Revision: 5.0 SDS Number: SD.SP.01.04US
Revision date: 25.03.2019 Issue date: 24.11.2009
SAFETY DATA SHEET
AKPEROX A50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
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1.1. Product identifier
Product name AKPEROX A50
Chemical name Methyl Ethyl Ketone Peroxide
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Industrial use.
Uses advised against No specific uses advised against are identified.
1.3. Details of the supplier of the safety data sheet
Manufacturer AKPA K MYA AMBALAJ SANAY VE T CARET ANON M RKET
Yenibosna Merkez Mah. Ladin Sok. No:36/70 Kat:12 34197
Townofis Bah elievler, stanbul, T RK YE
Web: www.akpakimya.com
TEL: +90 212 580 55 59
FAX: +90 212 580 55 21
E-mail: info@akpakimya.com
Contact person Export Department – export@akpakimya.com
1.4. Emergency telephone number
Emergency telephone CHEMTREC: TOLL Free 1-800-424-9300 / Local: +1-703-527-3887
For product information AKPA CHEMICALS US: +1 803 686 2888
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical hazards Org. Perox. D – H242
Health hazards Acute Tox. 4 – H302 Skin Corr. 1B – H314 Eye Dam. 1 – H318
Environmental hazards Not Classified.
2.2. Label elements
Pictogram
Signal Word Danger
Hazard statements H242 Heating may cause a fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
SECTION 1: Identi cation of the substance/mixture and of the company/undertaking
SECTION 2: Hazards identification
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Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P220 Keep away from acids, alkalis, heavy metal compounds,
oxidizing material, combustible materials.
P234 Keep only in original container.
P280 Wear protective gloves/protective clothing/ eye protection/
face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician
if you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P411+P235 Store at temperatures not exceeding (5) – (30) C. Keep cool.
P501 Dispose of contents/ container in accordance with national
regulations.
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Contains Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-
2,2-diyl dihydroperoxide
2.3. Other hazards
This substance is not classified as PBT or vPvB according to current EU
criteria.
3.2. Mixtures
Dimethyl Phthalate
REACH Reg. No: 01-2119437229-36-0008
%55-70
CAS Number 131-11-3 EC Number 205-011-6
Classification
Not Classified.
Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
REACH Reg. No: 01-2119514691-43-0007
%25-40
CAS Number 1338-23-4 EC Number 700-954-4
Classification
Org. Perox. D H242
Acute Tox. 4 H302
Skin Corr. 1B H314
Eye Dam. 1 H318
Acute Tox. 4 H332
SECTION 3: Composition/information on ingredients
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BUTANONE
REACH Reg. No: 01-2119457290-43-0004
%1-5
CAS Number 78-93-3 EC Number 201-159-0
Classification
Flam. Liq. 2 H225
Eye Irrit. 2 H319
STOT SE 3 H336
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
4.1. Description of first aid measures
General information Effects may be delayed. Keep affected person under observation.
Chemical burns must be treated by a physician.
Inhalation Remove affected person from source of contamination. Keep affected
person warm and at rest. Get medical attention immediately.
Ingestion Rinse mouth thoroughly with water. DO NOT induce vomiting. Get
medical attention immediately.
Skin contact Remove affected person from source of contamination. Immediately
remove contaminated clothing. Wash skin thoroughly with soap and
water. Get medical attention promptly if symptoms occur after
washing.
Eye contact Remove affected person from source of contamination. Remove any
contact lenses and open eyelids wide apart. Continue to rinse for at
least 15 minutes. Get medical attention immediately. Continue to rinse.
Protection of first aiders First aid personnel should wear appropriate protective equipment
during any rescue. Wash contaminated clothing thoroughly with water
before removing it from the affected person, or wear gloves. It may be
dangerous for first aid personnel to carry out mouth-to-mouth
resuscitation.
4.2. Most important symptoms and effects, both acute and delayed
General information Move out of dangerous ares. Show this Safety data sheet to the doktor
in attendance. Do not leave the victim unattended. Symptoms of
poisoning may appear several hours later. Call a physician immediately.
Inhalation Nausea, vomiting. Dizziness.
Ingestion May cause stomach pain or vomiting. Chemical burns.
SECTION 4: First aid measures
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Skin contact May cause serious chemical burns to the skin.
Eye contact May cause severe eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or
water fog.
Unsuitable extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Specific hazards Protection against nuisance dust must be used when the airborne
concentration exceeds 10 mg/m3. Vapours may form explosive
mixtures with air. Forms explosive mixtures with air. May explode when
heated or when exposed to flames or sparks. Containers can burst
violently or explode when heated, due to excessive pressure build-up.
Hazardous decomposition products
Thermal decomposition or combustion products may include the
following substances: Toxic gases or vapours.
5.3. Advice for firefighters
Protective actions during
firefighting
Wear positive-pressure self-contained breathing apparatus (SCBA) and
appropriate protective clothing. Cool containers exposed to flames
with water until well after the fire is out. Fight fire from safe distance
or protected location. Move containers from fire area if it can be done
without risk. Do not use water jet as an extinguisher, as this will spread
the fire. Control run-off water by containing and keeping it out of
sewers and watercourses. If risk of water pollution occurs, notify
appropriate authorities.
Special protective equipment for
firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and
appropriate protective clothing. Firefighter’s clothing conforming to
European standard EN469 (including helmets, protective boots and
gloves) will provide a basic level of protection for chemical incidents.
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Wear protective clothing as described in Section 8 of this safety data
sheet. No smoking, sparks, flames or other sources of ignition near
SECTION 5: Firefighting measures
SECTION 6: Accidental release measures
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spillage. Avoid inhalation of vapours and contact with skin and eyes.
Provide adequate ventilation.
6.2. Environmental precautions
Environmental precautions Avoid or minimise the creation of any environmental contamination.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Keep combustible materials away from spillage. Eliminate all sources of
ignition. No smoking, sparks, flames or other sources of ignition near
spillage. Provide adequate ventilation. Absorb in vermiculite, dry sand
or earth and place into containers. Wash thoroughly after dealing with
a spillage. Do not touch or walk into spilled material. Wear suitable
protective equipment, including gloves, goggles/face shield, respirator,
boots, clothing or apron, as appropriate.
6.4. Reference to other sections
Reference to the other sections For personal protection, see Section 8. See Section 11 for additional
information on health hazards. For waste disposal, see section 13.
7.1. Precautions for safe handling
Usage precautions Keep away from heat, sparks and open flame. Avoid inhalation of
vapours/spray and contact with skin and eyes. Provide adequate
ventilation. Avoid inhalation of vapours. Use approved respirator if air
contamination is above an acceptable level. Do not handle broken
packages without protective equipment.
Advice on general occupational
hygiene
Eye wash facilities and emergency shower must be available when
handling this product. Good personal hygiene procedures should be
implemented. Wash hands and any other contaminated areas of the
body with soap and water before leaving the work site. Good personal
hygiene procedures should be implemented. Mechanical ventilation or
local exhaust ventilation may be required. Container must be kept
tightly closed when not in use.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Keep away from oxidising materials, heat and flames. Store in tightly-
closed, original container in a dry, cool and well-ventilated place. Avoid
contact with oxidising agents. Store away from the following materials:
Acids. Alkalis. Keep away from flammable and combustible materials.
Storage Class IIA
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 7: Handling and storage
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8.1. Control Parameters
Occupational exposure limits
Ingredients CAS No. Value Control
Parameters
Basis Form of exposure
Dimethyl phthalate 131-11-3
TWA 5 mg/m
3
ACGIH
NIOSH REL
OSHA Z-1
OSHA P0
CAL PEL
MPC-TWA 0,3 mg/m
3
RU OEL
Mixture of vapour
and aerosol
MPC-Stel 1 mg/m
3
RU OEL
Mixture of vapour
and aerosol
Reaction mass of
butane-2,2-diyl
dihydroperoxide and
dioxydibutane-2,2-diyl
dihydroperoxide
1338-23-4 C
0.2 ppm ACGIH
0.2 ppm
1.5 mg/m
3
NIOSH REL
0.7 ppm
5 mg/m
3
OSHA P0
0.2 ppm
1.5 mg/m
3
CAL PEL
Methyl Ethyl Ketone 78-93-3
TWA 200 ppm ACGIH
MPC-TWA 200 mg/m
3
RU OEL Vapour and/or gas
STEL 300 ppm ACGIH
MPC-STEL 400 mg/m
3
RU OEL Vapour and/or gas
TWA
200 ppm
590 mg/m
3
NIOSH REL
OSHA Z-1
OSHA P0
CAL PEL
ST
300 ppm
885 mg/m
3
NIOSH REL
OSHA P0
CAL PEL
SECTION 8: Exposure Controls/personal protection
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Decomposition
products
CAS No. Value Control
Parameters
Basis Form of exposure
Formic acid 64-18-6
TWA 5 ppm ACGIH
STEL 10 ppm ACGIH
TWA
5 ppm
9 mg/m
3
NIOSH REL
OSHA Z-1
OSHA P0
CAL PEL
STEL
10 ppm
19 mg/m
3
CAL PEL
MPC-STEL 1 mg/m
3
RU OEL Vapour and/or gas
Acetic acid 64-19-7
TWA 10 ppm ACGIH
STEL 15 ppm ACGIH
TWA
10 ppm
25 mg/m
3
NIOSH REL
OSHA Z-1
OSHA P0
ST
15 ppm
37 mg/m
3
NIOSH REL
PEL
10 ppm
25 mg/m
3
CAL PEL
STEL
15 ppm
37 mg/m
3
CAL PEL
C 40 ppm CAL PEL
MPC-STEL 5 mg/m
3
RU OEL Vapour and/or gas
Propionic acid 79-09-4
TWA 10 ppm ACGIH
TWA
10 ppm
30 mg/m
3
NIOSH REL
ST
15 ppm
45 mg/m
3
NIOSH REL
OSHA P0
PEL
10 ppm
30 mg/m
3
CAL PEL
MPC-STEL 20 mg/m
3
RU OEL Vapour and/or gas
8.2. Exposure controls
Protective equipment
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Appropriate engineering controls
Provide adequate ventilation. Avoid inhalation of vapours. Observe any
occupational exposure limits for the product or ingredients.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk
assessment indicates eye contact is possible. The following protection
should be worn: Chemical splash goggles or face shield.
Hand protection
Wear protective gloves made of the following material: Neoprene.
Nitrile rubber. Rubber (natural, latex). The most suitable glove should
be chosen in consultation with the glove supplier/manufacturer, who
can provide information about the breakthrough time of the glove
material.
Other skin and body protection Appropriate footwear and additional protective clothing complying
with an approved standard should be worn if a risk assessment
indicates skin contamination is possible.
Hygiene measures Provide eyewash station and safety shower. Do not smoke in work area.
Wash hands at the end of each work shift and before eating, smoking
and using the toilet. Promptly remove any clothing that becomes
contaminated. Wash promptly with soap and water if skin becomes
contaminated. Use appropriate skin cream to prevent drying of skin.
When using do not eat, drink or smoke.
Respiratory protection If ventilation is inadequate, suitable respiratory protection must be
worn. Check that the respirator fits tightly and the filter is changed
regularly.
Environmental exposure controls Residues and empty containers should be taken care of as hazardous
waste according to local and national provisions.
9.1. Information on basic physical and chemical properties
Appearance Clear liquid.
Colour Colorless.
Odour Characteristic.
Density 1,18 0,005 gr/cm
3
@20 C
Solubility(ies) Partially soluble in water.
SECTION 9: Physical and Chemical Properties
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Flammability (liquids) Decomposition products may be flammable.
Viscosity 23-25 mPa.s (@20 C)
9.2. Other information
Active Oxygen Content 8,50 – 8,95 %
SADT 60 C
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this
product.
10.2. Chemical stability
Stability Stable at normal ambient temperatures.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions Not available.
10.4. Conditions to avoid
Conditions to avoid Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials
Materials to avoid Strong alkalis. Strong acids. Strong reducing agents. Strong
oxidising agents. Some metals.
10.6. Hazardous decomposition products
Hazardous decomposition Products Oxides of carbon. Carbon monoxide (CO). Carbon dioxide (CO2).
Hydrocarbons. Formic acid, acetic acid, propionic acid, methyl
ethyl ketone.
11.1. Information on toxicological effects
Product Information
Toxicological information
Acute oral toxicity LD50 Oral 1070 mg/kg
Species: Rat
Acute inhalation toxicity LC50 (Rat): 1,5 mg/l
Exposure time: 4h
Acute dermal toxicity LD50: 4000 mg/kg
Species: Rabbit
Serious eye damage/irritation: Corrosivity to eyes is assumed.
SECTION 10: Stability and reactivity
SECTION 11: Toxicological information
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Skin corrosion/irritation: Causes burns.
Respiratory or skin sensitisation:
Respiratory sensitisation Based on available data the classification criteria are not met.
Skin sensitisation Based on available data the classification criteria are not met.
Germ cell mutagenicity: Genotoxicity – In Vitro – In Vivo Based on available data the
classification criteria are not met.
Carcinogenicity: Based on available data the classification criteria are not met.
Reproductive Toxicity – Fertility Based on available data the classification criteria are not met.
Reproductive Toxicity
Development
Based on available data the classification criteria are not met.
Specific target organ toxicity – single exposure:
STOT – Single exposure Based on available data the classification criteria are not met.
Specific target organ toxicity – repeated exposure:
STOT – Repeated exposure Based on available data the classification criteria are not met.
Aspiration Hazard Based on available data the classification criteria are not met.
Inhalation Harmful by inhalation. May cause damage to mucous membranes in
nose, throat, lungs and bronchial system.
Ingestion Harmful if swallowed. May cause burns in mucous membranes, throat,
oesophagus and stomach.
Skin contact Causes burns. Harmful in contact with skin. May cause sensitisation or
allergic reactions in sensitive individuals.
Eye contact Causes burns.
Route of entry Ingestion Inhalation Skin and/or eye contact
Target organs Respiratory system, lungs
Medical considerations Skin disorders and allergies.
Toxicology Data For The Ingredients:
Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
Acute oral toxicity LD50: 1017 mg/kg Species: Rat
Acute dermal toxicity LD50: 4000 mg/kg Species: Rat
Acute inhalation toxicity LC50 (Rat): 17 mg/l Exposure time: 4h
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Dimethyl phthalate
Acute oral toxicity LD50: >5000 mg/kg Species: Rat
Acute dermal toxicity LD50: >10000 mg/kg Species: Rabbit
Acute inhalation toxicity The substance or mixture has no acute inhalation toxicity
Butanone
Acute oral toxicity LD50: 2,737 mg/kg Species: Rat
Acute dermal toxicity LD50: 6,480 mg/kg Species: Rabbit
12.1. Toxicity
Ecological information on ingredients.
Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
Toxicity to fish LC50, 96h: 44,2 mg/l
Toxicity to algae ErC50, 72h: 5,6 mg/ll
Toxicity to bacteria EC10, 0,5h: 5,6 mg/l
Toxicity to daphnia and other
aquatic invertebrates
39 mg/l, 48h
Butanone
Toxicity to fish LC50, 96h: 3.220 mg/l
Dimethyl phthalate
Toxicity to fish LC50, 96h: 420 mg/l
Toxicity to algae EC10, 72h: 193,09 mg/l
Toxicity to fish (Chronic
Toxicity)
NOEC, 102d: 11 mg/l
Toxicity to daphnia and other
aquatic invertebrates (Chronic
Toxicity)
NOEC, 21d: 9,6 mg/l
12.2. Persistence and degradability
Persistence and degradability The product is readily biodegradable.
12.3. Bio accumulative potential
Bio accumulative potential No data available on bioaccumulation.
12.4. Mobility in soil
Mobility The product is partly miscible with water and may spread in the aquatic
environment.
SECTION 12: Ecological Information
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12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment This product does not contain any substances classified as PBT or vPvB.
12.6. Other adverse effects
Other adverse effects Not available.
13.1. Waste treatment methods
General information Waste should be treated as controlled waste. Dispose of waste to
licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. When handling waste, the safety
precautions applying to handling of the product should be considered.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the
requirements of the local Waste Disposal Authority. Containers should
be thoroughly emptied before disposal because of the risk of an
explosion. Environmental Manager must be informed of all maj r
spillages.
General information For limited quantity packaging/limited load information, consult the
relevant modal documentation using the data shown in this section.
14.1. UN number
UN No. (ADR/RID) 3105
UN No. (IMDG) 3105
UN No. (ICAO) 3105
UN No. (ADN) 3105
14.2. UN proper shipping name
Proper Shipping name(ADR/RID) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (IMDG) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (ICAO) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (ADN) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
14.3. Transport hazard class(es)
ADR/RID class 5.2
SECTION 13: Disposal considerations
SECTION 14: Transport information
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ADR/RID label 5.2
IMDG class 5.2
ICAO class/division 5.2
ADN class 5.2
Transport labels
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
No.
14.6. Special precautions for user
Always transport in closed containers that are upright and secure. Ensure that persons transporting the product
know what to do in the event of an accident or spillage.
EmS
ADR Transport Category
F-J, S-R
2
Emergency Action Code 2WE
Hazard Identification Number –
(ADR/RID)
Tunnel restriction code (D)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to
Annex II of MARPOL
Not Applicable.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Health and Safety at Work etc. Act 1974 (as amended). The Chemicals
(Hazard Information and Packaging for Supply) Regulations 2009 (SI
2009 No. 716).
The Carriage of Dangerous Goods and Use of Transportable Pressure
Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) [“CDG
2009”]. EH40/2005 Workplace exposure limits.
SECTION 15: Regulatory information
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EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the
Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the
Council of 16 December 2008 on classification, labelling and packaging
of substances and mixtures (as amended).
Storage Class IIA
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
Key literature references and
sources for data
This SDS is prepared based on the information received from the
product owner.
Classification procedures according
to Regulation (EC) 1272/2008
Aqute Tox. 4 – H302; Skin Corr. 1B – H314; Eye Dam. 1 – H318:
Calculation Method. Org. Perox. D – H242: Expert Judgement.
Training advice Read and follow manufacturer’s recommendations. Only trained
personnel should use this material.
Revision comments Added REACH Numbers.
Issued By Simge ARIK – lab@akpakimya.com +90 282 361 80 99
Issued Date 24.11.2009
Revision date 25.03.2019
Revision 5.0
Hazard statements in full
H225
H242
Highly flammable liquid and vapour.
Heating may cause a fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
Other abbreviations
ACGIH USA, ACGIH Thershold Limit Values (TLV)
SECTION 16: Other information
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CAL PEL California permissible exposure limits for chemical contaminants (Title
8, Article 107)
NIOSH REL USA NIOSH Recommended Exposure Limits
OSHA P0 USA OSHA TABLE Z-1 Limits for air contaminants 1910.1000
OSHA Z-1 Usa Occupational Exposure Limits (OSHA) Table Z-1 Limits for air
contaminants
ACGIH/TWA 8-hour, time-weighted average
ACGIH/STEL Short-term exposure limit
ACGIH/C Ceiling limit
CAL PEL/STEL Short term exposure limit
CAL PEL/PEL Permissible exposure limit
CAL PEL/C Ceiling
NIOSH REL/TWA Time-weighted average concentration for up to a 10-hour workday
during a 40-hour workweek
NIOSH REL/ST STEL-15minute TWA exposure that should not be exceeded at any
time during a workday
NIOSH REL/C Celing value not be exceeded at any time
OSHA P0/TWA 8-hour time weighted average
OSHA P0/STEL Short-term exposure limit
OSHA P0/C Ceiling limit
OSHA Z-1/TWA 8-hour time weighted average
RU OEL / MPC-STEL Russia. Maximum Permissible Concentration Short Term Exposure
RU OEL / MPC-TWA Russia. Maximum Permissible Concentration Time Weighted
Average
This information relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process. Such information is, to the best of the
company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty,
guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s
responsibility to satisfy himself as to the suitability of such information for his own particular use.