23BD540550_SDS.pdf
SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 7
BD5402, BD5405, BD5410, BD54110, BD5420,
BD54125, BD5430 FLEX, LV, MV, HV, NS, BK Part B
Hardener
Revision No.: 4
Revision Date:03/20/2020
3
Section 1 IDENTIFICATION
Product Name: BD5402, BD5405, BD5410, BD54110, BD5420, BD54125, BD5430
FLEX, LV, MV, HV, NS, BK Part B Hardener
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD5402, BD5405, BD5410, BD54110, BD5420, BD54125, BD5430
FLEX, LV, MV, HV, NS, BK Part B Hardener
Materials Uses: Epoxy Hardener used with an Epoxy Resin to Bond Various Substrates.
In Case of Emergency Contact CHEMTREC: 800-424-9300; USA 703-527-3887
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Health
Acute Oral Toxicity, Category 4
Acute Dermal Toxicity, Category 4
Acute Inhalation Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
GHS Precaution Statements:
Prevention:
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
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P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only if
the person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept low so that the
stomach vomit doesn t enter the lungs.
Part B Hardener:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, C, D2B
Health 2
Flammability 1
1
Reactivity 0
PPE X
2
0
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name: Mixtures, Adhesives CAS # % by Weight
Fatty acids, C18-unsaturated, dimers, reaction 68410-23-1 > 80%
Products with polyethylenepolyamines
Triethylenetetramine < 3 %
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
SDS
SAFETY DATA SHEET
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BD5402, BD5405, BD5410, BD54110, BD5420,
BD54125, BD5430 FLEX, LV, MV, HV, NS, BK Part B
Hardener
Revision No.: 4
Revision Date:03/20/2020
3
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Loosen clothing as necessary and position individual in a comfortable position. Move exposed to
fresh air. Give artificial respiration if necessary. If breathing is difficult give oxygen. Immediately get medical
assistance.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, water spray, fog, dry chemical or CO2, or alcohol resistant foam.
Specific Hazards Arising from the Chemical: Fire may produce irritating, corrosive and/or toxic gases.
Special Protective Equipment and Precautions for Firefighters: Firefighters must use standard protective
equipment including flame retardant coat, helmet with face shield, gloves, and rubber boots. In enclosed
spaces, use self-contained breathing apparatus (SCBA) and protective clothing.
Flammability Classification: Combustible, Class IIIB estimated.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Autoignition Temp.: 816
o
F (436
o
C).
LEL: Not Available
UEL: Not Available
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: Keep unnecessary personnel
away. Avoid contact with skin or inhalation of spillage, dust or vapor. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them.
Eliminate all sources of ignition. For large spill or leak wear self-contained breathing apparatus (SCBA) and
appropriate PPE.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Avoid releases to the environment. Retain and dispose of contaminated was water. Keep out of sewers and
drains. Contact local authorities if case of spillage to drain/aquatic environment.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Keep container closed. Handle containers with care. Open slowly in order to control
possible pressure release. Store in a cool, well ventilated area.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Fatty acids, C18-unsaturated, dimers, reaction
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Products with polyethylenepolyamines (CAS No: 68410-23-1) None
Triethylenetetramine AIHA WEEL (1999-01-01)
TWA TLV and PEL 1 PPM
Engineering Controls: Provide adequate ventilation (general or local exhaust). Ensure that a working
eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Part B Hardener
Appearance: Viscous Liquid
Odor: Faint Amine Odor
Odor Threshold: Not Available
pH: Not Available
Melting Point / Freezing Point: Not Available
Initial Boiling Point: Not Available
Flash Point and Method: Open Cup: Greater than > 110
o
C (>230
o
F) (ASTM D 4206)
Flammability: Combustible, Class IIIB
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Vapor Pressure: .09 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 1 (Air = 1)
Relative Density: 7.7 9.8 lbs./gallon
Solubility in Water: Slightly
Partition Coefficient (n-Octanol in Water): Not Applicable
Auto-Ignition Temperature: 816
o
F (436
o
C)
Decomposition Temperature: Not Available
Viscosity (Dynamic CPS/mPa-s): Various
Percent Volatile: Not Available
Specific Gravity: 0.95 1.2
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable under normal conditions.
