231701_SDS.pdf

CHT UK BRIDGWATER LTD
AS1701
Revision nr.3
Dated 4/2/2024
Printed on 4/2/2024
Page n. 1 / 10
Replaced revision:2 (Dated 10/19/2021)
EN
EPY 11.6.1 – SDS 1004.14
Safety Data Sheet

According to U.S.A. Federal Hazcom 2012
1. Identification

1.1. Product identifier

Product name AS1701

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use Adhesive sealant.

1.3. Details of the supplier of the safety data sheet

Name CHT UK BRIDGWATER LTD
Full address Amber House Showground Road
District and Country TA6 6AJ Bridgwater (Somerset)
England
Tel. +44(0)1278411400
Fax +44(0)1278411444
e-mail address of the competent person
responsible for the Safety Data Sheet info.uk@cht.com

Supplier: CHT USA, Inc.
805 Wolfe Avenue
Cassopolis, MI 49031

1.4. Emergency telephone number

For urgent inquiries refer to Transport: +1-703-527-3887 CHEMTREC (North America, 24 hours) (CCN 1014369)
Toll Free: 1-800-424-9300 CHEMTREC (North America, 24 hours)
+52 55 8526 4930 CHEMTREC (Central America, 24 hours)
+55 11 4349 1359 CHEMTREC (South America, 24 hours)

2. Hazards identification

2.1. Classification of the substance or mixture

The product is not classified as hazardous pursuant to the provisions set forth in OSHA Hazard Communication Standard (HCS) (29 CFR
1910.1200). However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it
requires a safety data sheet with appropriate information.

Hazard pictograms: —
Signal words: —

Hazard statements: —

Precautionary statements:
Prevention:
—
Response:
—
Storage:
—
Disposal:
—

2.2. Other hazards

Information not available

3. Composition/information on ingredients

3.1. Substances

Information not relevant

CHT UK BRIDGWATER LTD
AS1701
Revision nr.3
Dated 4/2/2024
Printed on 4/2/2024
Page n. 2 / 10
Replaced revision:2 (Dated 10/19/2021)
EN
EPY 11.6.1 – SDS 1004.14
3. Composition/information on ingredients… / >>
3.2. Mixtures

Contains:

Identification x = Conc. % Classification:

VINYLTRIMETHOXYSILANE
2,5 x < 3 Flammable liquid, category 3 H226, Acute toxicity, category 4 H332 EC 220-449-8 CAS 2768-02-7 REACH Reg. 01-2119513215-52 TETRA-ISOPROPYLTITANATE 2 x < 2,5 Flammable liquid, category 3 H226, Eye irritation, category 2 H319, Specific target organ toxicity - single exposure, category 3 H336 EC 208-909-6 CAS 546-68-9 REACH Reg. 01-2119967389-17 * There is a batch to batch variation. The full wording of hazard (H) phrases is given in section 16 of the sheet. 4. First-aid measures 4.1. Description of first aid measures EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists, seek medical advice. SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash contaminated clothing before using it again. INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately. INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person, unless authorised by a doctor. 4.2. Most important symptoms and effects, both acute and delayed Specific information on symptoms and effects caused by the product are unknown. 4.3. Indication of any immediate medical attention and special treatment needed Information not available 5. Fire-fighting measures 5.1. Extinguishing media SUITABLE EXTINGUISHING EQUIPMENT Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can be used to disperse flammable vapours and protect those trying to stem the leak. UNSUITABLE EXTINGUISHING EQUIPMENT Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent explosions. 5.2. Special hazards arising from the substance or mixture HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. 5.3. Advice for firefighters GENERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). CHT UK BRIDGWATER LTD AS1701 Revision nr.3 Dated 4/2/2024 Printed on 4/2/2024 Page n. 3 / 10 Replaced revision:2 (Dated 10/19/2021) EN EPY 11.6.1 - SDS 1004.14 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Block the leakage if there is no hazard. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures. 6.2. Environmental precautions The product must not penetrate into the sewer system or come into contact with surface water or ground water. 6.3. Methods and material for containment and cleaning up Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. 6.4. Reference to other sections Any information on personal protection and disposal is given in sections 8 and 13. 7. Handling and storage 7.1. Precautions for safe handling Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic charges. When performing transfer operations involving large containers, connect to an earthing system and wear antistatic footwear. Vigorous stirring and flow through the tubes and equipment may cause the formation and accumulation of electrostatic charges. In order to avoid the risk of fires and explosions, never use compressed air when handling. Open containers with caution as they may be pressurised. Do not eat, drink or smoke during use. Avoid leakage of the product into the environment. 7.2. Conditions for safe storage, including any incompatibilities Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a cool and well ventilated place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any incompatible materials, see section 10 for details. 7.3. Specific end use(s) Information not available 8. Exposure controls/personal protection 8.1. Control parameters Information not available 8.2. Exposure controls As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. HAND PROTECTION Protect hands with category III work gloves. The following should be considered when choosing work glove material (OSHA 29 CFR 1910.138): compatibility, degradation, failure time and permeability. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use. SKIN PROTECTION Wear category I professional long-sleeved overalls and safety footwear. Wash body with soap and water after removing protective clothing. EYE PROTECTION Wear airtight protective goggles (OSHA 29 CFR 1910.133). RESPIRATORY PROTECTION If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a CHT UK BRIDGWATER LTD AS1701 Revision nr.3 Dated 4/2/2024 Printed on 4/2/2024 Page n. 4 / 10 Replaced revision:2 (Dated 10/19/2021) EN EPY 11.6.1 - SDS 1004.14 8. Exposure controls/personal protection... / >>
NIOSH certified filter, whose class must be chosen according to the limit of use concentration (NIOSH 42 CFR 84, OSHA 29 CFR
1910.134). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes,
mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker’s exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, wear open-circuit compressed air breathing apparatus or external air-intake breathing apparatus. For a correct choice of
respiratory protection device, see standard NIOSH 42 CFR 84, OSHA 29 CFR 1910.134.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.

9. Physical and chemical properties

9.1. Information on basic physical and chemical properties

Properties Value Information
Appearance paste
Colour black
Odour characteristic
Odour threshold not available
pH not available
Melting point / freezing point not available
Initial boiling point not available
Boiling range not available
Flash point 150 C (302 F)>
Evaporation rate not available
Flammability not available
Lower inflammability limit not available
Upper inflammability limit not available
Lower explosive limit not available
Upper explosive limit not available
Vapour pressure not available
Vapour density not available
Relative density 1.28
Solubility immiscible with water
Partition coefficient: n-octanol/water not available
Auto-ignition temperature 400 C>
Decomposition temperature not available
Viscosity Paste
Explosive properties not available
Oxidising properties not available
9.2. Other information

Information not available

10. Stability and reactivity

10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

The vapours may also form explosive mixtures with the air.

10.4. Conditions to avoid

Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition.

10.5. Incompatible materials

CHT UK BRIDGWATER LTD
AS1701
Revision nr.3
Dated 4/2/2024
Printed on 4/2/2024
Page n. 5 / 10
Replaced revision:2 (Dated 10/19/2021)
EN
EPY 11.6.1 – SDS 1004.14
10. Stability and reactivity… / >>
Information not available

10.6. Hazardous decomposition products

In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released.

11. Toxicological information

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
toxicological effects of exposure to the product.
11.1. Information on toxicological effects

Metabolism, toxicokinetics, mechanism of action and other information

Information not available

Information on likely routes of exposure

Information not available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Information not available

Interactive effects

Information not available

ACUTE TOXICITY

VINYLTRIMETHOXYSILANE
7430 mg/kg (Rat)LD50 (Oral):
3460 mg/kg (Rabbit)LD50 (Dermal):
16,79 mg/l/4h (Rat)LC50 (Inhalation vapours):

SKIN CORROSION / IRRITATION