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SAFETY DATA SHEET

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : H.B. Fuller RP-2400
Product code : 100000009750
Manufacturer or supplier’s details
Company : H.B. Fuller Engineering Adhesives

Address : 9001 W Fey Drive
Frankfort, IL, 60423
Telephone : 1-815-464-5606

Medical Emergency Phone Number (24 Hours): 1-888-853-1758

Transport Emergency Phone Number (CHEMTREC): 1-800-424-9300

Recommended use of the chemical and restrictions on use
Recommended use : Cyanoacrylate Adhesive

Restrictions on use : For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview
Appearance liquid
Color Clear liquid, light yellow to light green in color
Odor characteristic

GHS Classification
Flammable liquids : Category 4
Skin irritation : Category 2
Eye irritation : Category 2A
Skin sensitization : Category 1
Carcinogenicity : Category 2
Specific target organ toxicity –
single exposure
: Category 3 (Respiratory system)
GHS label elements
Hazard pictograms :

Signal Word : Warning

Hazard Statements:

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H227 Combustible liquid. H315 Causes skin irritation. H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of
causing cancer.
Precautionary Statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety
precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot
surfaces. No smoking. P261 Avoid breathing mist or vapors. P264 Wash skin thoroughly after
handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing
must not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF
INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 +
P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash
occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/
attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire:
Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235
Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Potential Health Effects

Carcinogenicity:
IARC No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous ingredients
Chemical name CAS-No. Concentration [%]
ethyl 2-cyanoacrylate 7085-85-0 70 – 90
hydroquinone 123-31-9 0.1 – 1
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : Show this material safety data sheet to the doctor in
attendance.

If inhaled : Move to fresh air.

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If not breathing, give artificial respiration.
Keep patient warm and at rest.
Consult a physician after significant exposure.

In case of skin contact : Wash off immediately with soap and plenty of water.
Call a physician if irritation develops or persists.
Cyanoacrylate. Danger. Bonds skin and eyes in seconds.
Keep out of the reach of children.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Seek medical advice.

If swallowed : If swallowed, call a poison control center or doctor
immediately.
Do not induce vomiting without medical advice.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.

Unsuitable extinguishing
media
: Water spray jet

Hazardous combustion
products
: Nitrogen oxides (NOx)
Specific extinguishing
methods
:
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Special protective equipment
for fire-fighters
: Wear an approved positive pressure self-contained breathing
apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,
protective equipment and
emergency procedures
: Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.

Environmental precautions : Prevent product from entering drains.
Do not flush into surface water or sanitary sewer system.

Methods and materials for
containment and cleaning up
: Allow to solidify.
Pick up and transfer to properly labeled containers.
Ventilate the area.

SECTION 7. HANDLING AND STORAGE

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Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Wear personal protective equipment.
Do not get on skin or clothing.
Use only in an area equipped with a safety shower.

Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in original container.

Materials to avoid : Do not store together with oxidizing and self-igniting products.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
ethyl 2-cyanoacrylate 7085-85-0 PEL 0.2 ppm
1.02 mg/m3
CAL PEL
TWA 0.2 ppm ACGIH
STEL 1 ppm ACGIH
hydroquinone 123-31-9 TWA 1 mg/m3 ACGIH
TWA 2 mg/m3 OSHA Z-1
TWA 2 mg/m3 OSHA P0
PEL 2 mg/m3 CAL PEL

Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Filter type : Combined particulates and organic vapor type

Hand protection
Material : Nitrile rubber
Remarks : Do not wear cotton or natural fiber gloves.

Eye protection : Tightly fitting safety goggles
Ensure that eyewash stations and safety showers are close to
the workstation location.

Skin and body protection : Long sleeved clothing
Preventive skin protection

Protective measures : Avoid contact with skin.

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Hygiene measures : Avoid contact with skin, eyes and clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : Clear liquid, light yellow to light green in color
Odor : characteristic
Odor Threshold : No data available
pH : is not determined
Melting point/freezing point : is not determined
Boiling point/boiling range : is not determined
Flash point : 83 C
Not applicable
Evaporation rate : is not determined
Flammability (solid, gas) : Not classified as a flammability hazard

Upper explosion limit : Upper flammability limit
is not determined
Lower explosion limit : Lower flammability limit
is not determined
Vapor pressure : is not determined
Density : 1.06 g/cm3
Solubility(ies)
Water solubility : is not determined
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : is not determined
Viscosity
Viscosity, kinematic : is not determined

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : The product is chemically stable.

Hazardous decomposition
products
: Stable under normal conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:

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Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Components:
hydroquinone:
Acute oral toxicity : LD50 Oral Rat: 320 mg/kg

Acute dermal toxicity : LD50 Dermal Rat: > 900 mg/kg

Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration toxicity
No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
hydroquinone :
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.044 mg/l
Exposure time: 96 h
Test Method: flow-through test

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.29 mg/l

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aquatic invertebrates Exposure time: 48 h
Test Method: static test

Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (microalgae)): 0.335
mg/l
Exposure time: 72 h
Test Type: flow-through test

Persistence and degradability
No data available
Bioaccumulative potential
Mobility in soil
No data available
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of together with household waste.
Do not dispose of waste into sewer.
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous
Waste Regulations 40 CFR 261. Disposal via incineration at
an approved facility is recommended, as industry best
practice. Consult state, local or provincial authorities for more
restrictive requirements.

SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : NA 1993

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Proper shipping name : Combustible liquid, n.o.s.
(ethyl 2-cyanoacrylate)
Class : CBL
Packing group : III
ERG Code : 128
Marine pollutant : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Respiratory or skin sensitization
Carcinogenicity
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

Clean Air Act

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR
61):
hydroquinone 123-31-9

US State Regulations
California Prop 65 Please contact Supplier for more information.

The ingredients of this product are reported in the following inventories:
TSCA All substances listed as active on the TSCA inventory
DSL All components of this product are on the Canadian DSL
AIIC On the inventory, or in compliance with the inventory
KECI On the inventory, or in compliance with the inventory
PICCS On the inventory, or in compliance with the inventory
IECSC On the inventory, or in compliance with the inventory

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Inventories LegendTSCA (USA), DSL (Canada), REACH(Europe), AIIC (Australia), NZIoC (New
Zealand), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China), TWINV (Taiwan)

SECTION 16. OTHER INFORMATION

Prepared by: Global Regulatory Office – phone: 1-651-236-5842 – email: msds.request@hbfuller.com

Further information

NFPA: HMIS III:

The information and recommendations set forth herein are believed to be accurate. Because some of
the information is derived from information provided to the H.B. Fuller Company from its suppliers, and
because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B.
Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the
results to be obtained from the use thereof. The information is supplied solely for your information and
consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is
the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal,
state and local laws and regulations.

Flammability

Health

Instability

2
2

0

Special hazard
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
2

0

2*

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic