Page 1/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
43.0
* 1 Identification
Product identifier
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
Relevant identified uses of the substance or mixture.Adhesive
Application of the substance / the mixtureAdhesives
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
Information department:Environment protection department.
Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
GHS05 Corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) USA
Page 2/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 1)
43.0
Hazard pictograms
GHS02GHS05GHS07GHS08
Signal wordDanger
Hazard statements
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
May cause respiratory irritation.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dusts or mists.
Wear protective gloves / eye protection / face protection.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a POISON CENTER/doctor.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If swallowed: Rinse mouth. Do NOT induce vomiting.
In case of fire: Use for extinction: CO2, powder or water spray.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
3
2
Health = 2
Fire = 3
Reactivity = 2
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
PHYSICAL HAZARD
2
3
2
Health = 2
Fire = 3
Physical Hazard = 2
(Contd. on page 3)
USA
Page 3/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 2)
43.0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture
Hazardous components:
80-62-6 methyl methacrylate 25-50%
79-41-4 methacrylic acid 2.5-10%
* 4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:
Overexposure, remove to fresh air and seek medical attention.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:Do not induce vomiting; immediately call for medical help.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:Protective clothing and respiratory protective device.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
(Contd. on page 4)
USA
Page 4/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 3)
43.0
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location away from direct heat.
Information about storage in one common storage facility:Store away from oxidizing agents.
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
80-62-6 methyl methacrylate
PEL Long-term value: 410 mg/m , 100 ppm
REL Long-term value: 410 mg/m , 100 ppm
TLV Short-term value: 410 mg/m , 100 ppm
Long-term value: 205 mg/m , 50 ppm
DSEN
79-41-4 methacrylic acid
REL Long-term value: 70 mg/m , 20 ppm
Skin
TLV Long-term value: 70 mg/m , 20 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment (see listings below)
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
(Contd. on page 5)
USA
Page 5/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 4)
43.0
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
Face protection (face shield)
Body protection:
Protective work clothing
Emergency showers and eye wash stations should be available.
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Off White
Odor: Characteristic
Odor threshold: Not determined.
pH-value at 20 C (68 F): 3.3
Change in condition
Melting point: Undetermined.
Boiling point: 101 C (214 F)
Flash point: 10 C (50 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 430 C (806 F)
Decomposition temperature: Not determined.
Auto igniting: Not determined.
Danger of explosion: Not determined.
Flammable limits:
Lower: 2.1 Vol %
Upper: 12.5 Vol %
Vapor pressure at 20 C (68 F):28 mm Hg
Specific gravity at 20 C (68 F):1 g/cm (8.345 lbs/gal)
(Contd. on page 6)
USA
Page 6/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 5)
43.0
Relative density Not determined.
Vapor density >1 at 20C
Evaporation rate 3
Solubility in / Miscibility with
Water: Insoluble
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.0 %
Solids content: Not available
Other information <20 grams/liter [mixed]
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoid
Heat, flames, sparks.
Avoid high temperatures. Avoid freezing.
Avoid oxygen free atmospheres or inert blanketing.
Incompatible materials:
Reacts with acids.
Reacts with oxidizing agents.
Reacts with alkalis (bases)
Halogens
Avoid contact with copper, brass and black iron.
Hazardous decomposition products:
Carbon monoxide
Carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
80-62-6 methyl methacrylate
Oral LD50 7872 mg/kg (rat)
79-41-4 methacrylic acid
Oral LD50 1332 mg/kg (mouse)
Dermal LD50 500 mg/kg (rabbit)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Strong irritant with the danger of severe eye injury.
(Contd. on page 7)
USA
Page 7/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 6)
43.0
Sensitization:Skin Contact - Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
80-62-6 methyl methacrylate 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:At present there are no ecotoxicological assessments.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:Must be specially treated adhering to official regulations.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1133
UN proper shipping name
DOT Adhesives
IMDG, IATA ADHESIVES
(Contd. on page 8)
USA
Page 8/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 7)
43.0
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): 33
EMS Number: F-E,S-D
Stowage Category B
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:Limited Quantities are allowed. Refer to 49 CFR for conditions that
apply.
UN "Model Regulation": UN 1133 ADHESIVES, 3, II
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
80-62-6 methyl methacrylate
TSCA (Toxic Substances Control Act):
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
(Contd. on page 9)
USA
Page 9/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 8)
43.0
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(DSL) Canada Dosmestic Substance List
All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL
requirements.
New Jersey Right-to-Know List:
80-62-6 methyl methacrylate
79-41-4 methacrylic acid
New Jersey Special Hazardous Substance List:
80-62-6 methyl methacrylate F3, R2
79-41-4 methacrylic acid CO, F2, R2
Pennsylvania Right-to-Know List:
80-62-6 methyl methacrylate
79-41-4 methacrylic acid
Pennsylvania Special Hazardous Substance List:
80-62-6 methyl methacrylate E
Cancerogenity categories
EPA (Environmental Protection Agency)
80-62-6 methyl methacrylate E, NL
TLV (Threshold Limit Value established by ACGIH)
80-62-6 methyl methacrylate A4
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
National regulations:
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
* 16 Other information
Although the information and recommendations set forth in this SDS are presented in good faith and are believed
to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the
completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it
will make their own determination as to the suitability for their purpose prior to use. In no event will Royal
Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from
the use or reliance on the information set forth in the SDS.
Department issuing SDS:Environment protection department.
Creation Date:11/14/2016
Date of preparation / last revision11/17/2016 / -
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
(Contd. on page 10)
USA
Page 10/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/17/2016 Revision Date 11/14/2016Revision Number 1
Trade name: MP55300/MP55305/MP55315 Part A (Resin)
(Contd. of page 9)
43.0
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flam. Liq. 2: Flammable liquids Category 2
Skin Corr. 1A: Skin corrosion/irritation Category 1A
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Muta. 2: Germ cell mutagenicity Category 2
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
USA
Page 1/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
44.0
* 1 Identification
Product identifier
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
Relevant identified uses of the substance or mixture.Activator
Application of the substance / the mixtureActivator
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
Information department:Environment protection department.
Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07
Signal wordDanger
Hazard statements
Highly flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
(Contd. on page 2)
USA
Page 2/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 1)
44.0
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wear protective gloves / eye protection / face protection.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
Wash contaminated clothing before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
2
3
2
Health = 2
Fire = 3
Reactivity = 2
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
PHYSICAL HAZARD
2
3
2
Health = 2
Fire = 3
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture
Hazardous components:
80-62-6 methyl methacrylate 50-100%
* 4 First-aid measures
Description of first aid measures
After inhalation:
Supply fresh air and to be sure call for a doctor.
(Contd. on page 3)
USA
Page 3/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 2)
44.0
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:Do not induce vomiting; immediately call for medical help.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fire with alcohol resistant foam.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Firefighters use standard protective equipment including flame retardant coat, helmet with face shield, gloves,
rubber boots, and in enclosed spaces, SCBA.
Protective equipment:Protective clothing and respiratory protective device.
* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
80-62-6 methyl methacrylate 17 ppm
PAC-2:
80-62-6 methyl methacrylate 120 ppm
PAC-3:
80-62-6 methyl methacrylate 570 ppm
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Ensure good ventilation/exhaustion at the workplace.
(Contd. on page 4)
USA
Page 4/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 3)
44.0
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep container closed when not in use.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location away from direct heat.
Information about storage in one common storage facility:Store away from oxidizing agents.
Further information about storage conditions:
Protect product from freezing.
Protect from heat and direct sunlight.
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
80-62-6 methyl methacrylate
PEL Long-term value: 410 mg/m , 100 ppm
REL Long-term value: 410 mg/m , 100 ppm
TLV Short-term value: 410 mg/m , 100 ppm
Long-term value: 205 mg/m , 50 ppm
DSEN
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment (see listings below)
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
(Contd. on page 5)
USA
Page 5/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 4)
44.0
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Face protection (face shield)
Safety glasses with side shields.
Tightly sealed goggles
Body protection:
Emergency showers and eye wash stations should be available.
Protective work clothing
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Paste
Color: Not determined.
Odor: Characteristic
Odor threshold: Not determined.
pH-value: 5
Change in condition
Melting point: Undetermined.
Boiling point: 101 C (214 F)
Flash point: 10 C (50 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 430 C (806 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Flammable limits:
Lower: 2.1 Vol %
Upper: 12.5 Vol %
Vapor pressure at 20 C (68 F):47 hPa (35 mm Hg)
Specific gravity at 20 C (68 F):0.96 g/cm (8.011 lbs/gal)
Relative density Not determined.
Vapor density 3.5
Evaporation rate 3
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
(Contd. on page 6)
USA
Page 6/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 5)
44.0
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 0.0 %
Solids content: Not available
Other information <20 grams/liter [mixed]
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoid
Avoid high temperatures. Avoid freezing.
Heat, flames, sparks.
Direct sunlight
Incompatible materials:
Reacts with acids.
Reacts with oxidizing agents.
Reacts with alkalis (bases)
Copper and copper alloys.
Hazardous decomposition products:
Carbon monoxide
Carbon dioxide
Nitrogen oxides
Hydrocarbons
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
80-62-6 methyl methacrylate
Oral LD50 7872 mg/kg (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:
May irritate the eye.
Vapors may be irritating to the eyes.
Sensitization:Skin Contact - Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
(Contd. on page 7)
USA
Page 7/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 6)
44.0
Carcinogenic categories
IARC (International Agency for Research on Cancer)
80-62-6 methyl methacrylate 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:At present there are no ecotoxicological assessments.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:Must be specially treated adhering to official regulations.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1133
UN proper shipping name
DOT Adhesives
IMDG, IATA ADHESIVES mixture
Transport hazard class(es)
DOT
Class 3 Flammable liquids
(Contd. on page 8)
USA
Page 8/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 7)
44.0
Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): 33
EMS Number: F-E,S-D
Stowage Category B
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:Limited Quantities are allowed. Refer to 49 CFR for conditions that
apply.
UN "Model Regulation": UN 1133 ADHESIVES MIXTURE, 3, II
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
80-62-6 methyl methacrylate
TSCA (Toxic Substances Control Act):
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(DSL) Canada Dosmestic Substance List
All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL
requirements.
(Contd. on page 9)
USA
Page 9/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 8)
44.0
New Jersey Right-to-Know List:
80-62-6 methyl methacrylate
New Jersey Special Hazardous Substance List:
80-62-6 methyl methacrylate F3, R2
Pennsylvania Right-to-Know List:
80-62-6 methyl methacrylate
Pennsylvania Special Hazardous Substance List:
80-62-6 methyl methacrylate E
Cancerogenity categories
EPA (Environmental Protection Agency)
80-62-6 methyl methacrylate E, NL
TLV (Threshold Limit Value established by ACGIH)
80-62-6 methyl methacrylate A4
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
National regulations:
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
* 16 Other information
Although the information and recommendations set forth in this SDS are presented in good faith and are believed
to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the
completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it
will make their own determination as to the suitability for their purpose prior to use. In no event will Royal
Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from
the use or reliance on the information set forth in the SDS.
Department issuing SDS:Environment protection department.
Creation Date:02/02/2017
Date of preparation / last revision02/02/2017 / -
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
(Contd. on page 10)
USA
Page 10/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 02/02/2017 Revision Date 02/02/2017Revision Number 1
Trade name: MP55300, MP55305, MP55315 Part B (Activator)
(Contd. of page 9)
44.0
Flam. Liq. 2: Flammable liquids Category 2
Skin Irrit. 2: Skin corrosion/irritation Category 2
Skin Sens. 1: Skin sensitisation Category 1
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
USA