Chemical Stability: The product is stable.
Possibility of Hazardous Reactions: Under normal conditions of storage and use, hazardous reactions will not
occur.
Conditions to Avoid: Avoid exposure obtain special instructions before use. Avoid all possible sources of
ignition (spark or flame).
Materials to Avoid (Incompatibility): strong oxidizing agents,
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Revision No.: 4
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Hazardous Decomposition Products: Under normal conditions of storage and use, hazardous decomposition
products should not be produced.
Other hazards: Heating this substance above 300
o
F in the presence of air may cause slow oxidative
decomposition; above 500
o
F polymerization may occur.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Fatty acids, C18-unsaturated, dimers, reaction
Products with polyethylenepolyamines (CAS No: 68410-23-1) LD50 = > 5,000 mg/kg (oral, rat)
Triethylenetetramine LD50 = 2,500 mg/kg (oral, rat)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation:
Product/ingredient name Result Species Score Exposure Observation
Triethylenetetramine Eyes -Moderate irritant Rabbit 24 hours
Skin Severe irritant Rabbit 24 hours
Eyes Severe irritant Rabbit
Eye Damage / Irritation: Causes serious eye damage.
Respiratory Sensitization: Harmful if inhaled.
Skin Sensitization: Harmful in contact with skin.
Ingestion: Harmful if swallowed.
Mutagenicity: Not Available.
Carcinogenicity: Not Available.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Not Available.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be toxic to aquatic organisms and may cause long term
adverse effects in an aquatic environment.
Product/ingredient name Result Species Exposure
Triethylenetetramine Acute LC50 33,900 g/l Fresh water Aquatic invertebrates, Water flea 48 hour
Acute EC50 3,700 g/l Fresh water Aquatic plants Green algae 96 hour
Persistence and Degradability: Benzyl Alcohol (CAS 100-51-6) – Biodegradability Biotic/Aerobic Result 92 to
96% – Readily Biodegradable.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
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Revision No.: 4
Revision Date:03/20/2020
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Product/ingredient name LogPow BCF Potential
Triethylenetetramine -1.66 to -1.4 Low
Fatty acids, C18-unsaturated,
dimers, reaction products with
polyethylenepolyamines
(CAS 68410-23-1)
492.00 Low
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Part B Hardener: The generation of waste should be avoided or minimized wherever possible. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and
non-recycle-able products via a licensed waste disposal contractor. Waste should not be disposed of untreated
to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken when handling emptied
containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers.
Section 14 TRANSPORT INFORMATION
CFR: Not Regulated
TDG: Not Regulated
DOT Classification: Not Regulated
IATA:
IMO:
Marine Pollutant: No
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
United States TSCA 12(b) Chemical export notification: None required.
United States TSCA 5(a)2 Final significant new use rules: Not listed.
United States TSCA 5(a)2 Proposed significant new use rules: Not listed.
United States TSCA 5(e) Substances consent order: Not listed.
SARA 311/312 Chemical: Yes
Classification Hazard Categories: Immediate (acute) health hazard
Acute Toxicity (any route of exposure)
Serious eye damage or eye irritation
SARA 313 (TRI reporting) Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPS) List: Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated.
Safe Drinking Water Act (SDWA): Not regulated.
State Regulations
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Revision No.: 4
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California Proposition 65: None required.
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: March 20, 2020
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: sales@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the
above-named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
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SAFETY DATA SHEET
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BD54125, BD5430, FLEX, LV, MV, HV, NS, BK Part A
RESIN
Revision No.: 4
Revision Date:03/20/2020
3
Section 1 IDENTIFICATION
Product Name: BD5402, BD5405, BD5410, BD54110, BD5420, BD54125, BD5430,
FLEX, LV, MV, HV, NS, BK Part A RESIN
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD5402, BD5405, BD5410, BD54110, BD520, BD54125, BD5430
FLEX, LV, MV, HV, NS, BK Part A RESIN
Materials Uses: Epoxy RESIN used with an Epoxy Hardener (Part B) to Bond Various Substrates.
In Case of Emergency Contact CHEMTREC: 800-424-9300; USA 703-527-3887
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Health
Skin Corrosion/Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause an allergic skin reaction
H335 May cause respiratory irritation
GHS Precaution Statements:
Prevention:
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
SDS
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P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only if
the person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept low so that the
stomach vomit doesn t enter the lungs.
Part A RESIN:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, C, D2B
Health 2
Flammability 1
1
Reactivity 0
PPE X
2
0
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name: Mixtures, Adhesives CAS # % by Weight
Bisphenol A Epoxy Resin 25068-38-6 80 100%
Non-hazardous Ingredients Not Applicable < 10%
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
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SDS Number:
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RESIN
Revision No.: 4
Revision Date:03/20/2020
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Respiratory: Loosen clothing as necessary and position individual in a comfortable position. Move exposed to
fresh air. Give artificial respiration if necessary. If breathing is difficult give oxygen. Immediately get medical
assistance.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, water spray, fog, dry chemical or CO2, or alcohol resistant foam.
Specific Hazards Arising from the Chemical: Fire may produce irritating, corrosive and/or toxic gases.
Hazardous Thermal: Decomposition products may include the following materials: Carbon dioxide, carbon
monoxide, halogenated compounds.
Special Protective Equipment and Precautions for Firefighters: Firefighters must use standard protective
equipment including flame retardant coat, helmet with face shield, gloves, and rubber boots. In enclosed
spaces, use self-contained breathing apparatus (SCBA) and protective clothing.
Flammability Classification: Combustible, Class IIIB estimated.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Autoignition Temp.: Not Available
LEL: Not Available
UEL: Not Available
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: Keep unnecessary personnel
away. Avoid contact with skin or inhalation of spillage, dust or vapor. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them.
Eliminate all sources of ignition. For large spill or leak wear self-contained breathing apparatus (SCBA) and
appropriate PPE.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Avoid releases to the environment. Retain and dispose of contaminated was water. Keep out of sewers and
drains. Contact local authorities if case of spillage to drain/aquatic environment.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Keep container closed. Handle containers with care. Open slowly in order to control
possible pressure release. Store in a cool, well ventilated area.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Bisphenol A Epoxy Resin (CAS: 25068-38-6) None
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Engineering Controls: Provide adequate ventilation (general or local exhaust). Ensure that a working
eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Part A RESIN
Appearance: Viscous Liquid
Color: Clear
Odor: Not Available
Odor Threshold: Not Available
pH: Not Available
Melting Point / Freezing Point: Not Available
Initial Boiling Point: 260
o
C (500
o
F)
Flash Point and Method: Pensky-Martens Closed Cup: 251
o
C (>484
o
F) (ASTM D 93)
Flammability: Not Available
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Vapor Pressure: .03 mm Hg @ 77
o
C (171
o
F)
Vapor Density: Not Available
Relative Density: 1.17 (9.7 lbs./gallon)
Solubility in Water: Negligible
Partition Coefficient (n-Octanol in Water): Not Available
Auto-Ignition Temperature: Not Available
Decomposition Temperature: Not Available
Viscosity (Dynamic CPS/mPa-s): 8,000 to 10,000 CPS
Percent Volatile: Not Available
Specific Gravity: 1.17
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable under normal conditions.
Chemical Stability: The product is stable.
Possibility of Hazardous Reactions: Under normal conditions of storage and use, hazardous reactions will not
occur.
Conditions to Avoid: Avoid exposure obtain special instructions before use. Avoid all possible sources of
ignition (spark or flame).
Materials to Avoid (Incompatibility): strong oxidizing materials, strong acids, strong alkalis.
Hazardous Decomposition Products: Under normal conditions of storage and use, hazardous decomposition
products should not be produced.
Other hazards: Reacts with considerable heat release with some curing agents.
SDS
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Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Bisphenol A Epoxy Resin (CAS: 25068-38-6) LD50 = 11,400 mg/kg (oral, rat)
LD50 = 2,000 mg/kg (dermal, rat)
Conclusion/Summary: Not Available
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Irritation/Corrosion:
Product/ingredient name Result Species Score Exposure Observation
Bisphenol A Epoxy Resin
(CAS: 25068-38-6)
Skin Erythema/Eschar 404 Acute
Dermal Irritation/Corrosion
Rabbit 1.5 2
Skin Edema 404 Acute
Dermal Irritation/Corrosion
Rabbit 1.0 1.5
Eyes 405 Acute Eye
Irritation/Corrosion
Rabbit 0
Eyes Redness of the Conjunctivae Rabbit 0.7
Skin Moderate Irritation Rabbit 24 hours
Skin Severe Irritant Rabbit 24 hours
Eyes Mild Irritant Rabbit
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Ingestion: Not Available.
Mutagenicity: Not Available.
Carcinogenicity: Not Available.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Not Available.
STOST- Single Exposure:
Product/ingredient name Category Route of Exposure Target Organ
Bisphenol A Epoxy Resin (CAS 26068-38-6) Category 3
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be toxic to aquatic organisms and may cause long term
adverse effects in an aquatic environment.
Product/ingredient name Result Species Exposure
Bisphenol A Epoxy Resin
(CAS 25068-38-6)
Acute LC50 1.3 mg/l – 203 Fish,
Acute Toxicity Test
Fish – Fish 96 hour
Acute EC50 2.1 mg/l – 202 Daphnia sp.
Acute Immobilization Test and Reproductive
Test
Aquatic invertebrates. Water Flea 48 hour
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BD54125, BD5430, FLEX, LV, MV, HV, NS, BK Part A
RESIN
Revision No.: 4
Revision Date:03/20/2020
3
Acute No-observable-effect-concentration
0.3 mg/l 211 Daphnia Magna
Reproduction Test
Aquatic invertebrates. Water Flea 21 day
Acute LC50 > 11 mg/l Aquatic plants – Algae 72 hour
Persistence and Degradability: Not Available.
Bioaccumulative Potential:
Product/ingredient name LogPow BCF Potential
Bisphenol A Epoxy Resin
(CAS 26068-38-6)
2.64 3.78 3 31 31.00 Low
Mobility in Soil: Not Available.
Other Adverse Effects: No known significant effects or critical hazards.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Part A RESIN: The generation of waste should be avoided or minimized wherever possible. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and
non-recycle-able products via a licensed waste disposal contractor. Waste should not be disposed of untreated
to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken when handling emptied
containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers.
Section 14 TRANSPORT INFORMATION
CFR: Not Regulated
TDG: Not Regulated
DOT Classification: Not Regulated
IATA:
IMO:
Marine Pollutant: YES
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
United States TSCA 12(b) Chemical export notification: None required.
United States TSCA 5(a)2 Final significant new use rules: Not listed.
United States TSCA 5(a)2 Proposed significant new use rules: Not listed.
United States TSCA 5(e) Substances consent order: Not listed.
SARA 311/312 Chemical: Yes
Classification Hazard Categories: Immediate (acute) health hazard
SDS
SAFETY DATA SHEET
SDS Number:
Page 7 of 7
BD5402, BD5405, BD5410, BD54110, BD5420,
BD54125, BD5430, FLEX, LV, MV, HV, NS, BK Part A
RESIN
Revision No.: 4
Revision Date:03/20/2020
3
SARA 313 (TRI reporting) Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPS) List: Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated.
Safe Drinking Water Act (SDWA): Not regulated.
State Regulations
California Proposition 65: WARNING: This product contains less than 0.1% of a chemical known to the
State of California to cause cancer. WARNING: This product contains less than
1% of a chemical known to the State of California to cause birth defects or other
reproductive harm.
Ingredient Name Cancer Reproductive No significant risk level Maximum acceptable dosage
level
Oxirane, 2-(phenoxymethyl)- Yes No 5 g/day No
Phenol, 4,4 -(1-methylethylidene)bis- No Yes No No
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: March 20, 2020
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: sales@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the
above-named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
23BD5301200B_SDS.pdf
SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
Section 1 IDENTIFICATION
Product Name: BD310, BD530, BD560, BD590 Acrylic Structural Bonding Adhesive Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD310, BD530, BD560, BD590 Acrylic Structural Bonding Adhesive
Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
DANGER
H225 Highly flammable liquid and vapor
Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2B
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H316 Causes skin irritation
H320 Causes eye irritation
H317 May cause an allergic skin reaction
H335 May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
SDS
SAFETY DATA SHEET
SDS Number:
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P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
SDS
SAFETY DATA SHEET
SDS Number:
Page 3 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Maleic Acid Powder 110-16-7 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
SDS
SAFETY DATA SHEET
SDS Number:
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Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
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Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Maleic Acid Powder (CAS 110-16-7): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point and Boiling Range: 212
o
F (100
o
C) 212
o
F (100
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPA-s): 40k to 120k 60k to 150k
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05
VOC: < 50 g/L of mixed product < 50 g/L of mixed product
SDS
SAFETY DATA SHEET
SDS Number:
Page 5 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive - Cartridges
Revision No.: 4
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3
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Maleic Acid Powder (CAS 110-16-7): LC50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment. Do not empty into drains.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
SDS
SAFETY DATA SHEET
SDS Number:
Page 6 of 7
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Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
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3
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of in landfill or by
incineration. Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: II.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Maleic Acid Powder (CAS 110-16-7)
All quantities are in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Maleic Acid Powder (CAS 110-16-7) X X X
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
SDS
SAFETY DATA SHEET
SDS Number:
Page 7 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
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3
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: July 9, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
23BD42050_SDS.pdf
SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Section 1 IDENTIFICATION
Product Name: BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550 FX Structural Acrylic
Bonding Adhesive – Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD 440FX, BD550FX
Structural Acrylic Bonding Adhesives
Materials Uses: High strength acrylic adhesive for bonding fiberglass, steel, aluminum, and various
substrates together. 10:1 product has high flexural strength and tensile strengths.
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA) +1-703-527-3887
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
Organic Peroxides, Type F
DANGER
WARNING
H225 Highly flammable liquid and vapor
H242 Heating may cause a fire
Health
Acute Oral Toxicity, Category 4
Skin Corrosion, Category 1
Serious Eye Damage, Category 1
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause an allergic skin reaction
H335 – May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closes.
SDS
SAFETY DATA SHEET
SDS Number:
Page 2 of 8
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Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
P240 Ground/Bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P301/P330/P331 IF SWALLOWED: Rinse mouth. Do not induce vomiting.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P303/P361/P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304/P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you fell unwell.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
P362/P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish small fires. Use water for large fires.
Storage:
P403 Store in a well-ventilated place.
P405 Store locked up.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
SDS
SAFETY DATA SHEET
SDS Number:
Page 3 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 3
Flammability 3
3
Reactivity 2
PPE B
3
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 80
Methacrylic Acid 79-41-4 1 10
Activator: Benzoyl Peroxide 94-36-0 5 30
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
SDS
SAFETY DATA SHEET
SDS Number:
Page 4 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Benzoyl Peroxide (CAS 94-36-0): OSHA PEL: TWA 5 mg/m
3
ACGIH TLV: TWA 5 mg/m
3
Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
SDS
SAFETY DATA SHEET
SDS Number:
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3
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) paste
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) Not Available
Initial Boiling Point: 212
o
F (100
o
C) > 550
o
F (288
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup Not Available
Evaporation Rate: 3 <1 (butyl acetate = 1)
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% Not Available
Upper Explosion Limit: 12.5% Not Available
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) < 0.5 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 Not Available
Relative Density: 7.7 8.8 lbs./gallon Not Available
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) Not Available
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPa-s): 60k 250k 40k to 120k
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 1.0 to 1.15
VOC: < 50 g/L of mixed product Not Available
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
SDS
SAFETY DATA SHEET
SDS Number:
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Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Benzoyl Peroxide (CAS 94-36-0): LC50 = 2 mg/L (96 hour inhalation, guppy)
LD50 = 6400 mg/kg (oral, rat)
LD50 > 2000 mg/kg (oral, mouse)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
SDS
SAFETY DATA SHEET
SDS Number:
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3
Transport Hazard Class: 3.
Packing Group: II
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Benzoyl Peroxide (CAS 94-36-0) 1.0
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Benzoyl Peroxide (CAS 94-36-0) X X X X
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: August 21, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
SDS
SAFETY DATA SHEET
SDS Number:
Page 8 of 8
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Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
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3
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
23BD420490_SDS.pdf
SDS
SAFETY DATA SHEET
SDS Number:
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3
Section 1 IDENTIFICATION
Product Name: BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550 FX Structural Acrylic
Bonding Adhesive – Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD 440FX, BD550FX
Structural Acrylic Bonding Adhesives
Materials Uses: High strength acrylic adhesive for bonding fiberglass, steel, aluminum, and various
substrates together. 10:1 product has high flexural strength and tensile strengths.
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA) +1-703-527-3887
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
Organic Peroxides, Type F
DANGER
WARNING
H225 Highly flammable liquid and vapor
H242 Heating may cause a fire
Health
Acute Oral Toxicity, Category 4
Skin Corrosion, Category 1
Serious Eye Damage, Category 1
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause an allergic skin reaction
H335 – May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closes.
SDS
SAFETY DATA SHEET
SDS Number:
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P240 Ground/Bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P301/P330/P331 IF SWALLOWED: Rinse mouth. Do not induce vomiting.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P303/P361/P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304/P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you fell unwell.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
P362/P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish small fires. Use water for large fires.
Storage:
P403 Store in a well-ventilated place.
P405 Store locked up.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
SDS
SAFETY DATA SHEET
SDS Number:
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ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 3
Flammability 3
3
Reactivity 2
PPE B
3
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 80
Methacrylic Acid 79-41-4 1 10
Activator: Benzoyl Peroxide 94-36-0 5 30
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
SDS
SAFETY DATA SHEET
SDS Number:
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Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Benzoyl Peroxide (CAS 94-36-0): OSHA PEL: TWA 5 mg/m
3
ACGIH TLV: TWA 5 mg/m
3
Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
SDS
SAFETY DATA SHEET
SDS Number:
Page 5 of 8
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3
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) paste
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) Not Available
Initial Boiling Point: 212
o
F (100
o
C) > 550
o
F (288
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup Not Available
Evaporation Rate: 3 <1 (butyl acetate = 1)
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% Not Available
Upper Explosion Limit: 12.5% Not Available
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) < 0.5 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 Not Available
Relative Density: 7.7 8.8 lbs./gallon Not Available
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) Not Available
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPa-s): 60k 250k 40k to 120k
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 1.0 to 1.15
VOC: < 50 g/L of mixed product Not Available
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
SDS
SAFETY DATA SHEET
SDS Number:
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Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Benzoyl Peroxide (CAS 94-36-0): LC50 = 2 mg/L (96 hour inhalation, guppy)
LD50 = 6400 mg/kg (oral, rat)
LD50 > 2000 mg/kg (oral, mouse)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
SDS
SAFETY DATA SHEET
SDS Number:
Page 7 of 8
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Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Transport Hazard Class: 3.
Packing Group: II
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Benzoyl Peroxide (CAS 94-36-0) 1.0
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Benzoyl Peroxide (CAS 94-36-0) X X X X
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: August 21, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
SDS
SAFETY DATA SHEET
SDS Number:
Page 8 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
23BD350400_SDS.pdf
SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 7
BD310/BD350/BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 1
Date:10/01/2017
3
Section 1 IDENTIFICATION
Product Name: BD310/BD350/BD590 Acrylic Structural Bonding Adhesive Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 Fax: 1-833-244-3649
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD310/BD350/BD590 Acrylic Structural Bonding Adhesive
Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
DANGER
H225 Highly flammable liquid and vapor
Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 3
Eye Irritation, Category 2B
Skin Sensitization, Category 1
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H316 Causes mild skin irritation
H320 Causes eye irritation
H317 May cause an allergic skin reaction
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
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P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
SDS
SAFETY DATA SHEET
SDS Number:
Page 3 of 7
BD310/BD350/BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 1
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Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Maleic Acid Powder 110-16-7 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
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BD310/BD350/BD590
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Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Maleic Acid Powder (CAS 110-16-7): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point and Boiling Range: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity: Not Available Not Available
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05
VOC: < 50 g/L of mixed product < 50 g/L of mixed product
SDS
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SDS Number:
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BD310/BD350/BD590
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Revision No.: 1
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Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Maleic Acid Powder (CAS 110-16-7): LC50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment. Do not empty into drains.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
SDS
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BD310/BD350/BD590
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Revision No.: 1
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Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of in landfill or by
incineration. Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: III.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group III, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Maleic Acid Powder (CAS 110-16-7)
All quantities are in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Maleic Acid Powder (CAS 110-16-7) X X X
International Regulations
DSL (Canada): Components of this product are listed. Methyl Methacrylate (CAS 80-62-6); Maleic Acid
Powder (CAS 110-16-7)
EINECS: Methyl Methacrylate Monomer (201-291-1); Maleic Acid Powder (203-742-5).
WHMIS: B2, C, D2B.
SDS
SAFETY DATA SHEET
SDS Number:
Page 7 of 7
BD310/BD350/BD590
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Revision No.: 1
Date:10/01/2017
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Section 16 OTHER INFORMATION
Changes to This Revision: October 1, 2017
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
23BD330400B_SDS.pdf
23BD320490_SDS.pdf
SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Section 1 IDENTIFICATION
Product Name: BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550 FX Structural Acrylic
Bonding Adhesive – Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD 440FX, BD550FX
Structural Acrylic Bonding Adhesives
Materials Uses: High strength acrylic adhesive for bonding fiberglass, steel, aluminum, and various
substrates together. 10:1 product has high flexural strength and tensile strengths.
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA) +1-703-527-3887
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
Organic Peroxides, Type F
DANGER
WARNING
H225 Highly flammable liquid and vapor
H242 Heating may cause a fire
Health
Acute Oral Toxicity, Category 4
Skin Corrosion, Category 1
Serious Eye Damage, Category 1
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause an allergic skin reaction
H335 – May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closes.
SDS
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BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
P240 Ground/Bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P301/P330/P331 IF SWALLOWED: Rinse mouth. Do not induce vomiting.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P303/P361/P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304/P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you fell unwell.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
P362/P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish small fires. Use water for large fires.
Storage:
P403 Store in a well-ventilated place.
P405 Store locked up.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
SDS
SAFETY DATA SHEET
SDS Number:
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BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 3
Flammability 3
3
Reactivity 2
PPE B
3
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 80
Methacrylic Acid 79-41-4 1 10
Activator: Benzoyl Peroxide 94-36-0 5 30
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
SDS
SAFETY DATA SHEET
SDS Number:
Page 4 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Benzoyl Peroxide (CAS 94-36-0): OSHA PEL: TWA 5 mg/m
3
ACGIH TLV: TWA 5 mg/m
3
Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
SDS
SAFETY DATA SHEET
SDS Number:
Page 5 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) paste
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) Not Available
Initial Boiling Point: 212
o
F (100
o
C) > 550
o
F (288
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup Not Available
Evaporation Rate: 3 <1 (butyl acetate = 1)
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% Not Available
Upper Explosion Limit: 12.5% Not Available
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) < 0.5 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 Not Available
Relative Density: 7.7 8.8 lbs./gallon Not Available
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) Not Available
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPa-s): 60k 250k 40k to 120k
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 1.0 to 1.15
VOC: < 50 g/L of mixed product Not Available
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
SDS
SAFETY DATA SHEET
SDS Number:
Page 6 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Benzoyl Peroxide (CAS 94-36-0): LC50 = 2 mg/L (96 hour inhalation, guppy)
LD50 = 6400 mg/kg (oral, rat)
LD50 > 2000 mg/kg (oral, mouse)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
SDS
SAFETY DATA SHEET
SDS Number:
Page 7 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Transport Hazard Class: 3.
Packing Group: II
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Benzoyl Peroxide (CAS 94-36-0) 1.0
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Benzoyl Peroxide (CAS 94-36-0) X X X X
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: August 21, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
SDS
SAFETY DATA SHEET
SDS Number:
Page 8 of 8
BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
23BD31050_SDS.pdf
SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 7
BD310/BD350/BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 1
Date:10/01/2017
3
Section 1 IDENTIFICATION
Product Name: BD310/BD350/BD590 Acrylic Structural Bonding Adhesive Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 Fax: 1-833-244-3649
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD310/BD350/BD590 Acrylic Structural Bonding Adhesive
Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
DANGER
H225 Highly flammable liquid and vapor
Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 3
Eye Irritation, Category 2B
Skin Sensitization, Category 1
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H316 Causes mild skin irritation
H320 Causes eye irritation
H317 May cause an allergic skin reaction
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
SDS
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P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
SDS
SAFETY DATA SHEET
SDS Number:
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Revision No.: 1
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Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Maleic Acid Powder 110-16-7 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
SDS
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Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Maleic Acid Powder (CAS 110-16-7): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point and Boiling Range: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity: Not Available Not Available
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05
VOC: < 50 g/L of mixed product < 50 g/L of mixed product
SDS
SAFETY DATA SHEET
SDS Number:
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Revision No.: 1
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Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Maleic Acid Powder (CAS 110-16-7): LC50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment. Do not empty into drains.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
SDS
SAFETY DATA SHEET
SDS Number:
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Revision No.: 1
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3
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of in landfill or by
incineration. Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: III.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group III, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Maleic Acid Powder (CAS 110-16-7)
All quantities are in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Maleic Acid Powder (CAS 110-16-7) X X X
International Regulations
DSL (Canada): Components of this product are listed. Methyl Methacrylate (CAS 80-62-6); Maleic Acid
Powder (CAS 110-16-7)
EINECS: Methyl Methacrylate Monomer (201-291-1); Maleic Acid Powder (203-742-5).
WHMIS: B2, C, D2B.
SDS
SAFETY DATA SHEET
SDS Number:
Page 7 of 7
BD310/BD350/BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 1
Date:10/01/2017
3
Section 16 OTHER INFORMATION
Changes to This Revision: October 1, 2017
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
23BD310400_SDS.pdf
SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 7
BD310/BD350/BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 1
Date:10/01/2017
3
Section 1 IDENTIFICATION
Product Name: BD310/BD350/BD590 Acrylic Structural Bonding Adhesive Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 Fax: 1-833-244-3649
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD310/BD350/BD590 Acrylic Structural Bonding Adhesive
Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
DANGER
H225 Highly flammable liquid and vapor
Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 3
Eye Irritation, Category 2B
Skin Sensitization, Category 1
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H316 Causes mild skin irritation
H320 Causes eye irritation
H317 May cause an allergic skin reaction
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
SDS
SAFETY DATA SHEET
SDS Number:
Page 2 of 7
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Revision No.: 1
Date:10/01/2017
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P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
SDS
SAFETY DATA SHEET
SDS Number:
Page 3 of 7
BD310/BD350/BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 1
Date:10/01/2017
3
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Maleic Acid Powder 110-16-7 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
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Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Maleic Acid Powder (CAS 110-16-7): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point and Boiling Range: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity: Not Available Not Available
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05
VOC: < 50 g/L of mixed product < 50 g/L of mixed product
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Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Maleic Acid Powder (CAS 110-16-7): LC50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment. Do not empty into drains.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
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Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of in landfill or by
incineration. Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: III.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group III, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Maleic Acid Powder (CAS 110-16-7)
All quantities are in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Maleic Acid Powder (CAS 110-16-7) X X X
International Regulations
DSL (Canada): Components of this product are listed. Methyl Methacrylate (CAS 80-62-6); Maleic Acid
Powder (CAS 110-16-7)
EINECS: Methyl Methacrylate Monomer (201-291-1); Maleic Acid Powder (203-742-5).
WHMIS: B2, C, D2B.
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Section 16 OTHER INFORMATION
Changes to This Revision: October 1, 2017
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT