SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 1 of 12
1. Product and company identification
Product identifier
Trade name: Toolfusion 3A
Relevant identified uses of the substance or mixture and uses advised against
General use: Epoxy resin
For industrial purposes only
Details of the supplier of the safety data sheet
Company name:
Airtech International, Inc.
5700 Skylab Road
Huntington Beach, CA 92647
E-mail: airtech@airtechintl.com
Website: www.airtechonline.com
Telephone: +1 714.899.8100
Dept. responsible for information:
Telephone: +1 714.899.8100
E-mail: airtech@airtechintl.com
Airtech Europe Sarl
Zone industrielle Haneboesch
L 4562 Differdange
Luxembourg
Website: www.airtech.lu
Telephone: +352 582.282
Dept. responsible for information:
Telephone: +352 582.282
E-mail: sales@airtech.lu
Tygavac Advanced Materials Ltd.
The Causeway
Broadway Business Park
Chadderton, Oldham
OL9 9XD United Kingdom
Website: www.tygavac.co.uk
Telephone: +44 161.947.1610
Dept. responsible for information:
Telephone: +44 161.947.1610
E-mail: sales@tygavac.co.uk
Airtech Asia Ltd.
No. 161 of Anyuan Rd
Chagugang County
Wuqing District
301721, Tianjin, P.R. China
Website: www.airtech.asia
Telephone: +86 22 8862 9800
Telefax:: +86 22 8862 9900
Dept. responsible for information:
Telephone: +86 22 8862 9800
E-mail: airtech.asia@airtechasia.com.cn
Emergency phone number
CHEMTREC EMERGENCY PHONE:
Within USA/Canada: 1-(800)424-9300
International: +1 703-741-5970
2. Hazards identification
Emergency overview
Appearance: Form: liquid
Color: yellowish
Odor: characteristic
Classification: Sensitization – skin – Category 1;
Hazard symbols:
Signal word: Warning
Hazard statements:
May cause an allergic skin reaction.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 2 of 12
Precautionary statements:
Avoid breathing vapors.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of water/soap.
Specific treatment (see ‘ First aid ‘ on this label).
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Dispose of contents/container to hazardous or special waste collection point.
Regulatory status
This material is considered hazardous by the U.S. OSHA Hazard Communication
Standard (29 CFR 1910.1200) and SIMDUT in Canada.
Hazards not otherwise classified
see section 11: Toxicological information
3. Composition / Information on ingredients
Chemical characterization:
Epoxy resin and traces of Styrene, 1,3-Butadiene, Acrylonitrile, Methyl methacrylate.
Relevant ingredients:
CAS No. Designation Content Classification
CAS
2386-87-0
7-Oxabicyclo[4.1.0]hept-3-ylmethyl-7-
oxabicyclo[4.1.0]heptane-3-carboxylate
>= 70 % Sensitization – skin –
Category 1.
Additional information:The maximum workplace exposure limits are, where necessary, listed in section 8.
4. First aid measures
In case of inhalation:Move victim to fresh air; if necessary, provide artificial respiration or oxygen.
Seek medical attention.
Following skin contact:Contaminated/fouled clothing and shoes must be removed immediately.
Immediately clean with water and soap followed by thorough rinsing.
Seek medical treatment in case of troubles.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently seek the immediate attention of an ophthalmologist.
After swallowing: Never give anything by mouth to an unconscious person. Rinse mouth with water.
Consult physician immediately.
Most important symptoms/effects, acute and delayed
May cause an allergic skin reaction.
Information to physician
Treat symptomatically.
5. Fire fighting measures
Flash point/flash point range:
395.6 F
Auto-ignition temperature:
No data available
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 3 of 12
Suitable extinguishing media:
Water spray jet, dry chemical powder, foam, carbon dioxide.
Extinguishing media which must not be used for safety reasons:
Full water jet.
Specific hazards arising from the chemical
In case of fire may be liberated: Phenols, carbon monoxide and carbon dioxide.
Formation of numerous unknown compounds is possible.
Protective equipment and precautions for firefighters:
Wear self-contained breathing apparatus. Wear appropriate protective equipment.
Additional information:Cool endangered containers with water spray and, if possible, remove from danger zone.
Use a water fog to control vapors. Do not breathe fumes.
Do not allow water used to extinguish fire to enter drains, ground or waterways.
6. Accidental release measures
Personal precautions:Avoid contact with skin, eyes, and clothing. Do not breathe vapor or spray.
Wear appropriate protective equipment. Ensure adequate ventilation, especially in
confined areas.
Keep unprotected people away. Take off contaminated clothing and wash it before reuse.
Environmental precautions:
Do not allow to penetrate into soil, waterbodies or drains.
Methods for clean-up:Plug leak if safely possible.
Soak up with absorbent materials such as sand, siliceus earth, acid- or universal binder.
Store in special closed containers and dispose of according to ordinance.
In case of greater quantities: Collect mechanically (use only explosion-proof equipment
when pumping out).
7. Handling and storage
Handling
Advices on safe handling:Provide adequate ventilation, and local exhaust as needed.
Avoid contact with skin, eyes, and clothing. Do not breathe vapor or spray.
Wear appropriate protective equipment. When using do not eat, drink or smoke.
Take off contaminated clothing and wash it before reuse.
Precautions against fire and explosion:
Usual measures for fire prevention.
Storage
Requirements for storerooms and containers:
Keep container tightly closed in a cool, well-ventilated place.
Take care when re-opening already used containers.
Protect from heat and direct sunlight. Keep container dry.
Handle empty containers with care. Incineration may cause explosion.
Hints on joint storage:Do not store together with strong bases, oxidizing agents, strong acids or amines.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 4 of 12
8. Exposure controls / personal protection
Exposure guidelines
Occupational exposure limit values:
CAS No.Designation Type Limit value
100-42-5Styrene USA: ACGIH: STEL 170 mg/m ; 40 ppm
USA: ACGIH: TWA 85 mg/m ; 20 ppm
USA: NIOSH: STEL 425 mg/m ; 100 ppm
USA: NIOSH: TWA 215 mg/m ; 50 ppm
USA: OSHA: Ceiling 200 ppm
(Acceptable maximum peak above
the acceptable ceiling concentration
for an 8-hr shift: 600 ppm 5 mins. in
any 3 hrs.)
USA: OSHA: TWA 100 ppm
(Acceptable maximum peak above
the acceptable ceiling concentration
for an 8-hr shift: 600 ppm 5 mins. in
any 3 hrs.)
80-62-6Methyl
methacrylate
USA: ACGIH: STEL 410 mg/m ; 100 ppm
USA: ACGIH: TWA 205 mg/m ; 50 ppm
USA: NIOSH: TWA 410 mg/m ; 100 ppm
USA: OSHA: TWA 410 mg/m ; 100 ppm
106-99-01,3-Butadiene USA: ACGIH: TWA 4.4 mg/m ; 2 ppm
USA: OSHA: STEL 11 mg/m ; 5 ppm
USA: OSHA: TWA 2.21 mg/m ; 1 ppm
107-13-1Acrylonitrile USA: ACGIH: TWA 4.3 mg/m ; 2 ppm
(may be absorbed through the skin)
USA: NIOSH: Ceiling 10 ppm
(may be absorbed through the skin)
USA: NIOSH: TWA 1 ppm
(may be absorbed through the skin)
USA: OSHA: Ceiling 10 ppm
(may be absorbed through the skin)
USA: OSHA: TWA 2 ppm
(may be absorbed through the skin)
Biological limit values:
CAS No.DesignationType Limit valueParameter Sampling
100-42-5Styrene USA:
ACGIH-
BEI, urine
40 g/L Styrene in urine end of
exposure or
end of shift
USA:
ACGIH-
BEI, urine
400 mg/g
creatinine
Mandelic acid + Phenylglyoxylic
acid
end of
exposure or
end of shift
106-99-01,3-ButadieneUSA:
ACGIH-
BEI, blood
2.5 pmol/g HbMixture of N-1 and
N2-(hydroxybutenyl)valine
hemoglobin (Hb) adduts
No restriction
USA:
ACGIH-
BEI, urine
2.5 mg/L 1,2
Dihydroxy-4-(N-acetylcysteinyl)-
butane
end of
exposure or
end of shift
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 5 of 12
Engineering controls
Provide adequate ventilation, and local exhaust as needed.
See also information in chapter 7, section storage.
Personal protection equipment (PPE)
Eye/face protectionTightly sealed goggles according to OSHA Standard – 29 CFR: 1910.133 or ANSI
Z87.1-2010.
Skin protection Wear suitable protective clothing.
Protective gloves according to OSHA Standard – 29 CFR: 1910.138.
Glove material: Neoprene.
Observe glove manufacturer’s instructions concerning penetrability and breakthrough time.
Respiratory protection:When vapors form, use respiratory protection.
Recommended: Use filter type A (= against vapors of organic substances) according to
OSHA Standard – 29 CFR: 1910.134 or ANSI Z88.2.
The filter class must be suitable for the maximum contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when handling the product. If the
concentration is exceeded, self-contained breathing apparatus must be used.
General hygiene considerations:
Avoid contact with skin, eyes, and clothing.
Do not breathe vapor or spray. Wear appropriate protective equipment.
Work place should be equipped with a shower and an eye rinsing apparatus.
When using do not eat, drink or smoke.
Wash hands before breaks and after work.
Take off contaminated clothing and wash it before reuse.
9. Physical and chemical properties
Information on basic physical and chemical properties
Appearance: Form: liquid
Color: yellowish
Odor: characteristic
Odor threshold: No data available
pH value: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range:> 482 F
Flash point/flash point range: 395.6 F
Evaporation rate: No data available
Flammability: No data available
Explosion limits: No data available
Vapor pressure: No data available
Vapor density: No data available
Density: 1.1 g/mL
Water solubility: negligible
Partition coefficient: n-octanol/water:No data available
Auto-ignition temperature: No data available
Thermal decomposition: No data available
Additional information: No data available
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 6 of 12
10. Stability and reactivity
Reactivity: No data available
Chemical stability:Stable under recommended storage conditions.
Possibility of hazardous reactions
Avoid contact with: amines (aliphatic). Polymerization along with heat production.
Conditions to avoid:Keep away from heat sources, sparks and open flames.
Heating will lead to pressure increase: Danger of bursting and explosion.
Incompatible materials:Strong oxidizing agents, Lewis-acid or mineral acids and bases (organic and inorganic).
Hazardous decomposition products:
Emits toxic fumes under fire conditions.
In case of fire may be liberated: phenols, carbon monoxide and carbon dioxide.
Formation of numerous unknown compounds is possible.
Thermal decomposition:No data available
11. Toxicological information
Toxicological tests
Toxicological effects:The statements are derived from the properties of the single components. No toxicological
data is available for the product as such.
Acute toxicity (oral): Lack of data.
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Lack of data.
Serious eye damage/irritation: Lack of data.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Sensitization – skin – Category 1 = May cause an allergic skin reaction.
Germ cell mutagenicity/Genotoxicity: Lack of data.
Carcinogenicity: Lack of data.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 7 of 12
Other information: Information about styrene:
Harmful if inhaled. Suspected of damaging fertility or the unborn child. Causes damage
to organs through prolonged or repeated exposure. lung damages May be fatal if
swallowed and enters airways. Causes serious eye irritation. Causes skin irritation.
For carcinogenic effects: IARC Rating: Group 2B OSHA Carcinogen: not listed NTP
Rating: not listed
Information about 1,3-Butadiene:
May cause cancer. May cause genetic defects.
Information about Acrylonitrile:
Toxic if swallowed, in contact with skin or if inhaled. May cause cancer. Causes serious
eye damage. May cause an allergic skin reaction. Causes skin irritation. May cause
respiratory irritation.
Information about Methyl methacrylate:
May cause an allergic skin reaction. Causes skin irritation. May cause respiratory
irritation.
Symptoms
In case of ingestion:
Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal
tract.
After eye contact: Causes tears. Pain, redness.
12. Ecological information
Ecotoxicity
Aquatic toxicity: Information about
7-Oxabicyclo[4.1.0]hept-3-ylmethyl-7-oxabicyclo[4.1.0]heptane-3-carboxylate:
Fish toxicity:
EC50 Oncorhynchus mykiss: 24 mg/L/96 h (OECD 203).
Daphnia toxicity:
LC50 Daphnia magna (Big water flea): 40 mg/L/48h (OECD 202).
Algae toxicity:
EC50 Pseudokirchneriella subcapitata (green algae): 90 mg/L/72h (OECD 201).
Effects in sewage plants:Information about
7-Oxabicyclo[4.1.0]hept-3-ylmethyl-7-oxabicyclo[4.1.0]heptane-3-carboxylate:
Toxicity to microorganisms:
EC50 activated sludge: >2000 mg/L/3h (OECD 209).
Mobility in soil
No data available
Persistence and degradability
Further details: No data available
Additional ecological information
General information:Do not allow to penetrate into soil, waterbodies or drains.
13. Disposal considerations
Product
Recommendation: Incinerate as hazardous waste according to applicable local, state, and federal regulations.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 8 of 12
Contaminated packaging
Recommendation: Waste key number 150102: Plastic container
Waste key number 150104: Packages of metal
Empty carefully and completely, if possible.
Dispose of waste according to applicable legislation.
14. Transport information
USA: Department of Transportation (DOT)
Proper shipping name: Not restricted
Sea transport (IMDG)
Proper shipping name: Not restricted
Marine pollutant: no
Air transport (IATA)
Proper shipping name: Not restricted
Further information
No dangerous good in sense of these transport regulations.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 9 of 12
15. Regulatory information
National regulations – U.S. Federal Regulations
7-Oxabicyclo[4.1.0]hept-3-ylmethyl-7-
oxabicyclo[4.1.0]heptane-3-carboxylate:
TSCA Inventory: listed
TSCA HPVC: not listed
Styrene: TSCA Inventory: listed
TSCA HPVC: not listed
Carcinogen Status:
IARC Rating: Group 2B
OSHA Carcinogen: not listed
NTP Rating: listed
Clean Air Act:
Hazardous Air Pollutants: Code XOV
SOCMI Chemical: yes
Clean Water Act:
Hazardous Substances: RQ 1000 lbs.
Other Environmental Laws:
CERCLA: RQ 1000 lbs.
RCRA Groundwater Monitoring: Methods 8020, 8240
/ PQL 1, 5
SARA Title III Section 313, Toxic Release: Conc.
0.1% / Threshold Standard
NIOSH Recommendations:
Occupational Health Guideline: 0571
Methyl methacrylate: TSCA Inventory: listed; EPA flags T
TSCA HPVC: not listed
TSCA: listed – Flags: T
Carcinogen Status:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Clean Air Act:
Hazardous Air Pollutants: Code XOV
SOCMI Chemical: yes
Clean Water Act:
Hazardous Substances: RQ 1000 lbs.
Other Environmental Laws:
CERCLA: RQ 1000 lbs.
RCRA Hazardous Wastes: Code U162
RCRA Groundwater Monitoring: Methods 8015, 8240
/ PQL 2, 5
SARA Title III Section 313, Toxic Release: Conc.
1.0% / Threshold Standard
NIOSH Recommendations:
Occupational Health Guideline: 0426
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 10 of 12
1,3-Butadiene: TSCA Inventory: listed
TSCA HPVC: not listed
Carcinogen Status:
IARC Rating: Group 1
OSHA Carcinogen: listed
NTP Rating: listed
Clean Air Act:
Accidental Release Prevention: Threshold 10000 lbs.
/ Basis for listing = f
Hazardous Air Pollutants: Code XOV
SOCMI Chemical: yes
Other Environmental Laws:
CERCLA: RQ 10 lbs.
SARA Title III Section 313, Toxic Release: Conc.
0.1% / Threshold Standard
NIOSH Recommendations:
Occupational Health Guideline: 0067
Acrylonitrile: TSCA Inventory: listed; EPA flags T
TSCA HPVC: not listed
Carcinogen Status:
IARC Rating: Group 2B
OSHA Carcinogen: listed
NTP Rating: listed
Clean Air Act:
Accidental Release Prevention: Threshold 20000 lbs.
/ Basis for listing = b
Hazardous Air Pollutants: Code XOV
SOCMI Chemical: yes
Clean Water Act:
Hazardous Substances: RQ 100 lbs.
Priority Pollutant: yes
Other Environmental Laws:
CERCLA: RQ 100 lbs.
RCRA Hazardous Wastes: Code U009
RCRA Groundwater Monitoring: Methods 8030, 8240
/ PQL 5, 5
SARA Title III Section 302, EHS: TPQ 10000 lbs. /
RQ 100 lbs.
SARA Title III Section 313, Toxic Release: Conc.
0.1% / Threshold Standard
NIOSH Recommendations:
Occupational Health Guideline: 0014
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 11 of 12
National regulations – U.S. State Regulations
Styrene: Delaware Air Quality Management List:
DRQ: 1000 – RQ State: Federal Regulations Apply
Idaho Air Pollutant List:
Title 585 — AAC: 1 — EL: 6.67 — WEL: – Title 586 –
Maine Hazardous Air Pollutants:
Me 2005: HAP – Hap Rpt: 2000
Massachusetts Haz. Substance codes: 1,2,4,5,6,9 *E*C* F7 F8
Michigan Critical Material:
Note: 2 – CMR#: 27 – Parameter#: 00100-42-5 – Annual Usage Parameter: 100
Minnesota Haz. Substance:
Codes: ANO — Ratings: 9.63 — Status: Air Pollutant. Carcinogen. Title III. TRI.
New Jersey RTK Hazardous Substance:
DOT 2055 – Sub No.: 1748 – TPQ: –
New York List of Hazardous Substances:
RQ — Air: 1000 – RQ — Land: 1 – Note: No Note Associated with this chemical.
Pennsylvania Haz. Substance code: E
Washington Air Contaminant:
TWA: 50 ppm / 215 mg — STEL: 100 ppm / 425 mg
California Proposition 65: cancer
Methyl methacrylate:Delaware Air Quality Management List:
DRQ: 1000 – RQ State: Federal Regulations Apply
Idaho Air Pollutant List:
Title 585; AAC: 20,5 – EL: 27,3 – OEL: 410 – Title 586: –
Massachusetts Haz. Substance Codes: 2,4,5,6 F8 F9
Main: HAP – 2000
Minnesota Haz. Substance:
Codes: AO – Ratings: 3.79 – Status: Air Pollutant. Title III. TRI.
New Jersey RTK Hazardous Substance:
DOT: 1247 – Sub No.: 1277
New York List of Hazardous Substances:
RQ-Air: 1000 – RQ-Land: 1
No Note Associated with this chemical
Pennsylvania Haz. Substance Code: E
Washington Air Contaminant: TWA: 100 ppm = 410 mg
1,3-Butadiene: California Proposition 65: cancer
Acrylonitrile: California Proposition 65: cancer
National regulations – Great Britain
Hazchem-Code: –
16. Other information
Text for labeling: Contains >= 70 %
7-Oxabicyclo[4.1.0]hept-3-ylmethyl-7-oxabicyclo[4.1.0]heptane-3-carboxylate. Safety
data sheet available on request.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3A
Material number 1070
Revision date: 9/4/2018
Version: 7
Language: en-US
Date of first version:4/22/2010
Page: 12 of 12
Hazard rating systems:
1
20
NFPA Hazard Rating:
Health: 2 (Moderate)
Fire: 1 (Slight)
Reactivity: 0 (Minimal)
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
X
HMIS Version III Rating:
Health: 2 (Moderate)
Flammability: 1 (Slight)
Physical Hazard: 0 (Minimal)
Personal Protection: X = Consult your supervisor
Reason of change: Changes in section 1: Company/undertaking identification
Department issuing data sheet
Contact person: see section 1: Dept. responsible for information
This data sheet cannot cover all possible situations which the user may experience during processing. Each
aspect of your operation should be examined to determine if, and which additional precautions may be
necessary. All health and safety information contained in this data sheet should be provided to your
employees and customers. It is your responsibility to develop appropriate workplace instructions and training
programs for employees.
As the conditions and methods of use are beyond our control, we do not assume any responsibility and
expressly disclaim any liability for any use of this product. The information supplied on this safety data sheet
complies with our current level of knowledge as well as with national and EU regulations. All statements or
suggestions are made without warranty, expressed or implied, regarding accuracy of information, the
hazards connected with the use of the product or the results to be obtained from the use thereof.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3B
Material number 1071
Revision date: 9/4/2018
Version: 8
Language: en-US
Date of first version:4/23/2010
Page: 1 of 7
1. Product and company identification
Product identifier
Trade name: Toolfusion 3B
Relevant identified uses of the substance or mixture and uses advised against
General use: Modified Anhydride Curing Agent.
For industrial purposes only.
Details of the supplier of the safety data sheet
Company name:
Airtech International, Inc.
5700 Skylab Road
Huntington Beach, CA 92647
E-mail: airtech@airtechintl.com
Website: www.airtechonline.com
Telephone: +1 714.899.8100
Dept. responsible for information:
Telephone: +1 714.899.8100
E-mail: airtech@airtechintl.com
Airtech Europe Sarl
Zone industrielle Haneboesch
L 4562 Differdange
Luxembourg
Website: www.airtech.lu
Telephone: +352 582.282
Dept. responsible for information:
Telephone: +352 582.282
E-mail: sales@airtech.lu
Tygavac Advanced Materials Ltd.
The Causeway
Broadway Business Park
Chadderton, Oldham
OL9 9XD United Kingdom
Website: www.tygavac.co.uk
Telephone: +44 161.947.1610
Dept. responsible for information:
Telephone: +44 161.947.1610
E-mail: sales@tygavac.co.uk
Airtech Asia Ltd.
No. 161 of Anyuan Rd
Chagugang County
Wuqing District
301721, Tianjin, P.R. China
Website: www.airtech.asia
Telephone: +86 22 8862 9800
Telefax:: +86 22 8862 9900
Dept. responsible for information:
Telephone: +86 22 8862 9800
E-mail: airtech.asia@airtechasia.com.cn
Emergency phone number
CHEMTREC EMERGENCY PHONE:
Within USA/Canada: 1-(800)424-9300
International: +1 703-741-5970
2. Hazards identification
Emergency overview
Appearance: Form: liquid
Color: colorless, clear
Odor: characteristic
Classification: Eye Damage – Category 1; Respiratory Sensitizer – Category 1; Sensitization – skin –
Category 1;
Hazard symbols:
Signal word: Danger
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3B
Material number 1071
Revision date: 9/4/2018
Version: 8
Language: en-US
Date of first version:4/23/2010
Page: 2 of 7
Hazard statements:
May cause an allergic skin reaction.
Causes serious eye damage.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Precautionary statements:
Avoid breathing vapors.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection.
[In case of inadequate ventilation] wear respiratory protection.
IF ON SKIN: Wash with plenty of water/soap.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
Immediately call a POISON CENTER/doctor.
Specific treatment (see ‘ First aid ‘ on this label).
If skin irritation or rash occurs: Get medical advice/attention.
If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
Take off contaminated clothing and wash it before reuse.
Dispose of contents/container to hazardous or special waste collection point.
Regulatory status
This material is considered hazardous by the U.S. OSHA Hazard Communication
Standard (29 CFR 1910.1200) and SIMDUT in Canada.
Hazards not otherwise classified
see section 11: Toxicological information
3. Composition / Information on ingredients
Relevant ingredients:
CAS No. Designation Content Classification
CAS
19438-60-9
Hexahydro-4-
methylphthalic
anhydride
97.8 – 100 % Eye Damage – Category 1.
Respiratory Sensitizer – Category 1.
Sensitization – skin – Category 1.
4. First aid measures
In case of inhalation:Move victim to fresh air; if necessary, provide artificial respiration or oxygen. Seek
medical attention.
Following skin contact:Immediately clean with water and soap followed by thorough rinsing. Take off
immediately all contaminated clothing and wash it before reuse. In case of skin irritation,
consult a physician.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently seek the immediate attention of an ophthalmologist.
After swallowing: Rinse mouth with water. Do not induce vomiting.
Give affected person large quantities of water, better milk. Seek medical attention.
Never give anything by mouth to an unconscious person.
Most important symptoms/effects, acute and delayed
May cause an allergic skin reaction.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Causes serious eye damage.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3B
Material number 1071
Revision date: 9/4/2018
Version: 8
Language: en-US
Date of first version:4/23/2010
Page: 3 of 7
Information to physician
Treat symptomatically.
5. Fire fighting measures
Flash point/flash point range:
230 F (Hexahydro-4-methylphthalic anhydride)
Auto-ignition temperature:
No data available
Suitable extinguishing media:
Water spray jet, foam, dry chemical powder, carbon dioxide.
Extinguishing media which must not be used for safety reasons:
Full water jet.
Specific hazards arising from the chemical
Emits toxic fumes under fire conditions.
In case of fire may be liberated: hydrocarbons, carbon monoxide and carbon dioxide.
Protective equipment and precautions for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information:Seal off endangered area. Heating causes rise in pressure with risk of bursting. Cool
endangered containers with water spray and, if possible, remove from danger zone. Fight
fire from a safe distance. Stay upwind/keep distance from source.
6. Accidental release measures
Personal precautions:Provide adequate ventilation. Avoid contact with skin, eyes, and clothing. Do not breathe
vapor or spray. Wear appropriate protective equipment.
Environmental precautions:
Do not allow to penetrate into soil, waterbodies or drains.
Methods for clean-up:Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal
binding agents) and place in closed containers for disposal.
7. Handling and storage
Handling
Advices on safe handling:Provide adequate ventilation, and local exhaust as needed. Avoid contact with skin, eyes,
and clothing. Do not breathe vapor or spray. Wear appropriate protective equipment.
When using do not eat, drink or smoke. Wash hands before breaks and after work.
Precautions against fire and explosion:
Keep away from heat sources, sparks and open flames.
Storage
Requirements for storerooms and containers:
Keep container tightly closed in a cool, well-ventilated place. Keep container dry.
Do not drop, drag or bang the container. Protect from frost. Protect against direct sunlight.
Hints on joint storage:Keep away from food and drinks.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3B
Material number 1071
Revision date: 9/4/2018
Version: 8
Language: en-US
Date of first version:4/23/2010
Page: 4 of 7
8. Exposure controls / personal protection
Engineering controls
Provide good ventilation and/or an exhaust system in the work area.
See also information in chapter 7, section storage.
Personal protection equipment (PPE)
Eye/face protectionTightly sealed goggles according to OSHA Standard – 29 CFR: 1910.133 or ANSI
Z87.1-2010.
Skin protection Wear suitable protective clothing.
Protective gloves according to OSHA Standard – 29 CFR: 1910.138.
Glove material: Rubber.
Observe glove manufacturer’s instructions concerning penetrability and breakthrough time.
Respiratory protection:When vapors form, use respiratory protection.
Use filter type A (= against vapors of organic substances) according to OSHA Standard –
29 CFR: 1910.134 or ANSI Z88.2.
General hygiene considerations:
Avoid contact with skin, eyes, and clothing. Do not breathe vapor or spray. Work place
should be equipped with a shower and an eye rinsing apparatus. When using do not eat,
drink or smoke. Wash hands before breaks and after work.
9. Physical and chemical properties
Information on basic physical and chemical properties
Appearance: Form: liquid
Color: colorless, clear
Odor: characteristic
Odor threshold: No data available
pH value: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range:No data available
Flash point/flash point range: 230 F (Hexahydro-4-methylphthalic anhydride)
Evaporation rate: No data available
Flammability: No data available
Explosion limits: No data available
Vapor pressure: 5.7 hPa
Vapor density: No data available
Density: 1.16 g/mL
Water solubility: Contact with water liberates acid.
Partition coefficient: n-octanol/water:No data available
Auto-ignition temperature: No data available
Thermal decomposition: No data available
Viscosity, kinematic: 90 – 110 mPa*s
Solid content: >= 99 %
10. Stability and reactivity
Reactivity: Contact with water liberates acid.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3B
Material number 1071
Revision date: 9/4/2018
Version: 8
Language: en-US
Date of first version:4/23/2010
Page: 5 of 7
Chemical stability:Stable under recommended storage conditions.
Possibility of hazardous reactions
Hazardous polymerisation: Will not occur.
Conditions to avoid:Excessive heating, humidity. Keep away from heat sources, sparks and open flames.
Avoid the formation of aerosol/vapors.
Incompatible materials:Avoid contact with strong oxidizing agents and Water .
Hazardous decomposition products:
In case of fire may be liberated: hydrocarbons, carbon monoxide and carbon dioxide.
Thermal decomposition:No data available
11. Toxicological information
Toxicological tests
Toxicological effects:Acute toxicity (oral): Lack of data.
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Lack of data.
Serious eye damage/irritation: Eye Damage – Category 1 = Causes serious eye damage.
Sensitisation to the respiratory tract: Respiratory Sensitizer –
Category 1 = May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Skin sensitisation: Sensitization – skin – Category 1 = May cause an allergic skin reaction.
Germ cell mutagenicity/Genotoxicity: Lack of data.
Carcinogenicity: Lack of data.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.
Symptoms
In case of inhalation:
Symptoms: Tickel in the throat, cough, wheezing, shortness of breath.
After contact with skin: Upon direct contact with skin may cause itching and redness.
12. Ecological information
Ecotoxicity
Further details: No data available
Mobility in soil
No data available
Persistence and degradability
Further details: No data available
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3B
Material number 1071
Revision date: 9/4/2018
Version: 8
Language: en-US
Date of first version:4/23/2010
Page: 6 of 7
Additional ecological information
General information:Do not allow to penetrate into soil, waterbodies or drains.
13. Disposal considerations
Product
Recommendation: Incinerate as hazardous waste according to applicable local, state, and federal regulations.
Contaminated packaging
Recommendation: Waste key number 150102 – Plastic packaging
Waste key number 150104 – Metallic packaging
Dispose of waste according to applicable legislation.
14. Transport information
USA: Department of Transportation (DOT)
Proper shipping name: Not restricted
Sea transport (IMDG)
Proper shipping name: Not restricted
Marine pollutant: no
Air transport (IATA)
Proper shipping name: Not restricted
Further information
No dangerous good in sense of these transport regulations.
15. Regulatory information
National regulations – U.S. Federal Regulations
Hexahydro-4-methylphthalic anhydride:TSCA Inventory: listed
TSCA HPVC: not listed
National regulations – Great Britain
Hazchem-Code: –
16. Other information
Text for labeling: Contains 97.8 – 100 % Hexahydro-4-methylphthalic anhydride. Safety data sheet
available on request.
Hazard rating systems:
1
21
NFPA Hazard Rating:
Health: 2 (Moderate)
Fire: 1 (Slight)
Reactivity: 1 (Slight)
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
X
HMIS Version III Rating:
Health: 2 (Moderate)
Flammability: 1 (Slight)
Physical Hazard: 1 (Slight)
Personal Protection: X = Consult your supervisor
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
Toolfusion 3B
Material number 1071
Revision date: 9/4/2018
Version: 8
Language: en-US
Date of first version:4/23/2010
Page: 7 of 7
Reason of change: Changes in section 1: Company/undertaking identification
Department issuing data sheet
Contact person: see section 1: Dept. responsible for information
This data sheet cannot cover all possible situations which the user may experience during processing. Each
aspect of your operation should be examined to determine if, and which additional precautions may be
necessary. All health and safety information contained in this data sheet should be provided to your
employees and customers. It is your responsibility to develop appropriate workplace instructions and training
programs for employees.
As the conditions and methods of use are beyond our control, we do not assume any responsibility and
expressly disclaim any liability for any use of this product. The information supplied on this safety data sheet
complies with our current level of knowledge as well as with national and EU regulations. All statements or
suggestions are made without warranty, expressed or implied, regarding accuracy of information, the
hazards connected with the use of the product or the results to be obtained from the use thereof.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT