37WA140A_SDS.pdf

Safety Data Sheet PARTALL Paste #2
PARTALL Paste #2
Safety Data Sheet Version: 5.2
according to OSHA HCS and GHS Canada WHMIS 2015 Revision date: 2023 11 09
Print date: 2023 11 10
SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product Identifier
Product form : Mixture
Trade name : PARTALL Paste #2
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses : Industrial; release agent
Uses advised against : Do not use for purposes other than those listed
1.3 Details of the supplier of the safety data sheet
Supplier : REXCO
P.O. Box 80996
Conyers, GA 30013
U.S.A.
Telephone : 1 770 483 7610
Fax : 1 770 483 8550
Email : info@rexco usa.com
Website : www.rexco usa.com
1.4 Emergency telephone number
Chemtrec (24 hours/day) : 1 800 434 9300 (USA and Canada)
: 1 703 527 3887 (international; collect calls accepted)
SECTION 2. Hazards Identification
2.1 Classification of the substance or mixture
Classification according to OSHA HCS and GHS Canada WHMIS 2015
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways
See section 16 for full text of H phrases.
2.2 Label elements
Labeling according to the Globally Harmonized System (GHS)
Pictograms
Signal word :Danger
Hazard statements
H304 May be fatal if swa llowed and enters airways
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doct or.
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Safety Data Sheet PARTALL Paste #2
P331 Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regi onal/national/international regulations.
2.3 Other hazards
Material does not meet the criteria for PBT or vPvB in accordance with REACH Annex XIII.
SECTION 3. Composition/information on ingredients
3.1 Substances
Not applicable. This material is not defined as a substance.
3.2 Mixtures
This material is defined as a mixture.
Components contributing to the classification of this material %
Distillates (petroleum), hydrotreated light 70 80
CAS No. 64742 47 8
Asp. Tox. 1, H304
SECTION 4. First aid measures
General information
4.1 Description of first aid measures
Inhalation
Skin
Eyes
Ingestion
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment
Treat symptomatically. Seek immediate medical attention if ingested.
SECTION 5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Components not listed are either non hazardous or are below reportable limits. Concentrations are in percent by weight.
Do not leave victim unattended. Show this safety data sheet to doctor in attendance.
Provide fresh air if light headed or having difficulty breathing. Provide artificial respiration if needed. If difficulty breathing persists, seek medical attention.
If unconscious, place victim on their side for transport to medical facility.
Remove contaminated clothing and wash affected area with soap and warm water. If irritation persists, seek medical attention. Launder contaminated
clothing and shoes prior to reuse.
Flush immediately with cold water for 15 minutes. Remove contact lenses. Keep eye wide open while rinsing. Get prompt medical attention.
Seek immediate medical attention. Do not induce vomiting. If spontaneous vomiting occurs keep victim s head below hips to prevent aspiration into lungs.
Do not leave individual unattended.
Can cause eye irritation. May cause skin irritation. If swallowed, can cause nausea and vomiting with danger of Chemical Pneumonia. Prolonged or repeated
exposure may result in conjunctiva, skin dermatitis, and central nervous system depression, including headache, dizziness, loss of coordination, and
unconsciousness.
Standard procedure for chemical fires. Use dry chemicals or foam. Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
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Safety Data Sheet PARTALL Paste #2
Unsuitable extinguishing media
5.2 Special hazards arising from the substance or mixture
Hazardous decomposition products formed during combusion
Carbon oxides
5.3 Advice for firefighters
SECTION 6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning up
6.4 Reference to other sections
SECTION 7. Handling and storage
See section 1.2
SECTION 8. Exposure controls/personal protection
Ingredients with limit values that require monitoring:
Contains no substances with occupational exposure limit values.
Ingredients with biological monitoring guidance values (BMGV) and/or biological exposure index (BEI):
Contains no substances with biological monitoring guidance values.
Do not use high volume water jet. Avoid spreading burning liquid with water used for cooling purposes.
8.1 Control parameters
None inherent to this product.
Evacuate area. Firefighters should use standard protective equipment and should use self contained breathing apparatus in enclosed spaces. Use water
spray to cool surfaces exposed to fire and to protect personnel.
Use personal protective equipment. Ensure adequate ventilation. Keep sources of ignition and hot metal surfaces isolated from spill.
Prevent product from entering drains, waterways, sewers, and soil. Stop spill at source and prevent further leakage or spillage if safe to do so. Notify proper
authorities if product enters sewers or public waters.
Confine spill and place into suitable, closed container for disposal. Dispose of in accordance with regional, national, and local laws and regulations.
Section 7: safe handling. Section 8: personal and protective equipment. Section 10: incompatible materials. Section 13: disposal information. Section 16: full
text of abbreviations.
7.1 Precautions for safe handling
Use in a well ventilated area or use appropriate respirator when ventilation is inadequate. Do not breathe vapor. Wear personal protective clothing and
equipment as indicated in Section 8. Eliminate all sources of ignition. Do not ingest. Use good industrial hygiene practices in handling this material. Do not
smoke, eat or drink while using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and leaving
work. Clean up spills as soon as they occur. Empty containers may contain residual amounts of this product and should be handled with care. Do not reuse
containers.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in a dry, cool and well ventilated area away from direct sunlight. Avoid freezing. Store away from
incompatible materials (see Section 10) and food and drink. Store in original container. Keep container tightly closed when not in use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Provide appr
opriate fire extinguishers
and spill cleanup equipment in or near storage area. Keep unauthorized personnel away.
7.3 Specific end uses
8.2 Exposure controls
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Safety Data Sheet PARTALL Paste #2
Wear chemical resistant clothing and shoes. Safety showers are recommended for the work area.
SECTION 9. Physical and chemical properties
Physical state :Solid
Colour :Green or White
Odour :Aliphatic
Melting point :48 C (120 F)
Freezing point :No data available
Initial boiling point and boiling range :No data available
Flammability :Not classified
Upper flammability limit :Not applicable
Lower flammability limit :Not applicable
Flash point :> 80 C (> 176 F)
Auto ignition temperature :No data available
Decomposition temperature :No data available
pH :No data available
Viscosity :Not applicable
Solubility (water) :Not soluble
Partition coefficient n octanol/water (log value) :No data available
Vapour pressure :No data available
Relative density at 24 C (water = 1) :0.76 0.80
Volatile organic compounds (VOC)
VOC actual :562 g/L
VOC less water & exempt solvents :562 g/L
SECTION 10. Stability and reactivity
Not reactive under normal conditions of use.
Stable under normal conditions of use.
Hand protection
Engineering controls
Provide adequate local exhaust ventilation. Maintain eye wash fountain and safety shower in work area.
Personal protective equipment
General protective and hygenic measures
Do not eat, drink, or smoke while using. Wash hands before breaks and at the end of workday. Immediately remove all soiled or contaminated clothing.
Eye and face protection
Chemical safety glasses with side shields, goggles or face shield are recommended. Eye wash stations are recommended for the work area.
Skin and body protection
Respiratory protection
Provide sufficient general and/or local exhaust. If engineering controls are not sufficient to protect worker health use a half face filter respirator suitable for
organic vapor approved under applicable regulatory standards.
Wear chemical resistant impervious gloves: Viton, Nitrile. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove sel
ection and breakthrough times for your use conditions. Inspect and replace worn or damaged
gloves.
Environmental controls
Prevent product from entering drains. Stop spill at source and prevent further leakage or spillage if safe to do so. If product contaminates rivers and lakes or
drains, notify proper authorities.
10.1 Reactivity
10.2 Chemical stability
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Safety Data Sheet PARTALL Paste #2
No dangerous reactions known under normal conditions of use.
Avoid heat, sparks, open flames, hot surfaces, or other sources of ignition.
SECTION 11. Toxicological Information
Acute toxicity : Not classified
LD/LC50 values that are relevant for classification:
Distillates (petroleum), hydrotreated light
CAS No. 64742 47 8
LD50 rat > 5000 mg/kg
LD50 rabbit 2000 4000 mg/kg
LC50 rat > 0.5 mg/l/4h
Skin corrosion/irritation : Expec ted to be slightly irritating
Serious eye damage/irritation : Exp ected to be slightly irritating
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT single exposure : Not classified
STOT repeated exposure : Not classified
Aspiration hazard :
SECTION 12: Ecological information
12.1 Toxicity : Not expected to be toxic.
12.2 Persistence and degradability : Expected to be inherently biodegradable.
12.3 Bioaccumulative potential : No data available
12.4 Mobility in soil : No data available
12.5 Results of PBT and vPvB assessment :
12.6 Endocrine disrupting properties : No data available
12.7 Other adverse effects : No data available
SECTION 13. Disposal considerations
13.1 Waste treatment methods
Dispose of in accordance with regional, national, and local laws and regulations.
Material disposal :
Container disposal :
Oral
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Carbon oxides
11.1 Information on hazard classes
Dermal
Inhalative
May be fatal if swallowed and enters airway
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
Do not dispose of waste into sewer. Do not contaminate ponds, waterways, or ditches with product or used
container. Send to a licensed waste management company.
Do not dispose of waste into sewer. Do not contaminate ponds, waterways, or ditches with product or used
container. Send to a licensed waste management company.
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Safety Data Sheet PARTALL Paste #2
SECTION 14. Transport information
14.1 UN number
Not regulated
14.2 UN proper shipping name
DOT : Not regulated
ADR : Not regulated
IMDG : Not regulated
IATA : Not regulated
14.3 Transport hazard class
Not regulated
14.4 Packing group
Not regulated
14.5 Environmental hazards
Not regulated
14.6 Special precautions for user
Not regulated
14.7 Transport in bulk according to IMO instruments
Not regulated
14.8 Additional information
Not regulated
SECTION 15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No information available for this material. Information provided is for components.
OSHA Hazard Communication Standard
This material is hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200
Superfund Amendments and Reauthorization Act (SARA)
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 311/312 Hazard Categories
Immediate (acute) health hazard
SARA 313 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 313.
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)
California Proposition 65
This product contains the following Right to Know components:
Component U.S. State Right to Know list
Distillates (petroleum), hydrotreated light (CAS No. 64742 47 8) : Massachusetts, New Jersey, Pennsylvania
International Agency for Research on Cancer (IARC)
No chemicals in this material are subject to the reporting requirements of CERCLA.
No chemicals in this material are subject to the reporting requirements of California Proposition 65.
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Safety Data Sheet PARTALL Paste #2
This product contains the following chemicals classified by IARC as carcinogenic:
None known
Chemical inventories
Components are listed or exempted from listing on the following chemical inventories:
AICS Australian Inventory of Chemical Substances
DSL / NDSL Domestic Substances List / Non Domestic Substances List
EINECS European Inventory of Exis ting Commercial Chemical Substances
ENCS Existing and New Chemical Substances
IECS Inventory of Existing Chemic al Substances Produced or Imported in China
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chem icals and Chemical Substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substances Control Act
15.2 Chemical safety assessment
A chemical safety assessment has not been carried out for this product.
SECTION 16. Other information
Abbreviations and acronyms
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
Asp. Tox. 1 Aspiration hazard Category 1
CAS Chemical Abstract Service
DOT U.S. Department of Transportation
EC European Community
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Lethal concentration, 50 percent
LD50 Lethal dose, 50 percent
NIOSH National Institute for O ccupational Safety and Health
OSHA U.S. Occupational Safety and Health Administration
OSHA HCS U.S. Occupational Safety and Health Administration Hazard Communication Standard
PBT: Persistent, Bioaccumalative and Toxic
vPvB: very Persistent and very Bioaccumulative
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. REXCO MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether this product is fit for a particular purpose and suitable for user’s method
of use or application. Given the variety of factors that can affect the use and application of a product, some of which are uniquely within the user’s
knowledge and control, it is essential that the user evaluate this product to determine whether it is fit for a particular purpose and suitable for user’s
method of use or application.
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37WA138B_SDS.pdf

SAFETY DATA SHEET
1. Identification
TR-920 Semi-Permanent Liquid Mold ReleaseProduct identifier
Other means of identification
MR-920Product code
Release agent.Recommended use
All other uses.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 3Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 2Carcinogenicity
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2 (central nervous system, blood)Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer.
May cause damage to organs (central nervous system, blood) through prolonged or repeated
exposure. Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective
gloves/protective clothing/eye protection/face protection.
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Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable
for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Wash contaminated clothing before reuse. Collect spillage. In case of fire: Use
foam, carbon dioxide, dry powder or water fog to extinguish.
Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
CAS numbe
r %Chemical name
95-63-61,2,4-Trimethylbenzene 30 – 60
64742-95-6Solvent naphtha (petroleum), light
aromatic
30 – 60
108-67-81,3,5-Trimethylbenzene 5 – 10
98-82-8Cumene 1 – 5
25340-17-4Diethylbenzene 1 – 5
1330-20-7Xylene 1 – 5
100-41-4Ethylbenzene 0.1 – 1
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.
Narcosis. Headache. Nausea, vomiting. Behavioral changes. Decrease in motor functions. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin
irritation. May cause redness and pain. Prolonged exposure may cause chronic effects.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Wash contaminated clothing before reuse.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Fire fighting
equipment/instructions
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Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Flammable liquid and vapor.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools. This material is classified as a water
pollutant under the Clean Water Act and should be prevented from contaminating soil or from
entering sewage and drainage systems which lead to waterways.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not handle, store or open near an open flame, sources of heat or sources of
ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general
and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure.
Should be handled in closed systems, if possible. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe
good industrial hygiene practices.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area
equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 245 mg/m3Cumene (CAS 98-82-8)
50 ppm
PEL 435 mg/m3Ethylbenzene (CAS
100-41-4)
100 ppm
PEL 435 mg/m3Xylene (CAS 1330-20-7)
100 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 25 ppm1,2,4-Trimethylbenzene
(CAS 95-63-6)
TWA 10 ppm1,3,5-Trimethylbenzene
(CAS 108-67-8)
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US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 5 ppmCumene (CAS 98-82-8)
TWA 20 ppmEthylbenzene (CAS
100-41-4)
STEL 150 ppmXylene (CAS 1330-20-7)
TWA 100 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 125 mg/m31,2,4-Trimethylbenzene
(CAS 95-63-6)
25 ppm
TWA 125 mg/m31,3,5-Trimethylbenzene
(CAS 108-67-8)
25 ppm
TWA 245 mg/m3Cumene (CAS 98-82-8)
50 ppm
STEL 545 mg/m3Ethylbenzene (CAS
100-41-4)
125 ppm
TWA 435 mg/m3
100 ppm
STEL 655 mg/m3Xylene (CAS 1330-20-7)
150 ppm
TWA 435 mg/m3
100 ppm
US. Workplace Environmental Exposure Level (WEEL) Guides
ValueComponents Type
TWA 5 ppmDiethylbenzene (CAS
25340-17-4)
Biological limit values
ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
0.15 g/g Sum of
mandelic acid
and
phenylglyoxylic
acid
Creatinine in
urine
*Ethylbenzene (CAS
100-41-4)
1.5 g/g Methylhippuric
acids
Creatinine in
urine
*Xylene (CAS 1330-20-7)
* – For sampling details, please see the source document.
Exposure guidelines
US – California OELs: Skin designation
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US – Minnesota Haz Subs: Skin designation applies
Cumene (CAS 98-82-8) Skin designation applies.
US – Tennessee OELs: Skin designation
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Cumene (CAS 98-82-8) Can be absorbed through the skin.
TR-920 Semi-Permanent Liquid Mold Release SDS US
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Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Rubber gloves, butyl rubber, neoprene or PVC gloves
are recommended.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. When using do not smoke. Always observe good
personal hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Liquid.Form
Colorless.Color
Mild.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
127.4 F (53 C)
Flash point 100.4 F (38 C) Tag Closed Cup
Evaporation rate Slower than ether.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
Vapor pressure 49 mm Hg
Vapor pressure temp. 68 F (20 C)
Vapor density > 1 (Air= 1)
Relative density 0.873 (Water = 1)
Solubility(ies)
Solubility (water) Slightly soluble in water.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature 896 F (480 C) (Estimated)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
VOC 100 %
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10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid
temperatures exceeding the flash point. Contact with incompatible materials.
Conditions to avoid
Strong acids. Strong oxidizing agents. Halogens.Incompatible materials
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contac
t Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.
Narcosis. Headache. Nausea, vomiting. Behavioral changes. Decrease in motor functions. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin
irritation. Ma
y cause redness and pain. Prolonged exposure may cause chronic effects.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsComponents Species
1,2,4-Trimethylbenzene (CAS 95-63-6)
Oral
Acute
LD50 Rat 2720 – 3960 mg/kg
Cumene (CAS 98-82-8)
Dermal
Acute
LD50 Rabbit > 3160 mg/kg, 24 Hours
Inhalation
LC50 Rat 8000 ppm, 4 Hours
Oral
LD50 Rat 2910 mg/kg
Diethylbenzene (CAS 25340-17-4)
Dermal
Acute
LD50 Rat > 2000 mg/kg
Oral
LD50 Rat 2050 mg/kg
Ethylbenzene (CAS 100-41-4)
Dermal
Acute
LD50 Rabbit 15400 mg/kg
Inhalation
LC50 Rat 17.4 mg/m , 4 Hours
Oral
LD50 Rat 35000 – 47000 mg/kg
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Test ResultsComponents Species
Xylene (CAS 1330-20-7)
Oral
Acute
LD50 Rat 3523 mg/kg
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity Suspected of causing cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cumene (CAS 98-82-8) 2B Possibly carcinogenic to humans.
Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans.
Solvent naphtha (petroleum), light aromatic
(CAS 64742-95-6)
3 Not classifiable as to carcinogenicity to humans.
Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Cumene (CAS 98-82-8) Reasonably Anticipated to be a Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (central nervous system, blood) through prolonged or repeated
exposure.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may
be harmful. May be harmful if absorbed through skin.
Further information Symptoms may be delayed. May be absorbed through the skin.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity
Components Test ResultsSpecies
1,2,4-Trimethylbenzene (CAS 95-63-6)
Aquatic
Acute
LC50Fish 7.72 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Cumene (CAS 98-82-8)
Aquatic
Acute
LC50Fish 2.7 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
Diethylbenzene (CAS 25340-17-4)
Aquatic
Acute
ErC50Algae 1.21 mg/l, 72 hoursPseudokirchneriella subcapitata
EC50Crustacea 2.01 mg/l, 48 hoursDaphnia magna
LC50Fish 0.673 mg/l, 96 hoursOncorhynchus mykiss
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Components Test ResultsSpecies
Ethylbenzene (CAS 100-41-4)
Aquatic
Acute
EC50Crustacea > 1.81 – < 2.38 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 4.2 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Chronic EC50Crustacea 3.6 mg/l, 7 daysCeriodaphnia dubia Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6) Aquatic Acute EL50Crustacea 4.5 mg/l, 48 hoursDaphnia LL50Fish 10 mg/l, 96 hoursOncorhynchus mykiss Xylene (CAS 1330-20-7) Aquatic LC50Fish 2.6 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) No data is available on the degradability of any ingredients in the mixture. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 1,2,4-Trimethylbenzene (CAS 95-63-6) 3.78 1,3,5-Trimethylbenzene (CAS 108-67-8) 3.42 Cumene (CAS 98-82-8) 3.66 Ethylbenzene (CAS 100-41-4) 3.15 The product is slightly soluble in water. Expected to have low mobility in soil.Mobility in soil Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation potential. 13. Disposal considerations Dispose of this material and its container to hazardous or special waste collection point. Incinerate the material under controlled conditions in an approved incinerator. Do not incinerate sealed containers. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations D001: Waste Flammable material with a flash point <140 F The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1268UN number Petroleum distillates, n.o.s.UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesMarine pollutant Environmental hazards TR-920 Semi-Permanent Liquid Mold Release SDS US 916418 Version #: 01 Revision date: - Issue date: 07-November-2022 8 / 11 Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 144, B1, IB3, T4, TP1, TP29Special provisions 150Packaging exceptions 203Packaging non bulk 242Packaging bulk IATA UN1268UN number Petroleum distillates, n.o.s.UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesEnvironmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1268UN number Petroleum distillates, n.o.s.UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIIPacking group YesMarine pollutant Environmental hazards F-E, S-EEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Cumene (CAS 98-82-8) Listed. Ethylbenzene (CAS 100-41-4) Listed. Xylene (CAS 1330-20-7) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. Toxic Substances Control Act (TSCA) All components of the mixture on the TSCA 8(b) inventory are designated active . SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. YesSARA 311/312 Hazardous chemical Flammable (gases, aerosols, liquids, or solids) Skin corrosion or irritation Serious eye damage or eye irritation Carcinogenicity Specific target organ toxicity (single or repeated exposure) Aspiration hazard Classified hazard categories TR-920 Semi-Permanent Liquid Mold Release SDS US 916418 Version #: 01 Revision date: - Issue date: 07-November-2022 9 / 11 SARA 313 (TRI reporting) Chemical name % by wt. CAS number 1,2,4-Trimethylbenzene 30 - 60 95-63-6 Cumene 1 - 5 98-82-8 Ethylbenzene 0.1 - 1 100-41-4 Xylene 1 - 5 1330-20-7 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Contains component(s) regulated under the Safe Drinking Water Act.Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. New Jersey Worker and Community Right-to-Know Act 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Diethylbenzene (CAS 25340-17-4) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. Pennsylvania Worker and Community Right-to-Know Law 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. Rhode Island RTK 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) California Proposition 65 This product can expose you to chemicals including Cumene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. WARNING: California Proposition 65 - CRT: Listed date/Carcinogenic substance Cumene (CAS 98-82-8) Listed: April 6, 2010 Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6) Xylene (CAS 1330-20-7) International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Industrial Chemicals (AICIS) TR-920 Semi-Permanent Liquid Mold Release SDS US 916418 Version #: 01 Revision date: - Issue date: 07-November-2022 10 / 11 Country(s) or region Inventory name On inventory (yes/no)* YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) YesJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesTaiwan Taiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 07-November-2022Issue date -Revision date Version # 01 NFPA ratings 02 3 List of abbreviations LC50: Lethal Concentration, 50%. ErC50: EC50 in terms of reduction of growth rate. EC50: Effective Concentration, 50%. EL50: Effective level, 50%. LL50: Lethal level, 50%. TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer TR-920 Semi-Permanent Liquid Mold Release SDS US 916418 Version #: 01 Revision date: - Issue date: 07-November-2022 11 / 11

37WA138C_SDS.pdf

SAFETY DATA SHEET
1. Identification
TR-920 Semi-Permanent Liquid Mold ReleaseProduct identifier
Other means of identification
MR-920Product code
Release agent.Recommended use
All other uses.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 3Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 2Carcinogenicity
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2 (central nervous system, blood)Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer.
May cause damage to organs (central nervous system, blood) through prolonged or repeated
exposure. Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective
gloves/protective clothing/eye protection/face protection.
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Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable
for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Wash contaminated clothing before reuse. Collect spillage. In case of fire: Use
foam, carbon dioxide, dry powder or water fog to extinguish.
Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
CAS numbe
r %Chemical name
95-63-61,2,4-Trimethylbenzene 30 – 60
64742-95-6Solvent naphtha (petroleum), light
aromatic
30 – 60
108-67-81,3,5-Trimethylbenzene 5 – 10
98-82-8Cumene 1 – 5
25340-17-4Diethylbenzene 1 – 5
1330-20-7Xylene 1 – 5
100-41-4Ethylbenzene 0.1 – 1
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.
Narcosis. Headache. Nausea, vomiting. Behavioral changes. Decrease in motor functions. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin
irritation. May cause redness and pain. Prolonged exposure may cause chronic effects.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Wash contaminated clothing before reuse.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Fire fighting
equipment/instructions
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Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Flammable liquid and vapor.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools. This material is classified as a water
pollutant under the Clean Water Act and should be prevented from contaminating soil or from
entering sewage and drainage systems which lead to waterways.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not handle, store or open near an open flame, sources of heat or sources of
ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general
and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure.
Should be handled in closed systems, if possible. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe
good industrial hygiene practices.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area
equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 245 mg/m3Cumene (CAS 98-82-8)
50 ppm
PEL 435 mg/m3Ethylbenzene (CAS
100-41-4)
100 ppm
PEL 435 mg/m3Xylene (CAS 1330-20-7)
100 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 25 ppm1,2,4-Trimethylbenzene
(CAS 95-63-6)
TWA 10 ppm1,3,5-Trimethylbenzene
(CAS 108-67-8)
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US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 5 ppmCumene (CAS 98-82-8)
TWA 20 ppmEthylbenzene (CAS
100-41-4)
STEL 150 ppmXylene (CAS 1330-20-7)
TWA 100 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 125 mg/m31,2,4-Trimethylbenzene
(CAS 95-63-6)
25 ppm
TWA 125 mg/m31,3,5-Trimethylbenzene
(CAS 108-67-8)
25 ppm
TWA 245 mg/m3Cumene (CAS 98-82-8)
50 ppm
STEL 545 mg/m3Ethylbenzene (CAS
100-41-4)
125 ppm
TWA 435 mg/m3
100 ppm
STEL 655 mg/m3Xylene (CAS 1330-20-7)
150 ppm
TWA 435 mg/m3
100 ppm
US. Workplace Environmental Exposure Level (WEEL) Guides
ValueComponents Type
TWA 5 ppmDiethylbenzene (CAS
25340-17-4)
Biological limit values
ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
0.15 g/g Sum of
mandelic acid
and
phenylglyoxylic
acid
Creatinine in
urine
*Ethylbenzene (CAS
100-41-4)
1.5 g/g Methylhippuric
acids
Creatinine in
urine
*Xylene (CAS 1330-20-7)
* – For sampling details, please see the source document.
Exposure guidelines
US – California OELs: Skin designation
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US – Minnesota Haz Subs: Skin designation applies
Cumene (CAS 98-82-8) Skin designation applies.
US – Tennessee OELs: Skin designation
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Cumene (CAS 98-82-8) Can be absorbed through the skin.
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Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Rubber gloves, butyl rubber, neoprene or PVC gloves
are recommended.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. When using do not smoke. Always observe good
personal hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Liquid.Form
Colorless.Color
Mild.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
127.4 F (53 C)
Flash point 100.4 F (38 C) Tag Closed Cup
Evaporation rate Slower than ether.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
Vapor pressure 49 mm Hg
Vapor pressure temp. 68 F (20 C)
Vapor density > 1 (Air= 1)
Relative density 0.873 (Water = 1)
Solubility(ies)
Solubility (water) Slightly soluble in water.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature 896 F (480 C) (Estimated)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
VOC 100 %
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10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid
temperatures exceeding the flash point. Contact with incompatible materials.
Conditions to avoid
Strong acids. Strong oxidizing agents. Halogens.Incompatible materials
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contac
t Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.
Narcosis. Headache. Nausea, vomiting. Behavioral changes. Decrease in motor functions. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin
irritation. Ma
y cause redness and pain. Prolonged exposure may cause chronic effects.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Test ResultsComponents Species
1,2,4-Trimethylbenzene (CAS 95-63-6)
Oral
Acute
LD50 Rat 2720 – 3960 mg/kg
Cumene (CAS 98-82-8)
Dermal
Acute
LD50 Rabbit > 3160 mg/kg, 24 Hours
Inhalation
LC50 Rat 8000 ppm, 4 Hours
Oral
LD50 Rat 2910 mg/kg
Diethylbenzene (CAS 25340-17-4)
Dermal
Acute
LD50 Rat > 2000 mg/kg
Oral
LD50 Rat 2050 mg/kg
Ethylbenzene (CAS 100-41-4)
Dermal
Acute
LD50 Rabbit 15400 mg/kg
Inhalation
LC50 Rat 17.4 mg/m , 4 Hours
Oral
LD50 Rat 35000 – 47000 mg/kg
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Test ResultsComponents Species
Xylene (CAS 1330-20-7)
Oral
Acute
LD50 Rat 3523 mg/kg
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity Suspected of causing cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cumene (CAS 98-82-8) 2B Possibly carcinogenic to humans.
Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans.
Solvent naphtha (petroleum), light aromatic
(CAS 64742-95-6)
3 Not classifiable as to carcinogenicity to humans.
Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Cumene (CAS 98-82-8) Reasonably Anticipated to be a Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (central nervous system, blood) through prolonged or repeated
exposure.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may
be harmful. May be harmful if absorbed through skin.
Further information Symptoms may be delayed. May be absorbed through the skin.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity
Components Test ResultsSpecies
1,2,4-Trimethylbenzene (CAS 95-63-6)
Aquatic
Acute
LC50Fish 7.72 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Cumene (CAS 98-82-8)
Aquatic
Acute
LC50Fish 2.7 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
Diethylbenzene (CAS 25340-17-4)
Aquatic
Acute
ErC50Algae 1.21 mg/l, 72 hoursPseudokirchneriella subcapitata
EC50Crustacea 2.01 mg/l, 48 hoursDaphnia magna
LC50Fish 0.673 mg/l, 96 hoursOncorhynchus mykiss
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Components Test ResultsSpecies
Ethylbenzene (CAS 100-41-4)
Aquatic
Acute
EC50Crustacea > 1.81 – < 2.38 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 4.2 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Chronic EC50Crustacea 3.6 mg/l, 7 daysCeriodaphnia dubia Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6) Aquatic Acute EL50Crustacea 4.5 mg/l, 48 hoursDaphnia LL50Fish 10 mg/l, 96 hoursOncorhynchus mykiss Xylene (CAS 1330-20-7) Aquatic LC50Fish 2.6 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) No data is available on the degradability of any ingredients in the mixture. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 1,2,4-Trimethylbenzene (CAS 95-63-6) 3.78 1,3,5-Trimethylbenzene (CAS 108-67-8) 3.42 Cumene (CAS 98-82-8) 3.66 Ethylbenzene (CAS 100-41-4) 3.15 The product is slightly soluble in water. Expected to have low mobility in soil.Mobility in soil Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation potential. 13. Disposal considerations Dispose of this material and its container to hazardous or special waste collection point. Incinerate the material under controlled conditions in an approved incinerator. Do not incinerate sealed containers. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations D001: Waste Flammable material with a flash point <140 F The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1268UN number Petroleum distillates, n.o.s.UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesMarine pollutant Environmental hazards TR-920 Semi-Permanent Liquid Mold Release SDS US 916418 Version #: 01 Revision date: - Issue date: 07-November-2022 8 / 11 Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 144, B1, IB3, T4, TP1, TP29Special provisions 150Packaging exceptions 203Packaging non bulk 242Packaging bulk IATA UN1268UN number Petroleum distillates, n.o.s.UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesEnvironmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1268UN number Petroleum distillates, n.o.s.UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIIPacking group YesMarine pollutant Environmental hazards F-E, S-EEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Cumene (CAS 98-82-8) Listed. Ethylbenzene (CAS 100-41-4) Listed. Xylene (CAS 1330-20-7) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. Toxic Substances Control Act (TSCA) All components of the mixture on the TSCA 8(b) inventory are designated active . SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. YesSARA 311/312 Hazardous chemical Flammable (gases, aerosols, liquids, or solids) Skin corrosion or irritation Serious eye damage or eye irritation Carcinogenicity Specific target organ toxicity (single or repeated exposure) Aspiration hazard Classified hazard categories TR-920 Semi-Permanent Liquid Mold Release SDS US 916418 Version #: 01 Revision date: - Issue date: 07-November-2022 9 / 11 SARA 313 (TRI reporting) Chemical name % by wt. CAS number 1,2,4-Trimethylbenzene 30 - 60 95-63-6 Cumene 1 - 5 98-82-8 Ethylbenzene 0.1 - 1 100-41-4 Xylene 1 - 5 1330-20-7 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Contains component(s) regulated under the Safe Drinking Water Act.Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. New Jersey Worker and Community Right-to-Know Act 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Diethylbenzene (CAS 25340-17-4) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. Pennsylvania Worker and Community Right-to-Know Law 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. Rhode Island RTK 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) California Proposition 65 This product can expose you to chemicals including Cumene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. WARNING: California Proposition 65 - CRT: Listed date/Carcinogenic substance Cumene (CAS 98-82-8) Listed: April 6, 2010 Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) 1,2,4-Trimethylbenzene (CAS 95-63-6) 1,3,5-Trimethylbenzene (CAS 108-67-8) Cumene (CAS 98-82-8) Ethylbenzene (CAS 100-41-4) Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6) Xylene (CAS 1330-20-7) International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Industrial Chemicals (AICIS) TR-920 Semi-Permanent Liquid Mold Release SDS US 916418 Version #: 01 Revision date: - Issue date: 07-November-2022 10 / 11 Country(s) or region Inventory name On inventory (yes/no)* YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) YesJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesTaiwan Taiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 07-November-2022Issue date -Revision date Version # 01 NFPA ratings 02 3 List of abbreviations LC50: Lethal Concentration, 50%. ErC50: EC50 in terms of reduction of growth rate. EC50: Effective Concentration, 50%. EL50: Effective level, 50%. LL50: Lethal level, 50%. TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer TR-920 Semi-Permanent Liquid Mold Release SDS US 916418 Version #: 01 Revision date: - Issue date: 07-November-2022 11 / 11

37WA138A_SDS.pdf

SAFETY DATA SHEET
1. Identification
905 TR Mold Prep CleanerProduct identifier
Other means of identification
TR 905Product code
Solvent.Recommended use
Use in accordance with supplier’s recommendations.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufacturer/Supplier TR Industries a Division of Granitize Products Inc.
Address 11022 Vulcan Street
South Gate, CA 90280-0893 United States
Telephone: (562) 923-5438
Emergency CHEMTREC: (800) 424-9300
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 2Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2BSerious eye damage/eye irritation
Category 2Reproductive toxicity
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2 (Central nervous system)Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Highly flammable liquid and vapor. Causes skin irritation. Causes eye irritation. Suspected of
damaging fertility or the unborn child. May cause drowsiness or dizziness. May cause damage to
organs (Central nervous system) through prolonged or repeated exposure. May be fatal if
swallowed and enters airways.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye
protection/face protection.
Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If inhaled:
Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you
feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If
exposed or concerned: Get medical advice/attention. In case of fire: Use water, water spray,
foam, dry powder, carbon dioxide (CO2) to extinguish.
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Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
108-88-3 50 – 52Toluene
CAS number %Chemical name
78-93-3 48 – 50Methyl ethyl ketone
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Move into fresh air and keep at rest. If breathing is difficult, give oxygen. Get medical attention if
discomfort develops or persists.
Inhalation
Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing separately before reuse. Get medical attention. Destroy or thoroughly
clean contaminated shoes.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention.
Eye contact
DO NOT induce vomiting. If victim is fully conscious, give a cupful of water. Never give anything by
mouth to an unconscious person. If vomiting occurs, keep head lower than the hips to help prevent
aspiration. Call a physician or poison control center immediately.
Ingestion
Irritant effects. Central nervous system depression. May be fatal if swallowed and enters airways.
Prolonged exposure may cause chronic effects.
Most important
symptoms/effects, acute and
delayed
Keep victim warm. Keep victim under observation. Symptoms may be delayed.Indication of immediate
medical attention and special
treatment needed
Take off contaminated clothing and shoes immediately. Wash contaminated clothing before
re-use. Ensure that medical personnel are aware of the material(s) involved, and take precautions
to protect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. Fire-fighting measures
Water. Water spray. Foam. Dry powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Material will float and may ignite on surface of water. Vapors may form explosive mixtures with air.
Vapors are heavier than air and may travel along the floor and in the bottom of containers. Vapors
may be ignited by a spark, a hot surface or an ember.
Specific hazards arising from
the chemical
Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask.
Special protective equipment
and precautions for firefighters
Move containers from fire area if you can do so without risk. Cool containers with flooding
quantities of water until well after fire is out.
Fire fighting
equipment/instructions
Highly flammable liquid and vapor. Heat may cause the containers to explode.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Local authorities should be advised if significant spillages
cannot be contained. Keep out of low areas. Ventilate closed spaces before entering them. Do not
touch damaged containers or spilled material unless wearing appropriate protective clothing.
Personal precautions,
protective equipment and
emergency procedures
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Extinguish all flames in the vicinity. Remove sources of ignition. Should not be released into the
environment. Prevent entry into waterways, sewers, basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re-use. This material and its container must be
disposed of as hazardous waste.
Methods and materials for
containment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat and sources of ignition. Use only with adequate ventilation.
Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Pregnant women should
not work with the product, if there is the least risk of exposure. When using, do not eat, drink or
smoke. Do not taste or swallow. Wash thoroughly after handling.
Precautions for safe handling
Follow rules for flammable liquids. Keep away from heat, sparks and open flame. Keep in a
well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal
feeding stuffs.
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents
PEL 590 mg/m3Methyl ethyl ketone (CAS
78-93-3)
200 ppm
US. OSHA Table Z-2 (29 CFR 1910.1000)
ValueTypeComponents
Ceiling 300 ppmToluene (CAS 108-88-3)
TWA 200 ppm
US. ACGIH Threshold Limit Values
ValueTypeComponents
STEL 300 ppmMethyl ethyl ketone (CAS
78-93-3)
TWA 200 ppm
TWA 20 ppmToluene (CAS 108-88-3)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueTypeComponents
STEL 885 mg/m3Methyl ethyl ketone (CAS
78-93-3)
300 ppm
TWA 590 mg/m3
200 ppm
STEL 560 mg/m3Toluene (CAS 108-88-3)
150 ppm
TWA 375 mg/m3
100 ppm
Biological limit values
ACGIH Biological Exposure Indices
Value Sampling TimeDeterminant SpecimenComponents
2 mg/l MEK Urine *Methyl ethyl ketone (CAS
78-93-3)
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ACGIH Biological Exposure Indices
Value Sampling TimeDeterminant SpecimenComponents
0.3 mg/g o-Cresol, with
hydrolysis
Creatinine
in urine
*Toluene (CAS 108-88-3)
0.03 mg/l Toluene Urine *
0.02 mg/l Toluene Blood *
* – For sampling details, please see the source document.
Exposure guidelines
US – California OELs: Skin designation
Toluene (CAS 108-88-3) Can be absorbed through the skin.
US – Minnesota Haz Subs: Skin designation applies
Toluene (CAS 108-88-3) Skin designation applies.
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Use
explosion-proof equipment. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear approved safety glasses or goggles. Wear face shield if there is risk of splashes.Eye/face protection
Skin protection
Wear protective gloves. Suitable gloves can be recommended by the glove supplier.Hand protection
Skin protection
Wear suitable protective clothing.Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. In the United States of America, if
respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR
1910.134. Respirator type: Air-purifying respirator with an appropriate, government approved
(where applicable), air-purifying filter, cartridge or canister.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Clear, colorless liquid.Appearance
Liquid.Physical state
Liquid.Form
Colorless, clear.Color
Hydrocarbon.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
> 175 F (> 79.44 C)
Flash point 33.4 F (0.8 C) Closed Cup (Calculated)
Evaporation rate > 1 (Butyl acetate = 1)
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
1.3
Flammability limit – upper
(%)
11.5
Explosive limit – lower (%)Not available.
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Explosive limit – upper (%)Not available.
Vapor pressure > 22 mmHg
Vapor density > 1 (Air= 1)
Relative density 0.83 (Water = 1)
Solubility(ies)
Solubility (water) Partially soluble in water.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Risk of ignition. Stable at normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Heat, flames and sparks. Electrostatic discharge. Contact with incompatible materials.Conditions to avoid
Strong oxidizing agents. Strong acids. Strong bases.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause central nervous system depression.
Skin contact Causes skin irritation.
Eye contac
t Causes eye irritation.
Ingestion May be fatal if swallowed and enters airways.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritant effects. May cause central nervous system effects. May be fatal if swallowed and enters
airways. May cause damage to organs (central nervous system) through prolonged or repeated
exposure.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Causes skin irritation.Skin corrosion/irritation
Causes eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
Not a skin sensitizer.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Suspected of damaging fertility or the unborn child.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause drowsiness or dizziness.
Specific target organ toxicity –
repeated exposure
May cause damage to the following organs through prolonged or repeated exposure: Central
nervous system.
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Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful. Prolonged or repeated exposure may cause lung injury.
May cause central nervous system effects.
Further information Symptoms may be delayed.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of this product.Persistence and degradability
No data available on bioaccumulation.Bioaccumulative potential
Expected to be slightly to moderately mobile in soil.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not
incinerate sealed containers. Do not dispose of waste into sewer. Do not contaminate ponds,
waterways or ditches with chemical or used container. Dispose of in accordance with local
regulations.
Disposal instructions
D001: Waste Flammable material with a flash point <140 FHazardous waste code Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1993UN number FLAMMABLE LIQUID, N.O.S. (toluene, methyl ethyl ketone)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group NoMarine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IB2, T7, TP1, TP8, TP28Special provisions 150Packaging exceptions 202Packaging non bulk 242Packaging bulk IATA UN1993UN number FLAMMABLE LIQUID, N.O.S. (toluene, methyl ethyl ketone)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group NoEnvironmental hazards 3HERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1993UN number FLAMMABLE LIQUID, N.O.S. (toluene, methyl ethyl ketone)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 905 TR Mold Prep Cleaner SDS US 913171 Version #: 02 Revision date: 18-December-2015 Issue date: 10-April-2014 6 / 8 3Label(s) IIPacking group NoMarine pollutant Environmental hazards F-E, S-EEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Methyl ethyl ketone (CAS 78-93-3) LISTED Toluene (CAS 108-88-3) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Hazard categories SARA 302 Extremely hazardous substance Not listed. YesSARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Toluene 108-88-3 50 - 52 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Toluene (CAS 108-88-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Hazardous substanceClean Water Act (CWA) Section 112(r) (40 CFR 68.130) Not regulated.Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Methyl ethyl ketone (CAS 78-93-3) 6714 Toluene (CAS 108-88-3) 6594 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Methyl ethyl ketone (CAS 78-93-3) 35 %WV Toluene (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Methyl ethyl ketone (CAS 78-93-3) 6714 Toluene (CAS 108-88-3) 594 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. US state regulations 905 TR Mold Prep Cleaner SDS US 913171 Version #: 02 Revision date: 18-December-2015 Issue date: 10-April-2014 7 / 8 US. Massachusetts RTK - Substance List Methyl ethyl ketone (CAS 78-93-3) Toluene (CAS 108-88-3) US. New Jersey Worker and Community Right-to-Know Act Methyl ethyl ketone (CAS 78-93-3) Toluene (CAS 108-88-3) US. Pennsylvania Worker and Community Right-to-Know Law Methyl ethyl ketone (CAS 78-93-3) Toluene (CAS 108-88-3) US. Rhode Island RTK Methyl ethyl ketone (CAS 78-93-3) Toluene (CAS 108-88-3) US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Toluene (CAS 108-88-3) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) YesAustralia Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical Substances (EINECS) YesEurope European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) YesJapan Existing Chemicals List (ECL) YesKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesPhilippines *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico 16. Other information, including date of preparation or last revision 10-April-2014Issue date 18-December-2015Revision date Version # 02 NFPA ratings 02 3 TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer 905 TR Mold Prep Cleaner SDS US 913171 Version #: 02 Revision date: 18-December-2015 Issue date: 10-April-2014 8 / 8

37WA137_SDS.pdf

SAFETY DATA SHEET
1. Identification
TR-930 Mold ReleaseProduct identifier
None.Other means of identification
Mold release.Recommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 3Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
Causes serious eye irritation. May cause drowsiness or dizziness. May cause respiratory irritation.
Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting// equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear
protective gloves/eye protection/face protection.
Response If swallowed: Immediately call a poison center/doctor/. Do NOT induce vomiting. If on skin (or
hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin
irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a poison
center/doctor// if you feel unwell. In case of fire: Use water fog, alcohol resistant foam, dry
chemical powder, carbon dioxide to extinguish. Collect spillage.
TR-930 Mold Release SDS US
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Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Not
assigned.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Not assigned.
Hazard(s) not otherwise
classified (HNOC)
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
64742-48-9 60-100Naphtha (petroleum),
hydrotreated heavy
CAS number %Chemical name
142-96-1 10 – 30Dibutyl Ether
90622-56-3 1 – 5Alkanes, C7-10-iso-
111-65-9 1 – 5Octane
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include stinging,
tearing, redness, swelling, and blurred vision. May cause drowsiness and dizziness. May cause
respiratory irritation. Headache. Nausea, vomiting. Swallowing of the liquid, or vomiting as a result,
may result in aspiration into the lungs. Aspiration may cause pulmonary edema and pneumonitis.
Be aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after
exposure.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. This product is a poor conductor of electricity and can become
electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can
occur. To reduce potential for static discharge, use proper bonding and grounding procedures.
This liquid may accumulate static electricity when filling properly grounded containers. Static
electricity accumulation may be significantly increased by the presence of small quantities of water
or other contaminants. Material will float and may ignite on surface of water. During fire, gases
hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to flames with water until well after the fire is out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Flammable liquid and vapor.General fire hazards
TR-930 Mold Release SDS US
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6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Use appropriate containment to avoid environmental
contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other
suitable container for recovery or safe disposal. Local authorities should be advised if significant
spillages cannot be contained.
Personal precautions,
protective equipment and
emergency procedures
Use water spray to reduce vapors or divert vapor cloud drift. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Take precautionary measures against static discharge. Use only
non-sparking tools. Prevent entry into waterways, sewer, basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb spill with vermiculite or other inert material. Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground. Use appropriate containment to avoid environmental
contamination.
Environmental precautions
7. Handling and storage
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Minimize fire risks from flammable and combustible materials (including combustible
dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling
operations that can promote accumulation of static charges include but are not limited to: mixing,
filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container
filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take
precautionary measures against static discharges. All equipment used when handling the product
must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or
swallow. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid
prolonged exposure. Wear appropriate personal protective equipment. Wash hands thoroughly
after handling. Avoid release to the environment. Observe good industrial hygiene practices.
For additional information on equipment bonding and grounding, refer to the Canadian Electrical
Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice
2003, “Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents” or National
Fire Protection Association (NFPA) 77, “Recommended Practice on Static Electricity” or National
Fire Protection Association (NFPA) 70, “National Electrical Code”.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Keep at temperature not
exceeding 48.8 C. Prevent electrostatic charge build-up by using common bonding and grounding
techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and
equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place
out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place.
Keep in an area equipped with sprinklers. Avoid contact with oxidizing agents. Store away from
incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 2350 mg/m3Octane (CAS 111-65-9)
500 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 300 ppmOctane (CAS 111-65-9)
TR-930 Mold Release SDS US
3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014
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US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
Ceiling 1800 mg/m3Octane (CAS 111-65-9)
385 ppm
TWA 350 mg/m3
75 ppm
No biological exposure limits noted for the ingredient(s).Biological limit values
Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Nitrile
gloves are recommended. Other suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing.Other
In case of inadequate ventilation or risk of inhalation of vapors, suitable respiratory equipment with
particulate filter and organic vapor cartridges can be used. If permissible levels are exceeded use
NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering
controls do not maintain airborne concentrations below recommended exposure limits (where
applicable) or to an acceptable level (in countries where exposure limits have not been
established), an approved respirator must be worn. Check with respiratory protective equipment
suppliers.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Colorless liquid.Form
Colorless.Color
Mild. Solvent.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot determined.
Initial boiling point and boiling
range
> 233.6 F (> 112 C)
Boiling point pressure 1013 hPa
Flash point 87.8 F (31.0 C) (Tagliabue Closed Cup)
Evaporation rate Slower than ether.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
TR-930 Mold Release SDS US
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Vapor pressure Not available.
Vapor density Heavier than air.
Relative density 0.754 (H2O=1)
Solubility(ies)
Solubility (water) Slightly soluble in water.
Solubility (solvents) Soluble in organic solvents.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature > 392 F (> 200 C) (Value for solvent)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
VOC 754 g/l (of coating)
10. Stability and reactivity
The product is stable and non reactive under normal conditions of use, storage and transport.Reactivity
Risk of ignition.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Avoid heat, sparks, open flames and other ignition sources. Static discharge may cause ignition at
temperatures at or above flashpoint. Avoid temperatures exceeding the flash point. Contact with
incompatible materials. Spray mist may be flammable at temperatures below the flash point.
Conditions to avoid
Strong oxidizing agents.Incompatible materials
Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.
Hydrocarbons.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. May cause respiratory irritation. Prolonged inhalation may
be harmful.
Skin contact Causes skin irritation.
Eye contac
t Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include
stinging, tearing, redness, swelling, and blurred vision. May cause drowsiness and dizziness. May
cause respiratory irritation. Headache. Nausea, vomiting. Swallowing or vomiting of the liquid may
result in aspiration into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Be
aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after
exposure.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
Dibutyl Ether (CAS 142-96-1)
Oral
Acute
LD50 Rat 3230 – 3920 mg/kg
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
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This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Naphtha (petroleum), hydrotreated heavy
(CAS 64742-48-9)
3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause respiratory irritation. May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
Not classified.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.
Further information Symptoms may be delayed.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity
Components Test ResultsSpecies
Octane (CAS 111-65-9)
Aquatic
LC50Crustacea 0.38 mg/l, 48 hoursDaphnia magna
No data is available on the degradability of this product.Persistence and degradability
No data available on bioaccumulation.Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Dibutyl Ether (CAS 142-96-1) 3.21
Octane (CAS 111-65-9) 5.18
This product is slightly water soluble and may disperse in soil.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D001: Waste Flammable material with a flash point <140 F The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1866UN number Resin SolutionUN proper shipping name 3Class Transport hazard class(es) TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 6 / 9 -Subsidiary risk 3Label(s) IIIPacking group YesMarine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user B1, B52, IB3, T2, TP1Special provisions 150Packaging exceptions 173Packaging non bulk 242Packaging bulk IATA UN1866UN number Resin Solution, FlammableUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesEnvironmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1866UN number Resin Solution, FlammableUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesMarine pollutant Environmental hazards F-E, S-EEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Dibutyl Ether (CAS 142-96-1) Listed. Octane (CAS 111-65-9) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. Toxic Substances Control Act (TSCA) SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. YesSARA 311/312 Hazardous chemical TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 7 / 9 Flammable (gases, aerosols, liquids, or solids) Skin corrosion or irritation Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Aspiration hazard Hazard not otherwise classified (HNOC) Classified hazard categories SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List Dibutyl Ether (CAS 142-96-1) Octane (CAS 111-65-9) US. New Jersey Worker and Community Right-to-Know Act Dibutyl Ether (CAS 142-96-1) Octane (CAS 111-65-9) US. Pennsylvania Worker and Community Right-to-Know Law Dibutyl Ether (CAS 142-96-1) Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Octane (CAS 111-65-9) US. Rhode Island RTK Dibutyl Ether (CAS 142-96-1) Octane (CAS 111-65-9) California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Octane (CAS 111-65-9) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) YesAustralia Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical Substances (EINECS) YesEurope European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) NoJapan Existing Chemicals List (ECL) YesKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesPhilippines Taiwan Chemical Substance Inventory (TCSI) YesTaiwan *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 8 / 9 16. Other information, including date of preparation or last revision 10-April-2014Issue date 24-November-2020Revision date Version # 04 NFPA ratings 02 3 TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 9 / 9

37WA137CLB_SDS.pdf

SAFETY DATA SHEET
1. Identification
TR-930 Mold ReleaseProduct identifier
None.Other means of identification
Mold release.Recommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 3Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
Causes serious eye irritation. May cause drowsiness or dizziness. May cause respiratory irritation.
Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting// equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear
protective gloves/eye protection/face protection.
Response If swallowed: Immediately call a poison center/doctor/. Do NOT induce vomiting. If on skin (or
hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin
irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a poison
center/doctor// if you feel unwell. In case of fire: Use water fog, alcohol resistant foam, dry
chemical powder, carbon dioxide to extinguish. Collect spillage.
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Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Not
assigned.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Not assigned.
Hazard(s) not otherwise
classified (HNOC)
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
64742-48-9 60-100Naphtha (petroleum),
hydrotreated heavy
CAS number %Chemical name
142-96-1 10 – 30Dibutyl Ether
90622-56-3 1 – 5Alkanes, C7-10-iso-
111-65-9 1 – 5Octane
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include stinging,
tearing, redness, swelling, and blurred vision. May cause drowsiness and dizziness. May cause
respiratory irritation. Headache. Nausea, vomiting. Swallowing of the liquid, or vomiting as a result,
may result in aspiration into the lungs. Aspiration may cause pulmonary edema and pneumonitis.
Be aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after
exposure.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. This product is a poor conductor of electricity and can become
electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can
occur. To reduce potential for static discharge, use proper bonding and grounding procedures.
This liquid may accumulate static electricity when filling properly grounded containers. Static
electricity accumulation may be significantly increased by the presence of small quantities of water
or other contaminants. Material will float and may ignite on surface of water. During fire, gases
hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to flames with water until well after the fire is out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Flammable liquid and vapor.General fire hazards
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6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Use appropriate containment to avoid environmental
contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other
suitable container for recovery or safe disposal. Local authorities should be advised if significant
spillages cannot be contained.
Personal precautions,
protective equipment and
emergency procedures
Use water spray to reduce vapors or divert vapor cloud drift. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Take precautionary measures against static discharge. Use only
non-sparking tools. Prevent entry into waterways, sewer, basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb spill with vermiculite or other inert material. Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground. Use appropriate containment to avoid environmental
contamination.
Environmental precautions
7. Handling and storage
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Minimize fire risks from flammable and combustible materials (including combustible
dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling
operations that can promote accumulation of static charges include but are not limited to: mixing,
filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container
filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take
precautionary measures against static discharges. All equipment used when handling the product
must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or
swallow. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid
prolonged exposure. Wear appropriate personal protective equipment. Wash hands thoroughly
after handling. Avoid release to the environment. Observe good industrial hygiene practices.
For additional information on equipment bonding and grounding, refer to the Canadian Electrical
Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice
2003, “Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents” or National
Fire Protection Association (NFPA) 77, “Recommended Practice on Static Electricity” or National
Fire Protection Association (NFPA) 70, “National Electrical Code”.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Keep at temperature not
exceeding 48.8 C. Prevent electrostatic charge build-up by using common bonding and grounding
techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and
equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place
out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place.
Keep in an area equipped with sprinklers. Avoid contact with oxidizing agents. Store away from
incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 2350 mg/m3Octane (CAS 111-65-9)
500 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 300 ppmOctane (CAS 111-65-9)
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US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
Ceiling 1800 mg/m3Octane (CAS 111-65-9)
385 ppm
TWA 350 mg/m3
75 ppm
No biological exposure limits noted for the ingredient(s).Biological limit values
Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Nitrile
gloves are recommended. Other suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing.Other
In case of inadequate ventilation or risk of inhalation of vapors, suitable respiratory equipment with
particulate filter and organic vapor cartridges can be used. If permissible levels are exceeded use
NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering
controls do not maintain airborne concentrations below recommended exposure limits (where
applicable) or to an acceptable level (in countries where exposure limits have not been
established), an approved respirator must be worn. Check with respiratory protective equipment
suppliers.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Colorless liquid.Form
Colorless.Color
Mild. Solvent.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot determined.
Initial boiling point and boiling
range
> 233.6 F (> 112 C)
Boiling point pressure 1013 hPa
Flash point 87.8 F (31.0 C) (Tagliabue Closed Cup)
Evaporation rate Slower than ether.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
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Vapor pressure Not available.
Vapor density Heavier than air.
Relative density 0.754 (H2O=1)
Solubility(ies)
Solubility (water) Slightly soluble in water.
Solubility (solvents) Soluble in organic solvents.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature > 392 F (> 200 C) (Value for solvent)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
VOC 754 g/l (of coating)
10. Stability and reactivity
The product is stable and non reactive under normal conditions of use, storage and transport.Reactivity
Risk of ignition.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Avoid heat, sparks, open flames and other ignition sources. Static discharge may cause ignition at
temperatures at or above flashpoint. Avoid temperatures exceeding the flash point. Contact with
incompatible materials. Spray mist may be flammable at temperatures below the flash point.
Conditions to avoid
Strong oxidizing agents.Incompatible materials
Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.
Hydrocarbons.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. May cause respiratory irritation. Prolonged inhalation may
be harmful.
Skin contact Causes skin irritation.
Eye contac
t Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include
stinging, tearing, redness, swelling, and blurred vision. May cause drowsiness and dizziness. May
cause respiratory irritation. Headache. Nausea, vomiting. Swallowing or vomiting of the liquid may
result in aspiration into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Be
aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after
exposure.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
Dibutyl Ether (CAS 142-96-1)
Oral
Acute
LD50 Rat 3230 – 3920 mg/kg
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
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This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Naphtha (petroleum), hydrotreated heavy
(CAS 64742-48-9)
3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause respiratory irritation. May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
Not classified.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.
Further information Symptoms may be delayed.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity
Components Test ResultsSpecies
Octane (CAS 111-65-9)
Aquatic
LC50Crustacea 0.38 mg/l, 48 hoursDaphnia magna
No data is available on the degradability of this product.Persistence and degradability
No data available on bioaccumulation.Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Dibutyl Ether (CAS 142-96-1) 3.21
Octane (CAS 111-65-9) 5.18
This product is slightly water soluble and may disperse in soil.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D001: Waste Flammable material with a flash point <140 F The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1866UN number Resin SolutionUN proper shipping name 3Class Transport hazard class(es) TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 6 / 9 -Subsidiary risk 3Label(s) IIIPacking group YesMarine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user B1, B52, IB3, T2, TP1Special provisions 150Packaging exceptions 173Packaging non bulk 242Packaging bulk IATA UN1866UN number Resin Solution, FlammableUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesEnvironmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN1866UN number Resin Solution, FlammableUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group YesMarine pollutant Environmental hazards F-E, S-EEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Dibutyl Ether (CAS 142-96-1) Listed. Octane (CAS 111-65-9) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. Toxic Substances Control Act (TSCA) SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. YesSARA 311/312 Hazardous chemical TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 7 / 9 Flammable (gases, aerosols, liquids, or solids) Skin corrosion or irritation Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Aspiration hazard Hazard not otherwise classified (HNOC) Classified hazard categories SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List Dibutyl Ether (CAS 142-96-1) Octane (CAS 111-65-9) US. New Jersey Worker and Community Right-to-Know Act Dibutyl Ether (CAS 142-96-1) Octane (CAS 111-65-9) US. Pennsylvania Worker and Community Right-to-Know Law Dibutyl Ether (CAS 142-96-1) Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Octane (CAS 111-65-9) US. Rhode Island RTK Dibutyl Ether (CAS 142-96-1) Octane (CAS 111-65-9) California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Octane (CAS 111-65-9) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) YesAustralia Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical Substances (EINECS) YesEurope European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) NoJapan Existing Chemicals List (ECL) YesKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesPhilippines Taiwan Chemical Substance Inventory (TCSI) YesTaiwan *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 8 / 9 16. Other information, including date of preparation or last revision 10-April-2014Issue date 24-November-2020Revision date Version # 04 NFPA ratings 02 3 TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer TR-930 Mold Release SDS US 3628 Version #: 04 Revision date: 24-November-2020 Issue date: 10-April-2014 9 / 9

37WA137A_SDS.pdf

SAFETY DATA SHEET
1. Identification
TR-100, TR-102, TR-104, TR-108 Mold ReleaseProduct identifier
Other means of identification
MR-100, MR-102, MR-104, MR-108Synonyms
Mold release.Recommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 2Flammable solidsPhysical hazards
Category 3 narcotic effectsSpecific target organ toxicity, single exposureHealth hazards
Category 3Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Warning
Hazard statement Flammable solid. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting
effects.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Ground/bond container and
receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing
vapors. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear
protective gloves/protective clothing/eye protection/face protection.
Response If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison
center/doctor if you feel unwell. Take off contaminated clothing and wash it before reuse. In case
of fire: Use water fog, alcohol resistant foam, dry chemical powder, carbon dioxide (CO2) to
extinguish.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
Repeated exposure may cause skin dryness or cracking.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
TR-100, TR-102, TR-104, TR-108 Mold Release SDS US
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CAS number %Chemical name
64742-48-9Naphtha (petroleum), hydrotreated
heavy
70 – 80
8015-86-9Carnauba wax 10 – 15
63148-62-9Polydimethylsiloxane 5 – 10
68441-17-8Polyethylene, oxidized 1 – 5
All concentrations are in percent by weight unless otherwise indicated.Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing is
difficult, give oxygen. Call a poison center or doctor/physician if you feel unwell.
Inhalation
Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Destroy or thoroughly clean contaminated shoes.
Skin contact
Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Continue
rinsing. Get medical attention if irritation develops and persists.
Eye contact
If vomiting occurs, keep head low so that stomach content does not get into the lungs. Get medical
attention immediately. Never give anything by mouth to a victim who is unconscious or is having
convulsions.
Ingestion
May cause drowsiness and dizziness. Narcosis. Headache. Nausea, vomiting.Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under
observation. Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off contaminated clothing and shoes immediately. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves. Show this safety data
sheet to the doctor in attendance. Wash contaminated clothing before re-use.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
During fire, gases hazardous to health may be formed. Thermal decomposition may produce
smoke, oxides of carbon and lower molecular weight organic compounds whose composition have
not been characterized.
Specific hazards arising from
the chemical
Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask.
Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective
equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. In the event
of fire, cool tanks with water spray. Cool containers exposed to flames with water until well after
the fire is out. Withdraw immediately in case of rising sound from venting safety device or any
discoloration of tanks due to fire. For massive fire in cargo area, use unmanned hose holder or
monitor nozzles, if possible. If not, withdraw and let fire burn out. Water runoff can cause
environmental damage.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Flammable solid.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. Be aware of potential for surfaces to become slippery. For personal
protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
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Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Should not be
released into the environment. Stop the flow of material, if this is without risk.
Large Spills: Wet down with water and dike for later disposal. Absorb in vermiculite, dry sand or
earth and place into containers. Shovel the material into waste container. Following product
recovery, flush area with water.
Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe
up with absorbent material. Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
This material and its container must be disposed of as hazardous waste. Absorb spill with
vermiculite or other inert material, then place in a sealed container for chemical waste.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Do not contaminate
water. Avoid discharge into drains, water courses or onto the ground.
Environmental precautions
7. Handling and storage
Provide adequate precautions, such as electrical grounding and bonding, or inert atmospheres. Do
not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Do not taste or swallow. Wear appropriate personal protective equipment. Avoid
release to the environment. Observe good industrial hygiene practices.
Precautions for safe handling
Keep away from heat, sparks and open flame. Store in a cool, dry place out of direct sunlight.
Store in tightly closed container. Store in a well-ventilated place. Store away from incompatible
materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
No exposure limits noted for ingredient(s).Occupational exposure limits
No biological exposure limits noted for the ingredient(s).Biological limit values
Occupational Exposure Limits are not relevant to the current physical form of the product.Exposure guidelines
Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Rubber gloves, butyl rubber, neoprene or PVC gloves
are recommended. Other suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Check with respiratory protective
equipment suppliers.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Solid.Physical state
Wax. Paste.Form
Various.Color
Hydrocarbon-like.Odor
Odor threshold Not available.
TR-100, TR-102, TR-104, TR-108 Mold Release SDS US
907216 Version #: 02 Revision date: 20-September-2022 Issue date: 10-June-2021
3 / 8

pH Not measured.
Melting point/freezing pointNot measured.
Initial boiling point and boiling
range
Not measured.
Flash point > 100.4 F (> 38 C) Cleveland Closed Cup (Estimated)
Evaporation rate Not available.
Flammable solid.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Explosive limit – lower (%)Not measured.
Explosive limit – upper (%)Not measured.
Vapor pressure Not measured.
Vapor density Not measured.
Relative density < 1 (H2O=1) (Estimated). Solubility(ies) Solubility (water) Negligible in water. Partition coefficient (n-octanol/water) Not applicable. Auto-ignition temperature Not measured. Decomposition temperature Not measured. Viscosity Not available. Other information Density < 1 (Estimated) Not explosive.Explosive properties Kinematic viscosity Not applicable. Not oxidizing.Oxidizing properties VOC 4.84 lb/gal (580g/l) 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Possibility of hazardous reactions Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Electrostatic discharge. Conditions to avoid Strong oxidizing agents.Incompatible materials Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Skin contact Repeated exposure may cause skin dryness or cracking. Eye contac t Direct contact with eyes may cause temporary irritation. Ingestion Ingestion may cause irritation and malaise. Symptoms related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Narcosis. Headache. Nausea, vomiting. Information on toxicological effects Acute toxicit y Not expected to be acutely toxic. Repeated exposure may cause skin dryness or cracking.Skin corrosion/irritation May cause eye irritation on direct contact.Serious eye damage/eye irritation TR-100, TR-102, TR-104, TR-108 Mold Release SDS US 907216 Version #: 02 Revision date: 20-September-2022 Issue date: 10-June-2021 4 / 8 Respiratory or skin sensitization Respiratory sensitizationNot a respiratory sensitizer. Not a skin sensitizer.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity Not classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) 3 Not classifiable as to carcinogenicity to humans. NTP Report on Carcinogens Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not relevant, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. Further information None known. 12. Ecological information Harmful to aquatic life with long lasting effects.Ecotoxicity There are no data on the degradability of this product.Persistence and degradability No data available on bioaccumulation.Bioaccumulative potential The product is insoluble or slightly soluble in water. Expected to have low mobility in soil.Mobility in soil Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation potential. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the material under controlled conditions in an approved incinerator. Do not incinerate sealed containers. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations D001: Waste Flammable material with a flash point <140 F The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner. Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN3175UN number Solids containing flammable liquid, n.o.s. (Naphtha (petroleum), hydrotreated heavy RQ = 125 LBS) UN proper shipping name 4.1Class Transport hazard class(es) -Subsidiary risk 4.1Label(s) IIPacking group TR-100, TR-102, TR-104, TR-108 Mold Release SDS US 907216 Version #: 02 Revision date: 20-September-2022 Issue date: 10-June-2021 5 / 8 NoMarine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 47, IB6, IP2, T3, TP33Special provisions 151Packaging exceptions 212Packaging non bulk 240Packaging bulk IATA UN3175UN number Solids containing flammable liquid, n.o.s. (Naphtha (petroleum), hydrotreated heavy)UN proper shipping name 4.1Class Transport hazard class(es) -Subsidiary risk 4.1Label(s) IIPacking group NoEnvironmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN3175UN number SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (Naphtha (petroleum), hydrotreated heavy)UN proper shipping name 4.1Class Transport hazard class(es) -Subsidiary risk IIPacking group NoMarine pollutant Environmental hazards F-A, S-IEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. Toxic Substances Control Act (TSCA) All components of the mixture on the TSCA 8(b) inventory are designated active . SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. YesSARA 311/312 Hazardous chemical Flammable (gases, aerosols, liquids, or solids) Specific target organ toxicity (single or repeated exposure) Classified hazard categories SARA 313 (TRI reporting) Not regulated. TR-100, TR-102, TR-104, TR-108 Mold Release SDS US 907216 Version #: 02 Revision date: 20-September-2022 Issue date: 10-June-2021 6 / 8 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Pennsylvania Worker and Community Right-to-Know Law Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) US. Rhode Island RTK Not regulated. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Industrial Chemicals (AICIS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesTaiwan Taiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 10-June-2021Issue date 20-September-2022Revision date Version # 02 NFPA ratings 02 2 HSDB - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity (Volumes 1-106) References TR-100, TR-102, TR-104, TR-108 Mold Release SDS US 907216 Version #: 02 Revision date: 20-September-2022 Issue date: 10-June-2021 7 / 8 TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Disclaimer TR-100, TR-102, TR-104, TR-108 Mold Release SDS US 907216 Version #: 02 Revision date: 20-September-2022 Issue date: 10-June-2021 8 / 8

37WA135B_SDS.pdf

SAFETY DATA SHEET
1. Identification
Product identifier
Other means of identification
Product code
Recommended use
TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound
MR307, MR307SP, MR309, MR315
Industrial use polish.
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Not classified.Physical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2Serious eye damage/eye irritation
Category 1ACarcinogenicity (inhalation)
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2 (lungs)Specific target organ toxicity, repeated
exposure (inhalation)
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. May
cause cancer by inhalation. May cause damage to organs (lungs) through prolonged or repeated
exposure by inhalation.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after
handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective
clothing/eye protection/face protection.
Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable
for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. If exposed or concerned: Get medical
advice/attention. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get
medical advice/attention. Take off contaminated clothing and wash it before reuse.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
SDS US
TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound
3627 Version #: 08 Revision date: – 15-September-2022 Issue date: 17-December-2014 1 / 8

Supplemental information None.
3. Composition/information on ingredients
Mixtures
7732-18-5 35 – 40Water
CAS number %Chemical name
64742-47-8 30 – 35Petroleum distillates
14808-60-7 15 – 20Quartz
61790-12-3 5 – 10Fatty acids, tall oil
8002-09-3 1 – 5Pine Oil
141-43-5 1 – < 32-Aminoethanol All concentrations are in percent by weight unless otherwise indicated.Composition comments 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. Inhalation Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical attention if symptoms occur. Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media During fire, gases hazardous to health may be formed.Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Cool containers exposed to flames with water until well after the fire is out. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods Will burn if involved in a fire.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures SDS US TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound 3627 Version #: 08 Revision date: - 15-September-2022 Is sue date: 17-December-2014 2 / 8 Prevent product from entering drains. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. Put material in suitable, covered, labeled containers. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment.Environmental precautions 7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep formation of airborne dusts to a minimum. Provide appropriate exhaust ventilation at places where dust is formed. Do not breathe dust/fume/vapors. Do not get in eyes, on skin, or on clothing. Avoid prolonged or repeated contact with skin. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Precautions for safe handling Keep away from heat and sources of ignition. Store in tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) ValueComponents Type TWA 0.05 mg/m3Quartz (CAS 14808-60-7) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 6 mg/m32-Aminoethanol (CAS 141-43-5) 3 ppm US. OSHA Table Z-3 (29 CFR 1910.1000) FormValueComponents Type TWA 0.1 mg/m3 Respirable.Quartz (CAS 14808-60-7) 2.4 mppcf Respirable. US. ACGIH Threshold Limit Values FormValueComponents Type STEL 6 ppm2-Aminoethanol (CAS 141-43-5) TWA 3 ppm TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7) US. NIOSH: Pocket Guide to Chemical Hazards Form ValueComponents Type STEL 15 mg/m32-Aminoethanol (CAS 141-43-5) 6 ppm TWA 8 mg/m3 3 ppm TWA 100 mg/m3Petroleum distillates (CAS 64742-47-8) TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7) No biological exposure limits noted for the ingredient(s).Biological limit values SDS US TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound 3627 Version #: 08 Revision date: - 15-September-2022 Is sue date: 17-December-2014 3 / 8 Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Provide easy access to water supply and eye wash facilities. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.Eye/face protection Skin protection Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Nitrile or neoprene gloves are recommended. Other suitable gloves can be recommended by the glove supplier. Hand protection Skin protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Check with respiratory protective equipment suppliers. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards Observe any medical surveillance requirements. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Solid.Physical state Paste.Form Not available.Color Not available.Odor Odor threshold Not available. pH Not applicable. Melting point/freezing pointNot available. Initial boiling point and boiling range Not available. Flash point > 140.0 F (> 60.0 C) (Estimated)
Evaporation rate Not applicable.
Will burn if involved in a fire.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Other information
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
SDS US
TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound
3627 Version #: 08 Revision date: – 15-September-2022 Is
sue date: 17-December-2014
4 / 8

10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizers, strong acids, and strong bases. Chlorine.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
Nitrogen oxides. Silicon oxide fumes.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
drowsiness and dizziness. May cause cancer by inhalation.
Skin contact Causes skin irritation. May be absorbed through the skin.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Eye contac
t Causes serious eye irritation.
Ingestion May cause discomfort if swallowed.
Symptoms related to the
physical, chemical and
toxicological characteristics
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain. Prolonged exposure may cause chronic effects.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
2-Aminoethanol (CAS 141-43-5)
Dermal
Acute
LD50 Rabbit 1025 mg/kg
Oral
LD50 Rat 1089 mg/kg
Quartz (CAS 14808-60-7)
Inhalation
Chronic
LOEC Human 0.0563 mg/m3
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity May cause cancer.
Occupational exposure to respirable dust and respirable crystalline silica should be monitored and
controlled.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
SDS US
TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound
3627 Version #: 08 Revision date: – 15-September-2022 Is
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5 / 8

This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (lungs) through prolonged or repeated exposure by inhalation.
Aspiration hazard Not an aspiration hazard.
Chronic effects May cause damage to organs through prolonged or repeated exposure. May be harmful if
absorbed through skin. Prolonged exposure may cause chronic effects.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Further information Symptoms may be delayed.
12. Ecological information
Not expected to be harmful to aquatic organisms.Ecotoxicity
Components Test ResultsSpecies
2-Aminoethanol (CAS 141-43-5)
Aquatic
Acute
EC50Algae 2.8 mg/l, 72 HoursPseudokirchnerella subcapitata
EC50Crustacea 32.6 mg/l, 48 HoursDaphnia magna
LC50Fish 150 mg/l, 96 HoursOncorhynchus mykiss
Chronic
EC50Crustacea 2.52 mg/l, 21 daysDaphnia magna
Petroleum distillates (CAS 64742-47-8)
Aquatic
Acute
LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss)
No data is available on the degradability of this product.Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Aminoethanol (CAS 141-43-5) -1.31
No data available for this product.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner.
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
Not regulated as dangerous goods.
SDS US
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3627 Version #: 08 Revision date: – 15-September-2022 Is
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IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
lung effects
immune system effects
kidney effects
Toxic Substances Control Act (TSCA) All components of the mixture on the TSCA 8(b) inventory are designated
active .
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK – Substance List
2-Aminoethanol (CAS 141-43-5)
Petroleum distillates (CAS 64742-47-8)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
2-Aminoethanol (CAS 141-43-5)
Petroleum distillates (CAS 64742-47-8)
Pine Oil (CAS 8002-09-3)
Quartz (CAS 14808-60-7)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Aminoethanol (CAS 141-43-5)
Petroleum distillates (CAS 64742-47-8)
Quartz (CAS 14808-60-7)
SDS US
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3627 Version #: 08 Revision date: – 15-September-2022 Is
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US. Rhode Island RTK
2-Aminoethanol (CAS 141-43-5)
Petroleum distillates (CAS 64742-47-8)
Quartz (CAS 14808-60-7)
California Proposition 65
This product can expose you to Quartz, which is known to the State of California to cause cancer.
For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 – CRT: Listed date/Carcinogenic substance
Quartz (CAS 14808-60-7) Listed: October 1, 1988
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Petroleum distillates (CAS 64742-47-8)
Quartz (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI) YesTaiwan
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
17-December-2014
15-September-2022
08
NFPA ratings
02
1
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
SDS US
TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound
3627 Version #: 08 Revision date: – 15-September-2022 Is
sue date: 17-December-2014
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