WB
ENTERPRIS 5
SAFETY DATA SHEET
SP.2O5 PART A
Date Issued : 0611912014
SDS No : SP-205 PART A
Date Revised : 1010612020
Revision No :2
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SP-205 PART A
GENERAL USE: Polyurethane resin
MANT]FACTURER
BJB Enterprises, Inc.
14791 FranklinAvenue
Tustin, CA92780
Emergency Phone: (714) 73+8r’50
24 HR. EMERGENCY TELEPHONE NI.]MBERS
CHEMTREC (USA & Canada): (800) 42,1-9300
or (703) 521-3887 CCN# 2820
2. HAZARDS IDENTIF’ICATION
GHS CT-ASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation , Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category I
Skin Sensitization, Category I
Cmcinogenici ty, Catngory 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS I-ABEL
Healthhazard Exclamation
mark
SIGNAL WORD: DANGER
TIAZARD STATEMENTS
H332: Harmful if inhaled.
H3 15: Causes skin irritation.
H3 19: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms orbreathing difficulties if inhaled.
H3 l7: May cause an allergic skin reaction.
H35l : Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repealed exposure.
PRECAU TI ONARY STATEMET.{TS
Prevention:
P201 : Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood
P260: Do not breathe dust/fu melgas/mist/vapours/spray.
P27l: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
t
I
SP.2O5 PART A
P2l2: Contaminated work clothing should not be allowed out of the workplace.
P2 80 : Wear protectiv e gl oves /protective cl othi ng/eye protecti on/face protecti on.
Response:
P3M+P340: IF INHALED: Remove person to fiesh air and keep comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P3A+P352 IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation orrash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P35 1+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P33’7+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: S tore in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501 : Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
WtVoChemical Name
40-704,4′-Diphenylmethane diisocyanate
10- 30B en zene, 1, l’-meth yl enebi s
[ 4-i so cyan ato -, h o mopol ymer
10- 30
1,2-B enzenedicarboxylic acid, di-C8 – I Gbranched alkyl esters, C9-rich
0.1 -l2,6-di -tert-bu tyl -p -cresol
CAS
101-68-8
25686-28-6
68515-48-0
128-31-0
4. FIRSTAIDMEAST]RES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attenti on.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Getmedical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
IIIIAI-ATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by rained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hows.
5. FIRE FIGHTING MEASI.]RES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQLIIPMENT: Firefighters should wear positive pressure self-contained brea*ring apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURBS : Evacuate unnecessary personnel from the spill area. Wear necess ary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Enswe adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to locaVnational regulations.
SP.2O5 PART A
ENTVIR OIM EN TAL PRECA UTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTLS: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANIDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaVmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contacl
Protect from fieezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80″F (1 8-27’C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. E)POSURE CONTROLS / PERSONAL PROTECTION
SP-205 PART A
EXPOSURE GUIDELINES
osHA HAZARDOUS COMPONENTS (29 CFRl910.1200)
EXPOSURE LIMITS
-dm’
0.2
0.05
0.Zltl
10
Footnotes:
1. l0-minute
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing, Wem nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (MOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910. 134).
Type ppmChemical Name
TWA
STEL
C 0.m
OSHA PEL
TWA 0.005
ACGIH TLV
STEL
TWA 0.005
STELNIOSH REL
c 0.02
trl
4,4′ -Diphenylmeth ane dii socyan ate
TWA
STEL
OSHA PEL
TWA
ACGIH TLV
STEL
TWA
NIOSH REL
STEL
B en zene, 1, l’-meth yl enebi s [4-i so cyan alo -, homop olymer
TWA
OSHA PEL
STH,
TWA
ACGIH TLV
STEL
TWA
NIOSH REL
STEL
1,2-B enzenedi carb oxyl ic acid, di -C8 – I Gbran ched allcyl e sters, C 9 -ri ch
TWA
OSHA PEL
STEL
TWA
ACGIH TLV
STEL
TWA
NIOSH REL
STFI
2,6-di -tert-butyl -p -cresol
SP.2O5 PART A
pROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines forthe Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIEIVC PRACTICES: Conraminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is imporlant. Follow all label precautions.
9. PITYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Yellow
pH: No data available
FLASHPOINT AND METHOD:201.2″C (4O5’F) Pensky-Martens CC
VAPORPRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLIIBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: l.l8 (water=1) at25″C (1’l”F)
USCOSITY #l: 325 Centipoise at 25″C (7 1″ n
(VOC): Nil
10. STABILITY AND REACTIVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing
active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if *re miscibility of the
reaction partners is good or is supported by stining or by the presence of solvents. MDI is insoluble with, and heavier fhan water and sinks to the
bottom but reacts slowly at the interface. A solid water,insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, amines, acids, bases, and strong oxidizing agents.
r T. TOXICOLOGICAL INFORMATION
ACUTE TO)ilCITY
INHALATIONLCsO
2.24m{l Rat (1 h,
dust/mist)
0.49 mg/l Rat
No data available
SKIN CORROSION/IRRITATION: C auses ski n i rrit ation’
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
ORAL LDso DERMAL LDsO
Chemical Name
> 2000 mg/kg Rat > 9400 mg/kg
Rabbit
4,4-Diphenylmethane diisocyanate
> 5000 mg/kg RatNo data available
Benzene, l, 1′-methylenebis[4-isocyanato-, homopolymer
No data availableNo data available
1,2-B enzenedicarb oxylic acid, di -C8 – 1 0-branch ed alkyl esters, C9-
rich
> 2000 mg/kg Rat> 29ffi mg/kgRat2,6-di+ert-bu tyl -p-cresol
No data available
SP-205 PART A
IARC Status
3
3
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: May cause respiratory irritation.
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
Chemical Name
4,4′ -Diphenylmethane dii socyanate
2,6-di -tert-bu tyl -p -cresol
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section I 5 for regulatory reporting information.
BIOACCUMUI-ATION/A CCUMLILATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
I.JNITED STATES
SARA TITLE III (ST]PERFUND AMEI{DMENTS AND REAUTHORIZATION ACT)
3llR72 HEALTH HAZARDS: Refer to Section 2 forhazard classification.
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 3I3 TION
Comments
Diisocyanate Compounds (Category Code Nl20)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name WLVo CAS
40-10101-68-84,4′-Diphenylmethane diisocyanate
Wt.VoChemical Name
40-704,4′ -Di phenyl methane dii socyan ate
CERCLA RQ
5,0001bs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGTILATORY: This product does not contain any substances subject toTSCA Section 12(b) export notification
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCT]PATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA)
SP-205 PART A
29 CFRr91O.T 19-.-PROCFSS SAFBTY MANAGEMENT OF HIGHI,Y HAZARDOUS CHBMICALS: NONC OI’thC ChCINiCAIS iN t]TiS
product are considered highly haz;rrdous by OSHA.
CALIF’OIfNIA PROPOSITION 65: A WARNING: This product cm expose yon to chemicals including Isee table belowl, wlrich is farel
known to tlte State of California to cause cancer. For nrorc infomration, go to www.P65Wa|llilrgs.ca.gov.
V,,/t.Vo
Chemical Name
r0- 30
1,2-B enzenedicarboxyl ic acid, di -C8 – I 0-brancl.red alkyl esters, C9-rich
Listed
o Carcer
OSHA HAZARD COMM. RULE: The contenls of the SDS comply with tlre OSHA Hazud Communication Standard 29 CFR 1910.1200′
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIAIf INFORMATION SYSTEM): This product hm been classified according to the
hazard criteria of the CPR and the SDS contains all the infonnation required by the CPR.
DOMFSTIC SUBSTANCE LIST (INVENTORY): All components in this product ale listed in or exempted from the Domestic Substances
List (DSL) ol the Non-Domestic Sttbstances List (NDSL).
GENERAL COMMENTS:
DINP RESTRJCTIONS: This product contains diisononyl phthalate (DINP), CAS# 68515-48-0 EINECS# 271-090-9.In the U.S., there is an
interim prohibition on DINP above 0.1 percent by weight (one thousand par ts per rnillion) in toys intended fol children age 12 and under that can
be placed in a child’s rnouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvemnet Act of 2008]. In
the EU, DINP shall not be used as substance oras consti.tuents of preparations, at concentrations of greater than 0.1 percent by weight (one
thonsand parts per million) of the plasticized material, in toys and childcare articles which can be place in the mouth by children. Such toys and
childcare articles containing DINP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
200st84tECl.
16. OfiIER INFORMATION
REASON FOR ISSUE: Revision
Date Revised : 1 0/ 0612020
RtrVISION SUMMARY: This SDS replaces theA9l1112017 SDS.
