39OMS-F_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
SDS Distribution: The information in this document
should be made available to all who may handle the
product.
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to
become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the Buyer’s/User’s responsibility to
ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented here pertains only to the product as shipped.
The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of
health, safety and environmental requirements only. NO warranty or guarantee is expressed or implied regarding the accuracy of this data or the results
to be obtained from the use of the product.
Product ID Odorless Mineral Spirits
Odorless Mineral Spirits
Page 1 of 7 www.aglayne.com

SECTION 2) HAZARDS IDENTIFICATION
Classification:
Aspiration Hazard – Category 1
Germ Cell Mutagenicity – Category 1B
Carcinogenicity – Category 1B
Pictograms:
Signal Word:
Danger
Hazardous Statements – Health:
May be fatal if swallowed and enters airways
May cause genetic defects.
May cause cancer.
Precautionary Statements – General:
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Precautionary Statements – Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary Statements – Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor.
Do NOT induce vomiting.
IF exposed or concerned: Get medical advice/attention.
SAFETY DATA SHEET
Sep 10, 2015
A. G. Layne, Inc.
Product ID:
4578 Brazil Street Los Angeles, CA, US, 90039
Product Name:
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND SUPPLIER’S IDENTIFICATION
Odorless Mineral Spirits
Version: 1.1
Date Printed: Sep 21, 2015
Supersedes Date: May 09, 2015
Odorless Mineral Spirits
Emergency Phone:
Information Phone:
CHEMTREC US : 1-800-424-9300, INTERNATIONAL CALLS : 1-703-527-3887
323-245-2345
Fax:
Product/Recommended Uses: Paint and coatings and other industrial applications.
Odorless Mineral Spirits
Page 2 of 7 www.aglayne.com

Precautionary Statements – Storage:
Store locked up.
Precautionary Statements – Disposal:
Dispose of contents/container to disposal recycling center.
Waste management should be in full compliance with federal, state and local laws.
Acute toxicity of 100% of the mixture is unknown
SECTION 4) FIRST-AID MEASURES
Inhalation:
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If victim is not breathing, call 911 and
administer CPR as directed.
Eliminate all ignition sources if safe to do so.
Skin Contact:
Rinse/wash with lukewarm, gently flowing water (and mild soap) for 15-20 minutes or until product is removed. If skin irritation occurs or
you feel unwell: Get medical advice/attention.
Eye Contact:
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for 15-20 minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. Take care not to rinse contaminated
water into the unaffected eye or onto the face. Get immidiate medical attention.
Ingestion:
Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Immediately call 911 POISON
CENTER/doctor/. Immediately transport to the nearest medical facility for treatment.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
Dry chemical, foam, carbon dioxide or fog is recommended. Water spray is recommended to cool or protect exposed materials or
structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of
foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media:
No data available.
Specific Hazards in Case of Fire:
No data available.
Fire-fighting Procedures:
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions:
Wear protective pressure self-contained breathing apparatus (SCBA) and full turnout gear.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
RELEASE CAN CAUSE FIRE/EXPLOSION. LIQUIDS/VAPORS MAY IGNITE.
Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities
if any exposure to the general public or the environment occurs or is likely to occur.
SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS
CAS Chemical Name % By Weight
0064741-65-7 ODORLESS MINERAL SPIRITS 80% – 100%
Odorless Mineral Spirits
Page 3 of 7 www.aglayne.com

If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment:
Positive pressure, full-facepiece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape SCBA
(NIOSH approved).
Personal Precautions:
Avoid breathing vapor. Avoid contact with skin, eye or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in
immediate area). Use explosive proof equipment. Avoid inhalation of dust and contact with skin and eyes. Do not touch damaged
containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions:
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems
and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up:
Sand, clay and absorbent socks can be used to contain a spill.
SECTION 7) HANDLING AND STORAGE
General:
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements:
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements:
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
Electrostatic charges may be generated during pumping. Keep away from aerosols, flammables, oxidizing agents, corrosives and from
other flammable products.
SECTION 8) EXPOSURE CONTROLS, PERSONAL PROTECTION
Chemical Name OSHA
TWA
(ppm)
OSHA
TWA
(mg/m3)
OSHA
STEL
(ppm)
OSHA
STEL
(mg/m3)
OSHA
Tables (Z1,
Z2, Z3)

OSHA
Carcinogen
OSHA
Skin
designation
NIOSH
TWA
(ppm)
NIOSH
TWA
(mg/m3)
NIOSH
STEL
(ppm)
NIOSH
STEL
(mg/m3)

NIOSH
Carcinogen
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers.
Skin Protection:
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene
or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced.
Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin
sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at
the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.
Eye Protection:
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
Odorless Mineral Spirits
Page 4 of 7 www.aglayne.com

ODORLESS MINERAL
SPIRITS
500 2000 1
Chemical Name ACGIH
TWA
(ppm)
ACGIH
TWA
(mg/m3)
ACGIH
STEL
(ppm)
ACGIH
STEL
(mg/m3)

ACGIH
Carcinogen

ACGIH
Notations

ACGIH
TLV Basis
ODORLESS MINERAL
SPIRITS
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Appearance Light colored liquid
Odor Threshold N/A
Odor Description Hydrocarbon
pH N/A
Water Solubility 0.05 g/l negligible
Flammability Flashpoints at or above 100 F and less than 200 F
Flash Point Symbol F
Flash Point 124 F
Viscosity N/A
Lower Explosion Level N/A
Upper Explosion Level N/A
Vapor Pressure N/A
Vapor Density 5.3 air = 1
Freezing Point N/A
Melting Point N/A
Low Boiling Point 347 F
High Boiling Point 383 F
Auto Ignition Temp 658 F
Decomposition Pt N/A
Evaporation Rate N/A
Coefficient Water/Oil N/A
VOC Composite Partial Pressure 0.830001 mmHg (Calculated @ 20 C/68 F)
Physical and Chemical Properties
Specific Gravity 0.76
Density 6.33 lb/gal
% VOC 100.00%
VOC Actual 6.33 lb/gal
Density VOC 6.33 lb/gal
% Solids By Weight 0.00%
SECTION 10) STABILITY AND REACTIVITY
Stability:
Stable under normal conditions of use.
Conditions to Avoid:
Avoid heat, sparks, open flames and other ignition sources.
Hazardous Reactions/Polymerization:
No data available.
Incompatible Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Odorless Mineral Spirits
Page 5 of 7 www.aglayne.com

Thermal decomposition may yield carbon dioxide and/or carbon monoxide.
SECTION 11) TOXICOLOGICAL INFORMATION
Potential Health Effects – Miscellaneous
0064741-65-7 ODORLESS MINERAL SPIRITS
Laboratory studies with rats have shown that petroleum distillates can cause kidney damage and kidney or liver tumors. These effects
were not seen in similar studies with guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown a
significant increase of kidney damage or an increase in kidney or liver tumors.
Acute toxicity:
Ingestion: May be harmful or fatal if swallowed.
Skin Corrosion/Irritation:
No data available
Serious eye damage/irritation:
No data available
Germ cell mutagenicity:
May cause genetic defects.
Respiratory/Skin Sensitization:
Slightly irritating to respiratory system.
Carcinogenicity:
May cause cancer.
Reproductive toxicity:
No data available
Specific Target Organ Toxicity – Repeated Exposure:
No data available
Specific Target Organ Toxicity – Single Exposure:
No data available
Aspiration hazard:
May be fatal if swallowed and enters airways
SECTION 12) ECOLOGICAL INFORMATION
Bio-accumulative Potential:
No data available.
Persistence and Degradability:
No data available.
Mobility in Soil:
No data available.
Toxicity:
No data available
Other adverse effects:
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria
for hazardous waste. Waste management should be in full compliance with federal, state and local laws.
Empty Containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
Odorless Mineral Spirits
Page 6 of 7 www.aglayne.com

SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information:
Non Regulated Combustible Liquids, Flash Point at or above 100 deg. F
Emergency Response Guide (ERG):
Emergency Response Guide 128
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0064741-65-7 ODORLESS MINERAL
SPIRITS
80% – 100% SARA312,VOC,TSCA,OSHA
SECTION 16) OTHER INFORMATION
General:
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or
appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the
Buyer’s/User’s responsibility to ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented
here pertains only to the product as shipped. The information contained herein is based on our current knowledge of the underlying data
and is intended to describe the product for the purpose of health, safety and environmental requirements only. NO warranty or guarantee
is expressed or implied regarding the accuracy of this data or the results to be obtained from the use of the product.
3
4
H
0
HMIS
Chronic :
Version 1.1:
Mame change, chng in Sect 8
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither A. G. Layne, Inc. nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently
formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
Odorless Mineral Spirits
Page 7 of 7 www.aglayne.com

39PCBTF-F_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
SDS Distribution: The information in this document
should be made available to all who may handle the
product.
Product ID Parachlorobenzotrifluoride
Parachlorobenzotrifluoride
Page 1 of 9 www.aglayne.com

SECTION 2) HAZARDS IDENTIFICATION
Classification
Acute aquatic toxicity – Category 2
Eye Irritation – Category 2A
Flammable Liquids – Category 3
Skin Irritation – Category 2
Specific Target Organ Toxicity – Single Exposure – Category 3
Specific Target Organ Toxicity -Single Exposure (Respiratory Tract Irritation) – Category 3
Signal Word
Warning
Pictograms
Signal Word
Warning
Hazardous Statements – Physical
Flammable liquid and vapor
Hazardous Statements – Health
Causes serious eye irritation
Causes skin irritation
May cause respiratory irritation
Hazardous Statements – Environmental
Toxic to aquatic life
Precautionary Statements – General
SAFETY DATA SHEET
May 21, 2015
A. G. Layne, Inc.
Product ID:
4578 Brazil Street Los Angeles, CA, US, 90039
Product Name:
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER’S IDENTIFICATION
Parachlorobenzotrifluoride
Version: 1.1
Date Printed: Aug 07, 2018
Supersedes Date: May 21, 2015
Parachlorobenzotrifluoride
Emergency Phone:
Information Phone Number:
CHEMTREC US : 1-800-424-9300, INTERNATIONAL CALLS : 1-703-527-3887
323-245-2345
Fax:
Product/Recommended Uses: Paint and coatings, and other industrial applications
Parachlorobenzotrifluoride
Page 2 of 9 www.aglayne.com

If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Precautionary Statements – Prevention
Avoid release to the environment.
Wash with soap and water thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take action to prevent static discharges.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Precautionary Statements – Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse with water or shower.
In case of fire: Use DRY chemical, alcohol- resistant foam, water spray/fog or carbon-dioxide to extinguish.
IF ON SKIN: Wash with plenty of water.
Specific treatment (see First-aid on this label).
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing. And wash it before reuse.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
Precautionary Statements – Storage
Store in a well-ventilated place. Keep cool.
Store in a well-ventilated place. Store locked up.
Precautionary Statements – Disposal
Dispose of contents/container to disposal recycling center.
Waste management should be in full compliance with federal, state and local laws.
SECTION 4) FIRST-AID MEASURES
Inhalation
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If victim is not breathing, call 911 and
administer CPR as directed.
Eliminate all ignition sources if safe to do so.
Skin Contact
Rinse/wash with lukewarm, gently flowing water (and mild soap) for 15-20 minutes or until product is removed. If skin irritation occurs or
CAS Chemical Name % By Weight
0000098-56-6 BENZENE-1-CHLORO-4(TRIFLUOROMETHYL)- 100.000%
SECTION 3) COMPOSITION, INFORMATION ON INGREDIENTS
Parachlorobenzotrifluoride
Page 3 of 9 www.aglayne.com

you feel unwell: Get medical advice/attention.
Eye Contact
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for 15-20 minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. Take care not to rinse contaminated
water into the unaffected eye or onto the face. Get immidiate medical attention.
Ingestion
Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Immediately call 911 POISON
CENTER/doctor/. Immediately transport to the nearest medical facility for treatment.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical, foam, carbon dioxide or fog is recommended. Water spray is recommended to cool or protect exposed materials or
structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of
foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media
No data available.
Specific Hazards in Case of Fire
No data available.
Fire-fighting Procedures
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions
Wear protective pressure self-contained breathing apparatus (SCBA) and full turnout gear.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
RELEASE CAN CAUSE FIRE/EXPLOSION. LIQUIDS/VAPORS MAY IGNITE.
Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify
authorities if any exposure to the general public or the environment occurs or is likely to occur.
If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment
Positive pressure, full-facepiece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape
SCBA (NIOSH approved).
Personal Precautions
Avoid breathing vapor. Avoid contact with skin, eye or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in
immediate area). Use explosive proof equipment. Avoid inhalation of dust and contact with skin and eyes. Do not touch damaged
containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage
systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up
Sand, clay and absorbent socks can be used to contain a spill.
Parachlorobenzotrifluoride
Page 4 of 9 www.aglayne.com

SECTION 7) HANDLING AND STORAGE
General
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
Electrostatic charges may be generated during pumping. Keep away from aerosols, flammables, oxidizing agents, corrosives and from
other flammable products.
SECTION 8) EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers.
Skin Protection
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact,
chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should
be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to
avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be
decontaminated.
Eye Protection
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Appropriate Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
Chemical Name OSHA
TWA
(ppm)
OSHA
TWA
(mg/m3)
OSHA
STEL
(ppm)
OSHA
STEL
(mg/m3)
OSHA
Tables (Z1,
Z2, Z3)

OSHA
Carcinogen
OSHA
Skin
designation
NIOSH
TWA
(ppm)
NIOSH
TWA
(mg/m3)
NIOSH
STEL
(ppm)
NIOSH
STEL
(mg/m3)

NIOSH
Carcinogen
BENZENE-1-CHLORO
-4
(TRIFLUOROMETHYL
)-
2.5 1
Chemical Name ACGIH
TWA
ACGIH
TWA
ACGIH
STEL
ACGIH
STEL

