by | Sep 27, 2025
VINYL ESTER RESIN
Vinyl Ester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
VINYL ESTER RESIN
Relevant identified uses of the substance or mixture and uses advised against
Product code :CORVE8153
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 1.8%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 48%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 1.8%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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VINYL ESTER RESIN CORVE8153
Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Take off contaminated clothing and wash it before
reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Vinyl Ester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 47.0 100-42-5
cobalt bis(2-ethylhexanoate) <= 1.0 136-52-7
Ingredient name % CAS number
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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VINYL ESTER RESIN CORVE8153
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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VINYL ESTER RESIN CORVE8153
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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VINYL ESTER RESIN CORVE8153
Section 6. Accidental release measures
Wear protective clothing and eye or face protection:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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VINYL ESTER RESIN CORVE8153
Section 8. Exposure controls/personal protection
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2017).
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Aromatic. Sweetish.Odor
pH
VariousColor
Not applicable.
0.1 ppmOdor threshold
:
:
:
:
:
:
Appearance
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VINYL ESTER RESIN CORVE8153
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
0.9 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Viscosity Not available.
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
Boiling point :145 C (293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :46.6 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 1.22 g/kg –
Product/ingredient name Result Species Dose Exposure
Information on toxicological effects
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VINYL ESTER RESIN CORVE8153
Section 11. Toxicological information
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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VINYL ESTER RESIN CORVE8153
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Acute toxicity estimates
Name Result
styrene ASPIRATION HAZARD – Category 1
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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VINYL ESTER RESIN CORVE8153
Section 11. Toxicological information
Oral 5723.9 mg/kg
Inhalation (gases) 5983.1 ppm
Inhalation (vapors) 25.49 mg/l
Route ATE value
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % – Readily – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
:Disposal methods
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VINYL ESTER RESIN CORVE8153
Section 13. Disposal considerations
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 2160 lbs / 980.62 kg [235.5 gal / 891.47 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 311: styrene
:
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
TSCA 5(a)2 final significant new use rules: pentane-2,4-dione
TSCA 8(a) PAIR: pentane-2,4-dione; Poly(oxy-1,2-ethanediyl), -[4-(1,1,3,3-
tetramethylbutyl)phenyl]- -hydroxy-; 4-tert-butylpyrocatechol; Siloxanes and Silicones, di
-Me, reaction products with silica
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Styrene
Cobalt Compounds
Methanol
Hydroquinone
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VINYL ESTER RESIN CORVE8153
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENEMassachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Styrene
Methanol
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
COBALT compounds
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; COBALT COMPOUNDS
State regulations
SARA 302/304
SARA 304 RQ :500000 lbs / 227000 kg [54515.5 gal / 206363.6 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
Inventory list
Australia :All components are listed or exempted.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :All components are listed or exempted.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 47.0
cobalt bis(2-ethylhexanoate) 136-52-7 <= 1.0
styrene 100-42-5 46.30
cobalt bis(2-ethylhexanoate) 136-52-7 0.11
Any concentration shown as exact is based on formula.
Date of issue/Date of revision :9/4/2018 Date of previous issue :No previous validationVersion:1 12/14
VINYL ESTER RESIN CORVE8153
Section 15. Regulatory information
Republic of Korea :All components are listed or exempted.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :Not determined.
Section 16. Other information
9/4/2018
History
Date of printing :
:9/4/2018
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
CARCINOGENICITY - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
Date of issue/Date of revision :9/4/2018 Date of previous issue :No previous validationVersion:1 13/14
VINYL ESTER RESIN CORVE8153
Section 16. Other information
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
No previous validation
1
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
Date of issue/Date of revision :9/4/2018 Date of previous issue :No previous validationVersion:1 14/14
by | Sep 27, 2025
Vinyl Ester Base Resin
Vinyl Ester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
Vinyl Ester Base Resin
Relevant identified uses of the substance or mixture and uses advised against
Product code :CORVE8129
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 1.2%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 48.4%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 1.2%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Vinyl Ester Base Resin CORVE8129
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Vinyl Ester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 48.0 100-42-5
Ingredient name % CAS number
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Remove contaminated clothing and shoes. Flush contaminated skin with plenty of
water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Skin contact
Ingestion :
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Wear protective clothing and eye or face protection:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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Vinyl Ester Base Resin CORVE8129
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Aromatic.Odor
pH
Brown.Color
Evaporation rate <1 (butyl acetate = 1)
Flash point Closed cup: 31 C (87.8 F)
Not applicable.
0.1 ppmOdor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 C (293 F)
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Vinyl Ester Base Resin CORVE8129
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Not available.
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :47.3 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Vinyl Ester Base Resin CORVE8129
Section 11. Toxicological information
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
styrene - 2A Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A)
based on hazard assessment data. The United States NTP listed styrene as reasonably
anticipated to be a human carcinogen based on "limited evidence" from studies in
humans, "sufficient evidence" from studies in experimental animals, and supporting
data on mechanisms of carcinogenesis. The significance of these results for humans
has not been established through risk assessment.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 5623.4 mg/kg
Inhalation (gases) 5878.1 ppm
Inhalation (vapors) 25.04 mg/l
Route ATE value
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene - - Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % - Readily - 28 days - -
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
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Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 2122 lbs / 963.41 kg [221.31 gal / 837.75 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 311: styrene; propionic acid
:
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
TSCA 5(a)2 final significant new use rules: pentane-2,4-dione
TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me, reaction products with silica; pentane-
2,4-dione; N,N-dimethylaniline; 4-tert-butylpyrocatechol; triethyl phosphate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
SARA 302/304
Composition/information on ingredients
Listed
If components are "Listed", and additional information is required, contact Supplier
using email in Section 16.
Date of issue/Date of revision :3/17/2021 Date of previous issue :9/4/2018 Version:1.01 11/14
Vinyl Ester Base Resin CORVE8129
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENEMassachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Styrene
Form R - Reporting
requirements
Supplier notification
California Prop. 65
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-
State regulations
SARA 304 RQ :4347826.1 lbs / 1973913 kg [453437.1 gal / 1716446.1 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
Inventory list
Australia :Not determined.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :All components are listed or exempted.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 48.0
styrene 100-42-5 47.12
Any concentration shown as exact is based on formula.
Date of issue/Date of revision :3/17/2021 Date of previous issue :9/4/2018 Version:1.01 12/14
Vinyl Ester Base Resin CORVE8129
Section 16. Other information
3/17/2021
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Date of previous issue
:
:
:
:
:
3/17/2021
9/4/2018
1.01
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
New form 08-2018
Date of issue/Date of revision :3/17/2021 Date of previous issue :9/4/2018 Version:1.01 13/14
Vinyl Ester Base Resin CORVE8129
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
Date of issue/Date of revision :3/17/2021 Date of previous issue :9/4/2018 Version:1.01 14/14
by | Sep 27, 2025
Vinyl Ester Base Resin
Vinyl Ester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
Vinyl Ester Base Resin
Relevant identified uses of the substance or mixture and uses advised against
Product code :CORVE8125-30
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs,
liver, nervous system) – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
liver, nervous system)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 1.2%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 43.6%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 5.7%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 1/14
Vinyl Ester Base Resin CORVE8125-30
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Vinyl Ester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 38.0 100-42-5
Styrene, methyl- <= 5.0 25013-15-4
Ingredient name % CAS number
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 2/14
Vinyl Ester Base Resin CORVE8125-30
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Remove contaminated clothing and shoes. Flush contaminated skin with plenty of
water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 3/14
Vinyl Ester Base Resin CORVE8125-30
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 4/14
Vinyl Ester Base Resin CORVE8125-30
Section 6. Accidental release measures
Wear protective clothing and eye or face protection:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Styrene, methyl- ACGIH TLV (United States, 3/2019).
TWA: 50 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Vinyl Ester Base Resin CORVE8125-30
Section 8. Exposure controls/personal protection
TWA: 242 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 483 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours.
TWA: 480 mg/m 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 480 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 480 mg/m 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.9 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Aromatic. Sweetish.Odor
pH
VariousColor
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Not applicable.
Viscosity Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 to 168 C (293 to 334.4 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :43.1 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
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Vinyl Ester Base Resin CORVE8125-30
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Styrene, methyl- LD50 Oral Rat 2255 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Styrene, methyl- Eyes - Mild irritant Rabbit - 90 mg -
Skin - Moderate irritantRabbit - 100 % -
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Styrene, methyl- Category 3 Not applicable.Respiratory tract
irritation
Name Category Route of
exposure
Target organs
Information on toxicological effects
Classification
styrene - 2A Reasonably anticipated to be a human carcinogen.
Styrene, methyl- - 3 -
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A)
based on hazard assessment data. The United States NTP listed styrene as reasonably
anticipated to be a human carcinogen based on "limited evidence" from studies in
humans, "sufficient evidence" from studies in experimental animals, and supporting
data on mechanisms of carcinogenesis. The significance of these results for humans
has not been established through risk assessment.
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 8/14
Vinyl Ester Base Resin CORVE8125-30
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Name Category
styrene Category 1 Inhalation hearing organs
Styrene, methyl- Category 2 Not determinedliver and nervous
system
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 9/14
Vinyl Ester Base Resin CORVE8125-30
Section 11. Toxicological information
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 6142.4 mg/kg
Inhalation (gases) 7317.5 ppm
Inhalation (vapors) 31.17 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Styrene, methyl- 3.35 100 to 320 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene - - Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Styrene, methyl- Acute EC50 1 to 10 mg/l Fresh waterDaphnia - Daphnia magna 48 hours
Acute LC50 8.9 mg/l Marine water Crustaceans - Chaetogammarus
marinus - Young
48 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % - Readily - 28 days - -
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 10/14
Vinyl Ester Base Resin CORVE8125-30
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 2641.7 lbs / 1199.3 kg [288.03 gal / 1090.3 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
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Vinyl Ester Base Resin CORVE8125-30
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; VINYL TOLUENE;
METHYLSTYRENE
Clean Water Act (CWA) 311: styrene; propionic acid
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Form R - Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
VINYL TOLUENE; BENZENE, ETHENYLMETHYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; BENZENE,
ETHENYLMETHYL-
State regulations
TSCA 5(a)2 final significant new use rules: pentane-2,4-dione
TSCA 8(a) PAIR: vinyltoluene; Siloxanes and Silicones, di-Me, reaction products with
silica; pentane-2,4-dione; Poly(oxy-1,2-ethanediyl), -[4-(1,1,3,3-tetramethylbutyl)phenyl
]- -hydroxy-; cinnamaldehyde; bornan-2-one
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :666666.7 lbs / 302666.7 kg [72687.3 gal / 275151.5 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs, liver,
nervous system) - Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 38.0
styrene 100-42-5 37.85
Any concentration shown as exact is based on formula.
Listed
If components are "Listed", and additional information is required, contact Supplier
using email in Section 16.
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Vinyl Ester Base Resin CORVE8125-30
Section 15. Regulatory information
Styrene
Methanol
Inventory list
Australia :Not determined.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :All components are listed or exempted.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 13/14
Vinyl Ester Base Resin CORVE8125-30
Section 16. Other information
7/21/2022
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
7/21/2022
9/4/2018
2
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs,
liver, nervous system) - Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
Date of issue/Date of revision :7/21/2022 Date of previous issue :9/4/2018 Version:2 14/14
by | Sep 27, 2025
by | Sep 27, 2025
VINYL ESTER RESIN
Vinyl Ester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
VINYL ESTER RESIN
Material uses
Product code :CORVE8101-45SS
Product use :Industrial applications.
CHEMTREC 24-Hour Emergency Telephone 800.424.9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :8/1/2017 Date of previous issue :3/30/2016 Version:2 1/15
VINYL ESTER RESINCORVE8101-45SS
Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Take off contaminated clothing and wash it before
reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene <= 44.0 100-42-5
cobalt carboxylate <= 1.0 136-52-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of
identification
:Vinyl Ester Resin
CAS number :Not applicable.
Substance/mixture
Product code :CORVE8101-45SS
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as
exact is based on formula.
See Section 9 for VOC content. See Section 15 for HAP information.
Date of issue/Date of revision :8/1/2017 Date of previous issue :3/30/2016 Version:2 2/15
VINYL ESTER RESINCORVE8101-45SS
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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VINYL ESTER RESINCORVE8101-45SS
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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VINYL ESTER RESINCORVE8101-45SS
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
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VINYL ESTER RESINCORVE8101-45SS
Section 8. Exposure controls/personal protection
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2016).
TWA: 0.02 mg/m , (as Co) 8 hours.
Ingredient name Exposure limits
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
:
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
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VINYL ESTER RESINCORVE8101-45SS
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Liquid.
Not available.
0.9 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Aromatic. Sweetish.Odor
pH
VariousColor
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Not applicable.
Viscosity Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 C (293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Decomposition temperature:Not available.
Solubility in water :Not applicable.
VOC content (industrial use)44.1 % (w/w) As shipped. Including monomer.
Section 10. Stability and reactivity
The product is stable.Chemical stability :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision :8/1/2017 Date of previous issue :3/30/2016 Version:2 7/15
VINYL ESTER RESINCORVE8101-45SS
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Reactive or incompatible with the following materials:
oxidizing materials
:
:
Incompatible materials :
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 1.22 g/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Date of issue/Date of revision :8/1/2017 Date of previous issue :3/30/2016 Version:2 8/15
VINYL ESTER RESINCORVE8101-45SS
Section 11. Toxicological information
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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VINYL ESTER RESINCORVE8101-45SS
Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 6036.7 mg/kg
Inhalation (gases) 6310.1 ppm
Inhalation (vapors) 26.88 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
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VINYL ESTER RESINCORVE8101-45SS
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % – Readily – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
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VINYL ESTER RESINCORVE8101-45SS
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable
quantity
2278 lbs / 1034.
2 kg [248.37
gal / 940.19 L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
– –
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No. No.
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
–
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 311: styrene
:TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
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VINYL ESTER RESINCORVE8101-45SS
Section 15. Regulatory information
1,4-dihydroxybenzene 0.02 Yes.500 / 10000- 100 –
The following components are listed: STYRENE; PHENYLETHYLENE
WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
Massachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene Yes. No. No. No.
methanol No. Yes. No. 23000 g/day
(ingestion)
47000 g/day
(inhalation)
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
styrene 100-42-5 <= 44.0
cobalt bis(2-ethylhexanoate) 136-52-7 <= 1.0
styrene 100-42-5 43.90
cobalt bis(2-ethylhexanoate) 136-52-7 0.14
Form R - Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
COBALT compounds
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; COBALT COMPOUNDS
State regulations
SARA 302/304
SARA 304 RQ :500000 lbs / 227000 kg [54515.5 gal / 206363.6 L]
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene
cobalt bis(2-ethylhexanoate)
N,N-dimethylaniline
methanol
1,4-dihydroxybenzene
Date of issue/Date of revision :8/1/2017 Date of previous issue :3/30/2016 Version:2 13/15
VINYL ESTER RESINCORVE8101-45SS
Section 15. Regulatory information
Canada inventory :All components are listed or exempted.
Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory: All components are listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
Taiwan Chemical Substances Inventory (TCSI): All components are listed or
exempted.
Turkey inventory: Not determined.
International regulations
International lists :
Section 16. Other information
8/1/2017
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
8/1/2017
3/30/2016
2
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :8/1/2017 Date of previous issue :3/30/2016 Version:2 14/15
VINYL ESTER RESINCORVE8101-45SS
Section 16. Other information
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Indicates information that has changed from previously issued version.
References :OSHA Hazard Communication Standard, March 2012 (29 CFR 1910.1200)
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Health, Safety and Environmental Department
Email :For questions regarding the SDS contact:iasafety@ip-corporation.com
Date of issue/Date of revision :8/1/2017 Date of previous issue :3/30/2016 Version:2 15/15
by | Sep 27, 2025
Modified Vinyl Ester Resin
Vinyl Ester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
Modified Vinyl Ester Resin
Relevant identified uses of the substance or mixture and uses advised against
Product code :MVR8051-60
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
GERM CELL MUTAGENICITY – Category 1
CARCINOGENICITY – Category 2
TOXIC TO REPRODUCTION (Fertility) – Category 2
TOXIC TO REPRODUCTION (Unborn child) – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 34%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 3%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 1/15
Modified Vinyl Ester Resin MVR8051-60
Section 2. Hazards identification
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
May cause genetic defects.
Suspected of damaging fertility or the unborn child.
Suspected of causing cancer.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling. Contaminated work clothing must
not be allowed out of the workplace.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Vinyl Ester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
styrene <= 31.0 100-42-5
triethyl phosphate <= 5.0 78-40-0
Proprietary Proprietary -
2-hydroxyethyl methacrylate <= 1.0 868-77-9
cobalt bis(2-ethylhexanoate) <= 1.0 136-52-7
Ingredient name % CAS number
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 2/15
Modified Vinyl Ester Resin MVR8051-60
Section 3. Composition/information on ingredients
Environmental composition is shown in Section 15.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 3/15
Modified Vinyl Ester Resin MVR8051-60
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Skin contact
Ingestion Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
phosphorus oxides
halogenated compounds
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 4/15
Modified Vinyl Ester Resin MVR8051-60
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Wear protective clothing and eye or face protection:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 5/15
Modified Vinyl Ester Resin MVR8051-60
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
styrene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
triethyl phosphate AIHA WEEL (United States, 10/2011).
