3M Perfect-It Gelcoat Heavy Cutting Compound, 36101, 36102, 36103
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Safety Data Sheet
2020, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written
agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention
of earning a profit thereon.
Document group:34-3827-2 Version number:2.00Issue Date:26/07/2020Supersedes date:11/05/2016
This Safety Data Sheet has been prepared in accordance with the New Zealand, Hazardous Substances (Safety Data Sheets)
Notice 2017.
SECTION 1: Identification
1.1. Product identifier
3M Perfect-It Gelcoat Heavy Cutting Compound, 36101, 36102, 36103
Product Identification Numbers
60-4550-8600-3
60-4550-8601-1
60-4550-8602-9
1.2. Recommended use and restrictions on use
Recommended use
Gel Coat, Marine
For Industrial or Professional use only
1.3. Supplier s details
Address:3M New Zealand Ltd, 94 Apollo Drive, Rosedale 0632, AucklandTelephone:(09) 477 4040E Mail:innovation@nz.mmm.comWebsite:3m.co.nz
1.4. Emergency telephone number
24 hr Medical Emergency, National Poisons Centre, 0800 764 766 (0800 POISON)
SECTION 2: Hazard identification
Classified as hazardous in accordance with the relevant criteria of the HSNO Act 1996, the Hazardous Substances
(Classification) Notice 2017 and Hazardous Substances (Minimum Degrees of Hazard) Notice 2017.
Refer to Section 14 of this Safety Data Sheet for product Dangerous Goods Classification.
2.1. Classification of the substance or mixture
GHSHSNOChronic Aquatic Toxicity: Category 39.1C Aquatic toxicity (chronic)
2.2. Label elements
SIGNAL WORD
3M Perfect-It Gelcoat Heavy Cutting Compound, 36101, 36102, 36103
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Not applicable.
Symbols:
Not applicable.
HAZARD STATEMENTS:
H412Harmful to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Disposal:
P501Dispose of contents/container in accordance with applicable
local/regional/national/international regulations.
2.3. Other hazards
Repeated exposure may cause skin dryness or cracking.
SECTION 3: Composition/information on ingredients
IngredientCAS Nbr% by WeightWater7732-18-5 20 – 60Polyethylene Glycol Sorbitan Monooleate9005-65-6 3 – 7White Mineral Oil (Petroleum)8042-47-5 3 – 7Polyethylene-Polypropylene Glycol9003-11-6 1 – 5Glycerin56-81-5 < 2
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
No need for first aid is anticipated.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist,
get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Use a fire fighting agent suitable for the surrounding fire.
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5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance ConditionCarbon monoxide.During combustion.Carbon dioxide.During combustion.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
5.4. Hazchem code: Not applicable.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic
absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not
remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed
container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a
qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and
Safety Data Sheet. Seal the container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.
SECTION 7: Handling and storage
Refer to Section 15 - Controls for more information
7.1. Precautions for safe handling
Avoid eye contact. Keep out of reach of children. Do not eat, drink or smoke when using this product. Wash thoroughly
after handling. Avoid release to the environment.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
7.3. Certified handler
Not required
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientCAS NbrAgencyLimit typeAdditional comments
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Glycerin56-81-5New Zealand
WES
TWA(as mist)(8 hours):10
mg/m3
Mineral oils, highly-refined oils8042-47-5ACGIHTWA(inhalable fraction):5
mg/m3
A4: Not class. as human
carcinogin
Paraffin oil8042-47-5New Zealand
WES
TWA(as mist)(8 hours):5
mg/m3;STEL(as mist)(15
minutes):10 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
New Zealand WES : New Zealand Workplace Exposure Standards.
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
ppm: parts per million
mg/m : milligrams per cubic metre
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
No engineering controls required.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.
Refer AS/NZS 1336 - Recommended practices for occupational eye protection and for performance specifications AS/NZS
1337, Parts 1 - 6 - Personal eye-protection.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
Respiratory protection
None required.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical stateLiquid. Specific Physical Form: GelColourWhiteOdourSlight SolventOdour thresholdNo data available.pH7.5 - 9Melting point/Freezing pointNo data available.Boiling point/Initial boiling point/Boiling rangeNo data available.Flash pointNo flash point
3M Perfect-It Gelcoat Heavy Cutting Compound, 36101, 36102, 36103
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Evaporation rateNo data available.Flammability (solid, gas)Not applicable.Flammable Limits(LEL)No data available.Flammable Limits(UEL)No data available.Vapour pressureNo data available.Vapor Density and/or Relative Vapor DensityNo data available.Density1.1 - 1.1 kg/lRelative density1.05 - 1.1 [Ref Std:WATER=1]Water solubilityNo data available.Solubility- non-waterNo data available.Partition coefficient: n-octanol/waterNo data available.Autoignition temperatureNo data available.Decomposition temperatureNo data available.Viscosity/Kinematic Viscosity30,000 - 40,000 mPa-s [Test Method:Brookfield]Volatile organic compounds (VOC)14.5 % weight [Test Method: calculated per CARB title 2]Percent volatile60.3 % weightVOC less H2O & exempt solvents323 g/l [Test Method:calculated SCAQMD rule 443.1]Average particle sizeNo data available.Bulk densityNo data available.Molecular weightNo data available.Softening pointNo data available.
Nanoparticles
This material does not contain nanoparticles.
* The values noted with an asterisk (*) in the above table are representative values based on testing of raw materials and selected products.
Additionally, a material's characteristics may change depending upon the process and conditions of use at a facility, including further
changes in particle size, or mixture with other materials. In order to obtain specific data for the material, we recommend the user conduct
characterization testing based on the use factors at the specific facility.
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
None known.
No data available.
10.6 Hazardous decomposition products
SubstanceCondition None known.
Refer to Section 5.2 for hazardous decomposition products during combustion.
3M Perfect-It Gelcoat Heavy Cutting Compound, 36101, 36102, 36103
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SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
No known health effects.
Skin contact
Dermal Defatting: Signs/symptoms may include localised redness, itching, drying and cracking of skin.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValueOverall productIngestionNo data available; calculated ATE >5,000 mg/kgPolyethylene-Polypropylene GlycolDermalProfessio
nal
judgeme
nt
LD50 estimated to be > 5,000 mg/kgPolyethylene-Polypropylene GlycolIngestionRatLD50 5,700 mg/kgPolyethylene Glycol Sorbitan MonooleateDermalNot
available
LD50 > 5,000 mg/kgPolyethylene Glycol Sorbitan MonooleateInhalation-
Dust/Mist
(4 hours)
RatLC50 > 5.1 mg/lPolyethylene Glycol Sorbitan MonooleateIngestionRatLD50 20,000 mg/kgWhite Mineral Oil (Petroleum)DermalRabbitLD50 > 2,000 mg/kgWhite Mineral Oil (Petroleum)IngestionRatLD50 > 5,000 mg/kgGlycerinDermalRabbitLD50 estimated to be > 5,000 mg/kgGlycerinIngestionRatLD50 > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValuePolyethylene Glycol Sorbitan MonooleateRabbitNo significant irritationWhite Mineral Oil (Petroleum)RabbitNo significant irritationGlycerinRabbitNo significant irritation
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Serious Eye Damage/Irritation
NameSpeciesValuePolyethylene Glycol Sorbitan MonooleateRabbitNo significant irritationWhite Mineral Oil (Petroleum)RabbitMild irritantGlycerinRabbitNo significant irritation
Sensitisation:
Skin Sensitisation
NameSpeciesValuePolyethylene Glycol Sorbitan MonooleateGuinea
pig
Not classifiedWhite Mineral Oil (Petroleum)Guinea
pig
Not classifiedGlycerinGuinea
pig
Not classified
Respiratory Sensitisation
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
NameRouteValuePolyethylene Glycol Sorbitan MonooleateIn VitroNot mutagenicWhite Mineral Oil (Petroleum)In VitroNot mutagenic
Carcinogenicity
NameRouteSpeciesValuePolyethylene Glycol Sorbitan MonooleateIngestionRatSome positive data exist, but the data are not
sufficient for classification
White Mineral Oil (Petroleum)DermalMouseNot carcinogenicWhite Mineral Oil (Petroleum)InhalationMultiple
animal
species
Not carcinogenicGlycerinIngestionMouseSome positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
NameRouteValueSpeciesTest result Exposure
Duration
Polyethylene Glycol Sorbitan MonooleateIngestionNot classified for female reproductionRatNOAEL
6,666
mg/kg/day
3 generationPolyethylene Glycol Sorbitan MonooleateIngestionNot classified for male reproductionRatNOAEL
6,666
mg/kg/day
3 generationPolyethylene Glycol Sorbitan MonooleateIngestionNot classified for developmentRatNOAEL
5,000
mg/kg/day
during
organogenesis
White Mineral Oil (Petroleum)IngestionNot classified for female reproductionRatNOAEL
4,350
mg/kg/day
13 weeksWhite Mineral Oil (Petroleum)IngestionNot classified for male reproductionRatNOAEL
4,350
mg/kg/day
13 weeksWhite Mineral Oil (Petroleum)IngestionNot classified for developmentRatNOAEL
4,350
during
gestation
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mg/kg/dayGlycerinIngestionNot classified for female reproductionRatNOAEL
2,000
mg/kg/day
2 generationGlycerinIngestionNot classified for male reproductionRatNOAEL
2,000
mg/kg/day
2 generationGlycerinIngestionNot classified for developmentRatNOAEL
2,000
mg/kg/day
2 generation
Target Organ(s)
Specific Target Organ Toxicity – single exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget Organ(s)ValueSpeciesTest result Exposure
Duration
Polyethylene Glycol
Sorbitan Monooleate
Ingestionheart | endocrine
system |
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
nervous system |
kidney and/or
bladder | respiratory
system
Not classifiedRatNOAEL
4,132
mg/kg/day
90 daysWhite Mineral Oil
(Petroleum)
Ingestionhematopoietic
system
Not classifiedRatNOAEL
1,381
mg/kg/day
90 daysWhite Mineral Oil
(Petroleum)
Ingestionliver | immune
system
Not classifiedRatNOAEL
1,336
mg/kg/day
90 daysGlycerinInhalationrespiratory system |
heart | liver | kidney
and/or bladder
Not classifiedRatNOAEL 3.91
mg/l
14 daysGlycerinIngestionendocrine system |
hematopoietic
system | liver |
kidney and/or
bladder
Not classifiedRatNOAEL
10,000
mg/kg/day
2 years
Aspiration Hazard
NameValueWhite Mineral Oil (Petroleum)Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. Additional information leading to material classification in
Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be
reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not
expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
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Ecotoxic to the aquatic environment.
Chronic Aquatic Toxicity: Category 3 (HSNO 9.1C Aquatic toxicity)
No product test data available.
MaterialCAS NumberOrganismTypeExposureTest endpointTest resultPolyethylene
Glycol Sorbitan
Monooleate
9005-65-6CopepodsEstimated48 hoursLethal Level
50%
>10,000 mg/lPolyethylene
Glycol Sorbitan
Monooleate
9005-65-6Green AlgaeEstimated72 hoursEffect Level
50%
58.84 mg/lPolyethylene
Glycol Sorbitan
Monooleate
9005-65-6Zebra FishEstimated96 hoursLC50>100 mg/lPolyethylene
Glycol Sorbitan
Monooleate
9005-65-6Green AlgaeEstimated72 hoursEffect
Concentration
10%
19.05 mg/lPolyethylene
Glycol Sorbitan
Monooleate
9005-65-6Water fleaEstimated21 daysNo obs Effect
Level
10 mg/lWhite Mineral
Oil (Petroleum)
8042-47-5Water fleaEstimated48 hoursEffect Level
50%
>100 mg/lWhite Mineral
Oil (Petroleum)
8042-47-5BluegillExperimental96 hoursLethal Level
50%
>100 mg/lWhite Mineral
Oil (Petroleum)
8042-47-5Green algaeEstimated72 hoursNo obs Effect
Level
>100 mg/lWhite Mineral
Oil (Petroleum)
8042-47-5Water fleaEstimated21 daysNo obs Effect
Level
>100 mg/lPolyethylene-
Polypropylene
Glycol
9003-11-6Data not
available or
insufficient for
classification
Glycerin56-81-5Rainbow troutExperimental96 hoursLC5054,000 mg/lGlycerin56-81-5Water fleaExperimental48 hoursLC501,955 mg/l
12.2. Persistence and degradability
MaterialCAS NumberTest typeDurationStudy TypeTest resultProtocolPolyethylene
Glycol Sorbitan
Monooleate
9005-65-6Experimental
Biodegradation
28 daysCO2 evolution61 % weightOther methodsWhite Mineral
Oil (Petroleum)
8042-47-5Experimental
Biodegradation
28 daysCO2 evolution0 % weightOECD 301B – Modified
sturm or CO2
Polyethylene-
Polypropylene
Glycol
9003-11-6 Data not
availbl-
insufficient
N/A Glycerin56-81-5Experimental
Biodegradation
14 daysBOD63 %
BOD/ThBOD
OECD 301C – MITI
test (I)
12.3 : Bioaccumulative potential
MaterialCAS NumberTest typeDurationStudy TypeTest resultProtocolPolyethylene 9005-65-6 Data not N/AN/AN/AN/A
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Glycol Sorbitan
Monooleate
available or
insufficient for
classification
White Mineral
Oil (Petroleum)
8042-47-5 Data not
available or
insufficient for
classification
N/AN/AN/AN/APolyethylene-
Polypropylene
Glycol
9003-11-6 Data not
available or
insufficient for
classification
N/AN/AN/AN/AGlycerin56-81-5Experimental
Bioconcentrati
on
Log Kow-1.76 Other methods
12.4. Mobility in soil
Please contact manufacturer for more details
12.5 Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1. Disposal methods
In accordance with the Hazardous Substances (Disposal) Notice 2017 and the relevant criteria of the HSNO Act 1996.
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.
Packaging (that may or may not contain any residual substance) may be lawfully disposed of by householders or other
consumers through public or commercial waste collection services.
SECTION 14: Transport Information
New Zealand Land Transport Rule: Dangerous Goods – Road/Rail Transport
UN No.: Not applicable.
Proper Shipping Name: Not applicable.
Class/Division: Not applicable.
Sub Risk: Not applicable.
Packing Group: Not applicable.
Hazchem Code: Not applicable.
IERG: Not applicable.
International Air Transport Association (IATA) – Air Transport
UN No.: Not applicable.
Proper Shipping Name: Not applicable.
Class/Division: Not applicable.
Sub Risk: Not applicable.
Packing Group: Not applicable.
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International Maritime Dangerous Goods Code (IMDG) – Marine Transport
UN No.: Not applicable.
Proper Shipping Name: Not applicable.
Class/Division: Not applicable.
Sub Risk: Not applicable.
Packing Group: Not applicable.
Marine Pollutant: Not applicable.
SECTION 15: Regulatory information
HSNO Approval numberHSR002670Group standard nameSurface Coatings and Colourants (Subsidiary Hazard) Group Standard 2017HSNO Hazard classificationRefer to Section 2: Hazard identification
NZ Inventory of Chemicals (NZIoC) Status
All applicable chemical ingredients in this material are in compliance with NZIoC listing requirements.
Controls in accordance with the Health and Safety at Work (Hazardous Substances) Regulations 2017
Certified handlerNot requiredLocation Compliance CertificateNot requiredHazardous atmosphere zoneNot requiredFire extinguishersNot requiredEmergency response plan1,000 L or 1,000 kg (for a HSNO 6.1D, 6.5A, 6.5B, 9.1B or 9.1C substance);
or 10,000 L or 10,000 kg (for a HSNO 6.6A, 6.8A, 6.9A, 8.3A, 9.1D
substance)
Secondary containment1,000 L or 1,000 kg (for a HSNO 6.1D, 6.5A, 6.5B, 9.1B or 9.1C substance);
or 10,000 L or 10,000 kg (for a HSNO 6.6A, 6.8A, 6.9A, 8.3A, 9.1D
substance)
TrackingNot requiredWarning signage1,000 L or 1,000 kg (for a HSNO 8.3A, 9.1B or 9.1C substance); or 10,000 L
or 10,000 kg (for a HSNO 6.1D or 9.1D substance)
SECTION 16: Other information
Revision information:
Complete document review.
Document group:34-3827-2Version number:2.00Issue Date:26/07/2020Supersedes date:11/05/2016
Key to abbreviations and acronyms
GHS means the Globally Harmonised System of Classification and Labelling of Chemicals, 5th revised edition 2013
HSNO means Hazardous Substances and New Organisms Act 1996
The information in this Safety Data Sheet (SDS) is believed to be correct as of the date of issue. TO THE EXTENT
PERMITTED BY LAW, 3M MAKES NO WARRANTY, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED
TO, ANY IMPLIED WARRANTY, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR
COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit
for a particular purpose and suitable for user’s method of use or application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within the user’s knowledge and control, it is essential that the
user evaluates the 3M product to determine whether it is fit for a particular purpose and suitable for user’s method of use or
application. 3M provides information in electronic form as a service to customers. Due to the remote possibility of electronic
transfer may have resulted in errors, omissions or alterations in this information; 3M makes no representations as to its
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completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from 3M.
3M New Zealand SDS are available at 3M New Zealand Website: http://solutions.3mnz.co.nz