SAFETY DATA SHEET
Date Issued : 08/05/2010
SDS No : TC-89 PRIMER PART A
Date Revised : 04/06/2021
Revision No : 3
TC-89 PRIMER PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-89 PRIMER PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
Page 1 of 6
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polymeric diphenylmethane diisocyanate 30 – 609016-87-9
4,4′-Diphenylmethane diisocyanate 30 – 60101-68-8
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
Page 2 of 6
TC-89 PRIMER PART A
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
Polymeric diphenylmethane diisocyanate
ACGIH TLV TWA 0.005
NIOSH REL
TWA 0.005 0.05
C 0.02 0.2
OSHA PEL C 0.02 0.2
4,4′-Diphenylmethane diisocyanate
OSHA PEL C 0.02 0.2
ACGIH TLV TWA 0.005 –
NIOSH REL
TWA 0.005 0.05
C 0.02
[1]
0.2
[1]
Footnotes:
1. 10-minute
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Page 3 of 6
TC-89 PRIMER PART A
PHYSICAL STATE: Liquid
ODOR: Slightly musty
COLOR: Brown
pH: No data available
FLASH POINT AND METHOD: 160 C (320 F) Closed Cup
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts with water
SPECIFIC GRAVITY: 1.23 (water=1) at 25 C (77 F)
VISCOSITY #1: 250 Centipoise at 25 C (77 F)
(VOC): Nil
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing
active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the
reaction partners is good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than water and sinks to the
bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, amines, acids, bases, and metals.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Polymeric diphenylmethane diisocyanate > 10000 mg/kg Rat > 9400 mg/kg Rabbit 490 mg/m3 Rat (4 h)
4,4′-Diphenylmethane diisocyanate > 2000 mg/kg Rat > 9400 mg/kg Rabbit 2.24 mg/l Rat (1 h, dust/mist)
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name IARC Status
Polymeric diphenylmethane diisocyanate 3
4,4′-Diphenylmethane diisocyanate 3
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: May cause respiratory irritation.
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
CHEMICAL FATE INFORMATION: No data available
Page 4 of 6
TC-89 PRIMER PART A
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: No data available
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
Polymeric diphenylmethane diisocyanate 30 – 609016-87-9Diisocyanate Compounds (Category Code N120)
4,4′-Diphenylmethane diisocyanate 30 – 60101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
4,4′-Diphenylmethane diisocyanate 30 – 60 5,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product does not contain any chemicals which are known to the State of California to cause cancer,
birth defects or other reproductive harm.
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
Page 5 of 6
TC-89 PRIMER PART A
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 04/06/2021
REVISION SUMMARY: This SDS replaces the 03/08/2018 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 6 of 6
TC-89 PRIMER PART A
SAFETY DATA SHEET
Date Issued : 08/05/2010
SDS No : TC-89 PRIMER PART B
Date Revised : 04/06/2021
Revision No : 4
TC-89 PRIMER PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-89 PRIMER PART B
GENERAL USE: Polyurethane primer
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 4
Eye Irritation, Category 2A
Physical:
Flammable Liquids, Category 2
GHS LABEL
Flame Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H225: Highly flammable liquid and vapour.
H302: Harmful if swallowed.
H319: Causes serious eye irritation.
PRECAUTIONARY STATEMENTS
Prevention:
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P240: Ground and bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting/material-handling equipment.
P242: Use non-sparking tools.
P243: Take action to prevent static discharges.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P370+P378: In case of fire: Use water spray, carbon dioxide, dry chemical, or foam for extinction.
P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell.
P330: Rinse mouth.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
Page 1 of 6
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
Storage:
P403+P235: Store in a well-ventilated place. Keep cool.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Methyl propyl ketone 60 – 100107-87-9
Methyl isobutyl ketone 5 – 10 108-10-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
GENERAL HAZARD: Flammable liquid and vapor.
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
EXPLOSION HAZARDS: Vapors may cause a flash fire or ignite explosively. Vapors may travel along the ground and reach remote ignition
sources causing a flashback fire danger.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
SENSITIVE TO STATIC DISCHARGE: This material can accumulate static charges which can cause an incendiary electrical discharge.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Eliminate sources of ignition. Evacuate the area. Clean-up should only be performed by trained personnel.
