f,trl
3MrM Scotch-WeldrM Concrete Repair DP600 Grav and Concrete Repair 600 Grav. Part A 04127121
Safety Data Sheet
Copyright,2O2l, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (l) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
Issue Date:
I 8-0894-8
04127121
Version Number:
Supercedes Date:
12.03
12102120
SECTION 1: Identification
1.1. Product identifier
3MrM Scotch-WeldrM Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Part A
Product Identification Numbers
62-2749-8535-7
7010130543
1.2. Recommended use and restrictions on use
Recommended use
Two-part urethane adhesive/sealant., Structural adhesive
This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(13)) for consumer paint or
coating removal
1.3. Supplier’s details
MANUFACTURER:
DIVISION:
ADDRESS:
Telephone:
1.4. Emergency telephone number
l-800-364-3577 or (651)737-6501 (24 hours)
3M
Industrial Adhesives and Tapes Division
3M Center, St. Paul, MN 55144-1000, USA
1 -888-3M HELPS ( l -888-364-3s77)
SECTION 2: Hazard identification
2.1. Hazar d classifi cation
Serious Eye Damage/Irritation: Category 24.
Skin Corrosion/Initation: Category 2.
Respiratory Sensitizer: Category 1.
Skin Sensitizer: Category l.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category I
2.2.Label elements
Signal word
Danger
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3MrM Scotch-Weldrrli Concrete Repair DP600 Gray and Concrete Repair 600 Grav. Part A 04127121
Symbols
Exclamation mark I Health Hazard
I
Pictograms
Hazard Statements
Causes serious eye irritation.
Causes skin irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure:
respiratory system
I
Precautionary Statements
Prevention:
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
In case of inadequate ventilation wear respiratory protection.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF INHALED: Remove person to fresh air and keep comforlable for breathing.
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
Get medical advice/attention if you feel unwell.
Storage:
Keep container tightly closed.
Store locked up in a well-ventilated place.
Disposal:
Dispose of contents/container in accordancs with applicable local/regional/national/international regulations.
Supplemental Information:
Persons previously sensitized to isocyanates rnay develop a cross-sensitization reaction to other isocyanates.
;
I
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. wr
o/
/o
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Page 2 of 12
3Ml
Nr
Scotch_WeldrNr Concrete r DP600 and Concrete 600 Part A 04/27t21
4,4′-diphenyllnethane diisocyanate I 0 I -68-8 35 – 53 Trade Secret
*
diphenylmethanediisocyanate prepolymer 68424-09-9 15 – 40 Trade Secret
*
poly(diphenylmethane-4,4′-diisocyanate) 2s686-28-6 25 – 40 Tracle Secret
*
arnorphous silica 6′,7’762-90-1 I – 5 Trade Secret
*
Methylene Chloride t5-09-2 < 0.01 Trade Secret
*
*The
specific cl.ren.rical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to firesh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
lf Srvallowed:
Rinse mouth. [f you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
lrritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Allergic respiratory
reacrion (difficulty breathing, wheezing, cough, and tightness ofchest). Allergic skin reaction (redness, swelling, blistering, and itching).
Target organ effects following prolonged or repeated exposure. See Section I I for additional details.
4,3. lndication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-tinmeasures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
llazardous Decomposition or By-Products
Substance
Carbon monoxide
Carbon dioxide
Hydrogen Cyanide
Oxides of Nitrogen
Toxic Vapor, Gas, Particulate
Condition
During Combustion
During Combustion
During Combustion
During Combustion
During Combustion
5.3. Special protective actions for fire-fighters
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunkcr coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas ofthe head.
SECTION 6: Accidental release measures
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3MTiu Scotch_weldTNr concrete Rr DP600 and Concrete 600 G Part A 04tz't/21
6.1. Pcrsonal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
infonnation regarding physical and health hazards, respiratory protection, ventilation, and personal protective equiprnent.
6.2. Environmental precautions
Avoid rcleasc to thc environrncnt.
bodies of water.
For larger spills, cover drains and build dikes to prevent entry into sewer systems or
6.3. Methods and material for containment and cleaning up
Contain spill. Pour isocyanate decontaminant solution (90Yowater,80/o concentrated ammoni a,2o/o detergent) on spill and
allow to leact for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent
material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available
inorganic absorbent rrraterial. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material
does not rcmove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a
container approved for transporlation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure
build-r.rp. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area
with fresh air. Read and follow safety precautions on the solvent label and SDS. Dispose of collected material as soon as
possible in accordance with applicable local/regional/national/international regulations.
SECTION 7: H and stor
7.1. Precautions for safe handling
For industrial/occupational use only. Not for consumer sale or use. Do not breathe dust/fume/gas/mist/vapors/spray.
not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after
handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment.
Wash contaminated clothing before reuse.
Do
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed to prevent contamination with water or air
is suspected, do not reseal container. Store away from acids. Store away from strong bases.
If contamination
SECTION 8: osure co nal on
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the
ACGIH : Anrerican Conference of Governmental lndustrial Hygienists
AIHA : Arnerican lndustrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
Ingredient C.A.S. No.Agencv Limit fype Additional Comments
4,4'-diphenylmethane
diisocyanate
1 0 I -68-8ACGIH TWA:0.005 ppm
4,4'-diphenyImethane
diisocyanate
I 0 l -68-8OSHA CEIL:0.2 mg/m3(0.02 ppm)
SILICA, AMORPHOUS 67762-90-7OSHA TWA:20 millions of
particles/cu. ft.;TWA
concentration:0. 8 melm3
Methylene Chloride 75-09-2 ACGIH TWA:50 ppm ,A.3: Confirmed animal
carctn.
Methylene Chloride 7s-09-2 OSHA TWA:25 ppm;STEL: I 25 ppm29 CFR 1910.1052,
SKIN
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3Mr.Nr Scotch_WeldTNr Concrctc air l)l'600 G and Concrete r 600 Part A 04t27 t21
OSLIA : Unitetl States Departnrcnt ol'Latror - Occupational Safety and l-lealth Administration
TWA: Tirne-Weighted-Average
STEL: Short'l'erm Exposr.rre Lirnit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airbome exposures to below relevant Exposure
Limits and/or control dust/ftuneigas/n-rist/vapols/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equiprnent (PPE)
Eye/face protection
Select and use eye/face protcction to prevent contact based on the results ofan exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protcctive clothing approved to relevant local standards to prevent skin contact based on the
results ofan exposure assessment. Selection should be based on use factors such as exposure levels, concentration ofthe
snbstance or mixture, frequency and duration, physical challenges such as temperafure extremes, and other use conditions
Consult with your glove and/or protective clothing manufacfurer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Neoprene
Nitrile Rubber
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - Neoprene
Apron -
Nitrile
Respiratory protection
An exposure assessment may be needcd to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer
SECTION 9: Phvsical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Specific Physical Form:
Odor
Odor threshold
pH
Melting point
Boiling Point
Flash Point
Liquid
Milky White
Viscous
Low Odor
No Data Available
Not Applicable
No Data Available
>:400’F
>:290
oF
fTest Method:Tagliabue Closed Cupl
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3MTM Scotch-Weldlrlt Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Part A 04127121
Evaporation rate
Flammability (solid, gas)
Flammable Limits(LEL)
Flammable Limits(UEL)
Vapor Pressure
Vapor Density
Density
Specific Gravity
Solubility in Water
Solubility- non-water
Partition coefficient: n-octanol/ water
Autoignition temperature
Decomposition temperature
Viscosity
Hazardous Air Pollutants
Molecular weight
VOC Less H2O & Exempt Solvents
10.6. Hazardous decomposition products
Substance
None known.
<:1
lDetails:Gels with exposure to hurnidity.]
Not Applicable
Not Applicable
Not Applicable
<:0.000004 mmHg [@ 68'F]
>:l
[Rel.trdjAlR:l]
1.l l g/ml
1.1I lRef Std:WATER:Il
Negligible
No Data Available
No Data Available
Not Applicable
No Data Available
1,250 – 2,750 centipoise
< 60
o
weight
[Test Method.'Calculated]
No Data Available
0 gll
lTest Method:calculated SCAQMD rule 443.11
lDetails:when used as intended with Part B]
0
o/o
fTest Method:calculated SCAQMD rule 443.1]
lDetails:when used as intended with Part B]
0 gll[Test Method:calculated SCAQMD rule 443.1] lDetails:as
suppliedl
Condition
VOC Less H2O & Exempt Solvents
VOC Less H2O & Exempt Solvents
SECTION L0: Stabilitv and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
I 0.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.
10.5. Incompatible materials
Water
Strong acids
Strong bases
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 1,1: Toxicolosical information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may tre
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3MTM Scotch_Weld',rilr Concrete DP6()O nnd Concrete r 600 GraPart A 04t27t21
present below the threshold for labeling, an ingredient lnay not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Allergic Respiratory Reaction: Signs/symptoms may inch-rde difficulty breathing, wheezing, cough, and tightness of chest.
May cause additional health effects (see below).
Skin Contact:
Skin lrritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Initation: Signs/symptoms may include significant reciness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and dianhea.
Additional Health Effects:
Prolonged or repeated exposure may cause target organ c'lTects:
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart
rate, bluish colored skin (cyanosis), sputum production, changes in lung finction tests, and/or respiratory failure.
Carcinogenicity:
Additional Information :
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute
Inqredient CAS No. Class Description Regulation
Methvlene Chloride 7s-09-2 Grp. 2,A: Probable human carc. International Asencv for Research on Cancer
Methylene Chloride 75-09-2 Anticinated humarr carcinoqen National Toxicolosv Prosram Carcinosens
Methylene Chloride 75-09-2 Cancer hazard OSHA Carcinosens
Name Route Snecies Value
Overall product lnhalation-
Vaoor(4 hr)
No data available; calculated ATE >50 mg/l
Overall product lngestion No data available; calculated ATE >5,000 mg/kg
4.4′-diohenvlmethane diisocvanate Dermal Rabbil LD50 > 5.000 me/ks
4,4′-diphenylmethane di isocyanate Inhalation-
Dust/Mist
(4 hours)
Rat LC50 0.368 mg/l
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3M’f
nt
Scotch-WeldlM Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Part A 04127/21
4.4′-diohenvlnrethane diisocvanate Insestion Rat LD50 3 1,600 nre/ke
poly(diphenyhnethane-4,4′-di isocyanate) Dennal Rabbit LD50 > 5.000 rns/kp
poly(diphenyhnethane-4,4′-diisocyanate) lnhalation-
Dust/Mist
(4 hours)
Rat LC50 0.368 rng/l
polv(diphenvlmethane-4.4′-diisocvanate) Insestion Rat LD50 31.600 rns/ks
amorphous silica Dennal Rabbit LD50 > 5.000 ms/ks
amorphous silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
amomhous silica Inseslion Rat LD50 > 5.1l0 ms/ks
Methylene Chloride Dennal Rat LD50 > 2,000 ms/ks
Methylene Chloride Inhalation-
Vapor (4
hours)
Rat LC50 63.7 mg/l
Methvlene Chloride lngestion Rat LD50 1.410 ms/ke
ATE: acute toxicity estimate
Skin Corrosionilrritation
Serious
Skin Sensitization
Sensitization
Name Species Value
4,4′-diphenylmethane diisocyanate official
classifica
tion
lrritant
poly(diphenylmethane-4,4′-diisocyanate) official
classifica
tion
Irritant
arnomhous silica Rabhit No signifi cant initation
Methylene Chloride Rabbit lnitant
Name Species Value
4,4′-diphenylmethane diisocyanate official
classifica
tion
Severe initant
poly(diphenylmethane-4,4′-diisocyanate) official
classifica
tion
Severe irritant
amorphous silica Rabbit No sisnifi cant initation
Methvlene Chloride Rabbit Severe irritant
Name Soecies Value
4,4′-diphenylmethane diisocyanate official
classifica
tion
Sensitizing
poly(diphenylmethane-4,4′-diisocyanate) official
classifica
tion
Sensitizing
amorphous silica FIuman
and
animal
Not classified
Name Species Value
4.4′-dinhenvlmethane diisocvanate Human Sensitizing
poly(diphenylmelhane-4,4′-diisocyanate) Human Sensitizine
Germ Cell
Name Route Value
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3MrM Scotch-WeldTrlr Concrete Repair DP600 Grav and Concrete Repair 600 Gray, Part A 0412’ll2l
4,4′-diphenylmethane diisocyanate ln Vitro Some positive data cxisl, but the data are not
sufJlcierrt for classi lication
poly(diphenylmethane-4,4′-diisocyanate) In Vitro Some positive data exist, bu1 the data are not
sulfi cient lor classifi cation
amomhous silica ln Vitro Not mutasenic
Methvlene Chloride ln vivo Not rrutagenic
Methylene Chloride In Vitro Sorne positive data exist, but the data are not
suffi cient lbr classiilcation
Carcino
Name Route Snecies Value
4,4′-diphenyhrethane di isocyanate InhalationRat Sorne positive data exist, but the data are not
suffi cient for classifi cation
poly(diphenyhnethane-4,4′-di isocyanate) InhalationRat Some positive data exist, but the data are not
suffi cient for classiflcation
arnorphous silica Not
Specified
Mouse Sorne positive data exist, but the data are not
sulfi cient for classifi cation
Methylene Chloride InhalationMultiple
animal
species
Carcinogenic
Reproductive Toxicity
roductive and/or Effects
Target Organ(s)
T T
Name Route Value Species
‘I’cst
Result Exposure
Duration
4,4′-diphenylmethane diisocyanate lnhalationNot classified for development Rat NOAEL O.OO4
mg/l
during
organogenesi
s
poly(diphenylmethane-4,4’-diisocyanate) InhalationNot classified for development Rat NOAEL O.OO4
mg/l
during
organogenesi
s
amorphous silica IngestionNot classified for female reproduction Rat NOAEL 509
ms/ks/dav
I generation
amorphous silica IngestionNot classified for male reproduction Rat NOAEL 497
ms/ks/dav
I generation
amorphous silica IngestionNot classified for development Rat NOAEL I,350
mg/kg/day
during
organogenesl
Methylene Chloride InhalationNot classified lor female reproduction Rat NOAEL 5.2
mr./l
2 generation
Methylene Chloride InhalationNot classified for male reproduction Rat NOAEL 5.2
ms/l
2 generation
Methylene Chloride InhalationNot classified for development Multiple
animal
species
NOAEL 4.3
mg/l
during
gestation
Name Route Target Organ(s) Value Species
‘l’est
Result Exposure
Duration
4,4′-diphenylmethane
diisocyanate
Inhalationrespiratory irritationMay cause respiratory irritationolficial
classifica
tion
NOAEL Not
available
May cause respiratory irritationpoly(diphenylm ethane-4,4′ –
diisocyanate)
Inhalationrespiratory irritation ofhcial
classifica
tion
NOAEL Not
available
Methylene Chloride Dermal blood Some positive data exist, but the
data are not sufficient lor
classification
Rat NOAEL Not
available
4 hours
Methylene Chloride Inhalationcentral nervous
svstem deoression
May cause drowsiness or
dizziness
Human NOAEL Not
available
occupational
exDosure
Methylene Chloride Inhalationblood Some positive data exist, but the
data are not sufficient for
Human NOAEL Not
available
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3NlIm Scotch-WeldTrn Concrete Repair DI’600 Gray and Concrete Repair 600 Gray, Part A 04127121
classification
Methylene Chloride lnhalationrespiratory irritationSorne positive data exist, but thc
data are not sufficient for
classification
NOAEL Not
availab le
ecific T n
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecolosical information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
Species Exposure
Duration
Name Route Target Organ(s) Value Test Result
4,4′-diphenylmethane
diisocvanate
lnhalationresplratory system Causes damage to organs through
nrolonged ol lepeated exDosure
Rat I-OAI]I,
0.004 rnsil
I 3 rveeks
poly(diphenylmethane-
4.4′-di isocvanate)
Inhalationresplratory system Causes damage to organs through
nrolonsed or reoeated exoosure
Rat LOAEL
0.004 rnq/l
l3 weeks
Inhalationrespiratory system
I
si I icos is
Not classified Human NOAEI- Not
available
occupational
exDosure
amorphous silica
Methylene Chloride Inhalationkidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 6.95
rrg/l
2 years
Methylene Chloride lnhalationliver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL O. I 7
mg/l
2 years
Methylene Chloride Inhalationresplratory system Some positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
LOAEL 35
mgll
8 weeks
Methylene Chloride Inhalationheart Not classified Human NOAEL Not
available
Methylene Chloride Inhalationlmmune system Not classified Rat NOAEL I8
ms/l
28 days
Some positive data exist, but the
data are not sufficient for
classification
Rat
1,200
LOAEL
mp/ks/dav
3 rnonthsMethylene Chloride Ingestionliver
Not classified Rat NOAEL 249
mp/ks/dav
2 yearsMethylene Chloride Ingestion blood
Methylene Chloride lngestion kidney and/or
bladder
Not classified Rat NOAEL
t,469
mp/ks/dav
3 months
Methylene Chloride lngestion eyes Not classified Rat NOAEL 249
ms/ks/dav
I 04 weeks
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3M1’M Scotch-WeldTlt Concrete Repair DP600 Gray and Concrete Renair 600 Grav. Part A 04127121
incinerate urlcured product in a permitted waste incineration faciliry. Proper destruction may require the use of additional fuel
during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chernical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered,
stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call l-800-364-3577 or 651-137-6501
SECTION 15: Regulatorv information
f5.1. US Federal Regulations
Contact 3M for more information.
EPCRA 3lll3l2 Hazard Classifications:
Physical llazards
ot applicable
flealth Hazards
Respiratory or Skin Sensitization
Serious eye damage or eye irritation
Skin Corrosion or lrritation
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient
4,4’-diphenylmethane diisocyanate
Insredient (Catesory if applicable)
Methylene Chloride
C.A.S. No %o bv Wt
101-68-8 Trade Secret 35 – 53
C.A.S. No
7s-09-2
Reeulation
Toxic Substances Control Act (TSCA) 6
Banned or Restricted Use Chemicals
Status
Applicable
Additional TSCA Information
15.2. State Regulations
Contact 3M lor more information
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Comnonents CAS No Additional Information
Methylene Chloride 75-09-2 This chemical/product is not and cannot be distributed in
commerce (as defined in TSCA section 3(5)) or processed (as
defined in TSCA section 3(13)) for consumer paint or coating
removal.
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Page l1 of 12
3MrM Scotch-WeldrM Concrete Repair DP600 Grav and Concrete Repair 600 Grav. Part A 04/27t21
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: I Instability: I Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies, Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:
Issue Date:
I 8-0894-8
04127121
Version Number:
Supercedes Date:
12.03
t2/02120
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be corect as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variefy of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
pg 27 5 of 444-PPrint5825829.pdt–405919212–267 13378
Page 12 of 12
gl,l
3M’tM Scotch-Weld’Iirr Concrete llepair DP600 Gray and Concrete llepair 600 Gray, Part B 04/L9/2t
Safety Data Sheet
Copyright,202l, 3M Company.
All rights reserued. Copying and/or downloading of this informatior.r for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of eaming a profit thereon
Document Group:
Issue Date:
18-0901-1
04119/21
Version Number:
,Sipercedes Date:
10.04
12111120
SECTION 1: Identification
1.1. Product identifier
3MrM Scotch-WeldrM Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Parl B
Product Identifi cation Numbers
62-2649-8535-9
70t0110293
1.2. Recommended use and restrictions on use
Recommended use
Two-pafi urethane adhesive/sealant., Structural adhesive
1.3. Supplier’s details
MANUFACTURER:
DIVISION:
ADDRESS:
Telephone:
1.4. Emergency telephone number
l-800-364-3577 or (651) 137-6501 (24 hours)
3M
Industrial Adhesives and Tapes Division
3M Center, St. Paul, MN 55144- 1000, USA
1 -888-3M HELPS (1 -888-364-3 577)
SECTION 2: Hazard identification
2.1. Hazar d classifi cation
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1A.
2.2.Label elements
Signal word
Warning
Symbols
Exclamation mark
I
Pictograms
pg 252 ol 444-PPrint5825829.pdt–40591921 2-267 1 3378
Page I of 12
I
t
3MrM Scotch-WeldTM Concrete ir DP600 G and Concrete 600 Part B 04n9121
Hazard Statements
Causes serious eye irritation.
May cause an allergic skin reaction
Precautionary Statements
Prevention:
Avoid breathing dust/fume/gas/mi st/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace
Response:
IF IN EYES: Rinse cautiously with water for several minutes.
Continue rinsing.
If eye initation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenry of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Remove contact lenses, if present and easy to do.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Supplemental Information :
Persons previously sensitized to amines may develop a cross-sensitization reaction to ceftain other amines.
SECTION 3: Comosition/information on in ts
Ingredient C.A.S. No. %o bv Wt
Polyether Polyol 9082-00-2 40 – 70 Trade Secret
*
Proooxvlated Trimethylolpropane 2s123-16-4 l0 – 30 Trade Secret
*
Tetrakis(2-hvdroxypropyl) ethylened iamine 102-60-3 l0 – 30 Trade Secret
*
Amorphous Silica 6861r-44-9 I – 5 Trade Secret
*
Bis( 1.2.2,6.6-pentamethyl-4-piperidinyl) sebacate 82919-37-1 < I Trade Secret
*
Polvmeric Benzotriazole l 048 l 0-48-2 < I Trade Secret
*
Po lvmeri c B enzotriazole lI l 048 1 0-47-1 < I Trade Secret
*
Substituted Pioervdinvl Sebcate 4t556-26-l < I Trade Secret
*
m-Xvlene-.alpha.alpha'. -diamine 1477-55-0 <: 0.5 Trade Secret
*
N,N'-Ethylenebis- I 2-Hydroxystearamide 123-26-2 <:0.5 Trade Secret
*
Titanium Dioxide 13463-6'7 -',| <: 0.5 Trade Secret
*
*The
specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
pg 253 of 444-P Print5825829.pdf--4O5919212--267 13378
Page 2 of 12
3Nfln scotch-Weldlrlr Concrete Repair DP600 Grav and Concrete Renair 600 Grav. Part B o4/l9tzl
I nhalation:
Rcmovc person to flesh air. If you feel unwell, get medical attention
Skin Contact:
Immediately wash'"vith soap and water. Remove contaminated clothing and wash before reuse. lf signs/symptoms develop, get
medical attention.
Eye Contact:
lmrnediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get nredical attention
lf Swallowed:
Rinse rnouth. If you leel unwell, get medical attention.
4,2. Most important symptoms and effects, both acute and delayed
Allergic skin rcaction (redness, swelling, blistering, and itching).
4.3. lndication of any immediate medical attention and special treatment required
Not applicable
SBCTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance
Aldehydes
Carbon monoxide
Carbon dioxide
Hydrogen Chloride
Oxides ofNitrogen
Condition
During Combustion
During Combustion
During Combustion
During Combustion
During Combustion
5.3. Special protective actions for fire-fighters
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas ofthe head.
StrCTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
rnaterial does not remove a physical, health, or environmentalhazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions
pg 254 ol 444-P Print5B25B29.pdf--405919212--267 13378
Page 3 of 12
3MTi Scotch_WeldTNr concrete r DP600 G and Concrete 600 G Part I] 04n9t27
on the solvent label and SDS. Seal the contaiuer. Dispose of collected material as soon as possible in accordance with
applicable local/rcgional/national/international regulations.
SECTION 7: Handlinand stora
7.1. Precautions for safe handling
For industrial/occupational use only. Not for consumer sale or use. Avoid breathing dust/fume/gas/mist/vapors/spray.
Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after
handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment.
Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidizing agents.
SECTION 8: osure controlsonal
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the
ACGIH : American Conference of Governmental IndustrialHygienists
AIHA : American lndustrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Cuidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limiis and/or control dust/ftime/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results ofan exposure assessment. The following eye/face
protection(s) are rccommended:
Indirect Vented Goggles
Skin/hand protection
Select and tise gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results ofan exposure asscssment. Selection should be based on use factors such as exposure levels, concentration ofthe
substance o, -i*tnr",
frequency and duration, physical challenges such as temperature extremes, and other use conditions
Ingredient C.A.S. NoAsencv Limit tvpe Additional Comments
Titanium Dioxide 13463-61-7ACGIH TWA:10 mglm3 A.4: Not class. as human
carcln
Titanium Dioxide 13463-67-1OSHA TWA(as total dust):15 ms/m3
m-Xylene-.alpha.alpha'.-diamine| 411-55-0ACGIH CEIL:O.018 ppm Danger of cutaneous
absorption
SILICA, AMORPHOUS 68611-44-9OSHA TWA:20 millions of
particles/cu. ft.;TWA
concentration:0.8 mg/m3
pg 255 oI 444-PPrint5B25829.pdf--40591 921 2--267 1 337 B
Page 4 of 12
3Mr'Nr Scotch-WeldTNr Concrcte ll.epair DP600 Gray nnd Concrcte llepair 600 Gray. Part B 04/79121
Consult with your glove andior protectivc clothing manufacturer for selection of appropriate compatible gloves/protecttve
clothing. Note: Nitrile gloves rnay be wom over polymer laminate gloves to improve dexterity.
Gloves made frorn thc follor,ving n-raterial(s) al'e recolr'lmended: Polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select fi'om the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about sr"ritability for a specific application, consult with your respirator manufacturer.
SECTION 9: Phvsical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Specific Physical Form:
Odor
Odor threshold
pH
Melting point
Boiling Point
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammable Limits(LEL)
Flammable Limits(UEL)
Vapor Pressure
Vapor Density
Density
Specific Gravity
Solubility in Water
Solubility- non-water
Partition coefficient: n-octanol/ water
Autoignition temperature
Decomposition temperature
Viscosity
Hazardous Air Pollutants
Molecular weight
VOC Less IJZO & Exempt Solvents
Liquid
Gray
Viscous
Slight Ammoniacal
No Data Available
Not Applicable
No Data Available
>:400
oF
>:290
oF
lTest Method:Tagliabue Closed Cupl
<:l
[Ref Std:WATER:l]
Not Applicable
Not Applicable
Not Applicable
Not Applicable
>:l
[RelSrd.AIR:I]
1.04 g/ml
1.04 lRef Std:WATER:ll
Negligible
No Data Available
No Data Available
Not Applicable
No Data Available
3,200 – 5,600 centipoise
0 % weight fTest Method:Calculatedl
No Data Available
0 gllfTest Method:calculated SCAQMD rule 443.1]
fDetails:when
used as intended with Part A]
0 gllfTest Method:calculated SCAQMD rule 443.1] lDetails:as
suppliedl
0
o/o
fTest Method:calculated SCAQMD rule 443.1]
lDetails:when used as intended with Part A]
VOC Less H2O & Exempt Solvents
VOC Less H2O & Exempt Solvents
SECTION l0: Stabilitv and reactivitv
10.1. Reactivity
This material may be reactive with certain agents under certain conditions – see the remaining headings in this section.
pg 256 ol 444
-PPrint5825829.pdl–40591
921 2 –267 1 337 B
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3MTrv Scotch_Weld
I M
Concrete DP6OO G and Concrete 600 GraPart B 04t19121
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
Strong acids
Strong oxidizing agents
10.6. Hazardous decomposition products
Substance
None known.
Condition
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: T information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation:
and throat pain.
Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
Skin Contact:
Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo
induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye lrritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Carcinogenicity:
Additional Information :
Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.
Insredient CAS No. Class l)escrintion Resulation
Titanium Dioxide 13463-67-7 Gm. 28: Possible human carc. lnternational Asencv lor Research on Cancer
pg 257 of 444-PPrints825829.pdf–405919212–267 13378
Page 6 of 12
3MTM Scotch-Weld’rM Concrete Repair DP600 Gray and Concrete Repair 600 Gray, Part B 04lt9t2t
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, eithel no data are available for that endpoint or
the data are not snfficient for classification.
Acute
ATE: acute toxicity estimate
Skin Corrosion/Irritation
Namc Route Species Value
Overall product Derrnal No data available; calculated ATE >5,000 mg/kg
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Polyether Polyol Dernral Rabbit LD50 > 5,000 rne/ks
Polyether Polyol lngestion Rat LD50 > 10.000 ms/ks
Propoxvlated Trimethvlolpropane Demral Rat LD50 > 2,000 rne/ks
Proooxvlated Trimethvlolnrooane Ingestion Rat LD50 > 2.500 rns/ks
Tetrakis(2-hydroxypropyl)ethvlenediamine Dennal Rat LD50 > 2,000 me/ks
Tetrakis(2-hvdroxvoronvl)ethvlenediamine lngestion Rat LD50 2.890 rns/ks
Amorphous Silica Dennal Rabbit LD50 > 5,000 me/ks
Amorphous Silica lnhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Amomhous Silica Insestion Rat LD50 > 5.1l0 ms/ks
rn-Xylene-.alpha.alpha’.-diamrne Dermal Rabbit LD50 > 2.000 ms/ks
m-Xylene-.alpha.alpha’.-diamine lnhalation-
Dust/Mist
(4 hours)
Rat LC50 1.2 mgll
m-Xvlene-.alpha.alpha’.-diamrne lneestion Rat LD50 980 me/ke
Substituted Piperydinyl Sebcate Dennal LD50 estimated ro be 2,000 – 5,000 mg/kg
Substituted Pipervdinvl Sebcate Insestion Ral LD50 3.125 ms/ks
Titanium Dioxide Dermal Rabbit LD50 > 10.000 ms/ks
Titanium Dioxide Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 6.82 mg/l
Titanium Dioxide lngestion Rat LD50 > 10.000 rns/ks
Polymeric Benzotriazole Derrnal Rat LD50 > 2,000 ms/ks
Polymeric Benzotriazole lnhalation-
Dust/Mist
(4 hours)
Rat LC50 > 5.8 mg/l
Polymeric Benzotriazole Insestion Rat LD50 > 5.000 me/ks
Polvmeric Benzotriazole II Demal Rat LD50 > 2.000 mp/ks
Polymeric Benzotriazole II Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 5.8 mg/l
Polvmeric Benzotriazole ll lngeslion Rat LD50 > 5.000 ms/ks
Bis( 1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Demal LD50 estimated to be 2,000 – 5,000 mg/kg
Bis( 1,2,2,6,6-pentamethvl-4-piperidinyl) sebacate lnqestion Rat LD50 3,125 me/day
N,N’-Ethylenebis- I 2-Hydroxystearamide Inhalation-
DusVMist
(4 hours)
Rat LC50 > 5.05 mg/l
N,N’-Ethylenebis- I 2-Hvdroxvstearamide lngestion Rat LD50 > 2,000 me/ka
N,N’-Ethylenebis- I 2-Hydroxystearamide Demal similar
health
hazards
LD50 Not available
Name Species Value
Propoxylated Trimethylolpropane Rabbit No sisnifi cant irritation
Tetrakis(2-hydroxypropyl)ethvlenediamine Rabbit No signifi cant irritation
Amorphous Silica Rabbit No sisnifi cant irritation
m-Xylene-.alpha.alpha’.-diamrne Rat Corrosive
Substituted Pioervdinvl Sebcate Rabbit No signifi cant irritation
Titanium Dioxide Rabbit No sisnifi cant irritation
Polymeric Benzotriazole Rabbit No signifi cant irritation
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3MrIlr Scotch-WeldrM Concrete ir DP600 and Concrete 600 Part B 04119121
Polyrneric Benzotriazole Il Rabbit No significant initation
Bis( 1,2,2,6,6-oentarnethyl-4-piperidinvl) sebacate Rabbit No sisnifi cant in’itation
Serious
Skin Sensitization
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell
C
Name Species Value
Propoxylated Trimethylolpropane Rabbit Mild irritant
Tetrakis(2-hydroxypropyl)ethylenediamine Rabbit Severe irritant
Amorphous Silica Rabbit No signifi cant initation
m-Xylene-.alpha.alpha’.-diamine Rabbit Corrosive
Substituted Piperydinyl Sebcale Rabbit No sisnificant initation
Titanium Dioxide Rabbit No siqnificant initation
Polymeric Benzotriazole Rabbit No significant initation
Polymeric Benzotriazole Il Rabbit No signifi cant irritation
Bis( 1,2,2,6,6-pentamethvl-4-piperidinvl) sebacate Rabbit No significant initation
Name Species Value
Tetrakis(2-hydroxypropyl)erhylenediam ine Guinea
Dla
Not classified
Amorphous Silica Human
and
animal
Not classified
m-Xylene-.alpha.alpha’.-diamine Guinea
ois
Sensitizing
Substituted Piperydinyl Sebcate Guinea
Dls
Sensitizing
Titanium Dioxide Human
and
animal
Not classified
Polymeric Benzotriazole Guinea
Dlg
Sensitizing
Polymeric Benzotriazole II Guinea
Drg
Sensitizing
Bis(,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Guinea
Drg
Sensitizing
N,N’-Ethylenebis- I 2-Flydroxystearamide Guinea
plg
Sensitizing
Name Route Value
Tetrakis(2-hydroxypropyl)ethylenediamine ln Vitro Not mutagenic
Amorphous Silica In Vitro Not mutagenic
m-Xylene-.alpha.alpha’.-diamine In Vitro Not mutaAenic
m-Xylene-.alpha.alpha’.-diamine ln vivo Not mutagenic
Substituted Piperydinyl Sebcate In Vitro Not mutagenic
Titanium Dioxide In Vitro Not mutagenic
Titanium Dioxide In vivo Not mutagenic
Polymeric Benzotriazole In Vitro Not mutagenic
Polymeric Benzotriazole In vivo Not mutagenic
Polymeric Benzotriazole II In Vitro Not mutagenic
Polymeric Benzotriazole ll In vivo Not mutagenic
Bis( 1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate In Vitro Not mutagenic
Name Route Species Value
Amorphous Silica Not
Snecified
Mouse Some positive data exist, but the data are not
suffi cient for classifi cation
Titanium Dioxide IngestionMultipleNot carcinogenic
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3Mrer Scotch-Weld
rM
Concrete air DP600 G and Concrete 600 G Part B 04Jt9t2l
anirnal
sDecies
Titanium Dioxidc lnhalationRat Carcinogenic
Reproductive Toxicity
roductive and/or Effects
Target Organ(s)
T ure
Name Route Value Species Tcst Result Exposure
Duration
Tetrakis(2-hydroxypropyl)ethylenediaminelngestionNot classified for female reproduction Rat NOAEL I,OOO
me/ke/dav
prematlng
into lactation
Tetrakis(2-hydroxypropyl)ethylenediaminelngestionNot classified for male reproduction Rat NOAEL 1,OOO
rns/kp/dav
30 days
Tetrakis(2-hydroxypropyl)ethylenediamineIngestionNot classified for development Rat NOAEL I,OOO
ms/ks/dav
prematrng
into lactation
Amorphous Silica IngestionNot classified for female reproduction Rat NOAEL 509
ms/ks/dav
I generation
Amorphous Silica IngestionNot classified for male reproduction Rat NOAEL 497
rne/ks/day
I generation
Amorphous Silica lngestionNot classified for development Rat NOAEL I,350
nrg/kg/day
during
organogenesi
S
m-Xylene-.alpha.alpha’.-diarnine lngestionNot classified for female reproduction Rat NOAEL 450
ms/kg/day
I generation
m-Xylene-.alpha.alpha’.-diamine IngestionNot classified for male reproduction Rat NOAEL 450
ms/ks
I generation
rn-Xylene-.alpha.alpha’.-diamine IngestionNot classified for development Rat NOAEL 450
n1e/ks./day
I generation
Polymeric Benzotriazole IngestionNot classified for female reproduction Rat NOAEL IOO
me/ke/day
premating
into lactation
Polymeric Benzotriazole IngestionNot classified for male reproduction Rat NOAEL IOO
me/ks/day
I l5 days
Polymeric Benzotriazole IngestionNot classified for development Rat NOAEL 2
me/ks/dav
prgmatlng
into Iactation
Polymeric Benzotriazole ll IngestionNot classified for female reproduction Rat NOAEL IOO
rns/ks/dav
prematlng
into Iactation
Polyrneric Benzotriazole II lngestionNot classified for male reproduction Rat NOAEL IOO
me/ks/day
I 15 days
Polymeric Benzotriazole ll IngestionNot classified for development Rat NOAEL 2
rns/keldav
prematrng
into lactation
Name Route Target Organ(s) Value Specics Test Result Exposure
Duration
Tetrakis(2-
hydroxypropyl)ethylenedia
mine
lnhalationrespiratory irritationSome positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL
Positive
m-Xylene-.alpha.alpha’.-
diamine
Inhalationrespiratory initationSome positive data exist, but the
data are not sufficient for
classification
Not
available
NOAEL Not
avaliable
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Tetrakis(2-
hydroxypropyl)ethylenedia
mine
Ingestionnervous system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 3OO
ng/kg/day
30 days
Tetrakis(2-
hydroxypropyl)ethylenedia
mine
lngestionheart
I skin
I
endocrine system
I
gastrointestinal tract
I bone, teeth, nails,
and/or hair
I
hematoooietic
Not classified Rat NOAEL
1,000
ng/kg/day
30 davs
pg 260 ot 444-P Print5B25B29.pdf–405919212–267 13378
Page 9 of 12
3M
t’M
Scotch_Weld’fM concrete ir DP600 and Concrete r600G Part B 04n9/2t
system
I liver
I
immune system
I
muscles
I
eyes
I
kidney and/or
bladder
I respiratory
system I vascular
system
Amorphous Silica Inhalationrespiratory system
I
si licosis
Not classifled Iluman NOAEL Not
available
occupational
exposr.lre
rn-Xylene-.alpha.alpha’
diamine
Ingestionendocrine systern
I
blood
I bone
marrow
Not classified Rat NOAEL 600
mg/kg/day
2tl days
Titanir”un Dioxide Inhalationrespiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL O.OI
mg/l
2 years
Titanium Dioxide Inhalationpulmonary fibrosisNot classified Human NOAEL Not
available
occupational
exDosure
Polymeric Benzotriazole Ingestionkidney and/or
bladder
Not classified Rat NOAEL not
available
28 days
Polymeric Benzotriazole Ingestionhematopoietic
svstem
Not classified Rat NOAEL 50
me/ks/dav
90 days
Polymeric Benzotriazole Ingestionliver Not classified Rat NOAEL IO
ms/ks/dav
28 days
Polymeric Benzotriazole Ingestion eyes Not classified Rat NOAEL 5O
ms/ks/dav
90 days
Polymeric Benzotriazole IIlngestionkidney and/or
bladder
Not classified Rat NOAEL not
available
28 days
Polymeric Benzotriazole Illngestionhematopoietic
svstem
Not classified Rat NOAEL 50
ms/ke/dav
90 days
Polymeric Benzotriazole llIngestionliver Not classified Rat NOAEL IO
ms/kp/dav
28 days
Polymeric Benzotriazole IlIngestion eyes Not classified Rat NOAEL 50
ms/ksldav
90 days
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecoloal information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on tlris material
and/or its components.
SECTION 13: considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Combustion products will include halogen acid (HC1/HF/HBr). Facility must be capable of
handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be consider d,
pg 261 ol 444-PPrint5825B29.pdI–4059 1921 2–267 1337 I
Page l0 of l2
3MTnr Scotch_Weld’rM Concrete r DP600 and Concrete 600 G Part B 04119127
stored, treated & disposed of as hazardolls wastes Llnless otherwise defined by applicable waste regulations. Consult with the
respective regr”rlating authorities to determine the available treatment and disposal facilities.
SECTION 14: ort Information
For Informati vlsrt M or call 1-800-364-3577 or 651-737-6501
SECTION 15: latoinformation
15.1. US Federal Regulations
Contact 3M for more inforrnation.
EPCRA 31ll3l2 Hazard Classifications:
Physical Hazards
Not applicable
llealth Hazards
Respiratory or Skin Sensitization
Serious eye damage or eye irritation
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. A11 required
components of this product are listed on the active portion of the TSCA Inventory.
Contact 3M for more information
15.4. International Regulations
Contact 3M for more information.
This SDS has been to meet the U.S. OSHA Hazard Communication 29 CFR 1910.r200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: I Instability: I Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by shorl-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:
Issue Date:
l8-0901-1
04/19/2t
Version Number:
Supercedes Date:
10.04
12/11/20
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be corect as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PEMORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M prodr”rct,
pg 262 ol 444-PPrint5B25B29.pdl–405919212–267 1337 B
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3MrM Scotch-weldrM DP6OO G and Concrete r 600 Part B 04tr9t2l
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s rnethod of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in enors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
pg 263 of 444-PPrint5825829.pdl–40591 921 2–267 1337 8
Page 12 of 12