37BO105_SDS.pdf

DURAGLAS FIBERGLASS REINFORCED FILLER
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
24030
24030Product code :
Product Information
Telephone Number
:(330) 830-6000
Regulatory Information
Telephone Number
:(216) 566-2902
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
13.6%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 1/15
24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Do not breathe vapor. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling.
Response :IF exposed or concerned: Get medical advice or attention. IF SWALLOWED:
Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF ON SKIN
(or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF ON
SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Talc 25 – 50 14807-96-6
Styrene 13 100-42-5
Magnesium Carbonate 10 – 25 546-93-0
Wollastonite 10 13983-17-0
Calcium Carbonate 10 471-34-1
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 2/15
24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 3. Composition/information on ingredients
Occupational exposure limits, if available, are listed in Section 8.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Inhalation Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 3/15
24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Ingestion Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Flammable liquid.Remark :
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For non-emergency
personnel
Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 4/15
24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure –
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Talc 14807-96-6 NIOSH REL (United States, 10/2020).
TWA: 2 mg/m 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 1/2022).
TWA: 2 mg/m 8 hours. Form: Respirable
fraction
Styrene 100-42-5 ACGIH TLV (United States, 1/2022).
Ototoxicant.
TWA: 10 ppm 8 hours.
STEL: 20 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2020).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
Magnesium Carbonate 546-93-0 NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Wollastonite 13983-17-0 ACGIH TLV (United States, 1/2022).
TWA: 1 mg/m 8 hours. Form: Inhalable
fraction
Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020).
[calcium carbonate]
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada,
3/2022).
TWA: 2 mg/m 8 hours. Form: Respirable
CA Quebec Provincial (Canada, 6/2021).
TWAEV: 2 mg/m 8 hours. Form: Respirable
dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m 8 hours. Form:
Respirable particulate
CA Ontario Provincial (Canada, 6/2019).
TWA: 2 mg/m 8 hours. Form: Respirable
particulate matter.
TWA: 2 f/cc 8 hours.
CA Saskatchewan Provincial (Canada,
Ingredient name Exposure limits
Occupational exposure limits (Canada)
CAS #
CAS #
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24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 8. Exposure controls/personal protection
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
7/2013).
TWA: 2 mg/m 8 hours. Form: respirable
fraction
Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 40 ppm 15 minutes.
15 min OEL: 170 mg/m 15 minutes.
8 hrs OEL: 85 mg/m 8 hours.
8 hrs OEL: 20 ppm 8 hours.
CA British Columbia Provincial (Canada,
3/2022).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 35 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Quebec Provincial (Canada, 6/2021).
Absorbed through skin.
TWAEV: 50 ppm 8 hours.
TWAEV: 213 mg/m 8 hours.
STEV: 100 ppm 15 minutes.
STEV: 426 mg/m 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 40 ppm 15 minutes.
TWA: 20 ppm 8 hours.
Environmental exposure
controls
:
Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016).
Absorbed through skin.
TWA: 5 ppm 8 hours.
STEL: 10 ppm 15 minutes.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Liquid.
Not available.
1.7
3.6 [Air = 1]
Not available.Odor
pH
Not available.Color
Evaporation rate 0.49 (butyl acetate = 1)
Flash point Closed cup: 29 C (84.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not applicable.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
:145 C (293 F)
:Flammable liquid.
:Lower: 1.1%
Upper: 6.1%
Boiling point, initial boiling
point, and boiling range
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
0.57 kPa (4.3 mm Hg)
Solubility(ies) :
Media Result
cold water Not soluble
Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 8/15
24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 9. Physical and chemical properties
Auto-ignition temperature Not available.
Viscosity Kinematic (40 C (104 F)): <20.5 mm 2 /s (<20.5 cSt) : : Decomposition temperature:Not available. Heat of combustion :5.954 kJ/g Aerosol product Molecular weight :Not applicable. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LD50 Oral Rat 2650 mg/kg - Magnesium Carbonate LD50 Oral Rat 8000 mg/kg - Calcium Carbonate LD50 Oral Rat 6450 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Talc Skin - Mild irritant Human - 72 hours 300 ug I - Styrene Eyes - Mild irritant Human - 50 ppm - Eyes - Moderate irritantRabbit - 24 hours 100 mg - Eyes - Severe irritantRabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Skin - Moderate irritantRabbit - 100 % - Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750 ug - Skin - Moderate irritantRabbit - 24 hours 500 mg - Product/ingredient name Result Score Exposure Observation Sensitization Species Information on toxicological effects Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 9/15 24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Styrene Category 3 - Respiratory tract irritation Category 3 Narcotic effects Name Category Name Category Talc Category 1 inhalation lungs Styrene Category 1 - hearing organs Aspiration hazard Name Result Styrene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Classification Talc - 3 - Styrene - 2A Reasonably anticipated to be a human carcinogen. Wollastonite - 3 - Product/ingredient name NTPIARCOSHA Information on the likely routes of exposure Inhalation :No known significant effects or critical hazards. May be fatal if swallowed and enters airways.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Eye contact :Adverse symptoms may include the following: pain or irritation watering redness :Not available. Potential acute health effects Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 10/15 24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure.General : May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Skin contact Ingestion Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 19424.58 mg/kg Inhalation (gases) 20304.19 ppm Inhalation (vapors) 86.49 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects:Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects:Not available. Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 11/15 24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Styrene - 13.49 low Toxicity Styrene Acute EC50 78000 g/l Marine waterAlgae - Skeletonema costatum96 hours Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN SOLUTION RESIN SOLUTION
UN1866 UN1866
DOT
Classification
IMDG
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN SOLUTION
Mexico
Classification
UN1866
RESIN SOLUTION
IATA
UN1866
RESIN
SOLUTION
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Section 14. Transport information
3
III
3
III
– Emergency
schedules F-E, S-
E
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.
Not available.
:
Proper shipping name :
Not available.
:
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No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
3).
3
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No.

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
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ERG No.
127 127
ERG No. ERG No.
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
International regulations
International lists :
Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 13/15
24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 15. Regulatory information
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
Section 16. Other information
4/5/2023
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
4/5/2023
11/29/2022
9.01
Hazardous Material Information System (U.S.A.)
3
3
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
FLAMMABLE LIQUIDS – Category 3 On basis of test data
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 14/15
24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of issue/Date of revision :4/5/2023 Date of previous issue :11/29/2022 Version:9.01 15/15
24030 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

37BO105Q_SDS.pdf

DURAGLAS FIBERGLASS REINFORCED FILLER
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
24035
24035Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 17.3%
(oral), 30.8% (dermal), 17.3% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 1/16
24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Wash contaminated clothing before
reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get
medical advice or attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:Mixture
Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 2/16
24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 3. Composition/information on ingredients
Talc 25 – 50 14807-96-6
Unsaturated Polyester 10 – 25 –
Styrene 10 – <20 100-42-5 Magnesium Carbonate 10 - 25 546-93-0 Wollastonite 10 13983-17-0 Calcium Carbonate 10 471-34-1 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May be fatal if swallowed and enters airways.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 3/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Flammable liquid.Remark : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 4/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 5/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : Talc 14807-96-6 NIOSH REL (United States, 10/2020). TWA: 2 mg/m 10 hours. Form: Respirable fraction ACGIH TLV (United States, 1/2024). TWA: 2 mg/m 8 hours. Form: Respirable fraction Unsaturated Polyester None. Styrene 100-42-5 ACGIH TLV (United States, 1/2024). Ototoxicant. TWA: 10 ppm 8 hours. STEL: 20 ppm 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2020). TWA: 50 ppm 10 hours. TWA: 215 mg/m 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. Magnesium Carbonate 546-93-0 NIOSH REL (United States, 10/2020). TWA: 5 mg/m 10 hours. Form: Respirable fraction TWA: 10 mg/m 10 hours. Form: Total OSHA PEL (United States, 5/2018). TWA: 5 mg/m 8 hours. Form: Respirable fraction TWA: 15 mg/m 8 hours. Form: Total dust Wollastonite 13983-17-0 ACGIH TLV (United States, 1/2024). TWA: 1 mg/m 8 hours. Form: Inhalable fraction Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020). [calcium carbonate] TWA: 5 mg/m 10 hours. Form: Respirable fraction TWA: 10 mg/m 10 hours. Form: Total Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 6/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada, 8/2023). Notes: the value is for particulate matter containing no asbestos and less than 1% crystalline silica. TWA: 2 mg/m 8 hours. Form: Respirable CA Alberta Provincial (Canada, 3/2023). OEL: 2 mg/m 8 hours. Form: Respirable particulate CA Ontario Provincial (Canada, 6/2019). TWA: 2 mg/m 8 hours. Form: Respirable particulate matter. TWA: 2 f/cc 8 hours. CA Quebec Provincial (Canada, 2/2024). TWAEV: 2 mg/m 8 hours. Form: respirable aerosol fraction CA Saskatchewan Provincial (Canada, 4/2021). TWA: 2 mg/m 8 hours. Form: respirable fraction Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 3/2023). OEL: 40 ppm 15 minutes. OEL: 170 mg/m 15 minutes. OEL: 85 mg/m 8 hours. OEL: 20 ppm 8 hours. CA British Columbia Provincial (Canada, 8/2023). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 35 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Quebec Provincial (Canada, 2/2024). TWAEV: 50 ppm 8 hours. STEV: 75 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 40 ppm 15 minutes. TWA: 20 ppm 8 hours. Ingredient name Exposure limits Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 5 ppm 8 hours. STEL: 10 ppm 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # CAS # Biological exposure indices (United States) Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 7/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Environmental exposure controls : Styrene ACGIH BEI (United States, 1/2024) BEI: 150 mg/g creatinine, mandelic acid plus phenylglyoxylic acid [in urine]. Sampling time: end of shift. BEI: 20 g/l, styrene [in urine]. Sampling time: end of shift. Ingredient name Exposure indices Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. Styrene Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 0.2 mg/L [semi-quantitative.The biological determinant is an indicator of chemical exposure, but the quantitative interpretation of the measure is ambiguous. These biological determinants should be used as a screening test if a quantitative test is not possible.], styrene [in venous blood]. Sampling time: at the end of the work shift. BEI: 400 mg/g creatinine [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], mandelic Acid plus Phenylglyoxylic Acid [in urine]. Sampling time: at the end of the work shift. Ingredient name Exposure indices Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 8/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Liquid. Not available. 1.66 3.6 [Air = 1] Not available.Odor pH Green.Color Evaporation rate 0.49 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 29 C (84.2 F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40 C (104 F)): <20.5 mm 2 /s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : Appearance :145 C (293 F) :Flammable liquid. :Lower: 1.1% Upper: 6.1% Decomposition temperature:Not available. Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 0.57 kPa (4.3 mm Hg) Solubility(ies) : Media Result cold water Not soluble Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 9/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 9. Physical and chemical properties Heat of combustion :5.88 kJ/g Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LD50 Oral Rat 2650 mg/kg - Magnesium Carbonate LD50 Oral Rat 8000 mg/kg - Calcium Carbonate LD50 Oral Rat 6450 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Irritation/Corrosion Talc Skin - Mild irritant Human - 72 hours 300 ug I - Styrene Eyes - Mild irritant Human - 50 ppm - Eyes - Moderate irritantRabbit - 24 hours 100 mg - Eyes - Severe irritantRabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Skin - Moderate irritantRabbit - 100 % - Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750 ug - Skin - Moderate irritantRabbit - 24 hours 500 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 10/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Styrene Category 3 - Respiratory tract irritation Name Category Name Category Talc Category 1 inhalation lungs Styrene Category 1 - hearing organs Aspiration hazard Name Result Styrene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Classification Talc - 3 - Styrene - 2A Reasonably anticipated to be a human carcinogen. Wollastonite - 3 - Product/ingredient name NTPIARCOSHA Information on the likely routes of exposure Inhalation :Harmful if inhaled. May be fatal if swallowed and enters airways.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness :Not available. Potential acute health effects Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 11/16 24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Ingestion Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 16248.31 mg/kg Inhalation (gases) 16984.08 ppm Inhalation (vapors) 72.35 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects:Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects:Not available. Section 12. Ecological information Toxicity Styrene Acute EC50 1400 g/l Fresh water Algae - Raphidocelis subcapitata72 hours Acute EC50 720 g/l Fresh water Algae - Raphidocelis subcapitata96 hours Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 63 g/l Fresh water Algae - Raphidocelis subcapitata96 hours Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Not available.
Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 12/16
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Styrene – 13.49 Low
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN SOLUTION
3
III
RESIN SOLUTION
3
III
UN1866 UN1866
– Emergency
schedules F-E, S-
E
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No.
TDG
Classification
UN1866
RESIN SOLUTION
3
III
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
Mexico
Classification
UN1866
RESIN SOLUTION
3
III
No.

IATA
UN1866
RESIN
SOLUTION
3
III
No.

Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 13/16
24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

Section 14. Transport information
Special precautions for user
Transport in bulk according
to IMO instruments
Not available.
:
Proper shipping name :
Not available.
:
3).
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
127
ERG No.
127 127
ERG No. ERG No.
Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Lead (as Pb) 0.000009
Styrene 13 100-42-5
Ingredient name CAS number% by weight
SARA 313
Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 14/16
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Section 15. Regulatory information
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
Section 16. Other information
1/13/2025
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/13/2025
12/13/2024
15
Hazardous Material Information System (U.S.A.)
3
3
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
FLAMMABLE LIQUIDS – Category 3 On basis of test data
ACUTE TOXICITY (inhalation) – Category 4 Calculation method
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 15/16
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of issue/Date of revision :1/13/2025Date of previous issue :12/13/2024 Version:15 16/16
24035 DURAGLAS FIBERGLASS REINFORCED FILLER SHW-85-NA-GHS-US

37BO104C_SDS.pdf

FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
21335
21335Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 31.5%
(oral), 48.2% (dermal), 31.5% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 1/17
21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
FILLER
SHW-85-NA-GHS-US

Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Wash contaminated clothing before
reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get
medical advice or attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:Mixture
Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 2/17
21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
FILLER
SHW-85-NA-GHS-US

Section 3. Composition/information on ingredients
Calcium Carbonate 25 – 50 471-34-1
Unsaturated Polyester 25 – 50 –
Styrene 10 – <20 100-42-5 Talc 10 14807-96-6 Silica gel, pptd., cryst.-free 3 112926-00-8 Titanium Dioxide 0.3 13463-67-7 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May be fatal if swallowed and enters airways.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 3/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Flammable liquid.Remark : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 4/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 5/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020). [calcium carbonate] TWA: 5 mg/m 10 hours. Form: Respirable fraction TWA: 10 mg/m 10 hours. Form: Total Unsaturated Polyester None. Styrene 100-42-5 ACGIH TLV (United States, 1/2024). Ototoxicant. TWA: 10 ppm 8 hours. STEL: 20 ppm 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2020). TWA: 50 ppm 10 hours. TWA: 215 mg/m 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. Talc 14807-96-6 NIOSH REL (United States, 10/2020). TWA: 2 mg/m 10 hours. Form: Respirable fraction ACGIH TLV (United States, 1/2024). TWA: 2 mg/m 8 hours. Form: Respirable fraction Silica gel, pptd., cryst.-free 112926-00-8 NIOSH REL (United States, 10/2020). [SILICA, AMORPHOUS] TWA: 6 mg/m 10 hours. Titanium Dioxide 13463-67-7 OSHA PEL (United States, 5/2018). TWA: 15 mg/m 8 hours. Form: Total dust ACGIH TLV (United States, 1/2024). TWA: 2.5 mg/m 8 hours. Form: respirable fraction, finescale particles Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Occupational exposure limits (Canada) CAS # Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 6/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 3/2023). OEL: 40 ppm 15 minutes. OEL: 170 mg/m 15 minutes. OEL: 85 mg/m 8 hours. OEL: 20 ppm 8 hours. CA British Columbia Provincial (Canada, 8/2023). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 35 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Quebec Provincial (Canada, 2/2024). TWAEV: 50 ppm 8 hours. STEV: 75 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 40 ppm 15 minutes. TWA: 20 ppm 8 hours. talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada, 8/2023). Notes: the value is for particulate matter containing no asbestos and less than 1% crystalline silica. TWA: 2 mg/m 8 hours. Form: Respirable CA Alberta Provincial (Canada, 3/2023). OEL: 2 mg/m 8 hours. Form: Respirable particulate CA Ontario Provincial (Canada, 6/2019). TWA: 2 mg/m 8 hours. Form: Respirable particulate matter. TWA: 2 f/cc 8 hours. CA Quebec Provincial (Canada, 2/2024). TWAEV: 2 mg/m 8 hours. Form: respirable aerosol fraction CA Saskatchewan Provincial (Canada, 4/2021). TWA: 2 mg/m 8 hours. Form: respirable fraction Ingredient name Exposure limits Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 5 ppm 8 hours. STEL: 10 ppm 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # CAS # Biological exposure indices (United States) Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 7/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Environmental exposure controls : Styrene ACGIH BEI (United States, 1/2024) BEI: 150 mg/g creatinine, mandelic acid plus phenylglyoxylic acid [in urine]. Sampling time: end of shift. BEI: 20 g/l, styrene [in urine]. Sampling time: end of shift. Ingredient name Exposure indices Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. Styrene Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 0.2 mg/L [semi-quantitative.The biological determinant is an indicator of chemical exposure, but the quantitative interpretation of the measure is ambiguous. These biological determinants should be used as a screening test if a quantitative test is not possible.], styrene [in venous blood]. Sampling time: at the end of the work shift. BEI: 400 mg/g creatinine [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], mandelic Acid plus Phenylglyoxylic Acid [in urine]. Sampling time: at the end of the work shift. Ingredient name Exposure indices Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 8/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Liquid. Not available. 0.98 3.6 [Air = 1] Not available.Odor pH White.Color Evaporation rate 0.49 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 41 C (105.8 F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40 C (104 F)): <20.5 mm 2 /s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : Appearance :145 C (293 F) :Flammable liquid. :Lower: 1.1% Upper: 6.1% Decomposition temperature:Not available. Molecular weight :Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 0.57 kPa (4.3 mm Hg) Solubility(ies) : Media Result cold water Not soluble Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 9/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 9. Physical and chemical properties Heat of combustion :7.622 kJ/g Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Calcium Carbonate LD50 Oral Rat 6450 mg/kg - Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LD50 Oral Rat 2650 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Mutagenicity Not available. Irritation/Corrosion Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750 ug - Skin - Moderate irritantRabbit - 24 hours 500 mg - Styrene Eyes - Mild irritant Human - 50 ppm - Eyes - Moderate irritantRabbit - 24 hours 100 mg - Eyes - Severe irritantRabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Skin - Moderate irritantRabbit - 100 % - Talc Skin - Mild irritant Human - 72 hours 300 ug I - Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 ug I - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 10/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Styrene Category 3 - Respiratory tract irritation Name Category Name Category Styrene Category 1 - hearing organs Talc Category 1 inhalation lungs Aspiration hazard Name Result Styrene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Classification Styrene - 2A Reasonably anticipated to be a human carcinogen. Talc - 3 - Silica gel, pptd., cryst.-free- 3 - Titanium Dioxide - 2B - Product/ingredient name NTPIARCOSHA Information on the likely routes of exposure Inhalation :Harmful if inhaled. May be fatal if swallowed and enters airways.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness :Not available. Potential acute health effects Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 11/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Skin contact Ingestion Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 10827.83 mg/kg Inhalation (gases) 11318.14 ppm Inhalation (vapors) 48.21 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Short term exposure Potential delayed effects:Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects:Not available. Section 12. Ecological information Toxicity Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 12/17 21335 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Styrene - 13.49 Low Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Styrene Acute EC50 1400 g/l Fresh water Algae – Raphidocelis subcapitata72 hours
Acute EC50 720 g/l Fresh water Algae – Raphidocelis subcapitata96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina 48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae – Raphidocelis subcapitata96 hours
Titanium Dioxide Acute LC50 >1000000 g/l Marine waterFish – Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN SOLUTION RESIN SOLUTION
UN1866 UN1866
DOT
Classification
IMDG
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN SOLUTION
Mexico
Classification
UN1866
RESIN SOLUTION
IATA
UN1866
RESIN
SOLUTION
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Section 14. Transport information
3
III
3
III
This product may
be re-classified as
“Combustible
Liquid,” unless
transported by
vessel or aircraft.
Non-bulk
packages (less
than or equal to
119 gal) of
combustible
liquids are not
regulated as
hazardous
materials in
package sizes
less than the
product reportable
quantity.
Emergency
schedules F-E, S-
E
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.
Not available.
:
Proper shipping name :
Not available.
:
3
III
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
3).
3
III
No.

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
3
III
No.

127
ERG No.
127 127
ERG No. ERG No.
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Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Lead (as Pb) 0.0000005
Styrene 17 100-42-5
Ingredient name CAS number% by weight
SARA 313
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Procedure used to derive the classification
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Section 16. Other information
1/13/2025
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/13/2025
12/14/2024
14
FLAMMABLE LIQUIDS – Category 3 On basis of test data
ACUTE TOXICITY (inhalation) – Category 4 Calculation method
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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Date of issue/Date of revision :1/13/2025Date of previous issue :12/14/2024 Version:14 17/17
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37BO103_SDS.pdf

CREAM HARDENER
RED
Not available.
Solid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
27110
27110Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
ORGANIC PEROXIDES – Type E
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1%
(oral), 57% (dermal), 57% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Heating may cause a fire.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep
away from clothing and other combustible materials. Keep only in original packaging.
Do not breathe dust. Wash thoroughly after handling. Contaminated work clothing
must not be allowed out of the workplace.
Response :Get medical advice or attention if you feel unwell. Take off contaminated clothing and
wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash
with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage :Protect from sunlight. Store at temperatures not exceeding 25 C/77 F. Keep cool.
Store separately.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains a chemical known to the State of California to cause
cancer. FOR PROFESSIONAL USE ONLY. This product must be mixed with other
components before use. Before opening the packages, READ AND FOLLOW
WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Dibenzoyl peroxide 50 – 75 94-36-0
Zinc Stearate 10 557-05-1
Calcium Sulfate 5 7778-18-9
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica 3 68909-20-6
Iron Oxide 3 1309-37-1
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
be delayed. The exposed person may need to be kept under medical surveillance for
48 hours.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Runoff to sewer may create fire or explosion hazard. This material increases the risk of
fire and may aid combustion. Heating may cause a fire. May re-ignite itself after fire is
extinguished. Hazardous decomposition may occur.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid contamination with reactive substances. Avoid dust
generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. Dispose of via a licensed waste
disposal contractor. Note: see Section 1 for emergency contact information and Section
13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid contamination with reactive substances. Avoid dust generation. Do not dry
sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Place spilled material in a designated, labeled waste container.
Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
To avoid the risk of formation of shock-sensitive crystals or loss of stability, it is
important to store the product within the recommended temperature range.
Temperature control may be required. Store in accordance with local regulations. Store
in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section 10) and food and drink. Store at temperatures not exceeding 25 C/77 F.
Eliminate all ignition sources. Separate from reducing agents and combustible
materials. Keep away from rust, iron and copper. Keep container tightly closed and
sealed until ready for use. Prevent product contamination. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Use only
with adequate ventilation. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Keep away from clothing, incompatible materials and combustible materials.
Temperature control may be required. Empty containers retain product residue and can
be hazardous. Do not reuse container.
:
Precautions for safe handling
Dibenzoyl peroxide 94-36-0 ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours.
Zinc Stearate 557-05-1 ACGIH TLV (United States, 1/2024).
[Stearates]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
TWA: 3 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Section 8. Exposure controls/personal protection
Calcium Sulfate 7778-18-9 ACGIH TLV (United States, 1/2024).
[Calcium sulfate]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-,
hydrolysis products with silica
68909-20-6 None.
Iron Oxide 1309-37-1 NIOSH REL (United States, 10/2020). [iron
oxide dust and fume]
TWA: 5 mg/m , (as Fe) 10 hours. Form: Dust
and fumes
ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Dibenzoyl peroxide 94-36-0 CA Alberta Provincial (Canada, 3/2023).
OEL: 5 mg/m 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 5 mg/m 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 5 mg/m 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 5 mg/m 8 hours.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 10 mg/m 15 minutes.
TWA: 5 mg/m 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Dibenzoyl peroxide 94-36-0 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 5 mg/m 8 hours.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
No exposure indices known.
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
No exposure indices known.
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment. Use with adequate ventilation.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Solid.
Not available.
Not available.Odor
pH
Red.Color
Flash point Closed cup: 94 C (201.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
Appearance
:100 C (212 F)Boiling point, initial boiling
point, and boiling range
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density 1.19
1 [Air = 1]
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature Not applicable.
Not applicable.
Viscosity Kinematic (40 C (104 F)): >20.5 mm
2
/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:Not available.
:Not applicable.
SADT 50 C (122 F):
Decomposition temperature:Not available.
Heat of combustion :21.85 kJ/g
Molecular weight :Not applicable.
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
2.3 kPa (17.5 mm Hg)
Solubility(ies) :
Media Result
cold water Partially soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid increased storage
temperature.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
combustible materials
reducing materials
copper
iron
rust
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Conditions may include the following:
temperature increase
high temperature
Reactions may include the following:
hazardous decomposition
risk of causing fire
Reactivity :This product, in laboratory testing, neither detonates nor deflagrates and only shows low
or no effect when heated under confinement.
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Section 11. Toxicological information
Acute toxicity
Dibenzoyl peroxide LD50 Oral Rat 6400 mg/kg –
Zinc Stearate LD50 Oral Rat >10 g/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Dibenzoyl peroxide Eyes – Mild irritant Rabbit – 24 hours 500
mg

Skin – Moderate irritantWoman – 1 % –
Skin – Severe irritantHuman – 1344 hours 5
% I

Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis
products with silica
Category 2 inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Dibenzoyl peroxide – 3 –
Iron Oxide – 3 –
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Dibenzoyl peroxide – – Inherent
Dibenzoyl peroxide EC10 0.001 mg/l Daphnia 21 days
EC50 0.0711 mg/l Algae 72 hours
Acute EC50 0.11 mg/l Daphnia 48 hours
Calcium Sulfate Acute LC50 >1910 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia
48 hours
Acute LC50 >1970 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 2980 ppm Fresh water Fish – Lepomis macrochirus 96 hours
Chronic NOEC 360 mg/l Fresh water Daphnia – Daphnia magna –
Neonate
3 weeks
Chronic NOEC 233 mg/l Fresh water Fish – Coregonus albula – Egg 60 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Do not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
:Disposal methods
Section 14. Transport information
UN3108 UN3108
DOT
Classification
IMDG
UN number
TDG
Classification
UN3108
Mexico
Classification
UN3108
IATA
UN3108
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Section 14. Transport information
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide). Marine
pollutant
(Dibenzoyl
peroxide, Zinc
Stearate)
5.2

– The marine
pollutant mark is
not required when
transported in
sizes of 5 L or 5
kg.
Emergency
schedules F-J, S-
R
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. Yes.
Not available.
:
Proper shipping name :
Not available.
:
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.23-2.25 (Class
5).
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

No.

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
ORGANIC
PEROXIDE
TYPE E, SOLID
(Dibenzoyl
peroxide)
5.2

Yes. The
environmentally
hazardous
substance mark
is not required.
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
145
ERG No.
145 145
ERG No. ERG No.
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Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains a chemical known to the State of California to cause cancer.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Zinc Compound 6
Dibenzoyl peroxide 50 94-36-0
Ingredient name CAS number% by weight
SARA 313
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
0
4
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Procedure used to derive the classification
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Section 16. Other information
1/15/2025
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/15/2025
12/13/2024
13.02
ORGANIC PEROXIDES – Type E Expert judgment
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2 Calculation method
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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37BO104B_SDS.pdf

FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
21330
21330Product code :
Product Information
Telephone Number
:(330) 830-6000
Regulatory Information
Telephone Number
:(216) 566-2902
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
CARCINOGENICITY – Category 1B
TOXIC TO REPRODUCTION – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1
ASPIRATION HAZARD – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
17%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 1/15
21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY
FILLER
SHW-85-NA-GHS-US

Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.
Response :IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water.
If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice or attention.
Storage :Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
lungs)
:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. This
product must be mixed with other components before use. Before opening the
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Calcium Carbonate 25 – 50 471-34-1
Styrene 10 – <20 100-42-5 Talc 10 14807-96-6 Silica gel, pptd., cryst.-free 3 112926-00-8 Titanium Dioxide 0.3 13463-67-7 Ingredient name CAS number% by weight Other means of identification :Not available. Substance/mixture CAS number/other identifiers :Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 2/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Occupational exposure limits, if available, are listed in Section 8. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May be fatal if swallowed and enters airways.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 3/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Ingestion Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Flammable liquid.Remark : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 4/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 5/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Calcium Carbonate 471-34-1 NIOSH REL (United States, 10/2020). [calcium carbonate] TWA: 5 mg/m 10 hours. Form: Respirable fraction TWA: 10 mg/m 10 hours. Form: Total Styrene 100-42-5 ACGIH TLV (United States, 1/2022). Ototoxicant. TWA: 10 ppm 8 hours. STEL: 20 ppm 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2020). TWA: 50 ppm 10 hours. TWA: 215 mg/m 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m 15 minutes. Talc 14807-96-6 NIOSH REL (United States, 10/2020). TWA: 2 mg/m 10 hours. Form: Respirable fraction ACGIH TLV (United States, 1/2022). TWA: 2 mg/m 8 hours. Form: Respirable fraction Silica gel, pptd., cryst.-free 112926-00-8 NIOSH REL (United States, 10/2020). [SILICA, AMORPHOUS] TWA: 6 mg/m 10 hours. Titanium Dioxide 13463-67-7 OSHA PEL (United States, 5/2018). TWA: 15 mg/m 8 hours. Form: Total dust ACGIH TLV (United States, 1/2022). TWA: 2.5 mg/m 8 hours. Form: respirable fraction, finescale particles Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Vinyl benzene 100-42-5 CA Alberta Provincial (Canada, 6/2018). 15 min OEL: 40 ppm 15 minutes. 15 min OEL: 170 mg/m 15 minutes. 8 hrs OEL: 85 mg/m 8 hours. 8 hrs OEL: 20 ppm 8 hours. CA British Columbia Provincial (Canada, 3/2022). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 35 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). Absorbed through skin. TWAEV: 50 ppm 8 hours. TWAEV: 213 mg/m 8 hours. STEV: 100 ppm 15 minutes. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # CAS # Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 6/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. STEV: 426 mg/m 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 40 ppm 15 minutes. TWA: 20 ppm 8 hours. talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada, 3/2022). TWA: 2 mg/m 8 hours. Form: Respirable CA Quebec Provincial (Canada, 6/2021). TWAEV: 2 mg/m 8 hours. Form: Respirable dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 2 mg/m 8 hours. Form: Respirable particulate CA Ontario Provincial (Canada, 6/2019). TWA: 2 mg/m 8 hours. Form: Respirable particulate matter. TWA: 2 f/cc 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). TWA: 2 mg/m 8 hours. Form: respirable fraction Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada, 3/2022). TWA: 10 mg/m 8 hours. Form: Total dust TWA: 3 mg/m 8 hours. Form: respirable fraction CA Quebec Provincial (Canada, 6/2021). TWAEV: 10 mg/m 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 10 mg/m 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 20 mg/m 15 minutes. TWA: 10 mg/m 8 hours. Styrene 100-42-5 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. N,N-dimethylaniline 121-69-7 NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 5 ppm 8 hours. STEL: 10 ppm 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 7/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : Section 9. Physical and chemical properties Physical state Melting point/freezing point Liquid. Not available. Not available.Odor pH Not available.Color Evaporation rate 0.49 (butyl acetate = 1) Flash point Closed cup: 41 C (105.8 F) [Pensky-Martens Closed Cup] Not applicable. Not available.Odor threshold : : : : : : : : Appearance :145 C (293 F) :Flammable liquid. :Lower: 1.1% Upper: 6.1% Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 8/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 9. Physical and chemical properties Vapor pressure Relative density 1 3.6 [Air = 1] Auto-ignition temperature Not available. Not applicable. Viscosity Kinematic (40 C (104 F)): <20.5 mm 2 /s (<20.5 cSt) Partition coefficient: n- octanol/water : : : : : : Decomposition temperature:Not available. Heat of combustion :7.756 kJ/g Aerosol product Molecular weight :Not applicable. Relative vapor density 0.57 kPa (4.3 mm Hg) Solubility(ies) : Media Result cold water Not soluble Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Calcium Carbonate LD50 Oral Rat 6450 mg/kg - Styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m 4 hours LD50 Oral Rat 2650 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Information on toxicological effects Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 9/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Calcium Carbonate Eyes - Severe irritantRabbit - 24 hours 750 ug - Skin - Moderate irritantRabbit - 24 hours 500 mg - Styrene Eyes - Mild irritant Human - 50 ppm - Eyes - Moderate irritantRabbit - 24 hours 100 mg - Eyes - Severe irritantRabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Skin - Moderate irritantRabbit - 100 % - Talc Skin - Mild irritant Human - 72 hours 300 ug I - Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 ug I - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Styrene Category 3 - Respiratory tract irritation Category 3 Narcotic effects Name Category Name Category Styrene Category 1 - hearing organs Talc Category 1 inhalation lungs Aspiration hazard Name Result Styrene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Classification Styrene - 2A Reasonably anticipated to be a human carcinogen. Talc - 3 - Silica gel, pptd., cryst.-free- 3 - Titanium Dioxide - 2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 10/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Information on the likely routes of exposure Inhalation :Harmful if inhaled. May be fatal if swallowed and enters airways.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Causes damage to organs through prolonged or repeated exposure.General : May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Acute toxicity estimates :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects:Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects:Not available. Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 11/15 21330 FEATHER-RITE QUALITY LIGHTWEIGHT AUTOBODY FILLER SHW-85-NA-GHS-US Section 11. Toxicological information Oral 15544.54 mg/kg Inhalation (gases) 16248.44 ppm Inhalation (vapors) 69.22 mg/l Route ATE value Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Styrene - 13.49 low Toxicity Calcium Carbonate Acute LC50 >56000 ppm Fresh water Fish – Gambusia affinis – Adult96 hours
Chronic NOEC 16.5 mg/l Fresh waterFish – Rhamdia quelen 30 days
Styrene Acute EC50 78000 g/l Marine waterAlgae – Skeletonema costatum96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Titanium Dioxide Acute LC50 >1000000 g/l Marine waterFish – Fundulus heteroclitus96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 12/15
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Section 14. Transport information
RESIN SOLUTION
3
III
RESIN SOLUTION
3
III
UN1866 UN1866
This product may
be re-classified as
“Combustible
Liquid,” unless
transported by
vessel or aircraft.
Non-bulk
packages (less
than or equal to
119 gal) of
combustible
liquids are not
regulated as
hazardous
materials in
package sizes
less than the
product reportable
quantity.
Emergency
schedules F-E, S-
E
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. No.
Not available.
:
Proper shipping name :
Not available.
:
TDG
Classification
UN1866
RESIN SOLUTION
3
III
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
3).
Mexico
Classification
UN1866
RESIN SOLUTION
3
III
No.

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
UN1866
RESIN
SOLUTION
3
III
No.

127
ERG No.
127 127
ERG No. ERG No.
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Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
11/29/2022
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
11/29/2022
6/20/2022
8
Hazardous Material Information System (U.S.A.)
3
2
0
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
FLAMMABLE LIQUIDS – Category 3 On basis of test data
ACUTE TOXICITY (inhalation) – Category 4 Calculation method
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
CARCINOGENICITY – Category 1B Calculation method
TOXIC TO REPRODUCTION – Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 1 Calculation method
ASPIRATION HAZARD – Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 14/15
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Key to abbreviations :
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :11/29/2022Date of previous issue :6/20/2022 Version:8 15/15
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37BO103D_SDS.pdf

CREAM HARDENER
RED
Not available.
Solid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
27120
27120Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
ORGANIC PEROXIDES – Type E
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1%
(oral), 57% (dermal), 57% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Heating may cause a fire.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep
away from clothing and other combustible materials. Keep only in original packaging.
Do not breathe dust. Wash thoroughly after handling. Contaminated work clothing
must not be allowed out of the workplace.
Response :Get medical advice or attention if you feel unwell. Take off contaminated clothing and
wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash
with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage :Protect from sunlight. Store at temperatures not exceeding 25 C/77 F. Keep cool.
Store separately.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains a chemical known to the State of California to cause
cancer. FOR PROFESSIONAL USE ONLY. This product must be mixed with other
components before use. Before opening the packages, READ AND FOLLOW
WARNING LABELS ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Dibenzoyl peroxide 50 – 75 94-36-0
Zinc Stearate 10 557-05-1
Calcium Sulfate 5 7778-18-9
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica 3 68909-20-6
Iron Oxide 3 1309-37-1
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
be delayed. The exposed person may need to be kept under medical surveillance for
48 hours.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Runoff to sewer may create fire or explosion hazard. This material increases the risk of
fire and may aid combustion. Heating may cause a fire. May re-ignite itself after fire is
extinguished. Hazardous decomposition may occur.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid contamination with reactive substances. Avoid dust
generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. Dispose of via a licensed waste
disposal contractor. Note: see Section 1 for emergency contact information and Section
13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid contamination with reactive substances. Avoid dust generation. Do not dry
sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Place spilled material in a designated, labeled waste container.
Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
To avoid the risk of formation of shock-sensitive crystals or loss of stability, it is
important to store the product within the recommended temperature range.
Temperature control may be required. Store in accordance with local regulations. Store
in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section 10) and food and drink. Store at temperatures not exceeding 25 C/77 F.
Eliminate all ignition sources. Separate from reducing agents and combustible
materials. Keep away from rust, iron and copper. Keep container tightly closed and
sealed until ready for use. Prevent product contamination. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Use only
with adequate ventilation. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Keep away from clothing, incompatible materials and combustible materials.
Temperature control may be required. Empty containers retain product residue and can
be hazardous. Do not reuse container.
:
Precautions for safe handling
Dibenzoyl peroxide 94-36-0 ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours.
Zinc Stearate 557-05-1 ACGIH TLV (United States, 1/2024).
[Stearates]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
TWA: 3 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Section 8. Exposure controls/personal protection
Calcium Sulfate 7778-18-9 ACGIH TLV (United States, 1/2024).
[Calcium sulfate]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-,
hydrolysis products with silica
68909-20-6 None.
Iron Oxide 1309-37-1 NIOSH REL (United States, 10/2020). [iron
oxide dust and fume]
TWA: 5 mg/m , (as Fe) 10 hours. Form: Dust
and fumes
ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Dibenzoyl peroxide 94-36-0 CA Alberta Provincial (Canada, 3/2023).
OEL: 5 mg/m 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 5 mg/m 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 5 mg/m 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 5 mg/m 8 hours.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 10 mg/m 15 minutes.
TWA: 5 mg/m 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Dibenzoyl peroxide 94-36-0 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 5 mg/m 8 hours.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
No exposure indices known.
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
No exposure indices known.
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment. Use with adequate ventilation.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Solid.
Not available.
Not available.Odor
pH
Red.Color
Flash point Closed cup: 94 C (201.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
Appearance
:100 C (212 F)Boiling point, initial boiling
point, and boiling range
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density 1.19
1 [Air = 1]
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature Not applicable.
Not applicable.
Viscosity Kinematic (40 C (104 F)): >20.5 mm
2
/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:Not available.
:Not applicable.
SADT 50 C (122 F):
Decomposition temperature:Not available.
Heat of combustion :21.85 kJ/g
Molecular weight :Not applicable.
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
2.3 kPa (17.5 mm Hg)
Solubility(ies) :
Media Result
cold water Partially soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid increased storage
temperature.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
combustible materials
reducing materials
copper
iron
rust
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Conditions may include the following:
temperature increase
high temperature
Reactions may include the following:
hazardous decomposition
risk of causing fire
Reactivity :This product, in laboratory testing, neither detonates nor deflagrates and only shows low
or no effect when heated under confinement.
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Section 11. Toxicological information
Acute toxicity
Dibenzoyl peroxide LD50 Oral Rat 6400 mg/kg –
Zinc Stearate LD50 Oral Rat >10 g/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Dibenzoyl peroxide Eyes – Mild irritant Rabbit – 24 hours 500
mg

Skin – Moderate irritantWoman – 1 % –
Skin – Severe irritantHuman – 1344 hours 5
% I

Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis
products with silica
Category 2 inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Dibenzoyl peroxide – 3 –
Iron Oxide – 3 –
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Dibenzoyl peroxide – – Inherent
Dibenzoyl peroxide EC10 0.001 mg/l Daphnia 21 days
EC50 0.0711 mg/l Algae 72 hours
Acute EC50 0.11 mg/l Daphnia 48 hours
Calcium Sulfate Acute LC50 >1910 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia
48 hours
Acute LC50 >1970 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 2980 ppm Fresh water Fish – Lepomis macrochirus 96 hours
Chronic NOEC 360 mg/l Fresh water Daphnia – Daphnia magna –
Neonate
3 weeks
Chronic NOEC 233 mg/l Fresh water Fish – Coregonus albula – Egg 60 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Do not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
:Disposal methods
Section 14. Transport information
UN3108 UN3108
DOT
Classification
IMDG
UN number
TDG
Classification
UN3108
Mexico
Classification
UN3108
IATA
UN3108
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Section 14. Transport information
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide). Marine
pollutant
(Dibenzoyl
peroxide, Zinc
Stearate)
5.2

– The marine
pollutant mark is
not required when
transported in
sizes of 5 L or 5
kg.
Emergency
schedules F-J, S-
R
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. Yes.
Not available.
:
Proper shipping name :
Not available.
:
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.23-2.25 (Class
5).
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

No.

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
ORGANIC
PEROXIDE
TYPE E, SOLID
(Dibenzoyl
peroxide)
5.2

Yes. The
environmentally
hazardous
substance mark
is not required.
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
145
ERG No.
145 145
ERG No. ERG No.
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Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
WARNING: This product contains a chemical known to the State of California to cause cancer.
California Prop. 65
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Zinc Compound 6
Dibenzoyl peroxide 50 94-36-0
Ingredient name CAS number% by weight
SARA 313
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
0
4
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Procedure used to derive the classification
Date of issue/Date of revision :1/15/2025Date of previous issue :12/13/2024 Version:13.03 13/14
27120 CREAM HARDENER
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Section 16. Other information
1/15/2025
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/15/2025
12/13/2024
13.03
ORGANIC PEROXIDES – Type E Expert judgment
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2 Calculation method
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :1/15/2025Date of previous issue :12/13/2024 Version:13.03 14/14
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37BO103C_SDS.pdf

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Safety Data Sheet
Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2)neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 24-8015-0 Version Number: 5.00
Issue Date: 01/23/14 Supercedes Date: 10/01/12
SECTION 1: Identification
1.1. Product identifier
3M Dyanatron White Cream Hardener 308, 30759
Product Identification Numbers
70-0080-0378-5, 70-0080-0379-3
1.2. Recommended use and restrictions on use
Recommended use
Automotive, Hardener for body fillers
1.3. Supplier s details
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements belowwere prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Organic Peroxide: Type E.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1.
2.2. Label elements
Signal word
Warning
Symbols
Flame | Exclamation mark |

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Pictograms
Hazard Statements
Heating may cause a fire.
Causes serious eye irritation.
Maycause an allergic skin reaction.
Precautionary Statements
General:
Keep out of reach of children.
If medical advice is needed, have product container or label at hand.
Prevention:
Keep awayfrom heat/sparks/open flames/hot surfaces. -No smoking.
Keep awayfrom clothing and other combustible materials.
Keep only in original container.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Storage:
Protect from sunlight.
Store at temperatures not exceeding 32C/90F. Keep cool.
Store awayfrom other materials.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician:
Not applicable
2.3. Hazards not otherwise classified
None.
4% of the mixture consists of ingredients of unknown acute dermal toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Benzoyl Peroxide 94-36-0 30 -60 Trade Secret *

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Benzoic Acid, C9-11-Branched Alkyl Esters 131298-44-7 10 -30 Trade Secret *
Water 7732-18-5 10 -30 Trade Secret *
Calcium Sulfate 7778-18-9 3 -7 Trade Secret *
Zinc Stearate 557-05-1 3 -7 Trade Secret *
Oxirane, Polymer with Methyloxirane, Monobutyl Ether9038-95-3 1 -5 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Eye Contact:
Immediatelyflush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising fromthe substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
5.3. Special protective actions for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. -No
smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information
regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

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6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for
transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized
person. Ventilate the area with fresh air. Read and followsafety precautions on the solvent label and SDS. Clean up residue.
Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. -No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage including anyincompatibilities
Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Keep only in original container. Store
away from other materials. Keep/store awayfrom clothing and other combustible materials.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
Ingredient C.A.S. No.Agency Limit type Additional Comments
STEARATES 557-05-1Amer Conf of
Gov. Indust.
Hyg.
TWA:10 mg/m3
Zinc Stearate 557-05-1US Dept of
Labor -OSHA
TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Calcium Sulfate 7778-18-9Amer Conf of
Gov. Indust.
Hyg.
TWA(inhalable fraction):10
mg/m3
Calcium Sulfate 7778-18-9US Dept of
Labor -OSHA
TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Benzoyl Peroxide 94-36-0 Amer Conf of
Gov. Indust.
Hyg.
TWA:5 mg/m3
Benzoyl Peroxide 94-36-0 US Dept of
Labor -OSHA
TWA:5 mg/m3
Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists
American Indust. Hygiene Assoc : American Industrial Hygiene Association
Chemical Manufacturer Rec Guid : Chemical Manufacturer’s Recommended Guidelines
US Dept of Labor -OSHA : United States Department of Labor -Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to belowrelevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

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8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Nitrile Rubber
Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective
clothing material(s) are recommended: If this product is used in a manner that presents a higher potential for exposure (eg.
spraying, high splash potential etc.), then use of protective coveralls may be necessary. Apron Nitrile
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Viscous
Odor, Color, Grade: White paste with slight ester odor
Odor threshold No Data Available
pH No Data Available
Melting point No Data Available
Boiling Point [Details: Decomposes]
Flash Point 111 C [Test Method: Estimated]
Evaporation rate Not Applicable
Flammability (solid, gas) Organic Peroxide: Type E.
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Specific Gravity 1.2 [@ 25 C] [Ref Std: WATER=1]
Solubility in Water Negligible
Solubility-non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity No Data Available
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]

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Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2]
Percent volatile 20 % [Details: Water is the volatile component]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions -see the remaining headings in this section.
10.2. Chemical stability
Stable. Stable unless exposed to heat, flames and drying conditions.

10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Not determined
10.5. Incompatible materials
Accelerators
10.6. Hazardous decomposition products
Substance Condition
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Toxic Vapor, Gas, Particulate Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material clas sification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing,
nasal discharge, headache, hoarseness, and nose and throat pain.
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may
include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin Contact:
Maybe harmful in contact with skin.
Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo

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induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route SpeciesValue
Overall product Dermal No data available; calculated ATE 4,464.3 mg/kg
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Benzoyl Peroxide Dermal LD50 estimated to be 2,000 -5,000 mg/kg
Benzoyl Peroxide Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 24.3 mg/l
Benzoyl Peroxide IngestionRat LD50 > 5,000 mg/kg
Benzoic Acid, C9-11-Branched Alkyl Esters Dermal Rabbit LD50 > 2,000 mg/kg
Benzoic Acid, C9-11-Branched Alkyl Esters Inhalation-
Dust/Mist
(4 hours)
Rat LC50 2 mg/l
Benzoic Acid, C9-11-Branched Alkyl Esters IngestionRat LD50 > 5,000 mg/kg
Zinc Stearate Dermal Rabbit LD50 > 2,000 mg/kg
Zinc Stearate IngestionRat LD50 > 5,000 mg/kg
Oxirane, Polymer with Methyloxirane, Monobutyl EtherDermal Rabbit LD50 > 16,960 mg/kg
Calcium Sulfate IngestionRat LD50 > 5,000 mg/kg
Oxirane, Polymer with Methyloxirane, Monobutyl EtherInhalation-
Dust/Mist
(4 hours)
Rat LC50 > 5 mg/l
Oxirane, Polymer with Methyloxirane, Monobutyl EtherIngestionRat LD50 4,240 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name SpeciesValue
Benzoyl Peroxide Rabbit Minimal irritation
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit Minimal irritation
Serious Eye Damage/Irritation
Name SpeciesValue
Benzoyl Peroxide Rabbit Severe irritant
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit No significant irritation
Skin Sensitization
Name SpeciesValue
Benzoyl Peroxide Human
and
animal
Sensitizing
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification

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Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Data not available or insufficient for classification
Respiratory Sensitization
Name SpeciesValue
Benzoyl Peroxide Data not available or insufficient for classification
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Data not available or insufficient for classification
Germ Cell Mutagenicity
Name Route Value
Benzoyl Peroxide In VitroNot mutagenic
Benzoyl Peroxide In vivo Not mutagenic
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Data not available or insufficient for classification
Carcinogenicity
Name Route SpeciesValue
Benzoyl Peroxide IngestionMultiple
animal
species
Not carcinogenic
Benzoyl Peroxide Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Benzoic Acid, C9-11-Branched Alkyl Esters Data not available or insufficient for classification
Zinc Stearate Data not available or insufficient for classification
Calcium Sulfate Data not available or insufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl Ether IngestionRat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value SpeciesTest Result Exposure
Duration
Benzoyl Peroxide IngestionNot toxic to female reproductionRat NOAEL
1,000
mg/kg/day
premating &
during
gestation
Benzoyl Peroxide IngestionSome positive male reproductive data
exist, but the data are not sufficient for
classification
Rat NOAEL 500
mg/kg/day
premating &
during
gestation
Benzoyl Peroxide IngestionSome positive developmental data exist,
but the data are not sufficient for
classification
Rat NOAEL 500
mg/kg/day
premating &
during
gestation
Benzoic Acid, C9-11-Branched Alkyl
Esters
Data not available or insufficient for
classification
Zinc Stearate Data not available or insufficient for
classification
Calcium Sulfate Data not available or insufficient for
classification
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
IngestionNot toxic to female reproductionRat NOAEL
3,770
mg/kg/day
90 days
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
IngestionNot toxic to male reproduction Rat NOAEL
3,770
mg/kg/day
90 days
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
InhalationSome positive male reproductive data
exist, but the data are not sufficient for
classification
Rat NOAEL 1
mg/l
2 weeks
Target Organ(s)

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Specific Target Organ Toxicity -single exposure
Name Route Target Organ(s)Value SpeciesTest Result Exposure
Duration
Benzoyl Peroxide Data not available or insufficient
for classification
Benzoic Acid, C9-11-
Branched Alkyl Esters
Data not available or insufficient
for classification
Zinc Stearate Data not available or insufficient
for classification
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionnervous system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL Not
available
Calcium Sulfate Data not available or insufficient
for classification
Specific Target Organ Toxicity -repeated exposure
Name Route Target Organ(s) Value SpeciesTest Result Exposure
Duration
Benzoyl Peroxide Data not available or insufficient
for classification
Benzoic Acid, C9-11-
Branched Alkyl Esters
Data not available or insufficient
for classification
Zinc Stearate Data not available or insufficient
for classification
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationendocrine system |
hematopoietic
system | liver |
nervous system
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 1
mg/l
2 weeks
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationkidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL .005
mg/l
2 weeks
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Rat LOAEL .001
mg/l
2 weeks
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationheart All data are negative Rat NOAEL .5
mg/l
2 weeks
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionliver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 145
mg/kg/day
90 days
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionhematopoietic
system
All data are negative Rat NOAEL 500
mg/kg/day
2 years
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionheart | endocrine
system | respiratory
system
All data are negative Rat NOAEL
3,770
mg/kg/day
90 days
Calcium Sulfate Data not available or insufficient
for classification
Aspiration Hazard
Name Value
Benzoyl Peroxide Not an aspiration hazard
Benzoic Acid, C9-11-Branched Alkyl Esters Not an aspiration hazard
Zinc Stearate Not an aspiration hazard
Calcium Sulfate Not an aspiration hazard
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information

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Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional
fuel during incineration processes. As a disposal alternative, Dispose of waste product in a permitted industrial waste
facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment anddisposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfoor call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -Yes Immediate Hazard -Yes Delayed Hazard -Yes
Section 313 Toxic Chemicals subject to the reporting requirements of thatsection and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Zinc Stearate (ZINC COMPOUNDS) 557-05-1 3 -7
Benzoyl Peroxide 94-36-0 30 -60
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Haza rd Communication Standard, 29 CFR 1910.1200.

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SECTION 16: Other information
NFPA Hazard Classification
Health:2 Flammability:2 Instability:1 Special Hazards:Oxidizer

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 24-8015-0 Version Number: 5.00
Issue Date: 01/23/14 Supercedes Date: 10/01/12
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product isfit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3MUSA SDSs are available at www.3M.com

37BO103B_SDS.pdf

CREAM HARDENER
BLUE
Not available.
Liquid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
27112
27112Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
ORGANIC PEROXIDES – Type E
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1%
(oral), 57% (dermal), 57% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Heating may cause a fire.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep
away from clothing and other combustible materials. Keep only in original packaging.
Do not breathe vapor. Wash thoroughly after handling. Contaminated work clothing
must not be allowed out of the workplace.
Response :Get medical advice or attention if you feel unwell. Take off contaminated clothing and
wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash
with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage :Protect from sunlight. Store at temperatures not exceeding 25 C/77 F. Keep cool.
Store separately.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
FOR PROFESSIONAL USE ONLY. This product must be mixed with other components
before use. Before opening the packages, READ AND FOLLOW WARNING LABELS
ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Dibenzoyl peroxide 50 – 75 94-36-0
Zinc Stearate 10 557-05-1
Calcium Sulfate 5 7778-18-9
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica 3 68909-20-6
Iron Blue 3 14038-43-8
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
be delayed. The exposed person may need to be kept under medical surveillance for
48 hours.
Skin contact
Ingestion :
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Runoff to sewer may create fire or explosion hazard. This material increases the risk of
fire and may aid combustion. Heating may cause a fire. May re-ignite itself after fire is
extinguished. Hazardous decomposition may occur. In a fire or if heated, a pressure
increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Avoid contamination with reactive
substances. Do not absorb in sawdust or other combustible material. It may lead to a
fire risk when it dries out. Wash spillages into an effluent treatment plant or proceed as
follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal according
to local regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the spilled
product. Note: see Section 1 for emergency contact information and Section 13 for
waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Avoid contamination with reactive substances. Dilute with
water and mop up if water-soluble. Do not absorb in sawdust or other combustible
material. It may lead to a fire risk when it dries out. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container.
Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
To avoid the risk of formation of shock-sensitive crystals or loss of stability, it is
important to store the product within the recommended temperature range.
Temperature control may be required. Store in accordance with local regulations. Store
in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section 10) and food and drink. Store at temperatures not exceeding 25 C/77 F.
Eliminate all ignition sources. Separate from reducing agents and combustible
materials. Keep away from rust, iron and copper. Keep container tightly closed and
sealed until ready for use. Prevent product contamination. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. Use only with adequate ventilation. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Store and use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Keep away from clothing, incompatible materials and
combustible materials. Temperature control may be required. Empty containers retain
product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Dibenzoyl peroxide 94-36-0 ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours.
Zinc Stearate 557-05-1 ACGIH TLV (United States, 1/2024).
[Stearates]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
TWA: 3 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Section 8. Exposure controls/personal protection
Calcium Sulfate 7778-18-9 ACGIH TLV (United States, 1/2024).
[Calcium sulfate]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-,
hydrolysis products with silica
68909-20-6 None.
Iron Blue 14038-43-8 ACGIH TLV (United States, 1/2024). [Iron
salts, soluble]
TWA: 1 mg/m , (as Fe) 8 hours.
NIOSH REL (United States, 10/2020). [iron
salts]
TWA: 1 mg/m , (as Fe) 10 hours.
OSHA PEL (United States, 5/2018).
[Cyanides] Absorbed through skin.
TWA: 5 mg/m , (as CN) 8 hours.
Dibenzoyl peroxide 94-36-0 CA Alberta Provincial (Canada, 3/2023).
OEL: 5 mg/m 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 5 mg/m 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 5 mg/m 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 5 mg/m 8 hours.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 10 mg/m 15 minutes.
TWA: 5 mg/m 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Dibenzoyl peroxide 94-36-0 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 5 mg/m 8 hours.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
No exposure indices known.
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
No exposure indices known.
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use process enclosures, local exhaust ventilation or other engineering controls to keep
worker exposure to airborne contaminants below any recommended or statutory limits.
The engineering controls also need to keep gas, vapor or dust concentrations below any
lower explosive limits. Use explosion-proof ventilation equipment. Use with adequate
ventilation.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Liquid.
Not available.
Not available.Odor
pH
Blue.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: 94 C (201.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
:100 C (212 F)Boiling point, initial boiling
point, and boiling range
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density 1.19
1 [Air = 1]
Auto-ignition temperature Not available.
Not applicable.
Viscosity Kinematic (40 C (104 F)): >20.5 mm
2
/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:Not available.
:Not available.
SADT 50 C (122 F):
Decomposition temperature:Not available.
Heat of combustion :21.85 kJ/g
Molecular weight :Not applicable.
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
2.3 kPa (17.5 mm Hg)
Solubility(ies) :
Media Result
cold water Partially soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid
increased storage temperature. Drying on clothing or other combustible materials may
cause fire.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
combustible materials
reducing materials
copper
iron
rust
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Conditions may include the following:
temperature increase
high temperature
Reactions may include the following:
hazardous decomposition
risk of causing fire
Reactivity :This product, in laboratory testing, neither detonates nor deflagrates and only shows low
or no effect when heated under confinement.
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Section 11. Toxicological information
Acute toxicity
Dibenzoyl peroxide LD50 Oral Rat 6400 mg/kg –
Zinc Stearate LD50 Oral Rat >10 g/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Dibenzoyl peroxide Eyes – Mild irritant Rabbit – 24 hours 500
mg

Skin – Moderate irritantWoman – 1 % –
Skin – Severe irritantHuman – 1344 hours 5
% I

Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis
products with silica
Category 2 inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Dibenzoyl peroxide – 3 –
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
Dibenzoyl peroxide EC10 0.001 mg/l Daphnia 21 days
EC50 0.0711 mg/l Algae 72 hours
Acute EC50 0.11 mg/l Daphnia 48 hours
Calcium Sulfate Acute LC50 >1910 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia
48 hours
Acute LC50 >1970 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 2980 ppm Fresh water Fish – Lepomis macrochirus 96 hours
Chronic NOEC 360 mg/l Fresh water Daphnia – Daphnia magna –
Neonate
3 weeks
Product/ingredient name SpeciesResult Exposure
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Dibenzoyl peroxide – – Inherent
Chronic NOEC 233 mg/l Fresh water Fish – Coregonus albula – Egg 60 days
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Do not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
:Disposal methods
Section 14. Transport information
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide). Marine
pollutant
(Dibenzoyl
peroxide, Zinc
Stearate)
5.2

UN3108 UN3108
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
TDG
Classification
UN3108
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

Mexico
Classification
UN3108
ORGANIC
PEROXIDE TYPE
E, SOLID
(Dibenzoyl
peroxide)
5.2

IATA
UN3108
ORGANIC
PEROXIDE
TYPE E, SOLID
(Dibenzoyl
peroxide)
5.2

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Section 14. Transport information
– The marine
pollutant mark is
not required when
transported in
sizes of 5 L or 5
kg.
Emergency
schedules F-J, S-
R
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to IMO instruments
No. Yes.
Not available.
:
Proper shipping name :
Not available.
:
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.23-2.25 (Class
5).
No.

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
Yes. The
environmentally
hazardous
substance mark
is not required.
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
145
ERG No.
145 145
ERG No. ERG No.
Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
Not applicable.
California Prop. 65
International regulations
Montreal Protocol
Not listed.
Zinc Compound 6
Dibenzoyl peroxide 50 94-36-0
Ingredient name CAS number% by weight
SARA 313
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Section 15. Regulatory information
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International lists :
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Section 16. Other information
1/15/2025
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Key to abbreviations :
1/15/2025
12/14/2024
13.01
Hazardous Material Information System (U.S.A.)
2
0
4
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
ORGANIC PEROXIDES – Type E Expert judgment
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Notice to reader
SGG = Segregation Group
UN = United Nations
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Not available.
Solid.
(888) 345-5732
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :U.S. CHEMICAL & PLASTICS
600 Nova Dr. S.E.
Massillon, OH 44646
USA
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
27114
27114Product code :
Product Information
Telephone Number
:(330) 830-6000
Transportation Emergency
Telephone Number
:(800) 424-9300
Section 2. Hazards identification
ORGANIC PEROXIDES – Type E
SKIN CORROSION/IRRITATION – Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 1%
(oral), 57% (dermal), 57% (inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Heating may cause a fire.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep
away from clothing and other combustible materials. Keep only in original packaging.
Do not breathe dust. Wash thoroughly after handling. Contaminated work clothing
must not be allowed out of the workplace.
Response :Get medical advice or attention if you feel unwell. Take off contaminated clothing and
wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash
with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or
attention.
Storage :Protect from sunlight. Store at temperatures not exceeding 25 C/77 F. Keep cool.
Store separately.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
FOR PROFESSIONAL USE ONLY. This product must be mixed with other components
before use. Before opening the packages, READ AND FOLLOW WARNING LABELS
ON ALL COMPONENTS.
:
Section 3. Composition/information on ingredients
Dibenzoyl peroxide 50 – 75 94-36-0
Zinc Stearate 10 557-05-1
Calcium Sulfate 5 7778-18-9
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica 3 68909-20-6
Ingredient name CAS number% by weight
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband. In case of inhalation of decomposition products in a fire, symptoms may
be delayed. The exposed person may need to be kept under medical surveillance for
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
48 hours.
Skin contact
Ingestion :
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Runoff to sewer may create fire or explosion hazard. This material increases the risk of
fire and may aid combustion. Heating may cause a fire. May re-ignite itself after fire is
extinguished. Hazardous decomposition may occur.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid contamination with reactive substances. Avoid dust
generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. Dispose of via a licensed waste
disposal contractor. Note: see Section 1 for emergency contact information and Section
13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid contamination with reactive substances. Avoid dust generation. Do not dry
sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Place spilled material in a designated, labeled waste container.
Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Section 7. Handling and storage
Precautions for safe handling
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
To avoid the risk of formation of shock-sensitive crystals or loss of stability, it is
important to store the product within the recommended temperature range.
Temperature control may be required. Store in accordance with local regulations. Store
in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section 10) and food and drink. Store at temperatures not exceeding 25 C/77 F.
Eliminate all ignition sources. Separate from reducing agents and combustible
materials. Keep away from rust, iron and copper. Keep container tightly closed and
sealed until ready for use. Prevent product contamination. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Use only
with adequate ventilation. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Keep away from clothing, incompatible materials and combustible materials.
Temperature control may be required. Empty containers retain product residue and can
be hazardous. Do not reuse container.
:
Dibenzoyl peroxide 94-36-0 ACGIH TLV (United States, 1/2024).
TWA: 5 mg/m 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours.
Zinc Stearate 557-05-1 ACGIH TLV (United States, 1/2024).
[Stearates]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
TWA: 3 mg/m 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Calcium Sulfate 7778-18-9 ACGIH TLV (United States, 1/2024).
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Section 8. Exposure controls/personal protection
[Calcium sulfate]
TWA: 10 mg/m 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2020).
TWA: 5 mg/m 10 hours. Form: Respirable
fraction
TWA: 10 mg/m 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m 8 hours. Form: Respirable
fraction
TWA: 15 mg/m 8 hours. Form: Total dust
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-,
hydrolysis products with silica
68909-20-6 None.
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment. Use with adequate ventilation.
Individual protection measures
Dibenzoyl peroxide 94-36-0 CA Alberta Provincial (Canada, 3/2023).
OEL: 5 mg/m 8 hours.
CA British Columbia Provincial (Canada,
8/2023).
TWA: 5 mg/m 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 5 mg/m 8 hours.
CA Quebec Provincial (Canada, 2/2024).
TWAEV: 5 mg/m 8 hours.
CA Saskatchewan Provincial (Canada,
4/2021).
STEL: 10 mg/m 15 minutes.
TWA: 5 mg/m 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
Dibenzoyl peroxide 94-36-0 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 5 mg/m 8 hours.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
Biological exposure indices (United States)
No exposure indices known.
Biological exposure indices (Canada)
Biological exposure indices (Mexico)
No exposure indices known.
No exposure indices known.
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Solid.
Not available.
1.19
1 [Air = 1]
Not available.Odor
pH
White.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: 94 C (201.2 F) [Pensky-Martens Closed Cup]
Not applicable.
Not available.Odor threshold
:
:
:
:
:
:
:
:
:
:
:
Appearance
:100 C (212 F)
:Not available.
:Not applicable.
Boiling point, initial boiling
point, and boiling range
Flammability
Lower and upper explosion
limit/flammability limit
Relative vapor density
The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
2.3 kPa (17.5 mm Hg)
Solubility(ies) :
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Section 9. Physical and chemical properties
Auto-ignition temperature Not applicable.
Not applicable.
Viscosity Kinematic (40 C (104 F)): >20.5 mm
2
/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
SADT 50 C (122 F):
Decomposition temperature:Not available.
Heat of combustion :21.85 kJ/g
Molecular weight :Not applicable.
Media Result
cold water Partially soluble
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid increased storage
temperature.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
combustible materials
reducing materials
copper
iron
rust
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Conditions may include the following:
temperature increase
high temperature
Reactions may include the following:
hazardous decomposition
risk of causing fire
Reactivity :This product, in laboratory testing, neither detonates nor deflagrates and only shows low
or no effect when heated under confinement.
Section 11. Toxicological information
Acute toxicity
Dibenzoyl peroxide LD50 Oral Rat 6400 mg/kg –
Zinc Stearate LD50 Oral Rat >10 g/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Dibenzoyl peroxide Eyes – Mild irritant Rabbit – 24 hours 500
mg

Skin – Moderate irritantWoman – 1 % –
Skin – Severe irritantHuman – 1344 hours 5
% I

Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis
products with silica
Category 2 inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Classification
Dibenzoyl peroxide – 3 –
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation No specific data.:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Skin contact
Ingestion No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
Dibenzoyl peroxide EC10 0.001 mg/l Daphnia 21 days
EC50 0.0711 mg/l Algae 72 hours
Acute EC50 0.11 mg/l Daphnia 48 hours
Calcium Sulfate Acute LC50 >1910 mg/l Fresh water Crustaceans – Ceriodaphnia
dubia
48 hours
Acute LC50 >1970 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 2980 ppm Fresh water Fish – Lepomis macrochirus 96 hours
Chronic NOEC 360 mg/l Fresh water Daphnia – Daphnia magna –
Neonate
3 weeks
Chronic NOEC 233 mg/l Fresh water Fish – Coregonus albula – Egg 60 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
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Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Dibenzoyl peroxide – – Inherent
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Do not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.
:Disposal methods
Section 14. Transport information
ORGANIC
PEROXIDE TYPE
E, SOLID
5.2

ORGANIC
PEROXIDE TYPE
E, SOLID. Marine
pollutant
(Dibenzoyl
peroxide, Zinc
Stearate)
5.2

UN3108 UN3108
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Environmental
hazards
No. Yes.
TDG
Classification
UN3108
ORGANIC
PEROXIDE TYPE
E, SOLID
5.2

No.
Mexico
Classification
UN3108
ORGANIC
PEROXIDE TYPE
E, SOLID
5.2

No.
IATA
UN3108
ORGANIC
PEROXIDE
TYPE E, SOLID
5.2

Yes. The
environmentally
hazardous
substance mark
is not required.
Date of issue/Date of revision :1/15/2025Date of previous issue :12/14/2024 Version:12.02 11/14
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Section 14. Transport information
– The marine
pollutant mark is
not required when
transported in
sizes of 5 L or 5
kg.
Emergency
schedules F-J, S-
R
Additional
information
Special precautions for user
Transport in bulk according
to IMO instruments
Not available.
:
Proper shipping name :
Not available.
:
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations:
2.23-2.25 (Class
5).

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
The
environmentally
hazardous
substance mark
may appear if
required by other
transportation
regulations.
145
ERG No.
145 145
ERG No. ERG No.
Section 15. Regulatory information
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED
and rely on information provided to us by our raw material suppliers. Our suppliers often provide an estimated value or
range less than a certain upper limit. We calculate MAXIMUM THEORETICAL VALUES using defined values, if provided,
or the upper limit reported by our supplier. Additionally, the suppliers information may include amounts present in the
product as unintentional byproducts or impurities. Variations may occur in individual batches due to adjustments made
during production. Reporting of chemicals in this section does not necessarily indicate their presence in the final
formulated product.
Not applicable.
California Prop. 65
International regulations
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Zinc Compound 6
Dibenzoyl peroxide 50 94-36-0
Ingredient name CAS number% by weight
SARA 313
Date of issue/Date of revision :1/15/2025Date of previous issue :12/14/2024 Version:12.02 12/14
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Section 15. Regulatory information
Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International lists :
Section 16. Other information
1/15/2025
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
1/15/2025
12/14/2024
12.02
Hazardous Material Information System (U.S.A.)
2
0
4
*
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
ORGANIC PEROXIDES – Type E Expert judgment
SKIN CORROSION/IRRITATION – Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2A Calculation method
SKIN SENSITIZATION – Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) – Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. (“Marpol” = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Notice to reader
Date of issue/Date of revision :1/15/2025Date of previous issue :12/14/2024 Version:12.02 14/14
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37AXERTWB_SDS.pdf

Page 1/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 11/17/2015 Reviewed on 11/17/2015
41.2.20
1 Identification
Product identifier
Trade name: RTWB-50NC
Application of the substance / the mixtureRelease agent
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Axel Plastics Research Laboratories, Inc.
PO Box 770855, 58-20 Broadway
Woodside, NY 11377-0855 USA
info@axelplastics.com
Information department:Product safety department
Emergency telephone number:
USA and Canada: 1-800-424-9300 (24 hours)
Outside of USA and Canada: 001-703-527-3887 (24 hours)
2 Hazard(s) identification
Classification of the substance or mixture
d~
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
d~
GHS08 Health hazard
Muta. 1B H340 May cause genetic defects.
Carc. 1B H350 May cause cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
d~
GHS07
Acute Tox. 4 H312 Harmful in contact with skin.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Label elements
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
d~
GHS02
d~
GHS07
d~
GHS08
Signal wordDanger
Hazard-determining components of labeling:
Proprietary/Alternative Chemical Name Pending
xylene
(Contd. on page 2)
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Trade name: RTWB-50NC
(Contd. of page 1)
41.2.20
toluene
Solvent naphtha (petroleum), light arom.
Hazard statements
Highly flammable liquid and vapor.
Harmful in contact with skin or if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause genetic defects.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
Wear protective gloves / protective clothing.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
IF exposed or concerned: Get medical advice/attention.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Do NOT induce vomiting.
In case of fire: Use for extinction: CO2, powder or water spray.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
3
0
Health = 2
Fire = 3
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
3
0
Health = *2
Fire = 3
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 3)
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Trade name: RTWB-50NC
(Contd. of page 2)
41.2.20
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
1330-20-7 xylene 10-<25% 108-88-3 toluene 10-<25% 64742-89-8 Solvent naphtha (petroleum), light aliph. 10-<25% Proprietary/Alternative Chemical Name Pending 10-<25 % 64742-95-6 Solvent naphtha (petroleum), light arom. 2.5-<10% 67-64-1 acetone 2.5-<10% 95-63-6 1,2,4-trimethylbenzene 2.5-<10% 98-82-8 cumene 0.1- 2.5% 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents:Water with full jet Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment:Mouth respiratory protective device. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 11/17/2015 Reviewed on 11/17/2015 Trade name: RTWB-50NC (Contd. of page 3) 41.2.20 Ensure adequate ventilation Environmental precautions:Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling Store in cool, dry place in tightly closed receptacles. Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:Store in a cool location. Information about storage in one common storage facility:Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Specific end use(s)No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: 1330-20-7 xylene PEL Long-term value: 435 mg/m , 100 ppm REL Short-term value: 655 mg/m , 150 ppm Long-term value: 435 mg/m , 100 ppm TLV Short-term value: 651 mg/m , 150 ppm Long-term value: 434 mg/m , 100 ppm BEI 108-88-3 toluene PEL Long-term value: 200 ppm Ceiling limit value: 300; 500* ppm *10-min peak per 8-hr shift REL Short-term value: 560 mg/m , 150 ppm Long-term value: 375 mg/m , 100 ppm TLV Long-term value: 75 mg/m , 20 ppm BEI (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 11/17/2015 Reviewed on 11/17/2015 Trade name: RTWB-50NC (Contd. of page 4) 41.2.20 67-64-1 acetone PEL Long-term value: 2400 mg/m , 1000 ppm REL Long-term value: 590 mg/m , 250 ppm TLV Short-term value: 1187 mg/m , 500 ppm Long-term value: 594 mg/m , 250 ppm BEI 95-63-6 1,2,4-trimethylbenzene REL Long-term value: 125 mg/m , 25 ppm TLV Long-term value: 123 mg/m , 25 ppm Ingredients with biological limit values: 1330-20-7 xylene BEI 1.5 g/g creatinine Medium: urine Time: end of shift Parameter: Methylhippuric acids 108-88-3 toluene BEI 0.02 mg/L Medium: blood Time: prior to last shift of workweek Parameter: Toluene 0.03 mg/L Medium: urine Time: end of shift Parameter: Toluene 0.3 mg/g creatinine Medium: urine Time: end of shift Parameter: o-Cresol with hydrolysis (background) 67-64-1 acetone BEI 50 mg/L Medium: urine Time: end of shift Parameter: Acetone (nonspecific) Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: _S Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 11/17/2015 Reviewed on 11/17/2015 Trade name: RTWB-50NC (Contd. of page 5) 41.2.20 Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: _R Tightly sealed goggles Body protection:Protective work clothing 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Color: Amber colored Odor: Aliphatic Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:38 - 60 C Flash point: < 23 C (< 73 F) Flammability (solid, gaseous):Not applicable. Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure at 20 C (68 F):29 hPa (22 mm Hg) Density: Not determined. Relative density 0.790 Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. (Contd. on page 7) US Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 11/17/2015 Reviewed on 11/17/2015 Trade name: RTWB-50NC (Contd. of page 6) 41.2.20 Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solids content: 8.0 % Other information No further relevant information available. 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stabilityThe product is stable under recommended storage conditions. Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: 1330-20-7 xylene Oral LD50 4300 mg/kg (rat) Dermal LD50 2000 mg/kg (rabbit) 108-88-3 toluene Oral LD50 5000 mg/kg (rat) Dermal LD50 12124 mg/kg (rabbit) Inhalative LC50/4 h 5320 mg/l (mouse) 64742-89-8 Solvent naphtha (petroleum), light aliph. Oral LD50 >200 mg/kg (Rat)
Dermal LD50 >200 mg/kg (Rat)
Inhalative LC50/4 h >7700 ppm (Rat)
Proprietary/Alternative Chemical Name Pending
Oral LD50 5000 mg/kg (Rat)
Dermal LD50 2000 mg/kg (rabbit)
Inhalative LC50 5.2 mg/l (Rat)
64742-95-6 Solvent naphtha (petroleum), light arom.
Oral LD50 >6800 mg/kg (rat)
Dermal LD50 >3400 mg/kg (rab)
Inhalative LC50/4 h >10.2 mg/l (rat)
95-63-6 1,2,4-trimethylbenzene
Oral LD50 5000 mg/kg (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
(Contd. on page 8)
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Trade name: RTWB-50NC
(Contd. of page 7)
41.2.20
Harmful
Irritant
The product can cause inheritable damage.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1330-20-7 xylene 3
108-88-3 toluene 3
98-82-8 cumene 2B
NTP (National Toxicology Program)
98-82-8 cumene R
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, IMDG, IATA UN1866
UN proper shipping name
DOT, IATA Resin solution
IMDG RESIN SOLUTION
Transport hazard class(es)
DOT, IMDG, IATA
Class 3 Flammable liquids
(Contd. on page 9)
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Trade name: RTWB-50NC
(Contd. of page 8)
41.2.20
Packing group
IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
EMS Number: F-E,S-E
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: UN 1866 RESIN SOLUTION, 3, II
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
1330-20-7 xylene
108-88-3 toluene
95-63-6 1,2,4-trimethylbenzene
98-82-8 cumene
TSCA (Toxic Substances Control Act) (Substances not listed):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
108-88-3 toluene
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
108-88-3 toluene
New Jersey Right-to-Know List:
1330-20-7 xylene
108-88-3 toluene
67-64-1 acetone
95-63-6 1,2,4-trimethylbenzene
98-82-8 cumene
New Jersey Special Hazardous Substance List:
1330-20-7 xylene F3
108-88-3 toluene TE, F3
67-64-1 acetone F3
98-82-8 cumene F3, R1
Pennsylvania Right-to-Know List:
1330-20-7 xylene
108-88-3 toluene
(Contd. on page 10)
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(Contd. of page 9)
41.2.20
67-64-1 acetone
95-63-6 1,2,4-trimethylbenzene
98-82-8 cumene
Pennsylvania Special Hazardous Substance List:
1330-20-7 xylene E
108-88-3 toluene E
67-64-1 acetone E
95-63-6 1,2,4-trimethylbenzene E
98-82-8 cumene E
US State Regulations
Connecticut – Hazardous Air Pollutants – HLVs (30 min)
None of the ingredients is listed.
Connecticut – Hazardous Air Pollutants – HLVs (8 hr)
None of the ingredients is listed.
Idaho – Non-Carcinogenic Toxic Air Pollutants – Emission Levels (ELs)
None of the ingredients is listed.
Idaho – Non-Carcinogenic Toxic Air Pollutants – Acceptable Ambient Concentrations
None of the ingredients is listed.
Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Michigan – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
Michigan – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Minnesota – Hazardous Substance List
None of the ingredients is listed.
Minnesota – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Minnesota – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
New Hampshire – Regulated Toxic Air Pollutants – Ambient Air Levels (AALs) – 24-Hour
None of the ingredients is listed.
New Hampshire – Regulated Toxic Air Pollutants – Ambient Air Levels (AALs) – Annual
None of the ingredients is listed.
New York – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
New York – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
North Dakota – Air Pollutants – Guideline Concentrations – 1-Hour
None of the ingredients is listed.
North Dakota – Air Pollutants – Guideline Concentrations – 8-Hour
None of the ingredients is listed.
Oregon – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
Tennessee – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
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(Contd. of page 10)
41.2.20
Tennessee – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Texas – Effects Screening Levels – Long Term
None of the ingredients is listed.
Texas – Effects Screening Levels – Short Term
None of the ingredients is listed.
Vermont – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Vermont – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
Washington – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Washington – Permissible Exposure Limits – STELs
None of the ingredients is listed.
Washington – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 25 Feet to Less
Than 40 Feet
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 40 Feet to Less
Than 75 Feet
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 75 Feet or
Greater
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights Less Than 25
Feet
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
1330-20-7 xylene I
108-88-3 toluene II
67-64-1 acetone I
98-82-8 cumene D, CBD
TLV (Threshold Limit Value established by ACGIH)
1330-20-7 xylene A4
108-88-3 toluene A4
67-64-1 acetone A4
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
d~
GHS02
d~
GHS07
d~
GHS08
(Contd. on page 12)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 11/17/2015 Reviewed on 11/17/2015
Trade name: RTWB-50NC
(Contd. of page 11)
41.2.20
Signal wordDanger
Hazard-determining components of labeling:
Proprietary/Alternative Chemical Name Pending
xylene
toluene
Solvent naphtha (petroleum), light arom.
Hazard statements
Highly flammable liquid and vapor.
Harmful in contact with skin or if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause genetic defects.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
Wear protective gloves / protective clothing.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
IF exposed or concerned: Get medical advice/attention.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Do NOT induce vomiting.
In case of fire: Use for extinction: CO2, powder or water spray.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:The components of this product are listed on the USA (TSCA) inventory.
Additional classification according to Decree on Hazardous Materials:
Carcinogenic hazardous material group III (dangerous).
Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
US
(Contd. on page 13)

Page 13/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 11/17/2015 Reviewed on 11/17/2015
Trade name: RTWB-50NC
(Contd. of page 12)
41.2.20
16 Other information
Disclaimer: This data is offered in good faith as typical values and not as a product specification. No
warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe
handling procedures are believed to be generally applicable. However, each user should review
recommendations in the specific context of the intended use and determine whether they are appropriate.
Contact:info@axelplastics.com
Date of preparation / last revision11/17/2015 / –
Abbreviations and acronyms:
ADR: Accord europ en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
Muta. 1B: Germ cell mutagenicity, Hazard Category 1B
Carc. 1B: Carcinogenicity, Hazard Category 1B
Repr. 2: Reproductive toxicity, Hazard Category 2
STOT SE 3: Specific target organ toxicity – Single exposure, Hazard Category 3
STOT RE 2: Specific target organ toxicity – Repeated exposure, Hazard Category 2
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
US