REVISED
JUNE/2014
MATERIAL SAFETY DATA SHEETS
1. CHEMICAL PRODUCT
Adhesive Systems, Inc.
9411 Corsair Road
Frankfort, IL 60423
1-800-552-0299 Phone
1-815-464-5650 Fax
EMERGENCY PHONE 1-800-255-3924 In ternational +01+813-248-0585
Product Name: MP55350 Part A (Resin)
Technical Name:
Methyl Methacrylate
2. HAZARDS IDENTIFICATION
Primary Routes of Entry: Inhalation and skin
Symptoms of Exposure: Eyes-redness, swelling, tearing, and hazy vision.
Skin-redness, swelling, and
itching.
Inhalation- Soreness of the nose and throat, coughing.
Medical Conditions Aggravated
by Exposure: Preexisting eye, respiratory, and skin disorders may be aggravated by
exposure.
Carcinogenicity: None
Hazard Classification
Physical Classification: Flammable Liquid and vapor Category 3
Symbol:
Signal
Word: Danger
Health Classification: Irritant: Causes mild skin or eye irritation Category 3
Symbol:
Signal Word: Warning
3. COMPOSITION AND INFORMAT ION ON HARMFUL INGREDIENTS
Ingredients Cas No. OSHA PEL ACGIH TLV Other Limits %Composition
Methyl Methacrylate
P(BD/MMA/STY)
Polychloroprene
80-62-6
25053-09-2
9010-98-4
100ppm
N.E.
N.E.
50ppm
N.E.
N.E.
100ppm (Canada)
N.E.
N.E.
35-65
5-15
5-15
*Proprietary means the specific chemical identity and/or weight percent is being withheld as a trade secret.
Page 1 of 4
MATERIAL SAFETY DATA SHEETS
MP55350 Part A (Resin)
Methyl Methacryalte
4. FIRST AID MEASURES
Ingestion: Get immediate medical attention, DO NOT INDUCE VOMITING.
Inhalation: Remove to fresh air, if symptoms continue, seek medical advice.
Skin Contact: Soak in warm soapy water. Discard contaminated clothing. Do not use organic solvents. If
irritation occurs, get medical attention.
Eye Contact: Immediately flush eyes with water fo r at least 20 minutes, seek medical attention.
5. FIRE FIGHTING MEASURES
Flammable Limits: LEL=2.1 for MMA UEL=12.5 for MMA
Extinguishing Media: Use dry chemical powder. Insoluble in water.
Special Fire Fighting Procedures: Wear self contained breathing app aratus and full turnout gear.
Unusual Fire / Explosion Hazards: None
6. ACCIDENTAL RELEASE MEASURES
Ventilate area of spill. Flood area with water to polymerize. Absorb with sand / earth and dispose in accordance
with local, state, and federal regulations.
7. HANDLING AND STORAGE
When using large volumes ensure that operational area is well ventilated.
Store between 5-25 C; avoid strong light and heat sources. These products should never be frozen.
Avoid skin contact and inhalation of vapor.
8. EXPOSURE CONTROL AND PERSONAL PROTECTION
OSHA PEL: N/A
TLV: 0.2 ppm TWA
Engineering Controls: Use good general local v entilation when working with this material.
Eye Protection: Safety goggles / glasses suitable for use with chemicals.
Respiratory Protection: Use with adequate ventilation. If adequate ventilation is not available always use
appropriate organic vapor mask.
Skin Protection: Nitrile / polyethylene gloves, coveralls, avoid cotton products.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor: Light gel, pungent, acrylic odor
Flashpoint: 51 F (TCC)
Solubility in Water: Slight
Boiling Point:214 F for MMA
Specific Gravity: 1.0-1.1 @25 C
Evaporation rate: N/D
Melting Point: N/D
Vapor Pressure: 29mm @ 20 C
Vapor Density:>1, 3.5 for MMA
V .O.C. Content: <50g/L (Mixed)
Page 2 of 4
MATERIAL SAFETY DATA SHEETS
MP55350 Part A (Resin)
Methyl Methacryalte
10. REACTIVITY AND STABILIITY
Chemical Stability: Stable
Hazardous Polymerization: May occur, Excessive agin g and/or heat, polymerization catalysts, oxygen-free
atmosphere, inhibitor depletion, direct sunlight.
Incompatibility: Oxidizers, acids, bases, uv radiation, amines.
Conditions to Avoid: None
Hazardous Decomposition Products: Carbon and nitro gen oxides, hydrogen cyanide,methylene bisphenyl,
isocyanate, hydrocarbons
11. TOXICOLOGICAL INFORMATION
Routes of Exposure; Inhalation and skin Related Symptoms: Moderate respiratory tract ir ritation. Moderate skin irritation , redness.
Chronic Effects: Chronic Exposure may lead to kidney or liver damage. Use adequate ventilation to maintain
airborne concentration below exposure li mits. Not believed to represent a carcinogenic or mutagenic hazard.
12. ECOLOGICAL INFORMATION
None.
13. DISPOSAL INFORMATION
This material must be disposed in compliance with l ocal, state, and federal regulations. When in consumer
packaging this material must be disposed of as household waste. Check local and state regulations for disposal of
this product as a household waste in your state or municipality.
14. TRANSPORTATION INFORMATION
U.S.DOT
Materials shipped in Quantities of more than 1 Liter in combination or single packaging.
UN 1133 Adhesives 3 II
Limited quantities, No shipping paper required. Limited quantity mark is required on the outer surface of the finished package.
ICAO/IATA
Materials shipped in Quantities of more than 1 Liter in combination or single packaging.
UN 1133 Adhesives 3 II
Materials shipped in Limited Quantities
ID 8000 Consumer Commodity 9 (Limited Quantity Marking with Y required on outer surface of the package and Class 9 label also
`required on the outer surface of the package)
IMDG
Materials shipped in Quantities of more than 1 Liter in combination or single packaging.
UN 1133 Adhesives 3 II
Limited quantities in combination packages only:
UN1133 Adhesives 3 II Ltd. Qty (FP in degrees C c.c. required on shipping paper) Limited marking only required on outer surface of
package.
Page 3 of 4
MATERIAL SAFETY DATA SHEETS
MP55350 Part A (Resin)
Methyl Methacryalte
15. REGULATORY INFORMATION
TSCA
All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory.
SARATitleIII,Section13
This product does contain the following chem ical(s) which are defined as toxic chemicals under and subject to the
reporting requirements of, Section 313 of Title III of the Superfund Am endments and Reauthorization Act of 1986
and40CFRPart372.
Methyl Methacrylate
16. OTHER INFORMATION
Initial: 8/22/2007
Revised: JUNE 2014
HMIS HEALTH 2 FLAMMABILITY 3 REACTIVITY 2
NFPA
HEALTH 2 FIRE HAZARD 3 REACTIVITY 2
NON-WARRANTY: Information contained herein is based on tests we believe to be reliable and accurate. It is offered in good faith for the
benefit of the consumer. Adhesive Systems shall not be liable for any injury, loss, or damage in the use of it's chemical products since the
conditions of use are beyond our control. In every case we urge and recommend the user conduct tests to determine to their own satisfaction
that the product is of acceptable quality and is suitable for their particular purpose under their own operating conditions. Statements
concerning the possible use of our products are not intended as recommendations to use our products in the infringement of any patent.
Because of changing reporting requirements and other variables it is impossible to guarantee the accuracy of the information contained in
this document. It is the responsibility of the user to determine proper personal protection based on the actual condition of use and to comply
with all Federal, State, and Local laws and regulations.
Revised JUNE 2014
Page 4 of 4
REVISED
JUNE/2014
MATERIAL SAFETY DATA SHEETS
1. CHEMICAL PRODUCT
Adhesive Systems, Inc.
9411 Corsair Road
Frankfort, IL 60423
1-800-552-0299 Phone
1-815-464-5650 Fax
EMERGENCY PHONE 1-800-255-3924 In ternational +01+813-248-0585
Product Name: MP55350 Part B (Activator)
Technical Name:
Methyl Methacrylate
2. HAZARDS IDENTIFICATION
Primary Routes of Entry: Inhalation and skin
Symptoms of Exposure: Eyes-redness, swelling, tearing, and hazy vision.
Skin-redness, swelling, and
itching.
Inhalation- Soreness of the nose and throat, coughing.
Medical Conditions Aggravated
by Exposure:
Preexisting eye, repiratory, and skin disorders may be aggravated by exposure.
Carcinogenicity: None
Hazard Classification
Physical Classification: Flammable Liquid Category 3
Symbol:
Signal Word: Danger
Health Classification:
Irritant: Causes mild skin or eye irritation Category 3
Symbol:
Signal Word: Warning
3. COMPOSITION AND INFORMAT ION ON HARMFUL INGREDIENTS
Ingredients Cas No. OSHA PEL ACGIH TLV Other Limits %Composition
Methyl Methacrylate
P(BD/MMA/STY)
80-62-6
25053-09-2
100ppm
N.E.
50ppm
N.E.
100ppm (Canada)
N.E
65-85
5-15
Page 1 of 4
MATERIAL SAFETY DATA SHEETS
MP55350 Part B (Activator)
Methyl Methacryalte
4. FIRST AID MEASURES
Ingestion: Get immediate medical attention,DO NOT INDUCE VOMITING.
Inhalation: Remove to fresh air, if symptoms continue, seek medical advice.
Skin Contact: Soak in warm soapy water.Discard cont aminated clothing. Do not use organic solvents. If
irritation occurs, get medical attention.
Eye Contact: Immediately flush eyes with water fo r at least 20 minutes, seek medical attention.
5. FIRE FIGHTING MEASURES
Flammable Limits: LEL=2.1 for MMA UEL=12.5 for MMA
Extinguishing Media: Use dry chemical powder. Insoluble in water.
Special Fire Fighting Procedures: Wear self contained breathing app aratus and full turnout gear.
Unusual Fire / Explosion Hazards: None
6. ACCIDENTAL RELEASE MEASURES
Ventilate area of spill. Flood area with water to polymerize. Absorb with sand / earth and dispose in accordance
with local, state, and federal regulations.
7. HANDLING AND STORAGE
When using large volumes ensure that operational area is well ventilated.
Store between 5-25 C; avoid strong light and heat sources. These products should never be frozen.
Avoid skin contact and inhalation of vapor.
8. EXPOSURE CONTROL AND PERSONAL PROTECTION
Engineering Controls: Use good general local v entilation when working with this material.
Eye Protection: Safety goggles / glasses suitable for use with chemicals.
Respiratory Protection: Use with adequate ventilation. If adequate ventilation is not available always use
appropriate organic vapor mask.
Skin Protection: Nitrile / polyethylene gloves, coveralls, avoid cotton products.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor: Off white, black, or grey liquid.
Flashpoint: 51 F (TCC)
Solubility in Water: Slight
Boiling Point:214 F for MMA
Specific Gravity: 1.2-1.3 @25 C
Evaporation rate: N/D
Melting Point: N/D
Vapor Pressure: 29mm @ 20 C
Vapor Density:>1, 3.5 for MMA
V .O.C. Content: <50g/L
Page 2 of 4
MATERIAL SAFETY DATA SHEETS
MP55350 Part B (Activator)
Methyl Methacryalte
10. REACTIVITY AND STABILITY
Chemical Stability: Stable
Hazardous Polymerization: May occur, Excessive agin g and/or heat, polymerization catalysts, oxygen-free
atmosphere, inhibitor depletion, direct sunlight.
Incompatibility: Oxidizers, acids, bases, uv radiation, amines.
Conditions to Avoid: None
Hazardous Decomposition Products: Carbon and nitro gen oxides, hydrogen cyanide,methylene bisphenyl,
isocyanate, hydrocarbons
11.TOXICOLOGICAL INFORMATION
Routes of Exposure; Inhalation and skin Related Symptoms: Moderate respiratory tract ir ritation. Moderate skin irritation , redness.
Chronic Effects: Chronic Exposure may lead to kidney or liver damage. Use adequate ventilation to maintain
airborne concentration below exposure li mits. Not believed to represent a carcinogenic or mutagenic hazard.
12. ECOLOGICAL INFORMATION
None.
13. DISPOSAL INFORMATION
This material must be disposed in compliance with l ocal, state, and federal regulations. When in consumer
packaging this material must be disposed of as household waste. Check local and state regulations for disposal of
this product as a household waste in your state or municipality.
14. TRANSPORTATION INFORMATION
U.S.DOT
Materials shipped in Quantities of more than 1 Liter in combination or single packaging.
UN 1133 Adhesives 3 II
Limited quantities, No shipping paper required. Limited quantity mark is required on the outer surface of the finished package.
ICAO/IATA
Materials shipped in Quantities of more than 1 Liter in combination or single packaging.
UN 1133 Adhesives 3 II
Materials shipped in Limited Quantities
ID 8000 Consumer Commodity 9 (Limited Quantity Marking with Y required on outer surface of the package and Class 9 label also
`required on the outer surface of the package)
IMDG
Materials shipped in Quantities of more than 1 Liter in combination or single packaging.
UN 1133 Adhesives 3 II
Limited quantities in combination packages only:
UN1133 Adhesives 3 II Ltd. Qty (FP in degrees C c.c. required on shipping paper) Limited marking only required on outer surface of
package.
Page 3 of 4
MATERIAL SAFETY DATA SHEETS
MP55350 Part B (Activator)
Methyl Methacryalte
15. REGULATORY INFORMATION
TSCA
All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory.
SARATitleIII,Section13
This product does contain the following chem ical(s) which are defined as toxic chemicals under and subject to the
reportingrequirements of, Section 313 of Title III of the Superfund Amendm ents and Reauthorization Act of 1986
and40CFRPart372.
Methyl Methacrylate
16. OTHER INFORMATION
Initial: 8/22/2007
Revised: JUNE 2014
HMIS HEALTH 2 FLAMMABILITY 3 REACTIVITY 2
NFPA
HEALTH 2 FIRE HAZARD 3 REACTIVITY 2
NON-WARRANTY: Information contained herein is based on tests we believe to be reliable and accurate. It is offered in good faith for the
benefit of the consumer. Adhesive Systems shall not be liable for any injury, loss, or damage in the use of it's chemical products since the
conditions of use are beyond our control. In every case we urge and recommend the user conduct tests to determine to their own satisfaction
that the product is of acceptable quality and is suitable for their particular purpose under their own operating conditions. Statements
concerning the possible use of our products are not intended as recommendations to use our products in the infringement of any patent.
Because of changing reporting requirements and other variables it is impossible to guarantee the accuracy of the information contained in
this document. It is the responsibility of the user to determine proper personal protection based on the actual condition of use and to comply
with all Federal, State, and Local laws and regulations.
Revised JUNE 2014
Page 4 of 4