80EPO400-F_SDS.pdf

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Safety Data Sheet
acc. to OSHA HCS
Printing date 11/16/2019 Reviewed on 11/16/2019
49.1.7
1 Identification
Product identifier
Trade name: Epopast 400NA Resin
Article number:I024877
Application of the substance / the mixtureResin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Carc. 1A H350 May cause cancer.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) US

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Safety Data Sheet
acc. to OSHA HCS
Printing date 11/16/2019 Reviewed on 11/16/2019
Trade name: Epopast 400NA Resin
(Contd. of page 1)
49.1.7
Hazard pictograms
GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
Quartz (SiO2)
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause cancer.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
1
0
Health = *2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 3)
US

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Safety Data Sheet
acc. to OSHA HCS
Printing date 11/16/2019 Reviewed on 11/16/2019
Trade name: Epopast 400NA Resin
(Contd. of page 2)
49.1.7
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 20-<25% CAS: 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 5-10% CAS: 14808-60-7 EINECS: 238-878-4 Quartz (SiO2) 1-5% * 4 First-aid measures Description of first aid measures General information:Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixtureNo further relevant information available. Advice for firefighters Protective equipment:Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. US (Contd. on page 4) Page 4/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 3) 49.1.7 * 6 Accidental release measures Personal precautions, protective equipment and emergency proceduresNot required. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 30 mg/m 14808-60-7 Quartz (SiO2) 0.075 mg/m PAC-2: 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 330 mg/m 14808-60-7 Quartz (SiO2) 33 mg/m PAC-3: 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 2,000 mg/m 14808-60-7 Quartz (SiO2) 200 mg/m * 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires:Keep respiratory protective device available. (Contd. on page 5) US Page 5/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 4) 49.1.7 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 6) US Page 6/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 5) 49.1.7 Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Pasty Color: Grey Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:201 C (393.8 F) Flash point: 151 C (303.8 F) Flammability (solid, gaseous):Not applicable. Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure: Not determined. Density at 20 C (68 F): 1.31 g/cm (10.93 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. (Contd. on page 7) US Page 7/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 6) 49.1.7 Kinematic: Not determined. Solvent content: VOC content: 0.00 % 0.0 g/l / 0.00 lb/gal Solids content: 65.7 % Other information No further relevant information available. * 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin:Irritant to skin and mucous membranes. on the eye:Irritating effect. Sensitization:Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) 14808-60-7 Quartz (SiO2) 1 NTP (National Toxicology Program) 14808-60-7 Quartz (SiO2) K OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. US (Contd. on page 8) Page 8/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 7) 49.1.7 12 Ecological information Toxicity Aquatic toxicity:No further relevant information available. Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Ecotoxical effects: Remark:Toxic for fish Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT not regulated IMDG, IATA UN3082 UN proper shipping name DOT not regulated IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin, Epoxy phenol novolac resin), MARINE POLLUTANT (Contd. on page 9) US Page 9/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 8) 49.1.7 IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin, Epoxy phenol novolac resin) Transport hazard class(es) DOT Class not regulated IMDG, IATA Class 9 Miscellaneous dangerous substances and articles Label 9 Packing group DOT not regulated IMDG, IATA III Environmental hazards: Product contains environmentally hazardous substances: Epoxy phenol novolac resin Marine pollutant: Yes Symbol (fish and tree) Special marking (IATA): Symbol (fish and tree) Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 90 EMS Number: F-A,S-F Stowage Category A Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN, EPOXY PHENOL NOVOLAC RESIN), 9, III US (Contd. on page 10) Page 10/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 9) 49.1.7 * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): None of the ingredients is listed. TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants None of the ingredients is listed. Proposition 65 Chemicals known to cause cancer: 1317-65-3 Calcium Carbonate 14808-60-7 Quartz (SiO2) 14808-60-7 Quartz (SiO2) Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) 14808-60-7 Quartz (SiO2) A2 NIOSH-Ca (National Institute for Occupational Safety and Health) 14808-60-7 Quartz (SiO2) Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 11) US Page 11/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 10) 49.1.7 Hazard pictograms GHS07GHS08GHS09 Signal wordDanger Hazard-determining components of labeling: Reaction Product of Bisphenol A and Epichlorohydrin Quartz (SiO2) Hazard statements Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause cancer. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. National regulations: Information about limitation of use: Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases. Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision11/16/2019 / 1 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association (Contd. on page 12) US Page 12/12 Safety Data Sheet acc. to OSHA HCS Printing date 11/16/2019 Reviewed on 11/16/2019 Trade name: Epopast 400NA Resin (Contd. of page 11) 49.1.7 ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A Skin Sens. 1: Skin sensitisation Category 1 Carc. 1A: Carcinogenicity Category 1A Aquatic Acute 2: Hazardous to the aquatic environment - acute aquatic hazard Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2 * Data compared to the previous version altered. US Page 1/12 Safety Data Sheet acc. to OSHA HCS Printing date 06/05/2020 Reviewed on 06/05/2020 51.0.8 1 Identification Product identifier Trade name: Epopast 400/402 NA Hardener Article number:I024878 Application of the substance / the mixtureHardening agent/ Curing agent Details of the supplier of the safety data sheet Sika Advanced Resins, US EHS Department Manufacturer/Supplier: Supplier's Name: Sika Advanced Resins, US Headquarters: 30800 Stephenson Hwy Madison Heights, MI 48071 USA advancedresins.ehs@us.sika.com Information department:Product safety department Emergency telephone number: During normal opening times: +1 (248) 588-2270 CHEMTREC 24-hour Emergency: +1 (800) 424-9300 * 2 Hazard(s) identification Classification of the substance or mixture GHS05 Corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Acute Tox. 4 H312 Harmful in contact with skin. Skin Irrit. 2 H315 Causes skin irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. Label elements GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05GHS07 (Contd. on page 2) US Page 2/12 Safety Data Sheet acc. to OSHA HCS Printing date 06/05/2020 Reviewed on 06/05/2020 Trade name: Epopast 400/402 NA Hardener (Contd. of page 1) 51.0.8 Signal wordDanger Hazard-determining components of labeling: Trimethylolpropane poly(oxypropylene)triamine Teta, reaction products with propylene oxide Polyoxylated Triethylenetetramine 3,6-diazaoctanethylenediamin Hazard statements Harmful in contact with skin. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Avoid breathing dust/fume/gas/mist/vapors/spray Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment (see on this label). Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0 - 4) 3 1 0 Health = 3 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *3 1 0 Health = *3 Fire = 1 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. US (Contd. on page 3) Page 3/12 Safety Data Sheet acc. to OSHA HCS Printing date 06/05/2020 Reviewed on 06/05/2020 Trade name: Epopast 400/402 NA Hardener (Contd. of page 2) 51.0.8 * 3 Composition/information on ingredients Chemical characterization: Mixtures Description:Mixture of the substances listed below with nonhazardous additions. Dangerous components: CAS: 39423-51-3 Trimethylolpropane poly(oxypropylene)triamine 50-100% CAS: 26950-63-0 Teta, reaction products with propylene oxide Polyoxylated Triethylenetetramine 20-50% CAS: 112-24-3 EINECS: 203-950-6 3,6-diazaoctanethylenediamin 1-<5% 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing:If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixtureNo further relevant information available. Advice for firefighters Protective equipment:Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. US (Contd. on page 4) Page 4/12 Safety Data Sheet acc. to OSHA HCS Printing date 06/05/2020 Reviewed on 06/05/2020 Trade name: Epopast 400/402 NA Hardener (Contd. of page 3) 51.0.8 * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 39423-51-3 Trimethylolpropane poly(oxypropylene)triamine 30 mg/m 112-24-3 3,6-diazaoctanethylenediamin 3 ppm PAC-2: 39423-51-3 Trimethylolpropane poly(oxypropylene)triamine 330 mg/m 112-24-3 3,6-diazaoctanethylenediamin 14 ppm PAC-3: 39423-51-3 Trimethylolpropane poly(oxypropylene)triamine 2,000 mg/m 112-24-3 3,6-diazaoctanethylenediamin 83 ppm * 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires:No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. (Contd. on page 5) US Page 5/12 Safety Data Sheet acc. to OSHA HCS Printing date 06/05/2020 Reviewed on 06/05/2020 Trade name: Epopast 400/402 NA Hardener (Contd. of page 4) 51.0.8 Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 112-24-3 3,6-diazaoctanethylenediamin WEEL Long-term value: 6 mg/m , 1 ppm Skin Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 6) US Page 6/12 Safety Data Sheet acc. to OSHA HCS Printing date 06/05/2020 Reviewed on 06/05/2020 Trade name: Epopast 400/402 NA Hardener (Contd. of page 5) 51.0.8 Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Green Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:Undetermined. Flash point: 113 C (235.4 F) Flammability (solid, gaseous):Not applicable. Ignition temperature: 320 C (608 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: 2 Vol % Upper: 6.7 Vol % Vapor pressure at 20 C (68 F):6.8 hPa (5.1 mm Hg) Density at 20 C (68 F): 1.03 g/cm (8.6 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Fully miscible. Partition coefficient (n-octanol/water):Not determined. (Contd. on page 7) US Page 7/12 Safety Data Sheet acc. to OSHA HCS Printing date 06/05/2020 Reviewed on 06/05/2020 Trade name: Epopast 400/402 NA Hardener (Contd. of page 6) 51.0.8 Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: VOC content: 0.00 % 0.0 g/l / 0.00 lb/gal Solids content: 2.7 % Other information No further relevant information available. * 10 Stability and reactivity ReactivityNo further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: 39423-51-3 Trimethylolpropane poly(oxypropylene)triamine Oral LD50 <2,000 mg/kg (rat) Dermal LD50 >1,000 mg/kg (rat)
38640-62-9 Diisopropyl naphthalene
Oral LD50 >4,000 mg/kg (mouse)
Dermal LD50 >4,000 mg/kg (rat)
Inhalative LC50/6 h (dynamic) >5.6 mg/l (rat) (Test Guideline 402)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
(Contd. on page 8)
US

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Trade name: Epopast 400/402 NA Hardener
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51.0.8
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:
39423-51-3 Trimethylolpropane poly(oxypropylene)triamine
48 hr EC50 (static) 13 mg/l (daphnia)
72 or 96 hr ErC50 (static) 4.4 mg/l (Algea)
NOEC (static) 1 mg/l (Algea)
38640-62-9 Diisopropyl naphthalene
48 hr EC50 0.16 mg/l (daphnia)
96 hr LC50 0.5 mg/l (Fish)
72 or 96 hr ErC50 0.15 mg/l (Algea)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
US
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51.0.8
* 13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
Recommended cleansing agent:Water, if necessary with cleansing agents.
14 Transport information
UN-Number
DOT, IMDG, IATA UN1760
UN proper shipping name
DOT Corrosive liquids, n.o.s. (Triethylenetetramine)
IMDG CORROSIVE LIQUID, N.O.S. (TRIETHYLENETETRAMINE,
Propoxylated Triamine), MARINE POLLUTANT
IATA CORROSIVE LIQUID, N.O.S. (TRIETHYLENETETRAMINE)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG
Class 8 Corrosive substances
Label 8
IATA
Class 8 Corrosive substances
(Contd. on page 10)
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(Contd. of page 9)
51.0.8
Label 8
Packing group
DOT, IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances:
Propoxylated Triamine
Marine pollutant: Yes
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Hazard identification number (Kemler code):80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: U N 1 7 6 0 C O R R O S I V E L I Q U I D , N . O . S .
(TRIETHYLENETETRAMINE), 8, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
(Contd. on page 11)
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(Contd. of page 10)
51.0.8
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07
Signal wordDanger
Hazard-determining components of labeling:
Trimethylolpropane poly(oxypropylene)triamine
Teta, reaction products with propylene oxide
Polyoxylated Triethylenetetramine
3,6-diazaoctanethylenediamin
(Contd. on page 12)
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(Contd. of page 11)
51.0.8
Hazard statements
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye damage.
May cause an allergic skin reaction.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision06/05/2020 / 3
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
* Data compared to the previous version altered.
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49.1.7
1 Identification
Product identifier
Trade name: EPOLAM 2500 Resin
Article number:I024954
Application of the substance / the mixtureLaminating epoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS09 Environment
Aquatic Acute 1 H400 Very toxic to aquatic life.
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
1
0
Health = 2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 3)
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vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 25- 50%
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin 10-20%
CAS: 2425-79-8
EINECS: 219-371-7
1,4-bis(2,3-epoxypropoxy)butane 10-20%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
US
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* 6 Accidental release measures
Personal precautions, protective equipment and emergency proceduresNot required.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
30 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 16 mg/m
PAC-2:
28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
330 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 170 mg/m
PAC-3:
28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin
2,000 mg/m
25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 220 mg/m
* 7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:No special measures required.
(Contd. on page 5)
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49.1.7
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 6)
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49.1.7
Eye protection:
Tightly sealed goggles
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Light beige
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:>200 C (>392 F)
Flash point: 110 C (230 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.28 g/cm (10.68 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
(Contd. on page 7)
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49.1.7
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.5 %
VOC content: 0.39 %
5.0 g/l / 0.04 lb/gal
Solids content: 30.7 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
108-78-1 melamine 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Very toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy phenol novolac resin, Epoxy Resin), MARINE
POLLUTANT
(Contd. on page 9)
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IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy phenol novolac resin, Epoxy Resin)
Transport hazard class(es)
DOT
Class not regulated
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
Environmental hazards: Product contains environmentally hazardous substances: Epoxy
phenol novolac resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 90
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY PHENOL NOVOLAC RESIN, EPOXY
RESIN), 9, III
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
95-63-6 1,2,4-trimethylbenzene
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
98-82-8 cumene
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
100-41-4 ethylbenzene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 11)
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Hazard pictograms
GHS07GHS09
Signal wordWarning
Hazard-determining components of labeling:
Reaction Product of Bisphenol A and Epichlorohydrin
1,4-bis(2,3-epoxypropoxy)butane
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves / eye protection / face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Specific treatment (see on this label).
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/28/2019 / 5
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
(Contd. on page 12)
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PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Acute 1: Hazardous to the aquatic environment – acute aquatic hazard Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment – long-term aquatic hazard Category 1
* Data compared to the previous version altered.
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49.1.7
1 Identification
Product identifier
Trade name: EPOLAM 2500 Hardener
Article number:I024955
Application of the substance / the mixtureLaminating epoxy hardener
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 3 H402 Harmful to aquatic life.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS05GHS07
Signal wordDanger
Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Polyoxypropylenediamine
3-aminopropyldiethylamine
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Harmful to aquatic life.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 3)
US

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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/28/2019 Reviewed on 10/28/2019
Trade name: EPOLAM 2500 Hardener
(Contd. of page 2)
49.1.7
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 2855-13-2
EINECS: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamine 50-100%
CAS: 9046-10-0 Polyoxypropylenediamine 10-20%
CAS: 104-78-9
EINECS: 203-236-4
3-aminopropyldiethylamine 1-<5% 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Immediately call a doctor. Drink copious amounts of water and provide fresh air. Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment: Mouth respiratory protective device. (Contd. on page 4) US Page 4/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/28/2019 Reviewed on 10/28/2019 Trade name: EPOLAM 2500 Hardener (Contd. of page 3) 49.1.7 Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 9046-10-0 Polyoxypropylenediamine 4.8 mg/m 104-78-9 3-aminopropyldiethylamine 1.7 mg/m PAC-2: 9046-10-0 Polyoxypropylenediamine 53 mg/m 104-78-9 3-aminopropyldiethylamine 18 mg/m PAC-3: 9046-10-0 Polyoxypropylenediamine 320 mg/m 104-78-9 3-aminopropyldiethylamine 110 mg/m * 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires:Keep respiratory protective device available. (Contd. on page 5) US Page 5/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/28/2019 Reviewed on 10/28/2019 Trade name: EPOLAM 2500 Hardener (Contd. of page 4) 49.1.7 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 6) US Page 6/12 Safety Data Sheet acc. to OSHA HCS Printing date 10/28/2019 Reviewed on 10/28/2019 Trade name: EPOLAM 2500 Hardener (Contd. of page 5) 49.1.7 Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Color: According to product specification Odor: Characteristic Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:232 C (449.6 F) Flash point: >100 C (>212 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 0.7 Vol %
Upper: 5 Vol %
Vapor pressure: Not determined.
Density at 20 C (68 F): 0.91 g/cm (7.59 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
(Contd. on page 7)
US

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Safety Data Sheet
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Printing date 10/28/2019 Reviewed on 10/28/2019
Trade name: EPOLAM 2500 Hardener
(Contd. of page 6)
49.1.7
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 0.0 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Oral LD50 1,030 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rat)
9046-10-0 Polyoxypropylenediamine
Oral LD50 2,855 mg/kg (rabbit)
Dermal LD50 2,980 mg/kg (rabbit)
Primary irritant effect:
on the skin:Strong caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
(Contd. on page 8)
US

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Safety Data Sheet
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Printing date 10/28/2019 Reviewed on 10/28/2019
Trade name: EPOLAM 2500 Hardener
(Contd. of page 7)
49.1.7
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
96 hr LC50 110 mg/l (Fish)
NOEC 3 mg/l (daphnia)
9046-10-0 Polyoxypropylenediamine
48 hr EC50 80 mg/l (daphnia)
96 hr LC50 772 mg/l (Fish)
72 or 96 hr ErC50 15 mg/l (Algea)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Harmful to fish
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
US
(Contd. on page 9)

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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/28/2019 Reviewed on 10/28/2019
Trade name: EPOLAM 2500 Hardener
(Contd. of page 8)
49.1.7
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, IMDG, IATA UN2289
UN proper shipping name
DOT Isophoronediamine
IMDG, IATA ISOPHORONEDIAMINE
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
(Contd. on page 10)
US

Page 10/12
Safety Data Sheet
acc. to OSHA HCS
Printing date 10/28/2019 Reviewed on 10/28/2019
Trade name: EPOLAM 2500 Hardener
(Contd. of page 9)
49.1.7
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: UN 2289 ISOPHORONEDIAMINE, 8, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
75-56-9 propylene oxide
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
(Contd. on page 11)
US

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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/28/2019 Reviewed on 10/28/2019
Trade name: EPOLAM 2500 Hardener
(Contd. of page 10)
49.1.7
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS07
Signal wordDanger
Hazard-determining components of labeling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Polyoxypropylenediamine
3-aminopropyldiethylamine
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Harmful to aquatic life.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 12)
US

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Safety Data Sheet
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Printing date 10/28/2019 Reviewed on 10/28/2019
Trade name: EPOLAM 2500 Hardener
(Contd. of page 11)
49.1.7
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision10/28/2019 / 2
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Skin Corr. 1A: Skin corrosion/irritation Category 1A
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Aquatic Acute 3: Hazardous to the aquatic environment – acute aquatic hazard Category 3
Aquatic Chronic 3: Hazardous to the aquatic environment – long-term aquatic hazard Category 3
* Data compared to the previous version altered.
US

80EPO2500B_SDS.pdf

@
BUILDING TRUST
Printing date I 0/28/201 9
Safety Dota Sheet
qcc. to OSHA HCS
Page I/12
Reviev,ed on I 0/28/201 9
Product idenli/ier
Trude name: EPOLAM 2500 Hurdener
Article number: 102495 5
Applicaliort of the substunce,/ the mixture Lantintrting epox1, fi4vrJu’tu”
Detoils of the supplier of lhe s(fetJ) data sheet
Sika Advanced Resins, US
EHS Department
M o tr ttfttcl u r er/S u pp I i e r :
Supplier’s Name: Sika Advanced Resin.s, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
I nfo rmoli o tt d ep a rt m e nl : P r o du ct s afety d ep a r t nt en t
E ntergency lelep h on e nu mb er :
During normal opening tintes: + I (24B) 5BB-2270
CHEMTREC 24-hour Entergency: +1 (800) 424-9300
2 Hazo rd (s) ide ntift c at i o n
of tlrc substunce or nixlure
GHS]5 Coryosion
Skin Con. IA
Eye Dam. I
H3I4 Cause.t severe skin burns and e1,s duntuge.
H3I8 Causes serious eye damage.
GHSOT
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. I H317 May cause an allergic skin react ion
Aquatic Acute 3 H402 Harmful to aquatic life.
Aquatic Chronic 3 H4l2 Harntful to aquatic Iife with long lasting e//bcts
Label elements
GHS label elemenls The product is classified and labeled uccording to the Globqlly Harmonized System (GHS).
(Contd. on page 2)
I
o
US

BUILDING TRUST
Printing date 1 0/28/20 1 9
Ssfety Dsta Sheet
qcc. to OSHA HCS
Page 2/12
Reviev,ed on I 0/28/20 1 9
I
Trade nanre: EPOLAM 2500 Hurrlener
(Contd. ofpage l)
Hazard piclogrants
GHSO5 GHSOT
Signal wotd Danger
H azard-delerni ni n g co mp o n en ts of I a be I i n g :
3 – antinom et hy l- 3, 5, 5 – t r i nt e t hy I ct, c I o lt,’xy I a nr i n e
P o I yoxypr opy I e n e d i a m i n e
3 – a m i n opropy I d i e t hy I a m i n e
Hazarrl stotemenls
Harmful if swallov,ed.
Causes severe skin burns and e1,e damage.
May cause an allergic skin reac!ion.
Harmful to aquatic life.
Harmful to aquatic life u,ith long lasting effbcts.
Precautionury stilements
Av o i d br e a t h ing du s t/fu nt e/ g a s/ m i s t/v a p ot” s/ s p r ay
Do not breathe dusts or mists.
LVear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor ifyoufeel unwell.
If on skin (or hair): Take off imnrediatellt all contantinated clothing. Rinse skin with water/shower.
IF INHALED: Remove pet’son to.fi”esh air and keep confortablefor breathing.
If in eyes: Rinse cautiously v,ith water.for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this lubel).
Store locked up.
Dispose of contents/container in accordancewith local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
Health :
3
Fire : I
Reactivity: 0
HMlS-ruings(scde0-4)
Health —
*3
Fire : l
nencrvtrvi b’l: Reactivity :
0
Otlter hazards
Results of PBT ond vPvB ussessntent
PBT: Not applicable.
(Contd. on page 3)
US

BUILDING TRUST
Pt’inting tlure I 0i28/20 I 9
Scfety Data Sheet
acc. to OSHA HCS
Page 3/12
Revievted on I 0/28/2019
Traile nume: EPOLA|VI 2500 Hardener
(Contd. ol-page 2)
t,PvB: Not upplicable.
3 Composition/information on ingredients
C h e m i co I c h o racle riz.uti o u : Mixlu res
Descriptiott: Mixture of the substances listed below with nonhazardous additions.
D a n g e ro u s c o rrlp o n ents :
CAS:101-78-9
EINECS: 203-236-4
50- I 00%L’AS: 2855-r3-2
EIN ECS,, 220-666-8
3 – a nt i n ont e t hy I – 3, 5, 5 – t r i m e t hy I cy c I o h exy I a nt i n e
CAS:9046-10-0 P o ly oxy p r o py I e n e d i a m i n e I0-20%
>t-<5%3 - a nt i n o p r opy I d ie t hy I a nt in e 4 First-aid measures D es c ri pti o tr o.f .fi rcl a i d me us u res G en erol i rtforntalion : lntmediutely remove any clothing soiled by the product. S),mptons of poisoning may even occur after several hour.s; therefore ntedical observationJbr qt least 48 hours u/ier the accident. A.fler inhalution: ,Supply/)'esh air and to be sure callfor a doctor. ln case of'unconsciousness place patient stably in side positionfor transportation. A.fter skitt conlocl: Imntediately u,ash with water and soap and rinse thoroughly. zl.fter eye conloct: Rinse opened eyefor several minutes under runningwater. Then consult a doctor. A.fter swullowirtg: lnmediately call a doctor. Drink copious amounts ofwater and providefresh air. Imntediately call a doctor. I n fo rmuti on fo r doctor: Most irnportont il,ntplonts und effects, both ucute tnd delayed Nofurther relevant information available. Indicatiort o.f any itnmediate medical otlention ond special lreulment needed N o .furt lt e t' r e l ev a n l i nform a t i on av ai la b l e. Extitrguishing media Saitfile extirtgtrisltiug agenls: Usefirefighting measures that suit the environment. Special hazurds orising front the substance or mixture During heating or in case offire poisonous gases are produced. .4 d v i c e .fo r .fi refi g h te rs Proleclive equipmenl: A4outh respiratory protective device. (Contd. on page 4) 5 Fire-lighting meas ures US BUILDING TRUST Printing date I 0/28/20 l 9 Ssfety Data Slreet qcc. to OSHA HCS Page 4/12 Revievted on I 0/28/20 I 9 Trade narne: EPOLAM 2500 Hurdener (Contd. olpage 3) LI/ e a r s e lf- c o n t a i n e d r es p ir a t ory p r o t e c t iv e d ev i c e. A dd i ti o n al i n fo rmali o rr Dispose offire debris and contaminated./ire.fightingvtater in accordance v,ith official regulations. Hundling: Precuutions for sufe ltandling Ensure good ventilation/exhaustion at the workplace. Pr ev ent for nt a tion of a eros o ls. Informatiort oboat proleclion against explosiotrs andJires: Keep respiratory) plotective device available. (Contd. on page 5) * 6 Accidental release measures Personol precaulions, prolective equipmenl and emergency procedures M ou n t r esp ir at ory pr ot ect iv e dev ice. Iilear protective equipment. Keep unprotected persons away. Ettvi ro nntenlil p recuu I i ons : Do not allow product lo reach sewage syslem or any water course. Infornt respective authorities in case of seepage intowater course or sewage system. Do not allow to enter sewers/ surface or ground vtater. Methods and mileriulfor contdnment ond cleaning up: Absorb with liquid-binding material (sand, dialomite, acid binders, universal binders, sawdust) Us e n eutra lizing agent. Dispose contaminated material qs waste according to itetn I3. Ensur e a dequ ate vent il a tion. Reference lo other sections See Section 7 for information on,sde handling. See Section Sfor information on personal protection equipntent. See Section l3 for disposal informalion. Protective Action Criteria for Chemicals PAC-I: 9046- I 0-0P o ly oxy p r o py I e n e d i a m i n e 4.8 ntg/m3 I 04-78-93 - am in opr opy I d i et hy I a m i n e 1.7 mg/nt3 PAC-2: 9046-1 0-0P o ly oxy pr opy I e ne di amin e 53 rug/m3 I 04-78-93 - aminop r opy I d i et hy I a m in e l8 mg/m3 PAC-3: 9046-1 0-0P o ly oxypr opyl enediam in e 320 mg/m3 I 04-78-93 - a m i n o p r o py I d i e t hy I a m i ne I l0 ntg/nt3 7 Handling &nd storflge US BUILDING TRUSTA Printing date I 0/28/20 I 9 Sofety Dcrtcr Slteet occ. t0 OSHA HCS Page 5/12 Revievted on I 0/28/2 0 I 9 * Trude nante: EPOLAM 2500 Hurderrer (Contd. olpage 4) Corrtlitiorrs for sufe slorage, incIutlirtg uny incompatibiIities Storage: Requirentenls to be mel by slorcroonrs and receplacles: No special requirentents. Informotiotr about slorage in one common slorage.fttcilily: Not required. Furlher informaliou aboul sloruge conditiotts: Keep receptacle tightly sealed. SpecrJic end use(s) Nofurther relevant inforntation available. Adtlitional informaliou aboul design of technical syslems: No further data; see item 7. Control prtrumelers Componenls with limil values thut require ntoniloring ot tlte workphce: The product does not contain any relevant cluantities of nraterials with critical values that have to be ntonitored al the workplace. Adrlitional information: The lists that were valid during the creation were used as basis. Exposure conlrols Pers o n a I p roteclive e q u ip menl : General prolective urtd hygienic nrcosures: K e ep aw ay fr ont fo o ds tuffs, b ev er a ges a n d fe e d. Immediately remove all soiled and contantinated clothing. Ilash hands before breaks and at the end ofwork. Avoid contact with the eyes. Avoid contact v,ith the eyes and skin. B reailt i tt g eq u ip rnenl : In case of brief exposure or low pollution use respiratoryfilter device. Incase of intensive or longer exposure use respiratory prolective device that is independent ofcirculating air. Prolecliort of huttds: Protective gloves The glove material has to be intpernteable and resistant Io the product/ the substance/ the preparation. Due to ntissing tests no recontmendation to the glove material can be givenfor the product/ the preparation/ the chemical ntixture. Selection of the glove ntateriol on consideration of the penetration times, rates of dffision and the degradation Malerial of gloves The selection of the suitable gloves does not only depend on the material, but also onfurther mark.s of quality and variesfront ntandacturer to manufacturer. As the product is a preparation ofseveral substances, the resistance of the glove ntaterial can not be calculqted in advance qnd has therefore to be checked prior to the application. Penetrctiotr tinte of glove materisl The exact break through time has to beJbund out by the ntanufacturer of the protective gloves and ha.s to be observed. (Conld. on page 6) 8 Exposure corrtrols/personal protection US BUILDING TRUST Printing date I0/28/20I 9 Scfety Dats Sheet ncc. to OSHA HCS Puge (t/12 Rct;icv'etl ott I 0/28/20 I 9 Trade name: EPOLAM 2500 Hurtlener Eye prolecliort: @ Tightly sealed goggles lContd. ol'page 5) * 9 Physical arrd chemicol properties Informotion on basic physical ond chenical properlies Generol Itrformotion Appeurance: Form: Fluid Color: According to product specification Odor: Characteristic Odor thresholtl: Not deterntined. pH-value: Flash poitrt: Not deterntined. >100″c(>212″F)
Change in conditiott
M elt i n g po i n t/M e lti rtg rnt ge :
B oil i n g poi trl/B o i I irt g range :
Undeternrined.
232 “C (449.6 “F)
Not deterntined.
Producl does not present an explosion hozard.
Product is not .selfgniting.
D eco nrp osili o n lentp e rotu re : Not deterntined.
Auto igniling:
Danger of explosiott
Vapor pressure:
0.7 Vol%
5Vol%
0.91 g/cmr (7.59 lbs/gal)
Not determined,
Not determined.
Not determined.
Flammability (solid, goseous): Not applicable.
Density ut 20
oC
(68 “F):
Relutive density
Vupor density
Evoporation rale
Explosiotr Iimits:
Lower:
Upper:
Soluhility in / Miscihility with
llaler: Not miscible or di//icult to mix.
Parlitiort coeflicient (n-oclanol/waler) : Not determined.
Viscosity:
Dynumic:
(Contd. on page 7)
Not deterntined.
IJS

@
BUILDING TRUST
Printing date I 0/28/20 I 9
Scfety Dotu Slteet
ncc. t0 OSHA HCS
Page 7/l 2
Reviewed on 10/28/2019
Trade nanrc: EPOLAM 2500 Hardener
(Contd. ofpage 6)
Kinemalic:
Solvenl conlent:
VOC content:
Solids content:
Otlter itrformatiort
Nol delerntined.
0.00 %
0.0 g/l / 0.00 lb/gul
0.0 %
N o.furt her rel eva n ! i nfbr nt o| i on av a i I a bI e.
I0 Stability and reactivity
Re o cl i v i ty N o fur
t h e r r e I ev a nt i nfornt a t i o n av a i I a h I e.
Chemicul stability
TIrcrmil tlecompositiort / corrtlitions to be avoided: No decomposition if-usecl according to specifications.
Possibility of hazardous reactions No dangerous reaclions knot’r,tt.
C o ttd itiotts to uvo id N o furt
h er rel ev a n t infor nt a t i on at, a i I u I’s I e.
I n contp ili b I e materi uls : N o fu
rt h e r r e I ev an t i nfornt a t i on av a i I u b I e.
Hszardous decomposition producls: Carbon monoxide antl cqrbon clioxide
I I Toxicological information
*
Infornrati on on toxi co Io gi cu I effecls
Acule toxicity:
9 04 6- I 0-0 Po Iy oxypropy I en ed iumi n e
2,855 mg/kg
2,980 mg/kg (rabbit)
P rintary i r r it ant effe ct :
on the skin: Strong caustic ffict
on skin and mucous membrqnes.
on tlte eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitizotion: Sensitization possible through skin con! oct.
Atl tlil i onul toxico lo gica I informot i o n :
The product shows thefollowing dangers according to internally approvecl calculation ntethodsfor preparations
Harnful
Cotosive
Irritant
(Contd. on page 8)
LD/LC10 volues lhat ore relevant.for clossiJicatiort:
Oral
Dermal
LD5O
LD5O
2 8 5 5- I 3 -2 3 -anrinomelltyl-3, 5, 5-lri methy lcJ) c I o h exy I u rtri n e
2,000 ng/kg (rat)
1,030 (rat)
Oral
Derntal
LD5O
LD5O
US

BUILDING TRUST
Puge 8/12
Sqfuty Dota Sheet
ncc. to OSHA HCS
Printing date I 0/28/2019 Revi etvecl on I 0/28/2 0 I 9
Trade name: EPOLAM 2500 Ilunlener
(Contd. ofpagc 7)
Stvallotving,vill leacl Io u. t’one cctu.stic e//bct on trtouth and throal and to the danget” oJ perforution ofesophagu.s
and stontach.
Carci n ogen ic calego ries
IARC (Intertrationol Agettc1,.fttr Reseurch on Cancer)
None oJ’tlte ingredients is li.ttetl.
NTP (Nalionol Toxicolog.l, Progrunt)
None of tlte ingredients is li.stctl.
OSHA-CI (Occupatiortul Sufety & lleulth Adtrtittistraliott)
None of the ingredients is li.stecl.
I 2 Ecological information
96 hr LC50
NOEC
2 8 5 5- I 3-2 3-umin oruethy I–1, 5,5-tri nrcthy IcycIoh exyIamine
Il0 nrg,’l (Fish)
3 ntg/l (dophnial
48 hr EC50
96 hr LC50
72 or 96 hr ErC50
Toxicity
Aquutic toxicity
904 6- I 0-0 Po lyoxypropy len ed i a tni n e
B0 ntgil (daphnia)
772 ntg/l (f i,e111
|5 ntg/l (Algea)
Persistettce and degradabil it1, l{s evant
Belruvior in environmertlul sJtslenrs:
B ioacc u nu I ative p ole n t i u I N o./ilr t h e r re I ev a nt i nfornt a t ion av a il a bl e.
Mobility irr soil Nofut’ther relevanl in/brntation available.
Ecotoxical effects:
Rernurk : Harmfu I to./i.sh
Additionol ecoIogicaI inJbrntation :
General noles:
Water hazard class I (SelJ-ussessntent): slightly hazardous for water
Do not allou,undilutecl product or lurge quantities of it to reach groundwater, water course orsewqge system.
Must not reach bodies of-v’uter or drainage ditch undiluted or unneutralized.
H annftrl !o aqua! ic ot’eutt i.snr.t
Resuhs of PBT and vPvB ussesstnenl
PBT: Not applicable.
vPvB: Not applicable.
Other udverse effects Nct.filrther relevunt inforntation available.
US
(Contd. on page 9)

BUILDING TRUST
Printittg tlate I 0/28/20I 9
Scfety Dats Sheet
ncc. t0 OSHA HCS
Page 9/12
Revievted on l 0/28/20 l 9
Trude name: EPOLAM 2500 Hurdener
(Contd. olpage 8)
13 Disposal considerations
Wosl e t realnr enl nteth o ds
Recomnrcndation:
Must rtd be disposed of together with household garbage. Do not allow product to reach sewage systenl
Uncleaned pockagings:
Recommendulion: Disposal ntust be made according to oficial regulations.
14 Transport information
/A
,/g#!
yz
Z
V
UN-Nnmber
DOT,IMDG,IATA
UN proper shipping name
DOT
IMDG,IATA
Tra n sp o rl h uza rd class (es)
DOT
Cluss
Label
IMDG,IATA
Class
Label
Pucking group
DOT,IMDG,IATA
Envi ro n m ent u I h aza rds :
Murine pollulant:
Special precuutiorrs for user
Danger code (Kemler):
EMS Number:
uN2289
Isophoronediamine
ISOPHORONEDIAMINE
B Corrosive substances
8
B Corrosive substances
8
ilI
No
VI/ arn ing : C orr os iv e subs t an c es
80
F-A,S-B
(Contd. on page I 0)
US

BUILDING TRUST
Printing date I 0/28/20 1 9
Snfnty Dttttt Sheet
lcc. to OSHA HCS
Page l0/12
Revieu,ed on I 0/28/20 I 9
Trade name: EPOLAM 2500 Hanlener
(Contd. ofpage 9)
Stowage Category A
Transport in bulk according to Annex II o./
MARPOLT3/78 and the IBC Code Not applicable.
T r n n s p o rl/A d d i t i o n a I i nfo r nru t i o tr :
DOT
Quonlity Iimitstions On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
IMDG
Limited qu antities (LQ)
Excepted qu antities (EQ)
5L
Code: El
Maxinttrm net quantity per inner packaging: 30 nl
Maxirnunt net quantity per outer packaging: 1000 ml
UN ” Model Regu latiort” : UN 2289 ISOPHORONED]AMINE, B, ]II
1 5 Regultttory informilion
*
Sofety, healllt trnd environntenlul regulcrtions/legislalion speciJic.for the subslonce or mixturc
Saru
Section 355 (extremely ltuardous subslunces):
None of the ingredients is listed.
Sectiott 313 (SpeciJic toxic chemical listings):
None of the ingredicnts is listed.
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicols reguliled by TSCA Sectiort l2(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(u)(2)rule:
None of the ingredients is listed.
H azardo u s Ai r Po I I u lanls
None of the i.s listed.
Propositiorr 65
Cltemicals knowtt to c(use cuncer:
7 5-56-9propylene oxide
Chemicsls ktrowrt lo cuuse reproductive toxicity.fot.females:
None of the ingredients is listed.
Chemicals known to cause reproduclive toxicity.for males
(Contd. on page I I )
None of’the ingredients is listed.
US

BUILDING TRUST
Printing date I 0/28/20 I 9
Sofnty Dsta Sheet
ncc. to OSHA HCS
Page l l/12
Reviewed on 10/28/2019
Trade nante: EPOLAM 2500 Hurdener
(Contd. ofpage l0)
Chemiculs knowtr to c(use developmental toxicity:
None of the ingredients is listed.
C orci n o gen i c c ileg o ries
TLV (Threshold Linit vslue estublished by ACGIH)
None of the ingredients is listed.
Listed in ClltC Regulatious
None of the ingredients is listed.
NIOSH-Ca (Nationol Institute for Occupational Sofety nnd Healtlt)
None of the ingredients is listed.
GHS lcbel elements
Hazard pictograms
t.sassifed and labeled according to (GHS)
GHSOs GHSOT
Signal word Danger
H azartl-deternrini n g co mp on enls of I a bel i n g :
3 – ant inomethyl- 3, 5, 5 -trin etlrylcyclo h exy I am ine
P o ly oxypr opy I en e di a m in e
3 – a m i n opr opy I d i e t hy I anr i n e
Hazard statements
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Harntful to aquatic life.
Harmful to aquatic life with long lasting efficts.
P r ec a u t ion a ry st ste nten I s
Do not breathe dusts or misls.
I4ear protective gloves/protective clothing/eye protection/face protection.
If swallou,ed: Call a poison center/doctor ifyoufeel unwell.
If on skin (or hair): Take offintnediately all contaminated clothing. Rinse skinwithwater/shower.
IF INHALED: Remove person tofresh air and keep comfortablefor breathing.
lf in eyes: Rinse cautiously with waterfor several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Imntediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up,
Dispose of contents/container in accordqnce v,ilh local/regional/national/international regulalions.
(Contd. on page l2)
Harmon
T
o
US

BUILDIN6 TRUST
Printing date 10/28/20I 9
Scfety Duttt Sheet
acc. to OSHA HCS
Pogc l2/12
Revietvccl on I 0/28/20 I 9
Trude name: EPOLAM 2500 Hardener
(Contd. ol’page I l)
Chemicul sofety asssssment: A Chentical Safety Assessment has no! been corrietl out
This in/brmation is based on our present knowledge. Hov,ever, this shall not crtrt.sliltrte a guurQnleefor any
specific prodtrct features
and shall not establish a legally valid contrctctual relationship.
Date of prepototiott / Iast revisiort 10/28/2019 / 2
Abhrevi ali o tts an d acro n)) ms :
IMDG: lntenntional Maritine Code.for Dangerous Goods
DOT: US Deparlnent of Tronsportalion
I ATA : I n le rna I i ona I A i r Transporl A ss oc ial i ot1
ACGIH: Anterican Conference of Governmenlal Industriol Hygienisls
EINECS: European lnventory of Exisling Comntercial Chemical Subslances
ELINCS: European List of Notrfied Chentical Substartces
CAS: Che rnical Abslracls Service (division of lhe Anretican Chemical Society)
NFPA: Notional Fire Protection Association (USA)
l’! lvl I S : U aza rd ous M ate r i a I s I d en t ifi ca t i on Sys te m (U S A)
ItOC: I/olotile Organic Compounds (USA, EU)
LC50: Lethal concenlration, 50 percenl
LD50: Lethol dose, 50 percent
PBT: Persislenl, Bioaccumulative and Toxic
vPvB: ve11, Persislent and vew Bioacatmulalive
NIOSH: Nalional lnslilute for Occupational Safety
OSHA: Occupational Safety & Health
TLII: Threshold Limit Value
PEL: Pernissible Exposure Linril
REL: Reconnrcnded Exposure Limil
Acule Tox. 4: tlcule loxicily – Category 4
Skin Corr. I il: Skin corrosion/itilation – Caregory l A
Eye Dant. l: Serious eye damage/eye irrilatiotl –
Category I
Skin Sens. l: Skin sensilisalion –
Category l
Aqucttic Acute 3: Hazardous lo lhe dqualic environnrcnt – aaile aqualic hazard Category 3
Aquotic Chronic 3: Hazardous lo the aquLtic environmenl – long-term aclualic hazard – Calegory 3
*
Dala conrporcd lo the previous vetsiotl ahered.
US

80EL337B-D_SDS.pdf

Page 1/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/09/2020 Reviewed on 01/09/2020
50.0
1 Identification
Product identifier
Trade name: EL337 Hardener
Article number:I501389-2
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) US

Page 2/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/09/2020 Reviewed on 01/09/2020
Trade name: EL337 Hardener
(Contd. of page 1)
50.0
Hazard pictograms
GHS05GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
cyclohex-1,2-ylenediamine
m-phenylenebis(methylamine)
3,6-diazaoctanethylenediamin
2-ethyl-4-methylimidazole
1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl-
(R)-p-mentha-1,8-diene
Hazard statements
Harmful if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
(Contd. on page 3)
US

Page 3/13
Safety Data Sheet
acc. to OSHA HCS
Printing date 01/09/2020 Reviewed on 01/09/2020
Trade name: EL337 Hardener
(Contd. of page 2)
50.0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 694-83-7
EINECS: 211-776-7
cyclohex-1,2-ylenediamine 20-50%
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 20-<25% CAS: 1477-55-0 EINECS: 216-032-5 m-phenylenebis(methylamine) 10-20% CAS: 616-47-7 EINECS: 210-484-7 1-methylimidazole 5-10% CAS: 931-36-2 EINECS: 213-234-5 2-ethyl-4-methylimidazole 1-5% CAS: 25513-64-8 EINECS: 247-134-8 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- 0.1-<1% CAS: 822-36-6 EINECS: 212-497-3 4-methylimidazole 0.1-1% CAS: 5989-27-5 EINECS: 227-813-5 (R)-p-mentha-1,8-diene 0.1-<0.25% * 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing:Drink copious amounts of water and provide fresh air. Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 3) 50.0 Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment: Mouth respiratory protective device. Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 694-83-7 cyclohex-1,2-ylenediamine 2.1 mg/m 112-24-3 3,6-diazaoctanethylenediamin 3 ppm 616-47-7 1-methylimidazole 2.3 mg/m 822-36-6 4-methylimidazole 10 mg/m 5989-27-5 (R)-p-mentha-1,8-diene 15 ppm (Contd. on page 5) US Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 4) 50.0 PAC-2: 694-83-7 cyclohex-1,2-ylenediamine 23 mg/m 112-24-3 3,6-diazaoctanethylenediamin 14 ppm 616-47-7 1-methylimidazole 25 mg/m 822-36-6 4-methylimidazole 110 mg/m 5989-27-5 (R)-p-mentha-1,8-diene 67 ppm PAC-3: 694-83-7 cyclohex-1,2-ylenediamine 140 mg/m 112-24-3 3,6-diazaoctanethylenediamin 83 ppm 616-47-7 1-methylimidazole 150 mg/m 822-36-6 4-methylimidazole 150 mg/m 5989-27-5 (R)-p-mentha-1,8-diene 170 ppm * 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires:Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 112-24-3 3,6-diazaoctanethylenediamin WEEL Long-term value: 6 mg/m , 1 ppm Skin (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 5) 50.0 Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Light yellow Odor: Amine-like (Contd. on page 7) US Page 7/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 6) 50.0 Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:188-192 C (370.4-377.6 F) Flash point: 105 C (221 F) Flammability (solid, gaseous):Not applicable. Ignition temperature: 335 C (635 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure: Not determined. Density at 20 C (68 F): 0.99 g/cm (8.26 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water):Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 0.1-0.2 % VOC content: 0.06-0.18 % 1.7 g/l / 0.01 lb/gal Solids content: 2 % Other information No further relevant information available. 10 Stability and reactivity ReactivityNo further relevant information available. (Contd. on page 8) US Page 8/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 7) 50.0 Chemical stability Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidNo further relevant information available. Incompatible materials:No further relevant information available. Hazardous decomposition products:Carbon monoxide and carbon dioxide * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: 112-24-3 3,6-diazaoctanethylenediamin Oral LD50 2,000 mg/kg (rat) Dermal LD50 2,000 mg/kg (rabbit) 1477-55-0 m-phenylenebis(methylamine) Oral LD50 1,040 mg/kg (rat) Dermal LD50 2,000 mg/kg (rabbit) Inhalative LC50/4 h 2.4 mg/l (rat) 616-47-7 1-methylimidazole Oral LD50 1,400 mg/kg (mouse) 5989-27-5 (R)-p-mentha-1,8-diene Oral LD50 4,400 mg/kg (rat) Primary irritant effect: on the skin:Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Strong irritant with the danger of severe eye injury. Sensitization:Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Corrosive Irritant Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. Carcinogenic categories IARC (International Agency for Research on Cancer) 822-36-6 4-methylimidazole 2B 5989-27-5 (R)-p-mentha-1,8-diene 3 (Contd. on page 9) US Page 9/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 8) 50.0 NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information Toxicity Aquatic toxicity: 1477-55-0 m-phenylenebis(methylamine) 72 or 96 hr ErC50 12 mg/l (Chaetogammarus marinus) Persistence and degradabilityNo further relevant information available. Behavior in environmental systems: Bioaccumulative potentialNo further relevant information available. Mobility in soilNo further relevant information available. Ecotoxical effects: Remark:Harmful to fish Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Danger to drinking water if even small quantities leak into the ground. Harmful to aquatic organisms Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable. Other adverse effectsNo further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation:Disposal must be made according to official regulations. US (Contd. on page 10) Page 10/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 9) 50.0 14 Transport information UN-Number DOT, IMDG, IATA UN3267 UN proper shipping name DOT Corrosive liquid, basic, organic, n.o.s. (Triethylenetetramine, m- phenylenebis(methylamine)) IMDG, IATA C O R R O S I V E L I Q U I D , B A S I C , O R G A N I C , N . O . S . (TRIETHYLENETETRAMINE, m-phenylenebis(methylamine)) Transport hazard class(es) DOT Class 8 Corrosive substances Label 8 IMDG, IATA Class 8 Corrosive substances Label 8 Packing group DOT, IMDG, IATA II Environmental hazards: Marine pollutant: No Special precautions for user Warning: Corrosive substances Danger code (Kemler): 80 EMS Number: F-A,S-B Segregation groups Alkalis Stowage Category B Stowage Code SW2 Clear of living quarters. Segregation Code SG35 Stow "separated from" SGG1-acids Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. (Contd. on page 11) US Page 11/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 10) 50.0 Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN "Model Regulation": UN 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. ( T R I E T H Y L E N E T E T R A M I N E , M - PHENYLENEBIS(METHYLAMINE)), 8, II * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): None of the ingredients is listed. TSCA (Toxic Substances Control Act): All components have the value ACTIVE. Chemicals regulated by TSCA Section 12(b) None of the ingredients is listed. Chemical regulated by TSCA 5(a)(2)rule: None of the ingredients is listed. Hazardous Air Pollutants None of the ingredients is listed. Proposition 65 Chemicals known to cause cancer: 822-36-6 4-methylimidazole Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. (Contd. on page 12) US Page 12/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 11) 50.0 Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. Listed in CWC Regulations None of the ingredients is listed. GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05GHS07GHS08 Signal wordDanger Hazard-determining components of labeling: cyclohex-1,2-ylenediamine m-phenylenebis(methylamine) 3,6-diazaoctanethylenediamin 2-ethyl-4-methylimidazole 1,6-Hexanediamine, 2,2,4 (or 2,4,4)-trimethyl- (R)-p-mentha-1,8-diene Hazard statements Harmful if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Suspected of causing cancer. Harmful to aquatic life with long lasting effects. Precautionary statements Do not breathe dusts or mists. Wear protective gloves/protective clothing/eye protection/face protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment (see on this label). Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. on page 13) US Page 13/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Hardener (Contd. of page 12) 50.0 Chemical safety assessment:A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision01/09/2020 / 7 Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Acute Tox. 4: Acute toxicity Category 4 Skin Corr. 1B: Skin corrosion/irritation Category 1B Eye Dam. 1: Serious eye damage/eye irritation Category 1 Skin Sens. 1: Skin sensitisation Category 1 Carc. 2: Carcinogenicity Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard Category 3 * Data compared to the previous version altered. 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1 Identification
Product identifier
Trade name: EL337 Resin
Article number:I337088
Application of the substance / the mixtureEpoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
advancedresins.ehs@us.sika.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS08 Health hazard
Carc. 1B H350 May cause cancer.
Repr. 1B H360 May damage fertility or the unborn child.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
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Hazard pictograms
GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane
N-methyl-2-pyrrolidone
Reaction Product of Bisphenol A and Epichlorohydrin
Hazard statements
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause cancer.
May damage fertility or the unborn child.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
1
0
Health = 2
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
1
0
Health = *2
Fire = 1
Reactivity = 0
(Contd. on page 3)
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Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 28064-14-4 Epoxy phenol novolac resin
Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 20-<25% CAS: 17557-23-2 EINECS: 241-536-7 1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane 5-<10% CAS: 2530-83-8 EINECS: 219-784-2 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane 1-<3% CAS: 25068-38-6 NLP: 500-033-5 Reaction Product of Bisphenol A and Epichlorohydrin 0.25-<1% CAS: 872-50-4 EINECS: 212-828-1 N-methyl-2-pyrrolidone 0.1-1% 4 First-aid measures Description of first aid measures After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact:Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixtureNo further relevant information available. (Contd. on page 4) US Page 4/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Resin (Contd. of page 3) 50.0 Advice for firefighters Protective equipment:Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency proceduresNot required. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 30 mg/m 2530-83-8 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane 9.3 mg/m 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 90 mg/m 872-50-4 N-methyl-2-pyrrolidone 30 ppm PAC-2: 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 330 mg/m 2530-83-8 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane 100 mg/m 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 990 mg/m 872-50-4 N-methyl-2-pyrrolidone 32 ppm PAC-3: 28064-14-4 Epoxy phenol novolac resin Reaction product of Phenol-Formaldehyde Novolac with Epichlorohydrin 2,000 mg/m 2530-83-8 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane 230 mg/m 25068-38-6 Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m 872-50-4 N-methyl-2-pyrrolidone 190 ppm US (Contd. on page 5) Page 5/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Resin (Contd. of page 4) 50.0 * 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires:Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:No special requirements. Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems:No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 872-50-4 N-methyl-2-pyrrolidone TLV BEI WEEL Long-term value: 10 ppm Skin Ingredients with biological limit values: 872-50-4 N-methyl-2-pyrrolidone BEI 100 mg/L Medium: urine Time: end of shift Parameter: 5-Hydroxy-N-methyl-2-pyrrolidone Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. (Contd. on page 6) US Page 6/13 Safety Data Sheet acc. to OSHA HCS Printing date 01/09/2020 Reviewed on 01/09/2020 Trade name: EL337 Resin (Contd. of page 5) 50.0 Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Thixotropic Paste Color: Grey Odor: Amine-like Odor threshold: Not determined. pH-value: Not determined. Change in condition Melting point/Melting range:Undetermined. Boiling point/Boiling range:>200 C (>392 F)
Flash point: 110 C (230 F)
Flammability (solid, gaseous):Not applicable.
(Contd. on page 7)
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Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: Not determined.
Density at 20 C (68 F): 1.39 g/cm (11.6 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.5 %
VOC content: 0.47 %
6.6 g/l / 0.05 lb/gal
Solids content: 21.8 %
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
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* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral LD50 4,500 mg/kg (rat)
Primary irritant effect:
on the skin:No irritant effect.
on the eye:Irritating effect.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
14807-96-6 Talc (Mg3H2(SiO3)4) 3
13463-67-7 titanium dioxide 2B
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:
96 hr LC50 3.6 mg/l (Fish)
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
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Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT not regulated
IMDG, IATA UN3082
UN proper shipping name
DOT not regulated
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy phenol novolac resin, Epoxy Resin), MARINE
POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Epoxy phenol novolac resin, Epoxy Resin)
Transport hazard class(es)
DOT
Class not regulated
IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT not regulated
IMDG, IATA III
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Environmental hazards: Product contains environmentally hazardous substances: Epoxy
phenol novolac resin
Marine pollutant: Yes
Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 60
EMS Number: F-A,S-F
Stowage Category A
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulation”: UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (EPOXY PHENOL NOVOLAC RESIN, EPOXY
RESIN), 9, III
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
872-50-4 N-methyl-2-pyrrolidone
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
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Proposition 65
Chemicals known to cause cancer:
1317-65-3 Calcium Carbonate
13463-67-7 titanium dioxide
1333-86-4 Carbon black
14808-60-7 Quartz (SiO2)
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
872-50-4 N-methyl-2-pyrrolidone
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
13463-67-7 titanium dioxide
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane
N-methyl-2-pyrrolidone
Reaction Product of Bisphenol A and Epichlorohydrin
Hazard statements
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause cancer.
May damage fertility or the unborn child.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
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Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:
Additional classification according to Decree on Hazardous Materials:
Carcinogenic hazardous material group III (dangerous).
Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision01/09/2020 / 3
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
Skin Sens. 1: Skin sensitisation Category 1
Carc. 1B: Carcinogenicity Category 1B
Repr. 1B: Reproductive toxicity Category 1B
(Contd. on page 13)
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Aquatic Acute 2: Hazardous to the aquatic environment – acute aquatic hazard Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment – long-term aquatic hazard Category 2
* Data compared to the previous version altered. US