SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 1 of 9
1. Product and company identification
Product identifier
Trade name: TMFP 3100, 3200
Relevant identified uses of the substance or mixture and uses advised against
General use: Fiberglass / epoxy prepreg
For industrial purposes only
Details of the supplier of the safety data sheet
Company name:
Airtech International, Inc.
5700 Skylab Road
Huntington Beach, CA 92647
E-mail: airtech@airtechintl.com
Website: www.airtechonline.com
Telephone: +1 714.899.8100
Dept. responsible for information:
Telephone: +1 714.899.8100
E-mail: airtech@airtechintl.com
Airtech Europe Sarl
Zone industrielle Haneboesch
L 4562 Differdange
Luxembourg
Website: www.airtech.lu
Telephone: +352 582.282
Dept. responsible for information:
Telephone: +352 582.282
E-mail: sales@airtech.lu
Tygavac Advanced Materials Ltd.
The Causeway
Broadway Business Park
Chadderton, Oldham
OL9 9XD United Kingdom
Website: www.tygavac.co.uk
Telephone: +44 161.947.1610
Dept. responsible for information:
Telephone: +44 161.947.1610
E-mail: sales@tygavac.co.uk
Airtech Asia Ltd.
No. 161 of Anyuan Rd
Chagugang County
Wuqing District
301721, Tianjin, P.R. China
Website: www.airtech.asia
Telephone: +86 22 8862 9800
Telefax:: +86 22 8862 9900
Dept. responsible for information:
Telephone: +86 22 8862 9800
E-mail: airtech.asia@airtechasia.com.cn
Emergency phone number
CHEMTREC EMERGENCY PHONE:
Within USA/Canada: 1-(800)424-9300
International: +1 703-741-5970
2. Hazards identification
Emergency overview
Appearance: Physical state at 68 F and 101.3 kPa: solid
Form: Carbon fabric impregnated with viscous blue paste
Color: blue
Odor: characteristic
Classification: Skin Irritation – Category 2; Eye Irritation – Category 2A; Sensitization – skin –
Category 1; Germ cell mutagenicity – Category 2; Carcinogenicity – Category 2;
Aquatic toxicity – chronic – Category 2;
Hazard symbols:
Signal word: Warning
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 2 of 9
Hazard statements:
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Suspected of causing genetic defects.
Suspected of causing cancer.
Toxic to aquatic life with long lasting effects.
Precautionary statements:
Obtain special instructions before use.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wash hands and face thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of water/soap.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see ‘ First aid ‘ on this label).
If skin irritation occurs: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
Collect spillage.
Store locked up.
Dispose of contents/container to hazardous or special waste collection point.
Regulatory status
This material is considered hazardous by the U.S. OSHA Hazard Communication
Standard (29 CFR 1910.1200) and SIMDUT in Canada.
Hazards not otherwise classified
see section 11: Toxicological information
3. Composition / Information on ingredients
Chemical characterization:
Fibreglass fabric impregnated with an epoxy resin system
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 3 of 9
Relevant ingredients:
CAS No. Designation Content Classification
CAS
28064-14-4
Bisphenol-F-
epichlorhydrine resin
25 – 50 % Skin Irritation – Category 2.
Eye Irritation – Category 2A.
Sensitization – skin – Category 1.
Aquatic toxicity – chronic – Category 2.
CAS 5026-74-4p-(2,3-Epoxypropoxy)-
N,N-bis(2,3-epoxypropyl)
aniline
10 – 20 % Acute Toxicity – oral – Category 4.
Skin Irritation – Category 2.
Sensitization – skin – Category 1.
Germ cell mutagenicity – Category 2.
Aquatic toxicity – chronic – Category 2.
CAS 80-08-0 4,4’-Diamino diphenyl
sulfone
10 – 20 % Acute Toxicity – oral – Category 4.
CAS
25068-38-6
Reaction product:
Bisphenol-A-
(epichlorhydrin) epoxy
resin (number average
molecular weight <=700)
< 2 % Skin Irritation - Category 2.
Eye Irritation - Category 2A.
Sensitization - skin - Category 1.
Aquatic toxicity - chronic - Category 2.
CAS 150-68-5Monuron (ISO) < 2 % Acute Toxicity - oral - Category 4.
Carcinogenicity - Category 2.
Aquatic toxicity - acute - Category 1.
Aquatic toxicity - chronic - Category 1.
Additional information:Contains Silicon dioxide. The maximum workplace exposure limits are, where necessary,
listed in section 8.
4. First aid measures
In case of inhalation:Remove the casualty into fresh air and keep him calm.
In case of breathing difficulties administer oxygen. No mouth-to-mouth or mouth-to-nose
resuscitation. Use Ambu bag or ventilator.
Immediately get medical attention.
Following skin contact:Take off contaminated clothing and wash it before reuse. Wash immediately with plenty
of water.
Seek medical attention if irritation persists.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Remove contact lenses, if present and easy to do. Continue rinsing. Subsequently
consult an ophthalmologist.
After swallowing: Rinse mouth immediately and drink plenty of water.
Never give anything by mouth to an unconscious person.
Do not induce vomiting. Immediately get medical attention.
Most important symptoms/effects, acute and delayed
Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction.
Information to physician
Treat symptomatically.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 4 of 9
5. Fire fighting measures
Flash point/flash point range:
Not applicable
Auto-ignition temperature:
No data available
Suitable extinguishing media:
Water spray jet, foam, dry chemical powder.
Extinguishing media which must not be used for safety reasons:
Full water jet
Specific hazards arising from the chemical
In case of fire may be liberated: nitrogen oxides (NOx), aldehydes, acids, carbon
monoxide and carbon dioxide.
Protective equipment and precautions for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information:Cool exposed containers with water spray.
Use a water fog to control vapors.
Do not allow fire water to penetrate into surface or ground water.
6. Accidental release measures
Personal precautions:Avoid exposure.
Provide adequate ventilation. Wear appropriate protective equipment.
Avoid contact with skin, eyes, and clothing. Take off contaminated clothing and wash it
before reuse.
Do not breathe gas/fume/vapour/spray. Keep unprotected people away.
Environmental precautions:
Do not allow to enter into ground-water, surface water or drains.
Methods for clean-up:Take up mechanically, placing in appropriate containers for disposal. Final cleaning.
7. Handling and storage
Handling
Advices on safe handling:Obtain special instructions before use.
Provide adequate ventilation. Wear appropriate protective equipment.
Avoid contact with skin, eyes, and clothing. Take off contaminated clothing and wash it
before reuse.
Do not breathe gas/fume/vapour/spray.
When using do not eat, drink or smoke. Wash hands before breaks and after work. Eye
wash facility must be provided.
Storage
Requirements for storerooms and containers:
Keep container tightly closed in a cool, well-ventilated place.
Refrigerated storage is recommended to maintain product quality.
This product may be stored at 41 F for up to 12 months.
Hints on joint storage:Incompatible materials: Strong oxidizing agents, strong Lewis acids or mineral acids.
Keep away from food, drink and animal feedingstuffs.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 5 of 9
8. Exposure controls / personal protection
Exposure guidelines
Occupational exposure limit values:
CAS No. Designation Type Limit value
7631-86-9 Silicon dioxideUSA: NIOSH: TWA 6 mg/m
USA: OSHA: TWA 20 mppcf
USA: OSHA: TWA 80 mg/m (total dust)
Engineering controls
Provide good ventilation and/or an exhaust system in the work area.
See also information in chapter 7, section storage.
Personal protection equipment (PPE)
Eye/face protectionTightly sealed goggles according to OSHA Standard - 29 CFR: 1910.133 or ANSI
Z87.1-2010.
Skin protection Wear suitable protective clothing.
Protective gloves according to OSHA Standard - 29 CFR: 1910.138.
Glove material: Neoprene or rubber.
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Respiratory protection:Respiratory protection must be worn whenever the TLV (WEL) levels have been exceeded.
The filter class must be suitable for the maximum contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when handling the product. If the
concentration is exceeded, self-contained breathing apparatus must be used.
General hygiene considerations:
Avoid exposure - obtain special instructions before use.
Avoid contact with skin, eyes, and clothing. Take off contaminated clothing and wash it
before reuse.
Do not breathe gas/fume/vapour/spray.
Have eye wash bottle or eye rinse ready at work place.
Wash hands before breaks and after work. When using do not eat or drink.
9. Physical and chemical properties
Information on basic physical and chemical properties
Appearance: Physical state at 68 F and 101.3 kPa: solid
Form: Carbon fabric impregnated with viscous blue paste
Color: blue
Odor: characteristic
Odor threshold: No data available
pH value: not applicable
Melting point/freezing point: No data available
Initial boiling point and boiling range:No data available
Flash point/flash point range: Not applicable
Evaporation rate: No data available
Flammability: No data available
Explosion limits: No data available
Vapor pressure: No data available
Vapor density: >= 1
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 6 of 9
Density: No data available
Water solubility: negligible
Partition coefficient: n-octanol/water:No data available
Auto-ignition temperature: No data available
Thermal decomposition: No data available
Additional information: No data available
10. Stability and reactivity
Reactivity: No data available
Chemical stability:Stable under recommended storage conditions.
This product may be stored at 41 F for up to 12 months.
Possibility of hazardous reactions
No dangerous reactions with proper and specified storage and handling
Conditions to avoid:Keep away from heat.
Incompatible materials:Strong oxidizing agents, strong Lewis acids or mineral acids
Hazardous decomposition products:
Exothermal decomposition with formation of: toxic gases, Nitrogen oxides (NOx),
aldehydes, acids, carbon monoxide and carbon dioxide.
Thermal decomposition:No data available
11. Toxicological information
Toxicological tests
Toxicological effects:The statements are derived from the properties of the single components. No toxicological
data is available for the product as such.
Acute toxicity (oral): Based on available data, the classification criteria are not met.
ATEmix calculated: > 2000 mg/kg
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Skin Irritation – Category 2 = Causes skin irritation.
Serious eye damage/irritation: Eye Irritation –
Category 2A = Causes serious eye irritation.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Sensitization – skin – Category 1 = May cause an allergic skin reaction.
Germ cell mutagenicity/Genotoxicity: Germ cell mutagenicity –
Category 2 = Suspected of causing genetic defects.
Carcinogenicity: Carcinogenicity – Category 2 = Suspected of causing cancer.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 7 of 9
Other information: Chronic toxicity – Carcinogenic effect:
4,4′-Diamino diphenylsulfone:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Monuron (ISO):
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Silicon dioxide:
Carcinogen Status:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
12. Ecological information
Ecotoxicity
Aquatic toxicity: Toxic to aquatic life with long lasting effects.
Mobility in soil
No data available
Persistence and degradability
Further details: No data available
Additional ecological information
General information:Do not allow to enter into ground-water, surface water or drains.
13. Disposal considerations
Product
Recommendation: Incinerate as hazardous waste according to applicable local, state, and federal regulations.
Contaminated packaging
Recommendation: Dispose of waste according to applicable legislation.
Handle contaminated packages in the same way as the substance itself.
14. Transport information
USA: Department of Transportation (DOT)
Proper shipping name: Not restricted
Sea transport (IMDG)
Proper shipping name: Not restricted
Marine pollutant: not applicable
Air transport (IATA)
Proper shipping name: Not restricted
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 8 of 9
Further information
No dangerous good in sense of these transport regulations.
15. Regulatory information
National regulations – U.S. Federal Regulations
Bisphenol-F-epichlorhydrine resin: TSCA Inventory: listed; UVCB; EPA flags
XU
TSCA HPVC: not listed
p-(2,3-Epoxypropoxy)-N,N-bis(2,3-epoxypropyl)aniline: TSCA Inventory: listed; EPA flags T
TSCA HPVC: not listed
4,4′-Diamino diphenyl sulfone: TSCA Inventory: listed
TSCA HPVC: not listed
Carcinogen Status:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Reaction product: Bisphenol-A-(epichlorhydrin) epoxy resin
(number average molecular weight <=700):
TSCA Inventory: listed; EPA flags XU
TSCA HPVC: not listed
Monuron (ISO): TSCA Inventory: listed
TSCA HPVC: not listed
Carcinogen Status:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Other Environmental Laws:
SARA Title III Section 313, Toxic
Release: Conc. 1.0% / Threshold Standard
Silicon dioxide: TSCA Inventory: listed
TSCA HPVC: not listed
Carcinogen Status:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
NIOSH Recommendations:
Occupational Health Guideline: 0552
National regulations - Great Britain
Hazchem-Code: -
16. Other information
Text for labeling: Contains 25 - 50 % Bisphenol-F-epichlorhydrine resin, 10 - 20 %
p-(2,3-Epoxypropoxy)-N,N-bis(2,3-epoxypropyl)aniline, 10 - 20 % 4,4'-Diamino diphenyl
sulfone, < 2 % Reaction product: Bisphenol-A-(epichlorhydrin) epoxy resin (number
average molecular weight <=700), < 2 % Monuron (ISO). Safety data sheet available on
request.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard
Z400.1-2010
TMFP 3100, 3200
Material number 1057
Revision date: 9/4/2018
Version: 12
Language: en-US
Date of first version:11/23/2009
Page: 9 of 9
Hazard rating systems:
1
20
NFPA Hazard Rating:
Health: 2 (Moderate)
Fire: 1 (Slight)
Reactivity: 0 (Minimal)
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
X
HMIS Version III Rating:
Health: 2 (Moderate) - Chronic effects
Flammability: 1 (Slight)
Physical Hazard: 0 (Minimal)
Personal Protection: X = Consult your supervisor
Reason of change: Changes in section 1: Company/undertaking identification
Department issuing data sheet
Contact person: see section 1: Dept. responsible for information
This data sheet cannot cover all possible situations which the user may experience during processing. Each
aspect of your operation should be examined to determine if, and which additional precautions may be
necessary. All health and safety information contained in this data sheet should be provided to your
employees and customers. It is your responsibility to develop appropriate workplace instructions and training
programs for employees.
As the conditions and methods of use are beyond our control, we do not assume any responsibility and
expressly disclaim any liability for any use of this product. The information supplied on this safety data sheet
complies with our current level of knowledge as well as with national and EU regulations. All statements or
suggestions are made without warranty, expressed or implied, regarding accuracy of information, the
hazards connected with the use of the product or the results to be obtained from the use thereof.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
TMGP-4000, 4100, 4200
Material number 1058
Revision date: 9/4/2018
Version: 13
Language: en-US
Date of first version:5/24/2008
Page: 1 of 8
1. Product and company identification
Product identifier
Trade name: TMGP-4000, 4100, 4200
Relevant identified uses of the substance or mixture and uses advised against
General use: Carbon epoxy prepreg
For industrial purposes only
Details of the supplier of the safety data sheet
Company name:
Airtech International, Inc.
5700 Skylab Road
Huntington Beach, CA 92647
E-mail: airtech@airtechintl.com
Website: www.airtechonline.com
Telephone: +1 714.899.8100
Dept. responsible for information:
Telephone: +1 714.899.8100
E-mail: airtech@airtechintl.com
Airtech Europe Sarl
Zone industrielle Haneboesch
L 4562 Differdange
Luxembourg
Website: www.airtech.lu
Telephone: +352 582.282
Dept. responsible for information:
Telephone: +352 582.282
E-mail: sales@airtech.lu
Tygavac Advanced Materials Ltd.
The Causeway
Broadway Business Park
Chadderton, Oldham
OL9 9XD United Kingdom
Website: www.tygavac.co.uk
Telephone: +44 161.947.1610
Dept. responsible for information:
Telephone: +44 161.947.1610
E-mail: sales@tygavac.co.uk
Airtech Asia Ltd.
No. 161 of Anyuan Rd
Chagugang County
Wuqing District
301721, Tianjin, P.R. China
Website: www.airtech.asia
Telephone: +86 22 8862 9800
Telefax:: +86 22 8862 9900
Dept. responsible for information:
Telephone: +86 22 8862 9800
E-mail: airtech.asia@airtechasia.com.cn
Emergency phone number
CHEMTREC EMERGENCY PHONE:
Within USA/Canada: 1-(800)424-9300
International: +1 703-741-5970
2. Hazards identification
Emergency overview
Appearance: Form: Carbon fabric impregnated with viscous blue paste
Color: blue
Odor: characteristic
Classification: Skin Irritation - Category 2; Eye Irritation - Category 2A; Sensitization - skin -
Category 1; Germ cell mutagenicity - Category 2; Carcinogenicity - Category 2;
Aquatic toxicity - chronic - Category 2;
Hazard symbols:
Signal word: Warning
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
TMGP-4000, 4100, 4200
Material number 1058
Revision date: 9/4/2018
Version: 13
Language: en-US
Date of first version:5/24/2008
Page: 2 of 8
Hazard statements:
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Suspected of causing genetic defects.
Suspected of causing cancer.
Toxic to aquatic life with long lasting effects.
Precautionary statements:
Obtain special instructions before use.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wash hands and face thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of water/soap.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see ' First aid ' on this label).
If skin irritation occurs: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
Collect spillage.
Store locked up.
Dispose of contents/container to hazardous or special waste collection point.
Regulatory status
This material is considered hazardous by the U.S. OSHA Hazard Communication
Standard (29 CFR 1910.1200) and SIMDUT in Canada.
Hazards not otherwise classified
see section 11: Toxicological information
3. Composition / Information on ingredients
Chemical characterization:
Carbon fabric impregnated with an epoxy resin system
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
TMGP-4000, 4100, 4200
Material number 1058
Revision date: 9/4/2018
Version: 13
Language: en-US
Date of first version:5/24/2008
Page: 3 of 8
Relevant ingredients:
CAS No. Designation Content Classification
CAS
28064-14-4
Bisphenol-F-
epichlorhydrine resin
< 50 % Skin Irritation - Category 2.
Eye Irritation - Category 2A.
Sensitization - skin - Category 1.
Aquatic toxicity - chronic - Category 2.
CAS 5026-74-4p-(2,3-Epoxypropoxy)-N,N-
bis(2,3-epoxypropyl)aniline
< 25 % Acute Toxicity - oral - Category 4.
Skin Irritation - Category 2.
Sensitization - skin - Category 1.
Germ cell mutagenicity - Category 2.
Aquatic toxicity - chronic - Category 2.
CAS 80-08-0 4,4'-Diamino diphenyl
sulfone
< 25 % Acute Toxicity - oral - Category 4.
CAS
25068-38-6
Reaction product:
Bisphenol-A-
(epichlorhydrin) epoxy
resin (number average
molecular weight <=700)
< 2 % Skin Irritation - Category 2.
Eye Irritation - Category 2A.
Sensitization - skin - Category 1.
Aquatic toxicity - chronic - Category 2.
CAS 150-68-5Monuron (ISO) < 2 % Acute Toxicity - oral - Category 4.
Carcinogenicity - Category 2.
Aquatic toxicity - acute - Category 1.
Aquatic toxicity - chronic - Category 1.
4. First aid measures
In case of inhalation:Remove the casualty into fresh air and keep him calm.
In case of breathing difficulties administer oxygen. Immediately get medical attention.
Following skin contact:Take off contaminated clothing and wash it before reuse.
After contact with skin, wash immediately with soap and plenty of water.
Seek medical attention if irritation persists.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart.
Subsequently consult an ophthalmologist.
After swallowing: Rinse mouth immediately and drink plenty of water.
Never give anything by mouth to an unconscious person.
Do not induce vomiting. Immediately get medical attention.
Most important symptoms/effects, acute and delayed
Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction.
Information to physician
Treat symptomatically.
5. Fire fighting measures
Flash point/flash point range:
Decomposes before flashing.
Auto-ignition temperature:
No data available
Suitable extinguishing media:
Water spray jet, foam, dry chemical powder, carbon dioxide.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
TMGP-4000, 4100, 4200
Material number 1058
Revision date: 9/4/2018
Version: 13
Language: en-US
Date of first version:5/24/2008
Page: 4 of 8
Extinguishing media which must not be used for safety reasons:
Full water jet
Specific hazards arising from the chemical
In case of fire may be liberated: nitrogen oxides (NOx), sulphur oxides, aldehydes, acids,
carbon monoxide and carbon dioxide.
Protective equipment and precautions for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information:Cool exposed containers with water spray.
Use a water fog to control vapors.
Do not allow fire water to penetrate into surface or ground water.
6. Accidental release measures
Personal precautions:Avoid exposure.
Provide adequate ventilation. Avoid contact with skin, eyes, and clothing. Take off
contaminated clothing and wash it before reuse. Do not inhale substance. Wear
appropriate protective equipment. Keep unprotected people away.
Environmental precautions:
Do not allow to enter into ground-water, surface water or drains.
Methods for clean-up:Take up mechanically, placing in appropriate containers for disposal. Final cleaning.
Do not touch or step on spilled substance.
7. Handling and storage
Handling
Advices on safe handling:Obtain special instructions before use.
Provide adequate ventilation. Avoid contact with skin, eyes, and clothing. Take off
contaminated clothing and wash it before reuse. Do not inhale substance. Wear
appropriate protective equipment.
When using do not eat, drink or smoke. Wash hands before breaks and after work. Eye
wash facility must be provided.
Storage
Requirements for storerooms and containers:
Refrigerated storage is recommended to maintain product quality.
This product may be stored at -0.4 F for up to 12 months. Store locked up.
Hints on joint storage:Incompatible materials: Strong oxidizing agents, strong Lewis acids or mineral acids.
Keep away from food, drink and animal feedingstuffs.
8. Exposure controls / personal protection
Engineering controls
Provide good ventilation and/or an exhaust system in the work area.
See also information in chapter 7, section storage.
Personal protection equipment (PPE)
Eye/face protectionTightly sealed goggles according to OSHA Standard - 29 CFR: 1910.133 or ANSI
Z87.1-2010.
Skin protection Wear suitable protective clothing.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
TMGP-4000, 4100, 4200
Material number 1058
Revision date: 9/4/2018
Version: 13
Language: en-US
Date of first version:5/24/2008
Page: 5 of 8
Protective gloves according to OSHA Standard - 29 CFR: 1910.138.
Glove material: Neoprene or rubber
Breakthrough time: >480 min.
Observe glove manufacturer’s instructions concerning penetrability and breakthrough time.
Respiratory protection:Provide adequate ventilation.
Processing, e.g. by cutting, sawing or grinding, can produce particles and dust.
Wear a dust mask, in case of excessive dust.
Recommendation: Particulates filter N100 according to OSHA Standard – 29 CFR:
1910.134 or ANSI Z88.2.
General hygiene considerations:
Avoid exposure – obtain special instructions before use. Have eye wash bottle or eye
rinse ready at work place.
Wash hands before breaks and after work. When using do not eat or drink.
Avoid contact with skin, eyes, and clothing. Take off contaminated clothing and wash it
before reuse.
9. Physical and chemical properties
Information on basic physical and chemical properties
Appearance: Form: Carbon fabric impregnated with viscous blue paste
Color: blue
Odor: characteristic
Odor threshold: No data available
pH value: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range:No data available
Flash point/flash point range: Decomposes before flashing.
Evaporation rate: No data available
Flammability: No data available
Explosion limits: No data available
Vapor pressure: No data available
Vapor density: No data available
Density: No data available
Water solubility: practically insoluble
Partition coefficient: n-octanol/water:No data available
Auto-ignition temperature: No data available
Thermal decomposition: No data available
Additional information: No data available
10. Stability and reactivity
Reactivity: No data available
Chemical stability:Stable under recommended storage conditions.
Possibility of hazardous reactions
No dangerous reactions with proper and specified storage and handling
Conditions to avoid:Keep away from heat.
Incompatible materials:Strong oxidizing agents, strong Lewis acids or mineral acids
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
TMGP-4000, 4100, 4200
Material number 1058
Revision date: 9/4/2018
Version: 13
Language: en-US
Date of first version:5/24/2008
Page: 6 of 8
Hazardous decomposition products:
Exothermal decomposition with formation of: toxic gases, nitrogen oxides (NOx), sulphur
oxides, aldehydes, acids, carbon monoxide and carbon dioxide.
Thermal decomposition:No data available
11. Toxicological information
Toxicological tests
Toxicological effects:The statements are derived from the properties of the single components. No toxicological
data is available for the product as such.
Acute toxicity (oral): Based on available data, the classification criteria are not met.
ATEmix calculated: > 2000 mg/kg
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Skin Irritation – Category 2 = Causes skin irritation.
Serious eye damage/irritation: Eye Irritation –
Category 2A = Causes serious eye irritation.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Sensitization – skin – Category 1 = May cause an allergic skin reaction.
Germ cell mutagenicity/Genotoxicity: Germ cell mutagenicity –
Category 2 = Suspected of causing genetic defects.
Carcinogenicity: Carcinogenicity – Category 2 = Suspected of causing cancer.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.
Other information: Chronic toxicity – Carcinogenic effect:
4,4′-Diamino diphenylsulfone:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Monuron (ISO):
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
12. Ecological information
Ecotoxicity
Aquatic toxicity: Harmful to aquatic life with long lasting effects.
Mobility in soil
No data available
Persistence and degradability
Further details: No data available
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
TMGP-4000, 4100, 4200
Material number 1058
Revision date: 9/4/2018
Version: 13
Language: en-US
Date of first version:5/24/2008
Page: 7 of 8
Additional ecological information
General information:Do not allow to enter into ground-water, surface water or drains.
13. Disposal considerations
Product
Recommendation: Incinerate as hazardous waste according to applicable local, state, and federal regulations.
Contaminated packaging
Recommendation: Dispose of waste according to applicable legislation.
14. Transport information
USA: Department of Transportation (DOT)
Proper shipping name: Not restricted
Sea transport (IMDG)
Proper shipping name: Not restricted
Marine pollutant: not applicable
Air transport (IATA)
Proper shipping name: Not restricted
Further information
No dangerous good in sense of these transport regulations.
15. Regulatory information
National regulations – U.S. Federal Regulations
Product: TSCA: All components listed
4,4′-Diamino diphenyl sulfone:Carcinogen Status:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Monuron (ISO): Carcinogen Status:
IARC Rating: Group 3
OSHA Carcinogen: not listed
NTP Rating: not listed
Other Environmental Laws:
SARA Title III Section 313, Toxic Release: Conc. 1.0% / Threshold Standard
National regulations – Great Britain
Hazchem-Code: –
printed by Airtech Advanced Materials Group with Qualisys SUMDAT
SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2010
TMGP-4000, 4100, 4200
Material number 1058
Revision date: 9/4/2018
Version: 13
Language: en-US
Date of first version:5/24/2008
Page: 8 of 8
16. Other information
Text for labeling: Contains < 50 % Bisphenol-F-epichlorhydrine resin, < 25 %
p-(2,3-Epoxypropoxy)-N,N-bis(2,3-epoxypropyl)aniline, < 25 % 4,4'-Diamino diphenyl
sulfone, < 2 % Reaction product: Bisphenol-A-(epichlorhydrin) epoxy resin (number
average molecular weight <=700), < 2 % Monuron (ISO). Safety data sheet available on
request.
Hazard rating systems:
1
20
NFPA Hazard Rating:
Health: 2 (Moderate)
Fire: 1 (Slight)
Reactivity: 0 (Minimal)
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
X
HMIS Version III Rating:
Health: 2 (Moderate) - Chronic effects
Flammability: 1 (Slight)
Physical Hazard: 0 (Minimal)
Personal Protection: X = Consult your supervisor
Reason of change: Changes in section 1: Company/undertaking identification
Department issuing data sheet
Contact person: see section 1: Dept. responsible for information
This data sheet cannot cover all possible situations which the user may experience during processing. Each
aspect of your operation should be examined to determine if, and which additional precautions may be
necessary. All health and safety information contained in this data sheet should be provided to your
employees and customers. It is your responsibility to develop appropriate workplace instructions and training
programs for employees.
As the conditions and methods of use are beyond our control, we do not assume any responsibility and
expressly disclaim any liability for any use of this product. The information supplied on this safety data sheet
complies with our current level of knowledge as well as with national and EU regulations. All statements or
suggestions are made without warranty, expressed or implied, regarding accuracy of information, the
hazards connected with the use of the product or the results to be obtained from the use thereof.
printed by Airtech Advanced Materials Group with Qualisys SUMDAT