and black iron.
Hazardous decomposition products:
Carbon monoxide
Carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
80-62-6 methyl methacrylate
Oral LD50 7872 mg/kg (rat)
79-41-4 methacrylic acid
Oral LD50 1332 mg/kg (mouse)
Dermal LD50 500 mg/kg (rabbit)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Strong irritant with the danger of severe eye injury.
(Contd. on page 7)
USA
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Sensitization:Skin Contact - Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
80-62-6 methyl methacrylate 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:At present there are no ecotoxicological assessments.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:Must be specially treated adhering to official regulations.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1133
UN proper shipping name
DOT Adhesives
IMDG, IATA ADHESIVES
(Contd. on page 8)
USA
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Safety Data Sheet
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Trade name: MP55300/MP55305/MP55315 Part A (Resin)
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Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): 33
EMS Number: F-E,S-D
Stowage Category B
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:Limited Quantities are allowed. Refer to 49 CFR for conditions that
apply.
UN "Model Regulation": UN 1133 ADHESIVES, 3, II
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
80-62-6 methyl methacrylate
TSCA (Toxic Substances Control Act):
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
(Contd. on page 9)
USA
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Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(DSL) Canada Dosmestic Substance List
All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL
requirements.
New Jersey Right-to-Know List:
80-62-6 methyl methacrylate
79-41-4 methacrylic acid
New Jersey Special Hazardous Substance List:
80-62-6 methyl methacrylate F3, R2
79-41-4 methacrylic acid CO, F2, R2
Pennsylvania Right-to-Know List:
80-62-6 methyl methacrylate
79-41-4 methacrylic acid
Pennsylvania Special Hazardous Substance List:
80-62-6 methyl methacrylate E
Cancerogenity categories
EPA (Environmental Protection Agency)
80-62-6 methyl methacrylate E, NL
TLV (Threshold Limit Value established by ACGIH)
80-62-6 methyl methacrylate A4
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
National regulations:
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
* 16 Other information
Although the information and recommendations set forth in this SDS are presented in good faith and are believed
to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the
completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it
will make their own determination as to the suitability for their purpose prior to use. In no event will Royal
Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from
the use or reliance on the information set forth in the SDS.
Department issuing SDS:Environment protection department.
Creation Date:11/14/2016
Date of preparation / last revision11/17/2016 / -
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
(Contd. on page 10)
USA
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ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flam. Liq. 2: Flammable liquids Category 2
Skin Corr. 1A: Skin corrosion/irritation Category 1A
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Muta. 2: Germ cell mutagenicity Category 2
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
USA
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* 1 Identification
Product identifier
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
Relevant identified uses of the substance or mixture.Activator
Application of the substance / the mixtureActivator
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
Information department:Environment protection department.
Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07
Signal wordDanger
Hazard statements
Highly flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
(Contd. on page 2)
USA
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Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves / eye protection / face protection.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
Wash contaminated clothing before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
2
3
2
Health = 2
Fire = 3
Reactivity = 2
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
PHYSICAL HAZARD
2
3
2
Health = 2
Fire = 3
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture
Hazardous components:
80-62-6 methyl methacrylate 50-100%
* 4 First-aid measures
Description of first aid measures
After inhalation:
Supply fresh air and to be sure call for a doctor.
(Contd. on page 3)
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In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:Do not induce vomiting; immediately call for medical help.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fire with alcohol resistant foam.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Firefighters use standard protective equipment including flame retardant coat, helmet with face shield, gloves,
rubber boots, and in enclosed spaces, SCBA.
Protective equipment:Protective clothing and respiratory protective device.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
80-62-6 methyl methacrylate 17 ppm
PAC-2:
80-62-6 methyl methacrylate 120 ppm
PAC-3:
80-62-6 methyl methacrylate 570 ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Ensure good ventilation/exhaustion at the workplace.
(Contd. on page 4)
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Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep container closed when not in use.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location away from direct heat.
Information about storage in one common storage facility:Store away from oxidizing agents.
Further information about storage conditions:
Protect product from freezing.
Protect from heat and direct sunlight.
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
80-62-6 methyl methacrylate
PEL Long-term value: 410 mg/m , 100 ppm
REL Long-term value: 410 mg/m , 100 ppm
TLV Short-term value: 410 mg/m , 100 ppm
Long-term value: 205 mg/m , 50 ppm
DSEN
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment (see listings below)
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
(Contd. on page 5)
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Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Face protection (face shield)
Safety glasses with side shields.
Tightly sealed goggles
Body protection:
Emergency showers and eye wash stations should be available.
Protective work clothing
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Paste
Color: Not determined.
Odor: Characteristic
Odor threshold: Not determined.
pH-value: 5
Change in condition
Melting point: Undetermined.
Boiling point: 101 C (214 F)
Flash point: 10 C (50 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 430 C (806 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Flammable limits:
Lower: 2.1 Vol %
Upper: 12.5 Vol %
Vapor pressure at 20 C (68 F):47 hPa (35 mm Hg)
Specific gravity at 20 C (68 F):0.96 g/cm (8.011 lbs/gal)
Relative density Not determined.
Vapor density 3.5
Evaporation rate 3
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
(Contd. on page 6)
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Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.0 %
Solids content: Not available
Other information <20 grams/liter [mixed]
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoid
Avoid high temperatures. Avoid freezing.
Heat, flames, sparks.
Direct sunlight
Incompatible materials:
Reacts with acids.
Reacts with oxidizing agents.
Reacts with alkalis (bases)
Copper and copper alloys.
Hazardous decomposition products:
Carbon monoxide
Carbon dioxide
Nitrogen oxides
Hydrocarbons
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
80-62-6 methyl methacrylate
Oral LD50 7872 mg/kg (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:
May irritate the eye.
Vapors may be irritating to the eyes.
Sensitization:Skin Contact - Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
(Contd. on page 7)
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Carcinogenic categories
IARC (International Agency for Research on Cancer)
80-62-6 methyl methacrylate 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:At present there are no ecotoxicological assessments.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:Must be specially treated adhering to official regulations.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1133
UN proper shipping name
DOT Adhesives
IMDG, IATA ADHESIVES mixture
Transport hazard class(es)
DOT
Class 3 Flammable liquids
(Contd. on page 8)
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Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): 33
EMS Number: F-E,S-D
Stowage Category B
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:Limited Quantities are allowed. Refer to 49 CFR for conditions that
apply.
UN "Model Regulation": UN 1133 ADHESIVES MIXTURE, 3, II
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
80-62-6 methyl methacrylate
TSCA (Toxic Substances Control Act):
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(DSL) Canada Dosmestic Substance List
All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL
requirements.
(Contd. on page 9)
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New Jersey Right-to-Know List:
80-62-6 methyl methacrylate
New Jersey Special Hazardous Substance List:
80-62-6 methyl methacrylate F3, R2
Pennsylvania Right-to-Know List:
80-62-6 methyl methacrylate
Pennsylvania Special Hazardous Substance List:
80-62-6 methyl methacrylate E
Cancerogenity categories
EPA (Environmental Protection Agency)
80-62-6 methyl methacrylate E, NL
TLV (Threshold Limit Value established by ACGIH)
80-62-6 methyl methacrylate A4
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
National regulations:
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
* 16 Other information
Although the information and recommendations set forth in this SDS are presented in good faith and are believed
to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the
completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it
will make their own determination as to the suitability for their purpose prior to use. In no event will Royal
Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from
the use or reliance on the information set forth in the SDS.
Department issuing SDS:Environment protection department.
Creation Date:02/02/2017
Date of preparation / last revision02/02/2017 / -
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
(Contd. on page 10)
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Flam. Liq. 2: Flammable liquids Category 2
Skin Irrit. 2: Skin corrosion/irritation Category 2
Skin Sens. 1: Skin sensitisation Category 1
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
USA
by | Sep 27, 2025
by | Sep 27, 2025
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1 Identification
Product identifier
Trade name: TS, HP Series Adhesives
Relevant identified uses of the substance or mixture.Adhesive
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
Information department:Environment protection department.
Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
Flam. Liq. 4 H227 Combustible liquid.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07
Signal wordWarning
Hazard statements
Combustible liquid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary statements
Keep away from flames and hot surfaces. No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves / eye protection / face protection.
Wash thoroughly after handling.
(Contd. on page 2)
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Use only outdoors or in a well-ventilated area.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
IF ON SKIN: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
2
1
Health = 2
Fire = 2
Reactivity = 1
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
PHYSICAL HAZARD
2
2
1
Health = 2
Fire = 2
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture
Hazardous components:
7085-85-0 ethyl 2-cyanoacrylate 50-100%
* 4 First-aid measures
Description of first aid measures
After inhalation:
Overexposure, remove to fresh air and seek medical attention.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for 20 minutes under running water. Call a Doctor immediately.
After swallowing:Seek medical treatment.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
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Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Firefighters use standard protective equipment including flame retardant coat, helmet with face shield, gloves,
rubber boots, and in enclosed spaces, SCBA.
Protective equipment:Protective clothing and respiratory protective device.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Avoid contact with skin and eyes.
Bonds skin and eyes in seconds.
Information about protection against explosions and fires:Keep container closed when not in use.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
Store in a cool location away from direct heat.
Store only in the original receptacle.
Information about storage in one common storage facility:Store away from oxidizing agents.
Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
(Contd. on page 4)
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Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment (see listings below)
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Material of gloves
Nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Safety glasses with side shields.
Tightly sealed goggles
Use full face shield over protective eye wear when there is a risk of a splash.
Body protection:
Protective work clothing
Apron
Emergency showers and eye wash stations should be available.
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* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: TS Series: clear/opaque. HP Series: Black
Odor: Characteristic
Odor threshold: 1ppm
pH-value: Not determined.
Change in condition
Melting point: Undetermined.
Boiling point: >149 C (>300 F)
Flash point: 93 C (199 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature:
Decomposition temperature: Not determined.
Auto igniting: 485C
Danger of explosion: Not determined.
Flammable limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not determined.
Specific gravity at 20 C (68 F):1.07 g/cm (8.929 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Insoluble
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.0 %
Solids content: Not available
Other information <20 grams/liter Per SCAQMD Method 316B.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
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Conditions to avoid
Moisture
Exposure to high temperatures.
Incompatible materials:
Reacts with water.
Reacts with alcohols.
Reacts with amines.
Reacts with alkali (lyes).
Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Nitrogen oxides
Trace amounts of the following may be formed:
Hydrogen cyanide (prussic acid)
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:
Irritating effect.
Vapors may be irritating to the eyes.
Sensitization:Skin Contact - May cause allergic skin reaction.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
9011-14-7 poly (methyl mmethacrlate) 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:At present there are no ecotoxicological assessments.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
(Contd. on page 7)
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Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:Must be specially treated adhering to official regulations.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, ADN, IMDG not regulated
IATA UN3334
UN proper shipping name
DOT, ADN, IMDG not regulated
IATA Aviation regulated liquid, n.o.s. (2-methoxyethyl 2-cyanoacrylate)
Transport hazard class(es)
DOT, ADN, IMDG
Class not regulated
IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT, IMDG not regulated
IATA III
Environmental hazards: Not applicable.
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IATA Less than 500 ml not regulated.
UN "Model Regulation": not regulated
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(DSL) Canada Dosmestic Substance List
All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL
requirements.
New Jersey Right-to-Know List:
7085-85-0 ethyl 2-cyanoacrylate
New Jersey Special Hazardous Substance List:
7085-85-0 ethyl 2-cyanoacrylate F2, R2
Pennsylvania Right-to-Know List:
None of the ingredients is listed.
Pennsylvania Special Hazardous Substance List:
None of the ingredients is listed.
Cancerogenity categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients listed.
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
National regulations:
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
(Contd. on page 9)
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Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
* 16 Other information
Although the information and recommendations set forth in this SDS are presented in good faith and are believed
to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the
completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it
will make their own determination as to the suitability for their purpose prior to use. In no event will Royal
Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from
the use or reliance on the information set forth in the SDS.
Department issuing SDS:Environment protection department.
Creation Date:11/15/2016
Date of preparation / last revision11/15/2016 / -
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flam. Liq. 4: Flammable liquids Category 4
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
USA
by | Sep 27, 2025
COR-Grip NEUTRAL RADIUS PUTTY
Unsaturated Polyester Resin Compound
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
COR-Grip NEUTRAL RADIUS PUTTY
Relevant identified uses of the substance or mixture and uses advised against
Product code :PF-228-532
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs,
respiratory system) – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
respiratory system)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 20.1%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 59.2%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 35%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :7/13/2021 Date of previous issue :9/5/2018 Version:2 1/14
COR-Grip NEUTRAL RADIUS PUTTY PF-228-532
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin Compound
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 25.0 100-42-5
talc (none asbestiform) <= 21.0 14807-96-6
Man-made mineral fibers <= 5.0 65997-17-3
Ingredient name % CAS number
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
Date of issue/Date of revision :7/13/2021 Date of previous issue :9/5/2018 Version:2 2/14
COR-Grip NEUTRAL RADIUS PUTTY PF-228-532
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Remove contaminated clothing and shoes. Flush contaminated skin with plenty of
water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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Section 6. Accidental release measures
Wear protective clothing and eye or face protection:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
talc (none asbestiform) OSHA PEL 1989 (United States, 3/1989).
TWA: 2 mg/m 8 hours. Form: Respirable dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
NIOSH REL (United States, 10/2016).
TWA: 2 mg/m 10 hours. Form: Respirable fraction
ACGIH TLV (United States, 3/2019).
