3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632 08/03/23
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Safety Data Sheet
Copyright,2023, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:24-8735-3Version Number:6.03Issue Date:08/03/23Supercedes Date:03/10/23
Product identifier
3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632
ID Number(s):
41-0003-6598-5, 41-0003-6676-9, 41-0003-6712-2, 41-0003-6733-8, 41-0003-6789-0, 60-4550-4436-6, 60-4550-4793-0, 60-4550-
5371-4, 60-4550-5544-6, 60-4550-5548-7, 60-4550-6546-0, 60-4550-8115-2, 60-4550-8621-9, 70-0080-0095-5, 70-0080-0096-3
7000001498, 7010314197, 7000119981, 7000120072, 7100142876
Recommended use
Automotive, Auto Body Repair
Supplier’s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:
29-5993-0, 24-8206-5
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user’s method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user’s knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
3M Platinum Plus , PN 0032, 01130, 01131, 01132, 01135B, 31181, 31139, 31632 08/03/23
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In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M.
3M USA SDSs are available at www.3M.com
3M Cream Hardener (Red, White & Blue) 02/24/22
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Safety Data Sheet
Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:29-5993-0Version Number:6.00Issue Date:02/24/22Supercedes Date:12/07/21
SECTION 1: Identification
1.1. Product identifier
3M Cream Hardener (Red, White & Blue)
Product Identification Numbers
LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0, LB-K100-0966-1, LB-K100-0966-2, LB-K100-
0966-3, LB-K100-1035-6, LB-K100-1045-4, LB-K100-1286-7, 41-0003-6674-4, 41-0003-6682-7, 41-0003-6685-0, 41-0003-
6686-8, 41-0003-6687-6, 41-0003-7901-0, 41-0003-7903-6, 41-0003-7904-4, 41-0003-7922-6, 41-0003-7928-3, 41-0003-
7930-9, 41-0003-7931-7, 41-0003-7932-5, 41-0003-7933-3, 41-0003-7935-8, 41-0003-7987-9, 41-0003-8059-6, 41-0003-
8072-9, 41-0003-8073-7, 41-0003-8074-5, 41-0003-8146-1, 60-4550-6617-9, 60-4550-6830-8, 60-4550-6981-9, 60-4550-
6982-7, 60-4550-8123-6, 60-4551-0388-1
7000120090, 7010327931, 7000120133, 7100191003
1.2. Recommended use and restrictions on use
Recommended use
Automotive, hardener for body fillers & glazes
1.3. Supplier s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Organic Peroxide: Type E.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1B.
Specific Target Organ Toxicity (single exposure): Category 1.
2.2. Label elements
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Signal word
Danger
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Heating may cause a fire. Causes serious eye irritation. May cause an allergic skin reaction. Causes damage to organs: cardiovascular system | nervous system | kidney/urinary tract | respiratory system |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep away from clothing and other combustible materials. Keep only in original container. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label).
Storage:
Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Store locked up. Store away from other materials.
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Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician:
This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV)
administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the
medical management.
SECTION 3: Composition/information on ingredients
IngredientC.A.S. No.% by WtBenzoyl Peroxide94-36-0 30 – 60 Trade Secret *Benzoic Acid, C9-11-Branched Alkyl Esters131298-44-7 10 – 30 Trade Secret *Water7732-18-5 10 – 30 Trade Secret *Calcium Sulfate7778-18-9 1 – 10 Trade Secret *Zinc Stearate557-05-1 1 – 10 Trade Secret *Ethylene Glycol107-21-1<= 7.5 Trade Secret *Iron Oxide (FE2O3)1309-37-1<= 5 Trade Secret *Oxirane, Polymer with Methyloxirane, Monobutyl Ether9038-95-3<= 5 Trade Secret *Ferric Ammonium Ferrocyanide25869-00-5<= 1 Trade Secret *Ferric Ferrocyanide14038-43-8<= 1 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Allergic skin reaction (redness, swelling, blistering, and itching). Target organ effects. See Section 11 for additional details.
4.3. Indication of any immediate medical attention and special treatment required
This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV) administration with
either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management.
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
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Closed containers exposed to heat from fire may build pressure and explode. Part of the oxygen for combustion is supplied
by the peroxide itself.
5.3. Special protective actions for fire-fighters
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No
smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces,
provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning!
A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to
other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for
transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as
possible in accordance with applicable local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on
clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing
before reuse.
