Vinyl Ester Resin
Product name
Product type
Section 1. Identification
Chemical family Aromatic.
Relevant identified uses of the substance or mixture and uses advised against
SDS No. XNA-1804:1446 (Version: 2.1)
Uses advised against
Identified uses Used in the manufacture of thermoset plastic parts.
No additional information.
XR-4995
SAFETY DATA SHEET
Date of issue: 09/20/2018
Date of previous issue: 08/15/2018
Emergency telephone number
Supplier’s details
CHEMTREC Within USA and Canada
CHEMTREC Outside USA and Canada
CANUTEC Within Canada
+1 (800) 424-9300
+1 (703) 527-3887
+1 (613) 996-6666
CCN1023
AOC, LLC
955 Highway 57 East
Collierville, TN 38017
Phone Number: (901) 854-2800
Hours: 8AM-5pm (Central Time) Mon-Fri
AOC, LLC
38 Royal Road
Guelpha, Ontario Canada N1H 1G3
Phone Number: (519) 821-5180
Hours: 8am-5pm (Eastern) Mon-Fri
E-Mail: aoc.sds@aoc-resins.com
Website: www.aoc-resins.com
United States: Canada:
Section 2. Hazards identification
OSHA/HCS status
SKIN CORROSION/IRRITATION Category 2 H315
SERIOUS EYE DAMAGE/ EYE IRRITATION Category 2 H319
SENSITIZATION (Skin) Category 1 H317
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory system) Category 3 H335
Classification of the substance or mixture
Signal word
Warning
Hazard statements
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
Hazard pictograms
Precautionary statements
Prevention
P261: Do not breathe vapor or mist.
P270: Do not eat, drink or smoke when using this product.
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
GHS label elements
General
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Section 2. Hazards identification
Response
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation occurs, get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists, get medical advice/attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P391: Collect spillage.
Storage
P403 + P235: Store in a well-ventilated place. Keep cool.
P233: Keep container tightly closed.
P405: Store locked up.
Disposal
P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
None known.
Section 3. Composition/information on ingredients
Ingredient name CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture.
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate 42978-66-5 25 – 50
phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide 162881-26-7 0.3
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Seek immediate medical attention.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby
shampoo will aid in removal. If irritation persists, get medical attention.
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists, seek
medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse.
Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give oxygen.
If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Eye contact
Skin contact
Inhalation
Ingestion
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Irritating to mouth, throat and stomach.
Causes serious eye irritation.
May cause allergic skin reactions with repeated exposure.
May cause respiratory irritation.
Eye contact
Skin contact
Inhalation
Ingestion
Over-exposure signs/symptoms
Eye contact
Adverse symptoms may include the following: pain or irritation, watering, redness.
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Section 4. First aid measures
Notes to physician
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: irritation, redness.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach..
Section 5. Fire-fighting measures
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
No specific data.
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment
if released in large quantities.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor.
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or walk
through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation.
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See also the information in
“For non-emergency personnel”.
Small spill
Large spill
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Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating
areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all
ignition sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. Refer to the product label and/or technical data sheet for further information.
Protective measures
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not ingest. Avoid contact
with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks,
open flame or any other ignition source. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Precautions for safe handling
None.
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists or dusts.
Eye/face protection
Respiratory protection
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Appropriate engineering controls
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or
dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Hygiene measures
Control parameters
Individual protection measures
Occupational exposure limits
Other skin protection
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.
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Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.038 (Water = 1)
Not established.
Not available.
Negligible.
AcrylateOdor
pH
Yellow.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
>201 F / >94 C
Not available.
Not applicable.
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-octanol/water
Appearance
Boiling point Not applicable.
Flammability (solid, gas) Not applicable.
Lower and upper explosive (flammable)
limits
Not available.
Molecular weight Not available.
Decomposition temperature Not available.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable. Stable under recommended storage and handling conditions (see Section 7).
Chemical stability
Reactive or incompatible with the following materials: oxidizing materials
Incompatible materials
Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
(1-methyl-1,2-ethanediyl)bis[oxy
(methyl-2,1-ethanediyl)] diacrylate
LD50 Oral Rat 6200 mg/kg –
phenyl bis(2,4,6-trimethylbenzoyl)-
phosphine oxide
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat >2000 mg/kg –
Ingredient name Result Species Dose Exposure
Carcinogenicity
Irritation/Corrosion
(1-methyl-1,2-ethanediyl)bis[oxy
(methyl-2,1-ethanediyl)] diacrylate
Eyes – Severe irritant Rabbit – 24 hours 100
microliters
–
Skin – Moderate irritant Rabbit – 500 milligrams-
Ingredient name Result Score Exposure Observation
Sensitization
Species
Information on toxicological effects
May cause sensitization by skin contact.
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Section 11. Toxicological information
Mutagenicity
Teratogenicity
Reproductive toxicity
Inhalation
May cause respiratory irritation.
Irritating to mouth, throat and stomach.
Ingestion
Skin contact
May cause allergic skin reactions with repeated exposure.
Causes serious eye irritation.
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Adverse symptoms may include the following: respiratory tract irritation, coughing.
Adverse symptoms may include the following: Irritating to mouth, throat and stomach..
Adverse symptoms may include the following: irritation, redness.
Eye contact
Adverse symptoms may include the following: pain or irritation, watering, redness.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Potential acute health effects
Classification
None of the components are listed.
Ingredient name NTPIARCACGIH
No mutagenic effect.
Not considered to be toxic to the reproductive system.
No known effect according to our database.
No known effect according to our database.
No known effect according to our database.
No known effect according to our database.
Inhalation
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
(1-methyl-1,2-ethanediyl)bis[oxy
(methyl-2,1-ethanediyl)] diacrylate
2 46.83 low
phenyl bis(2,4,6-trimethylbenzoyl)-
phosphine oxide
5.77 <5 low
Toxicity
(1-methyl-1,2-ethanediyl)bis[oxy
(methyl-2,1-ethanediyl)] diacrylate
EC50 3.68 mg/l Algae 96 hours
LC50 35.96 mg/l Daphnia 48 hours
LC50 4.9 mg/l Fish 96 hours
Ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
Not available.
Mobility in soil
Not available.
Ingredient name
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Section 12. Ecological information
Other adverse effects
No known effect according to our database.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local
authority requirements. Avoid disposal. Attempt to use product completely in accordance with intended use. Waste packaging should be
recycled. Incineration or landfill should only be considered when recycling is not feasible.
Disposal methods
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any
available use-specific information provided in the Exposure Scenario(s).
Special precautions
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues. Do not cut, weld or grind used containers unless they
have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Section 14. Transport information
Environmentally hazardous substance, liquid, n.o.s.(Tri(propylene glycol) diacrylate)
9
III
UN3082UN number
Proper shipping name
Transport hazard class(es)
Packing group
DOT / TDG/ IMDG/IMO / ICAO/IATA and National regulations.
Additional information US regulations require the reporting of spills when the amount exceeds the Reportable
Quantity (RQ) for specific components of this material. See CERCLA in Section 15,
Regulatory Information, for the Reportable Quantities.
Environmental hazards Marine pollutant: Yes.
Special precautions for user Transport within user s premises: always transport in closed containers that are upright and
secure. Ensure that persons transporting the product know what to do in the event of an
accident or spillage.
IMDGNo additional information.
IATANo additional information.
Section 15. Regulatory information
International regulations lists
All components are listed or exempted.
SARA 311/312
United States inventory (TSCA 8b)
Australia (AICS) Not determined.
Canada (DSL) All components are listed or exempted.
China (IECSC) Not determined.
Europe (EINECS) Not determined.
Japan Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea (KECI) Not determined.
Malaysia (EHS Register) Not determined.
New Zealand (NZIoC) Not determined.
Philippines (PICCS) Not determined.
Taiwan (CSNN) Not determined.
U.S. Federal regulations
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Section 15. Regulatory information
SARA 313
Ingredient name
None.
Form R - Reporting
requirements
CAS number
California Prop. 65
State regulations
None.CERCLA RQ -
Not available.
Per the June 13, 2016 Federal Register notice, EPA harmonized the EPCRA 311/312 hazard categories with the 2012 OSHA hazard
communication standard for classifying and labeling of chemicals (i.e. GHS). Please refer to Section 2 of the SDS to identify the appropriate
hazard categories for reporting purposes.
Section 16. Other information
History
Version
Prepared by
The information contained in this data sheet is furnished in good faith and without warranty, representation, or inducement or license of any kind,
except that it is accurate to the best of AOC, LLC's knowledge, or was obtained from sources believed by AOC, LLC to be reliable. The accuracy,
adequacy or completeness of health and safety precautions set forth herein cannot be guaranteed, and the buyer is solely responsible for
ensuring that the product is used, handled, stored, and disposed of safely and in compliance with applicable federal, state or provincial, and local
laws. AOC, LLC disclaims liability for any loss, damage or personal injury that arises from, or is in any way related to, use of the information
contained in this data sheet.
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by
the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
09/20/2018
08/15/2018
2.1
National Fire Protection Association (U.S.A.)
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This
reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and
reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether
the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
AOC Corporate Regulatory Affairs
This Safety Data Sheet (SDS) and its content are the confidential and proprietary information of AOC and it may not be modified, altered,
deconstructed, or presented in any other manner, without the explicit authorization of AOC and/or its legal counsel.
2
1
2
Health
Special
Instability
Flammability
Date of issue
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