Carlisle Polyurethane Systems
Safety Data Sheet
1. Identification of Substance:
Product Name: 4203-4 B
Supplier Identification:
Carlisle Polyurethane Systems
Address:
2500 Adie Rd
Maryland Heights, MO 63043
Telephone:
(314) 872-8700
24-Hr. Emergency Phone Number:
CHEMTREC (800) 424-9300
INTERNATIONAL: +1-(703) 527- 3887
Product Use: Polyurethane polyol component
2. Hazards Identification:
GHS Ratings:
GHS Hazards
GHS Precautions
Signal Word:
There are no GHS ratings that apply to this product at this time.
Acute Toxicity:
Eyes: Minor potential for irritation.
Skin: Minor potential for irritation.
Inhalation: Not expected to be a route of exposure.
Ingestion: Consult physician.
Conditions Aggravated: None known.
Chronic Effects: Not expected to cause any adverse chronic health effects.
3. Composition/Data on Components:
Chemical Name CAS number Weight Concentration %
1,4-Butanediol 110-63-4 1.00% – 5.00%
SDS for: 4203-4 B
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4. First Aid Measures:
Inhalation: Move to fresh air. If breathing is difficult, give oxygen.
After Eye Contact: Rinse opened eye for at least 15 minutes under running water.
Remove contact lenses if present and easy to do so, and continue rinsing.
After Skin Contact: Clean affected area with soap and plenty of water.
After Swallowing: Consult physician.
Notes to Physician: Treat symptomatically
5. Fire Fighting Measures:
Flash Point: 121 C (250 F)
LEL: N/A UEL: N/A
Upper and lower explosive limits listed if known.
Suitable Extinguishing Agents: Water spray, CO2, Foam, Dry chemical
Information about Protection against Explosions and Fires: Closed containers may rupture when
exposed to extreme heat.
Dangerous Products of Decomposition: Oxides of carbon, hydrocarbons.
Protective Equipment: Firefighters should wear a pressure demand self-contained breathing apparatus and
protective clothing.
6. Accidental Release Measures:
Person-Related Safety Precautions: Avoid contact with skin and eyes.
Measures for Environmental Protection: Cover and contain spill with absorbent material. Collect for
proper disposal according to local, state, and federal regulations.
Small Spills: Absorb with earth, sand or other absorbent material and transfer to containers for later disposal.
Wipe up with absorbent material (e g. cloth, fleece) clean surface thoroughly to remove residual
contamination.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.
Use an absorbent material like vermiculite, sand or earth to soak up the product and place Into a container for
later disposal. Following product recovery, flush area with water.
7. Handling and Storage:
Information for Safe Handling: Avoid contact with skin or inhalation.
Storage Requirements: Store in dry, well ventilated area. Keep containers tightly closed. Store between
60 F-100 F. Material may settle.
SDS for: 4203-4 B
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Regulatory Requirements: Store according to all local, state, and federal regulations.
8. Exposure Controls and Personal Protection:
Other Exposure Limits ACGIH Exposure Limits OSHA Exposure Limits Chemical Name / CAS No.
1,4-Butanediol
110-63-4
Not Established Not Established Not Established
Engineering Controls: No specific measures required if proper PPE precautions are followed.
General Protective and Hygienic Measures: Usual precautionary measures should be adhered to when
handling chemicals.
Respiratory Protection: None required if work area is properly ventilated.
Protection of Hands: Protective chemical resistant gloves.
Eye Protection: Safety glasses.
Body Protection: Protective work clothing. Launder separately.
Contaminated Gear: Observe local requirements. Dispose of in accordance with local/state/federal
regulations.
9. Physical and Chemical Properties:
Physical properties listed where known.
Various colored liquid Appearance: Mild Odor:
N/A Vapor Pressure: N/A Odor threshold:
N/A Vapor Density: N/A pH:
1.05 Specific Gravity N/A Melting point:
N/A Freezing point: N/A Solubility:
100 – 235 C Boiling range: 250 F,121 C Flash point:
N/A Evaporation rate: N/A Flammability:
N/A Explosive Limits: N/A Partition coefficient
(n-octanol/water):
385 C Autoignition temperature: N/A Decomposition temperature:
10. Stability and Reactivity:
Incompatible Materials: Avoid contact with isocyanates and strong oxidizing agents.
Hazardous Polymerization: Not expected to occur.
Dangerous Products of Decomposition: Oxides of carbon, hydrocarbons.
11. Toxicological Information:
Mixture Toxicity
Component Toxicity
Toxicity Values Listed if Known
SDS for: 4203-4 B
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Acute Toxicity:
Eyes: Minor potential for irritation.
Skin: Minor potential for irritation.
Inhalation: Not expected to be a route of exposure.
Ingestion: Consult physician.
Chronic Effects: Not expected to cause any adverse chronic health effects.
Routes of Entry: Eye contact, skin contact.
Target Organs: None known.
Chemicals with Known or Possible Carcinogenic Effects:
Carcinogen Rating CAS Number Description % Weight
None None
12. Ecological Information:
General Information: Based on experience, no adverse effects are to be expected if correct disposal
procedures have been followed as indicated in section 13.
Individual component ecotoxicity listed if known.
Component Ecotoxicity
1,4-Butanediol 48 Hr EC50 Daphnia magna: 813 mg/L
72 Hr EC50 Desmodesmus subspicatus: >500 mg/L
13. Disposal Considerations:
Recommendation: Observe local requirements. Dispose of in accordance with local/state/federal regulations.
Empty Container Precautions: Recondition or dispose of empty container in accordance with governmental
regulations. If container is to be disposed, ensure all product residues are removed and container is empty
prior to disposal.
14. Transport Information:
DOT Regulated Components:
This product is not regarded as dangerous goods according to the national and international regulations on the
transport of dangerous goods unless specifically cited below:
Hazard Class Packing Group UN Number Proper Shipping Name Agency
None
15. Regulatory Information:
SDS for: 4203-4 B
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OSHA HAZARD COMMUNICATION STANDARD: This material is not classified as hazardous in accordance
with OSHA 29 CFR 1910.1200.
SARA 311/312 Hazard Categories: None.
WARNING: This product can expose you to chemicals listed below, which are known
to the State of California to cause cancer, birth defects, or reproductive harm. For more
information, visit www.P65Warnings.ca.gov
Styrene 100-42-5 29 PPM CARC
Acrylonitrile 107-13-1 29 PPM CARC
Massachusetts Right To Know List:
– None
New Jersey Right To Know List:
– None
Pennsylvania Right To Know List:
– None
SARA 302 Extremely Hazardous Substances:
– None
Chemicals subject to SARA 313 Reporting:
– None
All Components Listed Regulation Country
Canada Canada DSL Yes
US Toxic Substances Control Act Yes
16. Other Information:
Safety Data Sheet issued by Product Safety Department
This information is furnished without warranty, expressed or implied, except that it is accurate to the best
knowledge of Carlisle Polyurethane Systems. The data on these sheets relates only to the specific material
designated herein. Carlisle Polyurethane Systems assumes no legal responsibility for use or reliance upon
this data. It is the user’s responsibility to ensure that their activities comply with federal, state, or local laws.
Reviewer Revision 0 Date revised: 2020-09-24
Date Prepared: 9/24/2020
SDS for: 4203-4 B
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