23BD3101200_SDS.pdf

SDS
SAFETY DATA SHEET

SDS Number:
Page 1 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
Section 1 IDENTIFICATION
Product Name: BD310, BD530, BD560, BD590 Acrylic Structural Bonding Adhesive Cartridges

Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD310, BD530, BD560, BD590 Acrylic Structural Bonding Adhesive

Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)

Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2

DANGER

H225 Highly flammable liquid and vapor

Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2B
Skin Sensitization, Category 1
STOT SE, Category 3

WARNING
WARNING
WARNING
WARNING
WARNING

H302 Harmful if swallowed
H316 Causes skin irritation
H320 Causes eye irritation
H317 May cause an allergic skin reaction
H335 May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4

H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life

GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.

SDS
SAFETY DATA SHEET

SDS Number:
Page 2 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.

ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

SDS
SAFETY DATA SHEET

SDS Number:
Page 3 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Maleic Acid Powder 110-16-7 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%

Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.

Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.

Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.

Section 7 HANDLING AND STORAGE

SDS
SAFETY DATA SHEET

SDS Number:
Page 4 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.

Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Maleic Acid Powder (CAS 110-16-7): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.

Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point and Boiling Range: 212
o
F (100
o
C) 212
o
F (100
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPA-s): 40k to 120k 60k to 150k
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05
VOC: < 50 g/L of mixed product < 50 g/L of mixed product SDS SAFETY DATA SHEET SDS Number: Page 5 of 7 BD310, BD530, BD560, BD590 Acrylic Structural Bonding Adhesive - Cartridges Revision No.: 4 Date:07/26/2018 3 Section 10 STABILITY AND REACTIVITY Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under certain conditions or in contact with incompatible materials. Chemical Stability: Not Available. Possibility of Hazardous Reactions: Polymerization may occur under certain conditions. Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight. Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free atmospheres, inert gas blanketing, and free radical initiators. Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various Hydrocarbons. Section 11 TOXICOLOGICAL INFORMATION Acute Toxicity to Animals: Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat) LD50 = 7940 mg/kg (oral, rat) LD50 > 7550 mg/kg (dermal, rabbit)
Maleic Acid Powder (CAS 110-16-7): LC50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)

Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.

Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment. Do not empty into drains.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.

SDS
SAFETY DATA SHEET

SDS Number:
Page 6 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.

Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of in landfill or by
incineration. Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.

Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: II.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.

Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Maleic Acid Powder (CAS 110-16-7)
All quantities are in pounds.

State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Maleic Acid Powder (CAS 110-16-7) X X X

TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.

SDS
SAFETY DATA SHEET

SDS Number:
Page 7 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.

Section 16 OTHER INFORMATION
Changes to This Revision: July 9, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT

23BD30550_SDS.pdf

SDS
SAFETY DATA SHEET

SDS Number:
Page 1 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
Section 1 IDENTIFICATION
Product Name: BD305 Acrylic Structural Bonding Adhesive Cartridges

Manufacturer: Big Dog Adhesives, LLC
435 Harrison Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com

Trade Name: Big Dog Acrylic Structural Bonding Adhesive BD305 Cartridges

Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel.
In Case of Emergency Contact CHEMTREC: 800-424-9300 or 703-527-3887

Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2

DANGER

H225 Highly flammable liquid and vapor

Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
STOT SE, Category 3

WARNING
WARNING
WARNING
WARNING
WARNING

H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause an allergic skin reaction
H335 May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4

H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life

GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.

SDS
SAFETY DATA SHEET

SDS Number:
Page 2 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.

ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

SDS
SAFETY DATA SHEET

SDS Number:
Page 3 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Methacrylic Acid 79-41-4 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%

Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.

Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.

Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.

Section 7 HANDLING AND STORAGE

SDS
SAFETY DATA SHEET

SDS Number:
Page 4 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.

Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.

Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point: 212
o
F (100
o
C) 212
o
F (100
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPa-s): 20K 200K 20K 200K
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05

SDS
SAFETY DATA SHEET

SDS Number:
Page 5 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
VOC: < 50 g/L of mixed product < 50 g/L of mixed product Section 10 STABILITY AND REACTIVITY Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under certain conditions or in contact with incompatible materials. Chemical Stability: Not Available. Possibility of Hazardous Reactions: Polymerization may occur under certain conditions. Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight. Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free atmospheres, inert gas blanketing, and free radical initiators. Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various Hydrocarbons. Section 11 TOXICOLOGICAL INFORMATION Acute Toxicity to Animals: Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat) LD50 = 7940 mg/kg (oral, rat) LD50 > 7550 mg/kg (dermal, rabbit)
Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)

Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.

Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.

SDS
SAFETY DATA SHEET

SDS Number:
Page 6 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.

Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.

Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: II.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.

Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.

State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X

TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.

SDS
SAFETY DATA SHEET

SDS Number:
Page 7 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.

Section 16 OTHER INFORMATION
Changes to This Revision: January 4, 2022
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: sales@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT

23BD305400B_SDS.pdf

SDS
SAFETY DATA SHEET

SDS Number:
Page 1 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
Section 1 IDENTIFICATION
Product Name: BD305 Acrylic Structural Bonding Adhesive Cartridges

Manufacturer: Big Dog Adhesives, LLC
435 Harrison Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com

Trade Name: Big Dog Acrylic Structural Bonding Adhesive BD305 Cartridges

Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel.
In Case of Emergency Contact CHEMTREC: 800-424-9300 or 703-527-3887

Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2

DANGER

H225 Highly flammable liquid and vapor

Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
STOT SE, Category 3

WARNING
WARNING
WARNING
WARNING
WARNING

H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause an allergic skin reaction
H335 May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4

H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life

GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.

SDS
SAFETY DATA SHEET

SDS Number:
Page 2 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.

ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

SDS
SAFETY DATA SHEET

SDS Number:
Page 3 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Methacrylic Acid 79-41-4 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%

Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.

Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.

Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.

Section 7 HANDLING AND STORAGE

SDS
SAFETY DATA SHEET

SDS Number:
Page 4 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.

Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.

Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point: 212
o
F (100
o
C) 212
o
F (100
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPa-s): 20K 200K 20K 200K
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05

SDS
SAFETY DATA SHEET

SDS Number:
Page 5 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
VOC: < 50 g/L of mixed product < 50 g/L of mixed product Section 10 STABILITY AND REACTIVITY Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under certain conditions or in contact with incompatible materials. Chemical Stability: Not Available. Possibility of Hazardous Reactions: Polymerization may occur under certain conditions. Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight. Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free atmospheres, inert gas blanketing, and free radical initiators. Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various Hydrocarbons. Section 11 TOXICOLOGICAL INFORMATION Acute Toxicity to Animals: Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat) LD50 = 7940 mg/kg (oral, rat) LD50 > 7550 mg/kg (dermal, rabbit)
Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)

Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.

Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.

SDS
SAFETY DATA SHEET

SDS Number:
Page 6 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.

Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.

Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: II.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.

Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.

State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X

TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.

SDS
SAFETY DATA SHEET

SDS Number:
Page 7 of 7
BD305 Acrylic Structural Bonding Adhesive –
Cartridges
Revision No.: 5
Revision Date:01/04/2022
3
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.

Section 16 OTHER INFORMATION
Changes to This Revision: January 4, 2022
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: sales@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT

23BD30050_SDS.pdf

SDS
SAFETY DATA SHEET

SDS Number:
Page 1 of 7
BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3
Section 1 IDENTIFICATION
Product Name: BD300/BD305/BD315/BD330 Acrylic Structural Bonding Adhesive Cartridges

Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: lou@bigdogadhesives.com Website: www.bigdogadhesives.com

Trade Name: Big Dog Acrylic Structural Bonding Adhesive BD300/BD305/BD315/BD330

Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel.
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)

Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2

DANGER

H225 Highly flammable liquid and vapor

Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
STOT SE, Category 3

WARNING
WARNING
WARNING
WARNING
WARNING

H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause an allergic skin reaction
H335 May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4

H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life

GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.

SDS
SAFETY DATA SHEET

SDS Number:
Page 2 of 7
BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3
P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.

ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2

Flammability 3

3

Reactivity 2

PPE B

2

2

SDS
SAFETY DATA SHEET

SDS Number:
Page 3 of 7
BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3

Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Methacrylic Acid 79-41-4 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%

Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.

Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.

Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.

Section 7 HANDLING AND STORAGE

SDS
SAFETY DATA SHEET

SDS Number:
Page 4 of 7
BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.

Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.

Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point: 212
o
F (100
o
C) 212
o
F (100
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPa-s): 20K 200K 20K 200K
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05

SDS
SAFETY DATA SHEET

SDS Number:
Page 5 of 7
BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3
VOC: < 50 g/L of mixed product < 50 g/L of mixed product Section 10 STABILITY AND REACTIVITY Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under certain conditions or in contact with incompatible materials. Chemical Stability: Not Available. Possibility of Hazardous Reactions: Polymerization may occur under certain conditions. Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight. Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free atmospheres, inert gas blanketing, and free radical initiators. Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various Hydrocarbons. Section 11 TOXICOLOGICAL INFORMATION Acute Toxicity to Animals: Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat) LD50 = 7940 mg/kg (oral, rat) LD50 > 7550 mg/kg (dermal, rabbit)
Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)

Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.

Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.

SDS
SAFETY DATA SHEET

SDS Number:
Page 6 of 7
BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.

Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.

Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: II.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.

Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.

State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X

TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.

SDS
SAFETY DATA SHEET

SDS Number:
Page 7 of 7
BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.

Section 16 OTHER INFORMATION
Changes to This Revision: July 9, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT

23BD2400_SDS.pdf

Page 1/9
Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
60.0.5
1 Identification
Product identifier
Trade name: BDRP Series Instant Adhesive
CAS Number:
7085-85-0
Other means of identification
EC number:
230-391-5
Index number:
607-236-00-9
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Big Dog Adhesives LLC
435 Harrison Street
ELKHART, IN 46516
USA
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (520) 271-7313
24 Hours: CHEMTREC 1-800-424-9300
2 Hazard(s) identification
Classification of the substance or mixture

GHS07
Skin irritation 2 H315 Causes skin irritation.
Eye irritation 2A H319 Causes serious eye irritation.
Specific target organ toxicity (single exposure) 3 H335 May cause respiratory irritation.
Label elements
GHS label elementsThe substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms

GHS07
Signal wordWarning
Hazard-determining components of labeling:
ethyl 2-cyanoacrylate
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
(Contd. on page 2)
US

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Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
Trade name: BDRP Series Instant Adhesive
(Contd. of page 1)
60.0.5
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves / eye protection / face protection.
If on skin: Wash with plenty of water.
If inhaled: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
Specific treatment (see on this label).
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Information pertaining to particular dangers for man and environment:
Classification system:
NFPA ratings (scale 0 – 4)
2
2
0
Health = 2
Fire = 2
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
2
0
Health = 2
Fire = 2
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Classification according to (d)(1)(ii) of 1910.12000
The SDS issuer does not object to the classifications provided by importers or manufacturers of precursor
products.
Hazards not otherwise classified
There are no adverse physical or health effects known that are not covered by the hazard classes of the Hazard
Communications Standard.
3 Composition/information on ingredients
Chemical characterization: Substances
CAS No. Description
7085-85-0 ethyl 2-cyanoacrylate
Identification number(s)
EC number:230-391-5
Index number:607-236-00-9
US
(Contd. on page 3)

Page 3/9
Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
Trade name: BDRP Series Instant Adhesive
(Contd. of page 2)
60.0.5
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:No special measures required.
6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
Protective Action Criteria for Chemicals
PAC-1:
Substance is not listed.
PAC-2:
Substance is not listed.
PAC-3:
Substance is not listed.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
(Contd. on page 4)
US

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Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
Trade name: BDRP Series Instant Adhesive
(Contd. of page 3)
60.0.5
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Control parameters
Components with limit values that require monitoring at the workplace:
7085-85-0 ethyl 2-cyanoacrylate
TLV Short-term value: 1 ppm
Long-term value: 0.2 ppm
DSEN, RSEN
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Appropriate engineering controlsNo further data; see section 7.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:

Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Safety glasses
(Contd. on page 5)
US

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Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
Trade name: BDRP Series Instant Adhesive
(Contd. of page 4)
60.0.5

