30XR4995D_SDS.pdf

by | Sep 27, 2025

Vinyl Ester Resin
Product name
Product type
Section 1. Identification
Chemical family Aromatic.
Relevant identified uses of the substance or mixture and uses advised against
SDS No. XNA-1804:1446 (Version: 2.1)
Uses advised against
Identified uses Used in the manufacture of thermoset plastic parts.
No additional information.
XR-4995
SAFETY DATA SHEET
Date of issue: 09/20/2018
Date of previous issue: 08/15/2018
Emergency telephone number
Supplier’s details
CHEMTREC Within USA and Canada
CHEMTREC Outside USA and Canada
CANUTEC Within Canada
+1 (800) 424-9300
+1 (703) 527-3887
+1 (613) 996-6666
CCN1023
AOC, LLC
955 Highway 57 East
Collierville, TN 38017
Phone Number: (901) 854-2800
Hours: 8AM-5pm (Central Time) Mon-Fri
AOC, LLC
38 Royal Road
Guelpha, Ontario Canada N1H 1G3
Phone Number: (519) 821-5180
Hours: 8am-5pm (Eastern) Mon-Fri
E-Mail: aoc.sds@aoc-resins.com
Website: www.aoc-resins.com
United States: Canada:
Section 2. Hazards identification
OSHA/HCS status
SKIN CORROSION/IRRITATION Category 2 H315
SERIOUS EYE DAMAGE/ EYE IRRITATION Category 2 H319
SENSITIZATION (Skin) Category 1 H317
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory system) Category 3 H335
Classification of the substance or mixture
Signal word
Warning
Hazard statements
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
Hazard pictograms
Precautionary statements
Prevention
P261: Do not breathe vapor or mist.
P270: Do not eat, drink or smoke when using this product.
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
GHS label elements
General
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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XR-4995
Section 2. Hazards identification
Response
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation occurs, get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists, get medical advice/attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P391: Collect spillage.
Storage
P403 + P235: Store in a well-ventilated place. Keep cool.
P233: Keep container tightly closed.
P405: Store locked up.
Disposal
P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
None known.
Section 3. Composition/information on ingredients
Ingredient name CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture.
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate 42978-66-5 25 – 50
phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide 162881-26-7 0.3
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Seek immediate medical attention.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby
shampoo will aid in removal. If irritation persists, get medical attention.
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists, seek
medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse.
Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give oxygen.
If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Eye contact
Skin contact
Inhalation
Ingestion
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Irritating to mouth, throat and stomach.
Causes serious eye irritation.
May cause allergic skin reactions with repeated exposure.
May cause respiratory irritation.
Eye contact
Skin contact
Inhalation
Ingestion
Over-exposure signs/symptoms
Eye contact
Adverse symptoms may include the following: pain or irritation, watering, redness.
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XR-4995
Section 4. First aid measures
Notes to physician
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: irritation, redness.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach..
Section 5. Fire-fighting measures
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
No specific data.
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment
if released in large quantities.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor.
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or walk
through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation.
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See also the information in
“For non-emergency personnel”.
Small spill
Large spill
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XR-4995
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating
areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all
ignition sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. Refer to the product label and/or technical data sheet for further information.
Protective measures
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not ingest. Avoid contact
with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks,
open flame or any other ignition source. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Precautions for safe handling
None.
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists or dusts.
Eye/face protection
Respiratory protection
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Appropriate engineering controls
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or
dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Hygiene measures
Control parameters
Individual protection measures
Occupational exposure limits
Other skin protection
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.
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XR-4995
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.038 (Water = 1)
Not established.
Not available.
Negligible.
AcrylateOdor
pH
Yellow.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
>201 F / >94 C
Not available.
Not applicable.
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-octanol/water
Appearance
Boiling point Not applicable.
Flammability (solid, gas) Not applicable.
Lower and upper explosive (flammable)
limits
Not available.
Molecular weight Not available.
Decomposition temperature Not available.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable. Stable under recommended storage and handling conditions (see Section 7).
Chemical stability
Reactive or incompatible with the following materials: oxidizing materials
Incompatible materials
Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
(1-methyl-1,2-ethanediyl)bis[oxy
(methyl-2,1-ethanediyl)] diacrylate
LD50 Oral Rat 6200 mg/kg –
phenyl bis(2,4,6-trimethylbenzoyl)-
phosphine oxide
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat >2000 mg/kg –
Ingredient name Result Species Dose Exposure
Carcinogenicity
Irritation/Corrosion
(1-methyl-1,2-ethanediyl)bis[oxy
(methyl-2,1-ethanediyl)] diacrylate
Eyes – Severe irritant Rabbit – 24 hours 100
microliters
–
Skin – Moderate irritant Rabbit – 500 milligrams-
Ingredient name Result Score Exposure Observation
Sensitization
Species
Information on toxicological effects
May cause sensitization by skin contact.
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XR-4995
Section 11. Toxicological information
Mutagenicity
Teratogenicity
Reproductive toxicity
Inhalation
May cause respiratory irritation.
Irritating to mouth, throat and stomach.
Ingestion
Skin contact
May cause allergic skin reactions with repeated exposure.
Causes serious eye irritation.
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach..
Adverse symptoms may include the following: irritation, redness.
Eye contact
Adverse symptoms may include the following: pain or irritation, watering, redness.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Potential acute health effects
Classification
None of the components are listed.
Ingredient name NTPIARCACGIH
No mutagenic effect.
Not considered to be toxic to the reproductive system.
No known effect according to our database.
No known effect according to our database.
No known effect according to our database.
No known effect according to our database.
Inhalation
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
(1-methyl-1,2-ethanediyl)bis[oxy
(methyl-2,1-ethanediyl)] diacrylate
2 46.83 low
phenyl bis(2,4,6-trimethylbenzoyl)-
phosphine oxide
5.77 <5 low Toxicity (1-methyl-1,2-ethanediyl)bis[oxy (methyl-2,1-ethanediyl)] diacrylate EC50 3.68 mg/l Algae 96 hours LC50 35.96 mg/l Daphnia 48 hours LC50 4.9 mg/l Fish 96 hours Ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) Not available. Mobility in soil Not available. Ingredient name Page: 6 of 8Date of issue: 09/20/2018 Date of previous issue: 08/15/2018 XNA-1804:1446 (Version: 2.1) XR-4995 Section 12. Ecological information Other adverse effects No known effect according to our database. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid disposal. Attempt to use product completely in accordance with intended use. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. Disposal methods The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). Special precautions This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information Environmentally hazardous substance, liquid, n.o.s.(Tri(propylene glycol) diacrylate) 9 III UN3082UN number Proper shipping name Transport hazard class(es) Packing group DOT / TDG/ IMDG/IMO / ICAO/IATA and National regulations. Additional information US regulations require the reporting of spills when the amount exceeds the Reportable Quantity (RQ) for specific components of this material. See CERCLA in Section 15, Regulatory Information, for the Reportable Quantities. Environmental hazards Marine pollutant: Yes. Special precautions for user Transport within user s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. IMDGNo additional information. IATANo additional information. Section 15. Regulatory information International regulations lists All components are listed or exempted. SARA 311/312 United States inventory (TSCA 8b) Australia (AICS) Not determined. Canada (DSL) All components are listed or exempted. China (IECSC) Not determined. Europe (EINECS) Not determined. Japan Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea (KECI) Not determined. Malaysia (EHS Register) Not determined. New Zealand (NZIoC) Not determined. Philippines (PICCS) Not determined. Taiwan (CSNN) Not determined. U.S. Federal regulations Page: 7 of 8Date of issue: 09/20/2018 Date of previous issue: 08/15/2018 XNA-1804:1446 (Version: 2.1) XR-4995 Section 15. Regulatory information SARA 313 Ingredient name None. Form R - Reporting requirements CAS number California Prop. 65 State regulations None.CERCLA RQ - Not available. Per the June 13, 2016 Federal Register notice, EPA harmonized the EPCRA 311/312 hazard categories with the 2012 OSHA hazard communication standard for classifying and labeling of chemicals (i.e. GHS). Please refer to Section 2 of the SDS to identify the appropriate hazard categories for reporting purposes. Section 16. Other information History Version Prepared by The information contained in this data sheet is furnished in good faith and without warranty, representation, or inducement or license of any kind, except that it is accurate to the best of AOC, LLC's knowledge, or was obtained from sources believed by AOC, LLC to be reliable. The accuracy, adequacy or completeness of health and safety precautions set forth herein cannot be guaranteed, and the buyer is solely responsible for ensuring that the product is used, handled, stored, and disposed of safely and in compliance with applicable federal, state or provincial, and local laws. AOC, LLC disclaims liability for any loss, damage or personal injury that arises from, or is in any way related to, use of the information contained in this data sheet. Notice to reader Date of previous issue Indicates information that has changed from previously issued version. Key to abbreviations ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 09/20/2018 08/15/2018 2.1 National Fire Protection Association (U.S.A.) Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. AOC Corporate Regulatory Affairs This Safety Data Sheet (SDS) and its content are the confidential and proprietary information of AOC and it may not be modified, altered, deconstructed, or presented in any other manner, without the explicit authorization of AOC and/or its legal counsel. 2 1 2 Health Special Instability Flammability Date of issue Page: 8 of 8Date of issue: 09/20/2018 Date of previous issue: 08/15/2018 XNA-1804:1446 (Version: 2.1)

30XR4198D_SDS.pdf

by | Sep 27, 2025

Vinyl Ester Resin
Product name
Product type
Section 1. Identification
Chemical family Aromatic.
Relevant identified uses of the substance or mixture and uses advised against
SDS No. XUS-1602:618 (Version: 3.0)
Uses advised against
Identified uses Used in the manufacture of thermoset plastic parts.
No additional information.
XR-4198
SAFETY DATA SHEET
For U.S. Only
Date of issue: 02/01/2021
Date of previous issue: 02/01/2017
Emergency telephone number
Supplier’s details
CHEMTREC Within USA and Canada
CHEMTREC Outside USA and Canada
CANUTEC Within Canada
+1 (800) 424-9300
+1 (703) 527-3887
+1 (613) 996-6666
CCN1023
AOC
955 Highway 57 East
Collierville, TN 38017
Phone Number: (901) 854-2800
Hours: 8AM-5pm (Central Time) Mon-Fri
AOC
38 Royal Road
Guelph, Ontario Canada N1H 1G3
Phone Number: (519) 821-5180
Hours: 8am-5pm (Eastern) Mon-Fri
E-Mail: aoc.sds@aocresins.com
Website: www.aocresins.com
United States: Canada:
Section 2. Hazards identification
OSHA/HCS status
FLAMMABLE LIQUIDS Category 3 H226
ACUTE TOXICITY (Inhalation) Category 4 H332
SKIN IRRITATION Category 2 H315
EYE IRRITATION Category 2A H319
CARCINOGENICITY Category 2 H351
REPRODUCTIVE TOXICITY Category 2 H361d
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) Category 3 H335
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Category 1 H372
ASPIRATION HAZARD Category 1 H304
Classification of the substance or mixture
Signal word
Danger
Hazard statements
H226: Flammable liquid and vapor.
H332: Harmful if inhaled.
H319: Causes serious eye irritation.
H315: Causes skin irritation.
H361d: Suspected of damaging the unborn child.
H351: Suspected of causing cancer.
H304: May be fatal if swallowed and enters airways.
H335: May cause respiratory irritation.
H372: Causes damage to organs through prolonged or repeated exposure. (hearing organs, kidneys)
Hazard pictograms
Precautionary statements
GHS label elements
General
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Page: 1 of 9Date of issue: 02/01/2021
Date of previous issue: 02/01/2017XUS-1602:618 (Version: 3.0)
XR-4198

Section 2. Hazards identification
Prevention
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P210: Keep away from heat, sparks and hot surfaces. – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting/material-handling equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P233: Keep container tightly closed.
P271: Use only outdoors or in a well-ventilated area.
P260: Do not breathe vapor or mist.
P270: Do not eat, drink or smoke when using this product.
P264: Wash hands thoroughly after handling.
Response
P314: Get medical attention if you feel unwell.
P308+P313: IF exposed or concerned: Get medical attention.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or physician if you feel unwell.
P370+P378: In case of fire: Use dry chemical, CO , water spray (fog) or foam.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P362+P364: Take off contaminated clothing and wash it before reuse.
P332+P313: If skin irritation occurs: Get medical attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical attention.
P391: Collect spillage.
Storage
P405: Store locked up.
P403+P235: Store in a well-ventilated place. Keep cool.
P233: Keep container tightly closed.
Disposal
P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
Hazards not otherwise classified
None known.
Section 3. Composition/information on ingredients
Ingredient name CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture.
styrene 100-42-5 12.5
methacrylic acid 79-41-4 3
Section 4. First aid measures
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby
shampoo will aid in removal. If irritation persists, get medical attention.
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists, seek
medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse.
Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give oxygen.
If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Eye contact
Skin contact
Inhalation
Description of necessary first aid measures
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Date of previous issue: 02/01/2017XUS-1602:618 (Version: 3.0)
XR-4198

Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Seek immediate medical attention.
Ingestion
Notes to physician
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Most important symptoms/effects, acute and delayed
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Irritating to mouth, throat and stomach.
Causes serious eye irritation.
Causes skin irritation.
Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness.
Eye contact
Skin contact
Inhalation
Ingestion
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following: pain or irritation, watering, redness.
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: irritation, redness.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach.
Section 5. Fire-fighting measures
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined
areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This
material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented
from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
For emergency responders
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or walk
through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation.
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See also the information in
“For non-emergency personnel”.
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Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment
if released in large quantities.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor.
Methods and materials for containment and cleaning up
Small spill
Large spill
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating
areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all
ignition sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. Refer to the product label and/or technical data sheet for further information.
Protective measures
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not ingest. Avoid contact
with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks,
open flame or any other ignition source. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2019). Absorbed through skin.
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
methacrylic acid ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
TWA: 70 mg/m 8 hours.
NIOSH REL (United States, 10/2016). Absorbed through skin.
TWA: 20 ppm 10 hours.
TWA: 70 mg/m 10 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Appropriate engineering controls
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists or dusts.
Eye/face protection
Respiratory protection
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or
dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Other skin protection
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
23.8 F / 30.6 C (Styrene)
1.1 (Water = 1)
3.6 (Air = 1) (Styrene )
5.0 mm Hg@ 68 F / 20 C (Styrene)
Slight.
Aromatic.Odor
pH
Clear to Amber.Color
Evaporation rate < 1 (Butyl acetate = 1) Auto-ignition temperature Flash point 914 F / 490 C (Styrene) 88 F / 31 C (Styrene) Not available. Not applicable. Viscosity Not available. 0.01 - 0.1 ppm (Styrene)Odor threshold Partition coefficient: n-octanol/water Appearance Boiling point 293 F / 145 C (Styrene) Flammability (solid, gas) Not applicable. Lower and upper explosive (flammable) limits Lower: 1.1% Upper: 6.1% (Styrene) Molecular weight 1,000 to 15,000 Decomposition temperature Not available. Section 10. Stability and reactivity Conditions to avoid The product is stable. Stable under recommended storage and handling conditions (see Section 7). Chemical stability Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity No specific test data related to reactivity available for this product or its ingredients. Page: 5 of 9Date of issue: 02/01/2021 Date of previous issue: 02/01/2017XUS-1602:618 (Version: 3.0) XR-4198 Section 10. Stability and reactivity Hazardous decomposition products Sunlight, open flames and storage above 25 C. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Reactive or incompatible with the following materials: oxidizing materials Incompatible materials Section 11. Toxicological information Acute toxicity styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LC50 Inhalation Vapor Rat 5634.2 ppm 4 hours LD50 Oral Rat 2650 mg/kg - methacrylic acid LC50 Inhalation Dusts and mists Rat 7100 mg/m 4 hours LD50 Dermal Rabbit 500 mg/kg - LD50 Oral Mouse 1250 mg/kg - LD50 Oral Rat 1060 mg/kg - LD50 Oral Rat 1060 mg/kg - Ingredient name Result Species Dose Exposure Carcinogenicity Mutagenicity Teratogenicity Reproductive toxicity Irritation/Corrosion styrene Eyes - Mild irritant Human - 50 ppm - Eyes - Moderate irritant Rabbit - 24 hours 100 mg- Eyes - Severe irritant Rabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Skin - Moderate irritant Rabbit - 100 % - Ingredient name Result Score Exposure Observation Sensitization Species Inhalation Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Causes serious eye irritation. Eye contact Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Information on toxicological effects Potential acute health effects Classification styrene - 2A Reasonably anticipated to be a human carcinogen. Ingredient name NTPIARCACGIH May cause sensitization by skin contact. No known significant effects or critical hazards. 1) Negative Study A published study concluded that the mechanism for producing cancer in mice exposed to styrene is not applicable in human metabolism. (June 2013 Pharmacology & Toxicology 66 (2013)) 2) Negative Study A recent update to an extensive study of reinforced plastic workers from 1948-1977 concluded that there was no coherent evidence that styrene exposure increased risk of cancer (March 2013 Epidemiology Vol. 24 Issue 2) 3) Positive Study Styrene induced pulmonary toxicity and carcinogenicity in mice was shown to be caused by a metabolite of styrene, probably styrene oxide. (Dec.2001 Toxicology Vol.169 Issue 2) Suspected of damaging the unborn child. No known significant effects or critical hazards. May cause respiratory irritation. A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm, 8 hour TWA, indicated a possible mild hearing loss. May be fatal if swallowed and enters airways. Page: 6 of 9Date of issue: 02/01/2021 Date of previous issue: 02/01/2017XUS-1602:618 (Version: 3.0) XR-4198 Section 11. Toxicological information Irritating to mouth, throat and stomach. Ingestion Skin contact Causes skin irritation. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Adverse symptoms may include the following: respiratory tract irritation, coughing. Adverse symptoms may include the following: Irritating to mouth, throat and stomach. Adverse symptoms may include the following: irritation, redness. Eye contact Adverse symptoms may include the following: pain or irritation, watering, redness. Inhalation Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects No known effect according to our database. styrene 0.35 13.49 low methacrylic acid 0.93 - low Toxicity styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours methacrylic acid Chronic NOEC 53 mg/l Fresh water Daphnia - Daphnia magna - Neonate21 days Ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) Not available. Mobility in soil Not available. Ingredient name Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid disposal. Attempt to use product completely in accordance with intended use. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. Disposal methods The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). Special precautions This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Page: 7 of 9Date of issue: 02/01/2021 Date of previous issue: 02/01/2017XUS-1602:618 (Version: 3.0) XR-4198 Section 14. Transport information Resin Solution 3 III UN1866UN number Proper shipping name Transport hazard class(es) Packing group DOT /TDG / IMDG/IMO / ICAO/IATA and National regulations. Additional information US regulations require the reporting of spills when the amount exceeds the Reportable Quantity (RQ) for specific components of this material. See CERCLA in Section 15, Regulatory Information, for the Reportable Quantities. Environmental hazards Marine pollutant: No. Special precautions for user Transport within user s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. IMDGEmergency schedules (EmS): F-E, S-E Remarks: FP- 31 C IATANo additional information. Section 15. Regulatory information International regulations lists All components are active or exempted. SARA 313 Ingredient name styrene 100-42-5 Form R - Reporting requirements SARA 311/312 United States inventory (TSCA 8b) Australia (AICS) All components are listed or exempted. Canada (DSL) All components are listed or exempted. China (IECSC) All components are listed or exempted. Europe (EINECS) Not determined. Japan (ENCS) All components are listed or exempted. Republic of Korea (KECI) All components are listed or exempted. New Zealand (NZIoC) All components are listed or exempted. Philippines (PICCS) Not determined. Taiwan (CSNN) All components are listed or exempted. CAS number California Prop. 65 State regulations styrene - 1000 lbs. (453.6 kg)CERCLA RQ - WARNING: This product can expose you to Styrene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. Per the June 13, 2016 Federal Register notice, EPA harmonized the EPCRA 311/312 hazard categories with the 2012 OSHA hazard communication standard for classifying and labeling of chemicals (i.e. GHS). Please refer to Section 2 of the SDS to identify the appropriate hazard categories for reporting purposes. U.S. Federal regulations Page: 8 of 9Date of issue: 02/01/2021 Date of previous issue: 02/01/2017XUS-1602:618 (Version: 3.0) XR-4198 Section 16. Other information History Version Prepared by AOC is a registered trademark of the AOC group of companies. The information contained in this data sheet is based on laboratory data and field experience. We believe this information to be reliable, but do not guarantee its applicability to the user s process or assume any liability for occurrences arising out of its use. The user, by accepting the products as described herein, agrees to be responsible for thoroughly testing each such product before committing it to production. Altek , Atryl , Atryl TCA , Chroma-Tek , EcoTek , FirePel , Hydropel , Moldtru , PulTru , Vibrin , Vicast , Vipel , the AOC name, the AOC logo, and the Trusted Solutions logo are registered trademarks of the AOC group of companies. Our recommendations should not be construed as inducements to infringe any patent or violate any law, safety code or insurance regulation. The information and recommendations contained herein are to the best of our knowledge accurate and reliable, but no rights whatsoever may be derived by any party other than those expressly agreed to with a selling entity of the AOC group of companies in a legally binding agreement. AOC hereby makes no warranty of any kind, express or implied, including those of merchantability and fitness for purpose. Unless explicitly agreed to in writing by AOC otherwise, all offers, quotations, sales and deliveries of AOC products are subject to the general conditions of sale of AOC. Notice to reader Date of previous issue Indicates information that has changed from previously issued version. Key to abbreviations ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 02/01/2021 02/01/2017 3.0 National Fire Protection Association (U.S.A.) Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. AOC Corporate Regulatory Affairs This Safety Data Sheet (SDS) and its content are the confidential and proprietary information of AOC and it may not be modified, altered, deconstructed, or presented in any other manner, without the explicit authorization of AOC and/or its legal counsel. 2 3 2 Health Special Instability Flammability Date of issue Page: 9 of 9Date of issue: 02/01/2021 Date of previous issue: 02/01/2017XUS-1602:618 (Version: 3.0) XR-4198

30XP8616D_SDS.pdf

by | Sep 27, 2025

Vinyl Ester Resin
Product name
Product type
Section 1. Identification
Chemical family Aromatic.
Relevant identified uses of the substance or mixture and uses advised against
SDS No. XNA-2411:3042 (Version: 1.0)
Uses advised against
Identified uses Used in the manufacture of thermoset plastic parts.
No additional information.
XP-8616
SAFETY DATA SHEET
Date of issue: 11/19/2024
Date of previous issue: SDS – New Request
Emergency telephone number
Supplier’s details
CHEMTREC Within USA and Canada
CHEMTREC Outside USA and Canada
CANUTEC Within Canada
+1 (800) 424-9300
+1 (703) 527-3887
+1 (613) 996-6666
CCN1023
AOC
955 Highway 57 East
Collierville, TN 38017
Phone Number: (901) 854-2800
Hours: 8AM-5pm (Central Time) Mon-Fri
AOC
38 Royal Road
Guelph, Ontario Canada N1H 1G3
Phone Number: (519) 821-5180
Hours: 8am-5pm (Eastern) Mon-Fri
E-Mail: aoc.sds@aocresins.com
Website: www.aocresins.com
United States: Canada:
Section 2. Hazards identification
OSHA/HCS status
FLAMMABLE LIQUIDS Category 3 H226
ACUTE TOXICITY (Inhalation) Category 4 H332
SKIN IRRITATION Category 2 H315
EYE IRRITATION Category 2A H319
CARCINOGENICITY Category 2 H351
REPRODUCTIVE TOXICITY Category 2 H361d
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) Category 3 H335
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Category 1 H372
ASPIRATION HAZARD Category 1 H304
Classification of the substance or mixture
Signal word
Danger
Hazard statements
H226: Flammable liquid and vapor.
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H351: Suspected of causing cancer.
H361d: Suspected of damaging the unborn child.
H304: May be fatal if swallowed and enters airways.
H335: May cause respiratory irritation.
H372: Causes damage to organs through prolonged or repeated exposure. (hearing organs, kidneys)
Hazard pictograms
Precautionary statements
GHS label elements
General
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Section 2. Hazards identification
Prevention
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P240: Ground and bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting/material-handling equipment.
P242: Use non-sparking tools.
P243: Take action to prevent static discharges.
P271: Use only outdoors or in a well-ventilated area.
P260: Do not breathe vapor or mist.
P270: Do not eat, drink or smoke when using this product.
P264: Wash hands thoroughly after handling.
P272 (OSHA): Contaminated work clothing must not be allowed out of the workplace.
Response
P314: Get medical attention if you feel unwell.
P308+P313: IF exposed or concerned: Get medical attention.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312: Call a POISON CENTER or physician if you feel unwell.
P370+P378: In case of fire: Use dry chemical, CO , water spray (fog) or foam.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P332+P313: If skin irritation occurs: Get medical attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical attention.
Storage
P405: Store locked up.
P403+P235: Store in a well-ventilated place. Keep cool.
P233: Keep container tightly closed.
Disposal
P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
Hazards not otherwise classified
None known.
Section 3. Composition/information on ingredients
Ingredient name CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture
styrene 100-42-5 34.7
vinyltoluene 25013-15-4 3
cobalt bis(2-ethylhexanoate) 136-52-7 0.3
Section 4. First aid measures
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby
shampoo will aid in removal. If irritation persists, get medical attention.
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists, seek
medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse.
Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give oxygen.
If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Eye contact
Skin contact
Inhalation
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Seek immediate medical attention.
Ingestion
Notes to physician
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Most important symptoms/effects, acute and delayed
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Irritating to mouth, throat and stomach.
Causes serious eye irritation.
Causes skin irritation.
Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness.
Eye contact
Skin contact
Inhalation
Ingestion
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following: pain or irritation, watering, redness.
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: irritation, redness.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach.
Section 5. Fire-fighting measures
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent
explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a
considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This material is harmful
to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged
to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
For emergency responders
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or walk
through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation.
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See also the information in
“For non-emergency personnel”.
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Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment
if released in large quantities.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor.
Methods and materials for containment and cleaning up
Small spill
Large spill
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating
areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. Refer to the product label and/or technical data sheet for further information.
Protective measures
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not ingest. Avoid contact
with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks,
open flame or any other ignition source. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Precautions for safe handling
styrene ACGIH TLV (United States, 1/2023). Ototoxicant.
TWA: 10 ppm 8 hours.
STEL: 20 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2020).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
vinyltoluene NIOSH REL (United States, 10/2020). [VINYL TOLUENE]
TWA: 100 ppm 10 hours.
TWA: 480 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 480 mg/m 8 hours.
ACGIH TLV (United States, 1/2023).
TWA: 10 ppm 8 hours.
cobalt bis(2-ethylhexanoate) OSHA PEL (United States).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
TWA: 0.1 mg/m
ACGIH TLV (United States, 1/2023). [cobalt and inorganic
compounds] Skin sensitizer. Inhalation sensitizer.
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the
selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists or dusts.
Eye/face protection
Respiratory protection
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Appropriate engineering controls
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or
dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Other skin protection
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Odor
pH
Color
Evaporation rate
Auto-ignition temperature
Flash point
Viscosity
Odor threshold
Partition coefficient: n-octanol/water
Appearance
Boiling point
Flammability (solid, gas)
Lower and upper explosive (flammable)
limits
Molecular weight
Decomposition temperature
Liquid.
23.8 F / 30.6 C (Styrene)
1.1 (Water = 1)
3.6 (Air = 1) (Styrene)
5.0mmHg @ 68 F (20 C) (Styrene)
Slight.
Aromatic.
Amber.
<1 (Butyl acetate = 1) 914 F / 490 C (Styrene) 88 F / 31 C (Styrene) Not available. Not applicable. Not available. 0.01 - 0.1 ppm (Styrene) 293 F / 145 C (Styrene) Not applicable. Lower: 1.1% Upper: 6.1% (Styrene) 1,000 to 15,000 Not available. Page: 5 of 9Date of issue: 11/19/2024 Date of previous issue: SDS - New RequestXNA-2411:3042 (Version: 1.0) XP-8616 Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Sunlight, open flames and storage above 25 C. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable. Stable under recommended storage and handling conditions (see Section 7). Chemical stability Reactive or incompatible with the following materials: oxidizing materials Incompatible materials Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LC50 Inhalation Vapor Rat 5634.2 ppm 4 hours LD50 Oral Rat 2650 mg/kg - vinyltoluene LD50 Oral Rat 2255 mg/kg - cobalt bis(2-ethylhexanoate) LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 1.22 g/kg –
Ingredient name Result Species Dose Exposure
Carcinogenicity
Mutagenicity
Teratogenicity
Reproductive toxicity
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 ppm –
Eyes – Moderate irritant Rabbit – 24 hours 100 mg-
Eyes – Severe irritant Rabbit – 100 mg –
Skin – Mild irritant Rabbit – 500 mg –
Skin – Moderate irritant Rabbit – 100 % –
vinyltoluene Eyes – Mild irritant Rabbit – 90 mg –
Skin – Moderate irritant Rabbit – 100 % –
Ingredient name Result Score Exposure Observation
Sensitization
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Information on toxicological effects
Classification
styrene – 2A Reasonably anticipated to be a human carcinogen.
vinyltoluene – 3 –
cobalt bis(2-ethylhexanoate) – 2B Reasonably anticipated to be a human carcinogen.
Ingredient name NTPIARCACGIH
No data on skin sensitization due to this product.
No known significant effects or critical hazards.
1) Negative Study A published study concluded that the mechanism for producing cancer in mice exposed to styrene
is not applicable in human metabolism. (June 2013 Pharmacology & Toxicology 66 (2013))
2) Negative Study A recent update to an extensive study of reinforced plastic workers from 1948-1977 concluded that
there was no coherent evidence that styrene exposure increased risk of cancer (March 2013 Epidemiology Vol. 24
Issue 2)
3) Positive Study Styrene induced pulmonary toxicity and carcinogenicity in mice was shown to be caused by a
metabolite of styrene, probably styrene oxide. (Dec.2001 Toxicology Vol.169 Issue 2)
Suspected of damaging the unborn child.
No known significant effects or critical hazards.
May cause respiratory irritation.
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Section 11. Toxicological information
Inhalation
Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness.
Irritating to mouth, throat and stomach.
Ingestion
Skin contact
Causes skin irritation.
Causes serious eye irritation.
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach.
Adverse symptoms may include the following: irritation, redness.
Eye contact
Adverse symptoms may include the following: pain or irritation, watering, redness.
Aspiration hazard
Potential acute health effects
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm, 8 hour TWA, indicated a possible mild
hearing loss.
May be fatal if swallowed and enters airways.
