Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
1 / 17
1.1. Product identifier
Product name AKPEROX CMP50
Chemical name Methyl Ethyl Ketone Peroxide and Cumyl Hydroperoxide
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Industrial use.
Uses advised against No specific uses advised against are identified.
1.3. Details of the supplier of the safety data sheet
Manufacturer AKPA K MYA AMBALAJ SANAY VE T CARET ANON M RKET
Yenibosna Merkez Mah. Ladin Sok. No:36/70 Kat:12 34197
Townofis Bah elievler, stanbul, T RK YE
Web: www.akpakimya.com
TEL: +90 212 580 55 59
FAX: +90 212 580 55 21
E-mail: info@akpakimya.com
Contact person Export Department – export@akpakimya.com
1.4. Emergency telephone number
Emergency telephone CHEMTREC: TOLL Free 1-800-424-9300 / Local: +1-703-527-3887
For product information AKPA CHEMICALS US: +1 803 686 2888
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical hazards Org. Perox. D – H242
Health hazards Acute Tox. 4 – H302; Acute Tox. 3 – H331; Acute Tok. 4 – H312; Skin Corr.
1B – H314; STOT RE 2 H373
Environmental hazards Aquatic Chronic 2 – H411
2.2. Label elements
Pictogram
Signal Word Danger
Hazard statements H242 Heating may cause a fire.
H302 + H312 Harmful if swallowed or in contact with skin.
SECTION 1: Identi cation of the substance/mixture and of the company/undertaking
SECTION 2: Hazards identification
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
2 / 17
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H373 May cause damage to organs through prolonged or repeated
exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P220 Keep away from acids, alkalis, heavy metal compounds,
oxidizing material, combustible materials.
P234 Keep only in original container.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye
protection/face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician
if you feel unwell.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P301+P312 Call a POISON CENTER/doktor if you feel unwell.
P411+P235 Store at temperature not exceeding 5 C / 30 C. Keep cool.
P501 Dispose of contents/ container in accordance with national
regulations.
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Contains , -dimethylbenzyl hydroperoxide, Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
2.3. Other hazards
This substance is not classified as PBT or vPvB according to current EU
criteria.
3.2. Mixtures
Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
REACH Reg. No: 01-2119514691-43-0007
%45-55
CAS Number 1338-23-4 EC Number 700-954-4
Classification
Org. Perox. D H242
Acute Tox. 4 H302
Skin Corr. 1B H314
Eye Dam. 1 H318
Acute Tox. 4 H332
SECTION 3: Composition/information on ingredients
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
3 / 17
, -dimethylbenzyl hydroperoxide; cumene hydroperoxide %25-30
CAS Number 80-15-9 EC Number 201-254-7
Classification Specific concentration limits
Org. Perox. E H242 Skin Corr. 1B; H314: C 10 %
Acute Tox. 3 H331 Eye Irrit. 2; H319: 1 % C < 3 %
Acute Tox. 4 H302 Skin Irrit. 2; H315: 3 % C < 10 %
Acute Tox. 4 H312 STOT SE 3; H335: C < 10 %
Skin Corr. 1B H314 Eye Dam. 1; H318: 3 % C < 10 %
STOT RE 2 H373
Aquatic Chronic 2 H411
Cumene %5-10
CAS Number 98-82-8 EC Number 202-704-5
Classification
Flam. Liq. 3 H226
Asp. Tox. 1 H304
STOT SE 3 H335
Aquatic Chronic 2 H411
Acetophenone %1-5
CAS Number 98-86-2 EC Number 202-707-8
Classification
Acute Tox. 4 H302
Eye Irr t. 2 H319
Butanone
REACH Reg. No: 01-2119457290-43-0004
%1>
CAS Number 78-93-3 EC Number 201-159-0
Classification
Flam. Liq. 2 H225
Eye Irrit. 2 H319
STOT SE 3 H336
Hydrogen Peroxide Solution
REACH Reg. No: 01-2119485845-22-0000
%1>
CAS Number 7722-84-1 EC Number 231-765-0
Classification
Ox. Liq. 1 H271
Acute Tox. 4 H302
Acute Tox. 4 H332
Skin Corr. 1A H314
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
4 / 17
4.1. Description of first aid measures
General information Move out of dangerous ares. Show this Safety data sheet to the doktor
in attendance. Do not leave the victim unattended. Symptoms of
poisoning may appear several hours later. Call a physician immediately.
Inhalation Remove affected person from source of contamination. Move affected
person to fresh air and keep warm and at rest in a position comfortable
for breathing. Maintain an open airway. Loosen tight clothing such as
collar, tie or belt. When breathing is difficult, properly trained
personnel may assist affected person by administering oxygen. Place
unconscious person on their side in the recovery position and ensure
breathing can take place. Get medical attention if any discomfort
continues.
Ingestion Rinse mouth thoroughly with water. Stop if the affected person feels
sick as vomiting may be dangerous. Do not induce vomiting unless
under the direction of medical personnel. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs. Never give
anything by mouth to an unconscious person. Move affected person to
fresh air and keep warm and at rest in a position comfortable for
breathing. Place unconscious person on their side in the recovery
position and ensure breathing can take place. Maintain an open airway.
Loosen tight clothing such as collar, tie or belt. Get medical attention if
any discomfort continues.
Skin contact It is important to remove the substance from the skin immediately.
Take off immediately all contaminated clothing. Rinse immediately
with plenty of water. Continue to rinse for at least 15 minutes and get
medical attention. Chemical burns must be treated by a physician. Get
medical attention if symptoms are severe or persist after washing.
Eye contact Rinse immediately with plenty of water. Remove any contact lenses
and open eyelids wide apart. Continue to rinse for at least 10 minutes.
Get medical attention if symptoms are severe or persist after washing.
Protection of first aiders First aid personnel should wear appropriate protective equipment
during any rescue. Wash contaminated clothing thoroughly with water
before removing it from the affected person, or wear gloves. It may be
dangerous for first aid personnel to carry out mouth-to-mouth
resuscitation.
4.2. Most important symptoms and effects, both acute and delayed
SECTION 4: First aid measures
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
5 / 17
General information See Section 11 for additional information on health hazards. The
severity of the symptoms described will vary dependent on the
concentration and the length of exposure.
Inhalation Vapours may cause headache, fatigue, dizziness and nausea.
Ingestion May cause stomach pain or vomiting. Chemical burns.
Skin contact May cause serious chemical burns to the skin.
Eye contact Cause severe irritation to eyes.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically. May cause sensitization or allergic reactions in
sensitive individuals.
5.1. Extinguishing media
Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or
water fog. Use fire extinguishing media suitable for the surrounding
fire.
Unsuitable extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Specific hazards In case of fire, toxic gases may be formed. Vapours may form explosive
air mixtures even at room temperature. Containers can burst violently
when heated, due to excess pressure build-up.
Hazardous decomposition products
Thermal decomposition or combustion products may contain the
following materials: Very toxic or corrosive gases or vapors..
5.3. Advice for firefighters
Protective actions during
firefighting
Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to
avoid inhalation of gases, vapours, fumes and smoke. Ventilate closed
spaces before entering them. May cause or intensify fire; oxidiser. Cool
containers exposed to heat with water spray and remove them from
the fire area if it can be done without risk. Cool containers exposed to
flames with water until well after the fire is out. Avoid discharge to the
aquatic environment. Control run-off water by containing and keeping
it out of sewers and watercourses. If risk of water pollution occurs,
notify appropriate authorities.
Special protective equipment for
firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and
appropriate protective clothing. Firefighter’s clothing conforming to
SECTION 5: Firefighting measures
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
6 / 17
European standard EN469 (including helmets, protective boots and
gloves) will provide a basic level of protection for chemical incidents.
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions No action shall be taken without appropriate training or involving any
personal risk. Keep unnecessary and unprotected personnel away from
the spillage. Wear protective clothing as described in Section 8 of this
safety data sheet. Follow precautions for safe handling described in this
safety data sheet. Wash thoroughly after dealing with a spillage. Ensure
procedures and training for emergency decontamination and disposal
are in place. Do not touch or walk into spilled material. Avoid contact
with skin and eyes.
6.2. Environmental precautions
Environmental precautions Do not discharge into drains, water courses or onto the ground.
Spillages or uncontrolled discharges into watercourses must be
IMMEDIATELY alerted to the Environmental Agency or other
appropriate regulatory body.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Keep combustibles away from spilled material. Extinguish all ignition
sources. Avoid sparks, flames, heat and smoking. Ventilate. Dike far
ahead of larger spills for later disposal. Absorb in vermiculite, dry sand
or earth and place into containers. Wash thoroughly after dealing with
a spillage.
6.4. Reference to other sections
Reference to the other sections For personal protection, see Section 8. See Section 11 for additional
information on health hazards. For waste disposal, see section 13.
7.1. Precautions for safe handling
Usage precautions Read and follow manufacturer’s recommendations. Wear protective
clothing as described in Section 8 of this safety data sheet. Keep away
from food, drink and animal feeding stuffs. Keep container tightly
sealed when not in use. Avoid handling which leads to dust formation.
Avoid discharge to the aquatic environment. Do not handle until all
safety precautions have been read and understood. Do not handle
broken packages without protective equipment. Do not reuse empty
containers.
SECTION 6: Accidental release measures
SECTION 7: Handling and storage
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
7 / 17
Advice on general occupational
hygiene
Wash promptly if skin becomes contaminated. Take off contaminated
clothing. Wash contaminated clothing before reuse. Do not eat, drink
or smoke when using this product. Wash at the end of each work shift
and before eating, smoking and using the toilet. Change work clothing
daily before leaving workplace.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Store away from other materials. Keep
only in the original container. Keep container tightly closed, in a cool,
well ventilated place. Keep containers upright. Protect containers from
damage. Protect from sunlight. Bund storage facilities to prevent soil
and water pollution in the event of spillage. The storage area floor
should be leak-tight, jointless and not absorbent. Store at temperatures
between +5 C and +30 C.
Storage Class III
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
8.1. Control Parameters
Occupational exposure limits:
Ingredients CAS No. Value Control Parameters Basis
Reaction mass of
butane-2,2-diyl
dihydroperoxide and
dioxydibutane-2,2-diyl
dihydroperoxide
1338-23-4 TWA
0.2 ppm ACGIH
0.2 ppm
1.5 mg/m
3
NIOSH REL
0.7 ppm
5 mg/m
3
OSHA P0
0.2 ppm
1.5 mg/m
3
CAL PEL
, -dimethylbenzyl
hydroperoxide
80-15-9 TWA 1 ppm US WEEL
Cumene 98-82-8 TWA
50 ppm ACGIH
50 ppm
245 mg/m
3
NIOSH REL
OSHA Z-1
OSHA P0
Hydrogen peroxide 7722-84-1
TWA 1 ppm ACGIH
PEL
1 ppm
1.4 mg/m
3
OSHA Z-1
SECTION 8: Exposure Controls/personal protection
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
8 / 17
STEL
2 ppm
2.8 mg/m
3
ACGIH
Butanone 78-93-3
TWA 200 ppm ACGIH
MPC-TWA 200 mg/m
3
RU OEL
STEL 300 ppm ACGIH
MPC-STEL 400 mg/m
3
RU OEL
TWA
200 ppm
590 mg/m
3
NIOSH REL
OSHA Z-1
OSHA P0
CAL PEL
ST
300 ppm
885 mg/m
3
NIOSH REL
OSHA P0
CAL PEL
Acetophenone 98-86-2 TWA
50 ppm
246 mg/m
3
ACGIH
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health effects Value
, -dimethylbenzyl
hydroperoxide
Workers Inhalation Long-term exposure 6 mg/m
3
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
, -dimethylbenzyl
hydroperoxide
Fresh water 0,0031 mg/l
Marine water 0,00031 mg/l
Fresh water sediment 0,023 mg/kg
Marine sediment 0,0023 mg/kg
Soil 0,0029 mg/kg
Sewage treatment plant 0,35 mg/l
Intermittent use/release 0,031 mg/l
8.2. Exposure controls
Protective equipment
Appropriate engineering controls
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
9 / 17
Provide adequate ventilation Personal, workplace environment or
biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to
use respiratory protective equipment. Use process enclosures, local
exhaust ventilation or other engineering controls as the primary
means to minimize worker exposure. Personal protective equipment
should only be used if worker exposure cannot be controlled
adequately by the engineering control measures. Ensure control
measures are regularly inspected and maintained. Ensure operatives
are trained to minimize exposure.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk
assessment indicates eye contact is possible. Personal protective
equipment for eye and face protection should comply with European
Standard EN166. Wear tight-fitting, chemical splash goggles or face
shield. If inhalation hazards exist, a full-face respirator may be required
instead.
Hand protection
Chemical-resistant, impervious gloves complying with an approved
standard should be worn if a risk assessment indicates skin contact is
possible. The most suitable glove should be chosen in consultation
with the glove supplier/manufacturer, who can provide information
about the breakthrough time of the glove material. To protect hands
from chemicals, gloves should comply with European Standard EN374.
Considering the data specified by the glove manufacturer, check
during use that the gloves are retaining their protective properties and
change them as soon as any deterioration is detected. Frequent
changes are recommended.
Other skin and body protection Appropriate footwear and additional protective clothing complying
with an approved standard should be worn if a risk assessment
indicates skin contamination is possible.
Hygiene measures Provide eyewash station and safety shower. Contaminated work
clothing should not be allowed out of the workplace. Wash
contaminated clothing before reuse. Clean equipment and the work
area every day. Good personal hygiene procedures should be
implemented. Wash at the end of each work shift and before eating,
smoking and using the toilet. When using do not eat, drink or smoke.
Preventive industrial medical examinations should be carried out.
Warn cleaning personnel of any hazardous properties of the product.
Respiratory protection Respiratory protection complying with an approved standard should
be worn if a risk assessment indicates inhalation of contaminants is
possible. Wear suitable mask. Ensure all respiratory protective
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
10 / 17
equipment is suitable for its intended use and is CE – marked. Check
that the respirator fits tightly and the filter is changed regularly. Gas
and combination filter cartridges should comply with European
Standard EN14 387 and EN143. Full face mask respirators with
replaceable filter cartridges should comply with European Standard
EN136. Half mask and quarter mask respirators with replaceable filter
cartridges should comply with European Standard EN140.
Environmental exposure controls Keep container tightly sealed when not in use. Emissions from
ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection
legislation. In some cases, fume scrubbers, filters or engineering
modifications to the process equipment will be necessary to reduce
emissions to acceptable levels.
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Pale yellow.
Odour Characteristic.
Melting point No data available.
Flash point No data available.
Flammability (solid, gas) Not applicable
Density 1,05 – 1,11 gr/cm
3
20 C
Viscosity No data available.
Solubility Partially soluble in water.
9.2. Other information
Active Oxygen Content 7,50 – 8,20 %
SADT 60 C
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this
product.
10.2. Chemical stability
Stability Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions Not available.
10.4. Conditions to avoid
SECTION 9: Physical and Chemical Properties
SECTION 10: Stability and reactivity
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
11 / 17
Conditions to avoid Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials
Materials to avoid Strong alkalis. Strong acids. Strong oxides. Strong reducing agents.
Heavy metals.
10.6. Hazardous decomposition products
Hazardous decomposition Products Thermal decomposition or combustion may liberate carbon
oxides and other toxic gases or vapours. Carbon monoxide (CO).
Carbon dioxide (CO2). Hydrocarbons.
11.1. Information on toxicological effects
Product Information
Toxicological information The product is not tested.
Serious eye damage/irritation: Causes burns.
Skin corrosion/irritation: Causes severe burns.
Respiratory or skin sensitisation:
Respiratory sensitisation Based on available data the classification criteria are not met.
Skin sensitisation Based on available data the classification criteria are not met.
Germ cell mutagenicity: Genotoxicity – In Vitro – In Vivo Based on available data the
classification criteria are not met.
Carcinogenicity: Based on available data the classification criteria are not met.
Reproductive Toxicity – Fertility Based on available data the classification criteria are not met.
Reproductive Toxicity
Development
Based on available data the classification criteria are not met.
Specific target organ toxicity – single exposure:
STOT – Single exposure May cause respiratory irritation.
Specific target organ toxicity – repeated exposure:
STOT – Repeated exposure May cause damage to organs through prolonged or repeated exposure.
Aspiration Hazard Based on available data the classification criteria are not met.
Inhalation Toxic: danger of serious damage to health by prolonged exposure
through inhalation.
Ingestion Irritating. May cause nausea, stomach pain and vomiting.
SECTION 11: Toxicological information
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
12 / 17
Skin contact Strongly irritating. Prolonged contact may cause burns.
Eye contact May cause severe irritation to eyes. Irritation of eyes and mucous
membranes.
Route of entry Ingestion Inhalation Skin and/or eye contact
Target organs Respiratory system, lungs
Medical considerations Skin disorders and allergies.
Toxicology Data For The Ingredients:
, -dimethylbenzyl hydroperoxide
Acute oral toxicity LD50: 382 mg/kg Species: Rat
Acute dermal toxicity LD50: 1,100 mg/kg Species: Rat
Acute inhalation toxicity LC50 (Rat): 2,01 mg/l Exposure time: 4h
Cumene
Acute oral toxicity LD50: 2,700 mg/kg Species: Rat
Acute dermal toxicity LD50: >3,160 mg/kg Species: Rat
Acetophenone
Acute oral toxicity LD50: 815 mg/kg Species: Rat
Acute dermal toxicity LD50: 16,329 mg/kg Species: Rat
Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
Acute oral toxicity LD50: 1017 mg/kg Species: Rat
Acute dermal toxicity LD50: 4000 mg/kg Species: Rat
Acute inhalation toxicity LC50 (Rat): 17 mg/l Exposure time: 4h
Butanone
Acute oral toxicity LD50: 2,737 mg/kg Species: Rat
Acute dermal toxicity LD50: 6,480 mg/kg Species: Rabbit
Hydrogen Peroxide
Acute oral toxicity LD50: >225 mg/kg Species: Rat
Acute inhalation toxicity LD50 (Rat): >0,17 mg/l Exposure time: 4h
12.1. Toxicity
Ecological information on ingredients.
SECTION 12: Ecological Information
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
13 / 17
, -dimethylbenzyl hydroperoxide
Toxicity to fish LC50, 96h (Oncorhynchus mykiss (rainbow trout)): 3.9 mg/l
Toxicity to algae EC50, 72h (Desmodesmus subspicatus (green algae)): 1.6 mg/l
Toxicity to daphnia and other
aquatic invertebrates
EC50, 48h (Daphnia magna (Water flea)): 18 mg/l
Cumene
Toxicity to fish LC50, 96h (Oncorhynchus mykiss (rainbow trout)): 3.9 mg/l
Toxicity to algae EC50, 72h (Desmodesmus subspicatus (green algae)): 2.01 mg/l
Toxicity to daphnia and other
aquatic invertebrates
EC50, 48h (Daphnia magna (Water flea)): 2.14 mg/l
Toxicity to microorganisms EC50, 3h : > 2,000 mg/l
Toxicity to daphnia and other
aquatic invertebrates (Chronic
toxicity)
NOEC, 21d: 0.35 mg/l
Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
Toxicity to fish LC50, 96h: 44,2 mg/l
Toxicity to algae ErC50, 72h: 5,6 mg/ll
Toxicity to bacteria EC10, 0,5h: 5,6 mg/l
Toxicity to daphnia and other
aquatic invertebrates
39 mg/l, 48h
Butanone
Toxicity to fish LC50, 96h: 3.220 mg/l
12.2. Persistence and degradability
Persistence and degradability No data available.
12.3. Bio accumulative potential
Bio accumulative potential No data available on bioaccumulation.
12.4. Mobility in soil
Mobility The product is partly miscible with water and may spread in the aquatic
environment.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment This product does not contain any substances classified as PBT or vPvB.
12.6. Other adverse effects
Other adverse effects May be hazardous to aquatic life.
SECTION 13: Disposal considerations
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
14 / 17
13.1. Waste treatment methods
General information The generation of waste should be minimised or avoided wherever
possible. Reuse or recycle products wherever possible. This material
and its container must be disposed of in a safe way. Disposal of this
product, process solutions, residues and by-products should at all times
comply with the requirements of environmental protection and waste
disposal legislation and any local authority requirements. When
handling waste, the safety precautions applying to handling of the
product should be considered. Care should be taken when handling
emptied containers that have not been thoroughly cleaned or rinsed
out. Empty containers or liners may retain some product residues and
hence be potentially hazardous.
Disposal methods Dispose of surplus products and those that cannot be recycled via a
licensed waste disposal contractor. Waste, residues, empty containers,
discarded work clothes and contaminated cleaning materials should be
collected in designated containers, labelled with their contents.
Containers should be thoroughly emptied before disposal because of
the risk of a fire. Do not cut or weld used containers unless they have
been thoroughly cleaned internally.
General information For limited quantity packaging/limited load information, consult the
relevant modal documentation using the data shown in this section.
14.1. UN number
UN No. (ADR/RID) 3105
UN No. (IMDG) 3105
UN No. (ICAO) 3105
UN No. (ADN) 3105
14.2. UN proper shipping name
Proper Shipping name(ADR/RID) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (IMDG) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (ICAO) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (ADN) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
14.3. Transport hazard class(es)
SECTION 14: Transport information
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
15 / 17
ADR/RID class 5.2
ADR/RID label 5.2
IMDG class 5.2
ICAO class/division 5.2
ADN class 5.2
Transport labels
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
Yes.
14.6. Special precautions for user
Always transport in closed containers that are upright and secure. Ensure that persons transporting the product
know what to do in the event of an accident or spillage.
EmS F-J, S-R
Emergency Action Code 2WE
Hazard Identification Number –
(ADR/RID)
Tunnel restriction code (D)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to
Annex II of MARPOL
Not Applicable.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Health and Safety at Work etc. Act 1974 (as amended). The Chemicals
(Hazard Information and Packaging for Supply) Regulations 2009 (SI
2009 No. 716).
The Carriage of Dangerous Goods and Use of Transportable Pressure
Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) [“CDG
2009”]. EH40/2005 Workplace exposure limits.
SECTION 15: Regulatory information
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
16 / 17
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the
Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the
Council of 16 December 2008 on classification, labelling and packaging
of substances and mixtures (as amended).
Storage Class III
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
Key literature references and
sources for data
This SDS is prepared based on the information received from the
product owner.
Classification procedures according
to Regulation (EC) 1272/2008
Acute Tox. 4 – H302; Acute Tox. 4 – H312; Acute Tox. 3 – H331; Skin Corr.
1B – H314; STOT RE 2 – H373; Aquatic Chronic 2 – H411: Calculation
Method. Org. Perox. D – H242: Expert Judgement.
Training advice Read and follow manufacturer’s recommendations. Only trained
personnel should use this material.
Revision comments Added REACH Number.
Issued By Simge ARIK – lab@akpakimya.com +90 282 361 80 99
Issued Date 13.11.2014
Revision date 04.03.2019
Revision 2.0
Hazard statements in full
H226 Flammable liquid and vapour.
H242 Heating may cause a fire.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
SECTION 16: Other information
Revision: 2.0 SDS Number: SD.SP.01.35US
Revision date: 10.05.2019 Issue date: 13.11.2014
SAFETY DATA SHEET
AKPEROX CMP50
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
17 / 17
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long-lasting effects
Other abbreviations
ACGIH USA, ACGIH Thershold Limit Values (TLV)
NIOSH REL USA NIOSH Recommended Exposure Limits
OSHA P0 USA OSHA TABLE Z-1 Limits for ait contaminants 1910.1000
OSHA Z-1 USA Occupational Exposure Limits (OSHA) Table Z-1 Limits for air
contaminants
ACGIH/TWA 8-hour, time-weighted average
ACGIH/STEL Short-term exposure limit
ACGIH/C Ceiling limit
CAL PEL/STEL Short term exposure limit
CAL PEL/PEL Permissible exposure limit
CAL PEL/C Ceiling
NIOSH REL/TWA Time-weighted average concentration for up to a 10-hour workday
during a 40-hour workweek
NIOSH REL/ST STEL-15minute TWA exposure that should not be exceeded at any time
during a workday
NIOSH REL/C Celing value not be exceeded at any time
OSHA P0/TWA 8-hour time weighted average
OSHA P0/STEL Short-term exposure limit
OSHA P0/C Ceiling limit
OSHA Z-1/TWA 8-hour time weighted average
RU OEL / MPC-STEL Russia. Maximum Permissible Concentration Short Term Exposure
RU OEL / MPC-TWA Russia. Maximum Permissible Concentration Time Weighted Average
This information relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process. Such information is, to the best of the
company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty,
guarantee or representation is made to its accuracy, reliability or completeness. It is the user’s
responsibility to satisfy himself as to the suitability of such information for his own particular use.