HMIS RATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is fumished withotrt warl”nty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises,Inc. The dataon this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
xPERSONAL PROTECTION
HEALTH
F’I,AMMABILTlY
EA
E
BTB
ENTERPRISES
SAFETY DATA SHEET
SP-205 PART B
Date Issued : 06119/2014
SDS No: SP-205 PART B
Date Revised t 10106/2020
Revision No :2
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SP-205 PARTB
GENERAL US E: P olyureth ane curative
MANT]FACTURER
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA92780
Emergency Phone: (1 14) 73+8450
24 HR. EMERGENCY TELEPHONE I{T]MBERS
CHEMTREC (USA & Canada): (800) 42,1-9300
or (703) 527-3881 CCN# 2820
2. IIAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation , Category 2
Eye kritation, Category 2A
Skin Sensitization, Category 1
Target Organ Toxicity @epeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS I-ABEL
Healthhazard Exclamation Environment
mark
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H3 15: Causes skin irritation.
H3 19: Causes serious eye initation.
H3 17: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.
H41l: Toxic to aquatic life with long lasting effects.
PRECAUTI ONARY STATEM ENITS
Prevention:
P260: Do not breathe dust/fu me/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin initation orrash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P35 1+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
t
a
SP.2O5 PART B
P337+P313: If eye irritation persists: Get medical advice/attention.
P3 14: Get medical advice/anention if you feel unwell.
P39l : Collect spillage.
Disposal:
P50l: Dispose of contents/containerin arcordance with local/regional/national/international regulations
3. COMPOSITION / INFORMATION ON INGREDIEITS
Wt.9o
Chemical Name
60 – 100
Polyether polyol mixture
1-136-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine;2-methyl-4,6-bis(methylthio) phenylene-1,3-diamine
7 -13
1,2-B enzenedicarboxylic acid, di-C9 – I 1 -branched alkyl esters, C I 0-rich
0.5 – 1.5
Diethyl methylbenzenedi amine
0.1 -1
Titanium dioxide (Ti02)
< 0.1Carbon black
CAS
Proprietary
106264-19-3
68515-49-l
68479-98-r
13463-61:7
1333-864
4. FIRSTAIDMEASI.]RES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contract lenses and continue flushing for at least 15 minutes '
Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INIIALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops'
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEAST]RES
EXTINGTIISHING MEDIA: Water spray, carbon dioxide, dry chemical, orfoam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consideruse of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPLL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean wittr a liquid decontaminant. Remove and propoly
dispose of residues. Notify applicable govemment authorities if release is reportable. (See CERCLA in Section 15).
ET{VIR ONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater'
GEIERAL PROCEDLIRES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. IIAIIDLING AIID STORAGE
SP-205 PART B
GEIERAL PROCEDURES: Avoid contact witlr eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid opencontainerexposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaVmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away liom excessive heat, in original or similar container. Avoid unnecessary contacl
Protect from freezing. Containers should be tighfly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80"F (1 8-27'C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. E)OOSURE CONTROLS / PERSONAL PROTECTION
osHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
mdm3Type ppm
Chemical Name
TWA
sTEL
OSIIA PBL
TWA
sTEL
ACGtrI TLV
TWA
STEL
NIOSH REL
Polyether polyol mixture
TWA
STEL
OSHA PEL
TWA
ACGIII TLV
sTEL
TWA
IYIOSHREL
STEL
6-Methyl-2,4.bis(methylthio)phenylene-1,3-diamine; 2-mahyl-4,6-bis(methylthio) phenylene-1,3-
diamine
TWA
OSHA PEL
STEL
TWA
ACGIII TLV
STEL
TWA
IIOSHREL
STEL
7,Z-Beruendicarboxylic acid, di-C9-l l-branched alkyl esters, C 10-rich
TWA
OSHA PEL
STEL
TWA
ACGIH TLV
STFI
TWA
IIIOSH REL
STEL
Di ethyl methylbenzen edi amin e
_ tllTWA
OSHA PEL
STEL
15 trl
SP.2O5 PART B
STEL
TWA
NIOSH REL
STEL
TWA
OSHA PEL
STEL
TWA
ACGIH TLV
STEL
TWA
NIOSH REL
STEL
Carbon black
TWA r0
Titanium dioxide OiO2)
ACGIH TLV
3.5
3.5
3.5
tr'ootnotes:
1. Total dust
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below
recommended exposure limits.
PERSONA L PROTECTIVE EQU IPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor carffidge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910. 134).
PROTECTM CLOTHING: Protecrive clothing should be selected and used in accordance with "Guidelines forthe Selection of Chemical
Protective Clothing" published by ACGIH.
WORK IfYGIEMC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEIVIICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Gray
pH: No data available
PERCENT VOLATILE: 0.01
FLASH POINT AND METHOD: > 182.2’C (360’F) Pensky-Martens CC
VAPORPRESSURE: No data available
VAPORDF ISITY: No data available
BOILING POINT: No data available
SOLLIBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.052 (water=1) at25″C (77’D
VISCOSITY #1: 1000 Crntipoise at25″C (77’D
(VOC): < 1.052gll Calculated. Theoretical VOC minus water and exempt solvents'
10. STABILITY AND REACTIYITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions
SP-205 PART B
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
1 1. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
INHALATION
LCm
No data available
No data available
> 0.13 mg/l Rat
No data available
> 6.82 mg/l Rat (4
h)
No data available
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye initation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
ORAL LDso DERMAL LD5OChemical Name
No data
available
No data
available
Polyether polyol mixture
> 2000 mg/kg
Rabbit
1515 mg/kg
Rat
6-Methyl-2,i-,bis(methylthio)phenylene-1,3-diamine; Z-methyl-4,6-bis(methylthio)
phenylene-1,3-diamine
> 3.16 glkg
Rabbit
> l0 g/kg Rat
1,2-B enzenedicarboxylic acid, di -C9- I I -branched alkyl esters, C I O-rich
> 500 mg/kg
Rat
> 2000 mg/kg Rat
Di eth yl mettr ylbenzen ed i ami n e
> 10000 mg/kg
Rat
No data
available
Titanium dioxide (Ii02)
> 8000 mg/kg
Rat
No data
available
Carbon black
IARC Status
28
29
REPRODUCTM TO)ilCITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: May cause damage to organs *rrough prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
Chemical Name
Titanium dioxide Gi02)
Carbon black
12. ECOLOGICAL INFORMATION
EIYVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTO)ilCOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid
release to the environment.
B IOA CC LIMU I-A TION/A CCUMIJLATION: No d ata available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
SP-205 PART B
waste disposal contl’acior. Disposal ol’this product. solutions and any by-products should atall times comply with the lequirenrents ol’
nrnofT and contact with soil. waterways, dlains ancl sewel.s.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITEDSTATES
SARA TITLE III (SUPERFUND AMENDMBNTS AND REAUTHORJ ZATION A CT)
3lll3l2 HEALTH HAZARDS: Acute Hetrlth Hizard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporling requirements of Section 313 o1
Title III of the Superfund Amendn.rents and Reauthorization Act of 1986 ancl 40 CFR Pan 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION,ANDLIABILITY ACT)
CERCLA REGULATORY: This product does not contain any substances rcgulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCI-A) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains Diethylmethylbenzenediamine (CAS No.68479-98-1) which is subject toTSCA 12(b)
export notification (40 CFR part 707, subpart D).
TSCA STATUS: This product ot’its components are listed in ol’exempt fiom the TSCA inventory rcquirements.
OCCT]PATIONA L SAFETY AND HEA LTH A DMINISTRATION (OSHA
)
29 CFR1910.1I9—PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: A WARNfNG: This product can expose you to chemicals including fsee table below], which is [are]
known to the State of California to cause cancer and birth defects or other reproductive harm. For more information, go to
ww w.P65 Warni ngs.ca.gov.
Chemical Name Wt.Vo
1 ,2-Benzenedicarboxylic acid, di-C9-1 l-branched alkyl esters, C l0-rich ‘1 -13
Titanium dioxide (TiO2)
0.1 -1
Carbon black < 0.1
Listed
o Developmental Toxiciry
o Cancer
o Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Srandard 29 CFR 1910. 1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIAIf INFORMATION SYSTEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIoNS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4.In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand par ts per million) in toys intended for childlen age l2 and under that can
be placed in a child's lnouth and child care articles for children age 3 and under IH.R. 4M0, The Consumer Safety Improvement Act of 2008]. In
the EU, DIDP shall not be used as substance or as constituents of prcparations, at concentrations of greater than 0.1 percent by weight (one
thousand pafis per million) of the plasticized material, in toys and child care articles which can be place in the rnouth by children. Such toys and
child care articles containing DIDP in concentrations g eater than the limit mentioned above shall not be placed on the market [Directive
2W5/84tECl.
16. OTHER INFORMATION
SP.2O5 PART B
REASON FOR ISSLIE: Revision
Date Revised t I 0l 06/2020
REVISION SUMMARY: This SDS replaces theC9111D017 SDS.
RATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This infonnation is fumished without wananty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on dris sheet lelates only to the specific material designated herein. BJB Enterprises, lnc. assulrles
no legal responsibility for use or reliance upon this data.
PERSONAL PROTECTION
HEAL'fH
FLAMMAI}ILITY