SDS
SAFETY DATA SHEET
SDS Number:
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BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
3
Section 1 IDENTIFICATION
Product Name: BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550 FX Structural Acrylic
Bonding Adhesive – Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD 440FX, BD550FX
Structural Acrylic Bonding Adhesives
Materials Uses: High strength acrylic adhesive for bonding fiberglass, steel, aluminum, and various
substrates together. 10:1 product has high flexural strength and tensile strengths.
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA) +1-703-527-3887
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
Organic Peroxides, Type F
DANGER
WARNING
H225 Highly flammable liquid and vapor
H242 Heating may cause a fire
Health
Acute Oral Toxicity, Category 4
Skin Corrosion, Category 1
Serious Eye Damage, Category 1
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H317 May cause an allergic skin reaction
H335 – May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closes.
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BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
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P240 Ground/Bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P301/P330/P331 IF SWALLOWED: Rinse mouth. Do not induce vomiting.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P303/P361/P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304/P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you fell unwell.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
P362/P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish small fires. Use water for large fires.
Storage:
P403 Store in a well-ventilated place.
P405 Store locked up.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
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SAFETY DATA SHEET
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BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
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ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 3
Flammability 3
3
Reactivity 2
PPE B
3
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 80
Methacrylic Acid 79-41-4 1 10
Activator: Benzoyl Peroxide 94-36-0 5 30
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
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BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
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Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Benzoyl Peroxide (CAS 94-36-0): OSHA PEL: TWA 5 mg/m
3
ACGIH TLV: TWA 5 mg/m
3
Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
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BD320FX, BD415FX, BD420FX, BD422FX, BD425FX, BD440FX, BD550FX
Structural Acrylic Bonding Adhesive – Cartridges
Revision No.: 5
Date:08/21/2018
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Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) paste
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) Not Available
Initial Boiling Point: 212
o
F (100
o
C) > 550
o
F (288
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup Not Available
Evaporation Rate: 3 <1 (butyl acetate = 1)
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% Not Available
Upper Explosion Limit: 12.5% Not Available
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) < 0.5 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 Not Available
Relative Density: 7.7 8.8 lbs./gallon Not Available
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) Not Available
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPa-s): 60k 250k 40k to 120k
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 1.0 to 1.15
VOC: < 50 g/L of mixed product Not Available
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
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Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Benzoyl Peroxide (CAS 94-36-0): LC50 = 2 mg/L (96 hour inhalation, guppy)
LD50 = 6400 mg/kg (oral, rat)
LD50 > 2000 mg/kg (oral, mouse)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
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Date:08/21/2018
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Transport Hazard Class: 3.
Packing Group: II
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Benzoyl Peroxide (CAS 94-36-0) 1.0
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Benzoyl Peroxide (CAS 94-36-0) X X X X
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: August 21, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
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Date:08/21/2018
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Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT