HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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HenanMinmetalsEastIndustrialCo.,Ltd|MSDSHJSILFUMEDSILICA|Sep.2019
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1.IDENTIFICATIONOFTHESUBSTANCE/PREPARATIONANDTHECOMPANY/UNDERTAKING
Productname
Synonyms
Validity
Application
Company
Telephone
Fax
FumedSilica
SiliconDioxide,SyntheticAmorphousSilica,
(Fumed)AmorphousSilica
HJSIL150,HJSIL200,HJSIL300,HJSIL380
HJSILR110,HJSILR110H,HJSILR272,HJSILR274,HJSILR612,
HJSILR620,HJSILR622,HJSILR6200
Forindustrialuseonly
Rheologycontrol,reinforcement,freeflowagentincoatings,adhesives
andotherapplications
HenanMinmetalsEastIndustrialCo.,Ltd.
RenminRoad,
JiaozuoCity,HenanProvince,
P.R.China454000
+863913565627
+863913565657
2.HAZARDSIDENTIFICATION
Indicationofdanger:
NotahazardoussubstanceorpreparationaccordingtotheGlobalHarmonizedSystem(GHS)
Principleroutesofexposure:
Inhalation,Skincontact,Eyecontact
POTENTIALHEALTHEFFECTS
a.Eyecontact:
Maycausemechanicalirritation.Irritating,butwillnotpermanentlyinjureeyetissue.Lowhazardfor
usualindustrialorcommercialhandling.
b.Skincontact:
Repeatedexposuremaycauseskindrynessorcracking.
c.Inhalation:
Dustmaybeirritatingtorespiratorytract.Provideappropriateexhaustventilationatmachineryandat
placeswheredustcanbegenerated.
HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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d.Ingestion:
Healthinjuriesarenotknownorexpectedundernormaluse.Lowhazardforusualindustrialor
commercialhandling.
e.CarcinogenicEffects:
Doesnotcontainanysubstancesgreaterthan0.1%listedby
IARC(InternationalAgencyforResearchonCancer),
NTP(NationalToxicologyProgram),
OSHA(OccupationalSafetyandHealthAdministration),
ACGIH(AmericanConferenceforGovernmentalIndustrialHygienists),
EU(EuropeanUnion).
f.TargetOrganEffects:
Lungs
g.MedicalConditionsAggravatedbyExposure:
Asthma,Respiratorydisorder
h.PotentialEnvironmentalEffects:
Nospecialenvironmentalprecautionsrequired.
3.COMPOSITION/INFORMATIONONINGREDIENTS
Chemicalname
CASNumber
Content
FumedSilica
112945-52-5,7631-86-9
SiO
2>99.8%
4.FIRSTAIDMEASURES
SkinContact:
Washthoroughlywithsoapandwater.Seekmedicalattentionifredness,swelling,itching,orburning
occurs.
EyeContact:
Flusheyesimmediatelywithlargeamountsofwaterfor15minutes.Seekmedicalattentionif
redness,swelling,itching,burningorvisualdisturbancesoccur.
Inhalation:
Ifcough,shortnessofbreathorotherbreathingproblemsoccur,movetofreshair.Seekmedical
attentionifsymptomspersist.Ifnecessary,restorenormalbreathingthroughstandardfirstaid
measures.
HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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Ingestion:
Donotinducevomiting.Ifconscious,giveseveralglassesofwater.Nevergiveanythingbymouthto
anunconsciousperson.
NotestoPhysician:
Treatsymptomatically.
5.FIRE-FIGHTINGMEASURES
ExtinguishingMedia:
Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding
environment.
SpecialProtectiveEquipmentforFirefighters:
Wearsuitableprotectiveequipment.Intheeventoffire,wearself-containedbreathingapparatus.
SpecificHazards:
Productresistsignitionanddoesnotpromoteflamespread.
HazardousDecompositionand/orCombustionProducts:
None.
RiskofDustExplosion:
Thismaterialisaninorganicdustandwillnotcreatenorsupportconditionsthatwouldresultinadust
explosionorfire.
6.ACCIDENTALRELEASEMEASURES
PersonalPrecautions:
Avoiddustformation.Removeallsourcesofignition.Ensureadequateventilation.Usepersonal
protectiveequipment.
MethodsforCleaningUp:
Cleanuppromptlybyvacuum.Useasuitablevacuumcleaner.Donotcreateadustcloudbyusinga
brushorcompressedair.Pickupandtransfertoproperlylabeledcontainers.
EnvironmentalPrecautions:
Nospecialenvironmentalprecautionsrequired.Localauthoritiesshouldbeadvisedifsignificant
spillagescannotbecontained.
HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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7.HANDLINGANDSTORAGE
Handling:
Avoidcontactwithskinandeyes.Avoiddustformation.Donotbreathedust.Provideappropriate
exhaustventilationatmachineryandatplaceswheredustcanbegenerated.Donotcreateadust
cloudbyusingabrushorcompressedair.Takeprecautionarymeasuresagainststaticdischarge.All
metalpartsofthemixingandprocessingequipmentmustbeearthed/grounded.Ensureallequipment
iselectricallyearthed/groundedbeforebeginningtransferoperations.
Storage:
Keepcontainerstightlyclosedinadry,coolandwell-ventilatedplace.Donotstoretogetherwith
volatilechemicalsastheymaybeadsorbedontoproduct.Keepatambienttemperatures.
8.EXPOSURECONTROLS/PERSONALPROTECTION
ENGINEERINGCONTROLS:
Ensureadequateventilationtomaintainexposuresbelowoccupationallimits.Provideappropriate
exhaustventilationatmachineryandatplaceswheredustcanbegenerated.
PERSONALPROTECTIVEEQUIPMENT/RespiratoryProtection:
Approvedrespiratormaybenecessaryiflocalexhaustventilationisnotadequate.
HandProtection:
Repeatedexposuremaycauseskindrynessorcracking.Useprotectivebarriercreambefore
handlingtheproduct.Wearsuitablegloves.
EyeProtection:
Weareye/faceprotection.Safetyglasseswithside-shields.Goggles.
SkinandBodyProtection:
Wearsuitableprotectiveclothing.Nospecialprotectiveequipmentrequired.
Others:
Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Emergencyeyewashand
safetyshowershouldbelocatednearby.
HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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9.PHYSICALANDCHEMICALPROPERTIES
Appearance
Odor
PH
Density
SpecificGravity
BoilingPoint/Range
MeltingPoint/Range
VaporPressure
WaterSolubility
%Volatile(byVolume)
EvaporationRate
Viscosity
PartitionCoefficient
(n-octanol/water)
FlashPoint
Method
ExplosionLimitsinAir
-Upper(g/m3)
ExplosionLimitsinAir
-Lower(g/m3)
AutoignitionTemperature
Method
Whitepowder
None
3.6-4.5
2.2g/cm @20 C
Notapplicable
2230 C
1700 C
Notdetermined
Insoluble
Notapplicable
Notdetermined
Notdetermined
Notapplicable
Notdetermined
Notapplicable
Notdetermined
Notapplicable
Notdetermined
Notdetermined
HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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10.STABILITYANDREACTIVITY
Stability:
Stable.
HazardousPolymerization:
Hazardouspolymerizationdoesnotoccur.
MechanicalSensitivity(shock):
Notsensitivetomechanicalimpact
ConditionstoAvoid:
Keepawayfromheatandsourcesofignition.Avoiddustformation.Productresistsignitionanddoes
notpromoteflamespread.
HazardousDecompositionand/orCombustionProducts:
None.
StaticDischargeEffects:
Takeprecautionarymeasuresagainststaticdischarges.Avoiddustformation.Allmetalpartsofthe
mixingandprocessingequipmentmustbeearthed/grounded.Ensureallequipmentiselectrically
earthed/groundedbeforebeginningtransferoperations.Thismaterialisaninorganicdustandwillnot
createnorsupportconditionsthatwouldresultinadustexplosionorfire.
11.TOXICOLOGICALINFORMATION
ACUTETOXICITY
OralLD50
InhalationLC50
DermalLD50
EyeIrritation
SkinIrritation
LD50/oral/rat=>5000mg/kg
Duetotheproduct’sphysicalcharacteristics,nosuitabletesting
procedureisavailable.
LD50/dermal/rabbit=>2000mg/kg
Draizescore0.7/110@24hr.Non-irritating
0/8.Non-irritating
SUBCHRONICTOXICITY
Nodataareavailableontheproductitself.
HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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CHRONICTOXICITY
a.CarcinogenicEffects:
Doesnotcontainanysubstancesgreaterthan0.1%listedby
IARC(InternationalAgencyforResearchonCancer),
NTP(NationalToxicologyProgram),
OSHA(OccupationalSafetyandHealthAdministration),
ACGIH(AmericanConferenceforGovernmentalIndustrialHygienists),
EU(EuropeanUnion).
OTHER
MutagenicEffects:
NotmutagenicinAMESTest,unscheduledDNAsynthesis,chromosomalaberrationinChinese
hamsterovary(CHO)cells.
ReproductiveToxicity:
Didnotshowteratogeniceffectsinanimalexperiments.Accordingtoexperiencenotexpected.
SensitizingEffects:
AdelayedcontacthypersensitivitystudyinguineapigsutilizingtheMagnussonandKligman
Maximizationtechniquewasperformed.Nosensitizationresponseswereobserved.
SynergisticMaterials:
Nonereasonablyforeseeable.
12.ECOLOGICALINFORMATION
ACUTETOXICITY
AquaticToxicity
ENVIRONMENTALFATE
Mobility
Bioaccumulation
Persistence/Degradability
DistributiontoEnvironmental
Compartments
Fish(Brachydaniorerio)NOEC(96hours)=10,000mg/l
(Method:OECD203)
DaphniamagnaNOEC(24hours)=10,000mg/l
(Method:OECD202)
Notexpectedtomigrate
Accordingtoexperiencenotexpected
Themethodsfordeterminingbiodegradabilityarenot
applicabletoinorganicsubstances
Notdetermined
HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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13.DISPOSALCONSIDERATIONS
Material
a.Recommendation:
Aftersolidification,materialcanbestoredtogetherwithdomesticwaste.Observelocal/state/federal
regulations.
Uncleanedpackaging
a.Recommendation:
Completelydischargecontainers(noteardrops,nopowderrest,scrapedcarefully).Containersmay
berecycledorre-used.Observelocal/state/federalregulations.
14.TRANSPORTINFORMATION
Notclassifiedasdangerousinthemeaningoftransportregulations:
USDepartmentofTransportation
CanadianTransportofDangerousGoodsRegulation
EuropeanTransportofDangerousGoodsRegulation
GGVS,GGVE,RID,ADR,IMDGCode,ICAO-TI
UnitedNations(noUNnumber)
15.REGULATORYINFORMATION
ThisproducthasbeenclassifiedinaccordancewiththehazardcriteriaoftheControlledProducts
RegulationsandtheMSDScontainsalltheinformationrequiredbytheControlledProducts
Regulations.
InternationalInventories
Allcomponentsofthisproductarelistedonorexemptfromthefollowing
inventories:
YES-AustralianInventoryofChemicalSubstances(AICS)
YES-CanadianDomesticSubstancesList(DSL)
YES-ChineseInventory
YES-EuropeanInventoryofExistingCommercialChemicalSubstances(EINECS)
YES-JapaneseExistingandNewChemicalSubstances(ENCS)
YES-KoreanExistingChemicalsList(KECL)
YES-NewZealandHazardousSubstancesandNewOrganismsAct(HSNO)
YES-PhilippineInventoryofChemicalsandChemicalSubstances(PICCS)
YES-UnitedStatesToxicSubstancesControlAct(TSCA)Inventory
U.S.FederalRegulations
TSCA12(b)ExportNotification:
ThisproductdoesnotcontainanycomponentsthataresubjecttoTSCA12(b)ExportNotification.
HJSIL
MATERIALSAFETYDATASHEET
HJSIL
FUMEDSILICAMSDS
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HenanMinmetalsEastIndustrialCo.,Ltd|MSDSHJSILFUMEDSILICA|Sep.2019
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CleanAirActAmendmentsof1990(CAA,Section112,40CFR82):
ThisproductdoesnotcontainanycomponentslistedasaHazardousAirPollutant,Flammable
Substance,ToxicSubstance,orClass1or2OzoneDepletor.
CleanWaterAct(CWA,40CFR116)PriorityPollutants:
ThisproductdoesnotcontainanylistedPriorityPollutants.
ComprehensiveEnvironmentalResponse,
CompensationandLiabilityAct(CERCLA,40CFR302):
ThisproductdoesnotcontainanylistedHazardousSubstances.
SuperfundAmendmentsandReauthorizationAct,TitleIII(SARA)
a.SARASection302(40CFR355)ExtremelyHazardousSubstances:
NocomponentsarelistedasextremelyhazardouschemicalsunderSARASection302.
b.SARASections311/312(40CFR370)HazardCategory:
ThisproductdoesnotmeetanyoftheMSDSRequirementdefinitionsforahazardousmaterial
underSARASections311/312.Reportingmayberequiredifthematerialispresentatanyonetimein
amountsequaltoorgreaterthan10,000pounds.
c.SARASection313(40CFR372)ToxicsReleaseInventory:
DoesnotcontainanyofthesubstancesidentifiedunderSection313astoxicchemicalsinexcessof
thedeminimisconcentrationsnecessarytobesubjecttothesuppliernotificationrequirements.
FoodandDrugAdministration(FDA):
Notavailable.
CosmeticUse:
Notavailable.
PharmaceuticalInformation:
Notavailable.
U.S.StateRegulations:
a.CaliforniaProposition65:
ThisproductdoesnotcontainanycomponentslistedonCaliforniaProposition65.
ThisproductisnotlistedonCaliforniaProposition65.
b.USCoalitionofNortheasternGovernors(CONEG)MetalsList:
ThisproductmeetstheCONEGSourceReductionCouncillimitsforthesumofthelevelsoflead,
cadmium,mercuryandhexavalentchromiumoflessthan100partspermillionbyweight.
16.OTHERINFORMATION
Material:
Theaboveinformationdescribesexclusivelythesafetyrequirementsoftheproduct(s)andisbasedon
ourpresent-dayknowledge.Itdoesnotrepresentaguaranteeforthepropertiesoftheproduct(s)
describedintermsofthelegalwarrantyregulations.Propertiesoftheproductaretobefoundinthe
respectiveproductleaflet:
RevisionDate:10/SEPTEMBER/2019