Inhalation
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects
No known effect according to our database.
styrene 0.35 13.49 low
vinyltoluene 3.35 100 to 320 low
cobalt bis(2-ethylhexanoate) – 15600 high
Toxicity
styrene Acute EC50 78000 g/l Marine water Algae – Skeletonema costatum 96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina 48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
vinyltoluene Acute EC50 1 to 10 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 8.9 mg/l Marine water Crustaceans – Chaetogammarus
marinus – Young
48 hours
Ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
Not available.
Mobility in soil
Not available.
Ingredient name
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local
authority requirements. Avoid disposal. Attempt to use product completely in accordance with intended use. Waste packaging should be
recycled. Incineration or landfill should only be considered when recycling is not feasible.
Disposal methods
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any
available use-specific information provided in the Exposure Scenario(s).
Special precautions
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Section 13. Disposal considerations
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues. Do not cut, weld or grind used containers unless they
have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Section 14. Transport information
Resin Solution
3
III
UN1866UN number
Proper shipping name
Transport hazard class(es)
Packing group
DOT /TDG / IMDG/IMO / ICAO/IATA and National regulations.
Additional information US regulations require the reporting of spills when the amount exceeds the Reportable
Quantity (RQ) for specific components of this material. See CERCLA in Section 15,
Regulatory Information, for the Reportable Quantities.
Environmental hazards Marine pollutant: No.
Special precautions for user Transport within user s premises: always transport in closed containers that are upright and
secure. Ensure that persons transporting the product know what to do in the event of an
accident or spillage.
IMDGEmergency schedules (EmS): F-E, S-E
Remarks: FP- 31 C
IATANo additional information.
Section 15. Regulatory information
International regulations lists
All components are active or exempted.
SARA 313
Ingredient name
styrene 100-42-5
cobalt bis(2-ethylhexanoate) 136-52-7
Form R – Reporting
requirements
SARA 311/312
United States inventory (TSCA 8b)
Australia (AICS) All components are listed or exempted.
Canada (DSL) All components are listed or exempted.
China (IECSC) All components are listed or exempted.
Japan (ENCS) All components are listed or exempted.
Republic of Korea (KECI) All components are listed or exempted.
New Zealand (NZIoC) All components are listed or exempted.
Philippines (PICCS) Not determined.
Taiwan (CSNN) All components are listed or exempted.
CAS number
California Prop. 65
State regulations
styrene – 1000 lbs. (453.6 kg)CERCLA RQ –
WARNING: This product can expose you to chemicals including Styrene, which is known to the State of California to cause cancer, and
Methanol, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.
P65Warnings.ca.gov.
Per the June 13, 2016 Federal Register notice, EPA harmonized the EPCRA 311/312 hazard categories with the 2012 OSHA hazard
communication standard for classifying and labeling of chemicals (i.e. GHS). Please refer to Section 2 of the SDS to identify the appropriate
hazard categories for reporting purposes.
U.S. Federal regulations
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Section 16. Other information
History
Version
Prepared by
AOC is a registered trademark of the AOC group of companies.
The information contained in this data sheet is based on laboratory data and field experience. We believe this information to be reliable, but do not
guarantee its applicability to the user s process or assume any liability for occurrences arising out of its use. The user, by accepting the products
as described herein, agrees to be responsible for thoroughly testing each such product before committing it to production.
Altek , Atryl , Atryl TCA , Chroma-Tek , EcoTek , FirePel , Hydropel , Moldtru , PulTru , Vibrin , Vicast , Vipel , the AOC name, the
AOC logo, and the Trusted Solutions logo are registered trademarks of the AOC group of companies.
Our recommendations should not be construed as inducements to infringe any patent or violate any law, safety code or insurance regulation.
The information and recommendations contained herein are to the best of our knowledge accurate and reliable, but no rights whatsoever may be
derived by any party other than those expressly agreed to with a selling entity of the AOC group of companies in a legally binding agreement. AOC
hereby makes no warranty of any kind, express or implied, including those of merchantability and fitness for purpose. Unless explicitly agreed to in
writing by AOC otherwise, all offers, quotations, sales and deliveries of AOC products are subject to the general conditions of sale of AOC.
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by
the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
11/19/2024
Not applicable.
1.0
National Fire Protection Association (U.S.A.)
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This
reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and
reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether
the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
AOC Corporate Regulatory Affairs
This Safety Data Sheet (SDS) and its content are the confidential and proprietary information of AOC and it may not be modified, altered,
deconstructed, or presented in any other manner, without the explicit authorization of AOC and/or its legal counsel.
1
3
2
Health
Special
Instability
Flammability
Date of issue
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