3MGeneral Offices
3M Center
St. Paul, MN 55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
10/2/2012 7:32:59 AM
Material Safety Data Sheet
Purchase Order #: –
Customer Number: SMG1993
STE B
REVCHEM COMPOSITES INC
2720 S WILLOW AVE
BLOOMINGTON, CA 92316-3259
United States of America
Dear STE B
Enclosed is the Material Safety Data Sheet (MSDS) for the product that your company recently purchased from 3M.
The MSDS being sent to you is required by the Supplier Notification Requirement of 40 CFR 372.45 (c 4), a part of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. The Supplier
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changes an MSDS in any of the following ways related to EPCRA Section 313 chemical(s):
Additional EPCRA Section 313 chemical(s) were added to the MSDS,
The percent weight of any EPCRA Section 313 chemical(s) changed, or
EPCRA 313 chemical(s)were deleted from the MSDS.
Please forward the attached MSDS to the individual in your organization responsible for implementing Title III of
the Superfund Amendments and Reorganization Act of 1986 and 40 CFR Part 372 regulations.
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MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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Material Safety Data Sheet
Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M Dyanatron White Cream Hardener 308, 30759
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55144-1000
EMERGENCY PHONE: 1 -800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 10/01/12
Supercedes Date: 07/21/11
Document Group:24-8015-0
Product Use:
Intended Use: Automotive
Specific Use: Hardener for body fillers
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
BENZOYL PEROXIDE 94-36-0 30 -60
WATER 7732-18-5 10 -30
BENZOIC ACID, C9-11-BRANCHED ALKYL ESTERS 131298-44-7 10 -20
ZINC STEARATE 557-05-1 3 -7
OXIRANE, POLYMER WITH METHYLOXIRANE, MONOBUTYL ETHER 9038-95-3 3 -4
CALCIUM SULFATE 7778-18-9 3 -4
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Viscous
Odor, Color, Grade: White paste with slight ester odor
General Physical Form: Solid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Dust clouds of this material in combination with an ignition source may be explosive. May cause severe eye irritation.
Maycause allergic skin reaction.
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe EyeIrritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Maybe absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Prolonged or repeatedexposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back p ain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. Ifsigns/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available
Flash Point 111 C [Test Method: Estimated]
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Dust clouds
of this material in combination with an ignition source may be explosive.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the
area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in
accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or
vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or
flammability hazard.
6.2. Environmental precautions
For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container
approved for use in transportation by appropriate authorities.The container must be lined with polyethylene plastic or contain a
plastic drum liner made of polyethylene. Dispose of collected material as soon as possible.
Clean-up methods
Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Contain spill. Cover spill area with a fire -extinguishing foam. An aqueous film forming foam
(AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as
possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person.
Ventilate the area with fresh air. Read and followsafety precautions on the solvent label and MSDS. Seal the container.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away fromheat,
sparks, open flame, pilot lights and other sources of ignition. Avoid static discharge. Avoid eye contact with vapors, mists, or spray.
Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid eye contact
with dust or airborne particles.
7.2 STORAGE
Store awayfrom heat. Store out of direct sunlight. Keep containertightly closed. Do not heat under confinement to avoid risk of
explosion
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no
air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational
Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields
Indirect Vented Goggles
.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polymer laminate
. Use an additional glove (e.g. supported PVC or Nitrile) over the PE/EVAL glove, and change the over-glove frequently.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full
respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce
inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
IngredientAuthorityType Limit Additional Information
BENZOYL PEROXIDE ACGIH TWA 5 mg/m3
BENZOYL PEROXIDE OSHA TWA 5 mg/m3
CALCIUM SULFATE ACGIH TWA, inhalable
fraction
10 mg/m3
CALCIUM SULFATE OSHA TWA, respirable
fraction
5 mg/m3
CALCIUM SULFATE OSHA TWA, as total dust15 mg/m3
STEARATES ACGIH TWA 10 mg/m3
ZINC STEARATE OSHA TWA, respirable
fraction
5 mg/m3
ZINC STEARATE OSHA TWA, as total dust15 mg/m3
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: Viscous
Odor, Color, Grade: White paste with slight ester odor
General Physical Form: Solid
Autoignition temperature No Data Available
Flash Point 111 C [Test Method: Estimated]
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Boiling Point [Details: Decomposes]
Vapor Density Not Applicable
Vapor Pressure Not Applicable
Specific Gravity 1.2 [@ 25 C] [Ref Std: WATER=1]
pH No Data Available
Melting point No Data Available
Solubility in Water Negligible
Evaporation rate Not Applicable
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]
Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2]
Kow -Oct/Water partition coef No Data Available
Percent volatile 20 % [Details: Water is the volatile component]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1]
Viscosity No Data Available
SECTION 10: STABILITY AND REACTIVITY
Stability:Stable. Stable unless exposed to heat, flames and drying conditions.
Materials and Conditions to Avoid:
10.1 Conditions to avoid
Not determined
10.2 Materials to avoid
Accelerators
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Toxic Vapor, Gas, Particulate Not Specified
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in
a permitted hazardous waste facility.
This product has been classified on the basis that it is stable as sold. Material may become unstable if allowed to dry out. Classify
appropriately before disposal.
EPA Hazardous Waste Number (RCRA):D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
70-0080-0378-5, 70-0080-0379-3
For Transport Information, please visit http://3M.com/Transportinfo or call 1 -800-364-3577 or 651-737-6501.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -Yes Immediate Hazard -Yes Delayed Hazard -Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No% by Wt
ZINC STEARATE (ZINC COMPOUNDS) 557-05-1 3 -7
BENZOYL PEROXIDE 94-36-0 30 -60
STATE REGULATIONS
Contact 3M for more information.
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 2 Reactivity: 1 Special Hazards: Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill,or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 1: Product name was modified.
Section 1: Product use information was modified.
Section 10: Hazardous decomposition or by-products table was modified.
Section 13: Waste disposal method information was modified.
Section 13: EPA hazardous waste number (RCRA) information was modified.
Section 8: Respiratory protection -recommended respirators information was modified.
Section 8: Respiratory protection -recommended respirators was modified.
Page Heading: Product name was modified.
Section 9: Vapor density value was modified.
Section 9: Vapor pressure value was modified.
Section 9: Boiling point information was modified.
Section 5: Flammable limits (UE) information was modified.
Section 5: Flammable limits (LEL) information was modified.
Section 5: Autoignition temperature information was modified.
Section 5: Flash point information was modified.
Section 9: Property description for optional properties was modified.
Section 9: Specific gravity information was modified.
Section 9: pH information was modified.
Section 9: Melting point information was modified.
Section 9: Solubility in water text was modified.
Section 8: Respiratory protection -recommended respirators guide was modifi ed.
Section 9: Flash point information was modified.
Section 9: Flammable limits (LEL) information was modified.
Section 9: Flammable limits (UEL) information was modified.
Section 9: Autoignition temperature information was modified.
Section 2: Ingredienttable was modified.
Section 15: EPCRA 313 information was modified.
Section 8: Exposure guidelines ingredient information was modified.
MATERIAL SAFETY DATA SHEET 3M Dyanatron White CreamHardener 308, 30759 10/01/12
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Section 6: Personal precautions information was modified.
Section 6: Environmental procedures information was modified.
Section 6: Methods for cleaning up information was modified.
Copyright was modified.
Section 8: Respiratory protection -recommended respirators punctuation was deleted.
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particular purpose and suitable for user’s method of use or application.
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In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M
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