7.2. Conditions for safe storage including any incompatibilities
Keep container tightly closed. Protect from sunlight. Store away from heat. Store at temperatures not exceeding
32C/90F. Keep cool. Keep only in original container. Store away from other materials. Keep/store away from clothing
and other combustible materials.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.AgencyLimit typeAdditional CommentsEthylene Glycol107-21-1ACGIHTWA(Vapor fraction):25
ppm;STEL(Vapor fraction):50
ppm;STEL(Inhalable
aerosol):10 mg/m3
A4: Not class. as human
carcin
Iron Oxide (FE2O3)1309-37-1ACGIHTWA(respirable fraction):5
mg/m3
A4: Not class. as human
carcin
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Iron Oxide (FE2O3)1309-37-1OSHATWA(as fume):10 mg/m3CYANIDES14038-43-8OSHATWA(as CN):5 mg/m3SKINZinc Stearate557-05-1OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Calcium Sulfate7778-18-9ACGIHTWA(inhalable fraction):10
mg/m3
Calcium Sulfate7778-18-9OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Benzoyl Peroxide94-36-0ACGIHTWA:5 mg/m3A4: Not class. as human
carcin
Benzoyl Peroxide94-36-0OSHATWA:5 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. Use general dilution
ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Solid
Red
Specific Physical Form: PasteOdorSlight EsterOdor thresholdNo Data AvailablepHNo Data AvailableMelting pointNo Data AvailableBoiling PointNo Data AvailableFlash Point111 C [ Test Method:Estimated]Evaporation rateNo Data AvailableFlammability (solid, gas)Organic Peroxide: Type E.Flammable Limits(LEL)Not ApplicableFlammable Limits(UEL)Not ApplicableVapor PressureNot ApplicableVapor DensityNot ApplicableDensity1.2 g/cm3Specific Gravity1.2 [@ 25 C] [Ref Std:WATER=1]Solubility in WaterNegligibleSolubility- non-waterNo Data AvailablePartition coefficient: n-octanol/ waterNo Data AvailableAutoignition temperatureNo Data AvailableDecomposition temperatureNo Data AvailableViscosityNo Data AvailableHazardous Air Pollutants0 - 0.1209 lb HAPS/lb solids [Test Method:Calculated]Molecular weightNot ApplicableVolatile Organic Compounds0 - 90 g/l [ Test Method:calculated SCAQMD rule 443.1]Volatile Organic Compounds0 % weight [Test Method: calculated per CARB title 2]Percent volatile21 - 28.5 %VOC Less H2O & Exempt Solvents0 - 121 g/l [ Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable. Stable unless exposed to heat, flames and drying conditions.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat
10.5. Incompatible materials
Accelerators
10.6. Hazardous decomposition products
SubstanceCondition Carbon monoxide Not Specified
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Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
May be harmful in contact with skin.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia), changes in heart rate, damage to heart
muscle, heart attack, and may be fatal.
Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or
numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart
rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain,
increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValue
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Overall productDermalNo data available; calculated ATE >2,000 – 5,000
mg/kg
Overall productInhalation-
Dust/Mist(4
hr)
No data available; calculated ATE >12.5 mg/lOverall productIngestionNo data available; calculated ATE >5,000 mg/kgBenzoyl PeroxideDermalLD50 estimated to be 2,000 – 5,000 mg/kgBenzoyl PeroxideInhalation-
Dust/Mist
(4 hours)
RatLC50 > 24.3 mg/lBenzoyl PeroxideIngestionRatLD50 > 5,000 mg/kgBenzoic Acid, C9-11-Branched Alkyl EstersDermalRabbitLD50 > 2,000 mg/kgBenzoic Acid, C9-11-Branched Alkyl EstersInhalation-
Dust/Mist
(4 hours)
RatLC50 > 5 mg/lBenzoic Acid, C9-11-Branched Alkyl EstersIngestionRatLD50 > 5,000 mg/kgCalcium SulfateDermalProfessio
nal
judgeme
nt
LD50 estimated to be > 5,000 mg/kgCalcium SulfateIngestionRatLD50 > 5,000 mg/kgZinc StearateDermalRabbitLD50 > 2,000 mg/kgZinc StearateInhalation-
Dust/Mist
(4 hours)
RatLC50 > 50 mg/lZinc StearateIngestionRatLD50 > 5,000 mg/kgEthylene GlycolIngestionHumanLD50 1,600 mg/kgEthylene GlycolInhalation-
Dust/Mist
(4 hours)
OtherLC50 estimated to be 5 – 12.5 mg/lEthylene GlycolDermalRabbit 9,530 mg/kgIron Oxide (FE2O3)DermalNot
available
LD50 3,100 mg/kgIron Oxide (FE2O3)IngestionNot
available
LD50 3,700 mg/kgOxirane, Polymer with Methyloxirane, Monobutyl EtherDermalRabbitLD50 > 16,960 mg/kgOxirane, Polymer with Methyloxirane, Monobutyl EtherInhalation-
Dust/Mist
(4 hours)
RatLC50 > 5 mg/lOxirane, Polymer with Methyloxirane, Monobutyl EtherIngestionRatLD50 4,240 mg/kgFerric Ammonium FerrocyanideDermalLD50 estimated to be > 5,000 mg/kgFerric FerrocyanideDermalLD50 estimated to be > 5,000 mg/kgFerric Ammonium FerrocyanideIngestionRatLD50 > 5,110 mg/kgFerric FerrocyanideIngestionRatLD50 > 8,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValueBenzoyl PeroxideRabbitMinimal irritationZinc StearateRabbitNo significant irritationEthylene GlycolRabbitMinimal irritationIron Oxide (FE2O3)RabbitNo significant irritationOxirane, Polymer with Methyloxirane, Monobutyl EtherRabbitMinimal irritation
Serious Eye Damage/Irritation
NameSpeciesValueBenzoyl PeroxideRabbitSevere irritantZinc StearateRabbitNo significant irritationEthylene GlycolRabbitMild irritantIron Oxide (FE2O3)RabbitNo significant irritationOxirane, Polymer with Methyloxirane, Monobutyl EtherRabbitNo significant irritation
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Skin Sensitization
NameSpeciesValueBenzoyl PeroxideGuinea
pig
SensitizingEthylene GlycolHumanNot classifiedIron Oxide (FE2O3)HumanNot classified
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
NameRouteValueBenzoyl PeroxideIn VitroNot mutagenicBenzoyl PeroxideIn vivoNot mutagenicEthylene GlycolIn VitroNot mutagenicEthylene GlycolIn vivoNot mutagenicIron Oxide (FE2O3)In VitroNot mutagenic
Carcinogenicity
NameRouteSpeciesValueBenzoyl PeroxideIngestionMultiple
animal
species
Not carcinogenicBenzoyl PeroxideDermalMouseSome positive data exist, but the data are not
sufficient for classification
Ethylene GlycolIngestionMultiple
animal
species
Not carcinogenicIron Oxide (FE2O3)InhalationHumanSome positive data exist, but the data are not
sufficient for classification
Oxirane, Polymer with Methyloxirane, Monobutyl EtherIngestionRatNot carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
NameRouteValueSpeciesTest Result Exposure
Duration
Benzoyl PeroxideIngestionNot classified for female reproductionRatNOAEL 1,000
mg/kg/day
premating &
during
gestation
Benzoyl PeroxideIngestionNot classified for male reproductionRatNOAEL 500
mg/kg/day
premating &
during
gestation
Benzoyl PeroxideIngestionNot classified for developmentRatNOAEL 500
mg/kg/day
premating &
during
gestation
Ethylene GlycolDermalNot classified for developmentMouseNOAEL 3,549
mg/kg/day
during
organogenesi
s
Ethylene GlycolIngestionNot classified for developmentMouseLOAEL 750
mg/kg/day
during
organogenesi
s
Ethylene GlycolInhalationNot classified for developmentMouseNOAEL 1,000
mg/kg/day
during
organogenesi
s
Oxirane, Polymer with Methyloxirane,
Monobutyl Ether
InhalationNot classified for male reproductionRatNOAEL 1
mg/l
2 weeks
Target Organ(s)
Specific Target Organ Toxicity – single exposure
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NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Ethylene GlycolIngestionheart | nervous
system | kidney
and/or bladder |
respiratory system
Causes damage to organsHumanNOAEL Not
available
poisoning
and/or abuse
Ethylene GlycolIngestioncentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
poisoning
and/or abuse
Ethylene GlycolIngestionliverNot classifiedHumanNOAEL Not
available
poisoning
and/or abuse
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionnervous systemNot classifiedRatNOAEL Not
available
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Ethylene GlycolIngestionkidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
RatNOAEL 200
mg/kg/day
2 yearsEthylene GlycolIngestionvascular systemNot classifiedRatNOAEL 200
mg/kg/day
2 yearsEthylene GlycolIngestionheart |
hematopoietic
system | liver |
immune system |
muscles
Not classifiedRatNOAEL
1,000
mg/kg/day
2 yearsEthylene GlycolIngestionrespiratory systemNot classifiedMouseNOAEL
12,000
mg/kg/day
2 yearsEthylene GlycolIngestionskin | endocrine
system | bone, teeth,
nails, and/or hair |
nervous system |
eyes
Not classifiedMultiple
animal
species
NOAEL
1,000
mg/kg/day
2 yearsIron Oxide (FE2O3)Inhalationpulmonary fibrosis |
pneumoconiosis
Not classifiedHumanNOAEL Not
available
occupational
exposure
Oxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationendocrine system |
hematopoietic
system | liver |
nervous system
Not classifiedRatNOAEL 1
mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationkidney and/or
bladder
Not classifiedRatNOAEL
0.005 mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Inhalationrespiratory systemNot classifiedRatLOAEL
0.001 mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
InhalationheartNot classifiedRatNOAEL 0.5
mg/l
2 weeksOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionliver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
RatNOAEL 145
mg/kg/day
90 daysOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionhematopoietic
system
Not classifiedRatNOAEL 500
mg/kg/day
2 yearsOxirane, Polymer with
Methyloxirane, Monobutyl
Ether
Ingestionheart | endocrine
system | respiratory
system
Not classifiedRatNOAEL
3,770
mg/kg/day
90 days
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
3M Cream Hardener (Red, White & Blue) 02/24/22
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SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:
Physical HazardsOrganic peroxideHealth HazardsRespiratory or Skin SensitizationSerious eye damage or eye irritationSpecific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
IngredientC.A.S. No% by WtEthylene Glycol 107-21-1 Trade Secret <= 7.5Zinc Stearate (ZINC COMPOUNDS) 557-05-1 Trade Secret 1 - 10Benzoyl Peroxide 94-36-0 Trade Secret 30 - 60Ferric Ferrocyanide (CYANIDES) 14038-43-8 Trade Secret <= 1
15.2. State Regulations
Contact 3M for more information.
3M Cream Hardener (Red, White & Blue) 02/24/22
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15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: 4 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS IV ratings are to be used with a fully implemented HMIS IV
program. HMIS is a registered mark of the American Coatings Association (ACA).
Document Group:29-5993-0Version Number:6.00Issue Date:02/24/22Supercedes Date:12/07/21
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com
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Safety Data Sheet
Copyright,2023, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:24-8206-5Version Number:11.00Issue Date:02/15/23Supercedes Date:11/09/22
SECTION 1: Identification
1.1. Product identifier
3M Platinum Plus Filler, PN 0032, 01130, 01131, 01132, 01135, 01135B, 31135, 31181, 31139, 31361
Product Identification Numbers
LB-K100-0535-1, LB-K100-0535-2, LB-K100-0535-3, LB-K100-0601-5, LB-K100-1029-4, LB-K100-1959-7, LB-K100-
0913-2, 41-0003-6573-8, 41-0003-6595-1, 41-0003-7943-2, 41-3588-1070-7, 60-4550-5270-8, 60-4550-7279-7, 70-0080-
0094-8, 70-0080-0097-1
7000125034, 4010033246
1.2. Recommended use and restrictions on use
Recommended use
Automotive, Body Repair
1.3. Supplier s details
MANUFACTURER:3MDIVISION:Automotive AftermarketADDRESS:3M Center, St. Paul, MN 55144-1000, USATelephone:1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification
Flammable Liquid: Category 3.
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.
Carcinogenicity: Category 1A.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
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Signal word
Danger
Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Flammable liquid and vapor. Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause cancer. Causes damage to organs: liver | sensory organs | Causes damage to organs through prolonged or repeated exposure: respiratory system | sensory organs | May cause damage to organs through prolonged or repeated exposure: liver |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
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Wash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention. If skin irritation occurs: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
24% of the mixture consists of ingredients of unknown acute oral toxicity.
24% of the mixture consists of ingredients of unknown acute dermal toxicity.
26% of the mixture consists of ingredients of unknown acute inhalation toxicity.
SECTION 3: Composition/information on ingredients
IngredientC.A.S. No.% by WtStyrene Monomer100-42-5 10 - 30 Trade Secret *Talc14807-96-6 7 - 30 Trade Secret *Polyester PolymerTrade Secret* 10 - 30 Trade Secret *Proprietary Polyester ResinTrade Secret* 10 - 30 Trade Secret *Inert FillerTrade Secret* 5 - 10 Trade Secret *Limestone1317-65-3 1 - 5 Trade Secret *Magnesium Carbonate546-93-0 1 - 5 Trade Secret *Titanium Dioxide13463-67-7 1 - 5 Trade Secret *Organophilic PhyllosilicateTrade Secret* 1 - 5 Trade Secret *Chlorite (Mineral)1318-59-8< 3 Trade Secret *Zinc Phosphate7779-90-0 0.5 - 2.5 Trade Secret *PolyamideTrade Secret*< 2 Trade Secret *Paraffin Wax8002-74-2 0.1 - 1 Trade Secret *Poly(oxypropylene)diamine9046-10-0 0.1 - 1 Trade Secret *Quartz Silica14808-60-7< 0.3 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
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Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing.
Immediately get medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Irritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Central nervous
system depression (headache, dizziness, drowsiness, incoordination, nausea, slurred speech, giddiness, and unconsciousness). Target organ
effects. See Section 11 for additional details. Target organ effects following prolonged or repeated exposure. See Section 11 for
additional details.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance ConditionHydrocarbonsDuring CombustionCarbon monoxideDuring CombustionCarbon dioxideDuring Combustion
5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover
with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard.
Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for
transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and
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authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal
the container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against
static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat,
drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid
contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal
protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical
classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable
vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation
during transfer.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from
acids. Store away from strong bases. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.AgencyLimit typeAdditional CommentsStyrene Monomer100-42-5ACGIHTWA:10 ppm;STEL:20 ppmA3: Confirmed animal
carcin., Ototoxicant
Styrene Monomer100-42-5OSHATWA:100 ppm;CEIL:200 ppmLimestone1317-65-3OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Titanium Dioxide13463-67-7ACGIHTWA(Respirable nanoscale
particles):0.2
mg/m3;TWA(Respirable
finescale particles):2.5 mg/m3
A3: Confirmed animal
carcin.
Titanium Dioxide13463-67-7OSHATWA(as total dust):15 mg/m3Talc14807-96-6ACGIHTWA(respirable fraction):2
mg/m3
A4: Not class. as human
carcin
Talc14807-96-6OSHATWA
concentration(respirable):0.1
mg/m3(2.4 millions of
particles/cu. ft.);TWA:20
millions of particles/cu. ft.
Quartz Silica14808-60-7ACGIHTWA(respirable
fraction):0.025 mg/m3
A2: Suspected human
carcin.
Quartz Silica14808-60-7OSHATWA Table Z-
1(respirable):0.05
mg/m3;TWA Table Z-
3(respirable):0.1 mg/m3;TWA
concentration(respirable):0.1
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mg/m3(2.4 millions of
particles/cu. ft.)
Magnesium Carbonate546-93-0OSHATWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Paraffin Wax8002-74-2ACGIHTWA(as fume):2 mg/m3Inert FillerTrade
Secret
Manufacturer
determined
TWA(as non-fibrous,
respirable)(8 hours):3
mg/m3;TWA(as non-fibrous,
inhalable fraction)(8 hours):10
mg/m3
Inert FillerTrade
Secret
ACGIHTWA(as fiber):0.2 fiber/ccA2: Suspected human
carcin.
Inert FillerTrade
Secret
ACGIHTWA(as fiber):1 fiber/ccA3: Confirmed animal
carcin.
Inert FillerTrade
Secret
ACGIHTWA(as fiber):1 fiber/ccA4: Not class. as human
carcin
Inert FillerTrade
Secret
ACGIHTWA(inhalable fraction):5
mg/m3
A4: Not class. as human
carcin
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
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Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state
Color
Liquid
Gold
Specific Physical Form: PasteOdorPungent StyreneOdor thresholdNo Data AvailablepHNo Data AvailableMelting pointNo Data AvailableBoiling Point293 FFlash Point88 F [Test Method:Closed Cup]Evaporation rate0.1 - 0.5 [Ref Std:BUOAC=1]Flammability (solid, gas)Not ApplicableFlammable Limits(LEL)0.9 % [Details:based on styrene]Flammable Limits(UEL)6.8 % [Details:based on styrene]Vapor Pressure4.5 mmHgVapor Density3.6 [Ref Std:AIR=1]Density0.984 g/mlSpecific Gravity0.984 [Ref Std:WATER=1]Solubility in WaterNegligibleSolubility- non-waterNo Data AvailablePartition coefficient: n-octanol/ waterNo Data AvailableAutoignition temperatureNo Data AvailableDecomposition temperatureNo Data AvailableViscosity144,000 centipoise - 168,000 centipoiseHazardous Air Pollutants0.617 lb HAPS/lb solids [Test Method:Calculated]Volatile Organic Compounds23.7 % weight [Test Method: calculated per CARB title 2]Volatile Organic Compounds233 g/l [Test Method:calculated SCAQMD rule 443.1]Percent volatile24.1 % weightPercent volatile26.2 % volumeVOC Less H2O & Exempt Solvents234 g/l [Test Method:calculated SCAQMD rule 443.1]Solids Content38.2 % weight
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable. Stable under normal conditions. May become unstable at elevated temperatures and/or pressure.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Sparks and/or flames
Heat
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10.5. Incompatible materials
Strong acids
Strong oxidizing agents
Alkali and alkaline earth metals
Strong bases
10.6. Hazardous decomposition products
SubstanceCondition None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
May be harmful if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
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nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause target organ effects:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum,
and changes in lung function tests.
Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision.
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
IngredientCAS No.Class DescriptionRegulationSilica, Crystalline (Respirable Size)14808-60-7Known To Be Human Carcinogen.National Toxicology Program CarcinogensInert FillerTrade SecretGrp. 2B: Possible human carc.International Agency for Research on CancerInert FillerTrade SecretAnticipated human carcinogenNational Toxicology Program CarcinogensSilica dust, crystalline, in the form of quartz
or cristobalite
14808-60-7Grp. 1: Carcinogenic to humansInternational Agency for Research on CancerStyrene100-42-5Grp. 2A: Probable human carc.International Agency for Research on CancerStyrene100-42-5Anticipated human carcinogenNational Toxicology Program CarcinogensTitanium dioxide13463-67-7Grp. 2B: Possible human carc.International Agency for Research on Cancer
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValueOverall productDermalNo data available; calculated ATE >5,000 mg/kgOverall productInhalation-
Vapor(4 hr)
No data available; calculated ATE >20 – =50 mg/lOverall productIngestionNo data available; calculated ATE >2,000 – =5,000
mg/kg
Styrene MonomerDermalRatLD50 > 2,000 mg/kgStyrene MonomerInhalation-
Vapor (4
hours)
RatLC50 11.8 mg/lStyrene MonomerIngestionRatLD50 5,000 mg/kgTalcDermalLD50 estimated to be > 5,000 mg/kgTalcIngestionLD50 estimated to be > 5,000 mg/kgPolyester PolymerDermalLD50 estimated to be > 5,000 mg/kgPolyester PolymerIngestionLD50 estimated to be 2,000 – 5,000 mg/kgInert FillerDermalLD50 estimated to be > 5,000 mg/kgInert FillerIngestionLD50 estimated to be 2,000 – 5,000 mg/kgLimestoneDermalRatLD50 > 2,000 mg/kgLimestoneInhalation-
Dust/Mist
(4 hours)
RatLC50 3 mg/lLimestoneIngestionRatLD50 6,450 mg/kgMagnesium CarbonateDermalProfessio
nal
judgeme
nt
LD50 estimated to be 2,000 – 5,000 mg/kgMagnesium CarbonateIngestionRatLD50 > 2,000 mg/kgChlorite (Mineral)DermalLD50 estimated to be > 5,000 mg/kg
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Chlorite (Mineral)IngestionLD50 estimated to be > 5,000 mg/kgTitanium DioxideDermalRabbitLD50 > 10,000 mg/kgTitanium DioxideInhalation-
Dust/Mist
(4 hours)
RatLC50 > 6.82 mg/lTitanium DioxideIngestionRatLD50 > 10,000 mg/kgZinc PhosphateDermalLD50 estimated to be > 5,000 mg/kgZinc PhosphateIngestionRatLD50 > 5,000 mg/kgPolyamideDermalLD50 estimated to be > 5,000 mg/kgPolyamideIngestionLD50 estimated to be 2,000 – 5,000 mg/kgPoly(oxypropylene)diamineDermalRabbitLD50 2,090 mg/kgParaffin WaxDermalRatLD50 > 5,000 mg/kgParaffin WaxIngestionRatLD50 > 5,000 mg/kgPoly(oxypropylene)diamineIngestionRatLD50 475 mg/kgQuartz SilicaDermalLD50 estimated to be > 5,000 mg/kgQuartz SilicaIngestionLD50 estimated to be > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValueStyrene MonomerProfessio
nal
judgeme
nt
Mild irritantTalcRabbitNo significant irritationInert FillerProfessio
nal
judgeme
nt
No significant irritationLimestoneRabbitNo significant irritationMagnesium CarbonateIn vitro
data
No significant irritationChlorite (Mineral)Professio
nal
judgeme
nt
No significant irritationTitanium DioxideRabbitNo significant irritationParaffin WaxRabbitNo significant irritationPoly(oxypropylene)diamineRabbitCorrosiveQuartz SilicaProfessio
nal
judgeme
nt
No significant irritation
Serious Eye Damage/Irritation
NameSpeciesValueStyrene MonomerProfessio
nal
judgeme
nt
Moderate irritantTalcRabbitNo significant irritationInert FillerProfessio
nal
judgeme
nt
No significant irritationLimestoneRabbitNo significant irritationMagnesium CarbonateRabbitMild irritantChlorite (Mineral)Professio
nal
judgeme
nt
No significant irritation
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Titanium DioxideRabbitNo significant irritationParaffin WaxRabbitNo significant irritationPoly(oxypropylene)diamineRabbitCorrosive
Skin Sensitization
NameSpeciesValueStyrene MonomerGuinea
pig
Not classifiedTitanium DioxideHuman
and
animal
Not classifiedParaffin WaxGuinea
pig
Not classified
Respiratory Sensitization
NameSpeciesValueTalcHumanNot classified
Germ Cell Mutagenicity
NameRouteValueStyrene MonomerIn VitroSome positive data exist, but the data are not
sufficient for classification
Styrene MonomerIn vivoSome positive data exist, but the data are not
sufficient for classification
TalcIn VitroNot mutagenicTalcIn vivoNot mutagenicInert FillerIn VitroSome positive data exist, but the data are not
sufficient for classification
Titanium DioxideIn VitroNot mutagenicTitanium DioxideIn vivoNot mutagenicParaffin WaxIn VitroNot mutagenicPoly(oxypropylene)diamineIn VitroNot mutagenicPoly(oxypropylene)diamineIn vivoNot mutagenicQuartz SilicaIn VitroSome positive data exist, but the data are not
sufficient for classification
Quartz SilicaIn vivoSome positive data exist, but the data are not
sufficient for classification
Carcinogenicity
NameRouteSpeciesValueStyrene MonomerIngestionMouseCarcinogenicStyrene MonomerInhalationHuman
and
animal
CarcinogenicTalcInhalationRatSome positive data exist, but the data are not
sufficient for classification
Inert FillerInhalationMultiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Titanium DioxideIngestionMultiple
animal
species
Not carcinogenicTitanium DioxideInhalationRatCarcinogenicParaffin WaxIngestionRatNot carcinogenicQuartz SilicaInhalationHuman
and
animal
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
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NameRouteValueSpeciesTest Result Exposure
Duration
Styrene MonomerIngestionNot classified for female reproductionRatNOAEL 21
mg/kg/day
3 generationStyrene MonomerInhalationNot classified for female reproductionRatNOAEL 2.1
mg/l
2 generationStyrene MonomerInhalationNot classified for male reproductionRatNOAEL 2.1
mg/l
2 generationStyrene MonomerIngestionNot classified for male reproductionRatNOAEL 400
mg/kg/day
60 daysStyrene MonomerIngestionNot classified for developmentRatNOAEL 400
mg/kg/day
during
gestation
Styrene MonomerInhalationNot classified for developmentMultiple
animal
species
NOAEL 2.1
mg/l
during
gestation
TalcIngestionNot classified for developmentRatNOAEL 1,600
mg/kg
during
organogenesi
s
LimestoneIngestionNot classified for developmentRatNOAEL 625
mg/kg/day
premating &
during
gestation
Target Organ(s)
Specific Target Organ Toxicity – single exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Styrene MonomerInhalationauditory systemCauses damage to organsMultiple
animal
species
LOAEL 4.3
mg/l
not availableStyrene MonomerInhalationliverCauses damage to organsMouseLOAEL 2.1
mg/l
not availableStyrene MonomerInhalationcentral nervous
system depression
May cause drowsiness or
dizziness
HumanNOAEL Not
available
occupational
exposure
Styrene MonomerInhalationrespiratory irritationMay cause respiratory irritationHuman
and
animal
NOAEL Not
available
Styrene MonomerInhalationendocrine systemNot classifiedRatNOAEL Not
available
not availableStyrene MonomerInhalationkidney and/or
bladder
Not classifiedMultiple
animal
species
NOAEL 2.1
mg/l
not availableLimestoneInhalationrespiratory systemNot classifiedRatNOAEL
0.812 mg/l
90 minutesPoly(oxypropylene)diamin
e
Inhalationrespiratory irritationSome positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL Not
available
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget Organ(s)ValueSpeciesTest Result Exposure
Duration
Styrene MonomerInhalationauditory systemCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL not
available
occupational
exposure
Styrene MonomerInhalationeyesCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
Styrene MonomerInhalationliverMay cause damage to organs
though prolonged or repeated
exposure
MouseLOAEL 0.85
mg/l
13 weeksStyrene MonomerInhalationnervous systemSome positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
LOAEL 1.1
mg/l
not availableStyrene MonomerInhalationhematopoietic
system
Not classifiedRatNOAEL 0.85
mg/l
7 daysStyrene MonomerInhalationendocrine systemNot classifiedRatNOAEL 0.6
mg/l
10 days
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Styrene MonomerInhalationrespiratory systemNot classifiedMultiple
animal
species
LOAEL 0.09
mg/l
not availableStyrene MonomerInhalationheart |
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
muscles | kidney
and/or bladder
Not classifiedMultiple
animal
species
NOAEL 4.3
mg/l
2 yearsStyrene MonomerIngestionnervous systemSome positive data exist, but the
data are not sufficient for
classification
RatLOAEL 500
mg/kg/day
8 weeksStyrene MonomerIngestionimmune systemSome positive data exist, but the
data are not sufficient for
classification
Multiple
animal
species
NOAEL Not
available
not availableStyrene MonomerIngestionliver | kidney and/or
bladder
Not classifiedRatNOAEL 677
mg/kg/day
6 monthsStyrene MonomerIngestionhematopoietic
system
Not classifiedDogNOAEL 600
mg/kg/day
470 daysStyrene MonomerIngestionheart | respiratory
system
Not classifiedRatNOAEL 35
mg/kg/day
105 weeksTalcInhalationpneumoconiosisCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
TalcInhalationpulmonary fibrosis |
respiratory system
Not classifiedRatNOAEL 18
mg/m3
113 weeksInert FillerInhalationrespiratory systemNot classifiedHumanNOAEL not
available
occupational
exposure
LimestoneInhalationrespiratory systemNot classifiedHumanNOAEL Not
available
occupational
exposure
Titanium DioxideInhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
RatLOAEL 0.01
mg/l
2 yearsTitanium DioxideInhalationpulmonary fibrosisNot classifiedHumanNOAEL Not
available
occupational
exposure
Paraffin WaxIngestionheartSome positive data exist, but the
data are not sufficient for
classification
RatNOAEL 15
mg/kg/day
90 daysParaffin WaxIngestionhematopoietic
system | liver |
immune system |
skin | endocrine
system | bone, teeth,
nails, and/or hair |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system | vascular
system
Not classifiedRatNOAEL
1,500
mg/kg/day
90 daysQuartz SilicaInhalationsilicosisCauses damage to organs through
prolonged or repeated exposure
HumanNOAEL Not
available
occupational
exposure
Aspiration Hazard
NameValueStyrene MonomerAspiration hazardPoly(oxypropylene)diamineSome positive data exist, but the data are not sufficient for
classification
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
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Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate uncured product in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted
waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact manufacturer for more information
EPCRA 311/312 Hazard Classifications:
Physical HazardsFlammable (gases, aerosols, liquids, or solids)Health HazardsCarcinogenicitySerious eye damage or eye irritationSkin Corrosion or IrritationSpecific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
IngredientC.A.S. No% by WtStyrene Monomer 100-42-5 Trade Secret 10 – 30Zinc Phosphate (ZINC COMPOUNDS) 7779-90-0 Trade Secret 0.5 – 2.5
15.2. State Regulations
Contact manufacturer for more information
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
Contact manufacturer for more information
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15.4. International Regulations
Contact manufacturer for more information
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 3 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:24-8206-5Version Number:11.00Issue Date:02/15/23Supercedes Date:11/09/22
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.
3M USA SDSs are available at www.3M.com