24FILL100_SDS.pdf

Safety Data Sheet

Material: 60004600 HDK N20
HYDROPHILIC PYROGENIC SILICA

Version: 2.1 (US) Date of print: 06/25/20 15 Date of last alteration: 06/24/2015

Page: 1/8

1. Product and company identification

1.1 Identification of the substance or preparation:

Commercial product name: HDK N20
HYDROPHILIC PYROGENIC SILICA

Use of substance / preparation Industrial.
Auxiliary agent for: Plastics , Lacquer , Building materials , elastomer
products , cosmetics .

1.2 Company/undertaking identification:

Manufacturer/distributor: Wacker Chemie AG
Hanns-Seidel-Platz 4
81737 M nchen
Germany

Customer information: Wacker Chemical Corporation
3301 Sutton Road
Adrian, Michigan 49221-9397
USA
InfoLine:
Tel (517) 264-8240, Fax (517) 264-8740
Hours of operation:
Monday – Friday, 8 am to 5 pm (eastern standard time)
Corporate website: www.wacker.com

Emergency telephone no. (24h): (517) 264-8500
Transportation emergency: (800) 424-9300 (CHEMTREC, USA)
(703) 527-3887 (CHEMTREC, international)

This SDS was prepared by the Regulatory Affairs and Product Safety Department (RAPS) of Wacker Chemical Corporation.

2. Hazards identification

2.1 Classification of the substance or mixture

Classification (GHS):

Not a hazardous substance or mixture.

2.2 Label elements

Labelling (GHS):

No labeling according to GHS required.

2.3 Other hazards

No data available.

3. Composition/information on ingredients

3.1 Chemical characterization (substance)

CAS No. Chemical characteristics
112945-52-5 Pyrogenic micro-dispersed silica, synthetic X-ray amorphous silicon dioxide (SiO2)

3.2 Information on ingredients:

This material does not contain any reportable hazardous ingredients.

Substances listed in the Subsections “HAPS” and “California Proposition 65 Carcinogens / Reproductive Toxins” that are not
listed in this section are only present at quantities below 0.1% for California Proposition 65 listed toxins or below 1% for non-
carcinogenic HAPS or they are inextricably bound in the product.

Safety Data Sheet

Material: 60004600 HDK N20
HYDROPHILIC PYROGENIC SILICA

Version: 2.1 (US) Date of print: 06/25/20 15 Date of last alteration: 06/24/2015

Page: 2/8
4. First-aid measures

4.1 General information:

Get medical attention if irritation occurs or if breathing becomes difficult.

4.2 After inhalation

If inhaled, remove to fresh air.

4.3 After contact with the skin

If contact with skin, wash skin with plenty of water or with water and soap.

4.4 After contact with the eyes

If contact with eyes, immediately flush eyes with plenty of water.

4.5 After swallowing

Drink plenty of water. Get medical attention if symptoms occur. Show label if possible.

5. Fire-fighting measures

5.1 Flammable properties:

Property: Value: Method:
Flash point………………………………………………………: not applicable
Boiling point / boiling range ……………………………….: not applicable
Lower explosion limit (LEL) ……………………………….: not applicable
Ignition temperature …………………………………………: not applicable

5.2 Fire and explosion hazards:

Material does not burn. Electrostatic charging is possible.

5.3 Recommended extinguishing media:

Use extinguishing measures appropriate to the source of fire.

5.4 Unsuitable extinguishing media:

not applicable

5.5 Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases

not applicable

5.6 Fire fighting procedures:

Fire fighters should wear full protective clothing including a self-contained breathing apparatus.

6. Accidental release measures

6.1 Precautions:

Avoid dust formation. Do not breathe dust. Wear personal protection equipment (see section 8).

HAZWOPER PPE Level: D

6.2 Containment:

Cover any spilled material in accordance with regulations to prevent dispersal by wind.

Spills of material which could reach surface waters must be reported to the United States Coast Guard National Response
Center’s toll free phone number (800) 424-8802.

6.3 Methods for cleaning up

Damp down dust and fill into containers.

7. Handling and storage

Safety Data Sheet

Material: 60004600 HDK N20
HYDROPHILIC PYROGENIC SILICA

Version: 2.1 (US) Date of print: 06/25/20 15 Date of last alteration: 06/24/2015

Page: 3/8
7.1 Handling

Precautions for safe handling:
Avoid dust formation.

Precautions against fire and explosion:
Electrostatic discharge possible during transport and processing. Take precautionary measures against electrostatic charging.
Ensure all parts of equipment are well earthed. Use inert gas when working with combustible and explosive liquids. Avoid dust
deposit, remove dust regularly.

7.2 Storage

Conditions for storage rooms and vessels:
none known

Advice for storage of incompatible materials:
not applicable

Further information for storage:
Keep container dry and tightly closed.

8. Exposure controls and personal protection

8.1 Engineering controls

Ventilation:
Use only with adequate ventilation.

Local exhaust:
In case of dust formation: ( To maintain concentration below TLV. ) Local exhaust ventilation which meets the requirements of
ANSI Z9.2 is recommended to control airborne contaminants at the point of use.

8.2 Associate substances with specific control parameters such as limit values

Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m
3
ppm Dust fract.
7631-86-9 Silica, amorphous OSHA PEL 0.8
Particulates not otherwise classified ACGIH TWA 10.0 Inhalable
dust/mist
Particulates not otherwise classified ACGIH TWA 3.0 Respirable
dust/mist

Re Silica, amorphous: The exposure limits given for CAS-No. 7631-86-9 cover all types of synthetic amorphous silica; it appears,
that there is an error in the OSHA PEL entry for amorphous silica. There should have been a footnote to the Z-3 Table indicating
that the percent SiO2 in formula (80 mg/m3 + % SiO2) refers to crystaline silica content and not to amorphous silica. For
evaluation of U.S. exposure measurements WACKER recommends use of the current NIOSH REL (6 mg/m3) instead of the old
Z-3 Table entry.

Re Particulates not otherwise classified: The value is for particulate matter containing no asbestos and < 1% crystalline silica (ACGIH). 8.3 Personal protection equipment (PPE) Respiratory protection: In case of dust formation: A NIOSH approved particulate respirator with a P95 or higher rating. Hand protection: Recommendation: rubber gloves . Eye protection: Recommendation: Safety glasses with side shields or chemical safety goggles. Other protective clothing or equipment: Barrier cream may be used to prevent dryness of skin. 8.4 General hygiene and protection measures: Do not breathe dust/vapor/mist/gas/aerosol. Wash thoroughly after handling. Safety Data Sheet Material: 60004600 HDK N20 HYDROPHILIC PYROGENIC SILICA Version: 2.1 (US) Date of print: 06/25/20 15 Date of last alteration: 06/24/2015 Page: 4/8 9. Physical and chemical properties 9.1 Appearance Physical state / form ............................................... : solid - powder Colour..................................................................... : white Odour ..................................................................... : odourless 9.2 Safety parameters Property: Value: Method: Melting point / melting range ...................................: 1700 C (3,092 F) Boiling point / boiling range .....................................: not applicable Flash point...............................................................: not applicable Ignition temperature ................................................: not applicable Lower explosion limit (LEL) .....................................: not applicable Vapour pressure......................................................: not applicable Density ....................................................................: approx. 2.2 g/cm at 20 C (68 F) (DIN 51757) Bulk density.............................................................: 20 - 130 kg/m Water solubility / miscibility......................................: virtually insoluble at 20 C (68 F) pH-Value .................................................................: 3.6 - 4.5 (DIN EN ISO 787- 9) Viscosity (dynamic) .................................................: not applicable 9.3 Further information VOC........................................................................ : This material does not contain any reportable VOCs. 0 g/l (calculated value) 10. Stability and reactivity 10.1 General information: If stored and handled in accordance with standard industrial practices no hazardous reactions are known. 10.2 Conditions to avoid 10.3 Materials to avoid none known 10.4 Hazardous decomposition products If stored and handled properly: none known . 10.5 Further information: Hazardous polymerization cannot occur. 11. Toxicological information 11.1 Information on toxicological effects 11.1.1 Acute toxicity Assessment: Based on the available data acute toxic effects are not expected after single oral exposure. Based on the available data acute toxic effects are not expected after single dermal exposure. Based on the available data acute toxic effects are not expected after short-term inhalative exposure. Product details: Route of exposure Result/Effect Species/Test system Source oral LD 50 : > 5000 mg/kg rat literature
dermal LD
50
: > 5000 mg/kg rabbit literature

Safety Data Sheet

Material: 60004600 HDK N20
HYDROPHILIC PYROGENIC SILICA

Version: 2.1 (US) Date of print: 06/25/20 15 Date of last alteration: 06/24/2015

Page: 5/8
by inhalation
(dust)
LC
50
: > 0.139 mg/l; 4 h
At the technically highest possible concentration no
mortality in animal test.
rat literature

11.1.2 Skin corrosion/irritation

Assessment:

Based on the available data a clinically relevant skin irritation hazard is not expected.

Product details:

Result/Effect Species/Test system Source
not irritating rabbit literature

11.1.3 Serious eye damage / eye irritation

Assessment:

Based on the available data a clinically relevant eye irritation hazard is not expected.

Product details:

Result/Effect Species/Test system Source
not irritating rabbit literature

11.1.4 Respiratory or skin sensitization

Assessment:

By handling the product for many years no damage to health was observed.

11.1.5 Germ cell mutagenicity

Assessment:

According to our present state of knowledge not mutagenic.

11.1.6 Carcinogenicity

Assessment:

Animal tests have not revealed any carcinogenic effects.

11.1.7 Reproductive toxicity

Assessment:

In animal experiments there have not been any indications of reproduction toxicity.

11.1.8 Specific target organ toxicity (single exposure)

Assessment:

For this endpoint no toxicological test data is available for the whole product.

11.1.9 Specific target organ toxicity (repeated exposure)

Assessment:

Changes in the lungs (inflammatory processes) observed in animal experiments after chronic inhalative exposure were reversible;
no indication of silicosis.

11.1.10 Aspiration hazard

Assessment:

For this endpoint no toxicological test data is available for the whole product.

11.1.11 Further toxicological information

No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by
NTP. No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.

Safety Data Sheet

Material: 60004600 HDK N20
HYDROPHILIC PYROGENIC SILICA

Version: 2.1 (US) Date of print: 06/25/20 15 Date of last alteration: 06/24/2015

Page: 6/8
Other information: By handling the product for many years no damage to health was observed.

12. Ecological information

12.1 Toxicity

Assessment:

No expected damaging effects to aquatic organisms. According to current knowledge adverse effects on water purification plants
are not expected.

Product details:

Result/Effect Species/Test system Source LC
50
: > 10000 mg/l zebra fish (Danio rerio) (96 h) literature
EC
50
: > 10000 mg/l Daphnia magna (24 h) literature

12.2 Persistence and degradability

Assessment:

The substance is degradable in abiotic processes.

12.3 Bioaccumulative potential

Assessment:

No adverse effects expected.

12.4 Mobility in soil

Assessment:

No adverse effects expected.

12.5 Other adverse effects

none known

12.6 Additional information

Insoluble in water.

13. Disposal considerations

13.1 Product disposal

Recommendation:
Material that cannot be used, reprocessed or recycled should be disposed of in accordance with Federal, State, and local
regulations at an approved facility. Depending on the regulations, waste treatment methods may include, e.g., landfill or
incineration.

13.2 Packaging disposal

Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.

14. Transport information

14.1 US DOT & CANADA TDG SURFACE

Valuation ……………………………………….. : Not regulated for transport

14.2 Transport by sea IMDG-Code

Valuation ……………………………………….. : Not regulated for transport

14.3 Air transport ICAO-TI/IATA-DGR

Valuation ……………………………………….. : Not regulated for transport

Safety Data Sheet

Material: 60004600 HDK N20
HYDROPHILIC PYROGENIC SILICA

Version: 2.1 (US) Date of print: 06/25/20 15 Date of last alteration: 06/24/2015

Page: 7/8
15. Regulatory information

15.1 U.S. Federal regulations

TSCA inventory status and TSCA information:
This material or its components are listed on or are in compliance with the requirements of the TSCA Chemical Substance
Inventory. This material is in compliance with TSCA under CAS Number 7631-86-9 (silica, amorphous).

TSCA 12(b) Export Notification:
This material does not contain any TSCA 12(b) regulated chemicals.

CERCLA Regulated Chemicals:
This material does not contain any CERCLA regulated chemicals.

SARA 302 EHS Chemicals:
This material does not contain any SARA extremely hazardous substances.

SARA 311/312 Hazard Class:
This product does not present any SARA 311/312 hazards.

SARA 313 Chemicals:
This material does not contain any SARA 313 chemicals above de minimus levels.

HAPS (Hazardous Air Pollutants):
This material does not contain any hazardous air pollutants.

15.2 U.S. State regulations

California Proposition 65 Carcinogens:
This material does not contain any chemicals known to the state of California to cause cancer.

California Proposition 65 Reproductive Toxins:
This material does not contain any chemicals known to the State of California to cause reproductive effects.

Massachusetts Substance List:
112945-52-5 Silica, amorphous, fumed

New Jersey Right-to-Know Hazardous Substance List:
112945-52-5 Silica, amorphous, fumed

Pennsylvania Right-to-Know Hazardous Substance List:
112945-52-5 Silica, amorphous, fumed

15.3 Canadian regulations

This product has been classified in accordance with the Hazard criteria of the CPR and the SDS contains all the information
required by the CPR.

WHMIS Hazard Classes:
None.

15.4 Details of international registration status

Relevant information about individual substance inventories, where available, is given below.

South Korea (Republic of Korea)…………….. : ECL (Existing Chemicals List):
This product is listed in, or complies with, the substance inventory.
Japan………………………………………………….. : ENCS (Handbook of Existing and New Chemical Substances):
This product is listed in, or complies with, the substance inventory.
Australia ……………………………………………… : AICS (Australian Inventory of Chemical Substances):
This product is listed in, or complies with, the substance inventory.
People’s Republic of China…………………….. : IECSC (Inventory of Existing Chemical Substances in China):
This product is listed in, or complies with, the substance inventory.
Canada……………………………………………….. : DSL (Domestic Substance List):
This product is listed in, or complies with, the substance inventory.
Philippines …………………………………………… : PICCS (Philippine Inventory of Chemicals and Chemical Substances):
This product is listed in, or complies with, the substance inventory.

Safety Data Sheet

Material: 60004600 HDK N20
HYDROPHILIC PYROGENIC SILICA

Version: 2.1 (US) Date of print: 06/25/20 15 Date of last alteration: 06/24/2015

Page: 8/8
United States of America (USA) ……………… : TSCA (Toxic Substance Control Act Chemical Substance Inventory):
This product is listed in, or complies with, the substance inventory.
European Economic Area (EEA) …………….. : REACH (Regulation (EC) No 1907/2006):
REACH registration number: 01-2119379499-16-0001
General note: the registration obligations for substances imported into the EEA or
manufactured within the EEA by the supplier mentioned in section 1 are fulfilled by
the said supplier. The registration obligations for substances imported into the EEA
by customers or other downstream users must be fulfilled by the latter.

16. Other information

16.1 Additional information:

This Safety Data Sheet (SDS) meets the requirements of the Federal OSHA Hazard Communication Standard (29 CFR
1910.1200). This product has been classified according to the hazard criteria of the Controlled Products Regulations (CPR) and
the SDS contains all of the information required by the CPR. This information relates to the specific material designated and may
not be valid for such material used in combination with any other materials or in any process. Such information is to the best of
our knowledge and belief accurate and reliable as of the date compiled. However, no representation, warranty or guarantee
expressed or implied, is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to
the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage
that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe
valid patents or as extending a license under valid patents. This SDS provides selected regulatory information on this product,
including its components. This is not intended to include all regulations. It is the responsibility of the user to know and comply with
all applicable rules, regulations and laws relating to the product being used.

Vertical lines in the left-hand margin indicate changes compared with the previous version.

All deliveries are subject to the WACKER SILICONES Health Care Policy, which is available at www.wacker.com.

16.2 Glossary of Terms:

ACGIH – American Conference of Governmental Industrial
Hygienists
DOT – Department of Transportation
hPa – Hectopascals
mPa*s – Milli Pascal-Seconds
OSHA – Occupational Safety and Health Administration
PEL – Permissible Exposure Limit
ppm – Parts per Million
SARA – Superfund Amendments and Reauthorization Act
STEL – Short Term Exposure Limit
TSCA – Toxic Substances Control Act
TWA – Time Weighted Average
WHMIS – Canadian Workplace Hazardous Materials
Identification System

Flash point determination methods………………………………….Common name
ASTM D56……………………………………………………………………….. Tagliabue (Tag) closed cup
ASTM D92, DIN 51376, ISO 2592 ………………………………………. Cleveland open cup
ASTM D93, DIN 51758, IS O 2719 ………………………………………. Pensky-Martens closed cup
ASTM D3278, DIN 55680, IS O 3679 …………………………………… Setaflash or Rapid closed cup
DIN 51755 ……………………………………………………………………….. Abel-Pensky closed cup

16.3 Conversion table:

Pressure:………………..: 1 hPa * 0.75 = 1 mm Hg = 1 torr; 1 bar = 1000 hPa
Viscosity: ………………..: 1 mPa*s = 1 centipoise (cP)

24F410-B_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… WEST SYSTEM

410 Microlight

Filler
APPLICABLE PRODUCT CODE S: ………………. 410, 410-2, 410-7 and 410-B
CHEMICAL FAMILY: ………………………………….. A blend of thermoplastic polymer microspheres and inorganic amorphous silicates.
INTENDED PRODUCT USES: ……………………… Thickening agent for liquid epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. 410-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 866-937-8797 or 989-684-7286 Non-transportation
www.westsystem.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 2
Eye damage/irritation, Category 2A
Combustible dust

Label Elements

Hazard Pictogram(s):

Signal Word:
WARNING

Hazard Statements:
H315 Causes skin irritation
H319 Causes serious eye irritation
May form combustible dust concentrations in the air

Precautionary Statements:
Prevention
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P332 + P313 If skin irritation occurs: Get medical attention/advice
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention/advice.
Keep away from all ignition sources including heat, sparks and open flame.
Prevent dust accumulations to minimize explosion hazard.

Other Hazards
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Amorphous sodium borosilicate 50815-87-7 30-60
Thermoplastic copolymer 25214-39-5 30-60
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 5-10
Isobutane 75-28-5 1-5
Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 1-5
Synthetic amorphous pyrogenic silica 112945-52-5 1-5

WEST SYSTEM

410 Microlight

Filler
Page 2 of 6 Last Revised: 03JAN22
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Excessive exposure may cause irritation and tearing.
RESPONSE: Flush with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician if symptoms develop
and persist.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: May cause skin irritation. RESPONSE: Wash with mild soap
and water. Consult a physician if effects occur and persist. No specific treatment is known or anticipated.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Excessive exposure may cause slight respiratory irritation.
RESPONSE: Remove to fresh air if symptoms develop and keep comfortable for breathing. Seek medical advice if symptoms develop and persist.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), water, or dry chemical. Fog or
mist is recommended if water is used. NON-SUITABLE: Avoid using high pressure media.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. May form combustible dust concentrations in the air. See Section 9 for
additional information. Combustion may result in the release of carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides,
formaldehyde, nitric acid and ammonia.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Dust may form an explosive mixture in the air, possibly resulting in a secondary explosion. Downwind personnel should be
evacuated.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Eliminate ignition sources. Use methods that avoid generating airborne
dust. Use a vacuum with high efficiency particulate air (HEPA) filtration is recommended. Do not create a dust cloud by brushing or sweeping, or
using compressed air.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Contain spilled product to the extent practical and feasible.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 0 F (-17 C) / 95 F (35 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Keep container tightly closed in a dry, well-
ventilated place. Do not store directly in the sun or in conditions exceeding 95 F (35 C). Keep away from sources of ignition or heat. Avoid storing
near incompatible materials identified in Section 10.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid dust formation. Avoid breathing dust. Wash after handling. Provide
appropriate exhaust ventilation at points of operation where dust can be generated. Avoid using compressed air. Dust may form explosive mixture
with air. Take precautionary measures against static discharges. Metal parts of mixing and processing equipment should be earthed/grounded.
Dust deposits should not be allowed to accumulate on surfaces.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields, or goggles if necessary.

SKIN PROTECTION GUIDELINES: ……………………………………………. Liquid-proof gloves (such as neoprene or nitrile) should be used to prevent
skin irritation. Barrier creams can be used effectively.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with particulate filter, such as a N95 or greater, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.

WEST SYSTEM

410 Microlight

Filler
Page 3 of 6 Last Revised: 03JAN22
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Wash thoroughly after handling. Do not eat, drink or smoke when handling this product. Generally speaking, working cleanly and following
basic precautionary measures will greatly minimize the exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LI MITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Amorphous sodium borosilicate 50815-87-7 Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable
Thermoplastic copolymer 25214-39-5 No data available.
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 No data available.
Isobutane 75-28-5 ACGIH TLV TWA 1000 ppm (central nervous
system)
NIOSH REL TWA 800 ppm; 1900 mg/m
3

Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 No data available.
Synthetic pyrogenic amorphous silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Powder, solid.
COLOR: ………………………………………………………………………………… Beige-tan.
ODOR: …………………………………………………………………………………… Slight.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 10.5
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. No data available
FLASH POINT: ……………………………………………………………………….. No data available
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. No data available
BULK DENSITY………………………………………………………………………. No data available
VAPOR DENSITY (air = 1) ……………………………………………………….. No data available
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. Largely insoluble.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available (mm
2
/s

@ 20

C)
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. Not applicable.
EXPLOSIVE PROPERTIES: ……………………………………………………… Dust may form explosive mixtures in air. Explosive properties of this mixture
have not been measured. One or more of the components of this mixture have been identified as having the potential to form an explosive mixture
with air when suspended as a dust cloud.
Kst VALUE: ……………………………………………………………………………. No data available
MAXIMUM EXPLOSION PRESSURE (Pmax) ……………………………… No data available
MINIMUM IGNITION ENERGY (MIE): …………………………………………. No data available
MAXIMUM EXPLOSION CONCENTRATION (MEC): ……………………. No data available
DUST EXPLOSION CLASSIFICATION: ……………………………………… No data available

10. STABILITY AND REACTIVITY

STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.

REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself.

INCOMPATIBILITIES: ……………………………………………………………… Strong oxidizing agents and acids. Contact with hydrofluoric acid will cause
the release of a toxic gas.

CONDITIONS TO AVOID: ………………………………………………………… Avoid settling dust collection and airborne dust formation. Avoid direct heat
or excessive sunlight.

DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides,
ammonia.

11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION

WEST SYSTEM

410 Microlight

Filler
Page 4 of 6 Last Revised: 03JAN22

Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Amorphous sodium borosilicate 50815-87-7 No data No data No data
Thermoplastic copolymer 25214-39-5 No data No data No data
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 >2000 mg/kg No data No data
Isobutane 75-28-5 No data No data No data
Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 2169 mg/kg No data No data
Synthetic pyrogenic amorphous silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria.

SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation. Category 2.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.

SKIN SENSITIZATION:…………………………………………………………….. Not classified. Does not meet criteria for skin sensitization.

REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Does not meet criteria for reproductive toxicity.

MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for mutagenicity.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity. Does not contain
components > 0.1% that are listed as a carcinogen by IARC, NTP or OSHA.

Synthetic amorphous silica: No evidence of carcinogenicity was observed in multiple animal species following repeated oral or inhalation exposure
to synthetic amorphous silica. Similarly, epidemiology studies show no evidence of carcinogenicity in workers who manufacture synthetic
amorphous silica.

May contain trace amounts of acrylonitrile at levels <0.005% by weight. Acrylonitrile is listed by IARC as a Group 2B carcinogen, by NTP as a reasonably anticipated human carcinogen, and is specifically regulated by OSHA as a carcinogen. STOT (Single Exposure): .................................................................. Not classified. Does not meet STOT SE criteria. STOT (Repeated Exposure): ............................................................. Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION : ...................................... None known. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated Estimate: Does not meet acute aquatic toxicity criteria. CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated Estimate: Does not meet chronic aquatic toxicity criteria. PERSISTANCE AND BIODEGRADABI LITY: ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION : ................................... Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification Information Amorphous sodium borosilicate 50815-87-7 No data available. Thermoplastic copolymer 25214-39-5 No data available. Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 No data available. Isobutane 75-28-5 No data available. Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 Acute Aquatic 3; Chronic Aquatic 3 Synthetic pyrogenic amorphous silica 112945-52-5 No data available. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. WEST SYSTEM 410 Microlight Filler Page 5 of 6 Last Revised: 03JAN22 Reclaim or reuse may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. ICAO/IATA UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. MARINE POLLUTANT: ....................................................................... Not applicable. IMDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. EmS Number: .................................................................................... Not applicable. MARINE POLLUTANT ........................................................................ Not applicable. 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS Data is not available for component CAS# 50815-87-7. South Korea KECI Data is not available for component CAS# 50815-87-7. China IECSC Data is not available for component CAS# 50815-87-7. Philippines PICCS Data is not available for component CAS# 50815-87-7. New Zealand NZIoC Data is not available for component CAS# 50815-87-7. US EPA TSCA Requirements: ........................................................... No data available. Canada WHMIS Confidential Business Information (CBI): .............. No data available. US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... Not regulated. Subject to Section 304 (RQ) ........................................................ Not regulated. Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2. Subject to Section 313 ................................................................ Not regulated. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. COMPONENT NAME /CAS NUMBER STATE CODE Amorphous silica 7631-86-9 or 112945-52-5 PA, NJ, MA Isobutane 75-28-5 PA, NJ, MA Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 PA, NJ Acrylonitrile WEST SYSTEM 410 Microlight Filler Page 6 of 6 Last Revised: 03JAN22 107-13-1 <0.005% PA, NJ, MA, 1 CA 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Approval date change. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 3, 2022 SUPERSEDES DATE: ........................................................................ December 9, 2019 SDS VERSION: .................................................................................. 410-2022a OTHER HAZARD INFORMATION AND RATING SYSTEMS : HMIS RATING NFPA 704 CODES HEALTH: 1 FLAMMABILITY: 2 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 1 0 2

24F140-B_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… WEST SYSTEM

410 Microlight

Filler
APPLICABLE PRODUCT CODE S: ………………. 410, 410-2, 410-7 and 410-B
CHEMICAL FAMILY: ………………………………….. A blend of thermoplastic polymer microspheres and inorganic amorphous silicates.
INTENDED PRODUCT USES: ……………………… Thickening agent for liquid epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. 410-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 866-937-8797 or 989-684-7286 Non-transportation
www.westsystem.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 2
Eye damage/irritation, Category 2A
Combustible dust

Label Elements

Hazard Pictogram(s):

Signal Word:
WARNING

Hazard Statements:
H315 Causes skin irritation
H319 Causes serious eye irritation
May form combustible dust concentrations in the air

Precautionary Statements:
Prevention
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P332 + P313 If skin irritation occurs: Get medical attention/advice
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention/advice.
Keep away from all ignition sources including heat, sparks and open flame.
Prevent dust accumulations to minimize explosion hazard.

Other Hazards
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Amorphous sodium borosilicate 50815-87-7 30-60
Thermoplastic copolymer 25214-39-5 30-60
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 5-10
Isobutane 75-28-5 1-5
Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 1-5
Synthetic amorphous pyrogenic silica 112945-52-5 1-5

WEST SYSTEM

410 Microlight

Filler
Page 2 of 6 Last Revised: 03JAN22
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Excessive exposure may cause irritation and tearing.
RESPONSE: Flush with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician if symptoms develop
and persist.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: May cause skin irritation. RESPONSE: Wash with mild soap
and water. Consult a physician if effects occur and persist. No specific treatment is known or anticipated.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Excessive exposure may cause slight respiratory irritation.
RESPONSE: Remove to fresh air if symptoms develop and keep comfortable for breathing. Seek medical advice if symptoms develop and persist.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), water, or dry chemical. Fog or
mist is recommended if water is used. NON-SUITABLE: Avoid using high pressure media.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. May form combustible dust concentrations in the air. See Section 9 for
additional information. Combustion may result in the release of carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides,
formaldehyde, nitric acid and ammonia.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Dust may form an explosive mixture in the air, possibly resulting in a secondary explosion. Downwind personnel should be
evacuated.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Eliminate ignition sources. Use methods that avoid generating airborne
dust. Use a vacuum with high efficiency particulate air (HEPA) filtration is recommended. Do not create a dust cloud by brushing or sweeping, or
using compressed air.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Contain spilled product to the extent practical and feasible.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 0 F (-17 C) / 95 F (35 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Keep container tightly closed in a dry, well-
ventilated place. Do not store directly in the sun or in conditions exceeding 95 F (35 C). Keep away from sources of ignition or heat. Avoid storing
near incompatible materials identified in Section 10.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid dust formation. Avoid breathing dust. Wash after handling. Provide
appropriate exhaust ventilation at points of operation where dust can be generated. Avoid using compressed air. Dust may form explosive mixture
with air. Take precautionary measures against static discharges. Metal parts of mixing and processing equipment should be earthed/grounded.
Dust deposits should not be allowed to accumulate on surfaces.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields, or goggles if necessary.

SKIN PROTECTION GUIDELINES: ……………………………………………. Liquid-proof gloves (such as neoprene or nitrile) should be used to prevent
skin irritation. Barrier creams can be used effectively.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with particulate filter, such as a N95 or greater, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.

WEST SYSTEM

410 Microlight

Filler
Page 3 of 6 Last Revised: 03JAN22
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Wash thoroughly after handling. Do not eat, drink or smoke when handling this product. Generally speaking, working cleanly and following
basic precautionary measures will greatly minimize the exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LI MITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Amorphous sodium borosilicate 50815-87-7 Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable
Thermoplastic copolymer 25214-39-5 No data available.
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 No data available.
Isobutane 75-28-5 ACGIH TLV TWA 1000 ppm (central nervous
system)
NIOSH REL TWA 800 ppm; 1900 mg/m
3

Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 No data available.
Synthetic pyrogenic amorphous silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Powder, solid.
COLOR: ………………………………………………………………………………… Beige-tan.
ODOR: …………………………………………………………………………………… Slight.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 10.5
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. No data available
FLASH POINT: ……………………………………………………………………….. No data available
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. No data available
BULK DENSITY………………………………………………………………………. No data available
VAPOR DENSITY (air = 1) ……………………………………………………….. No data available
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. Largely insoluble.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available (mm
2
/s

@ 20

C)
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. Not applicable.
EXPLOSIVE PROPERTIES: ……………………………………………………… Dust may form explosive mixtures in air. Explosive properties of this mixture
have not been measured. One or more of the components of this mixture have been identified as having the potential to form an explosive mixture
with air when suspended as a dust cloud.
Kst VALUE: ……………………………………………………………………………. No data available
MAXIMUM EXPLOSION PRESSURE (Pmax) ……………………………… No data available
MINIMUM IGNITION ENERGY (MIE): …………………………………………. No data available
MAXIMUM EXPLOSION CONCENTRATION (MEC): ……………………. No data available
DUST EXPLOSION CLASSIFICATION: ……………………………………… No data available

10. STABILITY AND REACTIVITY

STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.

REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself.

INCOMPATIBILITIES: ……………………………………………………………… Strong oxidizing agents and acids. Contact with hydrofluoric acid will cause
the release of a toxic gas.

CONDITIONS TO AVOID: ………………………………………………………… Avoid settling dust collection and airborne dust formation. Avoid direct heat
or excessive sunlight.

DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides,
ammonia.

11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION

WEST SYSTEM

410 Microlight

Filler
Page 4 of 6 Last Revised: 03JAN22

Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Amorphous sodium borosilicate 50815-87-7 No data No data No data
Thermoplastic copolymer 25214-39-5 No data No data No data
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 >2000 mg/kg No data No data
Isobutane 75-28-5 No data No data No data
Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 2169 mg/kg No data No data
Synthetic pyrogenic amorphous silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria.

SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation. Category 2.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.

SKIN SENSITIZATION:…………………………………………………………….. Not classified. Does not meet criteria for skin sensitization.

REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Does not meet criteria for reproductive toxicity.

MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for mutagenicity.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity. Does not contain
components > 0.1% that are listed as a carcinogen by IARC, NTP or OSHA.

Synthetic amorphous silica: No evidence of carcinogenicity was observed in multiple animal species following repeated oral or inhalation exposure
to synthetic amorphous silica. Similarly, epidemiology studies show no evidence of carcinogenicity in workers who manufacture synthetic
amorphous silica.

May contain trace amounts of acrylonitrile at levels <0.005% by weight. Acrylonitrile is listed by IARC as a Group 2B carcinogen, by NTP as a reasonably anticipated human carcinogen, and is specifically regulated by OSHA as a carcinogen. STOT (Single Exposure): .................................................................. Not classified. Does not meet STOT SE criteria. STOT (Repeated Exposure): ............................................................. Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION : ...................................... None known. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated Estimate: Does not meet acute aquatic toxicity criteria. CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated Estimate: Does not meet chronic aquatic toxicity criteria. PERSISTANCE AND BIODEGRADABI LITY: ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION : ................................... Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification Information Amorphous sodium borosilicate 50815-87-7 No data available. Thermoplastic copolymer 25214-39-5 No data available. Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 No data available. Isobutane 75-28-5 No data available. Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 Acute Aquatic 3; Chronic Aquatic 3 Synthetic pyrogenic amorphous silica 112945-52-5 No data available. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. WEST SYSTEM 410 Microlight Filler Page 5 of 6 Last Revised: 03JAN22 Reclaim or reuse may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. ICAO/IATA UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. MARINE POLLUTANT: ....................................................................... Not applicable. IMDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. EmS Number: .................................................................................... Not applicable. MARINE POLLUTANT ........................................................................ Not applicable. 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS Data is not available for component CAS# 50815-87-7. South Korea KECI Data is not available for component CAS# 50815-87-7. China IECSC Data is not available for component CAS# 50815-87-7. Philippines PICCS Data is not available for component CAS# 50815-87-7. New Zealand NZIoC Data is not available for component CAS# 50815-87-7. US EPA TSCA Requirements: ........................................................... No data available. Canada WHMIS Confidential Business Information (CBI): .............. No data available. US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... Not regulated. Subject to Section 304 (RQ) ........................................................ Not regulated. Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2. Subject to Section 313 ................................................................ Not regulated. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. COMPONENT NAME /CAS NUMBER STATE CODE Amorphous silica 7631-86-9 or 112945-52-5 PA, NJ, MA Isobutane 75-28-5 PA, NJ, MA Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 PA, NJ Acrylonitrile WEST SYSTEM 410 Microlight Filler Page 6 of 6 Last Revised: 03JAN22 107-13-1 <0.005% PA, NJ, MA, 1 CA 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Approval date change. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 3, 2022 SUPERSEDES DATE: ........................................................................ December 9, 2019 SDS VERSION: .................................................................................. 410-2022a OTHER HAZARD INFORMATION AND RATING SYSTEMS : HMIS RATING NFPA 704 CODES HEALTH: 1 FLAMMABILITY: 2 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 1 0 2

24COTR90_SDS.pdf

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 1 / 19
SECTION 1. IDENTIFICATION
Product name

: TIOXIDE TR93

Manufacturer or supplier’s details
Company name of supplier : Venator Americas LLC
Address : 10001 Woodloch Forest Drive
The Woodlands,
TX 77380
United States of America (USA)
Telephone : (001) 844 831 6720
Telefax : (001) 281 465 6731

E-mail address of person
responsible for the SDS
: msds@venatorcorp.com

Emergency telephone number : USA & Canada: +1-800-424-9300 Other Americas: +1-703-
741-5970 [CCN 820025]

Recommended use of the chemical and restrictions on use
Recommended use

: Pigment
Opacifying agent

Restrictions on use

: Do not use for cosmetics, food additives, drug additives, feed
additives or permanent implant applications., Due to lack of
related experience or data, the supplier cannot approve this
use.

SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with 29 CFR 1910.1200
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Other hazards
Handling and/or processing of this material may generate a dust which can cause mechanical
irritation of the eyes, skin, nose and throat.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture

: Substance
Chemical nature

: inorganic

Hazardous components
Chemical name CAS-No. Concentration (% w/w)

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 2 / 19
titanium dioxide 13463-67-7 90 – 100
aluminium oxide 1344-28-1 1 – 5
The specific chemical identity and/or exact percentage (concentration) of composition may be
withheld as a trade secret.

SECTION 4. FIRST AID MEASURES
General advice

: Do not leave the victim unattended.
Treat symptomatically.

If inhaled

: Remove person to fresh air. If signs/symptoms continue, get
medical attention.
If unconscious, place in recovery position and seek medical
advice.

In case of skin contact

: Wash off with soap and water.

In case of eye contact

: Rinse immediately with plenty of water, also under the eyelids.
Remove contact lenses.
Protect unharmed eye.
If eye irritation persists, consult a specialist.

If swallowed

: Rinse mouth with water.
If conscious, make the victim drink the following:
Give small amounts of water to drink.
Do not induce vomiting without medical advice.
Consult a physician if necessary.

Most important symptoms
and effects, both acute and
delayed

: Dust contact with the eyes can lead to mechanical irritation.
Inhalation of dust may cause shortness of breath, tightness of
the chest, a sore throat and cough.
The product is not irritant but as with all fine powders can
absorb moisture and natural oils from the surface of the skin
during prolonged exposure.
Individuals with sensitive skin may experience skin drying on
prolonged or repeated exposure.

Protection of first-aiders

: No action shall be taken involving any personal risk or without
suitable training.

Notes to physician

: No specific measures identified.

SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media

: Product is compatible with standard fire-fighting agents.

Unsuitable extinguishing
media

: High volume water jet

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 3 / 19
Specific hazards during
firefighting

: No information available.

Hazardous combustion
products

: No hazardous combustion products are known

Specific extinguishing
methods

: Cool containers/tanks with water spray.

Further information : Standard procedure for chemical fires.
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
No action shall be taken involving any personal risk or without
suitable training.

Special protective equipment
for firefighters

: Wear self-contained breathing apparatus for firefighting if
necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures

: No action shall be taken involving any personal risk or without
suitable training.
Prevent unauthorised persons entering the zone.
Avoid dust formation.
Remove all sources of ignition.
Ventilate the area.
Avoid breathing dust.
Keep people away from and upwind of spill/leak.
Only qualified personnel equipped with suitable protective
equipment may intervene.
Never return spills in original containers for re-use.
Treat recovered material as described in the section “Disposal
considerations”.
For disposal considerations see section 13.
The danger areas must be delimited and identified using
relevant warning and safety signs.

Environmental precautions

: Try to prevent the material from entering drains or water
courses.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

: Clean-up methods – small spillage
Clean up promptly by sweeping or vacuum.
Keep in suitable, closed containers for disposal.

Clean-up methods – large spillage
Approach release from upwind.
Clean up promptly by sweeping or vacuum.
Avoid creating dusty conditions and prevent wind dispersal.
Keep in suitable, closed containers for disposal.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 4 / 19
SECTION 7. HANDLING AND STORAGE
Technical measures

: Ensure that eyewash stations and safety showers are close to
the workstation location.

Local/Total ventilation

: Use only with adequate ventilation.

Advice on protection against
fire and explosion

: Normal measures for preventive fire protection.

Advice on safe handling : For personal protection see section 8.
Avoid creating dust.
Smoking, eating and drinking should be prohibited in the
application area.

Manual handling guidelines should be adhered to when
handling sacks.
In the manufacture of titanium dioxide, product is packaged at
temperatures of approximately 100 to 120 C (212 to 248
Fahrenheit). When pigment is shipped shortly after
manufacture, it may stay hot for a very long time depending
on ambient temperatures and inventory storage practices.
Due to the potential of elevated pigment temperature, caution
should be used while handling pigment and in solvent
applications. Each work environment must be assessed to
determine hazards.
Emptying of flexible intermediate bulk containers (FIBC’s) can
generate static electricity. Customers using FIBC’s should
consult leaflet “Tiotainer Handling Guidelines”.
Empty FIBC’s by gravity only (do not empty pneumatically).
Remove all wrapping prior to emptying FIBC’s.
In all cases, the protective cover or wrapping should remain in
place during storage and only be removed immediately prior
to use.
Care should be taken to avoid moisture, particularly with a
partly used pallet of material.
When transferring from one container to another apply
earthing measures and use conductive hose material.

Conditions for safe storage : Store in accordance with the particular national regulations.
Keep only in the original container in a cool, well ventilated place
away from oxidizing agents.
Keep in a dry place.
Keep cool. Protect from sunlight.
Eliminate all ignition sources if safe to do so.
Keep container closed when not in use.
Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Use appropriate container to avoid environmental contamination.
When using standard pallets, those containing paper or plastics bags
can be stacked to a maximum of 2 high.

Materials to avoid : No materials to be especially mentioned.

Further information on
storage stability
: Keep in a dry place.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 5 / 19

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
titanium dioxide 13463-67-7 TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA 10 mg/m3
(Titanium dioxide)
ACGIH
aluminium oxide 1344-28-1 TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA
(respirable
fraction)
5 mg/m3 OSHA Z-1
TWA
(Respirable
fraction)
1 mg/m3
(Aluminium)
ACGIH
Engineering measures : Ensure adequate ventilation, especially in confined areas.
Use engineering controls to keep exposures below the OEL
or DNEL

Personal protective equipment
Respiratory protection

: General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.

Filter type

: P2 filter

Hand protection
Directive : Use gloves approved to relevant standards e.g. EN 374
(Europe), F739 (US).

Eye protection

: Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary
to avoid exposure to liquid splashes, mists or dusts.
Ensure that eyewash stations and safety showers are close
to the workstation location.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 6 / 19
Skin and body protection

: Personal protective equipment for the body should be
selected based on the task being performed and the risks
involved and should be approved by a specialist before
handling this product.

Protective measures

: Wear suitable protective equipment.

Hygiene measures

: Handle in accordance with good industrial hygiene and safety
practice.
Smoking, eating and drinking should be prohibited in the
application area.
Wash face, hands and any exposed skin thoroughly after
handling.
Remove contaminated clothing and protective equipment
before entering eating areas.
Barrier creams may help to protect the exposed areas of
skin, they should however not be applied once exposure has
occurred.
Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance

: powder

Colour

: white

Odour

: slight
Odour Threshold

: No data is available on the product itself.

pH

: 6.5 – 9
Concentration: 100 g/l

Melting point

: ca. 1,800 C

Boiling point/boiling range

: Not applicable
Flash point : Not applicable

Evaporation rate : No data is available on the product itself.

Flammability (solid, gas) : No data is available on the product itself.

Flammability (liquids) : No data is available on the product itself.

Burning rate : Will not burn
Not combustible.

Upper explosion limit / Upper
flammability limit

: No data is available on the product itself.

Lower explosion limit / Lower
flammability limit
: No data is available on the product itself.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 7 / 19

Vapour pressure : No data is available on the product itself.

Relative vapour density : No data is available on the product itself.

Relative density : 4.05 (20 C)

Density : 4.05 g/cm3 (20 C)
Skeletal density

Solubility(ies)
Water solubility : Not applicable

Solubility in other solvents : Solvent: Methanol
Description: insoluble

Partition coefficient: n-
octanol/water
: No data is available on the product itself.

Auto-ignition temperature : No data is available on the product itself.

Thermal decomposition : No data is available on the product itself.

Self-Accelerating
decomposition temperature
(SADT)

: No data is available on the product itself.

Viscosity

: No data is available on the product itself.

Explosive properties

: No data is available on the product itself.

Oxidizing properties

: None.

Impact sensitivity

: Not impact sensitive.

Molecular weight

: No data available
Particle size

: No data is available on the product itself.

SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : No decomposition if stored and applied as directed.
Possibility of hazardous
reactions
: Stable under recommended storage conditions.
No hazards to be specially mentioned.

Conditions to avoid : No data available

Incompatible materials : None known.

Hazardous decomposition
products
: At high temperature, decomposition products could include
trace of alpha-ethyl acrolein and formaldehyde.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 8 / 19
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of
exposure
: No data is available on the product itself.

Acute toxicity
Components:
titanium dioxide:
Acute oral
toxicityComponents
: LD50 (Rat, female): > 5,000 mg/kg
Method: OECD Test Guideline 425
Assessment: The substance or mixture has no acute oral
toxicity

aluminium oxide:
Acute oral
toxicityComponents
: LD50 (Rat, male and female): > 10,000 mg/kg
Method: OECD Test Guideline 401

Components:
titanium dioxide:
Acute inhalation toxicity : LC50 (Rat, male and female): 3.43 – 5.09 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Assessment: The substance or mixture has no acute
inhalation toxicity

aluminium oxide:
Acute inhalation toxicity : LC50 (Rat, male and female): > 2.3 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Assessment: The substance or mixture has no acute
inhalation toxicity

Acute dermal toxicity –
Product
: Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute toxicity (other routes of
administration)
: No data available

Skin corrosion/irritation
Components:
titanium dioxide:
Species: Rabbit
Assessment: No skin irritation
Method: OECD Test Guideline 404
Result: Normally reversible injuries

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 9 / 19
aluminium oxide:
Species: Rabbit
Assessment: No skin irritation
Method: OECD Test Guideline 404
Result: No skin irritation

Serious eye damage/eye irritation
Components:
titanium dioxide:
Species: Rabbit
Result: Normally reversible injuries
Assessment: No eye irritation
Method: OECD Test Guideline 405

aluminium oxide:
Species: Rabbit
Result: No eye irritation
Assessment: No eye irritation
Method: OECD Test Guideline 405

Respiratory or skin sensitisation
Components:
titanium dioxide:
Test Type: Local lymph node assay (LLNA)
Exposure routes: Skin
Species: Mouse
Assessment: Does not cause skin sensitisation.
Method: OECD Test Guideline 429
Result: Does not cause skin sensitisation.

Exposure routes: Skin
Species: Guinea pig
Assessment: Does not cause skin sensitisation.
Method: OECD Test Guideline 406
Result: Does not cause skin sensitisation.

aluminium oxide:
Exposure routes: Skin
Species: Guinea pig
Result: Does not cause skin sensitisation.

Components:
titanium dioxide:
Assessment: No skin irritation, No eye irritation
Does not cause skin sensitisation., Does not cause respiratory
sensitisation.

Germ cell mutagenicity
Components:
titanium dioxide:
Genotoxicity in vitro : Test Type: Ames test
Concentration: 100 – 200 ug/plate

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 10 / 19
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative

Test Type: In vitro mammalian cell gene mutation test
Concentration: 31 – 500 g/L
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative

Test Type: Chromosome aberration test in vitro
Concentration: 125 – 2500 g/L
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: negative

Components:
titanium dioxide:
Genotoxicity in vivo : Test Type: Micronucleus test
Species: Mouse (males)
Application Route: Inhalation
Exposure time: 5 consecutive days
Dose: 0.8, 7.2, and 28.5 mg/m
Method: OECD Test Guideline 474
Result: negative

Test Type: Micronucleus test
Species: Rat (male and female)
Application Route: Oral
Exposure time: once
Dose: 500, 1000, and 2000 mg/kg bw
Method: OECD Test Guideline 474
Result: negative

Components:
titanium dioxide:
Germ cell mutagenicity-
Assessment
: Tests on bacterial or mammalian cell cultures did not show
mutagenic effects., Animal testing did not show any mutagenic
effects.

Germ cell mutagenicity-
Assessment
: No data available

Carcinogenicity
Components:
titanium dioxide:
Species: Rat, (male and female)
Application Route: Oral
Exposure time: 103 weeks
Dose: 0, 25000, 50000 ppm
Frequency of Treatment: 7 days/week
NOAEL: > 50.000 ppm

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 11 / 19
Method: No information available.
Remarks: Titanium Dioxide: based on the results of chronic inhalation studies (with positive
results only in a single species – rat), IARC has concluded that: “There is inadequate evidence
in humans for the carcinogenicity of titanium dioxide. ” but that : “There is sufficient evidence in
experimental animals for carcinogenicity of titanium dioxide”. IARCs overall evaluation was that
“titanium dioxide is possibly carcinogenic to humans (Group 2B).”

Venator has examined all of the available animal carcinogenicity and mechanistic data together
with workplace epidemiology data for titanium dioxide and concludes that the weight of scientific
evidence indicates that there is no causative link between titanium dioxide exposure and cancer
risk in humans and that workplace exposures in compliance with applicable exposure standards
will not result in lung cancer or chronic respiratory diseases in humans.

Components:
titanium dioxide:
Carcinogenicity –
Assessment
: Not classifiable as a human carcinogen.

IARC

Group 2B: Possibly carcinogenic to humans

titanium dioxide

ACGIH

No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Components:
aluminium oxide:
Effects on fertility : Species: Rat, male and female
Application Route: Oral
Dose: 1000 milligram per kilogram
Method: OECD Test Guideline 422
Result: Animal testing did not show any effects on fertility.

Components:
titanium dioxide:
Effects on foetal
development
: Species: Rat, male and female
Application Route: Oral
Dose: 100, 300, and 1000 mg/kg bw/
Duration of Single Treatment: 20 d
Frequency of Treatment: 7 days/week
General Toxicity Maternal: No observed adverse effect level:
1,000 mg/kg body weight
Developmental Toxicity: No observed adverse effect level:
1,000 mg/kg body weight
Method: OECD Test Guideline 414

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 12 / 19
Result: No adverse effects

aluminium oxide:
Species: Rat
Application Route: Oral
General Toxicity Maternal: No observed adverse effect level:
266 mg/kg body weight
Method: OECD Test Guideline 414
Result: No teratogenic effects

Components:
titanium dioxide:
Reproductive toxicity –
Assessment
: No evidence of adverse effects on sexual function and fertility,
or on development, based on animal experiments.

STOT – single exposure
No data available

STOT – repeated exposure
No data available

Repeated dose toxicity
Components:
titanium dioxide:
Species: Rat, male and female
: 3500 mg/m3
Application Route: Ingestion
Test atmosphere: dust/mist
Exposure time: 2 yr
Number of exposures: 5 d
Method: Chronic toxicity

Species: Rat, male and female
: 10 – 50 mg/m3
Application Route: Inhalation
Exposure time: 2 yr
Number of exposures: 6 hours/day, 5 days/week
Method: Chronic toxicity

Components:
titanium dioxide:
Repeated dose toxicity –
Assessment
: No skin irritation, No eye irritation
No adverse effect has been observed in chronic toxicity tests.

Aspiration toxicity
No data available

Experience with human exposure
General Information: No data available

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 13 / 19

Inhalation: No data available

Skin contact: No data available

Eye contact: No data available

Ingestion: No data available

Toxicology, Metabolism, Distribution
No data available

Neurological effects
No data available

Further information
Product:
Remarks: No data available

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
titanium dioxide:
Toxicity to fish

: LC50 (Cyprinodon variegatus (sheepshead minnow)): >
10,000 mg/l
Exposure time: 96 h
Test Type: semi-static test
Test substance: Marine water
Method: OECD Test Guideline 203

aluminium oxide:
Toxicity to fish

: LC50 (Fish): > 50 mg/l
Exposure time: 96 h
Test Type: static test
Test substance: Fresh water

Components:
aluminium oxide:
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 100 mg/l
Exposure time: 48 h

Components:

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 14 / 19
aluminium oxide:
Toxicity to algae : IC50 (Selenastrum capricornutum (green algae)): > 100 mg/l
Exposure time: 72 h

M-Factor (Acute aquatic
toxicity)
: No data available

Toxicity to fish (Chronic
toxicity)
: No data available

Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
: No data available

M-Factor (Chronic aquatic
toxicity)
: No data available

Toxicity to microorganisms : No data available

Toxicity to soil dwelling
organisms
: No data available

Components:
titanium dioxide:
Plant toxicity : NOEC: 100,000 mg/kg
Exposure time: 480 h

Components:
titanium dioxide:
Sediment toxicity : (Gammarus pulex (Amphipod)): > 100000 mg/kgsedimentdw
Study: Acute
Test Type: semi-static test
Water: Fresh water
Exposure duration: 28 d
Method: ASTM Method, other

(Gammarus pulex (Amphipod)): 100000 mg/kgsedimentdw
Study: Chronic
Test Type: semi-static test
Water: Fresh water
Exposure duration: 28 d
Method: ASTM Method, other

(Gammarus pulex (Amphipod)): 14989 mg/kgsedimentdw
Study: Acute
Test Type: semi-static test
Water: Marine water
Exposure duration: 10 d

Components:
titanium dioxide:
Toxicity to terrestrial
organisms
: NOEC: 10,000 mg/kg
Exposure time: 672 h

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 15 / 19
Ecotoxicology Assessment
Components:
aluminium oxide:
Acute aquatic toxicity : This product has no known ecotoxicological effects.

Components:
aluminium oxide:
Chronic aquatic toxicity : This product has no known ecotoxicological effects.

Toxicity Data on Soil : No data available

Other organisms relevant to
the environment
: No data available

Persistence and degradability
Biodegradability – Product : Remarks: The methods for determining biodegradability are
not applicable to inorganic substances.

Biochemical Oxygen
Demand (BOD)

: No data available

Chemical Oxygen Demand
(COD)
: No data available

BOD/COD : No data available

ThOD : No data available

BOD/ThOD : No data available

Dissolved organic carbon
(DOC)
: No data available

Physico-chemical
removability
: No data available

Stability in water : No data available

Photodegradation : No data available

Impact on Sewage
Treatment
: No data available

Bioaccumulative potential
Components:
titanium dioxide:
Bioaccumulation : Species: Oncorhynchus mykiss (rainbow trout)
Bioconcentration factor (BCF): 19 – 352
Exposure time: 14 d
Test substance: Fresh water
Method: semi-static test
Remarks: Does not bioaccumulate.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 16 / 19

Partition coefficient: n-
octanol/water

: No data available

Mobility in soil
Mobility : No data available

Components:
titanium dioxide:
Distribution among
environmental compartments
: Remarks: No data available

Stability in soil : No data available

Other adverse effects
Environmental fate and
pathways
: No data available

Results of PBT and vPvB
assessment
: No data available

Endocrine disrupting
potential
: No data available

Adsorbed organic bound
halogens (AOX)
: No data available

Hazardous to the ozone layer
Ozone-Depletion Potential

: Regulation: 40 CFR Protection of Environment; Part 82
Protection of Stratospheric Ozone – CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was
manufactured with a Class I or Class II ODS as defined by the
U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A +
B).

Additional ecological
information – Product
: No data available

Global warming potential
(GWP)
: No data available

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
This material and its container must be disposed of in a safe
way.
In accordance with local and national regulations.
Dispose of wastes in an approved waste disposal facility.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 17 / 19
If recycling is not practicable, dispose of in compliance with
local regulations.

Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulations
IATA
Not regulated as dangerous goods
IMDG
Not regulated as dangerous goods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
DOT Classification
Not regulated as dangerous goods

SECTION 15. REGULATORY INFORMATION
EPCRA – Emergency Planning and Community Right -to-Know Act

SARA 311/312 Hazards

: No SARA Hazards

SARA 313

: This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).

California Prop. 65
Titanium dioxide (airborne, unbound particles of respirable size) is known to the state of California
to cause cancer. This listing does not cover titanium dioxide when it remains bound within a
product matrix.
WARNING: This product can expose you to chemicals including titanium dioxide, which is/are
known to the State of California to cause cancer. For more information go to
www.P65Warnings.ca.gov.
The components of this product are reported in the following inventories:
CH INV : On the inventory, or in compliance with the inventory

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 18 / 19
DSL : All components of this product are on the Canadian DSL
AICS : On the inventory, or in compliance with the inventory
NZIoC : On the inventory, or in compliance with the inventory
ENCS : On the inventory, or in compliance with the inventory
KECI : On the inventory, or in compliance with the inventory
PICCS : On the inventory, or in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory
TCSI : On the inventory, or in compliance with the inventory
TSCA : On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA
(USA)

TSCA – 5(a) Significant New Use Rule List of Chemicals
No substances are subject to a Significant New Use Rule.

US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707,
Subpt D)
No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS IV:

HMIS ratings are based on a 0-4 rating
scale, with 0 representing minimal
hazards or risks, and 4 representing
significant hazards or risks. The “*”
represents a chronic hazard, while the “/”
represents the absence of a chronic
hazard.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as
a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only to
the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
Sources of key data used to
compile the Safety Data
Sheet
: Information taken from reference works and the literature.,
Information derived from practical experience.

Flammability

Health

Instability

1 0

Special hazard.
FLAMMABILITY
0
PHYSICAL HAZARD
HEALTH
0

1
0

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 19 / 19
Revision Date

: 03/14/2018
ACGIH : USA. ACGIH Threshold Limit Values (TLV)
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) – Table Z-1
Limits for Air Contaminants
ACGIH / TWA : 8-hour, time-weighted average
OSHA Z-1 / TWA : 8-hour time weighted average
The information and recommendations in this publication are to the best of our knowledge,
information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE
CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE
APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE
SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE
CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE
THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are
dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and
behaviour should be determined by the user and made known to handlers, processors and end
users.

The trademarks above are the property of Venator Materials PLC or an affiliate thereof.

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED VENATOR EMPLOYEE IS
AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR VENATOR
PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN
INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.

24CALSULPH_SDS.pdf

Safety Data Sheet
PMC Revision date:
January 1, 2023
1
1. IDENTIFICATION
Product Name: PMC
Synonyms: Gypsum, Calcium Sulfate Dihydrate ( CaSO
4 2H2O) SP, SPT, CWS, LP#2 Manufacturer: Performance Minerals Corp
10220 Wicker Ave Ste 4
Saint John, IN 46373
www.performancemineralscorp.com
Telephone Number: 1-800-847-3637
2.HAZARD IDENTIFICATION
Warning
May cause respiratory irritation
Prolonged inhalation of airborne dust can produce scar tissue in the lungs. The condition may not be
reversible.
Handling and Storage: Use general room or local exhaust ventilation. Wear MSHA/NIOSH approved dust
mask where dust levels exceed the threshold limit value (TLV) while handling the product. This product
is for manufacturing purposes only.
Potential Health Effects:
Inhalation (acute): Exposure to dust generated during the handling or use of the product may
cause temporary irritation to eyes, skin, nose, throat, and upper respiratory
tract. Persons subjected to large amounts of this dust will be forced to leave
area because of nuisance conditions such as coughing, sneezing, and nasal
irritation. Labored breathing may occur after excessive inhalation. If
respiratory symptoms persist, consult a physician.

Safety Data Sheet

PMC Revision date:
January 1, 2020

2

Inhalation (chronic): Exposures to respirable crystalline silica are not expected during the normal
use of this product. Prolonged and repeated exposure to airborne free
respirable crystalline silica can result in lung disease (i.e., silicosis) and/or
lung cancer. The development of silicosis may increase the risks of additional
health effects. The risk of developing silicosis is dependent upon the
exposure intensity and duration.

Eye Contact: Dust can cause temporary mechanical irritation of eyes. If burning, redness,
itching, pain or other symptoms persist or develop, consult a physician.

Skin Contact: None known

Ingestion: None known

3. COMPOSITION
Chemical Name % by weight CAS#
Gypsum >95 13397-24-5
Crystalline Silica .01-1 14808-60-7

4. FIRST AID MEASURES
Inhalation: Remove to fresh air. Leave the area of exposure and remain away until coughing
and other symptoms subside. Other measures are usually not necessary,
however if conditions warrant, contact a physician.

Eyes: In case of contact, do not rub or scratch eyes. To prevent mechanical irritation,
flush thoroughly with water for 15 minutes. If irritation persists, consult a
physician.

Skin: Wash with mild soap and water. If irritation persists, consult a physician.

Ingestion: This product is not intended to be ingested or eaten. If gastric disturbance
occurs, contact a physician.

Most Important Symptoms: Eye and respiratory irritation due to exposure to dust.

Immediate Medical Attention
/Special Treatment: No immediate medical attention anticipated. Treatment should
be directed at the control of symptoms and the clinical condition.

5. FIRE FIGHTING MEASURES
Extinguishing Media: Water or use extinguishing media appropriate for surrounding fire.

Specific Hazards: None known

Safety Data Sheet

PMC Revision date:
January 1, 2020

3

Protective equipment/
Precautions: Wear appropriate personal protective equipment. See Section 8

6. ACCIDENTAL RELEASE MEASURES
Containment: No special precautions. Wear appropriate personal protective equipment. See
Section 8

Clean- up: Use normal clean up procedures. No special precautions.

Disposal: Follow all local, state, provincial and federal regulations. Prevent discharge of
large releases directly into sewers or surface waters.

7. HANDLING AND STORAGE
Safe Handling: Avoid dust contact with eyes and skin. Wear the appropriate eye and skin protection against dust (See section 8). Minimize dust generation and accumulation. Avoid breathing dust.

Safe Storage: Store in a cool, dry, ventilated area away from sources of heat, moisture and
incompatibilities (See section 10).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
WT% TLV (mg/m3) PEL (mg/m3)
Gypsum >95 10 15(T)/5(R)
Crystalline Silica .01-1 0.025(R) 0.1(R)
(T) Total (R) Respirable

Engineering Controls: Provide ventilation sufficient to control airborne dust levels. If user
operations generate airborne dust, use ventilation to keep dust
concentrations below permissible exposure limits. Where general
ventilation is inadequate, use process enclosures, local exhaust ventilation,
or other engineering controls to control dust levels below permissible
exposure limits.

Personal Protective Equipment:

Specific Respiratory
Protection: Wear a NIOSH/MSHA approved respirator equipped with particulate
cartridges when dusty in poorly ventilated areas, and if TLV is exceeded.
A respiratory program that meets OSHA s 29 CFR 1910-134 and ANSI
Z88.2 requirements must be followed whenever workplace conditions
warrant a respirator s use. If engineering controls are not possible, wear
a properly fitted NIOSH/MSHA-approved particulate respirator.

Safety Data Sheet

PMC Revision date:
January 1, 2020

4

Specific Eye/Face
Protection: Wear eye protection, safety glasses or goggles, to avoid possible eye
contact.
Specific Skin
Protection: Wear gloves and protective clothing to prevent repeated or prolonged
skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White to off-white

Odor: Low to no odor

Odor Threshold: Not determined

pH at 25 C: 7

Melting Point: Not applicable

Freezing Point: Not applicable

Boiling Point: Not applicable

Flash Point: Not determined

Upper/ lower flammability limits: Not determined

Vapor Pressure/density: Not applicable

Specific Gravity: 2.32 (Gypsum)

Solubility in water: 0.2 g/100g (Gypsum)

Partition coefficient: Not determined

Auto-ignition temp: Not determined

Decomposition temp: 2642 F/1450 C

Viscosity: Not applicable

Particle Size: Varies

Bulk Density: 45-150 lb/ft
3
/ 0.7-2.5 kg/m
3

Molecular Weight: 172 g/mole

Safety Data Sheet

PMC Revision date:
January 1, 2020

5

VOC Content: Zero g/l

Percent Volatile: Zero

10. STABILITY AND REACTIVITY
Chemical Stability: Stable
Conditions to Avoid: Contact with incompatibles (see below)

Incompatibility: None known

Hazardous
Polymerization: None Known

11. TOXICOLOGICAL INFORMATION
Likely routes of exposure & symptoms:

Eyes: Exposure to dust may cause irritation

Skin: Exposure to dust may cause dryness and irritation

Ingestion: No adverse effects expected for normal, incidental ingestion

Inhalation: Exposure to dust may cause irritation in nose, throat and lungs

Chronic Health Effects: This product contains trace a mounts of crystalline silica. Prolonged or
repeated inhalation of respirable crystalline silica can cause silicosis, as
serious lung disease.
Respiratory or Skin
Sensitization: This material is not known to cause sensitization

Carcinogenicity: This product is not listed as carcinogenic by OSHA, IARC, NTP, ACGIH, or the EU
Directives. This product may contain trace amounts of crystalline silica quartz
which is listed by IARC as Carcinogenic to Humans (Group 1) and Known to
be a Human Carcinogen by NTP.

Reproductive Toxicity: No data available

12. ECOLOGICAL INFORMATION
This product has no known affect on ecology. Toxicity studies of gypsum performed with fish, aquatic
invertebrates and aquatic plants showed no toxic effects.
13. DISPOSAL CONSIDERATIONS
Dispose of material in accordance with federal, state and local regulations. Prevent discharge directly
into sewers or surface waters. Consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Safety Data Sheet

PMC Revision date:
January 1, 2020

6

14. TRANSPORT INFORMATION
This product is not classified as a hazardous material under US DOT or Canadian TDG regulations.

15. REGULATORY INFORMATION
CERCLA Hazardous Substance: Not listed

SARA Toxic Chemical (40 CFR 355): Not listed

SARA Section302 Extremely Hazardous Substance ( 40 CFR 355): Not listed

SARA 311/312: Not listed

SARA Section 313 Toxic Chemical Reporting Requirements: None

Threshold Planning Quantity (TPQ): Not listed

RCRA Hazardous Waste Classification (40 CFR 261): Not classified

EPA Toxic Substances Control Act (TSCA) Status: All components of this product are
listed on the TSCA

California Proposition 65: Airborne crystalline silica particulates of respirable size
are known to the State of California to cause cancer

NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0

HMIS Ratings: Health: 1 Fire: 0 Reactivity: 0 Personal Protection: A

OSHA Specifically Regulated Substance (29 CFR 1910): Not listed

OSHA Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Listed

MSHA: Not listed

Canada DSL: Listed

Canadian WHMIS Classification: D2A, Materials causing other toxic effects

Canada CPR: This product has been classified in accordance with the hazard criteria of the CPR
of Canada and this SDS contains all the required information.

Ontario Regulations: Refer to Regulation 845: Designated Substances – Silica

Safety Data Sheet

PMC Revision date:
January 1, 2020

7

16. OTHER INFORMATION
List of GHS H316: Causes mild skin irritation
Hazard H320: Causes eye irritation
Statements: H350: May cause cancer by inhalation
H372: Causes damage to lungs through prolonged or repeated exposure by
inhalation

List of GHS P201: Obtain special instructions before use
Precautionary P202: Do not handle until all safety precautions have been read and understood
Statements: P260: Do not breathe dust
P264: Wash hands thoroughly after handling
P270: Do not eat, drink or smoke when using this product
P281: Use personal protective equipment as required

Abbreviations

ANSI American National Standards Institute
ACGIH American Conference of Governmental Industrial Hygienists
CAA Clean Air Act
CAS Chemical Abstracts Service (Registry Number)
CERCLA Comprehensive Environmental Response, Compensation and Liability Act
CFR Code of Federal Regulations
DOT United States Department of Transportation
DSL Canadian Domestic Substances List
EPA United States Environmental Protections Agency
EPCRA Emergency Planning & Community Right-to-know Act
HMIS Hazardous Materials Identification System
IARC International Agency of Research of Cancer
MSHA Mine Safety and Health Administration
NDSL Canadian Non-Domestic Substances List
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety and Health
OSHA Occupational Health and Safety Administration
PEL Permissible Exposure Limit
PPE Personal Protection Equipment
RCRA Resource Conservation and Recovery Act
SARA Superfund Amendments and Reauthorizations Act of 1986
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
UN/NA# United Nations/North America number
WHMIS Workplace Hazardous Material Information Sheet
The information contained in this document applies to this specific material as supplied. It may not be
valid for this material if it is used in combination with any other materials. It is the user s responsibility
to satisfy oneself as to the suitability and completeness of this information for his/her own particular
use.

Safety Data Sheet

PMC Revision date:
January 1, 2020

8

24BJO0930Q_SDS.pdf

Page 1 of 5

SAFETY DATA SHEET

Document ID : SDSCLP-03 Issue Date : 03 April 20 15
Revision : 4 Supersedes date : 26 March 2015

1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMP ANY

1.1

Identification of product
Product Name
Trade Name
Chemical name
Manufacturer product ID

: Phenolic microspheres
: PHENOSET microspheres
: Phenol formaldehyde polymer, cured
: BJO-0930, BJO-0840, EPO-0360, SPO-0620

1.2

Use of product
Functional filler for composites

1.3

Company Identification
MALAYAN ADHESIVES & CHEMICALS SDN. BHD.
No. 9, Jalan Utas 15/7, 40200 Shah Alam,
Selangor Darul Ehsan, MALAYSIA

Importer/Distributor:

Tel: +603-5566 1188
Fax:+603-5566 1122
1.4 Emergency telephone
+603-5566 1188

2. HAZARDS IDENTIFICATION
Not classified as hazardous for use/supply

Dust may cause irritation, experienced as stinging with excessive blinking and tear production.
Material may contain trace amount (<0.2%) of free formaldehyde, which is listed by IARC, NTP and OSHA as a carcinogen. There should be minimal risk when adequate ventilation is used due to the very low formaldehyde concentration. Page 2 of 5 3. COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS no. EC no. Weight % Risk phrases Hazard Statements Fully polymerized phenolic resin, inert NA NA >99.8 None None
Formaldehyde* 50-00-0 200-001-8 <0.2 R45, R68, R23/24/25, R34, R43 H350, H341, H331, H311, H301, H314, H317 Note*: Material is not considered hazardous in the classification of product as its concentration is below concentration cut-off point Phenoset microspheres is an article fulfilling the exemption of substance registration requirements under REACH article 7(1). 4. FIRST AID MEASURES Skin contact: Remove contaminated clothing. Wash skin with soap and water. Obtain medical attention if irritation persists. Wash clothing before reuse. Eye contact: Immediately flush eyes with water and continue for several minutes. Obtain medical attention if discomfort persists. Inhalation: If signs and symptoms develop, remove person to fresh air. If signs or symptoms persist, obtain medical attention. Ingestion: Do not induce vomiting unless instructed to do so by medical personnel. Unless unconscious, give victim lots of water. Obtain medical attention. Notes to physician: There is no specific antidote. Treatment or overexposure should be directed at the control of the symptoms and the clinical condition of the patient 5. FIRE-FIGHTING MEASURES Suitable Extinguishing media: Apply alcohol type or all-purpose type foams by manufacturers recommended techniques for large fires. Use carbon monoxide or dry chemical media for small fires. Do not direct a solid stream of water or foam into burning molten material; this may cause spattering and spread of fire. Extinguishing media to be avoided: None Unusual fire and explosion hazards: Avoid dispersion of dust in air to reduce potential of dust ignition / explosion. Special protective equipment for fire fighters: Use self-contained breathing apparatus and protective coating. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Wear suitable protective clothing. Methods for cleaning up: Ventilate with fresh air. Collect as much of the spilled material as possible. Use wet sweeping or water to avoid dusting. Collect and place in a closed container. Dispose as approved by your State Regulations. Page 3 of 5 7. HANDLING AND STORAGE 7.1 Handling General precaution: For industrial and professional use only. Avoid dispersion of dust in air. Electrically bond and ground equipment. Avoid sparks and flame under dust conditions. Use with adequate ventilation. Ventilation: Special, local ventilation is recommended in areas where containers are opened and their containers are discharged or in any areas where dusting conditions may occur. Other precaution {Caution] May undergo spontaneous smouldering if stored or heated in bulk above 35 o C under conditions allowing air ingress to the product. Store package material in a cool, well-ventilated area. Do not store in the sun. Do not dry in package use special drying instructions as below. Microspheres will undergo oxidation at elevated temperatures. Due to the microspheres excellent insulating characteristics, the internal temperature of the mass can increase to the point where spontaneous ignition and smouldering can occur. The temperature at which this occurs is a function of the geometry, amount of material being heated and available oxygen. Smouldering appears as a soft glow similar to burning charcoal. Drying instructions for the Phenoset microspheres: To reduce the moisture content of this product to less than 4%, dry a two-inch layer of the product at a maximum temperature of 75 o C for 24 hours. To prevent oven or product contamination, the metal drying tray should be covered with a cloth that will allow the product moisture to evaporate. 7.2 Storage Keep container closed. 7.3 Specific use (s) For industrial and professional use only. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Exposure limit values . No exposure limit has been established. 8.2 8.2.1 Exposure controls Occupational exposure controls Respiratory protection: Hand protection : Eye protection : Other protective equipment: Dust respirator, if dusting occurs General working gloves are acceptable. Safety glasses Eye bath and safety shower. Adequate ventilation . 8.2.2 Environmental exposure controls None established. Page 4 of 5 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Red brown, fine powder Odour: Odourless Molecular weight: >10,000, Fully cured C-stage
Relative density: 0.20 0.80
Self-ignition temperature: 500
o
C (ASTM D1929)
Boiling point: Does not boil
Melting point: Does not melt
Solubility: Not soluble in water

10. STABILITY AND REACTIVITY
General : Stable
Conditions to avoid: None known
Materials to avoid: Strong acids and base, halogens , acyl halides
Hazardous decomposition products: Carbon monoxide, car bon dioxide, formaldehyde and phenol
derivatives upon decomposition.
Hazardous polymerisation: Will not occur.
11. TOXICOLOGICAL INFORMATION

Effects from inhalation:
Upper respiratory tract irritation signs/symptoms may include sneezing, cough, and nasal discharge.

Effects from ingestion:
Gastrointestinal irritation.

Effects from skin contact:
Mechanical skin irritation. May result in itching.

Effects from eye contact:
Mechanical eye irritation. Signs and symptoms may include pain, redness and tears.

Significant data with possible relevance to human health
Formaldehyde has been shown to cause cancer in laboratory animals and mutations in a variety of in-vitro
test systems. The relevance of these findings for human is unknown. Formaldehyde is listed as a
carcinogen by IARC, NTP and OSHA.

12. ECOLOGICAL INFORMATION
Ecotoxicity: None known.
Mobility: Does not dissolve in water.
Persistence and degradability: Not determined.
Bioaccumulative potential: Unknown.

13. DISPOSAL CONSIDERATIONS

Dispose off in accordance with appropriate National and local regulations.

Page 5 of 5
14. TRANSPORT INFORMATION
UN Number, ADR/RID:
IMDG/ICAO:
MONT-BLANC:
Not restricted for transportation.
Not restricted for transportation.
Not restricted for transportation.
15. REGULATORY INFORMATION
Label Elements [Regulations (EC) No. 1272/2008]
None Not classified as hazardous
Inventory Listed In:
China IECSC, EU EINECS, US TSCA, Canada DSL, Japan ENCS, Korea KECL, Taiwan NECI,
Philippine PICCS, Australia AICS, New Zealand NZIoC
16. OTHER INFORMATION
Text of R phrases referred to under headings 3
R45 May cause cancer
R68 Possible risk of irreversible effects
R23/24/25 Toxic by inhalation, in contact and if s wallowed
R34 Causes burns
R43 May cause sensitization by skin contact
H317 May cause an allergic skin reaction

Text of H phrases referred to under headings 3
H350 May cause cancer
H341 Suspected of causing genetic defects
H331 Toxic if inhaled
H311 Toxic in contact with skin
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction

Product category:
Phenoset microspheres is an article fulfilling the exemption of substance registration requirements under
REACH article 7(1).

Text on Label:
CAUTION! May undergo spontaneous smouldering if stored or heated in bulk above 35C under conditions
allowing air ingress to the product.
Store in cool, well-ventilated area.
Do not store in the sun
Do not dry in package refer special drying instructions.
FOR INDUSTRIAL USE ONLY

Recommended usage and restrictions:
Please consult the product and/or applications information bulletins for this product.

Disclaimer
The information contains herein is correct to the best of our knowledge. We disclaim any liability as to the
recommendations or completeness of the information. The final evaluation on the fitness of use lies on the
user digression. All material has hidden hazards and should be used with extreme care. Even though
various hazards had been listed herein, we do not warranty that those are the only existing hazards.

Revision Date: 03 April 2015
Revision Summary: Section 3 classification of formaldehyde.
Section 16 Text of R- and H-phrases