ACGIH

ACGIH

ACGIH
Parachlorobenzotrifluoride
Page 5 of 9 www.aglayne.com

(ppm) (mg/m3) (ppm) (mg/m3) Carcinogen Notations TLV Basis
BENZENE-1-CHLORO
-4
(TRIFLUOROMETHYL
)-
2.5 A4 A4; BEI Bone dam;
fluorosis
A4 – Not Classifiable as a Human Carcinogen, BEI – Substances for which there is a Biological Exposure Index or Indices, dam – Damage
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Appearance Clear liquid
Odor Threshold N/A
Odor Description mild
pH N/A
Water Solubility N/A
Flammability Flash point at or above 100 F/38 C and less than 200 F/93 C
Flash Point Symbol C
Flash Point 43 C
Viscosity N/A
Lower Explosion Level N/A
Upper Explosion Level N/A
Vapor Pressure N/A
Vapor Density N/A
Freezing Point N/A
Melting Point N/A
Low Boiling Point N/A
High Boiling Point N/A
Auto Ignition Temp N/A
Decomposition Pt N/A
Evaporation Rate N/A
Coefficient Water/Oil N/A
VOC Composite Partial Pressure 0 mmHg
Specific Gravity
Density
% VOC
Density VOC
% Solids By Weight
SECTION 10) STABILITY AND REACTIVITY
Stability
Stable under normal conditions of use.
Conditions to Avoid
Avoid heat, sparks, open flames and other ignition sources.
Parachlorobenzotrifluoride
Page 6 of 9 www.aglayne.com

Hazardous Reactions/Polymerization
No data available.
Incompatible Materials
Strong oxidizing agents.
Hazardous Decomposition Products
Thermal decomposition may yield carbon dioxide and/or carbon monoxide.
SECTION 11) TOXICOLOGICAL INFORMATION
Acute toxicity
Ingestion: May be harmful or fatal if swallowed.
No data available
Skin Corrosion/Irritation
Causes skin irritation
Serious eye damage/irritation
Causes serious eye irritation
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Respiratory/Skin Sensitization
Slightly irritating to respiratory system.
No data available
Reproductive toxicity
No data available
Specific Target Organ Toxicity – Repeated Exposure
No data available
Aspiration hazard
No data available
Specific Target Organ Toxicity – Single Exposure
May cause respiratory irritation
Potential Health Effects – Miscellaneous
0000098-56-6 BENZENE-1-CHLORO-4(TRIFLUOROMETHYL)-
Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: skin.
Prolonged or repeated exposure may cause damage to any of the following organs/systems: kidneys, liver, thyroid. Potential skin
sensitizer that may cause allergic reactions and contact dermatitis resulting in severe irritation, dryness, and cracking of the skin.
Ingestion may cause any of the following: gastrointestinal irritation. Eye contact may cause any of the following: permanent eye injury.
Inhalation may cause any of the following: stupor (central nervous system depression), respiratory tract irritation.
SECTION 12) ECOLOGICAL INFORMATION
Bio-accumulative Potential
Parachlorobenzotrifluoride
Page 7 of 9 www.aglayne.com

No data available.
Persistence and Degradability
No data available.
Mobility in Soil
No data available.
Toxicity
Toxic to aquatic life
Other adverse effects
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal Method
Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria
for hazardous waste. Waste management should be in full compliance with federal, state and local laws.
Empty Containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for
any other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information
UN2234, Chlorobenzotrifluorides, 3, PG III
Emergency Response Guide (ERG)
Emergency Response Guide 130
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0000098-56-6 BENZENE-1-CHLORO-4
(TRIFLUOROMETHYL)-
100.000% SARA312,VOC_exempt,TSCA,OSHA
SECTION 16) OTHER INFORMATION
General
Parachlorobenzotrifluoride
Page 8 of 9 www.aglayne.com

A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or
appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the
Buyer’s/User’s responsibility to ensure that his activities comply with all Federal, State, Provincial or Local laws. The information
presented here pertains only to the product as shipped. The information contained herein is based on our current knowledge of the
underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. NO
warranty or guarantee is expressed or implied regarding the accuracy of this data or the results to be obtained from the use of the product.
2
3
H
0
/
Health
FLAMMABILITY
Physical Hazard
Personal Protection
HMIS
( * ) – Chronic effects
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks
Version 1.1:
Revision Date: May 21, 2015
Change in Section 8-Respiratory
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither A. G. Layne, Inc. nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on
the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the
product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use
of this information.
Parachlorobenzotrifluoride
Page 9 of 9 www.aglayne.com

39OMS-D_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
SDS Distribution: The information in this document
should be made available to all who may handle the
product.
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to
become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the Buyer’s/User’s responsibility to
ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented here pertains only to the product as shipped.
The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of
health, safety and environmental requirements only. NO warranty or guarantee is expressed or implied regarding the accuracy of this data or the results
to be obtained from the use of the product.
Product ID Odorless Mineral Spirits
Odorless Mineral Spirits
Page 1 of 7 www.aglayne.com

SECTION 2) HAZARDS IDENTIFICATION
Classification:
Aspiration Hazard – Category 1
Germ Cell Mutagenicity – Category 1B
Carcinogenicity – Category 1B
Pictograms:
Signal Word:
Danger
Hazardous Statements – Health:
May be fatal if swallowed and enters airways
May cause genetic defects.
May cause cancer.
Precautionary Statements – General:
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Precautionary Statements – Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary Statements – Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor.
Do NOT induce vomiting.
IF exposed or concerned: Get medical advice/attention.
SAFETY DATA SHEET
Sep 10, 2015
A. G. Layne, Inc.
Product ID:
4578 Brazil Street Los Angeles, CA, US, 90039
Product Name:
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND SUPPLIER’S IDENTIFICATION
Odorless Mineral Spirits
Version: 1.1
Date Printed: Sep 21, 2015
Supersedes Date: May 09, 2015
Odorless Mineral Spirits
Emergency Phone:
Information Phone:
CHEMTREC US : 1-800-424-9300, INTERNATIONAL CALLS : 1-703-527-3887
323-245-2345
Fax:
Product/Recommended Uses: Paint and coatings and other industrial applications.
Odorless Mineral Spirits
Page 2 of 7 www.aglayne.com

Precautionary Statements – Storage:
Store locked up.
Precautionary Statements – Disposal:
Dispose of contents/container to disposal recycling center.
Waste management should be in full compliance with federal, state and local laws.
Acute toxicity of 100% of the mixture is unknown
SECTION 4) FIRST-AID MEASURES
Inhalation:
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If victim is not breathing, call 911 and
administer CPR as directed.
Eliminate all ignition sources if safe to do so.
Skin Contact:
Rinse/wash with lukewarm, gently flowing water (and mild soap) for 15-20 minutes or until product is removed. If skin irritation occurs or
you feel unwell: Get medical advice/attention.
Eye Contact:
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for 15-20 minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. Take care not to rinse contaminated
water into the unaffected eye or onto the face. Get immidiate medical attention.
Ingestion:
Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Immediately call 911 POISON
CENTER/doctor/. Immediately transport to the nearest medical facility for treatment.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
Dry chemical, foam, carbon dioxide or fog is recommended. Water spray is recommended to cool or protect exposed materials or
structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of
foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media:
No data available.
Specific Hazards in Case of Fire:
No data available.
Fire-fighting Procedures:
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions:
Wear protective pressure self-contained breathing apparatus (SCBA) and full turnout gear.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
RELEASE CAN CAUSE FIRE/EXPLOSION. LIQUIDS/VAPORS MAY IGNITE.
Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities
if any exposure to the general public or the environment occurs or is likely to occur.
SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS
CAS Chemical Name % By Weight
0064741-65-7 ODORLESS MINERAL SPIRITS 80% – 100%
Odorless Mineral Spirits
Page 3 of 7 www.aglayne.com

If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment:
Positive pressure, full-facepiece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape SCBA
(NIOSH approved).
Personal Precautions:
Avoid breathing vapor. Avoid contact with skin, eye or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in
immediate area). Use explosive proof equipment. Avoid inhalation of dust and contact with skin and eyes. Do not touch damaged
containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions:
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems
and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up:
Sand, clay and absorbent socks can be used to contain a spill.
SECTION 7) HANDLING AND STORAGE
General:
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements:
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements:
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
Electrostatic charges may be generated during pumping. Keep away from aerosols, flammables, oxidizing agents, corrosives and from
other flammable products.
SECTION 8) EXPOSURE CONTROLS, PERSONAL PROTECTION
Chemical Name OSHA
TWA
(ppm)
OSHA
TWA
(mg/m3)
OSHA
STEL
(ppm)
OSHA
STEL
(mg/m3)
OSHA
Tables (Z1,
Z2, Z3)

OSHA
Carcinogen
OSHA
Skin
designation
NIOSH
TWA
(ppm)
NIOSH
TWA
(mg/m3)
NIOSH
STEL
(ppm)
NIOSH
STEL
(mg/m3)

NIOSH
Carcinogen
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers.
Skin Protection:
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene
or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced.
Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin
sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at
the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.
Eye Protection:
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
Odorless Mineral Spirits
Page 4 of 7 www.aglayne.com

ODORLESS MINERAL
SPIRITS
500 2000 1
Chemical Name ACGIH
TWA
(ppm)
ACGIH
TWA
(mg/m3)
ACGIH
STEL
(ppm)
ACGIH
STEL
(mg/m3)

ACGIH
Carcinogen

ACGIH
Notations

ACGIH
TLV Basis
ODORLESS MINERAL
SPIRITS
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Appearance Light colored liquid
Odor Threshold N/A
Odor Description Hydrocarbon
pH N/A
Water Solubility 0.05 g/l negligible
Flammability Flashpoints at or above 100 F and less than 200 F
Flash Point Symbol F
Flash Point 124 F
Viscosity N/A
Lower Explosion Level N/A
Upper Explosion Level N/A
Vapor Pressure N/A
Vapor Density 5.3 air = 1
Freezing Point N/A
Melting Point N/A
Low Boiling Point 347 F
High Boiling Point 383 F
Auto Ignition Temp 658 F
Decomposition Pt N/A
Evaporation Rate N/A
Coefficient Water/Oil N/A
VOC Composite Partial Pressure 0.830001 mmHg (Calculated @ 20 C/68 F)
Physical and Chemical Properties
Specific Gravity 0.76
Density 6.33 lb/gal
% VOC 100.00%
VOC Actual 6.33 lb/gal
Density VOC 6.33 lb/gal
% Solids By Weight 0.00%
SECTION 10) STABILITY AND REACTIVITY
Stability:
Stable under normal conditions of use.
Conditions to Avoid:
Avoid heat, sparks, open flames and other ignition sources.
Hazardous Reactions/Polymerization:
No data available.
Incompatible Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Odorless Mineral Spirits
Page 5 of 7 www.aglayne.com

Thermal decomposition may yield carbon dioxide and/or carbon monoxide.
SECTION 11) TOXICOLOGICAL INFORMATION
Potential Health Effects – Miscellaneous
0064741-65-7 ODORLESS MINERAL SPIRITS
Laboratory studies with rats have shown that petroleum distillates can cause kidney damage and kidney or liver tumors. These effects
were not seen in similar studies with guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown a
significant increase of kidney damage or an increase in kidney or liver tumors.
Acute toxicity:
Ingestion: May be harmful or fatal if swallowed.
Skin Corrosion/Irritation:
No data available
Serious eye damage/irritation:
No data available
Germ cell mutagenicity:
May cause genetic defects.
Respiratory/Skin Sensitization:
Slightly irritating to respiratory system.
Carcinogenicity:
May cause cancer.
Reproductive toxicity:
No data available
Specific Target Organ Toxicity – Repeated Exposure:
No data available
Specific Target Organ Toxicity – Single Exposure:
No data available
Aspiration hazard:
May be fatal if swallowed and enters airways
SECTION 12) ECOLOGICAL INFORMATION
Bio-accumulative Potential:
No data available.
Persistence and Degradability:
No data available.
Mobility in Soil:
No data available.
Toxicity:
No data available
Other adverse effects:
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria
for hazardous waste. Waste management should be in full compliance with federal, state and local laws.
Empty Containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
Odorless Mineral Spirits
Page 6 of 7 www.aglayne.com

SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information:
Non Regulated Combustible Liquids, Flash Point at or above 100 deg. F
Emergency Response Guide (ERG):
Emergency Response Guide 128
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0064741-65-7 ODORLESS MINERAL
SPIRITS
80% – 100% SARA312,VOC,TSCA,OSHA
SECTION 16) OTHER INFORMATION
General:
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or
appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the
Buyer’s/User’s responsibility to ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented
here pertains only to the product as shipped. The information contained herein is based on our current knowledge of the underlying data
and is intended to describe the product for the purpose of health, safety and environmental requirements only. NO warranty or guarantee
is expressed or implied regarding the accuracy of this data or the results to be obtained from the use of the product.
3
4
H
0
HMIS
Chronic :
Version 1.1:
Mame change, chng in Sect 8
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither A. G. Layne, Inc. nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently
formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
Odorless Mineral Spirits
Page 7 of 7 www.aglayne.com

39NAPTA_SDS.pdf

by | Sep 27, 2025

39MSD60-D_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
SDS Distribution: The information in this document
should be made available to all who may handle the
product.
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to
become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the Buyer’s/User’s responsibility to
ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented here pertains only to the product as shipped.
The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of
health, safety and environmental requirements only. NO warranty or guarantee is expressed or implied regarding the accuracy of this data or the results
to be obtained from the use of the product.
Product ID Mineral Spirits
Mineral Spirits
Page 1 of 8 www.aglayne.com

SECTION 2) HAZARDS IDENTIFICATION
Classification:
Specific Target Organ Toxicity -Single Exposure (Narcotic Effects) – Category 3
Specific Target Organ Toxicity – Repeated Exposure – Category 1
Aspiration Hazard – Category 1
Flammable Liquids Category 3
Pictograms:
Signal Word:
Danger
Hazardous Statements – Physical:
Flammable liquid and vapor
Hazardous Statements – Health:
May cause drowsiness or dizziness
Causes damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways
Precautionary Statements – General:
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Precautionary Statements – Prevention:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Keep container tightly closed.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash with soap and water thoroughly after handling.
SAFETY DATA SHEET
Oct 05, 2015
A. G. Layne, Inc.
Product ID:
4578 Brazil Street Los Angeles, CA, US, 90039
Product Name:
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND SUPPLIER’S IDENTIFICATION
Mineral Spirits
Version: 1.0
Date Printed: Oct 05, 2015
Supersedes Date: N.A.
Mineral Spirits
Emergency Phone:
Information Phone:
CHEMTREC US : 1-800-424-9300, INTERNATIONAL CALLS : 1-703-527-3887
323-245-2345
Fax:
Product/Recommended Uses: Industrial solvent
Mineral Spirits
Page 2 of 8 www.aglayne.com

Do not eat, drink or smoke when using this product.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take action to prevent static discharges.
Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary Statements – Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
Get Medical advice/attention if you feel unwell.
IF SWALLOWED: Immediately call a POISON CENTER or doctor.
Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse with water or shower.
In case of fire: Use DRY chemical, alcohol- resistant foam, water spray/fog or carbon-dioxide to extinguish.
Precautionary Statements – Storage:
Store in a well-ventilated place. Store locked up.
Store locked up.
Store in a well-ventilated place. Keep cool.
Precautionary Statements – Disposal:
Dispose of contents/container to disposal recycling center.
Waste management should be in full compliance with federal, state and local laws.
SECTION 4) FIRST-AID MEASURES
Inhalation:
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If victim is not breathing, call 911 and
administer CPR as directed.
Eliminate all ignition sources if safe to do so.
Skin Contact:
Rinse/wash with lukewarm, gently flowing water (and mild soap) for 15-20 minutes or until product is removed. If skin irritation occurs or
you feel unwell: Get medical advice/attention.
Eye Contact:
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for 15-20 minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. Take care not to rinse contaminated
water into the unaffected eye or onto the face. Get immidiate medical attention.
Ingestion:
Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Immediately call 911 POISON
CENTER/doctor/. Immediately transport to the nearest medical facility for treatment.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
Dry chemical, foam, carbon dioxide or fog is recommended. Water spray is recommended to cool or protect exposed materials or
structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of
foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media:
No data available.
SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS
CAS Chemical Name % By Weight
0064742-88-7 MEDIUM MINERAL SPIRITS 80% – 100%
Mineral Spirits
Page 3 of 8 www.aglayne.com

Specific Hazards in Case of Fire:
No data available.
Fire-fighting Procedures:
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions:
Wear protective pressure self-contained breathing apparatus (SCBA) and full turnout gear.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
RELEASE CAN CAUSE FIRE/EXPLOSION. LIQUIDS/VAPORS MAY IGNITE.
Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities
if any exposure to the general public or the environment occurs or is likely to occur.
If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment:
Positive pressure, full-facepiece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape SCBA
(NIOSH approved).
Personal Precautions:
Avoid breathing vapor. Avoid contact with skin, eye or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in
immediate area). Use explosive proof equipment. Avoid inhalation of dust and contact with skin and eyes. Do not touch damaged
containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions:
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems
and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up:
Sand, clay and absorbent socks can be used to contain a spill.
SECTION 7) HANDLING AND STORAGE
General:
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements:
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements:
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
Electrostatic charges may be generated during pumping. Keep away from aerosols, flammables, oxidizing agents, corrosives and from
other flammable products.
SECTION 8) EXPOSURE CONTROLS, PERSONAL PROTECTION
Mineral Spirits
Page 4 of 8 www.aglayne.com

Chemical Name OSHA
TWA
(ppm)
OSHA
TWA
(mg/m3)
OSHA
STEL
(ppm)
OSHA
STEL
(mg/m3)
OSHA
Tables (Z1,
Z2, Z3)

OSHA
Carcinogen
OSHA
Skin
designation
NIOSH
TWA
(ppm)
NIOSH
TWA
(mg/m3)
NIOSH
STEL
(ppm)
NIOSH
STEL
(mg/m3)

NIOSH
Carcinogen
No applicable chemical – – – – – – – – – – – –
Chemical Name ACGIH
TWA
(ppm)
ACGIH
TWA
(mg/m3)
ACGIH
STEL
(ppm)
ACGIH
STEL
(mg/m3)

ACGIH
Carcinogen

ACGIH
Notations

ACGIH
TLV Basis
No applicable chemical – – – – – – –
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers.
Skin Protection:
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene
or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced.
Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin
sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at
the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.
Eye Protection:
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear to light colored liquid
Odor Threshold N/A
Odor Description Hydrocarbon
pH N/A
Water Solubility N/A
Flammability Flashpoints at or above 100 F and less than 200 F
Flash Point Symbol C
Flash Point 40 C
Viscosity N/A
Lower Explosion Level N/A
Upper Explosion Level N/A
Vapor Pressure N/A
Vapor Density N/A
Freezing Point N/A
Melting Point N/A
Low Boiling Point N/A
High Boiling Point N/A
Physical and Chemical Properties
Specific Gravity 0.79
Density 6.59 lb/gal
% VOC 100.00%
VOC Actual 6.59 lb/gal
Density VOC 6.59 lb/gal
% Solids By Weight 0.00%
Mineral Spirits
Page 5 of 8 www.aglayne.com

Auto Ignition Temp N/A
Decomposition Pt N/A
Evaporation Rate N/A
Coefficient Water/Oil N/A
VOC Composite Partial Pressure 1.08821 mmHg (Calculated @ 20 C/68 F)
SECTION 10) STABILITY AND REACTIVITY
Stability:
Stable under normal conditions of use.
Conditions to Avoid:
Avoid heat, sparks, open flames and other ignition sources.
Hazardous Reactions/Polymerization:
No data available.
Incompatible Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition may yield carbon dioxide and/or carbon monoxide.
SECTION 11) TOXICOLOGICAL INFORMATION
Potential Health Effects – Miscellaneous
0064742-88-7 MEDIUM MINERAL SPIRITS
Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: central
nervous system, kidneys, liver, respiratory system, skin. This substance may cause damage to any of the following organs/systems:
blood, central nervous system, eyes, kidneys, liver, lungs, reproductive system, skin. Laboratory studies with rats have shown that
petroleum distillates can cause kidney damage and kidney or liver tumors. These effects were not seen in similar studies with guinea
pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown a significant increase of kidney damage or an
increase in kidney or liver tumors.
Acute toxicity:
No data available
Skin Corrosion/Irritation:
No data available
Serious eye damage/irritation:
No data available
Germ cell mutagenicity:
No data available
Respiratory/Skin Sensitization:
Slightly irritating to respiratory system.
Carcinogenicity:
No data available
Reproductive toxicity:
No data available
Specific Target Organ Toxicity – Repeated Exposure:
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard:
May be fatal if swallowed and enters airways
Specific Target Organ Toxicity – Single Exposure:
May cause drowsiness or dizziness
SECTION 12) ECOLOGICAL INFORMATION
Mineral Spirits
Page 6 of 8 www.aglayne.com

Bio-accumulative Potential:
No data available.
Persistence and Degradability:
No data available.
Mobility in Soil:
No data available.
Toxicity:
No data available
Other adverse effects:
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria
for hazardous waste. Waste management should be in full compliance with federal, state and local laws.
Empty Containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information:
UN1268, Petroleum Distillates, N.O.S., 3, PG II
Emergency Response Guide (ERG):
Emergency Response Guide 128
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0064742-88-7 MEDIUM MINERAL
SPIRITS
80% – 100% SARA312,VOC,TSCA
SECTION 16) OTHER INFORMATION
General:
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or
appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the
Buyer’s/User’s responsibility to ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented
here pertains only to the product as shipped. The information contained herein is based on our current knowledge of the underlying data
and is intended to describe the product for the purpose of health, safety and environmental requirements only. NO warranty or guarantee
is expressed or implied regarding the accuracy of this data or the results to be obtained from the use of the product.
H
HMIS
Chronic :
Mineral Spirits
Page 7 of 8 www.aglayne.com

DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither A. G. Layne, Inc. nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently
formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
Mineral Spirits
Page 8 of 8 www.aglayne.com

39NAPTA-F_SDS.pdf

by | Sep 27, 2025

39MMA_SDS.pdf

by | Sep 27, 2025

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 1 / 11 Methyl Methacrylate 25 HQ

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Methyl Methacrylate 25 HQ
Recommended use of the chemical and restrictions on use
Recommended use : Acid.
Manufacturer or supplier’s details
Company : Univar Solutions USA, Inc.
Address

3075 Highland Pkwy Suite 200
Downers Grove, IL 60515
United States of America (USA)
Emergency telephone number:
Transport North America: CHEMTREC (1-800-424-9300)
CHEMTREC INTERNATIONAL Tel # 703-527-3887
Additional Information: : Responsible Party: Product Compliance Department
E-mail: SDSNA@univarsolutions.com
SDS Requests: 1-855-429-2661
Website: www.univarsolutions.com
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids

: Category 2
Skin irritation

: Category 2
Eye irritation

: Category 2A
Skin sensitisation

: Category 1
Specific target organ toxicity
– single exposure

: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms

:

Signal word

: Danger

Hazard statements

: H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.

Precautionary statements

: Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
P242 Use only non-sparking tools.

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 2 / 11 Methyl Methacrylate 25 HQ

P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam for extinction.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
CAS-No. Chemical name Weight percent
80-62-6 Methyl methacrylate 90 – 100
Any Concentration shown as a range is due to batch variation.

Molecular formula : C5H8O2
Synonyms : 2-propionic acid, methacrylic acid, methyl ester 2, methyl es-
ter, 2-methylpropionic acid, -methacrylic acid

SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
If inhaled : If symptoms persist, call a physician.
In case of skin contact : If skin irritation persists, call a physician.
If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact : Flush eyes with water as a precaution.
Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 3 / 11 Methyl Methacrylate 25 HQ

SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during fire-
fighting
: Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion prod-
ucts

: No hazardous combustion products are known

Specific extinguishing meth-
ods
: Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored sepa-
rately in closed containments.
Special protective equipment
for firefighters
: Wear self-contained breathing apparatus for firefighting if nec-
essary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
gency procedures

: Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentra-
tions. Vapours can accumulate in low areas.

Environmental precautions

: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

: Contain spillage, and then collect with non-combustible ab-
sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE
Advice on protection against
fire and explosion

: Do not spray on a naked flame or any incandescent material.
Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours). Use only
explosion-proof equipment. Keep away from open flames, hot
surfaces and sources of ignition.

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 4 / 11 Methyl Methacrylate 25 HQ

Advice on safe handling : Avoid formation of aerosol.
Do not breathe vapours/dust.
Avoid exposure – obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.
Conditions for safe storage : No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
CAS-No. Components Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis
80-62-6 Methyl methacrylate TWA 50 ppm ACGIH

STEL 100 ppm ACGIH

TWA 100 ppm
410 mg/m3
NIOSH REL

TWA 100 ppm
410 mg/m3
OSHA Z-1

TWA 100 ppm
410 mg/m3
OSHA P0
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally re-
quired.
In the case of vapour formation use a respirator with an ap-
proved filter.
Hand protection

Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Eye wash bottle with pure water
Tightly fitting safety goggles
Skin and body protection : Impervious clothing
Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 5 / 11 Methyl Methacrylate 25 HQ

Hygiene measures : When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Colour : colourless
Odour : fruity
Odour Threshold : No data available
pH : No data available

Freezing Point : No data available
Boiling Point (Boiling
point/boiling range)
: 101 C (214 F)

Flash point : 10 C (50 F)

Evaporation rate : No data available
Flammability (solid, gas) : No data available
Upper explosion limit

: 8.2 %(V)

Lower explosion limit

: 1.7 %(V)

Vapour pressure : 22.5 mmHg @ 16.67 C (62.01 F)
Calculated Vapor Pressure

Relative vapour density : No data available
Relative density : 0.945Reference substance: (water = 1)

Density : 0.936 g/cm3 @ 20 C (68 F)

Solubility(ies)
Water solubility : practically insoluble
Solubility in other solvents : No data available
Partition coefficient: n-
octanol/water
: No data available
Auto-ignition temperature : 421 – 435 C
Thermal decomposition : No data available

SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reac-
tions
: Vapours may form explosive mixture with air.
Hazardous polymerisation may occur.

Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Peroxides
Sulphur compounds
halogens

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 6 / 11 Methyl Methacrylate 25 HQ

Ammonium salts
Amines
Nitric acid
Strong oxidizing agents
water

SECTION 11. TOXICOLOGICAL INFORMATION
Skin corrosion/irritation
Product:
Remarks: Irritating to skin.

Components:
80-62-6:
Species: Rabbit
Result: Irritating to skin.

Serious eye damage/eye irritation
Product:
Remarks: Irritating to eyes.

Respiratory or skin sensitisation
Product:
Result: May cause sensitisation by skin contact.

Components:
80-62-6:
Test Type: lymph node assay
Species: Mouse
Result: The product is a skin sensitiser, sub-category 1A.

Carcinogenicity
IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

ACGIH

No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcino-
gen by ACGIH.

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 7 / 11 Methyl Methacrylate 25 HQ

STOT – single exposure
Components:
80-62-6:
Target Organs: Upper respiratory tract
Assessment: The substance or mixture is classified as specific target organ toxicant, single ex-
posure, category 3 with respiratory tract irritation.

Aspiration toxicity
Product:
No aspiration toxicity classification
Further information
Product:
Remarks: Solvents may degrease the skin.

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available

Mobility in soil
No data available

Other adverse effects
Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone – CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological infor-
mation
: No data available

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 8 / 11 Methyl Methacrylate 25 HQ

Waste from residues : Dispose of in accordance with all applicable local, state and
federal regulations.
For assistance with your waste management needs – including
disposal, recycling and waste stream reduction, contact Uni-
var Solutions ChemCare: 1-800-909-4897

Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14. TRANSPORT INFORMATION
DOT (Department of Transportation):
UN1247, METHYL METHACRYLATE MONOMER, STABILIZED, 3, II

IATA (International Air Transport Association):
UN1247, METHYL METHACRYLATE MONOMER, STABILIZED, 3, II

IMDG (International Maritime Dangerous Goods):
UN1247, METHYL METHACRYLATE MONOMER, STABILIZED, 3, II, Flash Point:10 C(50 F)

SECTION 15. REGULATORY INFORMATION
EPCRA – Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
Methyl methacrylate 80-62-6 1000 1001
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards

: Fire Hazard
Acute Health Hazard

SARA 302

: No chemicals in this material are subject to the reporting re-
quirements of SARA Title III, Section 302.

SARA 313

: The following components are subject to reporting levels es-
tablished by SARA Title III, Section 313:

80-62-6 Methyl methacrylate
Clean Air Act
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
80-62-6 Methyl methacrylate
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental
Release Prevention (40 CFR 68.130, Subpart F).

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 9 / 11 Methyl Methacrylate 25 HQ

The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final
VOC’s (40 CFR 60.489):
80-62-6 Methyl methacrylate
Clean Water Act
The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A:
80-62-6 Methyl methacrylate
The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3:
80-62-6 Methyl methacrylate
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
US State Regulations
Massachusetts Right To Know
80-62-6 Methyl methacrylate 90 – 100 %
Pennsylvania Right To Know
80-62-6 Methyl methacrylate 90 – 100 %
New Jersey Right To Know
80-62-6 Methyl methacrylate 90 – 100 %

California Prop 65 : This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other re-
productive harm.
The components of this product are reported in the following inventories:
CH INV

: The formulation contains substances listed on the Swiss In-
ventory

TSCA

: On TSCA Inventory

DSL

: All components of this product are on the Canadian DSL

AICS

: On the inventory, or in compliance with the inventory

NZIoC

: On the inventory, or in compliance with the inventory

ENCS

: On the inventory, or in compliance with the inventory

ISHL

: On the inventory, or in compliance with the inventory

KECI

: On the inventory, or in compliance with the inventory

PICCS

: On the inventory, or in compliance with the inventory

IECSC

: On the inventory, or in compliance with the inventory

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 10 / 11 Methyl Methacrylate 25 HQ

SECTION16. OTHER INFORMATION
NFPA: HMIS III:

The information accumulated is based on the data of which we are aware and is believed
to be correct as of the date hereof. Since this information may be applied under conditions
beyond our control and with which we may be unfamiliar and since data made become
available subsequently to the date hereof, we do not assume any responsibility for the
results of its use. Recipients are advised to confirm in advance of need that the information
is current, applicable, and suitable to their circumstances. This SDS has been prepared by
Univar Solutions Product Compliance Department (1-855-429-2661)
SDSNA@univarsolutions.com.

Revision Date : 09/02/2019

Material number:
16049878, 16049877, 16039805, 16028463, 16027986, 587589, 54904, 72966, 105168,
71786, 88585, 73483

Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH American Conference of Govern-
ment Industrial Hygienists
LD50 Lethal Dose 50%
AICS Australia, Inventory of Chemical
Substances
LOAEL Lowest Observed Adverse Effect
Level
DSL Canada, Domestic Substances List NFPA National Fire Protection Agency
NDSL Canada, Non-Domestic Subs-
tances List
NIOSH National Institute for Occupational
Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemi-
cals
EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
EGEST EOSCA Generic Exposure Scenar-
io Tool
OSHA Occupational Safety & Health
Administration
EOSCA European Oilfield Specialty Chem-
icals Association
PEL Permissible Exposure Limit
EINECS European Inventory of Existing PICCS Philippines Inventory of Commer-
Flammability

Health

Instability

2
3

2

W

FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3

2

2

Special hazard.
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 =Extreme, * = Chronic

Safety Data Sheet

Methyl Methacrylate 25 HQ
Version 1.1 Revision Date: 09/02/2019

SDS Number: 100000002700 11 / 11 Methyl Methacrylate 25 HQ

Chemical Substances cial Chemical Substances
MAK Germany Maximum Concentration
Values
PRNT Presumed Not Toxic
GHS Globally Harmonized System RCRA Resource Conservation Recovery
Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act.
IARC International Agency for Research
on Cancer
TLV Threshold Limit Value
IECSC Inventory of Existing Chemical
Substances in China
TWA Time Weighted Average
ENCS Japan, Inventory of Existing and
New Chemical Substances
TSCA Toxic Substance Control Act
KECI Korea, Existing Chemical Inventory UVCB Unknown or Variable Composi-
tion, Complex Reaction Products,
and Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System LC50 Lethal Concentration 50% METHYL METHACRYLATE 25 P Monomer. Additive Liquid. SAFETY DATA SHEET Product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Chemical name :methyl methacrylate Supplier's details :INTERPLASTIC CORPORATION 1225 Willow Lake Boulevard St. Paul, MN 55110-5145 651.481.6860 METHYL METHACRYLATE 25 P Product code :COR50-ZZ-00805 Product use :Industrial applications. CHEMTREC 24-Hour Emergency Telephone US and Canada 800.424.9300 Outside US and Canada +1 703.741.5970 Section 2. Hazard identification FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 SKIN SENSITIZATION - Category 1A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Classification of the substance or mixture : Signal word :Danger Hazard statements :Highly flammable liquid and vapor. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. Hazard pictograms : Precautionary statements Prevention :Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Response :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. Storage :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. GHS label elements Date of issue/Date of revision :2/10/2023Date of previous issue :10/4/2021 Version:0.03 1/11 METHYL METHACRYLATE 25 PCOR50-ZZ-00805 Canada Section 3. Composition/information on ingredients methyl methacrylate 80 - 100 80-62-6 Ingredient name CAS number There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Chemical name :methyl methacrylate Other means of identification :Monomer. Additive CAS number :80-62-6 Substance/mixture Product code :COR50-ZZ-00805 CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Substance % (w/w) Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Remove contaminated clothing and shoes. Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First-aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. May cause an allergic skin reaction. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Potential acute health effects Date of issue/Date of revision :2/10/2023Date of previous issue :10/4/2021 Version:0.03 2/11 METHYL METHACRYLATE 25 PCOR50-ZZ-00805 Canada Section 4. First-aid measures Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO , water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel Date of issue/Date of revision :2/10/2023Date of previous issue :10/4/2021 Version:0.03 3/11 METHYL METHACRYLATE 25 PCOR50-ZZ-00805 Canada Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store above the following temperature: 30 C (86 F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Store containers in a safe place. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision :2/10/2023Date of previous issue :10/4/2021 Version:0.03 4/11 METHYL METHACRYLATE 25 PCOR50-ZZ-00805 Canada Methyl methacrylate CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 205 mg/m 8 hours. 8 hrs OEL: 50 ppm 8 hours. 15 min OEL: 410 mg/m 15 minutes. 15 min OEL: 100 ppm 15 minutes. CA British Columbia Provincial (Canada, 6/2022). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). Skin sensitizer. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Quebec Provincial (Canada, 6/2021). Skin sensitizer. Inhalation sensitizer. TWAEV: 50 ppm 8 hours. STEV: 100 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). Skin sensitizer. STEL: 100 ppm 15 minutes. TWA: 50 ppm 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Date of issue/Date of revision :2/10/2023Date of previous issue :10/4/2021 Version:0.03 5/11 METHYL METHACRYLATE 25 PCOR50-ZZ-00805 Canada Section 8. Exposure controls/personal protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. -48 C (-54.4 F) 0.94 3.5 [Air = 1] 3.7 kPa (27.75 mm Hg) Not available. Characteristic.Odor pH Colorless.Color Evaporation rate 3.1 ( butyl acetate = 1) Auto-ignition temperature Flash point 400 C (752 F) [DIN 51794] Closed cup: 10 C (50 F) [DIN 51755] 1.38 [OECD 107] Not available. Viscosity Not available. 0.1 ppmOdor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point :100.36 C (212.6 F) Lower and upper explosive (flammable) limits :Lower: 1.7% Upper: 12.5% Decomposition temperature:Not available. Heat of combustion :-26516400 J/kg Solubility in water :15.3 g/l VOC content (industrial use)100 % (w/w) As shipped, including monomer. Section 10. Stability and reactivity Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. The product is stable.Chemical stability : : Possibility of hazardous reactions :Hazardous reactions or instability may occur under certain conditions of storage or use. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision :2/10/2023Date of previous issue :10/4/2021 Version:0.03 6/11 METHYL METHACRYLATE 25 PCOR50-ZZ-00805 Canada Section 10. Stability and reactivity Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Reactive or incompatible with the following materials: oxidizing materials : Incompatible materials : Hazardous polymerization may occur under certain conditions of storage or use. Keep away from heat and direct sunlight. Keep away from heat and flame. Keep away from oxidizing agents. Reactive or incompatible with the following materials: oxidizing materials, reducing materials, metals and acids. Incompatible with some strong acids. Section 11. Toxicological information Acute toxicity Methyl methacrylate LC50 Inhalation Vapor Rat 78000 mg/m 4 hours LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat 7872 mg/kg –
Product/ingredient nameResult Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Information on the likely
routes of exposure
Inhalation :May cause respiratory irritation.
No known significant effects or critical hazards.:Eye contact
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Methyl methacrylate Category 3 – Respiratory tract
irritation
Name Category
Not available.
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
:Not available.
Potential acute health effects
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METHYL METHACRYLATE 25 PCOR50-ZZ-00805
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Section 11. Toxicological information
Not available.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 7872 mg/kg
Inhalation (vapors) 78 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
Section 12. Ecological information
Toxicity
Methyl methacrylate Acute LC50 130000 g/l Fresh waterFish – Pimephales promelas –
Adult
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Not available.
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METHYL METHACRYLATE 25 PCOR50-ZZ-00805
Canada
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Methyl methacrylate 1.38 – low
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapor from product residues
may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Methyl methacrylate
monomer, inhibited
3
II
Methyl methacrylate
monomer, inhibited
UN1247
3
II
UN1247
– –
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
No. No.
DOT Classification
UN1247
Methyl methacrylate
monomer, inhibited
3
II
No.
Reportable quantity
1000 lbs / 454 kg
[127.59 gal / 482.98 L].
Package sizes
shipped in quantities
less than the product
reportable quantity are
not subject to the RQ
(reportable quantity)
transportation
requirements.
TDG Classification
UN1247
Methyl methacrylate
monomer, inhibited
3
II
No.
Product classified as
per the following
sections of the
Transportation of
Dangerous Goods
Regulations: 2.18-2.19
(Class 3).
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METHYL METHACRYLATE 25 PCOR50-ZZ-00805
Canada
Section 14. Transport information
Special precautions for user
Transport in bulk according
to IMO instruments
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:Not available.
:
Section 15. Regulatory information
Inventory list
Australia :This material is listed or exempted.
Canada inventory :This material is listed or exempted.
China :This material is listed or exempted.
Europe :This material is listed or exempted.
Japan :Japan inventory (CSCL): This material is listed or exempted.
Japan inventory (ISHL): This material is listed or exempted.
Republic of Korea :This material is listed or exempted.
Malaysia :This material is listed or exempted.
New Zealand :This material is listed or exempted.
Philippines :This material is listed or exempted.
Taiwan :This material is listed or exempted.
United States :This material is active or exempted.
Canadian lists
This material is listed.Canadian NPRI :
CEPA Toxic substances :This material is not listed.
Turkey :This material is listed or exempted.
Section 16. Other information
2/10/2023
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Date of previous issue
:
:
:
:
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
HPR = Hazardous Products Regulations
2/10/2023
10/4/2021
0.03
Procedure used to derive the classification
Health, Safety and Environmental
Email For questions about the SDS,
contact
iasafety@ip-corporation.com
Date of issue/Date of revision :2/10/2023Date of previous issue :10/4/2021 Version:0.0310/11

METHYL METHACRYLATE 25 PCOR50-ZZ-00805
Canada
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.
Notice to reader
Indicates information that has changed from previously issued version.
References :
Classification Justification
FLAMMABLE LIQUIDS – Category 2 Regulatory data
SKIN IRRITATION – Category 2 Regulatory data
SKIN SENSITIZATION – Category 1A Regulatory data
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) (Respiratory tract irritation) – Category 3
Regulatory data
Canada Hazardous Products Regulations SOR/2015-17
Date of issue/Date of revision :2/10/2023Date of previous issue :10/4/2021 Version:0.0311/11

MERACRYL MMA —

Version: 2.3
Issue Date: 03/25/2019
Last revised date: 09/09/2020
Supersedes Date: 08/28/2020

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SAFETY DATA SHEET
Classified in accordance with 29 CFR 1910.1200

1. Identification

Product identifier: MERACRYL MMA —

Chemical name: Methylmethacrylate

Other means of identification
CAS Number: 80-62-6
Recommended use: Monomer Chemical Intermediate For use in industrial
installations or professional treatment only. Consumers

Recommended restrictions: Applications where liquid monomer is intended to come
into contact with skin or nails.

Manufacturer/Importer/Distributor Information
Company Name : Roehm America LLC
299 Jefferson Road
Parsippany, NJ 07054
USA

Telephone : +1 800-225-0172

E-mail : product-regulatory-services@roehm.com

Emergency telephone number:
24-Hour Health Emergency : +1 800 424 9300 (CHEMTREC – US & CANADA)
+1 703 527 3887 (CHEMTREC WORLD)

2. Hazard(s) identification

Hazard Classification
Physical Hazards
Flammable liquids Category 2
Health Hazards
Skin irritation Category 2
Skin sensitizer Sub-category 1B
Specific Target Organ Toxicity –
Single Exposure
Category 3
(Respiratory
system)

Environmental Hazards
Acute hazards to the aquatic
environment
Category 3

Hazard Symbol:
Label Elements

MERACRYL MMA —

Version: 2.3
Issue Date: 03/25/2019
Last revised date: 09/09/2020
Supersedes Date: 08/28/2020

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Signal Word: Danger

Hazard Statement: Highly flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
Harmful to aquatic life.

Precautionary
Statements

Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep
container tightly closed. Ground and bond container and receiving
equipment. Use explosion-proof [electrical/ventilating/lighting/ ] equipment.
Use non-sparking tools. Take precautionary measures against static
discharge. Avoid breathing dust/fume/gas/mist/vapors/spray. Wash
thoroughly after handling. Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Avoid release to the environment. Wear protective gloves/eye
protection/face protection.

Response: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water [or shower]. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER/doctor if you feel
unwell. If skin irritation or rash occurs: Get medical advice/attention. Take off
contaminated clothing and wash it before reuse. In case of fire: Use water
spray, alcohol-resistant foam, dry chemical or carbon dioxide to extinguish.

Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked
up.

Disposal: Dispose of contents/ container to an approved waste disposal plant.

Hazard(s) not otherwise
classified (HNOC):
None.

3. Composition/information on ingredients

Chemical name:
Methylmethacrylate

Substances

Chemical Identity
Common
name and
synonyms
CAS number
Content in percent
(%)*
methyl methacrylate
methyl 2-
methylprop-2-
enoate
80-62-6
>99.9%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

MERACRYL MMA —

Version: 2.3
Issue Date: 03/25/2019
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Composition Comments: MMA10, MMA25, MMA40, MMA50 methyl methacrylate

The exact concentration has been withheld as a trade secret.

4. First-aid measures

Description of necessary first-aid measures

General information: First aider needs to protect himself. Take off all contaminated clothing
immediately. Medical treatment is necessary if symptoms occur which are
obviously caused by skin or eye contact with the product or by inhalation of
its vapours.

Inhalation: If inhaled, remove to fresh air. If breathing is difficult, get medical
attention.

Skin Contact: In case of contact, immediately flush skin with soap and plenty of
water. Remove contaminated clothing and shoes. Get immediate
medical advice/attention. Wash clothing before reuse. Destroy or
thoroughly clean contaminated shoes.

Eye contact: In case of contact, immediately flush eyes with plenty of water. Get
immediate medical advice/attention.

Ingestion: If swallowed, DO NOT induce vomiting unless directed to do so by
medical personnel. Get immediate medical advice/attention. Never
give anything by mouth to an unconscious person.

Personal Protection for First-
aid Responders:
As in any fire, wear self-contained breathing apparatus pressure-
demand, MSHA/NIOSH (approved or equivalent) and full protective
gear., Containers can build up pressure if exposed to heat (fire)., Cool
with water spray.

Most important symptoms/effects, acute and delayed

Symptoms: Headache. confusion Causes skin and eye irritation.
Sensitization Nausea Dermatitis May cause irritations of the
respiratory tract. Inhalation can lead to irritation of the mucous
membrane.

Hazards: May cause sensitization by skin contact.

Indication of immediate medical attention and special treatment needed

Treatment: Treat symptomatically.

5. Fire-fighting measures

General Fire Hazards: Flammable liquid. Vapors can travel to a source of ignition and flash back.
Explosive mixtures may occur at temperatures at or above the flashpoint.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing
media:
Extinguish with foam, carbon dioxide or dry powder.

MERACRYL MMA —

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Unsuitable extinguishing
media:
High volume water jet

Specific hazards arising from
the chemical:
May be released in case of fire: carbon monoxide, carbon dioxide, organic
products of decomposition.

Special protective equipment and precautions for firefighters

Special fire fighting
procedures:
Keep away from sources of ignition – No smoking. Take action to prevent
static discharges. In the event of fire, cool the endangered containers with
water. When heated above the flash point and/or during spraying
(atomizing), ignitible mixtures may form in air. Use only explosion-proof
equipment. Vapours are heavier than air and may spread along floors.

Special protective equipment
for fire-fighters:
As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear. Containers
can build up pressure if exposed to heat (fire). Cool with water spray.

6. Accidental release measures

Personal precautions,
protective equipment and
emergency procedures:
Assure sufficient ventilation. Use personal protective clothing. Keep away
sources of ignition. Use breathing apparatus if exposed to
vapours/dust/mist/aerosol.

Methods and material for
containment and cleaning
up:
Larger quantities: Remove mechanically (by pumping). Use explosion-proof
equipment! Smaller quantities and/or residues: Contain with absorbent
material (e.g. sand, diatomaceous earth, acid absorbent, universal
absorbent or sawdust). Dispose of in accordance with regulations.

Environmental Precautions: Prevent product from getting into drains/surface water/groundwater.

7. Handling and storage

Handling

Technical measures (e.g. Local
and general ventilation):
Use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels below recommended exposure limits. Use
explosion-proof ventilation equipment.

MERACRYL MMA —

Version: 2.3
Issue Date: 03/25/2019
Last revised date: 09/09/2020
Supersedes Date: 08/28/2020

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Safe handling advice: Do not breathe vapors. Avoid contact with skin and eyes. Do not eat, drink
or smoke during use.Keep away from sources of ignition – No smoking.
Take action to prevent static discharges. In the event of fire, cool the
endangered containers with water. When heated above the flash point
and/or during spraying (atomizing), ignitible mixtures may form in air. Use
only explosion-proof equipment. Vapours are heavier than air and may
spread along floors.Keep away from heat. Keep away from sparks, flames
and other sources of ignition. Avoid contact with eyes, skin, and clothing.
Wash thoroughly after handling. Avoid breathing mist or vapor. Use only
with adequate ventilation. The need for grounding and bonding of
containers in accordance with OSHA 29 CFR 1910.106 and NFPA 77
should be assessed for all product transfers. Container hazardous when
empty. Follow all SDS/label precautions even after the container is emptied.
Emptied container retains vapor and product residue. Residual vapors
might explode on ignition; do not apply heat, cut, drill, grind or weld on or
near this container. Provide good room ventilation even at ground level
(vapours are heavier than air).A safety shower and eye wash fountain
should be readily available. To identify additional Personal Protective
Equipment (PPE) requirements, it is recommended that a hazard
assessment in accordance with the OSHA PPE Standard
(29CFR1910.132) be conducted before using this product.

Contact avoidance measures: No data available.

Hygiene measures: Store work clothing separately. Take off all contaminated clothing
immediately. Follow the usual good standards of occupational hygiene.
Clean skin thoroughly after work; apply skin cream.

Storage

Safe storage conditions: Improper disposal or re-use of this container may be dangerous and
illegal.Keep in the original container at a temperature not exceeding 30 C
(86 F). Fill the container by approximately 90 % as oxygen (air) is required
for stabilisation. With large storage containers make sure the oxygen (air)
supply is sufficient to ensure stability. Store in a cool, dry place. Keep
container closed. Can polymerize with intense heat release. Protect from
the action of light.

Safe packaging materials: No data available.

Storage Temperature: No data available.

8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source
methyl methacrylate REL 100 ppm 410 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards, as amended (2010)

TWA 50 ppm US. ACGIH Threshold Limit Values, as
amended (03 2016)

STEL 100 ppm US. ACGIH Threshold Limit Values, as
amended (03 2016)

PEL 100 ppm 410 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000), as
amended (03 2016)

IDLH 1,000 ppm US. NIOSH. Immediately Dangerous to Life or
Health (IDLH) Values, as amended (10 2017)

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TWA 100 ppm 410 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000),
as amended (1989)

TWA 100 ppm 410 mg/m3 US. Tennessee. OELs. Occupational Exposure
Limits, Table Z1A, as amended (06 2008)

AN ESL 50 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality), as
amended (06 2018)

ST ESL 210 ppb US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality), as
amended (06 2018)

AN ESL 210 g/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality), as
amended (06 2018)

ST ESL 860 g/m3 US. Texas. Effects Screening Levels (Texas
Commission on Environmental Quality), as
amended (06 2018)

TWA PEL 50 ppm 205 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants, as
amended (01 2015)

STEL 100 ppm 410 mg/m3 US. California Code of Regulations, Title 8,
Section 5155. Airborne Contaminants, as
amended (01 2015)

Appropriate Engineering
Controls
Use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels below recommended exposure limits. Use
explosion-proof ventilation equipment.

Individual protection measures, such as personal protective equipment

Eye/face protection: Use safety glasses (ANSI Z87.1 or approved equivalent).

Skin Protection
Hand Protection: Material: butyl rubber gloves (minimal thickness 0.3 mm)
Break-through time: 60 min
Guideline: EN 374
Additional Information: The above mentioned hand protection is based on
special knowledge of the chemical and the intended handling of this
product, however, it still may not be suited for all workplaces. A qualified
hazard assessment should be made prior to the onset of work in order to
determine the suitability of gloves for specific working environments and
processes., Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the gloves. Also
take into consideration the specific local conditions under which the product
is used, such as the danger of cuts, abrasion, and the contact time., Gloves
should be discarded and replaced if there is any indication of degradation
or chemical breakthrough.Additional Information: nitrile rubber gloves,
Suitable as spray protection.

Skin and Body Protection: On handling of larger quantities: face mask, chemical-resistant boots and
apron

Respiratory Protection: A respiratory protection program that meets OSHA 1910.134 and ANSI
Z88.2 or applicable federal/provincial requirements must be followed
whenever workplace conditions warrant respirator use. NIOSH’s
“Respirator Decision Logic” may be useful in determining the suitability of
various types of respirators.

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Hygiene measures: Store work clothing separately. Take off all contaminated clothing
immediately. Follow the usual good standards of occupational hygiene.
Clean skin thoroughly after work; apply skin cream.

9. Physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
Color: Colorless
Odor: ester-like
Odor Threshold: 0.05 – 0.34 ppm
pH: Not applicable
Freezing point: -48 C -54.4 F
Boiling Point: 100.3 C 212.5 F (1,013 hPa)
Flash Point: 10 C (DIN 51755) 50 F (DIN 51755 / Abel Pensky
Closed Cup)
Evaporation Rate: 3.1 (butyl acetate = 1)
Flammability (solid, gas): Not applicable
Explosive limit – upper: 12.5 %(V)
Explosive limit – lower: 2.1 %(V) at 10,5 C / 33,8 F
Vapor pressure: 37 hPa (20 C)
Relative vapor density: approx. 3.5 20 C 68 F
Density: 0.94 g/cm3 (20 C) (68 F)
Relative density: No data available.
Solubility in Water: 15.3 g/l (20 C)
Solubility (other): miscible with most organic solvents
No data available.
Partition coefficient (n-octanol/water): 1.38 (Measured)
Self Ignition Temperature: 435 C (DIN 51 794) Auto Ignition Temperature 815.00 F
The substance or mixture is not classified as pyrophoric.
Decomposition Temperature: This product is stable under normal storage conditions.
Kinematic viscosity: No data available.
Dynamic viscosity: 0.53 mPa.s (20 C, Brookfield) | (68 F)

Other information
Explosive properties: No data available.
Oxidizing properties: No data available.

10. Stability and reactivity

Reactivity: see section “Possibility of hazardous reactions”

Chemical Stability: This product is stable under normal storage conditions.

Possibility of hazardous
reactions:
Polymerization with heat evolution may occur in the presence of radical
forming substances (e.g. peroxides), reducing substances, and/or heavy
metal ions.

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Conditions to avoid: Keep away from heat and sources of ignition. Protect from the action of
light. The product is normally supplied in a stabilized form. If the permissible
storage period and/or storage temperature is exceeded, the product may
polymerize with heat evolution.

Incompatible Materials: Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing
agents and oxidizing agents. Mineral Acid Free radical initiators.

Hazardous Decomposition
Products:
None when used as directed.

11. Toxicological information

General information: The substance is rapidly metabolized

Information on likely routes of exposure
Inhalation: Relevant route of exposure. Information on effects are given below.

Skin Contact: Relevant route of exposure. Information on effects are given below.

Eye contact: Relevant route of exposure. Information on effects are given below.

Ingestion: If handled correctly, not a relevant route of exposure. Information on effects
are given below.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation: Respiratory tract irritation. Drowsiness, dizziness, disorientation, vertigo.

Skin Contact: Prolonged or repeated contact may cause skin sensitization in susceptible
individuals.

Eye contact: Eye may become red, tear, and become painful.

Ingestion: If handled correctly, not a relevant route of exposure. Information on effects
are given below.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product: LD 50 (Rat): > 5,000 mg/kg

Dermal
Product: LD 50 (Rabbit): > 5,000 mg/kg

Inhalation
Product: LC 50 (Rat): 29.8 mg/l Vapour

Repeated dose toxicity
Product: NOAEL (Rat, Inhalativ, 2 years): 25 ppm Findings: Damage to mucous
membranes in the nose at 400 ppm
NOAEL (Rat, drinking water, 2 years): 2000 ppm Findings: no toxic effects

Skin Corrosion/Irritation

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Product: Skin irritant Category 2 (UN-GHS)
(Rabbit): Not irritating
If contact with skin is prolonged and/or frequent, irritations cannot be
excluded.

Serious Eye Damage/Eye Irritation
Product: Rabbit: Not irritating

Respiratory or Skin Sensitization
Product: Skin Sensitisation Category 1B (UN-GHS)
Local Lymph Node Assay (LLNA), OECD TG 429 (Mouse): Sensitising (own
study)

Carcinogenicity
Product: Not classified Non-carcinogenic in inhalation and feeding studies carried out
on rats, mice and dogs. No component of this product present at levels
greater than or equal to 0.1% is identified as a known or anticipated
carcinogen by NTP, IARC, or OSHA.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:
No carcinogens present or none present in regulated quantities

US. National Toxicology Program (NTP) Report on Carcinogens:
No carcinogens present or none present in regulated quantities

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050), as amended:
No carcinogens present or none present in regulated quantities

Germ Cell Mutagenicity

In vitro
Product: gene mutation (OECD 471): negative
gene mutation (OECD 476): positive (in the cytotoxic concentration range)
gene mutation (OECD 476): slightly positive
gene mutation (OECD 476): slightly positive
Chromosomal aberration (OECD 473): positive
Based on available data, the classification criteria are not met.

In vivo
Product: gene mutation (Dominant lethal test) Inhalativ (Mouse): negative
no evidence of mutagenic effects

Reproductive toxicity
Product: Not classified No indications of toxic effects were observed in reproduction
studies in animals. OECD 414 OECD 416

Specific Target Organ Toxicity – Single Exposure
Product: Respiratory tract irritation.
Specific target organ toxicity single exposure Category 3 (UN-GHS)

Specific Target Organ Toxicity – Repeated Exposure
Product: Based on available data, the classification criteria are not met.

Aspiration Hazard
Product: No aspiration toxicity classification

Other effects: Avoid contact with the skin and eyes and inhalation of the product vapours.

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12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish
Product: LC 50 (96 h): > 100 mg/l Expert judgement

Aquatic Invertebrates
Product: EC 50 (Daphnia magna (Water flea), 48 h): 69 mg/l

Chronic hazards to the aquatic environment:

Fish
Product: NOEC (Danio rerio (zebra fish)): 9.4 mg/l

Aquatic Invertebrates
Product: NOEC (Daphnia magna (Water flea), 21 d): 37 mg/l

Toxicity to Aquatic Plants
Product: EC 50 (Selenastrum capricornutum (green algae), 72 h): > 100 mg/l
NOEC (Selenastrum capricornutum (green algae), 72 h): > 110 mg/l

Persistence and Degradability

Biodegradation
Product: 94 % (14 d, OECD 301 C)

BOD/COD Ratio
Product: No data available.

Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: Accumulation in organisms is not expected due to the coefficient of
distribution of n-octanol in water (log Pow).

Partition Coefficient n-octanol / water (log Kow)
Product: Log Kow: 1.38 (Measured)

Mobility in soil: Binding to the solid soil phase, sediment or clarification sludge is not
expected. The substance evaporates gradually into the atmosphere from the
surface of the water. If the substance does get into the environment, it tends
to remain in the compartment it was discharged into.

Other adverse effects: Prevent substance from entering soil, natural bodies of water and sewer
systems. Photochemical degradation (air) takes place.

13. Disposal considerations

General information: Dispose of waste and residues in accordance with local authority
requirements.

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Disposal methods: Waste must be disposed of in accordance with federal, state and local
regulations. Roehm encourages the recycle, recovery and reuse of
materials, where permitted, as an alternate to disposal as a waste.

Contaminated Packaging: Empty containers must be handled with care due to product residue. DO
NOT HEAT OR CUT THE EMPTY CONTAINER WITH ELECTRIC OR GAS
TORCH.

14. Transport information

Domestic regulation
49 CFR
UN/ID/NA number : UN 1247
Proper shipping name : Methyl methacrylate monomer, stabilized

Class : 3
Packing group : II
Labels : 3
ERG Code : 129P
Marine pollutant : no
Remarks : FOR USA ONLY: When shipping in, by or via USA note of the
Reportable Quantity-Regulation!
International Regulations
IATA-DGR
UN/ID No. : UN 1247
Proper shipping name : Methyl methacrylate monomer, stabilized
Class : 3
Packing group : II
Labels : 3
Packing instruction (cargo
aircraft)
: 364
Packing instruction
(passenger aircraft)
: 353
Remarks : FOR USA ONLY: When shipping in, by or via USA note of the
Reportable Quantity-Regulation!
IMDG-Code
UN number : UN 1247
Proper shipping name : METHYL METHACRYLATE MONOMER, STABILIZED

Class : 3
Packing group : II
Labels : 3
EmS Code : F-E, S-D
Marine pollutant : no
Remarks : Clear of living quarters., FOR USA ONLY: When shipping in,
by or via USA note of the Reportable Quantity-Regulation!,
Protected from sources of heat.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based upon the
properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation
classifications may vary by mode of transportation, package sizes, and variations in regional or country
regulations.

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15. Regulatory information

US Federal Regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
None present or none present in regulated quantities.

US. Toxic Substances Control Act (TSCA) Section 5(a)(2) Final Significant New Use Rules (SNURs) (40
CFR 721, Subpt E)
None present or none present in regulated quantities.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050), as amended
None present or none present in regulated quantities.

CERCLA Hazardous Substance List (40 CFR 302.4):
Chemical Identity
2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
Flammable (gases, aerosols, liquids, or solids), Skin Corrosion or Irritation, Specific target organ
toxicity (single or repeated exposure)

US. EPCRA (SARA Title III) Section 304 Extremely Hazardous Substances Reporting Quantities and the
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Hazardous
Substances

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313
Toxic Chemicals (40 CFR 372.65) – Supplier Notification Required
Chemical Identity % by weight
methyl methacrylate 1.0%1.0%

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
None present or none present in regulated quantities.

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
None present or none present in regulated quantities.

US State Regulations

US. California Proposition 65
No ingredient requiring a warning under CA Prop 65.

US. New Jersey Worker and Community Right-to-Know Act
Chemical Identity
methyl methacrylate

US. Massachusetts RTK – Substance List
Chemical Identity
methyl methacrylate

US. Pennsylvania RTK – Hazardous Substances
Chemical Identity
methyl methacrylate

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US. Rhode Island RTK
Chemical Identity
methyl methacrylate

16.Other information, including date of preparation or last revision

HMIS Hazard ID

Health 2
Flammability 3
Physical Hazards 2

PERSONAL PROTECTION B
Hazard rating: 0 – Minimal; 1 – Slight; 2 – Moderate; 3 – Serious; 4 – Severe; RNP – Rating not
possible; *Chronic health effect

NFPA Hazard ID

Flammability

Health
Reactivity
Special hazard.
Hazard rating: 0 – Minimal; 1 – Slight; 2 – Moderate; 3 – Serious; 4 – Severe; RNP – Rating not possible

Issue Date: 09/09/2020

Version #: 2.3

Source of information:
relevant manuals and publications
own examinations
own toxicological and ecotoxicological studies
toxicological and ecotoxicological studies of other manufacturers
SIAR
OECD-SIDS
RTK public files

Further Information: The product is normally supplied in a stabilized form. If the permissible
storage period and/or storage temperature is exceeded, the product may
polymerize with heat evolution.

Revision Information Changes since the last version are highlighted in the margin. This version
replaces all previous versions.

B – Safety Glasses & Gloves
3

2

2

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Disclaimer: This information and any recommendations, technical or otherwise, are
presented in good faith and believed to be correct as of the date prepared.
Recipients of this information and recommendations must make their own
determination as to its suitability for their purposes. In no event shall ROEHM
assume liability for damages or losses of any kind or nature that result from
the use of or reliance upon this information and recommendations. ROEHM
EXPRESSLY DISCLAIMS ANY REPRESENTATIONS AND WARRANTIES
OF ANY KIND, WHETHER EXPRESS OR IMPLIED, AS TO THE
ACCURACY, COMPLETENESS, NON -INFRINGEMENT,
MERCHANTABILITY AND/OR FITNESS FOR A PARTICULAR PURPOSE
(EVEN IF ROEHM IS AWARE OF SUCH PURPOSE) WITH RESPECT TO
ANY INFORMATION AND RECOMMENDATIONS PROVIDED. Reference to
any trade names used by other companies is neither a recommendation nor
an endorsement of the corresponding product, and does not imply that similar
products could not be used. ROEHM reserves the right to make any changes
to the information and/or recommendations at any time, without prior or
subsequent notice.

Please ensure that this SDS is given to, and explained to people using this product.
Safety Data Sheet
1. PRODUCT IDENTIFICATION
Name Methyl Methacrylate
Synonyms methyl 2-methyl-2-propenoate; 2-methyl propenoic acid, methyl ester; methyl-alpha-methyl acrylate;
MMA; methyacrylic acid, methyl ester & others
CAS# 80
-62-6
Europe EC# 201
-297-1
Product Uses monomer for manufacture of acrylic plastics & coating resins
In an Emergency:

U.S.A. Call CHEMTREC
(800) 262-8200
2. HAZARDS
GHS Class flammable skin irritant eye irritant sensitizer STOT
(Category)
(2) (2) (2B) (1) (3)
Signal Words DANGER WARNING WARNING WARNING WARNING
no Pictogram
Hazard Statements highly flammable causes skin causes eye causes skin may cause
liquid & vapour irritation irritation sensitization respiratory tract
(H225) (H315) (H320) (H317) irritation (H335)
Canada WHMIS B 2, D 2B
Key: B 2 Flash Point <38 o C, B 3 Flash Point >38
o
C & <93 o C D 1 Immediately Toxic, D 2 Chronic Toxicity C Oxidising Substance, E - Corrosive 3. COMPOSITION % TWAEV / TLV ppm / mg/m 3 LD50 (mg/kg) ORAL LD50 (mg/kg) SKIN LC50 ppm INHALATION Methyl 2-Methyl-2-Propenoate 100% 50 / 205 3625 >5000 3205
4
. FIRST AID
SKIN: Wash with plenty of water. Remove contaminated clothing and do not reuse until laundered.
EYES: Wash eyes with plenty of water, holding eyelids open. Seek medical assistance promptly if there is irritation.
INHALATION: Remove from contaminated area promptly. CAUTION: Rescuer must not endanger himself! If breathing
stops, administer artificial respiration and seek medical aid promptly.
INGESTION: Give plenty of water to dilute product. Do not induce vomiting (NOTE below). Keep victim quiet. If vomiting
occurs, lower victim s head below hips to prevent inhalation of vomited material. Seek medical help promptly.
Inadvertent inhalation of vomited material may seriously damage the lungs. The danger of this is greater than the risk of poisoning through absorption of this
relatively low-toxicity substance. The stomach should only be emptied under medical supervision, and after the installation of an airway to protect the lungs.

Product Name: Methyl Methacrylate
Please ensure that this SDS is given to, and explained to people using this product.
2
5
FLAMMABILITY & FIRE FIGHTING
Flash Point 2
o
C / 36
o
F (closed cup); 10
o
C / 50
o
F (open cup)
Autoignition Temperature 435
o
C / 815
o
F
Flammable Limits 1.7% 8.2%
Combustion Products carbon monoxide, nitrogen oxides, smoke, part oxidised hydrocarbon fragments
Firefighting Precautions alcohol or polymer foam, dry chemical, water fog or spray, product floats on
water; firefighters must wear SCBA
Static Charge Accumulation probably not a static accumulator esters tend to have high electric conductivity
6
. SPILL PROCEDURES
Very Serious Fire Potential: blanket spill with foam as a precaution against accidental ignition. Take extreme
care to avoid sparks do not operate (turn on OR off) electrical appliances near spill, unless explosion proof.
Leak Precaution dyke to control spillage and prevent environmental contamination
Handling Spill ventilate contaminated area; recover free liquid with suitable pumps; absorb residue on an inert sorbent,
sweep & pick up using plastic or aluminium shovel, & store in closed containers for recycling or disposal
7
. HANDLING & STORAGE
Store no longer than 6 months below 25
o
C, & away from substances named in Part 10.
Take extreme care to avoid
sparks. Use only non-sparking bronze or aluminium hand tools. All electrical and mechanical equipment (including lighting,
switchgear & forklift trucks) used with or around this product must be explosion-proof. Although this product cannot retain a
static charge on agitation or transfer from one container to another, its flash point is low & it is prudent to ground or electrically
bond the source container, receiving container, & transfer pump before transferring contents. Avoid splashing by ensuring the
product nozzle is below the surface in the receiving container.
Never use compressed air to transfer this product. Pressurised air with ~8% oxygen can be used to transfer product
(consult the safe handling manuals below)
If stored over one month, check titre of inhibitor (hydroquinone 100-200ppm is often used). Replenish as necessary. The
inhibitor requires oxygen to work properly! Never store the product under nitrogen!
Avoid breathing product vapour. Use with adequate ventilation. If dealing with a spill, and ventilation is impossible or
impractical, wear a suitable respirator with an organic vapour cartridge. If the spill is extensive, wear an air-supplied respirator.
Never cut, drill, weld or grind on or near this container. Empty containers may contain a flammable vapour! Avoid
contact with skin and wash work clothes frequently. An eye bath and safety shower must be available near the workplace.
For detailed safety information, please consult the Safe Handling Manuals, references numbers 1 & 2 at the end of this document.
8. EXPOSURE CONTROL
Ontario TWAEV 50
ppm / 205 mg/m
3
Ontario STEV 100 ppm / 409mg/m
3
ACGIH TLV 50
ppm / 205 mg/m
3
ACGIH STEL 100 ppm / 409mg/m
3

OSHA PEL 100
ppm / 410mg/m
3
OSHA STEL not listed
Ventilation mechanical ventilation may be needed to control airborne titre to regulated limits Hands Tychem or Responder gloves others may also protect; consult supplier to confirm suitability
Eyes safety glasses with side shields always protect the eyes
Clothing wear impermeable (above) apron, boots, & long sleeves if there is any danger of splashing,

Product Name: Methyl Methacrylate
Please ensure that this SDS is given to, and explained to people using this product.
3
9
. PHYSICAL PROPERTIES
Odour & Appearance clear, colourless liquid with fruity but pungent, acrid odour
Odour Threshold 0.05ppm (detection, not recognition)
Vapour Pressure 29mmHg / 3.9kPa (20
o
C / 68
o
F)
Evaporation Rate (Butyl Acetate=1) 3.1
Vapour Density (air = 1) 3.5
Boiling Range 100
-101
o
C / 212-214
o
F
Freezing Point -48
o
C / -54
o
F
Specific Gravity 0.944 (20/20
o
C)
Water Solubility 15 grams per litre (20
o
C / 68
o
F)
Also soluble in most organic solvents, limited solubility in glycols and methanol
Log Po/w (Octanol/H
2O partition) 1.38
Viscosity 0.6centipoise (20
o
C / 68
o
F) thin mobile liquid
pH none (does not liberate hydrogen ions when dissolved)
Conversion Factor 1ppm = 4.09mg/m
3

Molecular Weight 100grams per mole
10. STABILITY / REACTIVITY
Dangerously Reactive With strong oxidising agents, alkalies, acids; azo-compounds, catalytic metals (copper or iron),
reducing agents, amines, halogens & propionaldehyde can cause dangerous, rapid polymerisation
Also Reactive With none known
Stability stable in presence of inhibitor; NOTE: methyl methacrylate vapour is inhibitor-free & prone
to polymerise in storage tank vents; vapour may also polymerize dangerously
Decomposes in Presence of sunlight, ultraviolet light, ionising radiation may decompose or cause polymerisation
Decomposition Products auto-oxidation in air may form explosive polyperoxides
Sensitive to Mechanical Impact no
11 TOXICITY
Effects, Acute Exposure
Skin Contact moderate irritant
Skin Absorption slight; no toxic effects likely by this route Eye Contact moderate irritant
Inhalation irritating above 170ppm; may cause headache, dizziness, drowsiness, intoxication, shortness of breath, chest pain, pulmonary oedema, eventual collapse
Ingestion probably irritating to mouth, throat & stomach; may cause headache, dizziness, drowsiness, intoxication not a route of industrial exposure
LD50 (oral) 79
00-9400mg/kg (rat, several tests), 3625 & 5300mg/kg (mouse), 5955mg/kg (guinea pig),
6000 & 8700mg/kg (rabbit), 4725mg/kg (dog)
LD50 (skin) >5000 & >7550mg/kg (rabbit)
LC50 (inhalation) 7090 & 19,000ppm (rat), 3205 & 4500ppm (mouse)
Effects, Chronic Exposure
General pulmonary & neurotoxic effects are proven; (the following observations unconfirmed): coughing &
mild chronic obstructive pulmonary disease; persistent headaches, dizzyness
Sensitising skin sensitiser in humans; not a respiratory sensitiser
Carcinogen/Tumorigen not considered a tumorigen or a carcinogen in humans or animals Reproductive Effect no known effect in humans or animals Mutagen no known effect on humans or animals
Synergistic With not known

Product Name: Methyl Methacrylate
Please ensure that this SDS is given to, and explained to people using this product.
4
12. ENVIRONMENTAL INFORMATION
Bioaccumulation rapidly metabolised and is not a bioaccumulator
Biodegradation biodegrades readily & rapidly in the presence of oxygen; >90% in 2 weeks, other tests show slower but
still rapid rates of biodegradation (eg: 88-95% in 20-28 days, 32% in 28 days, 68% in 30 days & others)
Abiotic Degradation reacts with atmospheric hydroxyl radicals; estimated -life in air is 2.7hr (clean air) 3hr (urban air)
Mobility in soil, water sufficiently water soluble to move readily in soil & water
Aquatic Toxicity
LC50 (Fish, 96hr) 191 & 232-357mg/litre (Lepomis macrochirus), >79mg/litre (Oncorhynchus mykiss),
277mg/litre (Carcassius auratus), 368mg/litre (Lebistes retilculatus & Poecilia reticulata),
130
-460mg/litre (Pimephelas promelas) & others
EC50 (Crustacea, 48hr) 69
mg/litre (Daphnia magna); 720 % 1750mg/litre (Dapnia magna 24hr)
EC50 (Algae) 170mg/litre (Selenastrum capricornutum)
EC3 (Algae) 120mg/litre (Microcystis aeruginosa), 37mg/litre (Scenedesmus quadricauda)
EC3 (Bacteria) 178mg/litre (Chilomonas paramecium), 72 & 450mg/litre (Entosiphon sulcatum),
100mg/litre (Pseudomonas putida), 556mg/litre (Urenoma parduzci)
EC20 (Bacteria) >1000mg/litre ( other bacteria )
13. DISPOSAL
Waste Disposal do not flush to sewer,
incinerate in approved facility with flue gas monitoring & scrubbing
Containers Drums should be reused. Recondition and pressure test by a licensed reconditioner prior to re-use.
Pails must be vented and thoroughly dried prior to crushing and recycling.
IBCs (intermediate bulk containers): polyethylene bottle must be pressure tested & recertified at 30 months.
Replace at 60 months (5yrs). Steel containers must be inspected, pressure tested & recertified every 5 years.
Never cut, drill, weld or grind on or near this container, even if empty
1
4. TRANSPORT
Canada TDG PIN UN – 1247
AND Shipping Name methyl methacrylate monomer, stabilised
U.S.A. 49 CFR Class & Packing Group 3 (II)
Marine Pollutant not a marine pollutant
ERAP Required NO
15. REGULATIONS
Canada DSL on inventory
U.S.A. TSCA on inventory
Europe EINECS on inventory
This common substance is present on most national chemical inventories.

Product Name: Methyl Methacrylate
Please ensure that this SDS is given to, and explained to people using this product.
5
15. REGULATIONS, cont d
U.S.A. Regulations:
Immediately Dangerous to Life or Health: 1000 ppm
Acceptable Daily Intakes: an acceptable daily intake of 0.1 mg/kg/day was calculated on basis of available chronic toxicity data.
OSHA Standards: Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 100 ppm (410 mg/cu m).
NIOSH Recommendations: Recommended Exposure Limit: 10 hr Time-Weighted avg: 100 ppm (410 mg/cu m).
Threshold Limit Values: 8 hr Time Weighted Avg (TWA): 50 ppm; 15 min Short Term Exposure Limit (STEL): 100 ppm. Sensitization. A4; Not classifiable as a human carcinogen.
Atmospheric Standards: This action promulgates standards of performance for equipment leaks of Volatile Organic Compounds (VOC) in the Synthetic Organic Chemical
Manufacturing Industry (SOCMI). The intended effect of these standards is to require all newly constructed, modified, and reconstructed SOCMI process units to use the best
demonstrated system of continuous emission reduction for equipment leaks of VOC, considering costs, non air quality health and environmental impact and energy requirements. Methyl
methacrylate is produced, as an intermediate or a final product, by process units covered under this subpart. Listed as a hazardous air pollutant (HAP) generally known or suspected to
cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA
is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Methyl methacrylate is included on
this list.
State Drinking Water Guidelines: Florida 25 ug/L
Clean Water Act Requirements: Methyl methacrylate is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further
regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply to discharges of this substance. This designation includes any isomers and hydrates, as well as any solutions and mixtures containing this substance.
CERCLA Reportable Quantities: Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this
designated hazardous substance, in an amount equal to or greater than its reportable quantity of 1000 lb or 454 kg. The toll free number of the NRC is (800) 424-8802. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV.D.3.b).
TSCA Requirements: Pursuant to section 8(d) of TSCA, EPA promulgated a model Health and Safety Data Reporting Rule. The section 8(d) model rule requires manufacturers,
importers, and processors of listed chemical substances and mixtures to submit to EPA copies and lists of unpublished health and safety studies. Methyl methacrylate is included on this list. Effective date 4/13/89; Sunset date: 6/30/98.
RCRA Requirements: As stipulated in 40 CFR 261.33, when methyl methacrylate, as a commercial chemical product or manufacturing chemical intermediate or an off-specification
commercial chemical product or a manufacturing chemical intermediate, becomes a waste, it must be managed according to Federal and/or State hazardous waste regulations. Also defined as a hazardous waste is any residue, contaminated soil, water, or other debris resulting from the cleanup of a spill, into water or on dry land, of this waste. Generators of small quantities of this waste may qualify for partial exclusion from hazardous waste regulations (40 CFR 261.5).
FDA Requirements: Homopolymers and copolymers of methyl methacrylate are an indirect food additive for use only as a component of adhesives.

39METHANOL_SDS.pdf

by | Sep 27, 2025

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 1 / 12 Methanol

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Methanol
Recommended use of the chemical and restrictions on use
Recommended use : Solvent.
Fuel
Feedstock
Manufacturer or supplier’s details
Company : Univar Solutions USA, Inc.
Address

3075 Highland Pkwy Suite 200
Downers Grove, IL 60515
United States of America (USA)
Emergency telephone number:
Transport North America: CHEMTREC (1-800-424-9300)
CHEMTREC INTERNATIONAL Tel # 703 -527-3887
Additional Information: : Responsible Party: Product Compliance Department
E-mail: SDSNA@univarsolutions.com
SDS Requests: 1-855-429-2661
Website: www.univarsolutions.com
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids

: Category 2
Acute toxicity (Oral)

: Category 3
Acute toxicity (Inhalation)

: Category 3
Acute toxicity (Dermal)

: Category 3
Eye irritation

: Category 2A
Specific target organ toxicity
– single exposure

: Category 1 (Eyes, Central nervous system)
Specific target organ toxicity
– single exposure

: Category 3 (Central nervous system)
GHS label elements
Hazard pictograms

:

Signal word

: Danger

Hazard statements

: H225 Highly flammable liquid and vapour.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or
if inhaled.
H319 Causes serious eye irritation.

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 2 / 12 Methanol

H336 May cause drowsiness or dizziness.
H370 Causes damage to organs.

Precautionary statements

: Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equip-
ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P301 + P310 + P330 IF SWALLOWED: Immediately call a
POISON CENTER/doctor. Rinse mouth.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P311 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON
CENTER/doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P307 + P311 IF exposed: Call a POISON CENTER or doctor/
physician.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Substance
Hazardous components
CAS-No. Chemical name Weight percent
67-56-1 Methanol 90 – 100

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 3 / 12 Methanol

Any Concentration shown as a range is due to batch variation.

SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled : If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact : If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact : Immediately flush eye(s) with plenty of water.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
Do not induce vomiting without medical advice.

SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during fire-
fighting
: Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion prod-
ucts

: Carbon oxides
formaldehyde
toxic fumes

Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored sepa-
rately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
: Wear self-contained breathing apparatus for firefighting if nec-
essary.
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 4 / 12 Methanol

Personal precautions, protec-
tive equipment and emer-
gency procedures

: Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentra-
tions. Vapours can accumulate in low areas.

Environmental precautions

: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

: Contain spillage, and then collect with non-combustible ab-
sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE
Advice on protection against
fire and explosion

: Do not spray on a naked flame or any incandescent material.
Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours). Use only
explosion-proof equipment. Keep away from open flames, hot
surfaces and sources of ignition.

Advice on safe handling : Avoid formation of aerosol.
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Container may be opened only under exhaust ventilation
hood.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
CAS-No. Components Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 5 / 12 Methanol

67-56-1 Methanol TWA 200 ppm ACGIH

STEL 250 ppm ACGIH

TWA 200 ppm
260 mg/m3
NIOSH REL

ST 250 ppm
325 mg/m3
NIOSH REL

TWA 200 ppm
260 mg/m3
OSHA Z-1

STEL 250 ppm
325 mg/m3
OSHA P0

TWA 200 ppm
260 mg/m3
OSHA P0
Personal protective equipment
Respiratory protection : General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are un-
known, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any hazardous
chemical is limited. Use a positive pressure air supplied respi-
rator if there is any potential for uncontrolled release, expo-
sure levels are unknown, or any other circumstance where air
purifying respirators may not provide adequate protection.
Hand protection

Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Skin and body protection : Impervious clothing
Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.
Hygiene measures : Avoid contact with skin, eyes and clothing.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and immediately after handling the
product.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Colour : Clear, Colorless
Odour : alcohol-like
Odour Threshold : 4.2 – 5960 ppm

pH : No data available

Freezing Point (Melting
point/freezing point)
: -97.8 – -97.6 C (-144.0 – -143.7 F)

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 6 / 12 Methanol

Boiling Point (Boiling
point/boiling range)
: 64.7 C (148.5 F)

Flash point : 11 C (52 F)

Evaporation rate : 4.1
(Butyl Acetate = 1)
Flammability (solid, gas) : No data available
Upper explosion limit

: 36.5 %(V)

Lower explosion limit

: 5.5 %(V)

Vapour pressure : 96.00 mmHg
Relative vapour density : 1.1 @ 20 C (68 F)
(Air = 1.0)

Relative density : 0.791 – 0.793 @ 20 C (68 F)
Reference substance: (water = 1)

Density : 0.792 g/cm3 @ 20 C (68 F)

Solubility(ies)
Water solubility : completely miscible
Solubility in other solvents : No data available
Partition coefficient: n-
octanol/water
: log Pow: 0.82

Auto-ignition temperature : 464 C
Thermal decomposition : No data available
Viscosity
Viscosity, dynamic : 0.8 mPa.s @ 25 C (77 F)

SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reac-
tions
: Vapours may form explosive mixture with air.

Conditions to avoid : Keep away from heat, flame, sparks and other ignition
sources.
Exposure to moisture
Incompatible materials : Acids
Alkali metals
Alkalis
Oxidizing agents
Reducing agents
Hazardous decomposition
products

: Carbon oxides
Formaldehyde

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 7 / 12 Methanol

SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate: 101.01 mg/kg

Acute inhalation toxicity : Acute toxicity estimate: 3.03 mg/l
Exposure time: 4 h
Test atmosphere: vapour

Acute dermal toxicity : Acute toxicity estimate: 303.03 mg/kg

Components:
67-56-1:
Acute oral toxicity : Assessment: The component/mixture is toxic after single in-
gestion.

Acute inhalation toxicity : Assessment: The component/mixture is toxic after short term
inhalation.
Remarks: Supporting toxicological evidence is limited for this
classification. This harmonized classification will replace the
indicated classification due to industry leaders and the EU
Harmonized Classification (Annex VII).

Acute dermal toxicity : Assessment: The component/mixture is toxic after single con-
tact with skin.

Carcinogenicity
IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

STOT – single exposure
Components:
67-56-1:
Target Organs: Eyes, Central nervous system
Assessment: The substance or mixture is classified as specific target organ toxicant, single ex-
posure, category 1.

Further information
Product:

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 8 / 12 Methanol

Remarks: Solvents may degrease the skin.

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available

Mobility in soil
No data available

Other adverse effects
Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone – CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological infor-
mation
: No data available

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of in accordance with all applicable local, state and
federal regulations.
For assistance with your waste management needs – including
disposal, recycling and waste stream reduction, contact Uni-
var Solutions ChemCare: 1-800-909-4897

Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14. TRANSPORT INFORMATION
DOT (Department of Transportation):
UN1230, Methanol, 3, II

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 9 / 12 Methanol

IATA (International Air Transport Association):
UN1230, Methanol, 3 (6.1), II

IMDG (International Maritime Dangerous Goods):
UN1230, METHANOL, 3, (6.1), II, Flash Point:11 C(52 F)

SECTION 15. REGULATORY INFORMATION
WHMIS Classification

: B2: Flammable liquid
D2B: Toxic Material Causing Other Toxic Effects

EPCRA – Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
Methanol 67-56-1 5000 5000
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards

: Flammable (gases, aerosols, liquids, or solids)
Acute toxicity (any route of exposure)
Specific target organ toxicity (single or repeated exposure)
Serious eye damage or eye irritation

SARA 302

: No chemicals in this material are subject to the reporting re-
quirements of SARA Title III, Section 302.

SARA 313

: The following components are subject to reporting levels es-
tablished by SARA Title III, Section 313:

67-56-1 Methanol
Clean Air Act
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
67-56-1 Methanol
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental
Release Prevention (40 CFR 68.130, Subpart F).
The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final
VOC’s (40 CFR 60.489):
67-56-1 Methanol
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section
311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311,
Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
Massachusetts Right To Know
67-56-1 Methanol

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 10 / 12 Methanol

Pennsylvania Right To Know
67-56-1 Methanol

California Prop 65
WARNING: This product can expose you to chemicals including Methanol, which is/are
known to the State of California to cause birth defects or other reproductive harm. For more in-
formation go to www.P65Warnings.ca.gov.

The components of this product are reported in the following inventories:
TSCA

: On TSCA Inventory

DSL

: All components of this product are on the Canadian DSL

AICS

: On the inventory, or in compliance with the inventory

NZIoC

: On the inventory, or in compliance with the inventory

ENCS

: On the inventory, or in compliance with the inventory

KECI

: On the inventory, or in compliance with the inventory

PHIL

: On the inventory, or in compliance with the inventory

IECSC

: On the inventory, or in compliance with the inventory

SECTION16. OTHER INFORMATION
NFPA: HMIS III:

The information accumulated is based on the data of which we are aware and is believed
to be correct as of the date hereof. Since this information may be applied under conditions
beyond our control and with which we may be unfamiliar and since data made become
available subsequently to the date hereof, we do not assume any responsibility for the
results of its use. Recipients are advised to confirm in advance of need that the information
is current, applicable, and suitable to their circumstances. This SDS has been prepared by
Univar Solutions Product Compliance Department (1-855-429-2661)
SDSNA@univarsolutions.com.
Flammability

Health

Instability

2
3

0

FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3

0

2

Special hazard.
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 =Extreme, * = Chronic

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 11 / 12 Methanol

Revision Date : 09/01/2019

Legacy SDS: : R0001447; 100000027675

Material number:
16141257, 16142280, 16134421, 16141541, 16127437, 16125772, 16121925, 145658,
16039562, 16110171, 16108079, 16002900, 16087724, 559683, 16032613, 779915,
16024445, 16018469, 736115, 730007, 730006, 717897, 716726, 713298, 710534, 695309,
694361, 689940, 690224, 682513, 638917, 625491, 602665, 554053, 554376, 554361,
554308, 554052, 554159, 546854, 117978, 132227, 118306, 116867, 161021, 130207,
130736, 159527, 160328, 115098, 115229, 143136, 508297, 501342, 20302, 22243, 20300,
20299, 500031, 16100717, 16076584, 16056428, 16056427, 16056426, 16056425, 16055184,
16053934, 16049742, 16031073, 16024444, 16021152, 16016316, 743459, 699273, 627702,
600798, 546132, 504381, 504224, 161018, 160329, 159524, 144602, 136311, 131538,
131334, 122681, 117981, 115232, 82470, 82339, 20305, 20304, 20303, 20301, 20298, 20297

Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH American Conference of Govern-
ment Industrial Hygienists
LD50 Lethal Dose 50%
AICS Australia, Inventory of Chemical
Substances
LOAEL Lowest Observed Adverse Effect
Level
DSL Canada, Domestic Substances List NFPA National Fire Protection Agency
NDSL Canada, Non-Domestic Substanc-
es List
NIOSH National Institute for Occupational
Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemi-
cals
EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
EGEST EOSCA Generic Exposure Scenar-
io Tool
OSHA Occupational Safety & Health
Administration
EOSCA European Oilfield Specialty Chem-
icals Association
PEL Permissible Exposure Limit
EINECS European Inventory of Existing
Chemical Substances
PICCS Philippines Inventory of Commer-
cial Chemical Substances
MAK Germany Maximum Concentration
Values
PRNT Presumed Not Toxic
GHS Globally Harmonized System RCRA Resource Conservation Recovery
Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act.
IARC International Agency for Research
on Cancer
TLV Threshold Limit Value
IECSC Inventory of Existing Chemical
Substances in China
TWA Time Weighted Average
ENCS Japan, Inventory of Existing and
New Chemical Substances
TSCA Toxic Substance Control Act
KECI Korea, Existing Chemical Inventory UVCB Unknown or Variable Composi-
tion, Complex Reaction Products,
and Biological Materials

Safety Data Sheet

Methanol
Version 2.7 Revision Date: 09/01/2019

SDS Number: 100000002748 12 / 12 Methanol

<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System LC50 Lethal Concentration 50%

39MEK_SDS.pdf

by | Sep 27, 2025

39MEK_SDS-8.pdf

by | Sep 27, 2025

INDEX

39IPA
39IPA
39IPA-5
39IPAD-S

SAFETY DATA SHEET
SDS Distribution: The information in this document
should be made available to all who may handle the
product.
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to
become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the Buyer’s/User’s responsibility to
ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented here pertains only to the product as shipped.
The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of
health, safety and environmental requirements only. NO warranty or guarantee is expressed or implied regarding the accuracy of this data or the results
to be obtained from the use of the product.
Isopropyl Alcohol 99%
Isopropyl Alcohol 99%
Page 1 of 8 www.aglayne.com

May 07, 2015
A. G. Layne, Inc.
Product ID :
4578 Brazil Street Los Angeles, CA, US, 90039
Product Name : Isopropyl Alcohol 99%
Manufacturer’s Name :
Revision Date :
Address :
SECTION 1) CHEMICAL PRODUCT AND SUPPLIER’S IDENTIFICATION
Isopropyl Alcohol 99%
Version: 1.0
Date Printed : May 09, 2015
Supersedes Date : N.A.
Emergency Phone :
Information Phone :
Chemtrec-800-424-9300/703-527-3887
323-245-2345, 8am-5pm PST
Fax :
Product/Recommended Uses: Paints and coatings, inks, cleaning solution and a variety of other applications.
SECTION 2) HAZARDS IDENTIFICATION
Classification:
Specific Target Organ Toxicity -Single Exposure (Narcotic Effects) – Category 3
Skin Irritation – Category 3
Eye Irritation – Category 2A
Flammable Liquids Category 2
Acute toxicity Oral Category 5
Pictograms:
Signal Word:
Danger
Hazardous Statements – Physical:
Highly flammable liquid and vapor
Hazardous Statements – Health:
May cause drowsiness or dizziness
Maybe harmful if swallowed
Causes mild skin irritation
Causes serious eye irritation
Precautionary Statements – General:
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Precautionary Statements – Prevention:
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take action to prevent static discharges.
Wear protective gloves/protective clothing/eye protection/face protection.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wash with soap and water thoroughly after handling.
Isopropyl Alcohol 99%
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Precautionary Statements – Response:
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse with water or shower.
In case of fire: Use DRY chemical, alcohol- resistant foam, water spray/fog or carbon-dioxide to extinguish.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
If skin irritation occurs: Get medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Precautionary Statements – Storage:
Keep cool.
Store in a well-ventilated place.
Store in a well-ventilated place. Store locked up.
Precautionary Statements – Disposal:
Dispose of contents/container to disposal recycling center.
Waste management should be in full compliance with federal, state and local laws.
SECTION 4) FIRST-AID MEASURES
Inhalation:
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If victim is not breathing, call 911 and
administer CPR as directed.
Eliminate all ignition sources if safe to do so.
Skin Contact:
Rinse/wash with lukewarm, gently flowing water (and mild soap) for 15-20 minutes or until product is removed. If skin irritation occurs or
you feel unwell: Get medical advice/attention.
Eye Contact:
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for 15-20 minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. Take care not to rinse contaminated
water into the unaffected eye or onto the face. Get immidiate medical attention.
Ingestion:
Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery position. Immediately call 911 POISON
CENTER/doctor/. Immediately transport to the nearest medical facility for treatment.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
Dry chemical, foam, carbon dioxide or fog is recommended. Water spray is recommended to cool or protect exposed materials or
structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of
foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media:
No data available.
Specific Hazards in Case of Fire:
No data available.
Fire-fighting Procedures:
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions:
% by Weight CAS Chemical Name
SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS
0000067-63-0 ISOPROPYL ALCOHOL 100%
Isopropyl Alcohol 99%
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Wear protective pressure self-contained breathing apparatus (SCBA) and full turnout gear.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
RELEASE CAN CAUSE FIRE/EXPLOSION. LIQUIDS/VAPORS MAY IGNITE.
Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities
if any exposure to the general public or the environment occurs or is likely to occur.
If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment:
Positive pressure, full-facepiece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape SCBA
(NIOSH approved).
Personal Precautions:
Avoid breathing vapor. Avoid contact with skin, eye or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in
immediate area). Use explosive proof equipment. Avoid inhalation of dust and contact with skin and eyes. Do not touch damaged
containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions:
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems
and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up:
Sand, clay and absorbent socks can be used to contain a spill.
SECTION 7) HANDLING AND STORAGE
General:
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements:
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements:
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
Electrostatic charges may be generated during pumping. Keep away from aerosols, flammables, oxidizing agents, corrosives and from
other flammable products.
SECTION 8) EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers.
Select a filter suitable for organic gases and vapors meeting EN371.
Skin Protection:
Isopropyl Alcohol 99%
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Chemical Name OSHA
TWA
(ppm)
OSHA
TWA
(mg/m3)
OSHA
STEL
(ppm)
OSHA
STEL
(mg/m3)
OSHA-
Tables-
Z1,2,3

OSHA
Carcinogen
OSHA
Skin
designation
NIOSH
TWA
(ppm)
NIOSH
TWA
(mg/m3)
NIOSH
STEL
(ppm)
NIOSH
STEL
(mg/m3)

NIOSH
Carcinogen
ISOPROPYL
ALCOHOL
400 980 1 400 980 500 1225
Chemical Name ACGIH
TWA
(ppm)
ACGIH
TWA
(mg/m3)
ACGIH
STEL
(ppm)
ACGIH
STEL
(mg/m3)

ACGIH
Carcinogen

ACGIH
Notations

ACGIH
TLV Basis
ISOPROPYL
ALCOHOL
200 400 A4 A4;BEI Eye &
URT irr;
CNS impair
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene
or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced.
Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin
sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at
the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.
Eye Protection:
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear liquid
Odor Threshold N/A
Odor Description Characteristic
pH N/A
Water Solubility N/A
Flammability Flashpoint below 73 F
Flash Point Symbol F
Flash Point 57 F
Viscosity N/A
Lower Explosion Level N/A
Upper Explosion Level N/A
Vapor Pressure N/A
Vapor Density N/A
Freezing Point N/A
Melting Point N/A
Low Boiling Point N/A
High Boiling Point N/A
Auto Ignition Temp 750 F
Decomposition Pt N/A
Evaporation Rate N/A
Physical and Chemical Properties
Density 6.60 lb/gal
% Solids By Weight 0.00%
Density VOC 6.60 lb/gal
% VOC 100.00%
VOC Actual 6.60 lb/gal
Specific Gravity 0.79
Isopropyl Alcohol 99%
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Coefficient Water/Oil N/A
VOC Composite Partial Pressure 30.9376 mmHg (Calculated @ 20 C/68 F)
SECTION 10) STABILITY AND REACTIVITY
Stability:
Stable under normal conditions of use.
Conditions to Avoid:
Avoid heat, sparks, open flames and other ignition sources.
Hazardous Reactions/Polymerization:
No data available.
Incompatible Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition may yield carbon dioxide and/or carbon monoxide.
SECTION 11) TOXICOLOGICAL INFORMATION
0000067-63-0 ISOPROPYL ALCOHOL
LC50 (rat): 17000 ppm (4-hour exposure); cited as 12000 ppm (8-hour exposure) (18)
LD 50 (oral, male rat): 4710 mg/kg (cited as 6.0 mL/kg) ( 19 )
LD 50 (oral, mouse): 3600 mg/kg ( 20 , unconfirmed)
LD 50 (dermal, rabbit): 12870 mg/kg (cited as 16.4 mL/kg) ( 14 )
Potential Health Effects – Miscellaneous
0000067-63-0 ISOPROPYL ALCOHOL
The following medical conditions may be aggravated by exposure: dermatitis, respiratory disease. Developmental toxicity was seen in
rat?s offspring at doses that were maternally toxic. Contact will cause moderate to severe redness and swelling, itching, tingling
sensation, painful burning. May cause injury to the cornea of the eyes. Prolonged or repeated exposure may cause damage to any of
the following organs/systems: liver. Ingestion studies on laboratory animals showed that very high oral doses caused increased liver
and kidney weights.
Acute toxicity:
Ingestion: May be harmful or fatal if swallowed.
Skin Corrosion/Irritation:
Causes mild skin irritation
Serious eye damage/irritation:
Causes serious eye irritation
Germ cell mutagenicity:
No data available
Respiratory/Skin Sensitization:
Slightly irritating to respiratory system.
Carcinogenicity:
No data available
Reproductive toxicity:
No data available
Specific Target Organ Toxicity – Repeated Exposure:
No data available
Aspiration hazard:
No data available
Specific Target Organ Toxicity – Single Exposure:
May cause drowsiness or dizziness
SECTION 12) ECOLOGICAL INFORMATION
Isopropyl Alcohol 99%
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Bio-accumulative Potential:
No data available.
Persistence and Degradability:
No data available.
Mobility in Soil:
No data available.
Toxicity:
No data available
Other adverse effects:
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria
for hazardous waste. Waste management should be in full compliance with federal, state and local laws.
Empty Containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information:
UN1219, Isopropanol, 3, PG II
Emergency Response Guide (ERG):
Emergency Response Guide 129
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0000067-63-0 ISOPROPYL ALCOHOL 98.000% – 100.000% SARA312,SARA313,VOC,IARCCarcinogen,TSCA,OSHA
SECTION 16) OTHER INFORMATION
General:
A.G. Layne, Inc. urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or
appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. It is the
Buyer’s/User’s responsibility to ensure that his activities comply with all Federal, State, Provincial or Local laws. The information presented
here pertains only to the product as shipped. The information contained herein is based on our current knowledge of the underlying data
and is intended to describe the product for the purpose of health, safety and environmental requirements only. NO warranty or guarantee
is expressed or implied regarding the accuracy of this data or the results to be obtained from the use of the product.
Isopropyl Alcohol 99%
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2
4
H
0
HMIS
Chronic :
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither A. G. Layne, Inc. nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently
formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
Isopropyl Alcohol 99%
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