23B750RF_SDS.pdf
Core-Bond B750R Drum
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Core-Bond B750R Drum
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
TOXIC TO REPRODUCTION (Fertility) – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H361 – Suspected of damaging fertility.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/8/2019 Date of previous issue :12/4/2017 Version:1.01 1/14
Core-Bond B750R Drum
Section 2. Hazards identification
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
P272 (OSHA) – Contaminated work clothing must not be allowed out of the workplace.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P363 – IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 – If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 32.335 100-42-5
cobalt bis(2-ethylhexanoate) 0.11184 136-52-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :CC750E02
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Date of issue/Date of revision :1/8/2019 Date of previous issue :12/4/2017 Version:1.01 2/14
Core-Bond B750R Drum
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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Core-Bond B750R Drum
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Specific treatments :No specific treatment.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Core-Bond B750R Drum
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure – obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Core-Bond B750R Drum
Section 8. Exposure controls/personal protection
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2016).
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
SolventOdor
pH
White.Color
Not available.
Not available.Odor threshold
:
:
:
:
:
:
Appearance
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Core-Bond B750R Drum
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
0.7 to 0.8
Not available.
Not available.
Not available.
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat >2000 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Core-Bond B750R Drum
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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Core-Bond B750R Drum
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :Suspected of damaging fertility.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 7073.9 mg/kg
Inhalation (gases) 7033.7 ppm
Inhalation (vapors) 29.96 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Core-Bond B750R Drum
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
cobalt bis(2-ethylhexanoate)- – Not readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Resin solution RESIN
SOLUTION
Resin solution
UN1866UN1866 UN1866
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN
SOLUTION
ADR/RID
UN1866
RESIN
SOLUTION
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
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Core-Bond B750R Drum
Section 14. Transport information
3
III
3
III
3
III
Reportable
quantity 3092.
6 lbs / 1404 kg
[494.55 gal /
1872.1 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
3
III
No.
Special
provisions 223
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Core-Bond B750R Drum
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; FIBROUS
GLASS
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 32.335
cobalt bis(2-ethylhexanoate) 136-52-7 0.11184
styrene 100-42-5 32.335
cobalt bis(2-ethylhexanoate) 136-52-7 0.11184
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :The following components are listed: Styrene
State regulations
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :933706816.1 lbs / 423902894.5 kg [149311063.3 gal / 565203859.3 L]
acrylonitrile <0.0000119Yes.10000 1488 100 14.9
methacrylonitrile <0.0000119Yes.500 75 1000 149.9
aniline 0.
000001365
- 0.
00001365
Yes.1000 117.6 5000 587.9
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 32.335 Yes. No. No. Yes. Yes.
cobalt bis(2-ethylhexanoate) 0.11184 No. No. No. Yes. Yes.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Date of issue/Date of revision :1/8/2019 Date of previous issue :12/4/2017 Version:1.01 12/14
Core-Bond B750R Drum
Section 15. Regulatory information
WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product
contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.
acrylonitrile Yes. No. Yes. -
styrene Yes. No. - -
ethanediol No. Yes. - -
aniline Yes. No. Yes. -
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
California Prop. 65
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
COBALT compounds
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; COBALT COMPOUNDS
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Date of issue/Date of revision :1/8/2019 Date of previous issue :12/4/2017 Version:1.01 13/14
Core-Bond B750R Drum
Section 16. Other information
1/8/2019
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
1/8/2019
12/4/2017
1.01
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :1/8/2019 Date of previous issue :12/4/2017 Version:1.01 14/14
23B73RF_SDS.pdf
Core-Bond B73 R
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Core-Bond B73 R
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H351 – Suspected of causing cancer.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Core-Bond B73 R
Section 2. Hazards identification
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P362+P364 – IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse.
P332 + P313 – If skin irritation occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 30.067 100-42-5
N,N-dimethylaniline 0.1323 121-69-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :CC073E00
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Core-Bond B73 R
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Core-Bond B73 R
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Core-Bond B73 R
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure –
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
N,N-dimethylaniline ACGIH TLV (United States, 3/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
TWA: 25 mg/m 8 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
Absorbed through skin.
TWA: 5 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Core-Bond B73 R
Section 8. Exposure controls/personal protection
TWA: 25 mg/m 8 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
NIOSH REL (United States, 10/2016).
Absorbed through skin.
TWA: 5 ppm 10 hours.
TWA: 25 mg/m 10 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
OSHA PEL (United States, 6/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
TWA: 25 mg/m 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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Core-Bond B73 R
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid. [Paste.]
Not available.
0.7 to 0.8
Not available.
Not available.
Not available.
SolventOdor
pH
White.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Core-Bond B73 R
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
N,N-dimethylaniline LC50 Inhalation Vapor Rat >5.1 mg/l 4 hours
LD50 Dermal Rabbit 1700 mg/kg –
LD50 Oral Rat 1120 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Information on toxicological effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
N,N-dimethylaniline – 3 –
Product/ingredient name NTPIARCOSHA
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Core-Bond B73 R
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 7297.5 mg/kg
Inhalation (gases) 7286.7 ppm
Inhalation (vapors) 31.04 mg/l
Route ATE value
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Core-Bond B73 R
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
N,N-dimethylaniline 1.171 16 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
N,N-dimethylaniline Acute EC50 5 mg/l Daphnia – Daphnia magna 48 hours
Acute IC50 340 mg/l Algae – Desmodesmus
subspicatus
96 hours
Acute LC50 65.6 mg/l Fish – Pimephales promelas 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
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Core-Bond B73 R
Section 14. Transport information
Resin solution
3
III
RESIN
SOLUTION
3
III
Resin solution
UN1866
3
III
UN1866 UN1866
Reportable
quantity 3325.
9 lbs / 1509.9
kg [531.85 gal /
2013.3 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
ADR/RID
UN1866
RESIN
SOLUTION
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
3
III
No.
Special
provisions 223
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Core-Bond B73 R
Section 14. Transport information
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
:Not available.
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; FIBROUS
GLASS
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 30.067
styrene 100-42-5 30.067
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
State regulations
TSCA 8(a) PAIR: N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :21801002628.1 lbs / 9897655193.2 kg [3486245176.5 gal / 13196873590.9 L]
aniline 0.
00000417 –
0.0000417
Yes.1000 117.6 5000 587.9
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 30.067 Yes. No. No. Yes. Yes.
N,N-dimethylaniline 0.1323 Yes. No. No. Yes. Yes.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
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Section 15. Regulatory information
WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product
contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.
styrene Yes. No. – –
ethanediol No. Yes. – –
aniline Yes. No. Yes. –
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
California Prop. 65
New York :The following components are listed: Styrene; n,n-Diethylaniline
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
DIMETHYLANILINE; BENZENAMINE, N,N-DIMETHYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; BENZENAMINE, N,N-
DIMETHYL-
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
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Section 16. Other information
1/8/2019
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
1/8/2019
3/5/2016
1.05
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/5/2016 Version:1.05 14/14
23B73RD_SDS.pdf
Core-Bond B73 R
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Core-Bond B73 R
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H351 – Suspected of causing cancer.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Core-Bond B73 R
Section 2. Hazards identification
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P362+P364 – IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse.
P332 + P313 – If skin irritation occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 30.067 100-42-5
N,N-dimethylaniline 0.1323 121-69-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :CC073E00
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Core-Bond B73 R
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Core-Bond B73 R
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Core-Bond B73 R
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure –
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
N,N-dimethylaniline ACGIH TLV (United States, 3/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
TWA: 25 mg/m 8 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
Absorbed through skin.
TWA: 5 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
TWA: 25 mg/m 8 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
NIOSH REL (United States, 10/2016).
Absorbed through skin.
TWA: 5 ppm 10 hours.
TWA: 25 mg/m 10 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
OSHA PEL (United States, 6/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
TWA: 25 mg/m 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid. [Paste.]
Not available.
0.7 to 0.8
Not available.
Not available.
Not available.
SolventOdor
pH
White.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Core-Bond B73 R
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
N,N-dimethylaniline LC50 Inhalation Vapor Rat >5.1 mg/l 4 hours
LD50 Dermal Rabbit 1700 mg/kg –
LD50 Oral Rat 1120 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Information on toxicological effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
N,N-dimethylaniline – 3 –
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/5/2016 Version:1.05 8/14
Core-Bond B73 R
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 7297.5 mg/kg
Inhalation (gases) 7286.7 ppm
Inhalation (vapors) 31.04 mg/l
Route ATE value
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/5/2016 Version:1.05 9/14
Core-Bond B73 R
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
N,N-dimethylaniline 1.171 16 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
N,N-dimethylaniline Acute EC50 5 mg/l Daphnia – Daphnia magna 48 hours
Acute IC50 340 mg/l Algae – Desmodesmus
subspicatus
96 hours
Acute LC50 65.6 mg/l Fish – Pimephales promelas 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/5/2016 Version:1.05 10/14
Core-Bond B73 R
Section 14. Transport information
Resin solution
3
III
RESIN
SOLUTION
3
III
Resin solution
UN1866
3
III
UN1866 UN1866
Reportable
quantity 3325.
9 lbs / 1509.9
kg [531.85 gal /
2013.3 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
ADR/RID
UN1866
RESIN
SOLUTION
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
3
III
No.
Special
provisions 223
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/5/2016 Version:1.05 11/14
Core-Bond B73 R
Section 14. Transport information
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
:Not available.
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; FIBROUS
GLASS
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 30.067
styrene 100-42-5 30.067
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
State regulations
TSCA 8(a) PAIR: N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :21801002628.1 lbs / 9897655193.2 kg [3486245176.5 gal / 13196873590.9 L]
aniline 0.
00000417 –
0.0000417
Yes.1000 117.6 5000 587.9
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 30.067 Yes. No. No. Yes. Yes.
N,N-dimethylaniline 0.1323 Yes. No. No. Yes. Yes.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/5/2016 Version:1.05 12/14
Core-Bond B73 R
Section 15. Regulatory information
WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product
contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.
styrene Yes. No. – –
ethanediol No. Yes. – –
aniline Yes. No. Yes. –
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
California Prop. 65
New York :The following components are listed: Styrene; n,n-Diethylaniline
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
DIMETHYLANILINE; BENZENAMINE, N,N-DIMETHYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; BENZENAMINE, N,N-
DIMETHYL-
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/5/2016 Version:1.05 13/14
Core-Bond B73 R
Section 16. Other information
1/8/2019
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
1/8/2019
3/5/2016
1.05
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :1/8/2019 Date of previous issue :3/5/2016 Version:1.05 14/14
23B600RF_SDS.pdf
SAFETY DATA SHEET
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
Core-Bond B600R PL Pail
Relevant identified uses of the substance or mixture and uses advised against
:
Supplier
e-mail address of person
responsible for this SDS
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SDS@scottbader.com
:
SB –
Canada
+1 215 207 0061 (NCEC Geographic) 24h
+1 800 579 7421 (NCEC Canada Toll free) 24h
+1 866 928 0789 (NCEC USA Toll free) 24h
Resins.
Identified uses
Core-Bond B600R PL Pail
Not available.
Liquid.
Product identifier
Other means of
identification
Product type
:
:
:
Product code :CC600E05
Section 2. Hazard identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1A
TOXIC TO REPRODUCTION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
May cause respiratory irritation.
May damage fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
Date of issue/Date of revision :10/02/2023Date of previous issue :11/03/2019 Version:2.01 1/13
Core-Bond B600R PL Pail
Section 2. Hazard identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Wear protective gloves, protective clothing and
eye or face protection. Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. Use only outdoors or in a well-ventilated
area. Do not breathe vapor. Do not eat, drink or smoke when using this product.
Wash thoroughly after handling. Contaminated work clothing should not be allowed
out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of
water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed.
Disposal :Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Section 3. Composition/information on ingredients
Other means of
identification
:Not available.
Substance/mixture :Mixture
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Ranges if listed above for hazardous ingredient(s) are prescribed ranges. The actual concentration(s) or actual
concentration range(s) are being withheld as a trade secret.
Ingredient name CAS number% (w/w)
styrene Benzene, ethenyl-; Ethenylbenzene;
Vinylbenzene; Styrol; Styrene
monomer; Phenylethylene; Styrene,
monomer; Styrene – monomer;
Cinnamol; Cinnamene; Styrolene
30 – 40 100-42-5
cobalt bis(2-ethylhexanoate) Hexanoic acid, 2-ethyl-, cobalt(2+)
salt (2:1); Hexanoic acid, 2-ethyl-,
cobalt(2+) salt; Cobalt octoate;
Cobalt 2-ethylhexanoate; Cobalt(II)
2-ethylhexanoate; Aliphatic
monocarboxylic acid (C6-28) salt (Pb,
Cu, Mn, Zn, Zr, Ce, Cd, Sn, Sr, Co);
2-Ethylhexanoic acid cobalt(2+) salt;
Cobaltous octoate; HEXANOATE,
2-ETHYL-, COBALT (II); HEXANOIC
ACID, 2-ETHYL, COBALT(2+)SALT
0.3 136-52-7
Synonyms
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Section 4. First-aid measures
Eye contact :
Description of necessary first aid measures
Date of issue/Date of revision :10/02/2023Date of previous issue :11/03/2019 Version:2.01 2/13
Core-Bond B600R PL Pail
Section 4. First-aid measures
Wash out mouth with water. Remove dentures if any. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention. Never give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the
event of any complaints or symptoms, avoid further exposure. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention. If necessary, call a poison center or physician.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Skin contact
Inhalation
Ingestion :
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :10/02/2023Date of previous issue :11/03/2019 Version:2.01 3/13
Core-Bond B600R PL Pail
Section 4. First-aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion.
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in “For non-emergency personnel”.
Date of issue/Date of revision :10/02/2023Date of previous issue :11/03/2019 Version:2.01 4/13
Core-Bond B600R PL Pail
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved
area. Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10) and food and
drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing
materials. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination. See Section 10 for incompatible materials
before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Avoid exposure – obtain special instructions before use.
Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not
breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when
not in use. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Take precautionary measures against
electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
styrene CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 40 ppm 15 minutes.
15 min OEL: 170 mg/m 15 minutes.
8 hrs OEL: 85 mg/m 8 hours.
8 hrs OEL: 20 ppm 8 hours.
CA British Columbia Provincial (Canada,
3/2022).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 35 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Quebec Provincial (Canada, 6/2021).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision :10/02/2023Date of previous issue :11/03/2019 Version:2.01 5/13
Core-Bond B600R PL Pail
Section 8. Exposure controls/personal protection
Absorbed through skin.
TWAEV: 50 ppm 8 hours.
TWAEV: 213 mg/m 8 hours.
STEV: 100 ppm 15 minutes.
STEV: 426 mg/m 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 40 ppm 15 minutes.
TWA: 20 ppm 8 hours.
cobalt bis(2-ethylhexanoate) CA British Columbia Provincial (Canada,
3/2022). [cobalt and inorganic
compounds] Skin sensitizer. Inhalation
sensitizer.
CA British Columbia Provincial (Canada,
3/2022). [Cobalt and inorganic
compounds] Skin sensitizer. Inhalation
sensitizer.
TWA: 0.02 mg/m , (as Co, Total) 8 hours.
CA Quebec Provincial (Canada, 6/2021).
[Cobalt elemental, and inorganic
compounds] Skin sensitizer.
TWAEV: 0.02 mg/m , (as Co) 8 hours.
CA Ontario Provincial (Canada, 6/2019).
[Cobalt and inorganic compounds]
TWA: 0.02 mg/m , (as Co) 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013). [Cobalt and inorganic
compounds]
STEL: 0.06 mg/m , (measured as Co) 15
minutes.
TWA: 0.02 mg/m , (measured as Co) 8
hours.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Eye/face protection :
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Biological exposure indices
No exposure indices known.
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Core-Bond B600R PL Pail
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
:
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Relative vapor density
Liquid.
Not available.
0.55 to 0.65
Not available.
Not available.
SolventOdor
pH
White.Color
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not applicable.
Not available.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point, initial boiling
point, and boiling range
:Not available.
Flammability :Not available.
Lower and upper explosion
limit/flammability limit
:Not available.
Solubility in water :Not available.
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
Viscosity Kinematic (40 C (104 F)): >40 mm
2
/s (>40 cSt):
Decomposition temperature:Not available.
Particle characteristics
Median particle size :Not applicable.
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Core-Bond B600R PL Pail
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat >2000 mg/kg –
Product/ingredient nameResult Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 ppm –
Eyes – Moderate irritantRabbit – 24 hours 100
mg
–
Eyes – Severe irritantRabbit – 100 mg –
Skin – Mild irritant Rabbit – 500 mg –
Skin – Moderate irritantRabbit – 100 % –
Product/ingredient nameResult Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
styrene 2A Reasonably anticipated
to be a human
carcinogen.
A3
cobalt bis(2-ethylhexanoate) 2B Reasonably anticipated
to be a human
carcinogen.
A3
Product/ingredient name NTPIARC ACGIH
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Core-Bond B600R PL Pail
Section 11. Toxicological information
Teratogenicity
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 – Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Long term exposure
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Core-Bond B600R PL Pail
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient nameResult Species Dose Exposure
Causes damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very
low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Potential chronic health effects
Potential immediate
effects
:Not available.
Potential delayed effects:Not available.
May damage fertility or the unborn child.Reproductive toxicity :
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name
Core-Bond B600R PL Pail N/A N/A 7833.2 33.4 N/A
styrene 2650 2500 2770 11.8 N/A
cobalt bis(2-ethylhexanoate) 2500 N/A N/A N/A N/A
Oral (mg/
kg)
Dermal
(mg/kg)
Inhalation
(gases)
(ppm)
Inhalation
(vapors)
(mg/l)
Inhalation
(dusts
and mists)
(mg/l)
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
styrene 0.35 13.49 low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
cobalt bis(2-ethylhexanoate)- – Not readily
Toxicity
styrene Acute EC50 4.9 mg/l Algae 72 hours
Acute EC50 78000 g/l Marine waterAlgae – Skeletonema costatum96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
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Core-Bond B600R PL Pail
Section 12. Ecological information
Other adverse effects :No known significant effects or critical hazards.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken when handling
emptied containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Vapor from product residues may create a
highly flammable or explosive atmosphere inside the container. Do not cut, weld or
grind used containers unless they have been cleaned thoroughly internally. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:Disposal methods
Section 14. Transport information
RESIN SOLUTION
3
III
Resin solution
UN1866
3
III
UN1866
Emergency schedules F-E, _S-E_
Special provisions 223, 955
The environmentally hazardous substance mark may appear if required by other
transportation regulations.
Quantity limitation Passenger and Cargo Aircraft: 60 L. Packaging instructions:
355. Cargo Aircraft Only: 220 L. Packaging instructions: 366. Limited Quantities –
Passenger Aircraft: 10 L. Packaging instructions: Y344.
Special provisions A3
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
No. No.
UN1866
Resin Solution
3
III
No.
Reportable quantity 2817.5 lbs / 1279.2 kg [563.2 gal / 2131.9 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
Limited quantity Yes.
Packaging instruction Exceptions: 150. Non-bulk: 173. Bulk: 242.
Quantity limitation Passenger aircraft/rail: 60 L. Cargo aircraft: 220 L.
Special provisions B1, B52, IB3, T2, TP1
TDG Classification
UN1866
RESIN SOLUTION
3
III
No.
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Explosive Limit and Limited Quantity Index 5
Passenger Carrying Road or Rail Index 60
TDG Classification
DOT Classification
IMDG
IATA
:
:
:
:
DOT Classification IMDG IATA
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Core-Bond B600R PL Pail
Section 14. Transport information
Special precautions for userTransport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Transport in bulk according
to IMO instruments
:Not available.
Section 15. Regulatory information
International regulations
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Canadian lists
The following components are listed: styrene; cobalt (and its compounds)Canadian NPRI :
CEPA Toxic substances :None of the components are listed.
Not listed.
Section 16. Other information
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
Key to abbreviations :
10/02/2023
11/03/2019
2.01
:
2/10/2023
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
HPR = Hazardous Products Regulations
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Procedure used to derive the classification
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Core-Bond B600R PL Pail
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.
Notice to reader
Indicates information that has changed from previously issued version.
References :Not available.
Classification Justification
FLAMMABLE LIQUIDS – Category 3 On basis of test data
ACUTE TOXICITY (inhalation) – Category 4 Calculation method
SKIN IRRITATION – Category 2 Calculation method
EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1A Calculation method
TOXIC TO REPRODUCTION – Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
Date of issue/Date of revision :10/02/2023Date of previous issue :11/03/2019 Version:2.0113/13
23B600RD_SDS.pdf
Core-Bond B600R Drum
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Core-Bond B600R Drum
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
TOXIC TO REPRODUCTION (Fertility) – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H361 – Suspected of damaging fertility.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Core-Bond B600R Drum
Section 2. Hazards identification
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
P272 (OSHA) – Contaminated work clothing must not be allowed out of the workplace.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P363 – IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 – If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 35.173 100-42-5
cobalt bis(2-ethylhexanoate) 0.12578 136-52-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :CC600E02
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Core-Bond B600R Drum
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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Core-Bond B600R Drum
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Specific treatments :No specific treatment.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Core-Bond B600R Drum
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure – obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Core-Bond B600R Drum
Section 8. Exposure controls/personal protection
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2016).
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
SolventOdor
pH
White.Color
Not available.
Not available.Odor threshold
:
:
:
:
:
:
Appearance
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:2.01 6/14
Core-Bond B600R Drum
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
0.55 to 0.65
Not available.
Not available.
Not available.
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat >2000 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:2.01 7/14
Core-Bond B600R Drum
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:2.01 8/14
Core-Bond B600R Drum
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :Suspected of damaging fertility.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 7564.9 mg/kg
Inhalation (gases) 7053.9 ppm
Inhalation (vapors) 30.05 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Core-Bond B600R Drum
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
cobalt bis(2-ethylhexanoate)- – Not readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Resin solution RESIN
SOLUTION
Resin solution
UN1866UN1866 UN1866
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN
SOLUTION
ADR/RID
UN1866
RESIN
SOLUTION
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:2.01 10/14
Core-Bond B600R Drum
Section 14. Transport information
3
III
3
III
3
III
Reportable
quantity 2843.
1 lbs / 1290.8
kg [568.31 gal /
2151.3 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
3
III
No.
Special
provisions 223
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:2.01 11/14
Core-Bond B600R Drum
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; FIBROUS
GLASS
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 35.173
cobalt bis(2-ethylhexanoate) 136-52-7 0.12578
styrene 100-42-5 35.173
cobalt bis(2-ethylhexanoate) 136-52-7 0.12578
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
COBALT compounds
State regulations
TSCA 8(a) PAIR: N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :218078726.4 lbs / 99007741.8 kg [43591797.2 gal / 165012903 L]
acrylonitrile <0.
00005095
Yes.10000 1488 100 14.9
methacrylonitrile <0.
00005095
Yes.500 75 1000 149.9
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 35.173 Yes. No. No. Yes. Yes.
cobalt bis(2-ethylhexanoate) 0.12578 No. No. No. Yes. Yes.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:2.01 12/14
Core-Bond B600R Drum
Section 15. Regulatory information
WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product
contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.
acrylonitrile Yes. No. Yes. -
styrene Yes. No. - -
ethanediol No. Yes. - -
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
California Prop. 65
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; COBALT COMPOUNDS
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:2.01 13/14
Core-Bond B600R Drum
Section 16. Other information
1/8/2019
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
1/8/2019
10/24/2018
2.01
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:2.01 14/14
23B39WD_SDS.pdf
Poly-Bond B39 W
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Poly-Bond B39 W
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:CHEMTREC: 1-800-424-9300 (24h)
SDS@scottbader.com:e-mail address of person
responsible for this SDS
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
TOXIC TO REPRODUCTION (Unborn child) – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H361 – Suspected of damaging the unborn child.
H351 – Suspected of causing cancer.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 1/14
Poly-Bond B39 W
Section 2. Hazards identification
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P362+P364 – IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse.
P332 + P313 – If skin irritation occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 23.974 100-42-5
Talc , not containing asbestiform fibres 22.783 14807-96-6
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :CB039D00
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 2/14
Poly-Bond B39 W
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 3/14
Poly-Bond B39 W
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 4/14
Poly-Bond B39 W
Section 6. Accidental release measures
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure –
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Talc , not containing asbestiform fibres OSHA PEL 1989 (United States, 3/1989).
TWA: 2 mg/m 8 hours. Form: Respirable
dust
ACGIH TLV (United States, 3/2015).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Poly-Bond B39 W
Section 8. Exposure controls/personal protection
TWA: 2 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2013).
TWA: 2 mg/m 10 hours. Form: Respirable
fraction
OSHA PEL Z3 (United States, 2/2013).
TWA: 0.1 f/cc 8 hours. Form: containing
asbestos
STEL: 1 f/cc 30 minutes. Form: containing
asbestos
TWA: 20 mppcf 8 hours. Form: not
containing asbestos
STEL: 1 f/cc 30 minutes. Form: not
containing asbestos
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 6/14
Poly-Bond B39 W
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid. [Paste.]
Not available.
1 to 1.1
Not available.
Not available.
Not available.
SolventOdor
pH
Grey.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Solubility in water :Not available.
VOC content (% by weight):Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 7/14
Poly-Bond B39 W
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
Talc , not containing
asbestiform fibres
LD50 Oral Rat >5000 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on the likely
routes of exposure
Causes serious eye irritation.:Eye contact
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
styrene Category 1 Not determinedhearing organs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
Talc , not containing
asbestiform fibres
– 3 –
Product/ingredient name NTPIARCOSHA
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 8/14
Poly-Bond B39 W
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Inhalation :Harmful if inhaled.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 11275.1 mg/kg
Inhalation (gases) 11785.6 ppm
Inhalation (vapors) 50.21 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 9/14
Poly-Bond B39 W
Section 11. Toxicological information
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52000 g/l Marine waterCrustaceans – Artemia salina –
Nauplii
48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 10/14
Poly-Bond B39 W
Section 14. Transport information
Resin solution
3
III
RESIN
SOLUTION
3
III
Resin solution
UN1866
3
III
UN1866 UN1866
Reportable
quantity
4171.1 lbs /
1893.7 kg [476.
44 gal / 1803.5
L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity
Yes.
Packaging
instruction
Passenger
aircraft
Quantity
limitation: 60 L
Cargo aircraft
Quantity
limitation: 220 L
Special
provisions
B1, B52, IB3,
T2, TP1
Emergency
schedules
(EmS)
F-E, _S-E_
Special
provisions
223, 955
Passenger
and Cargo
Aircraft
Quantity
limitation: 60 L
Packaging
instructions:
355
Cargo Aircraft
OnlyQuantity
limitation: 220 L
Packaging
instructions:
366
Limited
Quantities –
Passenger
Aircraft
Quantity
limitation: 10 L
Packaging
instructions:
Y344
Special
provisions
A3
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No. No.
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index
60
ADR/RID
UN1866
RESIN
SOLUTION
3
III
No.
Hazard
identification
number
30
Limited
quantity
5 L
Special
provisions
640E
Tunnel code
(D/E)
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
3
III
No.
Special
provisions
223
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 11/14
Poly-Bond B39 W
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE MONOMER; MAGNESITE DUST;
SOAPSTONE; MINERAL WOOL FIBER
Clean Water Act (CWA) 311: styrene
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 23.974
styrene 100-42-5 23.974
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :The following components are listed: Styrene
State regulations
TSCA 8(a) PAIR: N,N-dimethylaniline; 4-tert-butylpyrocatechol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 23.974 Yes. No. No. Yes. Yes.
Talc , not containing asbestiform fibres22.783 No. No. No. Yes. No.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 12/14
Poly-Bond B39 W
Section 15. Regulatory information
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
MAGNESITE; CARBONIC ACID, MAGNESIUM SALT (1:1); SOAPSTONE
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; TALC; SOAPSTONE
DUST; FIBROUS GLASS DUST
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia :Not determined.
Canada :Not determined.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :Not determined.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :Not determined.
Taiwan :Not determined.
United States :Not determined.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
0
0
0
0
3
2
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 13/14
Poly-Bond B39 W
Section 16. Other information
3/2/2016
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
3/2/2016
3/2/2016
1.01
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :3/2/2016 Date of previous issue :3/2/2016 Version:1.01 14/14
23B39SD_SDS.pdf
Poly-Bond B39 S
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Poly-Bond B39 S
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:3.01 1/13
Poly-Bond B39 S
Section 2. Hazards identification
Prevention :P280 – Wear protective gloves. Wear eye or face protection.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
Response :P314 – Get medical attention if you feel unwell.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P362+P364 – IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse.
P332 + P313 – If skin irritation occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 23.986 100-42-5
Talc , not containing asbestiform fibres 22.766 14807-96-6
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :CB039A00
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
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Poly-Bond B39 S
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Poly-Bond B39 S
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Poly-Bond B39 S
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Talc , not containing asbestiform fibres OSHA PEL 1989 (United States, 3/1989).
TWA: 2 mg/m 8 hours. Form: Respirable
dust
ACGIH TLV (United States, 3/2016).
TWA: 2 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2016).
TWA: 2 mg/m 10 hours. Form: Respirable
fraction
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Poly-Bond B39 S
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid. [Paste.]
Not available.
SolventOdor
pH
Grey.Color
Evaporation rate Not available.
Flash point Closed cup: 31 C (87.8 F)
Not available.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point :Not available.
Flammability (solid, gas):Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
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Poly-Bond B39 S
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1 to 1.1
Not available.
Not available.
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Lower and upper explosive
(flammable) limits
:Not available.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
Talc , not containing
asbestiform fibres
LD50 Oral Rat >5000 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure ObservationSpecies
Information on toxicological effects
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Poly-Bond B39 S
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Sensitization
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
Talc , not containing
asbestiform fibres
– 3 –
Product/ingredient name NTPIARCOSHA
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Poly-Bond B39 S
Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 11270.1 mg/kg
Inhalation (gases) 6225.2 ppm
Inhalation (vapors) 26.52 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
styrene 0.35 13.49 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
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Poly-Bond B39 S
Section 12. Ecological information
Other adverse effects :No known significant effects or critical hazards.
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Resin solution
3
III
RESIN
SOLUTION
3
III
Resin solution
UN1866
3
III
UN1866 UN1866
Reportable
quantity 4169.
2 lbs / 1892.8
kg [476.21 gal /
1802.7 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No. No.
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
ADR/RID
UN1866
RESIN
SOLUTION
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
3
III
No.
Special
provisions 223
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Poly-Bond B39 S
Section 14. Transport information
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Y344.
Special
provisions A3
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Road or Rail
Index 60
Section 15. Regulatory information
U.S. Federal regulations :
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
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Poly-Bond B39 S
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENE; MAGNESITE
DUST; TALC; SOAPSTONE; FIBROUS GLASS
WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product
contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.
Massachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene Yes. No. – –
ethanediol No. Yes. – –
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
styrene 100-42-5 23.986
styrene 100-42-5 23.986
Form R – Reporting
requirements
Supplier notification
California Prop. 65
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
MAGNESITE; CARBONIC ACID, MAGNESIUM SALT (1:1); SOAPSTONE
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; TALC; SOAPSTONE
DUST
State regulations
styrene 23.986 Yes. No. No. Yes. Yes.
Talc , not containing asbestiform fibres22.766 No. No. No. Yes. No.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:3.01 12/13
Poly-Bond B39 S
Section 16. Other information
1/8/2019
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
1/8/2019
10/24/2018
3.01
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :1/8/2019 Date of previous issue :10/24/2018 Version:3.01 13/13
23AP3220_SDS.pdf
SAFETY DATA SHEET
Date issued : 01/17/2017
SDS number : AP-3220 PART A
Date revised : 07/19/2023
Revision number : 2
AP-3220 PART A
1. Identification
Product identifier: AP-3220 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
Label elements
Health hazard Exclamation
mark
Signal word: DANGER
Hazard statement(s)
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
Page 1 of 6
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Polyurethane prepolymer 30 – 60Proprietary
4,4′-Diphenylmethane diisocyanate 30 – 60101-68-8
Benzene, 1,1′-methylenebis[isocyanato-, homopolymer 10 – 3039310-05-9
Benzene, 1,1′-methylenebis[isocyanato- 3 – 726447-40-5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Get immediate medical attention.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, silicon oxides, and formaldehyde.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Page 2 of 6
AP-3220 PART A
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 3 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
4,4′-Diphenylmethane diisocyanate
OSHA PEL C 0.02 0.2
ACGIH TLV TWA 0.005 –
NIOSH REL
TWA 0.005 0.05
C 0.02
[1]
0.2
[1]
Footnotes:
1. 10-minute
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection – hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection – other: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Pale yellow
Page 3 of 6
AP-3220 PART A
Odor: Slightly musty
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.163 (water=1) at 25 C (77 F)
Solubility: Reacts with water
Dynamic viscosity: 1430 Centipoise at 25 C (77 F)
VOC content: < 0.2 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing active hydrogen
groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the reaction partners is
good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than water and sinks to the bottom but reacts
slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, silicon oxides, methanol, and
formaldehyde.
Incompatible materials: Water, alcohols, amines, acids, bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation) mg/l
Polyurethane prepolymer No data available No data available No data available
4,4'-Diphenylmethane diisocyanate
> 2000 mg/kg Rat > 9400 mg/kg Rabbit 2.24 mg/l Rat (1 h,
dust/mist)
Benzene, 1,1′-methylenebis[isocyanato-,
homopolymer
No data available No data available No data available
Benzene, 1,1′-methylenebis[isocyanato-
> 2000 mg/kg Rat > 9400 mg/kg Rabbit 2.24 mg/l Rat (1 h,
dust/mist)
Skin corrosion / irritation: Causes skin irritation.
Serious eye damage / irritation: Causes serious eye irritation.
Respiratory or skin sensitization: May cause sensitization by inhalation and skin contact.
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name IARC
4,4′-Diphenylmethane diisocyanate 3
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: May cause respiratory irritation.
Specific Target Organ Toxicity – repeated exposure: May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard: No data available
12. Ecological information
Page 4 of 6
AP-3220 PART A
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Environmental data: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product contains the following substances subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA Section 313 Toxic Chemicals
Chemical name % w/wCAS No. Comments
4,4′-Diphenylmethane diisocyanate 30 – 60101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
CERCLA Hazardous Substances and Reportable Quantities (RQ)
Chemical name % w/w CERCLA rq
4,4′-Diphenylmethane diisocyanate 30 – 60 5,000 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119—process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer and birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Ethyl acrylate < 0.00001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
Page 5 of 6
AP-3220 PART A
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 07/19/2023
Revision summary: This SDS replaces the 01/16/2020 SDS.
HMIS rating
Health * 2
Flammability 1
Physical hazard 1
Personal protection X
NFPA codes
1
2 1
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 6 of 6
AP-3220 PART A
SAFETY DATA SHEET
Date issued : 01/17/2017
SDS number : AP-3220 PART B
Date revised : 07/19/2023
Revision number : 2
AP-3220 PART B
1. Identification
Product identifier: AP-3220 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Page 1 of 5
Chemical name % w/w CAS No.
Polyether polyol mixture 80 - 100Proprietary
Hydroxy terminated poly(oxyalkylated) polyol 10 - 30102-60-3
1,3-Benzenedimethanamine 1 - 51477-55-0
Silicon dioxide 1 - 57631-86-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, silicon oxides, and formaldehyde.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 3 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Page 2 of 5
AP-3220 PART B
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
1,3-Benzenedimethanamine
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA -
[1]
0.1
[1]
STEL - -
Silicon dioxide
OSHA PEL TWA 20 mppcf
[2]
80 %SiO2
[2]
NIOSH REL TWA - 6
Footnotes:
1. Skin
2. Mineral dusts
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Pale yellow
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.054 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 2870 Centipoise at 25 C (77 F)
VOC content: < 0.1 g/l Calculated. Theoretical VOC minus water and exempt solvents.
Page 3 of 5
AP-3220 PART B
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, silicon oxides, methanol, and formaldehyde.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
Hydroxy terminated poly(oxyalkylated) polyol 3280 mg/kg Rat > 2000 mg/kg Rabbit No data available
1,3-Benzenedimethanamine 980 mg/kg Rat 2000 mg/kg Rabbit 1.34 mg/l Rat (4 h)
Silicon dioxide > 3300 mg/kg Rat > 5000 mg/kg Rat 0.139 mg/l Rat (4 h)
Skin corrosion / irritation: Causes skin irritation.
Serious eye damage / irritation: Causes serious eye irritation.
Respiratory or skin sensitization: May cause sensitization by skin contact.
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name IARC
Silicon dioxide 3
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Environmental data: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
Page 4 of 5
AP-3220 PART B
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119—process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene < 0.001 Developmental Toxicity
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 07/19/2023
Revision summary: This SDS replaces the 01/16/2020 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
AP-3220 PART B
23AP1230_SDS.pdf
SAFETY DATA SHEET
Date issued : 09/04/2015
SDS number : AP-1230 PART A
Date revised : 11/27/2023
Revision number : 3
AP-1230 PART A
1. Identification
Product identifier: AP-1230 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
Label elements
Health hazard Exclamation
mark
Signal word: DANGER
Hazard statement(s)
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
Page 1 of 6
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Polyurethane prepolymer 40 – 70Proprietary
4,4′-Diphenylmethane diisocyanate 10 – 30101-68-8
1,3-Dioxolan-2-one, 4-methyl- 7 – 13108-32-7
Silane, trimethoxy[3-(oxiranylmethoxy)propyl]- 1 – 52530-83-8
Benzene, 1,1′-methylenebis[isocyanato- 1 – 526447-40-5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Get immediate medical attention.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-containing vapor.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
Page 2 of 6
AP-1230 PART A
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 3 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
4,4′-Diphenylmethane diisocyanate
OSHA PEL C 0.02 0.2
ACGIH TLV TWA 0.005 –
NIOSH REL
TWA 0.005 0.05
C 0.02
[1]
0.2
[1]
Footnotes:
1. 10-minute
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection – hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection – other: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Page 3 of 6
AP-1230 PART A
Color: Pale yellow
Odor: Slightly musty
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 110 C (230 F) Closed Cup
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.121 (water=1) at 25 C (77 F)
Solubility: Reacts with water
Dynamic viscosity: 3790 Centipoise at 25 C (77 F)
VOC content: < 0.2 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing active hydrogen
groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the reaction partners is
good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than water and sinks to the bottom but reacts
slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-containing vapor.
Incompatible materials: Water, alcohols, amines, bases, and acids.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyurethane prepolymer No data available No data available No data available
4,4'-Diphenylmethane diisocyanate > 2000 mg/kg Rat > 9400 mg/kg Rabbit 2.24 mg/l Rat (1 h, dust/mist)
1,3-Dioxolan-2-one, 4-methyl- > 5000 mg/kg Rat > 2000 mg/kg Rabbit No data available
Silane, trimethoxy[3-(oxiranylmethoxy)propyl]- Not Established Not Established Not Established
Benzene, 1,1′-methylenebis[isocyanato- > 2000 mg/kg Rat > 9400 mg/kg Rabbit 2.24 mg/l Rat (1 h, dust/mist)
Skin corrosion / irritation: Causes skin irritation.
Serious eye damage / irritation: Causes serious eye irritation.
Respiratory or skin sensitization: May cause sensitization by inhalation and skin contact.
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name IARC
4,4′-Diphenylmethane diisocyanate 3
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: May cause respiratory irritation.
Specific Target Organ Toxicity – repeated exposure: May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
Page 4 of 6
AP-1230 PART A
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Environmental data: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product contains the following substances subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA Section 313 Toxic Chemicals
Chemical name % w/wCAS No. Comments
4,4′-Diphenylmethane diisocyanate 10 – 30101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
CERCLA Hazardous Substances and Reportable Quantities (RQ)
Chemical name % w/w CERCLA rq
4,4′-Diphenylmethane diisocyanate 10 – 30 5,000 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119—process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer and birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Ethyl acrylate < 0.00001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
Page 5 of 6
AP-1230 PART A
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 11/27/2023
Revision summary: This SDS replaces the 04/23/2020 SDS.
HMIS rating
Health * 2
Flammability 1
Physical hazard 1
Personal protection X
NFPA codes
1
2 1
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 6 of 6
AP-1230 PART A
SAFETY DATA SHEET
Date issued : 09/04/2015
SDS number : AP-1230 PART B
Date revised : 11/27/2023
Revision number : 3
AP-1230 PART B
1. Identification
Product identifier: AP-1230 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
Page 1 of 5
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyether polyol mixture 80 - 100Proprietary
Hydroxy terminated poly(oxyalkylated) polyol 5 - 10 102-60-3
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-(2-aminomethylethyl)-.omega.-(2-aminomethylethoxy)- 0.5 - 1.59046-10-0
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, and nitrogen oxides.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 3 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Page 2 of 5
AP-1230 PART B
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Pale yellow
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.018 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 890 Centipoise at 25 C (77 F)
VOC content: < 0.2 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, and nitrogen dioxide.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Page 3 of 5
AP-1230 PART B
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyether polyol mixture No data available No data available No data available
Hydroxy terminated poly(oxyalkylated) polyol 3280 mg/kg Rat> 2000 mg/kg Rabbit No data available
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-(2-aminomethylethyl)-
.omega.-(2-aminomethylethoxy)-
475 mg/kg Rat 2090 mg/kg Rabbit No data available
Skin corrosion / irritation: Causes skin irritation.
Serious eye damage / irritation: Causes serious eye irritation.
Respiratory or skin sensitization: May cause sensitization by skin contact.
Germ cell mutagenicity: No data available
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Environmental data: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
Page 4 of 5
AP-1230 PART B
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119—process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer and birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene < 0.0001 Developmental Toxicity
Ethyl acrylate < 0.00001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 11/27/2023
Revision summary: This SDS replaces the 04/23/2020 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
AP-1230 PART B