People dealing with a major spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from
entering sewers or waterways. Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Do not use combustible
materials such as saw dust. Use only spark resistant and explosion proof recovery devices. Shovel into open-top drums or plastic bags for further
decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of residues. Notify
applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
Page 2 of 6
TC-89 PRIMER PART B
GENERAL PROCEDURES: Keep away from sources of ignition. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation.
Avoid breathing vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes, skin, and clothing.
Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat in the original or similar container. Avoid sources of ignition and
incompatible materials. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Avoid
unnecessary contact.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
ELECTROSTATIC ACCUMULATION HAZARD: This material can accumulate static charges which can cause an incendiary electrical
discharge. Use proper bonding and/or grounding procedures.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
Methyl propyl ketone
OSHA PEL
TWA 200 700
STEL – –
ACGIH TLV
TWA 150 530
STEL – –
NIOSH REL TWA 150 530
Supplier OEL STEL – –
Methyl isobutyl ketone
OSHA PEL
TWA 100 410
STEL – –
ACGIH TLV
TWA 20 –
STEL 75 –
NIOSH REL
TWA 50 205
STEL 75 300
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
Page 3 of 6
TC-89 PRIMER PART B
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Ketone
COLOR: Colorless
pH: No data available
PERCENT VOLATILE: 100
FLASH POINT AND METHOD: 7.8 C (46 F) TAG CC
LOWER EXPLOSION LIMIT: 1.56%(V)
UPPER EXPLOSION LIMIT: 8.7%(V)
AUTOIGNITION TEMPERATURE: 450 C (842 F)
VAPOR PRESSURE: 27.8 mmHg at 20 C (68 F)
VAPOR DENSITY: 2.9 (Air=1)
BOILING POINT: 101 C (213.8 F)
SOLUBILITY IN WATER: Moderately soluble
EVAPORATION RATE: 2.3
SPECIFIC GRAVITY: 0.81 (water=1) at 20 C (68 F)
VISCOSITY #1: 0.61 mPa.s at 20 C (68 F)
(VOC): 610 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.
POSSIBILITY OF HAZARDOUS REACTIONS: May form peroxides of unknown stability.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Methyl propyl ketone 1600 mg/kg Rat > 20 ml/kg Guinea Pig 25.5 mg/l Rat (4 h)
Methyl isobutyl ketone 2080 mg/kg Rat > 10 ml/kg Rabbit 2000 to 4000 ppm Rat (4 h)
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name IARC Status
Methyl isobutyl ketone 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
Page 4 of 6
TC-89 PRIMER PART B
regarding accidental release and Section 15 for regulatory reporting information.
CHEMICAL FATE INFORMATION: No data available
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: No data available
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
EMPTY CONTAINER: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper
instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. T HEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Ketones, liquid, n.o.s.
TECHNICAL NAME: (methyl propyl ketone, methyl isobutyl ketone)
PRIMARY HAZARD CLASS/DIVISION: 3
UN/NA NUMBER: UN1224
PACKING GROUP: II
NAERG: 127
LABEL: Flammable liquid
ROAD AND RAIL (ADR/RID)
UN NUMBER: UN1224
AIR (ICAO/IATA)
SHIPPING NAME: Ketones, liquid, n.o.s.
TECHNICAL NAME: (methyl propyl ketone, methyl isobutyl ketone)
UN/NA NUMBER: UN1224
PRIMARY HAZARD CLASS/DIVISION: 3
PACKING GROUP: II
ERG: 3L
LABEL: Flammable liquid
VESSEL (IMO/IMDG)
SHIPPING NAME: Ketones, liquid, n.o.s.
TECHNICAL NAME: (methyl propyl ketone, methyl isobutyl ketone)
UN/NA NUMBER: UN1224
PRIMARY HAZARD CLASS/DIVISION: 3
PACKING GROUP: II
EmS: F-E, S-D
LABEL: Flammable liquid
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazard, Fire Hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
Page 5 of 6
TC-89 PRIMER PART B
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS
Methyl isobutyl ketone 5 – 10108-10-1
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Methyl isobutyl ketone 5 – 10 5,000
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
Methyl isobutyl ketone 5 – 10 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 04/06/2021
REVISION SUMMARY: This SDS replaces the 03/08/2018 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
3
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
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TC-89 PRIMER PART B