Page 1/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 04/06/2016 Reviewed on 04/06/2016
42 .2 .3
*
Product Identifier
Trade name: LC-E221, LC-E222, LC-E224, LC-E229, LC-E232FR, LC-E237G, LC-E237G(175), LC-E242, LC-E330,
LC-E333
Relevant identified uses of the substance or mixture and uses advised against:
Product Description Epoxy Flame Retardant Film Adhesive/Prepreg
Details of the Supplier of the Safety Data Sheet:
Manufacturer/Supplier:
Lincoln Composite Materials, Inc.
15422 Electronic Ln.
Huntington Beach, CA 92649
P 714-898-8350
F 714-894-8418
www.lcmaterials.com
Emergency telephone number:
For Hazardous Materials [or Dangerous Goods] Incident. Spill, Leak, Fire, Exposure, or Accident
Call CHEMTREC Day or Night
Within USA and Canada: 1-800-424-9300 CCN701762 or +1 703-527-3887 (collect calls accepted)
Classification of the substance or mixture:
~
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements:
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms:
~
GHS07
Signal word: Warning
Hazard-determining components of labeling:
Bisphenol A Based Epoxy Resin
Epoxy resin
Hazard statements:
H317 May cause an allergic skin reaction.
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves.
P272 Contaminated work clothing must not be allowed out of the workplace.
P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of water.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Unknown acute toxicity:
6 % of the mixture consists of component(s) of unknown toxicity.
(Contd. on page 2)
2 Hazard(s) Identification
1 Identification
GHS 07
42 .2 .3
Page 2/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 04/06/2016 Reviewed on 04/06/2016
Trade name: LC-E221, LC-E222, LC-E224, LC-E229, LC-E232FR, LC-E237G LC-E237G(175), LC-E242, LC-E330, LC-E333
Classification system:
NFPA ratings (scale 0 – 4)
Health = 0
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
Health = 0
Fire = 1
Reactivity = 0
Hazard(s) not otherwise classified (HNOC): None known
Chemical characterization: Mixtures
Description: Mixture of substances listed below with non-hazardous additions.
Dangerous Components:
25085-99-8 Bisphenol A Based Epoxy Resin 60-90%
Skin Sens. 1, H317
25036-25-3 Epoxy resin 2-12%
Skin Sens. 1, H317; Eye Irrit. 2B, H320
10097-09-3 Methylene Diphenyl Bis (Dimethyl Urea) 2.5%
Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335
1314-60-9 diantimony pentoxide 2.5%
Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335
Description of first aid measures:
After inhalation: In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation occurs, consult a doctor.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing: If swallowed and symptoms occur, consult a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed: No further relevant information available.
Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
Extinguishing media:
Suitable extinguishing agents: Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture: No further relevant information available.
Advice for firefighters:
Protective equipment:
As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent)
and full protective gear to prevent contact with skin and eyes.
(Contd. on page 3)
4 First-Aid Measures
3 Composition/Information on Ingredients
5 Fire-Fighting Measures
1
0 0
HEALTH 0
FIRE 1
REACTIVITY 0
42 .2 .3
Page 3/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 04/06/2016 Reviewed on 04/06/2016
Trade name: LC-E221, LC-E222, LC-E224, LC-E229, LC-E232FR, LC-E237G LC-E237G(175), LC-E242, LC-E330, LC-E333
Personal precautions, protective equipment and emergency procedures: Not required.
Environmental precautions: Do not allow to enter sewers/surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (i.e. sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Dispose of the collected material according to regulations.
Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Handling
Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
Specific end use(s): No further relevant information available.
Additional information about design of technical systems: No further data; see section 7.
Control parameters:
Components with occupational exposure limits:
1314-60-9 diantimony pentoxide
PEL
Long-term value: 0.5 mg/m
as Sb
REL Long-term value: 0.5 mg/m
as Sb
TLV Long-term value: 0.5 mg/m
as Sb
108-95-2 Phenol
PEL
Long-term value: 19 mg/m , 5 ppm
Skin
REL Long-term value: 19 mg/m , 5 ppm
Ceiling limit value: 60* mg/m , 15.6* ppm
*15-min; Skin
TLV Long-term value: 19 mg/m , 5 ppm
Skin; BEI
(Contd. on page 4)
6 Accidental Release Measures
7 Handling and Storage
8 Exposure Controls/Personal Protection
42 .2 .3
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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 04/06/2016 Reviewed on 04/06/2016
Trade name: LC-E221, LC-E222, LC-E224, LC-E229, LC-E232FR, LC-E237G LC-E237G(175), LC-E242, LC-E330, LC-E333
Ingredients with biological limit values:
108-95-2 Phenol
BEI 250 mg/g creatinine
urine
end of shift
Phenol with hydrolysis (background, nonspecific)
Additional information: The lists that were valid during the creation of this SDS were used as basis.
Exposure controls:
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Immediately remove all soiled and contaminated clothing and wash before reuse.
Wash hands before breaks and at the end of work.
Breathing equipment: Not required.
Protection of hands:
Protective gloves
Eye protection:
Goggles recommended during refilling.
Information on basic physical and chemical properties
General Information
Appearance:
Form: Adhesive Film
Color: Cream
Odor: N/A
Odor threshold: Not determined.
Change in condition
Melting point/Melting range: Not determined.
Boiling point/Boiling range: Not determined.
Flash point: 252 C (486 F)
Flammability (solid, gaseous): Not applicable.
Ignition temperature: > 300 C (> 572 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not self-igniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
(Contd. on page 5)
9 Physical and Chemical Properties
42 .2 .3
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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 04/06/2016 Reviewed on 04/06/2016
Trade name: LC-E221, LC-E222, LC-E224, LC-E229, LC-E232FR, LC-E237G LC-E237G(175), LC-E242, LC-E330, LC-E333
Vapor pressure: Not determined.
Density:
Relative density: Not determined.
Vapor density: Not determined.
Evaporation rate: Not determined.
Solubility in / Miscibility with:
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.2 %
VOC content: 0.2 %
Other information: No further relevant information available.
Reactivity: No further relevant information available.
Chemical stability: Stable under normal conditions.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions: No dangerous reactions known.
Conditions to avoid: No further relevant information available.
Incompatible materials: No further relevant information available.
Hazardous decomposition products: No dangerous decomposition products known.
Information on toxicological effects:
Acute toxicity:
LD/LC50 values that are relevant for classification:
25085-99-8 Bisphenol A Based Epoxy Resin
Oral
Dermal
LD50
LD50
>5000 mg/kg (rat)
20000 mg/kg (rabbit)
10097-09-3 Methylene Diphenyl Bis (Dimethyl Urea)
Oral
Dermal
LD50
LD50
>2000 mg/kg (rat)
>5000 mg/kg (rabbit)
Primary irritant effect:
On the skin: May cause an allergic skin reaction.
On the eye: No irritating effect.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Irritant
Carcinogenic categories:
IARC (International Agency for Research on Cancer):
Group 1 – Carcinogenic to humans
Group 2A – Probably carcinogenic to humans
(Contd. on page 6)
10 Stability and Reactivity
11 Toxicological Information
42 .2 .3
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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 04/06/2016 Reviewed on 04/06/2016
Trade name: LC-E221, LC-E222, LC-E224, LC-E229, LC-E232FR, LC-E237G LC-E237G(175), LC-E242, LC-E330, LC-E333
Group 2B – Possibly carcinogenic to humans
Group 3 – Not classifiable as to its carcinogenicity to humans
Group 4 – Probably not carcinogenic to humans
108-95-2 Phenol 3
NTP (National Toxicology Program):
None of the ingredients are listed.
OSHA-Ca (Occupational Safety & Health Administration):
None of the ingredients are listed.
Toxicity:
Aquatic toxicity: No further relevant information available.
Persistence and degradability: No further relevant information available.
Behavior in environmental systems:
Bioaccumulative potential: No further relevant information available.
Mobility in soil: No further relevant information available.
Additional ecological information:
General notes:
Do not allow undiluted product or product that has not been neutralized to reach ground water, water course
or sewage system.
Results of PBT and vPvB assessment:
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects: No further relevant information available.
Waste treatment methods:
Recommendation:
Observe all federal, state and local environmental regulations when disposing of this material.
Uncleaned packagings
Recommendation: Disposal must be made according to official regulations.
UN-Number:
DOT, ADR, ADN, IMDG, IATA Non-Regulated Material
UN proper shipping name:
DOT, ADR, ADN, IMDG, IATA Non-Regulated Material
Transport hazard class(es):
DOT, ADR, ADN, IMDG, IATA
Class: Non-Regulated Material
Packing group:
DOT, ADR, IMDG, IATA Non-Regulated Material
Environmental hazards: Not applicable.
Special precautions for user: Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code: Not applicable.
UN “Model Regulation”: Non-Regulated Material
(Contd. on page 7)
12 Ecological Information
13 Disposal Considerations
14 Transport Information
42 .2 .3
Page 7/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 04/06/2016 Reviewed on 04/06/2016
Trade name: LC-E221, LC-E222, LC-E224, LC-E229, LC-E232FR, LC-E237G LC-E237G(175), LC-E242, LC-E330, LC-E333
Safety, health and environmental regulations/legislation specific for the substance or mixture:
SARA (Superfund Amendments and Reauthorization):
Section 355 (extremely hazardous substances):
108-95-2 Phenol
Section 313 (Specific toxic chemical listings):
1314-60-9 diantimony pentoxide
108-95-2 Phenol
TSCA (Toxic Substances Control Act):
All ingredients are listed or exempt from listing.
California Proposition 65:
Chemicals known to cause cancer:
None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed.
Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
New Jersey Right-to-Know List:
108-95-2 Phenol
New Jersey Special Hazardous Substance List:
108-95-2 Phenol MU, F2
Pennsylvania Right-to-Know List:
None of the ingredients are listed.
Pennsylvania Special Hazardous Substance List:
108-95-2 Phenol E
Carcinogenic categories:
EPA (Environmental Protection Agency):
108-95-2 Phenol D, I
TLV (Threshold Limit Value established by ACGIH):
108-95-2 Phenol A4
NIOSH-Ca (National Institute for Occupational Safety and Health):
None of the ingredients are listed.
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms:
~
GHS07
(Contd. on page 8)
15 Regulatory Information
42 .2 .3
Page 8/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 04/06/2016 Reviewed on 04/06/2016
Trade name: LC-E221, LC-E222, LC-E224, LC-E229, LC-E232FR, LC-E237G LC-E237G(175), LC-E242, LC-E330, LC-E333
National regulations:
Signal word: Warning
Hazard-determining components of labeling:
Bisphenol A Based Epoxy Resin
Epoxy resin
Hazard statements:
H317 May cause an allergic skin reaction.
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves.
P272 Contaminated work clothing must not be allowed out of the workplace.
P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of water.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as
of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall not
establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of
this information and the suitability of the material or product for any particular purpose.
Date of preparation / last revision: 04/06/2016 / 3
Abbreviations and acronyms:
ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
Eye Irrit. 2B: Serious eye damage/eye irritation, Hazard Category 2B
Skin Sens. 1: Sensitisation – Skin, Hazard Category 1
STOT SE 3: Specific target organ toxicity – Single exposure, Hazard Category 3
* Data compared to the previous version altered.
SDS created by MSDS Authoring Services www.msdsauthoring.com +1-877-204-9106
16 Other Information
The product is subject to be classified according with the latest version of the regulations on hazardous
substances.