SAFETY DATA SHEET
Date Issued : 1/20/2010
MSDS No : F-82 PART A
Date-Revised : 3/4/2013
Revision No : 1
F-82 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-82 PART A
GENERAL USE: Polyurethane resin
CHEMICAL FAMILY: Aromatic diisocyanate, plasticizer mixture
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887
2. HAZARDS IDENTIFICATION
HAZARD DESIGNATION
“Xn” – Harmful
R20: Harmful by inhalation.
R36/37/38: Irritating to eyes, respiratory system and skin.
R40: Limited evidence of a carcinogenic effect.
R42/43: May cause sensitization by inhalation and skin contact.
R48/20: Harmful : danger of serious damage to health by prolonged exposure through inhalation.
GHS CLASSIFICATIONS
Health
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Target Organ Toxicity (Single exposure), Category 3
GHS LABEL
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Exclamation mark
DANGER
H332: Harmful if inhaled.
H315: Causes skin irritation.
H320: Causes eye irritation.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
Health hazard
DANGER
H334: May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
H351: Suspected of causing cancer .
PRECAUTIONARY STATEMENT(S)
General:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P262: Do not get in eyes, on skin, or on clothing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P285: In case of inadequate ventilation wear respiratory protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P315: Get immediate medical advice/attention.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P310: Immediately call a POISON CENTER or doctor/physician.
P304+P341: IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale yellow liquid with a slight musty odor.
IMMEDIATE CONCERNS: Harmful by inhalation. Use in well ventilated areas. Irritating to eyes and respiratory system. May cause
sensitization by inhalation and skin contact. This product is a respiratory irritant and potential respiratory sensitizer: repeated inhalation of
vapour or aerosol at levels above the occupational exposure limit could cause respiratory sensitization. A hyper-reactive response to even
minimal concentrations of diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for
several hours after exposure.
Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures.
Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: May cause irritation, tearing, reddening, and swelling.
SKIN: May cause irritation and possible allergic sensitivity with repeated contact.
INGESTION: May be harmful if swallowed.
INHALATION: Hazardous in case of inhalation (lung irritant, lung sensitizer).
MEDICAL CONDITIONS AGGRAVATED: May cause or aggravate dermatitis and asthma.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS EINECS
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1′-methylenebis[4-
isocyanatobenzene]
20 – 509048-57-1500-028-8
Benzoate Esters 20 – 50ProprietaryProprietary
4,4′-Diphenylmethane diisocyanate 20 – 30101-68-8202-966-0
benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer 5 – 1025686-28-6500-040-3
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F-82 PART A
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Consult a physician.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash
clothing before reuse.
INGESTION: If swallowed, call a physician immediately. DO NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHALATION: Remove patient from exposure, keep warm and at rest. Obtain immediate medical attention. Treatment is symptomatic for
primary irritation or bronchospasm. If breathing is labored, oxygen should be administered by qualified personnel. Apply artificial respiration
if breathing has ceased or shows signs of failing.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
EXPLOSION HAZARDS: Avoid contact with strong oxidizers and strong acids, as sudden reaction may result in fire and toxic fumes. Reacts
slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrous oxide, and HCN.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
RELEASE NOTES: US regulations require reporting spills of this material that could reach any surface waters. The toll free number for the
US Coast Guard National Response Center is (800) 424-8802.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a cool, dry place, away from excessive heat, in original or similar container. Avoid unnecessary contact. Protect from
freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
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F-82 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-
hydroxy-, polymer with 1,1′-methylenebis[4-
isocyanatobenzene]
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Benzoate Esters
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
4,4′-Diphenylmethane diisocyanate
TWA 0.02 0.2 0.005 0.05 0.005
[1]
0.05
[1]
STEL NE NE NE NE NE NE
benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
OSHA TABLE COMMENTS:
1. NIOSH REL
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slightly musty
APPEARANCE: Clear
COLOR: Pale yellow
pH: Not Applicable
PERCENT VOLATILE: 0.07
FLASHPOINT AND METHOD: > 193.3 C (380 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: > 8.5
BOILING POINT: > 300 C (572 F) Decomposes
SOLUBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: 1.14 (water=1) at 25 C (77 F)
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F-82 PART A
VISCOSITY: 850 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 0.800 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: May occur when exposed to heat in the presence of moisture, alkalies, tertiary amines, metal compounds.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrous oxide, and HCN.
INCOMPATIBLE MATERIALS: Avoid contact with any materials containing active hydrogens such as water, alcohol, amines, bases, and
acids.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer
with 1,1'-methylenebis[4-isocyanatobenzene]
Not Established Not Established Not Established
Benzoate Esters Not Established Not Established Not Established
4,4'-Diphenylmethane diisocyanate > 10000 mg/kg > 9400 mg/kg 0.49 mg/l (4 h)
benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer Not Established Not Established Not Established
CARCINOGENICITY
Chemical Name
IARC
Status
4,4′-Diphenylmethane diisocyanate 3
IARC: This product contains substances that are not classifiable as carcinogens to humans.
12. ECOLOGICAL INFORMATION
AQUATIC TOXICITY
96-HOUR LC
50: > 1000 mg/l Zebra Fish
48-HOUR EC
50: > 1000 mg/l Daphnia magna (24 hour)
96-HOUR EC
50: > 100 mg/l E.Coli
Notes: This information is based only on MDI and its derivatives.
CHEMICAL FATE INFORMATION: It is unlikely that significant environmental exposure in the air or water will arise based on
consideration of the production and use of the substance.
GENERAL COMMENTS: Immiscible with water, but will react with water to produce an inert, non-biodegradable solids.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND
NOTE: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
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F-82 PART A
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
4,4′-Diphenylmethane diisocyanate 20 – 30101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
4,4′-Diphenylmethane diisocyanate 20 – 305,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the MSDS comply with the OSHA Hazard Communication Standard 29 CFR
1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
Toxic
Class D-1A: Material causing immediate and serious toxic effects (Very toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D1A – Acute lethality
D2A – Chronic toxicity
D2A – Respiratory tract sensitization
D2B – Skin irritation
D2B – Skin Sensitization
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: The D1A classification applies for this material in aerosol or mist form.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are included on the Domestic Substances List (DSL) or
the Non-Domestic Substances List (NDSL).
EUROPEAN COMMUNITY
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F-82 PART A
EEC LABEL SYMBOL AND CLASSIFICATION
“Xn” – Harmful
RISK PHRASES
R20: Harmful by inhalation.
R36/37/38: Irritating to eyes, respiratory system and skin.
R40: Limited evidence of a carcinogenic effect.
R42/43: May cause sensitization by inhalation and skin contact.
R48/20: Harmful : danger of serious damage to health by prolonged exposure through inhalation.
SAFETY PHRASES
S1/2: Keep locked up and out of reach of children.
S23: Do not breathe fumes/vapour/spray.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: After contact with skin, wash immediately with plenty of water and soap.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S62: If swallowed, do not induce vomiting : seek medical advice immediately and show this container or label.
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 1/20/2010 MSDS. Revised: Section 2: EMERGENCY OVERVIEW – IMMEDIATE
CONCERNS POTENTIAL HEALTH EFFECTS ( INHALATION, ING ESTION ). Section 3: Wt.%. Section 5: HAZARDOUS
COMBUSTION PRODUCTS, HAZARDOUS DECOMPOSITION PRODUC TS. Section 9: BOILING POINT, PERCENT VOLATILE, pH,
VAPOR PRESSURE, VOC (Volatile Organic Compound). Section 13: EMPTY CONTAINER. Section 15: WHMIS (WORKPLACE
HAZARDOUS MATERIALS INFORMATION SYSTEM), WHMIS CLAS S.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
2 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
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F-82 PART A