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1 Identification
Product identifier
Trade name: RTWB-50NC
Application of the substance / the mixtureRelease agent
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Axel Plastics Research Laboratories, Inc.
PO Box 770855, 58-20 Broadway
Woodside, NY 11377-0855 USA
info@axelplastics.com
Information department:Product safety department
Emergency telephone number:
USA and Canada: 1-800-424-9300 (24 hours)
Outside of USA and Canada: 001-703-527-3887 (24 hours)
2 Hazard(s) identification
Classification of the substance or mixture
d~
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
d~
GHS08 Health hazard
Muta. 1B H340 May cause genetic defects.
Carc. 1B H350 May cause cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
d~
GHS07
Acute Tox. 4 H312 Harmful in contact with skin.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Label elements
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
d~
GHS02
d~
GHS07
d~
GHS08
Signal wordDanger
Hazard-determining components of labeling:
Proprietary/Alternative Chemical Name Pending
xylene
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toluene
Solvent naphtha (petroleum), light arom.
Hazard statements
Highly flammable liquid and vapor.
Harmful in contact with skin or if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause genetic defects.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
Wear protective gloves / protective clothing.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
IF exposed or concerned: Get medical advice/attention.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Do NOT induce vomiting.
In case of fire: Use for extinction: CO2, powder or water spray.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
3
0
Health = 2
Fire = 3
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*2
3
0
Health = *2
Fire = 3
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
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41.2.20
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
1330-20-7 xylene 10-<25%
108-88-3 toluene 10-<25%
64742-89-8 Solvent naphtha (petroleum), light aliph. 10-<25%
Proprietary/Alternative Chemical Name Pending 10-<25 %
64742-95-6 Solvent naphtha (petroleum), light arom. 2.5-<10%
67-64-1 acetone 2.5-<10%
95-63-6 1,2,4-trimethylbenzene 2.5-<10%
98-82-8 cumene 0.1- 2.5%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents:Water with full jet
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:Mouth respiratory protective device.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
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Ensure adequate ventilation
Environmental precautions:Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
Handling:
Precautions for safe handling
Store in cool, dry place in tightly closed receptacles.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Specific end use(s)No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
1330-20-7 xylene
PEL Long-term value: 435 mg/m , 100 ppm
REL Short-term value: 655 mg/m , 150 ppm
Long-term value: 435 mg/m , 100 ppm
TLV Short-term value: 651 mg/m , 150 ppm
Long-term value: 434 mg/m , 100 ppm
BEI
108-88-3 toluene
PEL Long-term value: 200 ppm
Ceiling limit value: 300; 500* ppm
*10-min peak per 8-hr shift
REL Short-term value: 560 mg/m , 150 ppm
Long-term value: 375 mg/m , 100 ppm
TLV Long-term value: 75 mg/m , 20 ppm
BEI
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67-64-1 acetone
PEL Long-term value: 2400 mg/m , 1000 ppm
REL Long-term value: 590 mg/m , 250 ppm
TLV Short-term value: 1187 mg/m , 500 ppm
Long-term value: 594 mg/m , 250 ppm
BEI
95-63-6 1,2,4-trimethylbenzene
REL Long-term value: 125 mg/m , 25 ppm
TLV Long-term value: 123 mg/m , 25 ppm
Ingredients with biological limit values:
1330-20-7 xylene
BEI 1.5 g/g creatinine
Medium: urine
Time: end of shift
Parameter: Methylhippuric acids
108-88-3 toluene
BEI 0.02 mg/L
Medium: blood
Time: prior to last shift of workweek
Parameter: Toluene
0.03 mg/L
Medium: urine
Time: end of shift
Parameter: Toluene
0.3 mg/g creatinine
Medium: urine
Time: end of shift
Parameter: o-Cresol with hydrolysis (background)
67-64-1 acetone
BEI 50 mg/L
Medium: urine
Time: end of shift
Parameter: Acetone (nonspecific)
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use respiratory protective device that is independent of circulating air.
Protection of hands:
_S
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
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41.2.20
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
_R
Tightly sealed goggles
Body protection:Protective work clothing
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Fluid
Color: Amber colored
Odor: Aliphatic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:38 - 60 C
Flash point: < 23 C (< 73 F)
Flammability (solid, gaseous):Not applicable.
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure at 20 C (68 F):29 hPa (22 mm Hg)
Density: Not determined.
Relative density 0.790
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
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41.2.20
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solids content: 8.0 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stabilityThe product is stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:No dangerous decomposition products known.
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
1330-20-7 xylene
Oral LD50 4300 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
64742-89-8 Solvent naphtha (petroleum), light aliph.
Oral LD50 >200 mg/kg (Rat)
Dermal LD50 >200 mg/kg (Rat)
Inhalative LC50/4 h >7700 ppm (Rat)
Proprietary/Alternative Chemical Name Pending
Oral LD50 5000 mg/kg (Rat)
Dermal LD50 2000 mg/kg (rabbit)
Inhalative LC50 5.2 mg/l (Rat)
64742-95-6 Solvent naphtha (petroleum), light arom.
Oral LD50 >6800 mg/kg (rat)
Dermal LD50 >3400 mg/kg (rab)
Inhalative LC50/4 h >10.2 mg/l (rat)
95-63-6 1,2,4-trimethylbenzene
Oral LD50 5000 mg/kg (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
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41.2.20
Harmful
Irritant
The product can cause inheritable damage.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1330-20-7 xylene 3
108-88-3 toluene 3
98-82-8 cumene 2B
NTP (National Toxicology Program)
98-82-8 cumene R
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT, IMDG, IATA UN1866
UN proper shipping name
DOT, IATA Resin solution
IMDG RESIN SOLUTION
Transport hazard class(es)
DOT, IMDG, IATA
Class 3 Flammable liquids
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Packing group
IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
EMS Number: F-E,S-E
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: UN 1866 RESIN SOLUTION, 3, II
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
1330-20-7 xylene
108-88-3 toluene
95-63-6 1,2,4-trimethylbenzene
98-82-8 cumene
TSCA (Toxic Substances Control Act) (Substances not listed):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
98-82-8 cumene
Chemicals known to cause reproductive toxicity for females:
108-88-3 toluene
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
108-88-3 toluene
New Jersey Right-to-Know List:
1330-20-7 xylene
108-88-3 toluene
67-64-1 acetone
95-63-6 1,2,4-trimethylbenzene
98-82-8 cumene
New Jersey Special Hazardous Substance List:
1330-20-7 xylene F3
108-88-3 toluene TE, F3
67-64-1 acetone F3
98-82-8 cumene F3, R1
Pennsylvania Right-to-Know List:
1330-20-7 xylene
108-88-3 toluene
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41.2.20
67-64-1 acetone
95-63-6 1,2,4-trimethylbenzene
98-82-8 cumene
Pennsylvania Special Hazardous Substance List:
1330-20-7 xylene E
108-88-3 toluene E
67-64-1 acetone E
95-63-6 1,2,4-trimethylbenzene E
98-82-8 cumene E
US State Regulations
Connecticut – Hazardous Air Pollutants – HLVs (30 min)
None of the ingredients is listed.
Connecticut – Hazardous Air Pollutants – HLVs (8 hr)
None of the ingredients is listed.
Idaho – Non-Carcinogenic Toxic Air Pollutants – Emission Levels (ELs)
None of the ingredients is listed.
Idaho – Non-Carcinogenic Toxic Air Pollutants – Acceptable Ambient Concentrations
None of the ingredients is listed.
Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Michigan – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
Michigan – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Minnesota – Hazardous Substance List
None of the ingredients is listed.
Minnesota – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Minnesota – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
New Hampshire – Regulated Toxic Air Pollutants – Ambient Air Levels (AALs) – 24-Hour
None of the ingredients is listed.
New Hampshire – Regulated Toxic Air Pollutants – Ambient Air Levels (AALs) – Annual
None of the ingredients is listed.
New York – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
New York – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
North Dakota – Air Pollutants – Guideline Concentrations – 1-Hour
None of the ingredients is listed.
North Dakota – Air Pollutants – Guideline Concentrations – 8-Hour
None of the ingredients is listed.
Oregon – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
Tennessee – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
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Tennessee – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Texas – Effects Screening Levels – Long Term
None of the ingredients is listed.
Texas – Effects Screening Levels – Short Term
None of the ingredients is listed.
Vermont – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Vermont – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
Washington – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Washington – Permissible Exposure Limits – STELs
None of the ingredients is listed.
Washington – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 25 Feet to Less
Than 40 Feet
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 40 Feet to Less
Than 75 Feet
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 75 Feet or
Greater
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights Less Than 25
Feet
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
1330-20-7 xylene I
108-88-3 toluene II
67-64-1 acetone I
98-82-8 cumene D, CBD
TLV (Threshold Limit Value established by ACGIH)
1330-20-7 xylene A4
108-88-3 toluene A4
67-64-1 acetone A4
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
d~
GHS02
d~
GHS07
d~
GHS08
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Signal wordDanger
Hazard-determining components of labeling:
Proprietary/Alternative Chemical Name Pending
xylene
toluene
Solvent naphtha (petroleum), light arom.
Hazard statements
Highly flammable liquid and vapor.
Harmful in contact with skin or if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause genetic defects.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
Wear protective gloves / protective clothing.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see on this label).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
IF exposed or concerned: Get medical advice/attention.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Do NOT induce vomiting.
In case of fire: Use for extinction: CO2, powder or water spray.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:The components of this product are listed on the USA (TSCA) inventory.
Additional classification according to Decree on Hazardous Materials:
Carcinogenic hazardous material group III (dangerous).
Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
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41.2.20
16 Other information
Disclaimer: This data is offered in good faith as typical values and not as a product specification. No
warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe
handling procedures are believed to be generally applicable. However, each user should review
recommendations in the specific context of the intended use and determine whether they are appropriate.
Contact:info@axelplastics.com
Date of preparation / last revision11/17/2015 / –
Abbreviations and acronyms:
ADR: Accord europ en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
Muta. 1B: Germ cell mutagenicity, Hazard Category 1B
Carc. 1B: Carcinogenicity, Hazard Category 1B
Repr. 2: Reproductive toxicity, Hazard Category 2
STOT SE 3: Specific target organ toxicity – Single exposure, Hazard Category 3
STOT RE 2: Specific target organ toxicity – Repeated exposure, Hazard Category 2
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
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