TWA: 7.45 mg/m 8 hours.
Proprietary None.
2-hydroxyethyl methacrylate None.
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2017).
TWA: 0.02 mg/m , (as Co) 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Control parameters
Individual protection measures
Occupational exposure limits
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Modified Vinyl Ester Resin MVR8051-60
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.9 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Aromatic. Sweetish.Odor
pH
VariousColor
Evaporation rate <1 (butyl acetate = 1)
Flash point Closed cup: 31 C (87.8 F)
Not available.
Not applicable.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 C (293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
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Modified Vinyl Ester Resin MVR8051-60
Section 9. Physical and chemical properties
Auto-ignition temperature Not available.
Viscosity Not available.
:
:
VOC content :35.7 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
triethyl phosphate LD50 Oral Rat 1165 mg/kg -
Proprietary LD50 Oral Rat 8210 mg/kg -
2-hydroxyethyl methacrylateLD50 Oral Rat 5050 mg/kg -
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 1.22 g/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
triethyl phosphate Eyes – Moderate irritantRabbit – 100 –
Product/ingredient name Result Score Exposure ObservationSpecies
Information on toxicological effects
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 8/15
Modified Vinyl Ester Resin MVR8051-60
Section 11. Toxicological information
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
milligrams
Proprietary Eyes – Mild irritant Rabbit – 0.1 Mililiters-
Skin – Mild irritant Rabbit – 24 hours 0.5
milligrams
–
Sensitization
Not available.
Information on the likely
routes of exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 9/15
Modified Vinyl Ester Resin MVR8051-60
Section 11. Toxicological information
Not available.
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
May cause genetic defects.Mutagenicity :
Suspected of damaging the unborn child.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :Suspected of damaging fertility.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Acute toxicity estimates
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 10/15
Modified Vinyl Ester Resin MVR8051-60
Section 11. Toxicological information
Oral 6995 mg/kg
Inhalation (gases) 8941 ppm
Inhalation (vapors) 38.09 mg/l
Route ATE value
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
triethyl phosphate 1.11 <1.3 low
Proprietary -0.61 - low
2-hydroxyethyl methacrylate0.42 - low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene - - Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
triethyl phosphate Acute LC50 2100000 to 2400000 g/l
Marine water
Fish - Alburnus alburnus 96 hours
2-hydroxyethyl methacrylateAcute LC50 227000 g/l Fresh waterFish - Pimephales promelas -
Juvenile (Fledgling, Hatchling,
Weanling)
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % - Readily - 28 days - -
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 11/15
Modified Vinyl Ester Resin MVR8051-60
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 3227.8 lbs / 1465.4 kg [351.93 gal / 1332.2 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 12/15
Modified Vinyl Ester Resin MVR8051-60
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE
Clean Water Act (CWA) 307: ethylbenzene
Clean Water Act (CWA) 311: styrene; ethylbenzene; xylene
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Form R - Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
COBALT compounds
State regulations
TSCA 8(a) PAIR: Poly(oxy-1,2-ethanediyl), -[4-(1,1,3,3-tetramethylbutyl)phenyl]- -
hydroxy-; triethyl phosphate; mequinol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
Commerce control list precursor: Proprietary; dimethyl phosphonate
SARA 302/304
SARA 304 RQ :666666.7 lbs / 302666.7 kg [72687.3 gal / 275151.5 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
GERM CELL MUTAGENICITY - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Fertility) - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
styrene 100-42-5 <= 31.0
cobalt bis(2-ethylhexanoate) 136-52-7 <= 1.0
styrene 100-42-5 30.98
cobalt bis(2-ethylhexanoate) 136-52-7 0.13
Any concentration shown as exact is based on formula.
Listed
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 13/15
Modified Vinyl Ester Resin MVR8051-60
Section 15. Regulatory information
Styrene
Ethylbenzene
California Prop. 65
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; COBALT COMPOUNDS
Inventory list
Australia :Not determined.
Canada :At least one component is not listed in DSL but all such components are listed in NDSL.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :Not determined.
Malaysia :Not determined.
New Zealand :Not determined.
Philippines :Not determined.
Taiwan :Not determined.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :Not determined.
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 14/15
Modified Vinyl Ester Resin MVR8051-60
Section 16. Other information
10/11/2018
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
10/11/2018
9/4/2018
1.01
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
GERM CELL MUTAGENICITY - Category 1 Calculation method
CARCINOGENICITY - Category 2 Calculation method
TOXIC TO REPRODUCTION (Fertility) - Category 2 Calculation method
TOXIC TO REPRODUCTION (Unborn child) - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
Date of issue/Date of revision :10/11/2018 Date of previous issue :9/4/2018 Version:1.01 15/15
by | Sep 27, 2025
MODIFIED VINYL ESTER RESIN
Vinyl Ester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
MODIFIED VINYL ESTER RESIN
Relevant identified uses of the substance or mixture and uses advised against
Product code :MVR8031
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 1.5%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 48.4%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 1.5%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :9/4/2018 Date of previous issue :No previous validationVersion:1 1/14
MODIFIED VINYL ESTER RESIN MVR8031
Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Take off contaminated clothing and wash it before
reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Vinyl Ester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 47.0 100-42-5
cobalt bis(2-ethylhexanoate) <= 1.0 136-52-7
Ingredient name % CAS number
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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Section 6. Accidental release measures
Wear protective clothing and eye or face protection:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2017).
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Aromatic. Sweetish.Odor
pH
VariousColor
Not applicable.
0.1 ppmOdor threshold
:
:
:
:
:
:
Appearance
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
0.9 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Viscosity Not available.
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
Boiling point :145 C (293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :47 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 1.22 g/kg –
Product/ingredient name Result Species Dose Exposure
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
Styrene is listed by IARC as a possible carcinogen to humans (Group 2B) based on
“limited evidence” in humans, “limited evidence” in animals and “other relevant data”.
The United States NTP listed styrene as reasonably anticipated to be a human
carcinogen based on “limited evidence” from studies in humans, “sufficient evidence”
from studies in experimental animals, and supporting data on mechanisms of
carcinogenesis. The significance of these results for humans has not been established
through risk assessment.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Acute toxicity estimates
Name Result
styrene ASPIRATION HAZARD – Category 1
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Section 11. Toxicological information
Oral 5653.4 mg/kg
Inhalation (gases) 5909.4 ppm
Inhalation (vapors) 25.17 mg/l
Route ATE value
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % – Readily – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
:Disposal methods
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Section 13. Disposal considerations
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 2133.4 lbs / 968.55 kg [232.6 gal / 880.5 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307: Naphthenic acids, copper salts
Clean Water Act (CWA) 311: styrene
:
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
TSCA 8(a) PAIR: 4-tert-butylpyrocatechol; N,N-dimethylaniline; Siloxanes and Silicones,
di-Me, reaction products with silica; Siloxanes and Silicones, di-Me, reaction products
with silica
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Styrene
Quinone
Cobalt Compounds
Cobalt Compounds
Cobalt Compounds
N,N-Diethyl aniline
Methanol
Hydroquinone
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Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENEMassachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Styrene
Methanol
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
COBALT compounds
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; COBALT COMPOUNDS
State regulations
SARA 302/304
SARA 304 RQ :1000000 lbs / 454000 kg [109031 gal / 412727.3 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
Inventory list
Australia :All components are listed or exempted.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Malaysia :Not determined.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 47.0
cobalt bis(2-ethylhexanoate) 136-52-7 <= 1.0
styrene 100-42-5 46.87
cobalt bis(2-ethylhexanoate) 136-52-7 0.11
Any concentration shown as exact is based on formula.
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Section 15. Regulatory information
Republic of Korea :All components are listed or exempted.
New Zealand :All components are listed or exempted.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :Not determined.
Section 16. Other information
History
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
CARCINOGENICITY - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
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MODIFIED VINYL ESTER RESIN MVR8031
Section 16. Other information
9/4/2018Date of printing
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
9/4/2018
No previous validation
1
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
Date of issue/Date of revision :9/4/2018 Date of previous issue :No previous validationVersion:1 14/14
by | Sep 27, 2025
Polymer Concrete Resin
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :IP CORPORATION
1225 Willow Lake Blvd
St. Paul, MN 55110
651-481-6860
Polymer Concrete Resin
Relevant identified uses of the substance or mixture and uses advised against
Product code :SIL07BS-2967VW
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
liver, nervous system)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation
toxicity: 24.9%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Polymer Concrete Resin SIL07BS-2967VW
Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use
explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools.
Take action to prevent static discharges. Use only outdoors or in a well-ventilated area.
Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash
thoroughly after handling.
Response :Get medical advice or attention if you feel unwell. IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel
unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water. If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of
identification
:Unsaturated Polyester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
Styrene, methyl- <= 25.0 25013-15-4
styrene <= 23.0 100-42-5
Ingredient name % CAS number
Get medical attention following exposure or if feeling unwell.
Continue to rinse for at least 10 minutes. Get medical attention.
If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary,
call a poison center or physician.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Causes serious eye irritation.:Eye contact
Potential acute health effects
Get medical attention. Buffered baby shampoo will aid in removal of resin.
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Polymer Concrete Resin SIL07BS-2967VW
Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
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Polymer Concrete Resin SIL07BS-2967VW
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:
No specific hazard.
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. See also
Section 8 for additional information on hygiene measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Separate from oxidizing materials. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Take precautionary measures against electrostatic discharges.
:
Precautions for safe handling
vinyltoluene NIOSH REL (United States, 10/2020) [VINYL TOLUENE]
TWA 10 hours: 100 ppm.
TWA 10 hours: 480 mg/m .
CAL OSHA PEL (United States, 5/2018)
TWA 8 hours: 240 mg/m .
TWA 8 hours: 50 ppm.
OSHA PEL (United States, 5/2018)
TWA 8 hours: 100 ppm.
TWA 8 hours: 480 mg/m .
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 100 ppm.
TWA 8 hours: 480 mg/m .
ACGIH TLV (United States, 1/2024) A4.
TWA 8 hours: 10 ppm.
styrene NIOSH REL (United States, 10/2020)
TWA 10 hours: 50 ppm.
TWA 10 hours: 215 mg/m .
STEL 15 minutes: 100 ppm.
STEL 15 minutes: 425 mg/m .
OSHA PEL Z2 (United States, 2/2013)
TWA 8 hours: 100 ppm.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Polymer Concrete Resin SIL07BS-2967VW
Section 8. Exposure controls/personal protection
CEIL: 200 ppm.
AMP 5 minutes: 600 ppm.
CAL OSHA PEL (United States, 5/2018) Absorbed through
skin.
STEL 15 minutes: 425 mg/m .
STEL 15 minutes: 100 ppm.
C: 500 ppm.
TWA 8 hours: 215 mg/m .
TWA 8 hours: 50 ppm.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 50 ppm.
TWA 8 hours: 215 mg/m .
STEL 15 minutes: 100 ppm.
STEL 15 minutes: 425 mg/m .
ACGIH TLV (United States, 1/2024) A3. Ototoxicant.
TWA 8 hours: 10 ppm.
STEL 15 minutes: 20 ppm.
Hand protection
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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Polymer Concrete Resin SIL07BS-2967VW
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Liquid. [Liquid.]
Not applicable.
0.9 to 1.3
3.6 [Air = 1]
0.2 to 0.67 kPa (1.5 to 5 mm Hg)
Aromatic. Sweetish.Odor
pH
VariousColor
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >31 C (>87.8 F)
Not applicable.
Not applicable.
Viscosity Dynamic (room temperature): Not available.
Kinematic (room temperature): Not available.
Kinematic (40 C (104 F)): Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 to 168 C (293 to 334.4 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :47.6 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys., brass.
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Polymer Concrete Resin SIL07BS-2967VW
Section 11. Toxicological information
Acute toxicity
Styrene, methyl- LD50 Oral Rat 2255 mg/kg –
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Styrene, methyl- Eyes – Mild irritant Rabbit – 90 mg –
Skin – Moderate irritantRabbit – 100 % –
styrene Eyes – Mild irritant Human – 50 ppm –
Eyes – Moderate irritantRabbit – 24 hours 100
mg
–
Eyes – Severe irritantRabbit – 100 mg –
Skin – Mild irritant Rabbit – 500 mg –
Skin – Moderate irritantRabbit – 100 % –
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Styrene, methyl- Category 3 – Respiratory tract
irritation
styrene Category 3 – Respiratory tract
irritation
Name Category Route of
exposure
Target organs
Information on toxicological effects
Classification
Styrene, methyl- – 3 –
styrene – 2A Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A)
based on hazard assessment data. The United States NTP listed styrene as reasonably
anticipated to be a human carcinogen based on “limited evidence” from studies in
humans, “sufficient evidence” from studies in experimental animals, and supporting data
on mechanisms of carcinogenesis. The significance of these results for humans has not
been established through risk assessment.
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Polymer Concrete Resin SIL07BS-2967VW
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Name Category
Styrene, methyl- Category 2 – liver, nervous
system
styrene Category 1 inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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Polymer Concrete Resin SIL07BS-2967VW
Section 11. Toxicological information
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 5171.59 mg/kg
Inhalation (gases) 9447.38 ppm
Inhalation (vapors) 40.25 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene, methyl- 3.35 100 to 320 Low
styrene 2.96 13.49 Low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
Styrene, methyl- Acute EC50 1 to 10 mg/l Fresh waterDaphnia – Daphnia magna 48 hours
Acute LC50 8.9 mg/l Marine water Crustaceans – Chaetogammarus
marinus – Young
48 hours
styrene Acute EC50 1400 g/l Fresh water Algae – Raphidocelis subcapitata72 hours
Acute EC50 720 g/l Fresh water Algae – Raphidocelis subcapitata96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina 48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Raphidocelis subcapitata96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % – Readily – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
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Polymer Concrete Resin SIL07BS-2967VW
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 4538.7 lbs / 2060.6 kg [494.86 gal / 1873.2 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMO/IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Section 15. Regulatory information
U.S. Federal regulations
Listed
Listed
:
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
TSCA 8(a) PAIR: vinyltoluene; Poly(oxy-1,2-ethanediyl), -[4-(1,1,3,3-tetramethylbutyl)
phenyl]- -hydroxy-; cinnamaldehyde; N,N-dimethylaniline; bornan-2-one; 4-tert-
butylpyrocatechol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Listed
Clean Water Act (CWA) 307
Clean Water Act (CWA) 311
:
:
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Polymer Concrete Resin SIL07BS-2967VW
Section 15. Regulatory information
The following components are listed: VINYL TOLUENE; STYRENEMassachusetts :
SARA 313
Product name CAS number %
Styrene
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: VINYL TOLUENE; STYRENE MONOMER
Pennsylvania :The following components are listed: BENZENE, ETHENYLMETHYL-; BENZENE,
ETHENYL-
State regulations
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
Inventory list
Australia :Not determined.
Canada :All components are listed or exempted.
China :Not determined.
Eurasian Economic Union :Russian Federation inventory: Not determined.
Japan :Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined
New Zealand :Not determined.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Thailand :Not determined.
SARA 311/312
Classification :FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) –
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 23.0
styrene 100-42-5 22.03
If components are "Listed" for CWA or CAA and additional information is required, contact Supplier using email in
Section 16.
Not available.:Europe inventory
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Polymer Concrete Resin SIL07BS-2967VW
Section 15. Regulatory information
Turkey :Not determined.
United States :
Viet Nam :All components are listed or exempted.
All components are active or exempted.
Section 16. Other information
2/2/2025
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Date of previous issue
:
:
:
:
:
2/2/2025
10/18/2023
2
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method
Health, Safety and Environmental Department
New form 08-2018
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Polymer Concrete Resin SIL07BS-2967VW
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
Date of issue/Date of revision :2/2/2025 Date of previous issue :10/18/2023 Version:2 13/13
by | Sep 27, 2025
Polymer Concrete Resin
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :IP CORPORATION
1225 Willow Lake Blvd
St. Paul, MN 55110
651-481-6860
Polymer Concrete Resin
Relevant identified uses of the substance or mixture and uses advised against
Product code :SIL07BS-2967VS
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
liver, nervous system)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation
toxicity: 25%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Polymer Concrete Resin SIL07BS-2967VS
Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use
explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools.
Take action to prevent static discharges. Use only outdoors or in a well-ventilated area.
Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash
thoroughly after handling.
Response :Get medical advice or attention if you feel unwell. IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel
unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water. If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of
identification
:Unsaturated Polyester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
Styrene, methyl- <= 25.0 25013-15-4
styrene <= 22.0 100-42-5
Ingredient name % CAS number
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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Polymer Concrete Resin SIL07BS-2967VS
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Remove contaminated clothing and shoes. Flush contaminated skin with plenty of
water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Skin contact
Ingestion :
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Polymer Concrete Resin SIL07BS-2967VS
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local
regulations.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Section 7. Handling and storage
Precautions for safe handling
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Polymer Concrete Resin SIL07BS-2967VS
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
vinyltoluene NIOSH REL (United States, 10/2020) [VINYL TOLUENE]
TWA 10 hours: 100 ppm.
TWA 10 hours: 480 mg/m .
CAL OSHA PEL (United States, 5/2018)
TWA 8 hours: 240 mg/m .
TWA 8 hours: 50 ppm.
OSHA PEL (United States, 5/2018)
TWA 8 hours: 100 ppm.
TWA 8 hours: 480 mg/m .
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 100 ppm.
TWA 8 hours: 480 mg/m .
ACGIH TLV (United States, 1/2024) A4.
TWA 8 hours: 10 ppm.
styrene NIOSH REL (United States, 10/2020)
TWA 10 hours: 50 ppm.
TWA 10 hours: 215 mg/m .
STEL 15 minutes: 100 ppm.
STEL 15 minutes: 425 mg/m .
OSHA PEL Z2 (United States, 2/2013)
TWA 8 hours: 100 ppm.
CEIL: 200 ppm.
AMP 5 minutes: 600 ppm.
CAL OSHA PEL (United States, 5/2018) Absorbed through
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Polymer Concrete Resin SIL07BS-2967VS
Section 8. Exposure controls/personal protection
skin.
STEL 15 minutes: 425 mg/m .
STEL 15 minutes: 100 ppm.
C: 500 ppm.
TWA 8 hours: 215 mg/m .
TWA 8 hours: 50 ppm.
OSHA PEL 1989 (United States, 3/1989)
TWA 8 hours: 50 ppm.
TWA 8 hours: 215 mg/m .
STEL 15 minutes: 100 ppm.
STEL 15 minutes: 425 mg/m .
ACGIH TLV (United States, 1/2024) A3. Ototoxicant.
TWA 8 hours: 10 ppm.
STEL 15 minutes: 20 ppm.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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Polymer Concrete Resin SIL07BS-2967VS
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Liquid. [Liquid.]
Not applicable.
0.9 to 1.3
3.6 [Air = 1]
0.2 to 0.67 kPa (1.5 to 5 mm Hg)
Aromatic. Sweetish.Odor
pH
VariousColor
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >31 C (>87.8 F)
Not applicable.
Not applicable.
Viscosity Dynamic (room temperature): Not available.
Kinematic (room temperature): Not available.
Kinematic (40 C (104 F)): Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 to 168 C (293 to 334.4 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :47.7 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys., brass.
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Polymer Concrete Resin SIL07BS-2967VS
Section 11. Toxicological information
Acute toxicity
Styrene, methyl- LD50 Oral Rat 2255 mg/kg –
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Styrene, methyl- Eyes – Mild irritant Rabbit – 90 mg –
Skin – Moderate irritantRabbit – 100 % –
styrene Eyes – Mild irritant Human – 50 ppm –
Eyes – Moderate irritantRabbit – 24 hours 100
mg
–
Eyes – Severe irritantRabbit – 100 mg –
Skin – Mild irritant Rabbit – 500 mg –
Skin – Moderate irritantRabbit – 100 % –
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Styrene, methyl- Category 3 – Respiratory tract
irritation
styrene Category 3 – Respiratory tract
irritation
Name Category Route of
exposure
Target organs
Information on toxicological effects
Classification
Styrene, methyl- – 3 –
styrene – 2A Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A)
based on hazard assessment data. The United States NTP listed styrene as reasonably
anticipated to be a human carcinogen based on “limited evidence” from studies in
humans, “sufficient evidence” from studies in experimental animals, and supporting data
on mechanisms of carcinogenesis. The significance of these results for humans has not
been established through risk assessment.
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Polymer Concrete Resin SIL07BS-2967VS
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Name Category
Styrene, methyl- Category 2 – liver, nervous
system
styrene Category 1 inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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Polymer Concrete Resin SIL07BS-2967VS
Section 11. Toxicological information
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 5168.26 mg/kg
Inhalation (gases) 9470 ppm
Inhalation (vapors) 40.34 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene, methyl- 3.35 100 to 320 Low
styrene 2.96 13.49 Low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
Toxicity
Styrene, methyl- Acute EC50 1 to 10 mg/l Fresh waterDaphnia – Daphnia magna 48 hours
Acute LC50 8.9 mg/l Marine water Crustaceans – Chaetogammarus
marinus – Young
48 hours
styrene Acute EC50 1400 g/l Fresh water Algae – Raphidocelis subcapitata72 hours
Acute EC50 720 g/l Fresh water Algae – Raphidocelis subcapitata96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina 48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Raphidocelis subcapitata96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % – Readily – 28 days – –
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
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Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 4555.4 lbs / 2068.2 kg [496.69 gal / 1880.2 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMO/IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
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Polymer Concrete Resin SIL07BS-2967VS
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: VINYL TOLUENE; STYRENE
Listed
Listed
Massachusetts
:
:
SARA 313
Product name CAS number %
Styrene
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: VINYL TOLUENE; STYRENE MONOMER
Pennsylvania :The following components are listed: BENZENE, ETHENYLMETHYL-; BENZENE,
ETHENYL-
State regulations
TSCA 8(a) PAIR: vinyltoluene; Poly(oxy-1,2-ethanediyl), -[4-(1,1,3,3-tetramethylbutyl)
phenyl]- -hydroxy-; triethyl phosphate; cinnamaldehyde; bornan-2-one
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
SARA 302/304
SARA 304 RQ :689655.2 lbs / 313103.4 kg [75193.8 gal / 284639.5 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
Inventory list
Australia :Not determined.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 22.0
styrene 100-42-5 21.95
Listed
If components are "Listed" for CWA or CAA and additional information is required, contact Supplier using email in
Section 16.
Clean Water Act (CWA) 307
Clean Water Act (CWA) 311
:
:
Date of issue/Date of revision :2/2/2025 Date of previous issue :3/7/2024 Version:3 12/14
Polymer Concrete Resin SIL07BS-2967VS
Section 15. Regulatory information
Canada :All components are listed or exempted.
China :Not determined.
Eurasian Economic Union :Russian Federation inventory: Not determined.
Japan :Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined
New Zealand :Not determined.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :
Thailand :Not determined.
Viet Nam :All components are listed or exempted.
All components are active or exempted.
Not available.:Europe inventory
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Date of issue/Date of revision :2/2/2025 Date of previous issue :3/7/2024 Version:3 13/14
Polymer Concrete Resin SIL07BS-2967VS
Section 16. Other information
2/2/2025
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
2/2/2025
3/7/2024
3
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
Date of issue/Date of revision :2/2/2025 Date of previous issue :3/7/2024 Version:3 14/14
by | Sep 27, 2025
Dual Purpose Marble Resin
Unsaturated Polyester Resin
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
Dual Purpose Marble Resin
Relevant identified uses of the substance or mixture and uses advised against
Product code :SIL94BA-990
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 28.8%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Dual Purpose Marble Resin SIL94BA-990
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 29.0 100-42-5
Ingredient name % CAS number
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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Dual Purpose Marble Resin SIL94BA-990
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Remove contaminated clothing and shoes. Flush contaminated skin with plenty of
water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Skin contact
Ingestion :
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Dual Purpose Marble Resin SIL94BA-990
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Wear protective clothing and eye or face protection:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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Dual Purpose Marble Resin SIL94BA-990
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Dual Purpose Marble Resin SIL94BA-990
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Characteristic.Odor
pH
VariousColor
Evaporation rate <1 (butyl acetate = 1)
Flash point Closed cup: 31.1 C (88 F)
Not applicable.
0.1 ppmOdor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 C (293 F)
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Dual Purpose Marble Resin SIL94BA-990
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1 to 1.2
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Not available.
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :28.9 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Hazardous polymerization may occur under certain conditions of storage or use. Keep
away from heat and direct sunlight. Keep away from heat and flame. Keep away from
oxidizing agents.
Reactive or incompatible with the following materials: metals, acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids. Incompatible with copper alloys, brass.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Dual Purpose Marble Resin SIL94BA-990
Section 11. Toxicological information
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
styrene - 2A Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A)
based on hazard assessment data. The United States NTP listed styrene as reasonably
anticipated to be a human carcinogen based on "limited evidence" from studies in
humans, "sufficient evidence" from studies in experimental animals, and supporting
data on mechanisms of carcinogenesis. The significance of these results for humans
has not been established through risk assessment.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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Dual Purpose Marble Resin SIL94BA-990
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 9189.7 mg/kg
Inhalation (gases) 9605.9 ppm
Inhalation (vapors) 40.92 mg/l
Route ATE value
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Dual Purpose Marble Resin SIL94BA-990
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene - - Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % - Readily - 28 days - -
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision :7/13/2021 Date of previous issue :9/7/2018 Version:1.01 10/14
Dual Purpose Marble Resin SIL94BA-990
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 3467.8 lbs / 1574.4 kg [378.1 gal / 1431.3 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Section 15. Regulatory information
U.S. Federal regulations TSCA 4(a) proposed test rules: Quaternary ammonium compounds, benzyl-
C12-16-alkyldimethyl, chlorides
Clean Water Act (CWA) 307: Naphthenic acids, copper salts; 2-ethylhexanoic acid,
copper salt
Clean Water Act (CWA) 311: styrene; propionic acid
:
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
TSCA 5(a)2 final significant new use rules: pentane-2,4-dione
TSCA 8(a) PAIR: pentane-2,4-dione; triethyl phosphate
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
TSCA 8(c) calls for record of SAR: triethyl phosphate
Listed
If components are "Listed", and additional information is required, contact Supplier
using email in Section 16.
Date of issue/Date of revision :7/13/2021 Date of previous issue :9/7/2018 Version:1.01 11/14
Dual Purpose Marble Resin SIL94BA-990
Section 15. Regulatory information
The following components are listed: STYRENE; PHENYLETHYLENEMassachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Styrene
Form R - Reporting
requirements
Supplier notification
California Prop. 65
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-
Pennsylvania :The following components are listed: BENZENE, ETHENYL-
State regulations
SARA 302/304
SARA 304 RQ :3666006.3 lbs / 1664366.9 kg [399708.4 gal / 1513060.8 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
Inventory list
Australia :Not determined.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :Not determined.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 29.0
styrene 100-42-5 28.84
Any concentration shown as exact is based on formula.
Date of issue/Date of revision :7/13/2021 Date of previous issue :9/7/2018 Version:1.01 12/14
Dual Purpose Marble Resin SIL94BA-990
Section 15. Regulatory information
Viet Nam :All components are listed or exempted.
Section 16. Other information
7/13/2021
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Date of previous issue
:
:
:
:
:
7/13/2021
9/7/2018
1.01
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) -
Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
New form 08-2018
Date of issue/Date of revision :7/13/2021 Date of previous issue :9/7/2018 Version:1.01 13/14
Dual Purpose Marble Resin SIL94BA-990
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
Date of issue/Date of revision :7/13/2021 Date of previous issue :9/7/2018 Version:1.01 14/14
