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SAFETY DATA SHEET
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Version 1.0 Revision Date 05/21/2019
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : ASI MP-55330-A
Product code : 100000008550
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives
Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606
Medical Emergency Phone Number (24 Hours): 1-888-853-1758
Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300
Recommended use of the chemical and restrictions on use
Recommended use : Adhesive
Restrictions on use : For industrial use only.
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance paste
Color off-white
Odor characteristic
GHS Classification
Flammable liquids : Category 2
Acute toxicity (Inhalation) : Category 2
Skin irritation : Category 2
Serious eye damage : Category 1
Skin sensitization : Category 1
Carcinogenicity : Category 2
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :
Signal Word : Danger
Hazard Statements:
H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H317 May cause an allergic
skin reaction. H318 Causes serious eye damage. H330 Fatal if inhaled. H335 May cause
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respiratory irritation. H351 Suspected of causing cancer.
Precautionary Statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety
precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot
surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and
receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use
only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not
breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use
only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed
out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection. P284 Wear respiratory protection.
Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. P304 + P340 + P310 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351
+ P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation
or rash occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before
reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects
Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
tetrahydrofuran
109-99-9
cumene
98-82-8
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP Reasonably anticipated to be a human carcinogen
cumene
98-82-8
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients
Chemical name CAS-No. Concentration [%]
ethyl 2-cyanoacrylate 7085-85-0 50 – 70
methyl methacrylate 80-62-6 5 – 10
1,4-Naphthalenedione 130-15-4 3 – 5
2,6-di-tert-butyl-p-cresol 128-37-0 1 – 5
tetrahydrofuran 109-99-9 1 – 5
2-Propenoic acid, 2-methyl-, 2-hydroxyethyl ester,
phosphate
52628-03-2 0.1 – 1
, -dimethylbenzyl hydroperoxide 80-15-9 0.1 – 1
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cumene 98-82-8 0.1 – 1
SECTION 4. FIRST AID MEASURES
General advice : Show this material safety data sheet to the doctor in
attendance.
If inhaled : Move to fresh air.
Keep patient warm and at rest.
Consult a physician after significant exposure.
In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.
If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.
Drink plenty of water.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Carbon dioxide (CO2)
Sand
Foam
Unsuitable extinguishing
media
: Water
Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.
Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.
Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.
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Use neutralizing agents.
Shovel or sweep up.
SECTION 7. HANDLING AND STORAGE
Local/Total ventilation : Use only with adequate ventilation.
Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Keep away from heat and flame.
Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.
Materials to avoid : Do not store together with oxidizing and self-igniting products.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
ethyl 2-cyanoacrylate 7085-85-0 PEL 0.2 ppm
1.02 mg/m3
CAL PEL
TWA 0.2 ppm ACGIH
STEL 1 ppm ACGIH
methyl methacrylate 80-62-6 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 100 ppm
410 mg/m3
OSHA Z-1
TWA 100 ppm
410 mg/m3
OSHA P0
PEL 50 ppm
205 mg/m3
CAL PEL
STEL 100 ppm
410 mg/m3
CAL PEL
2,6-di-tert-butyl-p-cresol 128-37-0 TWA
(Inhalable
fraction and
vapor)
2 mg/m3 ACGIH
TWA 10 mg/m3 OSHA P0
PEL 10 mg/m3 CAL PEL
tetrahydrofuran 109-99-9 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 200 ppm
590 mg/m3
OSHA Z-1
STEL 250 ppm OSHA P0
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735 mg/m3
TWA 200 ppm
590 mg/m3
OSHA P0
PEL 200 ppm
590 mg/m3
CAL PEL
STEL 250 ppm
735 mg/m3
CAL PEL
cumene 98-82-8 TWA 50 ppm ACGIH
TWA 50 ppm
245 mg/m3
NIOSH REL
TWA 50 ppm
245 mg/m3
OSHA Z-1
TWA 50 ppm
245 mg/m3
OSHA P0
PEL 50 ppm
245 mg/m3
CAL PEL
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Filter type : Combined particulates and organic vapor type
Hand protection
Material : Impervious gloves
Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.
Skin and body protection : Long sleeved clothing
Preventive skin protection
Protective measures : Avoid contact with skin.
Hygiene measures : Avoid contact with skin, eyes and clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : paste
Color : off-white
Odor : characteristic
Odor Threshold : No data available
Melting point/freezing point : not determined
Boiling point/boiling range : not determined
Flash point : 10 C
Evaporation rate : not determined
Flammability (solid, gas) : Not classified as a flammability hazard
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Upper explosion limit : Upper flammability limit
not determined
Lower explosion limit : Lower flammability limit
not determined
Density : 0.99 g/cm3
Solubility(ies)
Water solubility : not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : not determined
Viscosity
Viscosity, kinematic : not determined
SECTION 10. STABILITY AND REACTIVITY
Chemical stability : The product is chemically stable.
Hazardous decomposition
products
: Nitrogen oxides (NOx)
Sulfur oxides
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : 2,347 mg/kg
Method: Calculation method
Acute inhalation toxicity : Acute toxicity estimate : 1.25 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Method: Calculation method
Components:
methyl methacrylate:
Acute inhalation toxicity : LC50 Rat: 4632 ppm
Exposure time: 4 h
Test atmosphere: vapor
2,6-di-tert-butyl-p-cresol:
Acute oral toxicity : LD50 Oral Rat: 6,000 mg/kg
, -dimethylbenzyl hydroperoxide:
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Acute oral toxicity : LD50 Oral Rat: 382 mg/kg
Acute inhalation toxicity : LC50 Rat: 220 ppm
Exposure time: 4 h
Test atmosphere: vapor
Acute dermal toxicity : LD50 Dermal Rat: 500 mg/kg
cumene:
Acute oral toxicity : LD50 Oral Rat: 1,400 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
methyl methacrylate :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 79 mg/l
Exposure time: 96 h
Test Method: flow-through test
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 69 mg/l
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aquatic invertebrates Exposure time: 48 h
Test Method: static test
2,6-di-tert-butyl-p-cresol :
Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): 5 mg/l
Exposure time: 48 h
Test Method: static test
Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 0.42 mg/l
Exposure time: 72 h
Test Type: flow-through test
, -dimethylbenzyl hydroperoxide :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 3.9 mg/l
Exposure time: 96 h
Test Method: static test
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 7 mg/l
Exposure time: 24 h
Test Method: static test
cumene :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.7 mg/l
Exposure time: 96 h
Test Method: semi-static test
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 0.6 mg/l
Exposure time: 48 h
Test Method: static test
Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (microalgae)): 2.6 mg/l
Exposure time: 72 h
Test Type: flow-through test
Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
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Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.
SECTION 14. TRANSPORT INFORMATION
Special precautions for user
Not applicable
Domestic regulation
49 CFR
UN/ID/NA number : 1133
Proper shipping name : Adhesives
Class : 3
Packing group : II
Labels : 3
ERG Code : 128
Marine pollutant : no
International Regulations
IATA-DGR
UN/ID No. : 1133
Proper shipping name : Adhesives
Class : 3
Packing group : II
Labels : 3
Packing instruction (cargo
aircraft)
: 364
Packing instruction
(passenger aircraft)
: 353
IMDG-Code
UN number : 1133
Proper shipping name : ADHESIVES
Class : 3
Packing group : II
Labels : 3
EmS Code : F-E, S-D
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
SECTION 15. REGULATORY INFORMATION
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SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitization
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
SARA 302 : This material does not contain any components with a section 302
EHS TPQ.
SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
methyl methacrylate 80-62-6
cumene 98-82-8
Clean Air Act
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR
61):
methyl methacrylate 80-62-6
cumene 98-82-8
US State Regulations
California Prop 65 Please contact Supplier for more information.
The ingredients of this product are reported in the following inventories:
TSCA On TSCA Inventory
DSL All components of this product are on the Canadian DSL
AICS On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AICS (Australia), NZIoC
(New Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV
(Taiwan)
SECTION 16. OTHER INFORMATION
Prepared by: Global Regulatory Department – phone: 1-651-236-5842 – email:
msds.request@hbfuller.com
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Further information
NFPA: HMIS III:
The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.
Flammability
Health
Instability
3
3
0
Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
0
3*
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : ASI MP-55330-B
Product code : 100000008551
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives
Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606
Medical Emergency Phone Number (24 Hours): 1-888-853-1758
Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300
Recommended use of the chemical and restrictions on use
Recommended use : Activator
Restrictions on use : For industrial use only.
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance liquid
Color light cream
Odor characteristic
GHS Classification
Flammable liquids : Category 2
Skin irritation : Category 2
Skin sensitization : Category 1
Carcinogenicity : Category 2
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :
Signal Word : Danger
Hazard Statements:
H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H317 May cause an allergic
skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer.
Precautionary Statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety
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precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot
surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and
receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use
only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid
breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use
only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed
out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. P304 + P340 + P312 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P308 +
P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash
occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects
Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
tetrahydrofuran
109-99-9
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients
Chemical name CAS-No. Concentration [%]
methyl methacrylate 80-62-6 70 – 90
3,5-diethyl-1,2-dihydro-1-phenyl-2-propylpyridine 34562-31-7 1 – 5
2,6-di-tert-butyl-p-cresol 128-37-0 1 – 5
tetrahydrofuran 109-99-9 0.1 – 1
SECTION 4. FIRST AID MEASURES
General advice : Show this material safety data sheet to the doctor in
attendance.
If inhaled : Move to fresh air.
Keep patient warm and at rest.
Consult a physician after significant exposure.
In case of skin contact : Wash off immediately with soap and plenty of water.
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Call a physician if irritation develops or persists.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.
If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Carbon dioxide (CO2)
Sand
Foam
Unsuitable extinguishing
media
: Water
Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.
Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.
Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.
Do not flush with water.
Shovel or sweep up.
SECTION 7. HANDLING AND STORAGE
Local/Total ventilation : Use only with adequate ventilation.
Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Keep away from heat and flame.
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Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.
Materials to avoid : Do not store together with oxidizing and self-igniting products.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
methyl methacrylate 80-62-6 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 100 ppm
410 mg/m3
OSHA Z-1
TWA 100 ppm
410 mg/m3
OSHA P0
PEL 50 ppm
205 mg/m3
CAL PEL
STEL 100 ppm
410 mg/m3
CAL PEL
2,6-di-tert-butyl-p-cresol 128-37-0 TWA
(Inhalable
fraction and
vapor)
2 mg/m3 ACGIH
TWA 10 mg/m3 OSHA P0
PEL 10 mg/m3 CAL PEL
tetrahydrofuran 109-99-9 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 200 ppm
590 mg/m3
OSHA Z-1
STEL 250 ppm
735 mg/m3
OSHA P0
TWA 200 ppm
590 mg/m3
OSHA P0
PEL 200 ppm
590 mg/m3
CAL PEL
STEL 250 ppm
735 mg/m3
CAL PEL
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Filter type : Combined particulates and organic vapor type
Hand protection
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Material : Impervious gloves
Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.
Skin and body protection : Long sleeved clothing
Preventive skin protection
Protective measures : Avoid contact with skin.
Hygiene measures : Avoid contact with skin, eyes and clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : light cream
Odor : characteristic
Odor Threshold : No data available
Melting point/freezing point : not determined
Boiling point/boiling range : not determined
Evaporation rate : not determined
Flammability (solid, gas) : Not classified as a flammability hazard
Upper explosion limit : Upper flammability limit
not determined
Lower explosion limit : Lower flammability limit
not determined
Density : 0.94 g/cm3
Solubility(ies)
Water solubility : not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : not determined
Viscosity
Viscosity, kinematic : not determined
SECTION 10. STABILITY AND REACTIVITY
Chemical stability : The product is chemically stable.
Hazardous decomposition
products
: Nitrogen oxides (NOx)
Sulfur oxides
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SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Components:
methyl methacrylate:
Acute inhalation toxicity : LC50 Rat: 4632 ppm
Exposure time: 4 h
Test atmosphere: vapor
2,6-di-tert-butyl-p-cresol:
Acute oral toxicity : LD50 Oral Rat: 6,000 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
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Components:
methyl methacrylate :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 79 mg/l
Exposure time: 96 h
Test Method: flow-through test
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 69 mg/l
Exposure time: 48 h
Test Method: static test
2,6-di-tert-butyl-p-cresol :
Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): 5 mg/l
Exposure time: 48 h
Test Method: static test
Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 0.42 mg/l
Exposure time: 72 h
Test Type: flow-through test
Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.
SECTION 14. TRANSPORT INFORMATION
Special precautions for user
Not applicable
Domestic regulation
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49 CFR
UN/ID/NA number : 1247
Proper shipping name : Methyl methacrylate monomer, stabilized solution
Class : 3
Packing group : II
Labels : 3
ERG Code : 129P
Marine pollutant : no
International Regulations
IATA-DGR
UN/ID No. : 1247
Proper shipping name : Methyl methacrylate monomer, stabilized
Class : 3
Packing group : II
Labels : 3
Packing instruction (cargo
aircraft)
: 364
Packing instruction
(passenger aircraft)
: 353
IMDG-Code
UN number : 1247
Proper shipping name : METHYL METHACRYLATE, MONOMER, STABILIZED
Class : 3
Packing group : II
Labels : 3
EmS Code : F-E, S-D
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
SECTION 15. REGULATORY INFORMATION
SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Skin corrosion or irritation
Respiratory or skin sensitization
Specific target organ toxicity (single or repeated exposure)
Carcinogenicity
SARA 302 : This material does not contain any components with a section 302
EHS TPQ.
SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
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methyl methacrylate 80-62-6
Clean Air Act
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR
61):
methyl methacrylate 80-62-6
US State Regulations
California Prop 65 : Please contact Supplier for more information.
The ingredients of this product are reported in the following inventories:
TSCA On TSCA Inventory
DSL All components of this product are on the Canadian DSL
AICS On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory
PICCS On the inventory, or in compliance with the inventory
IECSC On the inventory, or in compliance with the inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AICS (Australia), NZIoC
(New Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV
(Taiwan)
SECTION 16. OTHER INFORMATION
Prepared by: Global Regulatory Department – phone: 1-651-236-5842 – email:
msds.request@hbfuller.com
Further information
NFPA: HMIS III:
The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
Flammability
Health
Instability
2
3
0
Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
0
2*
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
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consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.