3M Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 05/02/22
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Safety Data Sheet
Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:16-5850-9Version Number:14.04Issue Date:05/02/22Supercedes Date:10/06/21
SECTION 1: Identification
1.1. Product identifier
3M Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
Product Identification Numbers
ID NumberUPCID NumberUPCLA-D100-3132-560-9800-4557-30005113506520460-9800-4558-10005113505220460-9800-4562-362-5239-0330-062-5239-5236-4
7000000629, 7000120490, 7000120491, 7010367674, 7010309906
1.2. Recommended use and restrictions on use
Recommended use
Adhesive Sealant, Sealant
1.3. Supplier s details
MANUFACTURER:3MDIVISION:Industrial Adhesives and Tapes DivisionADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Respiratory Sensitizer: Category 1.
Skin Sensitizer: Category 1.
Reproductive Toxicity: Category 1B.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
Signal word
Danger
Symbols
3M Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 05/02/22
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Health Hazard |
Pictograms
Hazard Statements
May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May damage fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure: respiratory system |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. In case of inadequate ventilation wear respiratory protection. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response:
IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention.
Storage:
Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Supplemental Information:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
2% of the mixture consists of ingredients of unknown acute inhalation toxicity.
SECTION 3: Composition/information on ingredients
IngredientC.A.S. No.% by WtUrethane Polymer51447-37-1 40 – 70 Trade Secret *Titanium Dioxide13463-67-7 10 – 30 Trade Secret *
3M Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 05/02/22
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Synthetic Amorphous Silica112945-52-5 1 – 5 Trade Secret *P,P’-Methylenebis(Phenyl Isocyanate)101-68-8< 2.4 Trade Secret *Zinc Oxide1314-13-2< 2.3 Trade Secret *Alkyl Isocynate Silane85702-90-5< 2 Trade Secret *Alumina Trihydrate21645-51-2< 2 Trade Secret *Carbitol Acetate112-15-2< 2 Trade Secret *Fumed Silica7631-86-9 1 - 2 Trade Secret *Toluene108-88-3< 1 Trade Secret *Heptane142-82-5< 0.3 Trade Secret *(Gamma-mercaptopropyl)trimethoxysilane4420-74-0< 0.2 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Allergic respiratory reaction (difficulty breathing, wheezing, cough, and tightness of chest). Allergic skin reaction (redness, swelling,
blistering, and itching). Target organ effects following prolonged or repeated exposure. See Section 11 for additional details.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance ConditionIsocyanatesDuring CombustionCarbon monoxideDuring CombustionCarbon dioxideDuring CombustionHydrogen CyanideDuring CombustionOxides of NitrogenDuring CombustionOxides of SulfurDuring Combustion
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Toxic Vapor, Gas, ParticulateDuring Combustion
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for
10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working
from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent
material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a
physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a container
approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up.
Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh
air. Read and follow safety precautions on the solvent label and SDS. Dispose of collected material as soon as possible in
accordance with applicable local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.
Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (gloves,
respirators, etc.) as required.
7.2. Conditions for safe storage including any incompatibilities
Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal
container. Store away from amines.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.AgencyLimit typeAdditional CommentsP,P'-Methylenebis(Phenyl
Isocyanate)
101-68-8ACGIHTWA:0.005 ppmP,P'-Methylenebis(Phenyl
Isocyanate)
101-68-8OSHACEIL:0.2 mg/m3(0.02 ppm)Toluene108-88-3ACGIHTWA:20 ppmA4: Not class. as human
carcin, Ototoxicant
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Toluene108-88-3OSHATWA:200 ppm;CEIL:300 ppmSILICA, AMORPHOUS112945-52-
5
OSHATWA:20 millions of
particles/cu. ft.;TWA
concentration:0.8 mg/m3
Zinc Oxide1314-13-2ACGIHTWA(respirable fraction):2
mg/m3;STEL(respirable
fraction):10 mg/m3
Zinc Oxide1314-13-2OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3;TWA(as
fume):5 mg/m3
Titanium Dioxide13463-67-7ACGIHTWA:10 mg/m3A4: Not class. as human
carcin
Titanium Dioxide13463-67-7OSHATWA(as total dust):15 mg/m3Heptane142-82-5ACGIHTWA:400 ppm;STEL:500 ppmHeptane142-82-5OSHATWA:2000 mg/m3(500 ppm)Aluminum, insoluble compounds21645-51-2ACGIHTWA(respirable fraction):1
mg/m3
A4: Not class. as human
carcin
DUST, INERT OR NUISANCE21645-51-2OSHATWA(as total dust):15
mg/m3;TWA(as total dust):50
millions of particles/cu. ft.(15
mg/m3);TWA(respirable
fraction):5
mg/m3;TWA(respirable
fraction):15 millions of
particles/cu. ft.(5 mg/m3)
DUST, INERT OR NUISANCE7631-86-9OSHATWA(as total dust):15
mg/m3;TWA(as total dust):50
millions of particles/cu. ft.(15
mg/m3);TWA(respirable
fraction):5
mg/m3;TWA(respirable
fraction):15 millions of
particles/cu. ft.(5 mg/m3)
SILICA, AMORPHOUS7631-86-9OSHATWA:20 millions of
particles/cu. ft.;TWA
concentration:0.8 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
None required.
3M Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 05/02/22
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Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Liquid
White
Specific Physical Form: PasteOdorSlight UrethaneOdor thresholdNo Data AvailablepHNot ApplicableMelting pointNot ApplicableBoiling PointNot ApplicableFlash PointNo flash pointEvaporation rateNo Data AvailableFlammability (solid, gas)Not ApplicableFlammable Limits(LEL)Not ApplicableFlammable Limits(UEL)Not ApplicableVapor PressureNo Data AvailableVapor DensityNo Data AvailableDensity1.3 g/mlSpecific Gravity1.3 [Ref Std:WATER=1]Solubility in WaterNilSolubility- non-waterNo Data AvailablePartition coefficient: n-octanol/ waterNo Data AvailableAutoignition temperatureNo Data AvailableDecomposition temperatureNo Data AvailableViscosity100,000 - 500,000 centipoiseHazardous Air Pollutants2.6 % weight [Test Method: Calculated]Molecular weightNo Data AvailableVolatile Organic Compounds38 g/l [Test Method:tested per EPA method 24] [Details: EU
VOC content]
Percent volatile2.83 % weightVOC Less H2O & Exempt Solvents38 g/l [Test Method:tested per EPA method 24]
3M Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 05/02/22
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SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
Amines
Alcohols
Water
10.6. Hazardous decomposition products
SubstanceCondition None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
May cause additional health effects (see below).
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Contact with the eyes during product use is not expected to result in significant irritation.
3M Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 05/02/22
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Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Prolonged or repeated exposure may cause target organ effects:
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart
rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
IngredientCAS No.Class DescriptionRegulationTitanium dioxide13463-67-7Grp. 2B: Possible human carc.International Agency for Research on Cancer
Additional Information:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValueOverall productInhalation-
Vapor(4 hr)
No data available; calculated ATE >50 mg/lOverall productIngestionNo data available; calculated ATE >5,000 mg/kgUrethane PolymerDermalLD50 estimated to be > 5,000 mg/kgUrethane PolymerIngestionRatLD50 > 5,000 mg/kgTitanium DioxideDermalRabbitLD50 > 10,000 mg/kgTitanium DioxideInhalation-
Dust/Mist
(4 hours)
RatLC50 > 6.82 mg/lTitanium DioxideIngestionRatLD50 > 10,000 mg/kgSynthetic Amorphous SilicaDermalRabbitLD50 > 5,000 mg/kgSynthetic Amorphous SilicaInhalation-
Dust/Mist
(4 hours)
RatLC50 > 0.691 mg/lSynthetic Amorphous SilicaIngestionRatLD50 > 5,110 mg/kgP,P’-Methylenebis(Phenyl Isocyanate)DermalRabbitLD50 > 5,000 mg/kgP,P’-Methylenebis(Phenyl Isocyanate)Inhalation-
Dust/Mist
(4 hours)
RatLC50 0.368 mg/lP,P’-Methylenebis(Phenyl Isocyanate)IngestionRatLD50 31,600 mg/kgZinc OxideDermalLD50 estimated to be > 5,000 mg/kgZinc OxideInhalation-
Dust/Mist
(4 hours)
RatLC50 > 5.7 mg/lZinc OxideIngestionRatLD50 > 5,000 mg/kgCarbitol AcetateDermalRabbitLD50 15,000 mg/kgCarbitol AcetateIngestionRatLD50 11,000 mg/kgFumed SilicaDermalRabbitLD50 > 5,000 mg/kgFumed SilicaInhalation-
Dust/Mist
(4 hours)
RatLC50 > 0.691 mg/l
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Fumed SilicaIngestionRatLD50 > 5,110 mg/kgAlumina TrihydrateDermalLD50 estimated to be > 5,000 mg/kgAlumina TrihydrateInhalation-
Dust/Mist
(4 hours)
RatLC50 > 2.3 mg/lAlumina TrihydrateIngestionRatLD50 > 5,000 mg/kgTolueneDermalRatLD50 12,000 mg/kgTolueneInhalation-
Vapor (4
hours)
RatLC50 30 mg/lTolueneIngestionRatLD50 5,550 mg/kgHeptaneDermalRabbitLD50 3,000 mg/kgHeptaneInhalation-
Vapor (4
hours)
RatLC50 103 mg/lHeptaneIngestionRatLD50 > 15,000 mg/kg(Gamma-mercaptopropyl)trimethoxysilaneDermalRabbitLD50 2,270 mg/kg(Gamma-mercaptopropyl)trimethoxysilaneIngestionRatLD50 770 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValueTitanium DioxideRabbitNo significant irritationSynthetic Amorphous SilicaRabbitNo significant irritationP,P’-Methylenebis(Phenyl Isocyanate)official
classifica
tion
IrritantZinc OxideHuman
and
animal
No significant irritationCarbitol AcetateHuman
and
animal
Minimal irritationFumed SilicaRabbitNo significant irritationAlumina TrihydrateRabbitNo significant irritationTolueneRabbitIrritantHeptaneHumanMild irritant(Gamma-mercaptopropyl)trimethoxysilaneRabbitNo significant irritation
Serious Eye Damage/Irritation
NameSpeciesValueTitanium DioxideRabbitNo significant irritationSynthetic Amorphous SilicaRabbitNo significant irritationP,P’-Methylenebis(Phenyl Isocyanate)official
classifica
tion
Severe irritantZinc OxideRabbitMild irritantCarbitol AcetateRabbitSevere irritantFumed SilicaRabbitNo significant irritationAlumina TrihydrateRabbitNo significant irritationTolueneRabbitModerate irritantHeptaneProfessio
nal
judgeme
nt
Moderate irritant(Gamma-mercaptopropyl)trimethoxysilaneRabbitNo significant irritation
Skin Sensitization
NameSpeciesValueTitanium DioxideHuman
and
animal
Not classified
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Synthetic Amorphous SilicaHuman
and
animal
Not classifiedP,P’-Methylenebis(Phenyl Isocyanate)official
classifica
tion
SensitizingZinc OxideGuinea
pig
Not classifiedCarbitol AcetateHuman
and
animal
Not classifiedFumed SilicaHuman
and
animal
Not classifiedAlumina TrihydrateGuinea
pig
Not classifiedTolueneGuinea
pig
Not classified(Gamma-mercaptopropyl)trimethoxysilaneGuinea
pig
Sensitizing
Respiratory Sensitization
NameSpeciesValueP,P’-Methylenebis(Phenyl Isocyanate)HumanSensitizing
Germ Cell Mutagenicity
NameRouteValueTitanium DioxideIn VitroNot mutagenicTitanium DioxideIn vivoNot mutagenicSynthetic Amorphous SilicaIn VitroNot mutagenicP,P’-Methylenebis(Phenyl Isocyanate)In VitroSome positive data exist, but the data are not
sufficient for classification
Zinc OxideIn VitroSome positive data exist, but the data are not
sufficient for classification
Zinc OxideIn vivoSome positive data exist, but the data are not
sufficient for classification
Carbitol AcetateIn VitroNot mutagenicFumed SilicaIn VitroNot mutagenicTolueneIn VitroNot mutagenicTolueneIn vivoNot mutagenicHeptaneIn VitroNot mutagenic(Gamma-mercaptopropyl)trimethoxysilaneIn VitroNot mutagenic
Carcinogenicity
NameRouteSpeciesValueTitanium DioxideIngestionMultiple
animal
species
Not carcinogenicTitanium DioxideInhalationRatCarcinogenicSynthetic Amorphous SilicaNot
Specified
MouseSome positive data exist, but the data are not
sufficient for classification
P,P’-Methylenebis(Phenyl Isocyanate)InhalationRatSome positive data exist, but the data are not
sufficient for classification
Fumed SilicaNot
Specified
MouseSome positive data exist, but the data are not
sufficient for classification
Alumina TrihydrateNot
Specified
Multiple
animal
species
Not carcinogenicTolueneDermalMouseSome positive data exist, but the data are not
sufficient for classification
TolueneIngestionRatSome positive data exist, but the data are not
sufficient for classification
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TolueneInhalationMouseSome positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
NameRouteValueSpeciesTest Result Exposure
Duration
Synthetic Amorphous SilicaIngestionNot classified for female reproductionRatNOAEL 509
mg/kg/day
1 generationSynthetic Amorphous SilicaIngestionNot classified for male reproductionRatNOAEL 497
mg/kg/day
1 generationSynthetic Amorphous SilicaIngestionNot classified for developmentRatNOAEL 1,350
mg/kg/day
during
organogenesi
s
P,P’-Methylenebis(Phenyl Isocyanate)InhalationNot classified for developmentRatNOAEL 0.004
mg/l
during
organogenesi
s
Zinc OxideIngestionNot classified for reproduction and/or
development
Multiple
animal
species
NOAEL 125
mg/kg/day
premating &
during
gestation
Fumed SilicaIngestionNot classified for female reproductionRatNOAEL 509
mg/kg/day
1 generationFumed SilicaIngestionNot classified for male reproductionRatNOAEL 497
mg/kg/day
1 generationFumed SilicaIngestionNot classified for developmentRatNOAEL 1,350
mg/kg/day
during
organogenesi
s
Alumina TrihydrateIngestionNot classified for developmentRatNOAEL 768
mg/kg/day
during
organogenesi
s
TolueneInhalationNot classified for female reproductionHumanNOAEL Not
available
occupational
exposure
TolueneInhalationNot classified for male reproductionRatNOAEL 2.3
mg/l
1 generationTolueneIngestionToxic to developmentRatLOAEL 520
mg/kg/day
during
gestation
TolueneInhalationToxic to developmentHumanNOAEL Not
available
poisoning
and/or abuse
Target Organ(s)
Specific Target Organ Toxicity – single exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
P,P’-Methylenebis(Phenyl
Isocyanate)
Inhalationrespiratory irritationMay cause respiratory irritationofficial
classifica
tion
NOAEL Not
available
Carbitol AcetateInhalationcentral nervous
system depression
May cause drowsiness or
dizziness
Human
and
animal
NOAEL Not
available
not applicableCarbitol AcetateIngestioncentral nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
NOAEL Not
available
not applicableTolueneInhalationcentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
TolueneInhalationrespiratory irritationSome positive data exist, but the
data are not sufficient for
classification
HumanNOAEL Not
available
TolueneInhalationimmune systemNot classifiedMouseNOAEL
0.004 mg/l
3 hoursTolueneIngestioncentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
poisoning
and/or abuse
HeptaneInhalationcentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
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HeptaneInhalationrespiratory irritationSome positive data exist, but the
data are not sufficient for
classification
HumanNOAEL Not
available
HeptaneIngestioncentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Titanium DioxideInhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
RatLOAEL 0.01
mg/l
2 yearsTitanium DioxideInhalationpulmonary fibrosisNot classifiedHumanNOAEL Not
available
occupational
exposure
Synthetic Amorphous
Silica
Inhalationrespiratory system |
silicosis
Not classifiedHumanNOAEL Not
available
occupational
exposure
P,P’-Methylenebis(Phenyl
Isocyanate)
Inhalationrespiratory systemCauses damage to organs through
prolonged or repeated exposure
RatLOAEL
0.004 mg/l
13 weeksZinc OxideIngestionnervous systemNot classifiedRatNOAEL 600
mg/kg/day
10 daysZinc OxideIngestionendocrine system |
hematopoietic
system | kidney
and/or bladder
Not classifiedOtherNOAEL 500
mg/kg/day
6 monthsCarbitol AcetateInhalationrespiratory system |
liver | immune
system | kidney
and/or bladder
Not classifiedRatNOAEL 0.48
mg/l
2 weeksFumed SilicaInhalationrespiratory system |
silicosis
Not classifiedHumanNOAEL Not
available
occupational
exposure
TolueneInhalationauditory system |
eyes | olfactory
system
Causes damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
poisoning
and/or abuse
TolueneInhalationnervous systemMay cause damage to organs
though prolonged or repeated
exposure
HumanNOAEL Not
available
poisoning
and/or abuse
TolueneInhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
RatLOAEL 2.3
mg/l
15 monthsTolueneInhalationheart | liver | kidney
and/or bladder
Not classifiedRatNOAEL 11.3
mg/l
15 weeksTolueneInhalationendocrine systemNot classifiedRatNOAEL 1.1
mg/l
4 weeksTolueneInhalationimmune systemNot classifiedMouseNOAEL Not
available
20 daysTolueneInhalationbone, teeth, nails,
and/or hair
Not classifiedMouseNOAEL 1.1
mg/l
8 weeksTolueneInhalationhematopoietic
system | vascular
system
Not classifiedHumanNOAEL Not
available
occupational
exposure
TolueneInhalationgastrointestinal tractNot classifiedMultiple
animal
species
NOAEL 11.3
mg/l
15 weeksTolueneIngestionnervous systemSome positive data exist, but the
data are not sufficient for
classification
RatNOAEL 625
mg/kg/day
13 weeksTolueneIngestionheartNot classifiedRatNOAEL
2,500
mg/kg/day
13 weeksTolueneIngestionliver | kidney and/or
bladder
Not classifiedMultiple
animal
species
NOAEL
2,500
mg/kg/day
13 weeksTolueneIngestionhematopoietic
system
Not classifiedMouseNOAEL 600
mg/kg/day
14 daysTolueneIngestionendocrine systemNot classifiedMouseNOAEL 105
mg/kg/day
28 daysTolueneIngestionimmune systemNot classifiedMouseNOAEL 105 4 weeks
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mg/kg/dayHeptaneInhalationliver | nervous
system | kidney
and/or bladder
Not classifiedRatNOAEL 12
mg/l
26 weeks
Aspiration Hazard
NameValueTolueneAspiration hazardHeptaneAspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered,
stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D018 (Benzene), D035 (Methyl ethyl ketone)
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:
Physical HazardsNot applicableHealth HazardsReproductive toxicity
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Respiratory or Skin SensitizationSpecific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
IngredientC.A.S. No% by WtP,P’-Methylenebis(Phenyl Isocyanate) 101-68-8 Trade Secret < 2.4P,P'-Methylenebis(Phenyl Isocyanate) (Benzene, 1,1'-
methylenebis[4-isocyanato-)
101-68-8 Trade Secret < 2.4P,P'-Methylenebis(Phenyl Isocyanate)
(DIISOCYANATES (CERTAIN CHEMICALS
ONLY))
101-68-8 Trade Secret < 2.4Zinc Oxide (ZINC COMPOUNDS) 1314-13-2 Trade Secret < 2.3Carbitol Acetate (GLYCOL ETHERS) 112-15-2 Trade Secret < 2
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:16-5850-9Version Number:14.04Issue Date:05/02/22Supercedes Date:10/06/21
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535 05/02/22
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3M USA SDSs are available at www.3M.com