Tightly sealed goggles
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Physical state Fluid
Color: Not determined.
Odor: Characteristic
Odor threshold: Not determined.
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 60 C (140 F)
Flammability: Not applicable.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Flash point: Not applicable.
Decomposition temperature: Not determined.
pH-value: Not determined.
Viscosity:
Kinematic: Not determined.
Dynamic: Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Vapor pressure: Not determined.
Vapor pressure:
Density at 20 C (68 F): 1.06 g/cm (8.8457 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Particle characteristics Not applicable.
Other information
Appearance:
Form: Fluid
Important information on protection of health and
environment, and on safety.
Ignition temperature: Not determined.
Danger of explosion: Product does not present an explosion hazard.
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 0-20 %
Change in condition
Evaporation rate Not determined.
10 Stability and reactivity
ReactivityNo further relevant information available.
(Contd. on page 6)
US

Page 6/9
Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
Trade name: BDRP Series Instant Adhesive
(Contd. of page 5)
60.0.5
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:No dangerous decomposition products known.
11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
Interactive effectsNo interactive effects between components are known.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.
Alternative sources for toxicological information
No non-standard sources for toxicological information where used.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effects
Additional ecological information:
General notes:
Water hazard class 1 (Assessment by list): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 7)
US

Page 7/9
Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
Trade name: BDRP Series Instant Adhesive
(Contd. of page 6)
60.0.5
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, IMDG, IATA not regulated
UN proper shipping name
DOT, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards: Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Special precautions for user Not applicable.
UN “Model Regulation”: not regulated
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
Sara
Section 355 (extremely hazardous substances):
Substance is not listed.
Section 313 (Specific toxic chemical listings):
Substance is not listed.
TSCA (Toxic Substances Control Act):
ACTIVE
Hazardous Air Pollutants
Substance is not listed.
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
Chemicals known to cause developmental toxicity:
Substance is not listed.
(Contd. on page 8)
US

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Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
Trade name: BDRP Series Instant Adhesive
(Contd. of page 7)
60.0.5
Carcinogenic categories
EPA (Environmental Protection Agency)
Substance is not listed.
TLV (Threshold Limit Value)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
GHS label elementsThe substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms

GHS07
Signal wordWarning
Hazard-determining components of labeling:
ethyl 2-cyanoacrylate
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves / eye protection / face protection.
If on skin: Wash with plenty of water.
If inhaled: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
Specific treatment (see on this label).
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Department issuing SDS:Environment protection department.
Contact:-
Date of preparation01/10/2025
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
(Contd. on page 9)
US

Page 9/9
Safety Data Sheet
acc. to OSHA HCS
Date of issue: 01/10/2025 Reviewed on 01/10/2025
Trade name: BDRP Series Instant Adhesive
(Contd. of page 8)
60.0.5
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin irritation 2: Skin corrosion/irritation Category 2
Eye irritation 2A: Serious eye damage/eye irritation Category 2A
Specific target organ toxicity (single exposure) 3: Specific target organ toxicity (single exposure) Category 3
US

23BB70R_SDS.pdf

Core-Bond B70 R
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Core-Bond B70 R
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H351 – Suspected of causing cancer.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 1/14

Core-Bond B70 R
Section 2. Hazards identification
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P362+P364 – IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse.
P332 + P313 – If skin irritation occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 32.186 100-42-5
dimethyl glutarate <1.0123 1119-40-0 N,N-dimethylaniline 0.268 121-69-7 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification :Not available. CAS number :Not applicable. Substance/mixture Product code :CC070E00 CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 2/14 Core-Bond B70 R Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 3/14 Core-Bond B70 R Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 4/14 Core-Bond B70 R Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling styrene ACGIH TLV (United States, 3/2016). TWA: 20 ppm 8 hours. TWA: 85 mg/m 8 hours. STEL: 40 ppm 15 minutes. STEL: 170 mg/m 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 50 ppm 8 hours. TWA: 215 mg/m 8 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2016). TWA: 50 ppm 10 hours. TWA: 215 mg/m 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. N,N-dimethylaniline ACGIH TLV (United States, 3/2016). Absorbed through skin. TWA: 5 ppm 8 hours. TWA: 25 mg/m 8 hours. STEL: 10 ppm 15 minutes. STEL: 50 mg/m 15 minutes. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 5 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 5/14 Core-Bond B70 R Section 8. Exposure controls/personal protection TWA: 25 mg/m 8 hours. STEL: 10 ppm 15 minutes. STEL: 50 mg/m 15 minutes. NIOSH REL (United States, 10/2016). Absorbed through skin. TWA: 5 ppm 10 hours. TWA: 25 mg/m 10 hours. STEL: 10 ppm 15 minutes. STEL: 50 mg/m 15 minutes. OSHA PEL (United States, 6/2016). Absorbed through skin. TWA: 5 ppm 8 hours. TWA: 25 mg/m 8 hours. Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 6/14 Core-Bond B70 R Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Paste.] Not available. 0.65 to 0.75 Not available. Not available. Not available. SolventOdor pH White.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: 31 C (87.8 F) Not available. Not available. Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 7/14

Core-Bond B70 R
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
dimethyl glutarate LD50 Dermal Rabbit >5000 mg/kg –
LD50 Oral Rat >5000 mg/kg –
N,N-dimethylaniline LC50 Inhalation Vapor Rat >5.1 mg/l 4 hours
LD50 Dermal Rabbit 1700 mg/kg –
LD50 Oral Rat 1120 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million

Eyes – Moderate irritantRabbit – 24 hours 100
milligrams

Eyes – Severe irritantRabbit – 100
milligrams

Skin – Mild irritant Rabbit – 500
milligrams

Skin – Moderate irritantRabbit – 100 Percent-
dimethyl glutarate Eyes – Moderate irritantRabbit – 0.1 Mililiters-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Route of
exposure
Target organs
Route of
exposure
Target organs
Information on toxicological effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
N,N-dimethylaniline – 3 –
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 8/14

Core-Bond B70 R
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Acute toxicity estimates
Name Result
styrene ASPIRATION HAZARD – Category 1
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 9/14

Core-Bond B70 R
Section 11. Toxicological information
Oral 7287.1 mg/kg
Inhalation (gases) 7164.6 ppm
Inhalation (vapors) 30.52 mg/l
Route ATE value
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
dimethyl glutarate 0.49 – low
N,N-dimethylaniline 1.171 16 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
N,N-dimethylaniline Acute EC50 5 mg/l Daphnia – Daphnia magna 48 hours
Acute IC50 340 mg/l Algae – Desmodesmus
subspicatus
96 hours
Acute LC50 65.6 mg/l Fish – Pimephales promelas 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 10/14

Core-Bond B70 R
Section 14. Transport information
Resin solution
3
III
RESIN
SOLUTION
3
III
Resin solution
UN1866
3
III
UN1866 UN1866
Reportable
quantity 3106.
9 lbs / 1410.6
kg [532.33 gal /
2015.1 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
ADR/RID
UN1866
RESIN
SOLUTION
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
3
III
No.
Special
provisions 223
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 11/14

Core-Bond B70 R
Section 14. Transport information
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
:Not available.
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: FIBROUS GLASS; STYRENE;
PHENYLETHYLENE
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 32.186
styrene 100-42-5 32.186
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
State regulations
TSCA 8(a) PAIR: N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :24437927663.7 lbs / 11094819159.3 kg [4187058777 gal / 15849741656.2 L]
aniline 0.
00000372 –
0.0000372
Yes.1000 117.6 5000 587.9
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 32.186 Yes. No. No. Yes. Yes.
dimethyl glutarate <1.0123 No. No. No. Yes. No. N,N-dimethylaniline 0.268 Yes. No. No. Yes. Yes. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 12/14 Core-Bond B70 R Section 15. Regulatory information WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. styrene Yes. No. - - ethanediol No. Yes. - - aniline Yes. No. Yes. - Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level California Prop. 65 New York :The following components are listed: Styrene; n,n-Diethylaniline New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-; DIMETHYLANILINE; BENZENAMINE, N,N-DIMETHYL- Pennsylvania :The following components are listed: BENZENE, ETHENYL-; BENZENAMINE, N,N- DIMETHYL- International regulations Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. International lists National inventoryNot determined Section 16. Other information Hazardous Material Information System (U.S.A.) 3 3 0 0 3 2 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual. Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 13/14 Core-Bond B70 R Section 16. Other information 1/8/2019 History Date of printing Date of issue/Date of revision Version To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Date of previous issue : : : : Indicates information that has changed from previously issued version. References :Not available. Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 1/8/2019 10/3/2018 2.01 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Date of issue/Date of revision :1/8/2019 Date of previous issue :10/3/2018 Version:2.01 14/14