TWA: 2 mg/m 8 hours. Form: Respirable fraction
Man-made mineral fibers NIOSH REL (United States, 10/2016).
TWA: 3 f/cc 10 hours. Form: Fibers of spec length
TWA: 3 f/cc 10 hours.
TWA: 5 mg/m 10 hours. Form: Total
ACGIH TLV (United States, 3/2019).
TWA: 5 mg/m 8 hours. Form: Inhalable fraction
TWA: 1 f/cc 8 hours. Form: Respirable fibers: length greater than 5
uM; aspect ratio equal to or greater than 3:1 as determined by the
membrane filter method at 400-450X magnification (4-mm objective)
phase contrast illumination.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.9 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Sweetish.Odor
pH
Tan.Color
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Not applicable.
Viscosity Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 C (293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :24.6 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Polymerization may occur under certain conditions of storage and use. Keep away from
heat and flame. Keep away from oxidizing agents.
Reactive or incompatible with the following materials: acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids.
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Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
talc (none asbestiform) Skin - Mild irritant Human - 72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Man-made mineral fibers Category 3 Not applicable.Respiratory tract
irritation
Name Category Route of
exposure
Target organs
Information on toxicological effects
Classification
styrene - 2A Reasonably anticipated to be a human carcinogen.
talc (none asbestiform) - 3 -
Man-made mineral fibers - 3 -
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A)
based on hazard assessment data. The United States NTP listed styrene as reasonably
anticipated to be a human carcinogen based on "limited evidence" from studies in
humans, "sufficient evidence" from studies in experimental animals, and supporting
data on mechanisms of carcinogenesis. The significance of these results for humans
has not been established through risk assessment.
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Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Name Category
styrene Category 1 Inhalation hearing organs
talc (none asbestiform) Category 1 Inhalation Not determined
Man-made mineral fibers Category 1 Not determinedrespiratory system
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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Section 11. Toxicological information
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 7914.3 mg/kg
Inhalation (gases) 7436.8 ppm
Inhalation (vapors) 31.68 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene - - Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % - Readily - 28 days - -
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
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Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 4127.3 lbs / 1873.8 kg [450 gal / 1703.4 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
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Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; FIBROUS GLASS;
MAGNESITE DUST; TALC; SOAPSTONE
Clean Water Act (CWA) 307: Naphthenic acids, copper salts; 2-ethylhexanoic acid,
copper salt
Clean Water Act (CWA) 311: styrene; propionic acid
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Styrene
Ethylene Glycol
Form R - Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
MAGNESITE; CARBONIC ACID, MAGNESIUM SALT (1:1); SOAPSTONE
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; TALC; SOAPSTONE DUST
State regulations
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :1666666.7 lbs / 756666.7 kg [181718.4 gal / 687878.8 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs, respiratory
system) - Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 25.0
styrene 100-42-5 24.23
Any concentration shown as exact is based on formula.
Listed
If components are "Listed", and additional information is required, contact Supplier
using email in Section 16.
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Section 15. Regulatory information
Inventory list
Australia :Not determined.
Canada :At least one component is not listed in DSL but all such components are listed in NDSL.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :Not determined.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :Not determined.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
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Section 16. Other information
7/13/2021
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
7/13/2021
9/5/2018
2
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs,
respiratory system) - Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
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by | Sep 27, 2025
Safety Data Sheet
C 160
SDS Revision: Version 2.1
SDS Revision Date: 6/10/21
Page 1 of 11
1. Identification
1.1. Product identifier
Product Identity C 160
Alternate Names C 160
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet
Company Name STABOND CORPORATION
1722 W. 139th Street, GARDENA CA. 90249
Customer Service: STABOND CORPORATION (310) 380-6168 Mon. to Fri. 07:00 15:30 PT
Emergency Contact: CHEMTREC (800) 424-9300 24-hour
2. Hazard(s) identification
2.1. Classification of the substance or mixture
Flam. Liq. 2;H225 Highly Flammable liquid and vapor.
Eye Dam. 2A;H319 Causes serious eye irritation.
Repr. 2;H361D Suspected of damaging the unborn child.
STOT SE 3;H336 May cause drowsiness or dizziness.
Aquatic Chronic 3;H412 Harmful to aquatic life with long lasting effects.
2.2. Label elements
Danger
H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.
H336 May cause drowsiness and dizziness.
H361d Suspected of damaging the unborn child.
H412 Harmful to aquatic life with long lasting effects.
[Prevention]:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, sparks, open flames, and other ignition sources – No smoking.
P233 Keep container tightly closed.
P240 Ground, bond container and receiving equipment.
Name: C 160 SDS Revision Date: 6/10/21
Page 2 of 11
P241 Use explosion-proof electrical, ventilating, light, equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust, fume, gas, mist, vapors, spray.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves, eye protection, face protection.
[Response]:
P303+361+353 IF ON SKIN (or hair): Remove, take off immediately all contaminated clothing. Rinse skin with water,
shower.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and
easy to do – continue rinsing.
P308+313 IF exposed or concerned: Get medical advice or attention.
P312 Call a POISON CENTER, doctor or physician if you feel unwell.
P337+313 If eye irritation persists: Get medical advice or attention.
P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction.
[Storage]:
P403+233 Store in a well ventilated place. Keep container tightly closed.
P403+235 Store in a well ventilated place. Keep cool.
P405 Store locked up.
[Disposal]:
P501 Dispose of contents or container in accordance with local and national regulations.
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and
Federal Hazardous Substances regulations.
Ingredient/Chemical Designations Weight % GHS Classification Notes
Acetone
CAS Number: 0000067-64-1
50 – 75 Flam. Liq. 2;H225
Eye Irrit. 2;H319
STOT SE 3;H336
—-
2-Propenenitrile, polymer with 1,3-butadiene
CAS Number: 0009003-18-3
10 – 25 Not Classified —-
Chlorinated paraffin
CAS Number: 0063449-39-8
5 – 10 Not Classified —-
FORMALDEHYDE, POLYMER WITH 4-(1,1-
DIMETHYLETHYL)PH
CAS Number: 0025085-50-1
5 – 10 Not Classified —-
Formaldehyde, polymer with ammonia
CAS Number: 0055185-45-0
1 – 5 Not Classified —-
Salicylic acid
CAS Number: 0000069-72-7
1 – 5 Acute Tox. 4;H302
Eye Dam. 1;H318
Repr. 2;H361D
—-
Zinc oxide
CAS Number: 0001314-13-2
1 – 5 Aquatic Acute 1;H400
Aquatic Chronic 1;H410
—-
Name: C 160 SDS Revision Date: 6/10/21
Page 3 of 11
p-tert-Butyl phenol
CAS Number: 0000098-54-4
0.10 – 1.0 Skin Irrit. 2;H315
Eye Dam. 1;H318
Aquatic Chronic 1;H410
Repr. 2;H361F
—-
In accordance with paragraph (i) of 1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret.
*PBT/vPvB – PBT-substance or vPvB-substance.
The full texts of the phrases are shown in Section 16.
Section 4. First aid measures
4.1. Description of first aid measures
General In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.
Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give
artificial respiration. If unconscious, place in the recovery position and obtain immediate
medical attention. Give nothing by mouth.
Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and
seek medical attention.
Skin Remove contaminated clothing. Wash skin thoroughly with soap and water or use a
recognized skin cleanser.
Ingestion If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. If
vomiting should occur spontaneously keep victims head below knees to prevent aspiration
into the lungs.
4.2. Most important symptoms and effects, both acute and delayed
Overview No specific symptom data available.
Treat symptomatically. Check section 2.2 (GHS Label Elements) for further details.
Inhalation May cause drowsiness or dizziness.
Eyes Causes serious eye irritation.
Chronic effects Moderate CNS depression may be shown by giddiness, headache, dizziness and nausea.
If vomiting occurs, keep head below hips to prevent aspiration of liquid into lungs, which
can cause severe lung damage. Aspiration pneumonitis may be evidenced by coughing
and cyanosis.
Section 5. Fire-fighting measures
5.1. Extinguishing media
Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray.
Unsuitable extinguishing media: Do not use; water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition: Burning may produce fumes of carbon dioxide, carbon monoxide, hydrogen cyanide,
phenols and nitrous oxides.
Keep away from heat, sparks, open flames, and other ignition sources – No smoking.
Keep container tightly closed.
Ground, bond container and receiving equipment.
Use explosion-proof electrical, ventilating, light, equipment.
Name: C 160 SDS Revision Date: 6/10/21
Page 4 of 11
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust, fume, gas, mist, vapors, spray.
5.3. Advice for fire-fighters
Volatile solvent constituent can readily form explosive or flammable mixtures in air. Vapors can flow along surfaces to
distant ignition sources and flash back.
Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from
fire fighting to enter drains or water ways.
ERG Guide No. 127
Section 6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a major spill or
spillage in a confined space evacuate the area and check that solvent vapor levels are below the Lower Explosive
Limit before re-entering.
6.2. Environmental precautions
Do not allow spills to enter drains or waterways.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove
soiled clothing and wash thoroughly before reuse.
6.3. Methods and material for containment and cleaning up
Soak up wet material on a non-combustible absorbent and place in a closed metal container.
Section 7. Handling and storage
7.1. Precautions for safe handling
Ground and bond metal containers when dispensing. Not smoking in areas of use or stroage. Use only non-sparking
tools near wet adhesive or solvent vapors. Solvent vapor is much heavier than air and can collect in dangerous
concentrations in floor drains or low areas.
Store in cool, well ventilated area away from any ignition sources and strong oxidizing agents. Keep containers tightly
closed when not in use. Do not transfer to plastic containers.
Check section 2.2 (GHS Label Elements) for further details. – [Prevention]:
7.2. Conditions for safe storage, including any incompatibilities
Incompatible materials: Strong oxidizing agents can cause spontaneous combustion.
Check section 2.2 (GHS Label Elements) for further details. – [Storage]:
7.3. Specific end use(s)
No data available.
Name: C 160 SDS Revision Date: 6/10/21
Page 5 of 11
Section 8. Exposure controls / personal protection
8.1. Control parameters
Exposure
CAS No. Ingredient Source Value
0000067-64-1 Acetone OSHA TWA 1000 ppm (2400 mg/m3) STEL 2400 mg/m3
ACGIH TWA: 500 ppm STEL: 750 ppm
NIOSH 250 ppm (590 mg/m3) TWA
0000069-72-7 Salicylic acid OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
0000098-54-4 p-tert-Butyl phenol OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
0001314-13-2 Zinc oxide OSHA TWA 5 mg/m3 (fume) TWA 15 mg/m3 (total dust) TWA 5 mg/m3
(resp dust)
ACGIH TWA: 2 mg/m3 STEL: 10 mg/m3
NIOSH No Established Limit
0009003-18-3 2-Propenenitrile, polymer with 1,3-
butadiene
OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
0025085-50-1 FORMALDEHYDE, POLYMER WITH 4-
(1,1-DIMETHYLETHYL)PH
OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
0055185-45-0 Formaldehyde, polymer with ammonia OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
0063449-39-8 Chlorinated paraffin OSHA No Established Limit
ACGIH No Established Limit
NIOSH No Established Limit
8.2. Exposure controls
Respiratory Atmospheric levels should be maintained below the exposure guideline. Use an approved,
full-face, supplied air respirator or a NIOSH approved positive pressure, self-contained
breathing apparatus if these levels are exceeded.
Eyes Wear safety glasses with side shields to protect the eyes. An eye wash station is
suggested as a good workplace practice.
Skin Overalls which cover the body, arms and legs should be worn. Skin should not be exposed.
All parts of the body should be washed after contact. Use neoprene, vinyl or natural rubber
gloves.
Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the
use of local exhaust ventilation and good general extraction. If these are not sufficient to
maintain concentrations of particulates and any vapor below occupational exposure limits
suitable respiratory protection must be worn.
Name: C 160 SDS Revision Date: 6/10/21
Page 6 of 11
Other Work Practices Eye wash fountain or bottles. Solvent insoluble barrier hand cream. Use good personal
hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly
remove soiled clothing and wash thoroughly before reuse.
Check section 2.2 (GHS Label Elements) for further details.
Section 9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Color: medium viscosity syrup Physical State: Liquid
Odor Acetone
Odor threshold Not determined
pH Not Measured
Melting point / freezing point Not Measured
Initial boiling point and boiling range 133 F
Flash Point -4 F
Evaporation rate (Ether = 1) Slower than ether
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: 2.2%
Upper Explosive Limit: 13.0%
Vapor pressure (Pa) Not Measured
Vapor Density Heavier than air
Relative Density 0.9 (H2O=1)
Solubility in Water Nil
Partition coefficient n-octanol/water (Log Kow) Not Measured
Auto-ignition temperature Not Measured
Decomposition temperature Not Measured
Viscosity (cSt) Not Measured
VOC Content NA
Method Used TCC
9.2. Other information
No other relevant information.
Section 10. Stability and reactivity
10.1. Reactivity
Hazardous Polymerization will not occur.
10.2. Chemical stability
Stable under normal circumstances.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid
Keep away from all sources of ignition or heat.
10.5. Incompatible materials
Name: C 160 SDS Revision Date: 6/10/21
Page 7 of 11
Strong oxidizing agents can cause spontaneous combustion.
10.6. Hazardous decomposition products
Burning may produce fumes of carbon dioxide, carbon monoxide, hydrogen cyanide, phenols and nitrous oxides.
Section 11. Toxicological information
Acute toxicity
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate
was used in the calculation of the product’s ATE (Acute Toxicity Estimate).
Ingredient Oral LD50,
mg/kg
Skin LD50,
mg/kg
Inhalation
Vapor LC50,
mg/L/4hr
Inhalation
Dust/Mist
LC50,
mg/L/4hr
Inhalation
Gas LC50,
ppm
Acetone – (67-64-1) 5,800.00, Rat –
Category: NA
7,426.00, Rabbit
– Category:
NA
76.00, Rat –
Category: NA
50.10, Rat –
Category: NA
No data
available
2-Propenenitrile, polymer with 1,3-butadiene – (9003-18-
3)
No data
available
No data
available
No data
available
No data
available
No data
available
Chlorinated paraffin – (63449-39-8) 11,700.00, Rat –
Category: NA
No data
available
No data
available
No data
available
No data
available
FORMALDEHYDE, POLYMER WITH 4-(1,1-
DIMETHYLETHYL)PH – (25085-50-1)
No data
available
No data
available
No data
available
No data
available
No data
available
Formaldehyde, polymer with ammonia – (55185-45-0) No data
available
No data
available
No data
available
No data
available
No data
available
Salicylic acid – (69-72-7) 891.00, Rat –
Category: 4
10,000.00,
Rabbit –
Category: NA
No data
available
No data
available
No data
available
Zinc oxide – (1314-13-2) > 5,000.00, Rat
– Category:
NA
No data
available
No data
available
5.70, Rat –
Category: 5
No data
available
p-tert-Butyl phenol – (98-54-4) 4,000.00, Rat –
Category: 5
1,580.00,
Mammal –
Category: 4
No data
available
5.60, Rat –
Category: NA
No data
available
Carcinogen Data
CAS No. Ingredient Source Value
0000067-64-1 Acetone OSHA Regulated Carcinogen: No;
NTP Known: No; Suspected: No;
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH A4
0000069-72-7 Salicylic acid OSHA Regulated Carcinogen: No;
NTP Known: No; Suspected: No;
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0000098-54-4 p-tert-Butyl phenol OSHA Regulated Carcinogen: No;
NTP Known: No; Suspected: No;
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0001314-13-2 Zinc oxide OSHA Regulated Carcinogen: No;
NTP Known: No; Suspected: No;
Name: C 160 SDS Revision Date: 6/10/21
Page 8 of 11
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0009003-18-3 2-Propenenitrile, polymer with 1,3-
butadiene
OSHA Regulated Carcinogen: No;
NTP Known: No; Suspected: No;
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0025085-50-1 FORMALDEHYDE, POLYMER
WITH 4-(1,1-DIMETHYLETHYL)PH
OSHA Regulated Carcinogen: No;
NTP Known: No; Suspected: No;
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0055185-45-0 Formaldehyde, polymer with
ammonia
OSHA Regulated Carcinogen: No;
NTP Known: No; Suspected: No;
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
ACGIH No Established Limit
0063449-39-8 Chlorinated paraffin OSHA Regulated Carcinogen: No;
NTP Known: No; Suspected: Yes;
IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No;
ACGIH No Established Limit
Classification Category Hazard Description
Acute toxicity (oral) — Not Applicable
Acute toxicity (dermal) — Not Applicable
Acute toxicity (inhalation) — Not Applicable
Skin corrosion/irritation — Not Applicable
Serious eye damage/irritation 2A Causes serious eye irritation.
Respiratory sensitization — Not Applicable
Skin sensitization — Not Applicable
Germ cell mutagenicity — Not Applicable
Carcinogenicity — Not Applicable
Reproductive toxicity 2 Suspected of damaging the unborn child.
STOT-single exposure 3 May cause drowsiness or dizziness.
STOT-repeated exposure — Not Applicable
Aspiration hazard — Not Applicable
Section 12. Ecological information
Name: C 160 SDS Revision Date: 6/10/21
Page 9 of 11
12.1. Toxicity
Harmful to aquatic life with long lasting effects.
Aquatic Ecotoxicity
Ingredient
96 hr LC50 fish,
mg/l
48 hr EC50 crustacea,
mg/l
ErC50 algae,
mg/l
Acetone – (67-64-1) 8,120.00, Pimephales
promelas
8,800.00, Daphnia
pulex
7,000.00 (96 hr), Pseudokirchneriella
subcapitata
2-Propenenitrile, polymer with 1,3-butadiene – (9003-
18-3)
Not Available Not Available Not Available
Chlorinated paraffin – (63449-39-8) 300.00, Lepomis
macrochirus
102.00, Daphnia
magna
Not Available
FORMALDEHYDE, POLYMER WITH 4-(1,1-
DIMETHYLETHYL)PH – (25085-50-1)
Not Available Not Available Not Available
Formaldehyde, polymer with ammonia – (55185-45-0) Not Available Not Available Not Available
Salicylic acid – (69-72-7) 90.00, Leuciscus idus 105.00, Daphnia
magna
Not available
Zinc oxide – (1314-13-2) Not Available 101.00, Daphnia
magna
Not Available
p-tert-Butyl phenol – (98-54-4) 5.14, Pimephales
promelas
3.90, Daphnia magna Not available
12.2. Persistence and degradability
There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available.
Section 13. Disposal considerations
13.1. Waste treatment methods
Observe all federal, state and local regulations when disposing of this substance.
Section 14. Transport information
DOT (Domestic Surface
Transportation)
IMO / IMDG (Ocean
Transportation)
ICAO/IATA
14.1. UN number UN1133 UN1133 UN1133
14.2. UN proper
shipping name
UN1133, Adhesives, containing a
flammable liquid, 3, II
Adhesives, containing a
flammable liquid
Adhesives, containing a
flammable liquid
Name: C 160 SDS Revision Date: 6/10/21
Page 10 of 11
14.3. Transport
hazard class(es)
DOT Hazard Class: 3
Sub Class: Not Applicable
IMDG: 3
Sub Class: Not Applicable
Air Class: 3
Sub Class: Not
Applicable
14.4. Packing group II II II
14.5. Environmental hazards
IMDG Marine Pollutant: No;
14.6. Special precautions for user
Not Applicable
Section 15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected
regulations are represented.
Toxic Substance
Control Act ( TSCA)
All components of this material are either listed or exempt from listing on the TSCA
Inventory.
EPCRA 302 Extremely Hazardous:
Cresol
Phenol
EPCRA 313 Toxic Chemicals:
Zinc oxide
Proposition 65 – Carcinogens (>0.0%):
1,3 Butadiene
4-Vinylcyclohexene
Benzene
Cadmium
Formaldehyde
Lead
Propenenitrile
Proposition 65 – Developmental Toxins (>0.0%):
1,3 Butadiene
Benzene
Lead
Proposition 65 – Female Repro Toxins (>0.0%):
1,3 Butadiene
4-Vinylcyclohexene
Lead
Proposition 65 – Male Repro Toxins (>0.0%):
1,3 Butadiene
Benzene
Cadmium
Name: C 160 SDS Revision Date: 6/10/21
Page 11 of 11
Lead
Proposition 65 Label Warning:
WARNING: This product can expose you to chemicals including [1,3 Butadiene, 4-Vinylcyclohexene,
Benzene, Cadmium, Formaldehyde, Lead, Propenenitrile], which are known to the State of California to
cause cancer, and [1,3 Butadiene, 4-Vinylcyclohexene, Benzene, Cadmium, Lead], which are known to
the State of California to cause birth defects or other reproductive harm. For more information go to
www.P65Warnings.ca.gov.
Section 16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no
guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We
accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our
products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and
orders.
The full text of the phrases appearing in section 3 is:
H225 Highly flammable liquid and vapor.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness and dizziness.
H361 Suspected of damaging fertility or the unborn child.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
SDS Revision History
Version 1.1 Initial SDS issued 12/19/2014
Version 1.2 Sections 3, 8.1, 11, 12 corrections 5/27/2015
Version 1.3 Section 1.3 Change to Emergency Tele. Number 6/17/2015
Version 1.4 Sections 3, 8.1, 11, 12.1 Polymer name correction 3/09/2016
Version 1.5 Section 1.3 Update to Emergency Tele. Number 11/20/2018
Version 2.1 SDS revised and reissued 6/10/2021
ALL INFORMATION IS BASED UPON DATA FROM MFG S AND/OR TECHNICAL SOURCE, & IS BELIEVED TO BE
ACCURATE. CONDITIONS OF USE ARE BEYOND OUR CONTROL & THEREFORE USERS ARE RESPONSIBLE TO
VERIFY THIS DATA UNDER THEIR OWN CONDITIONS TO DETERMINE SUITABILITY FOR THEIR PURPOSE, &
THEY ASSUME ALL R ISKS OF USE, HANDLING, & DISPOSAL, OR FROM USE OF INFORMATION CONTAINED
HEREIN. THIS INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DOES NOT
RELATE TO ITS USE IN COMBINATION WITH OTHER MATERIAL OR IN ANY OTHER PROCESS.
End of Document
by | Sep 27, 2025
Poly-Fair F26 R
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Poly-Fair F26 R
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
TOXIC TO REPRODUCTION (Fertility) – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
AQUATIC HAZARD (ACUTE) – Category 3
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H361 – Suspected of damaging fertility.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
H402 – Harmful to aquatic life.
Hazard pictograms :
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:3.01 1/14
Poly-Fair F26 R
Section 2. Hazards identification
Precautionary statements
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P273 – Avoid release to the environment.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
P272 (OSHA) – Contaminated work clothing must not be allowed out of the workplace.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P363 – IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 – If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 34.447 100-42-5
cobalt bis(2-ethylhexanoate) 0.59735 136-52-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :CF026E03
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Specific treatments :No specific treatment.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. This material is harmful to aquatic life. Fire water
contaminated with this material must be contained and prevented from being discharged
to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure – obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Avoid release to the environment. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Store and use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Take precautionary measures against electrostatic
discharges. Empty containers retain product residue and can be hazardous. Do not
reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2016).
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state Liquid. [Paste.]
SolventOdor
pH
PinkColor
Not available.
Not available.Odor threshold
:
:
:
:
:
Appearance
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Section 9. Physical and chemical properties
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Not available.
0.65 to 0.75
Not available.
Not available.
Not available.
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat >2000 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :Suspected of damaging fertility.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 6769.7 mg/kg
Inhalation (gases) 6568.2 ppm
Inhalation (vapors) 27.98 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
cobalt bis(2-ethylhexanoate)- – Not readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Resin solution RESIN
SOLUTION
Resin solution
UN1866UN1866 UN1866
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN
SOLUTION
ADR/RID
UN1866
RESIN
SOLUTION
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
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Section 14. Transport information
3
III
3
III
3
III
Reportable
quantity 2903
lbs / 1318 kg
[497.38 gal /
1882.8 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
3
III
No.
Special
provisions 223
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Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: FIBROUS GLASS; STYRENE;
PHENYLETHYLENE
WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product
contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 34.447
cobalt bis(2-ethylhexanoate) 136-52-7 0.59735
styrene 100-42-5 34.447
cobalt bis(2-ethylhexanoate) 136-52-7 0.59735
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: COBALT compounds; STYRENE MONOMER;
BENZENE, ETHENYL-
Pennsylvania :The following components are listed: COBALT COMPOUNDS; BENZENE, ETHENYL-
State regulations
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 34.447 Yes. No. No. Yes. Yes.
cobalt bis(2-ethylhexanoate) 0.59735 No. No. No. Yes. Yes.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
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Section 15. Regulatory information
styrene Yes. No. – –
ethanediol No. Yes. – –
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Section 16. Other information
1/8/2019
History
Date of printing :
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
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Section 16. Other information
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
1/8/2019
10/24/2018
3.01
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:3.01 14/14
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
by | Sep 27, 2025
SDS
SAFETY DATA SHEET
SDS Number:
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BD54125, BD5430 FLEX, LV, MV, HV, NS, BK Part B
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Revision No.: 4
Revision Date:03/20/2020
3
Section 1 IDENTIFICATION
Product Name: BD5402, BD5405, BD5410, BD54110, BD5420, BD54125, BD5430
FLEX, LV, MV, HV, NS, BK Part B Hardener
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD5402, BD5405, BD5410, BD54110, BD5420, BD54125, BD5430
FLEX, LV, MV, HV, NS, BK Part B Hardener
Materials Uses: Epoxy Hardener used with an Epoxy Resin to Bond Various Substrates.
In Case of Emergency Contact CHEMTREC: 800-424-9300; USA 703-527-3887
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Health
Acute Oral Toxicity, Category 4
Acute Dermal Toxicity, Category 4
Acute Inhalation Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
GHS Precaution Statements:
Prevention:
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
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P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only if
the person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept low so that the
stomach vomit doesn t enter the lungs.
Part B Hardener:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, C, D2B
Health 2
Flammability 1
1
Reactivity 0
PPE X
2
0
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name: Mixtures, Adhesives CAS # % by Weight
Fatty acids, C18-unsaturated, dimers, reaction 68410-23-1 > 80%
Products with polyethylenepolyamines
Triethylenetetramine < 3 %
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
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Revision Date:03/20/2020
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Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Loosen clothing as necessary and position individual in a comfortable position. Move exposed to
fresh air. Give artificial respiration if necessary. If breathing is difficult give oxygen. Immediately get medical
assistance.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, water spray, fog, dry chemical or CO2, or alcohol resistant foam.
Specific Hazards Arising from the Chemical: Fire may produce irritating, corrosive and/or toxic gases.
Special Protective Equipment and Precautions for Firefighters: Firefighters must use standard protective
equipment including flame retardant coat, helmet with face shield, gloves, and rubber boots. In enclosed
spaces, use self-contained breathing apparatus (SCBA) and protective clothing.
Flammability Classification: Combustible, Class IIIB estimated.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Autoignition Temp.: 816
o
F (436
o
C).
LEL: Not Available
UEL: Not Available
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: Keep unnecessary personnel
away. Avoid contact with skin or inhalation of spillage, dust or vapor. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them.
Eliminate all sources of ignition. For large spill or leak wear self-contained breathing apparatus (SCBA) and
appropriate PPE.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Avoid releases to the environment. Retain and dispose of contaminated was water. Keep out of sewers and
drains. Contact local authorities if case of spillage to drain/aquatic environment.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Keep container closed. Handle containers with care. Open slowly in order to control
possible pressure release. Store in a cool, well ventilated area.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Fatty acids, C18-unsaturated, dimers, reaction
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Products with polyethylenepolyamines (CAS No: 68410-23-1) None
Triethylenetetramine AIHA WEEL (1999-01-01)
TWA TLV and PEL 1 PPM
Engineering Controls: Provide adequate ventilation (general or local exhaust). Ensure that a working
eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Part B Hardener
Appearance: Viscous Liquid
Odor: Faint Amine Odor
Odor Threshold: Not Available
pH: Not Available
Melting Point / Freezing Point: Not Available
Initial Boiling Point: Not Available
Flash Point and Method: Open Cup: Greater than > 110
o
C (>230
o
F) (ASTM D 4206)
Flammability: Combustible, Class IIIB
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Vapor Pressure: .09 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 1 (Air = 1)
Relative Density: 7.7 9.8 lbs./gallon
Solubility in Water: Slightly
Partition Coefficient (n-Octanol in Water): Not Applicable
Auto-Ignition Temperature: 816
o
F (436
o
C)
Decomposition Temperature: Not Available
Viscosity (Dynamic CPS/mPa-s): Various
Percent Volatile: Not Available
Specific Gravity: 0.95 1.2
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable under normal conditions.
Chemical Stability: The product is stable.
Possibility of Hazardous Reactions: Under normal conditions of storage and use, hazardous reactions will not
occur.
Conditions to Avoid: Avoid exposure obtain special instructions before use. Avoid all possible sources of
ignition (spark or flame).
Materials to Avoid (Incompatibility): strong oxidizing agents,
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Hazardous Decomposition Products: Under normal conditions of storage and use, hazardous decomposition
products should not be produced.
Other hazards: Heating this substance above 300
o
F in the presence of air may cause slow oxidative
decomposition; above 500
o
F polymerization may occur.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Fatty acids, C18-unsaturated, dimers, reaction
Products with polyethylenepolyamines (CAS No: 68410-23-1) LD50 = > 5,000 mg/kg (oral, rat)
Triethylenetetramine LD50 = 2,500 mg/kg (oral, rat)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation:
Product/ingredient name Result Species Score Exposure Observation
Triethylenetetramine Eyes -Moderate irritant Rabbit 24 hours
Skin Severe irritant Rabbit 24 hours
Eyes Severe irritant Rabbit
Eye Damage / Irritation: Causes serious eye damage.
Respiratory Sensitization: Harmful if inhaled.
Skin Sensitization: Harmful in contact with skin.
Ingestion: Harmful if swallowed.
Mutagenicity: Not Available.
Carcinogenicity: Not Available.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Not Available.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be toxic to aquatic organisms and may cause long term
adverse effects in an aquatic environment.
Product/ingredient name Result Species Exposure
Triethylenetetramine Acute LC50 33,900 g/l Fresh water Aquatic invertebrates, Water flea 48 hour
Acute EC50 3,700 g/l Fresh water Aquatic plants Green algae 96 hour
Persistence and Degradability: Benzyl Alcohol (CAS 100-51-6) – Biodegradability Biotic/Aerobic Result 92 to
96% – Readily Biodegradable.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
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Product/ingredient name LogPow BCF Potential
Triethylenetetramine -1.66 to -1.4 Low
Fatty acids, C18-unsaturated,
dimers, reaction products with
polyethylenepolyamines
(CAS 68410-23-1)
492.00 Low
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Part B Hardener: The generation of waste should be avoided or minimized wherever possible. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and
non-recycle-able products via a licensed waste disposal contractor. Waste should not be disposed of untreated
to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken when handling emptied
containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers.
Section 14 TRANSPORT INFORMATION
CFR: Not Regulated
TDG: Not Regulated
DOT Classification: Not Regulated
IATA:
IMO:
Marine Pollutant: No
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
United States TSCA 12(b) Chemical export notification: None required.
United States TSCA 5(a)2 Final significant new use rules: Not listed.
United States TSCA 5(a)2 Proposed significant new use rules: Not listed.
United States TSCA 5(e) Substances consent order: Not listed.
SARA 311/312 Chemical: Yes
Classification Hazard Categories: Immediate (acute) health hazard
Acute Toxicity (any route of exposure)
Serious eye damage or eye irritation
SARA 313 (TRI reporting) Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPS) List: Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated.
Safe Drinking Water Act (SDWA): Not regulated.
State Regulations
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California Proposition 65: None required.
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: March 20, 2020
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: sales@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the
above-named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
SDS
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Revision Date:03/20/2020
3
Section 1 IDENTIFICATION
Product Name: BD5402, BD5405, BD5410, BD54110, BD5420, BD54125, BD5430,
FLEX, LV, MV, HV, NS, BK Part A RESIN
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD5402, BD5405, BD5410, BD54110, BD520, BD54125, BD5430
FLEX, LV, MV, HV, NS, BK Part A RESIN
Materials Uses: Epoxy RESIN used with an Epoxy Hardener (Part B) to Bond Various Substrates.
In Case of Emergency Contact CHEMTREC: 800-424-9300; USA 703-527-3887
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Health
Skin Corrosion/Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause an allergic skin reaction
H335 May cause respiratory irritation
GHS Precaution Statements:
Prevention:
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
SDS
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P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only if
the person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept low so that the
stomach vomit doesn t enter the lungs.
Part A RESIN:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, C, D2B
Health 2
Flammability 1
1
Reactivity 0
PPE X
2
0
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name: Mixtures, Adhesives CAS # % by Weight
Bisphenol A Epoxy Resin 25068-38-6 80 100%
Non-hazardous Ingredients Not Applicable < 10%
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
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Respiratory: Loosen clothing as necessary and position individual in a comfortable position. Move exposed to
fresh air. Give artificial respiration if necessary. If breathing is difficult give oxygen. Immediately get medical
assistance.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, water spray, fog, dry chemical or CO2, or alcohol resistant foam.
Specific Hazards Arising from the Chemical: Fire may produce irritating, corrosive and/or toxic gases.
Hazardous Thermal: Decomposition products may include the following materials: Carbon dioxide, carbon
monoxide, halogenated compounds.
Special Protective Equipment and Precautions for Firefighters: Firefighters must use standard protective
equipment including flame retardant coat, helmet with face shield, gloves, and rubber boots. In enclosed
spaces, use self-contained breathing apparatus (SCBA) and protective clothing.
Flammability Classification: Combustible, Class IIIB estimated.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Autoignition Temp.: Not Available
LEL: Not Available
UEL: Not Available
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: Keep unnecessary personnel
away. Avoid contact with skin or inhalation of spillage, dust or vapor. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them.
Eliminate all sources of ignition. For large spill or leak wear self-contained breathing apparatus (SCBA) and
appropriate PPE.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Avoid releases to the environment. Retain and dispose of contaminated was water. Keep out of sewers and
drains. Contact local authorities if case of spillage to drain/aquatic environment.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Keep container closed. Handle containers with care. Open slowly in order to control
possible pressure release. Store in a cool, well ventilated area.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Bisphenol A Epoxy Resin (CAS: 25068-38-6) None
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Engineering Controls: Provide adequate ventilation (general or local exhaust). Ensure that a working
eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Part A RESIN
Appearance: Viscous Liquid
Color: Clear
Odor: Not Available
Odor Threshold: Not Available
pH: Not Available
Melting Point / Freezing Point: Not Available
Initial Boiling Point: 260
o
C (500
o
F)
Flash Point and Method: Pensky-Martens Closed Cup: 251
o
C (>484
o
F) (ASTM D 93)
Flammability: Not Available
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Vapor Pressure: .03 mm Hg @ 77
o
C (171
o
F)
Vapor Density: Not Available
Relative Density: 1.17 (9.7 lbs./gallon)
Solubility in Water: Negligible
Partition Coefficient (n-Octanol in Water): Not Available
Auto-Ignition Temperature: Not Available
Decomposition Temperature: Not Available
Viscosity (Dynamic CPS/mPa-s): 8,000 to 10,000 CPS
Percent Volatile: Not Available
Specific Gravity: 1.17
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable under normal conditions.
Chemical Stability: The product is stable.
Possibility of Hazardous Reactions: Under normal conditions of storage and use, hazardous reactions will not
occur.
Conditions to Avoid: Avoid exposure obtain special instructions before use. Avoid all possible sources of
ignition (spark or flame).
Materials to Avoid (Incompatibility): strong oxidizing materials, strong acids, strong alkalis.
Hazardous Decomposition Products: Under normal conditions of storage and use, hazardous decomposition
products should not be produced.
Other hazards: Reacts with considerable heat release with some curing agents.
SDS
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Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Bisphenol A Epoxy Resin (CAS: 25068-38-6) LD50 = 11,400 mg/kg (oral, rat)
LD50 = 2,000 mg/kg (dermal, rat)
Conclusion/Summary: Not Available
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Irritation/Corrosion:
Product/ingredient name Result Species Score Exposure Observation
Bisphenol A Epoxy Resin
(CAS: 25068-38-6)
Skin Erythema/Eschar 404 Acute
Dermal Irritation/Corrosion
Rabbit 1.5 2
Skin Edema 404 Acute
Dermal Irritation/Corrosion
Rabbit 1.0 1.5
Eyes 405 Acute Eye
Irritation/Corrosion
Rabbit 0
Eyes Redness of the Conjunctivae Rabbit 0.7
Skin Moderate Irritation Rabbit 24 hours
Skin Severe Irritant Rabbit 24 hours
Eyes Mild Irritant Rabbit
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Ingestion: Not Available.
Mutagenicity: Not Available.
Carcinogenicity: Not Available.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Not Available.
STOST- Single Exposure:
Product/ingredient name Category Route of Exposure Target Organ
Bisphenol A Epoxy Resin (CAS 26068-38-6) Category 3
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be toxic to aquatic organisms and may cause long term
adverse effects in an aquatic environment.
Product/ingredient name Result Species Exposure
Bisphenol A Epoxy Resin
(CAS 25068-38-6)
Acute LC50 1.3 mg/l – 203 Fish,
Acute Toxicity Test
Fish – Fish 96 hour
Acute EC50 2.1 mg/l – 202 Daphnia sp.
Acute Immobilization Test and Reproductive
Test
Aquatic invertebrates. Water Flea 48 hour
SDS
SAFETY DATA SHEET
SDS Number:
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RESIN
Revision No.: 4
Revision Date:03/20/2020
3
Acute No-observable-effect-concentration
0.3 mg/l 211 Daphnia Magna
Reproduction Test
Aquatic invertebrates. Water Flea 21 day
Acute LC50 > 11 mg/l Aquatic plants – Algae 72 hour
Persistence and Degradability: Not Available.
Bioaccumulative Potential:
Product/ingredient name LogPow BCF Potential
Bisphenol A Epoxy Resin
(CAS 26068-38-6)
2.64 3.78 3 31 31.00 Low
Mobility in Soil: Not Available.
Other Adverse Effects: No known significant effects or critical hazards.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Part A RESIN: The generation of waste should be avoided or minimized wherever possible. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and
non-recycle-able products via a licensed waste disposal contractor. Waste should not be disposed of untreated
to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken when handling emptied
containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers.
Section 14 TRANSPORT INFORMATION
CFR: Not Regulated
TDG: Not Regulated
DOT Classification: Not Regulated
IATA:
IMO:
Marine Pollutant: YES
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
United States TSCA 12(b) Chemical export notification: None required.
United States TSCA 5(a)2 Final significant new use rules: Not listed.
United States TSCA 5(a)2 Proposed significant new use rules: Not listed.
United States TSCA 5(e) Substances consent order: Not listed.
SARA 311/312 Chemical: Yes
Classification Hazard Categories: Immediate (acute) health hazard
SDS
SAFETY DATA SHEET
SDS Number:
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BD54125, BD5430, FLEX, LV, MV, HV, NS, BK Part A
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Revision Date:03/20/2020
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SARA 313 (TRI reporting) Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPS) List: Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated.
Safe Drinking Water Act (SDWA): Not regulated.
State Regulations
California Proposition 65: WARNING: This product contains less than 0.1% of a chemical known to the
State of California to cause cancer. WARNING: This product contains less than
1% of a chemical known to the State of California to cause birth defects or other
reproductive harm.
Ingredient Name Cancer Reproductive No significant risk level Maximum acceptable dosage
level
Oxirane, 2-(phenoxymethyl)- Yes No 5 g/day No
Phenol, 4,4 -(1-methylethylidene)bis- No Yes No No
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: March 20, 2020
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: sales@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the
above-named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
