3M Glass Bubbles, Types K and S 07/20/15
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Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit there on.
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
SECTION 1: Identification
1.1. Product identifier
3M Glass Bubbles, Types K and S
Product Identification Numbers
70-0701-1952-7, 70-0701-8213-7, 70-0701-9409-0, 70-0701-9423-1, 70-0703-2625-4, 70-0703-2736-9, 70-0703-2737-7, 70-
0703-2749-2, 70-0703-2815-1, 70-0703-2816-9, 70-0703-3031-4, 70-0704-1615-4, 70-0704-1616-2, 70-0704-2949-6, 70-
0704-2950-4, 70-0704-2956-1, 70-0704-2959-5, 70-0704-2962-9, 70-0704-2966-0, 70-0704-2967-8, 70-0704-2968-6, 70-
0704-2971-0, 70-0704-5810-7, 70-0704-5811-5, 70-0704-5816-4, 70-0704-5822-2, 70-0704-5908-9, 70-0704-8401-2, 70-
0704-8402-0, 70-0704-8403-8, 70-0704-8404-6, 70-0704-8405-3, 70-0704-8406-1, 70-0704-8408-7, 70-0704-8409-5, 70-
0704-8410-3, 70-0704-8764-3, 70-0706-6017-3, 70-0707-4394-6, 98-0212-1022-8, 98-0212-1024-4, 98-0212-1025-1, 98-
0212-2726-3, 98-0212-2743-8, 98-0212-2744-6, 98-0212-2972-3, 98-0212-3053-1, 98-0212-3072-1, 98-0212-3206-5, 98-
0212-3207-3, 98-0212-3208-1, 98-0212-3210-7, 98-0212-3281-8, 98-0212-3315-4, 98-0212-3316-2, 98-0212-3317-0, 98-
0212-3320-4, 98-0212-3323-8, 98-0212-3351-9, 98-0212-3366-7, 98-0212-3389-9, 98-0212-3520-9, 98-0212-3522-5, 98-
0212-3532-4, 98-0212-3579-5, 98-0212-3587-8, 98-0212-3590-2, 98-0212-3591-0, 98-0212-3604-1, 98-0212-3622-3, 98-
0212-3640-5, 98-0213-3043-0, FJ-9600-0081-0, FJ-9600-0082-8, FJ-9600-0083-6, FS-9000-2572-7, FS-9000-2590-9, FS-
9100-0397-9, FS-9100-0398-7, FS-9100-0410-0, FS-9100-0411-8, FS-9100-0414-2, FS-9100-0437-3, FS-9100-0441-5, FS-
9100-0444-9, FS-9100-0746-7, FS-9100-0846-5, FS-9100-0882-0, FS-9100-1029-7, FS-9100-1313-5, FS-9100-1717-7, FS-
9100-1831-6, FS-9100-2037-9, FS-9100-2330-8, FS-9100-2363-9, FS-9100-2366-2, FS-9100-2395-1, FS-9100-2396-9, FS-
9100-2412-4, FS-9100-2438-9, FS-9100-2544-4, FS-9100-2590-7, FS-9100-2629-3, FS-9100-2708-5, FS-9100-2709-3, FS-
9100-2711-9, FS-9100-2984-2, FS-9100-3027-9, FS-9100-3028-7, FS-9100-3325-7, FS-9100-3346-3, FS-9100-3452-9, FS-
9100-3618-5, FS-9100-4083-1, FS-9100-4179-7, FS-9100-4216-7, FS-9100-4225-8, FS-9100-4227-4, FS-9100-4280-3, FS-
9100-4300-9, FS-9100-4311-6, FS-9100-4324-9, FS-9100-4360-3, FS-9100-4439-5, FS-9100-4472-6, FS-9100-4561-6, FS-
9100-5009-5, FS-9100-5010-3, FS-9100-5053-3, FS-9100-5065-7, FS-9100-5068-1, FS-9100-5121-8, FS-9100-5146-5, FS-
9100-5183-8, FS-9100-5184-6, FS-9100-5192-9, FS-9100-5194-5, FS-9100-5198-6, FS-9100-5199-4, FS-9100-5250-5, FS-
9100-5300-8, FS-9100-5304-0, FS-9100-5375-0, FS-9100-5392-5, FS-9100-5397-4, FS-9100-5415-4, H0-0021-5045-8, HB-
0040-8050-1, HB-0041-0069-7, HB-0041-8096-2, HB-0041-8898-1, HB-0041-8905-4, HB-0041-8906-2, HB-0041-8907-0,
HB-0041-8908-8, HB-0041-8909-6, HB-0041-8910-4, HB-0041-8911-2, HB-0041-8913-8, HB-0041-9053-2, HB-0041-
9054-0, HB-0041-9055-7, HB-0041-9074-8, HB-0041-9077-1, HB-0041-9124-1, HB-0041-9125-8, HB-0041-9126-6, HB-
0041-9127-4, HB-0041-9128-2, HB-0041-9131-6, HB-0041-9140-7, HB-0041-9142-3, HB-0041-9143-1, HB-0041-9146-4,
HB-0041-9147-2, HB-0041-9190-2, HB-0041-9193-6, HB-0041-9194-4, HB-0041-9234-8, HB-0042-0876-3, HB-0042-
0879-7, HB-0042-0881-3, HB-0042-0887-0, HB-0042-0888-8, HB-0042-3265-6, HB-0042-3909-9, HB-0042-4880-1, HB-
0042-7100-1, HB-0042-7135-7, HC-0006-2403-7, HC-0006-2404-5, HC-0006-2405-2, HC-0006-2406-0, HC-0006-2407-8,
HC-0006-2408-6, HC-0006-2409-4, HC-0006-2410-2, HC-0006-2411-0, HC-0006-2412-8, HC-0006-2413-6, HC-0006-
2414-4, HC-0006-2415-1, HC-0006-2416-9, HC-0006-2417-7, HC-0006-2418-5, HC-0006-2419-3, HC-0006-2420-1, HC-
0006-2421-9, HC-0006-2629-7, HC-0006-2630-5, HC-0006-2632-1, HC-0006-2633-9, HC-0006-2634-7, HC-0006-2635-4,
HC-0006-2636-2, HC-0006-2637-0, HC-0006-2638-8, HC-0006-2705-5, HC-0006-2706-3, HC-0006-2707-1, HC-0006-
3381-4, HC-0006-3389-7, HC-0006-3491-1, HC-0006-4572-7, JF-1000-4245-2, JF-1000-4246-0, JF-1000-4247-8, JF-1000-
4251-0, JF-1000-4252-8, JF-1000-4253-6, JF-1000-4254-4, JF-1000-4255-1, JF-1000-4257-7, JF-1000-4258-5, JF-1000-
4259-3, JF-1000-4261-9, JF-1000-4398-9, JF-1000-4422-7, JF-1000-4423-5, WF-6001-0106-8, WF-6001-0107-6, WF-6001-
0108-4, WF-6001-0109-2, WF-6001-0110-0, WF-6001-0111-8, WF-6001-0112-6, WF-6001-0113-4, WF-6001-0114-2, WF-
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6001-0115-9, WF-6001-0116-7, WF-6001-0117-5, WF-6001-0118-3, WF-6001-0119-1, WF-6001-0120-9, WF-6001-0121-7,
WF-6001-0126-6, WF-6001-0127-4, WF-6001-0128-2, WF-6001-0129-0, WF-6001-0130-8, WF-6001-0131-6, WF-6001-
0132-4, WF-6001-0134-0, WF-6001-0135-7, WF-6001-0136-5, WF-6001-0137-3, WF-6001-0138-1, WF-6001-0148-0, WF-
6001-0150-6, WF-6001-0169-6, WF-6001-0170-4, WF-6001-1734-6, WF-6001-1814-6, WF-6009-0001-4, WF-6009-0002-2,
WF-6009-0003-0, WF-6009-0004-8, WF-6009-0005-5, WF-6009-0006-3, WF-6009-0007-1, WF-6009-0009-7, WF-6009-
0010-5, WF-6009-0017-0, WF-6009-0028-7, WF-6009-0029-5, WF-6009-0038-6, WF-6009-0039-4, WF-6009-0053-5, WF-
6009-0054-3, WF-6009-0055-0, WF-6009-0056-8, WF-6009-0057-6, WF-6009-0064-2, WF-6009-0065-9, WF-6009-0066-7,
WF-6009-0070-9, WF-6009-0077-4, WF-6009-0087-3, WF-6009-0091-5, WF-6009-0128-5, WF-6009-0162-4, WF-6009-
0163-2, WF-6009-0164-0, WF-6009-0210-1, WF-6009-0211-9, WF-6009-0366-1, WF-6009-0422-2, WF-6009-0423-0, WF-
6009-0473-5, WF-6009-0633-4, WF-6009-0634-2, WF-6009-0932-0, ZF-9100-1831-4
1.2. Recommended use and restrictions on use
Recommended use
Lightweight Filler
1.3. Supplier s details
MANUFACTURER: 3M
DIVISION: Advanced Materials Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Soda Lime Borosilicate Glass 65997-17-3 97 – 100
Synthetic Amorphous Crystalline-Free Silica 7631-86-9 0 – 3
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
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Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Washwith soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising fromthe substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up. Place
in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of
collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when
using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
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Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.Agency Limit type Additional Comments
Soda Lime Borosilicate Glass65997-17-3Manufacturer
determined
TWA(as dust):10 mg/m3
SILICA, AMORPHOUS 7631-86-9OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Synthetic Amorphous Crystalline-
Free Silica
7631-86-9CMRG TWA(as respirable dust):3
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer’s Recommended Guidelines
OSHA : United States Department of Labor -Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to belowrelevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specificapplication, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Low density fine powder (< 100 microns)
Odor, Color, Grade: White odorless
Odor threshold Not Applicable
Melting point No Data Available
Boiling Point Not Applicable
Flash Point Not Applicable
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Evaporation rateNot Applicable
Flammability (solid, gas) Not Classified
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Density 0.1 -0.6 g/cm3
Specific Gravity 0.1 -0.6 [Ref Std: WATER=1]
Solubility in Water Negligible
Solubility-non-water Not Applicable
Partition coefficient: n-octanol/ water Not Applicable
Autoignition temperature Not Applicable
Decomposition temperature Not Applicable
Viscosity Not Applicable
Volatile Organic Compounds Not Applicable
Percent volatile < 0.5 % weight
Softening point >=600 C
VOC Less H2O & Exempt Solvents Not Applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known. Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material cla ssification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
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Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing,nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If acomponent is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRoute SpeciesValue
Soda Lime Borosilicate Glass Dermal LD50 estimated to be > 5,000 mg/kg
Soda Lime Borosilicate Glass Ingestion LD50 estimated to be 2,000 -5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Dermal Rabbit LD50 > 5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Synthetic Amorphous Crystalline-Free Silica IngestionRat LD50 > 5,110 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Serious Eye Damage/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Skin Sensitization
Name SpeciesValue
Synthetic Amorphous Crystalline-Free Silica Human
and
animal
Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
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Soda Lime Borosilicate GlassIn VitroSome positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica In VitroNot mutagenic
Carcinogenicity
Name Route SpeciesValue
Soda Lime Borosilicate Glass InhalationMultiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value SpeciesTest Result Exposure
Duration
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to female reproductionRat NOAEL 509
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to development Rat NOAEL 1,350
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity -single exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity -repeated exposure
Name Route Target Organ(s) Value SpeciesTest Result Exposure
Duration
Soda Lime Borosilicate
Glass
Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational
exposure
Synthetic Amorphous
Crystalline-Free Silica
Inhalationrespiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this materia l and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information onthis material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
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Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in
a permitted industrial waste facility. If no other disposal options are available, waste product may be placed in a landfill
properly designed for industrial waste.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classificationand packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of
applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information
applies only to transportation classification and notthe packaging, labeling, or marking requirements. The original 3M
package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet
applicable regulatory requirements.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -No Immediate Hazard -No Delayed Hazard -No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain
restrictions may apply. Contact the selling division for additional information.
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910 .1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 0 Flammability: 0 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
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emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health:0 Flammability:0 Physical Hazard:0 Personal Protection:X -See PPE section.
Hazardous Material Identification System (HMIS III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratingsare based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS III ratings are to be used with a fully implemented HMIS III
program. HMIS is a registered mark of the American Coatings Association (ACA).
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR P URPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3MUSA SDSs are available at www.3M.com