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SAFETY DATA SHEET
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Version 1.2 Revision Date 05/11/2021
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : ASI MP-55320-A
Product code : 100000007520
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives
Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606
Medical Emergency Phone Number (24 Hours): 1-888-853-1758
Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300
Recommended use of the chemical and restrictions on use
Recommended use : Adhesive
Restrictions on use : For industrial use only.
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance liquid
Color No data available
Odor characteristic
GHS Classification
Flammable liquids : Category 2
Skin corrosion : Category 1A
Serious eye damage : Category 1
Skin sensitization : Category 1
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :
Signal Word : Danger
Hazard Statements:
H225 Highly flammable liquid and vapor. H314 Causes severe skin burns and eye damage. H317
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May cause an allergic skin reaction. H335 May cause respiratory irritation.
Precautionary Statements:
Prevention: P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233
Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use
explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243
Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/
vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-
ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response: P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 +
P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep
comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 +
P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER. P333 + P313 If
skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing
before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects
Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
N,N-dimethyl-p-toluidine
99-97-8
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients
Chemical name CAS-No. Concentration [%]
methyl methacrylate 80-62-6 50 – 70
methacrylic acid 79-41-4 5 – 10
N,N-dimethyl-p-toluidine 99-97-8 0.1 – 1
Rosin 8050-09-7 0.1 – 1
2-Propenoic acid, 2-methyl-, 2-hydroxyethyl ester,
phosphate
52628-03-2 0.1 – 1
Actual concentration is withheld as a trade secret
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SECTION 4. FIRST AID MEASURES
General advice : Show this material safety data sheet to the doctor in
attendance.
If inhaled : Move to fresh air.
Keep patient warm and at rest.
Consult a physician after significant exposure.
In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.
If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.
Drink plenty of water.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Carbon dioxide (CO2)
Sand
Foam
Unsuitable extinguishing
media
: Water
Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.
Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.
Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.
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Use neutralizing agents.
Shovel or sweep up.
SECTION 7. HANDLING AND STORAGE
Local/Total ventilation : Use only with adequate ventilation.
Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Keep away from heat and flame.
Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.
Materials to avoid : Do not store together with oxidizing and self-igniting products.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
methyl methacrylate 80-62-6 TWA 50 ppm ACGIH
STEL 100 ppm ACGIH
TWA 100 ppm
410 mg/m3
OSHA Z-1
TWA 100 ppm
410 mg/m3
OSHA P0
PEL 50 ppm
205 mg/m3
CAL PEL
STEL 100 ppm
410 mg/m3
CAL PEL
methacrylic acid 79-41-4 TWA 20 ppm ACGIH
TWA 20 ppm
70 mg/m3
OSHA P0
PEL 20 ppm
70 mg/m3
CAL PEL
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Filter type : Combined particulates and organic vapor type
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Hand protection
Material : Impervious gloves
Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.
Skin and body protection : Long sleeved clothing
Preventive skin protection
Protective measures : Avoid contact with skin.
Hygiene measures : Avoid contact with skin, eyes and clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : No data available
Odor : characteristic
Odor Threshold : No data available
Melting point/freezing point : is not determined
Boiling point/boiling range : is not determined
Flash point : 11 C
Evaporation rate : is not determined
Flammability (solid, gas) : Not classified as a flammability hazard
Upper explosion limit : Upper flammability limit
is not determined
Lower explosion limit : Lower flammability limit
is not determined
Vapor pressure : is not determined
Density : 0.94 g/cm3
Solubility(ies)
Water solubility : is not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : is not determined
Viscosity
Viscosity, kinematic : is not determined
SECTION 10. STABILITY AND REACTIVITY
Chemical stability : The product is chemically stable.
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Hazardous decomposition
products
: Nitrogen oxides (NOx)
Sulfur oxides
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute inhalation toxicity : Acute toxicity estimate : 5.02 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Components:
methyl methacrylate:
Acute inhalation toxicity : LC50 Rat: 4632 ppm
Exposure time: 4 h
Test atmosphere: vapor
methacrylic acid:
Acute inhalation toxicity : LC50 Rat: 7.1 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
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No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
methyl methacrylate :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 79 mg/l
Exposure time: 96 h
Test Method: flow-through test
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 69 mg/l
Exposure time: 48 h
Test Method: static test
N,N-dimethyl-p-toluidine :
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 42 – 50.5 mg/l
Exposure time: 96 h
Test Method: flow-through test
Rosin :
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 3.8 – 5.4 mg/l
Exposure time: 48 h
Test Method: static test
Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
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Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.
SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR
UN/ID No. : UN 2920
Proper shipping name : Corrosive liquid, flammable, n.o.s.
(METHACRYLIC ACID, METHYLMETHACRYLATE )
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : Corrosive, Flammable Liquids
Packing instruction (cargo
aircraft)
: 855
Packing instruction
(passenger aircraft)
: 851
IMDG-Code
UN number : UN 2920
Proper shipping name : CORROSIVE LIQUID, FLAMMABLE, N.O.S.
(METHACRYLIC ACID, METHYLMETHACRYLATE )
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : 8 (3)
EmS Code : F-E, S-C
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 2920
Proper shipping name : Corrosive liquids, flammable, n.o.s.
(METHACRYLIC ACID, METHYLMETHACRYLATE )
Class : 8
Subsidiary risk : 3
Packing group : II
Labels : CORROSIVE, FLAMMABLE LIQUID
ERG Code : 132
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Marine pollutant : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.
SECTION 15. REGULATORY INFORMATION
SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Respiratory or skin sensitization
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
SARA 302 : This material does not contain any components with a section 302
EHS TPQ.
SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
methyl methacrylate 80-62-6
Clean Air Act
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR
61):
methyl methacrylate 80-62-6
US State Regulations
California Prop 65 Please contact Supplier for more information.
The ingredients of this product are reported in the following inventories:
TSCA All substances listed as active on the TSCA inventory
DSL All components of this product are on the Canadian DSL
AIIC On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AICS (Australia), NZIoC
(New Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV
(Taiwan)
SECTION 16. OTHER INFORMATION
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Prepared by: Global Regulatory Department – phone: 1-651-236-5842 – email:
msds.request@hbfuller.com
Further information
NFPA: HMIS III:
The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.
Flammability
Health
Instability
3
3
0
Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
0
3*
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : ASI MP-55320-B
Product code : 100000007007
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives
Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606
Medical Emergency Phone Number (24 Hours): 1-888-853-1758
Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300
Recommended use of the chemical and restrictions on use
Recommended use : Activator
Restrictions on use : For industrial use only.
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance solid
Color yellow
Odor characteristic
GHS Classification
Skin irritation : Category 2
Eye irritation : Category 2A
Skin sensitization : Category 1
Carcinogenicity : Category 2
Reproductive toxicity : Category 1B
Specific target organ toxicity –
repeated exposure
: Category 2
GHS label elements
Hazard pictograms :
Signal Word : Danger
Hazard Statements:
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H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye
irritation. H351 Suspected of causing cancer. H360 May damage fertility or the unborn child. H373
May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety
precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/
spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing must not be
allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye
irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash
before reuse.
Storage: P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects
Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
cumene
98-82-8
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP Reasonably anticipated to be a human carcinogen
cumene
98-82-8
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients
Chemical name CAS-No. Concentration [%]
dibenzoyl peroxide 94-36-0 20 – 30
Epoxy resin 25068-38-6 10 – 20
dibutyl phthalate 84-74-2 10 – 20
zinc distearate 557-05-1 1 – 5
calcium sulfate 7778-18-9 1 – 5
, -dimethylbenzyl hydroperoxide 80-15-9 1 – 3
Silica, amorphous fumed 112945-52-5 1 – 5
2,6-di-tert-butyl-p-cresol 128-37-0 1 – 5
cumene 98-82-8 0.1 – 1
SECTION 4. FIRST AID MEASURES
General advice : Show this material safety data sheet to the doctor in
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attendance.
If inhaled : Move to fresh air.
Keep patient warm and at rest.
Consult a physician after significant exposure.
In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.
If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Carbon dioxide (CO2)
Sand
Foam
Unsuitable extinguishing
media
: Water
Hazardous combustion
products
: No hazardous combustion products are known
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.
Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.
Methods and materials for
containment and cleaning up
: Ventilate the area.
Soak up with inert absorbent material.
Do not flush with water.
Shovel or sweep up.
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SECTION 7. HANDLING AND STORAGE
Local/Total ventilation : Use only with adequate ventilation.
Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Keep away from heat and flame.
Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.
Materials to avoid : Do not store together with oxidizing and self-igniting products.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
dibenzoyl peroxide 94-36-0 TWA 5 mg/m3 ACGIH
TWA 5 mg/m3 NIOSH REL
TWA 5 mg/m3 OSHA Z-1
TWA 5 mg/m3 OSHA P0
PEL 5 mg/m3 CAL PEL
dibutyl phthalate 84-74-2 TWA 5 mg/m3 ACGIH
TWA 5 mg/m3 OSHA Z-1
TWA 5 mg/m3 OSHA P0
PEL 5 mg/m3 CAL PEL
zinc distearate 557-05-1 TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA
(respirable
fraction)
5 mg/m3 OSHA Z-1
TWA (Total) 10 mg/m3 OSHA P0
TWA
(Respirable
fraction)
5 mg/m3 OSHA P0
TWA 10 mg/m3 ACGIH
TWA (Total
dust)
10 mg/m3 OSHA P0
TWA
(respirable
dust fraction)
5 mg/m3 OSHA P0
PEL 10 mg/m3 CAL PEL
TWA
(Inhalable
10 mg/m3 ACGIH
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particulate
matter)
TWA
(Respirable
particulate
matter)
3 mg/m3 ACGIH
calcium sulfate 7778-18-9 TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA
(respirable
fraction)
5 mg/m3 OSHA Z-1
TWA (Total) 15 mg/m3 OSHA P0
TWA
(Respirable
fraction)
5 mg/m3 OSHA P0
TWA
(Inhalable
particulate
matter)
10 mg/m3 ACGIH
TWA (Total
dust)
15 mg/m3 OSHA P0
TWA
(respirable
dust fraction)
5 mg/m3 OSHA P0
PEL (Total
dust)
10 mg/m3 CAL PEL
PEL
(respirable
dust fraction)
5 mg/m3 CAL PEL
TWA
(Inhalable
particulate
matter)
10 mg/m3 ACGIH
Silica, amorphous fumed 112945-52-5 TWA (Dust) 20 Million
particles per cubic
foot
OSHA Z-3
TWA (Dust) 80 mg/m3
/ %SiO2
OSHA Z-3
TWA (Dust) 20 Million
particles per cubic
foot
OSHA Z-3
TWA (Dust) 80 mg/m3
/ %SiO2
OSHA Z-3
2,6-di-tert-butyl-p-cresol 128-37-0 TWA
(Inhalable
fraction and
vapor)
2 mg/m3 ACGIH
TWA 10 mg/m3 OSHA P0
PEL 10 mg/m3 CAL PEL
cumene 98-82-8 TWA 50 ppm ACGIH
TWA 50 ppm
245 mg/m3
NIOSH REL
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TWA 50 ppm
245 mg/m3
OSHA Z-1
TWA 50 ppm
245 mg/m3
OSHA P0
PEL 50 ppm
245 mg/m3
CAL PEL
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Filter type : Combined particulates and organic vapor type
Hand protection
Material : Impervious gloves
Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.
Skin and body protection : Long sleeved clothing
Preventive skin protection
Protective measures : Avoid contact with skin.
Hygiene measures : Avoid contact with skin, eyes and clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : solid
Color : yellow
Odor : characteristic
Odor Threshold : No data available
Melting point/freezing point : is not determined
Boiling point/boiling range : is not determined
Evaporation rate : is not determined
Flammability (solid, gas) : Not classified as a flammability hazard
Upper explosion limit : Upper flammability limit
is not determined
Lower explosion limit : Lower flammability limit
is not determined
Vapor pressure : is not determined
Density : 0.94 g/cm3
Solubility(ies)
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Water solubility : is not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : is not determined
Viscosity
Viscosity, kinematic : is not determined
SECTION 10. STABILITY AND REACTIVITY
Chemical stability : The product is chemically stable.
Hazardous decomposition
products
: Nitrogen oxides (NOx)
Sulfur oxides
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute inhalation toxicity : Acute toxicity estimate : 175.15 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Method: Calculation method
Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Components:
, -dimethylbenzyl hydroperoxide:
Acute oral toxicity : LD50 Oral Rat: 382 mg/kg
Acute inhalation toxicity : LC50 Rat: 220 ppm
Exposure time: 4 h
Test atmosphere: vapor
Acute dermal toxicity : LD50 Dermal Rat: 500 mg/kg
2,6-di-tert-butyl-p-cresol:
Acute oral toxicity : LD50 Oral Rat: 6,000 mg/kg
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cumene:
Acute oral toxicity : LD50 Oral Rat: 1,400 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
dibutyl phthalate :
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 0.31 – 5.45
mg/l
Exposure time: 96 h
Test Method: static test
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 2.99 mg/l
Exposure time: 48 h
Test Method: static test
Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (microalgae)): 0.4 mg/l
Exposure time: 96 h
Test Type: static test
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calcium sulfate :
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,970 mg/l
Exposure time: 96 h
Test Method: static test
, -dimethylbenzyl hydroperoxide :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 3.9 mg/l
Exposure time: 96 h
Test Method: static test
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 7 mg/l
Exposure time: 24 h
Test Method: static test
2,6-di-tert-butyl-p-cresol :
Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): 5 mg/l
Exposure time: 48 h
Test Method: static test
Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 0.42 mg/l
Exposure time: 72 h
Test Type: flow-through test
cumene :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.7 mg/l
Exposure time: 96 h
Test Method: semi-static test
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 0.6 mg/l
Exposure time: 48 h
Test Method: static test
Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (microalgae)): 2.6 mg/l
Exposure time: 72 h
Test Type: flow-through test
Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
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Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.
SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR
UN/ID No. : UN 3077
Proper shipping name : Environmentally hazardous substance, solid, n.o.s.
(DIBUTYL PHTHALATE, EPOXY RESIN)
Class : 9
Packing group : III
Labels : Miscellaneous,
Packing instruction (cargo
aircraft)
: 956
Packing instruction
(passenger aircraft)
: 956
Remarks : PACKAGES <5 L NOT REGULATED, IATA 4.4, SP A197
IMDG-Code
UN number : UN 3077
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(DIBUTYL PHTHALATE, EPOXY RESIN )
Class : 9
Subsidiary risk : ENVIRONM.
Packing group : III
Labels : 9 (ENVIRONM.)
EmS Code : F-A, S-F
Marine pollutant : yes
Remarks : PACKAGES <5 L NOT REGULATED, IMDG 3.3 SP 969
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 3077
Proper shipping name : Environmentally hazardous substance, solid, n.o.s.
(DIBUTYL PHTHALATE)
Class : 9
Packing group : III
Labels : CLASS 9
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ERG Code : 171
Marine pollutant : yes
Remarks : PACKAGES <450 L NOT REGULATED, CFR 172.102 SP
149
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.
SECTION 15. REGULATORY INFORMATION
SARA 311/312 Hazards : Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitization
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity (single or repeated exposure)
SARA 302 : This material does not contain any components with a section 302
EHS TPQ.
SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
dibenzoyl peroxide 94-36-0
dibutyl phthalate 84-74-2
zinc distearate 557-05-1
, -dimethylbenzyl hydroperoxide 80-15-9
cumene 98-82-8
Clean Air Act
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR
61):
dibutyl phthalate 84-74-2
cumene 98-82-8
US State Regulations
California Prop 65 Please contact Supplier for more information.
The ingredients of this product are reported in the following inventories:
TSCA All substances listed as active on the TSCA inventory
DSL All components of this product are on the Canadian DSL
AIIC On the inventory, or in compliance with the inventory
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KECI On the inventory, or in compliance with the inventory
IECSC On the inventory, or in compliance with the inventory
Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AICS (Australia), NZIoC
(New Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV
(Taiwan)
SECTION 16. OTHER INFORMATION
Prepared by: Global Regulatory Department - phone: 1-651-236-5842 - email:
msds.request@hbfuller.com
Further information
NFPA: HMIS III:
The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.
Flammability
Health
Instability
2
1
0
Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
2*
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic