Safety Data Sheet
Revision Number: 006.0 Issue date: 08/01/2014
IDH number: 548991 Product name: LOCTITE FREKOTE 700NC known as FREKOTE 700-NC RELEASING INT
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1. PRODUCT AND COMPANY IDENTIFICATION
Product name: LOCTITE FREKOTE 700NC known as
FREKOTE 700-NC RELEASING INT
IDH number: 548991
Product type: Mold Release Item number: 38426
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation
One Henkel Way
Rocky Hill, Connecticut 06067
Telephone: (860) 571-5100
MEDICAL EMERGENCY Phone: Poison Control Center
1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com
Contains one or more components for which a Toxic Substances Control Act (TSCA) Low Volume Exemption (LVE) applies. See
Section 15.
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: FLAMMABLE LIQUID AND VAPOR.
MAY BE FATAL IF SWALLOWED AND ENTERS AIR WAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 3
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGA N TOXICITY – SINGLE EXPOSURE 3
ASPIRATION HAZARD 1
PICTOGRAM(S)
Precautionary Statements
Prevention: Keep away from heat,sparks, open flames, hot surfaces – no smoking. Keep container tightly
closed. No release into water. Use explosion-proof equipment. Use only non-sparking tools.
Take precautionary measures against static discharge. Avoid breathing vapors, mist, or spray.
Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective
gloves, eye protection, and face protection.
Response: IF SWALLOWED: Immediately call a physician or poison control center. If on skin (or hair):
Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to remove. Continue rinsing. Call a poison control center or physician if you
feel unwell. Do NOT induce vomiting. If skin irritation occurs: Get medical attention. If eye
irritation persists: Get medical attention. Take off contaminated clothing. In case of fire: Use
foam, dry chemical or carbon dioxide to extinguish.
IDH number: 548991 Product name: LOCTITE FREKOTE 700NC known as FREKOTE 700-NC RELEASING INT
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Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.
Keep cool. Store locked up.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.
Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDI ENTS
Hazardous Component(s) CAS Number Percentage*
Dibutyl ether 142-96-1 10 – 30
Naphtha, hydrotreated heavy; (petroleum) 64742-48-9 60 – 100
Alkanes, C7-10-iso- 90622-56-3 1 – 5
Octane 111-65-9 1 – 5
* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.
4. FIRST AID MEASURES
Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Skin contact: Remove contaminated clothing and footwear. Immediately flush skin with
plenty of water (using soap, if available). If symptoms develop and persist, get
medical attention. Wash clothing before reuse.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get immediate medical attention.
Ingestion: Keep individual calm. Do not induce vomiting: contains petroleum distillates
and/or aromatic solvents. Never give anything by mouth to an unconscious
person. Get immediate medical attention. If vomiting occurs, prevent
aspiration by keeping the patient’s head below the knees.
Symptoms: See Section 11.
Notes to physician: This material is an aspiration hazard. Potential danger from aspiration must
be weighed against possible oral toxicity when deciding whether to induce
vomiting.
5. FIRE FIGHTING MEASURES
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Do not use high
volume water jet.
Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear. In case of fire, keep containers cool with water spray. Keep
personnel upwind of fire.
Unusual fire or explosion hazards: Vapors may form explosive mixtures with air. Do not handle or store near an
open flame, heat or other sources of ignition. Hydrocarbon solvents are
basically non-conductors of electricity and can become electrostatically
charged during mixing, filtering or pumping at high flow rates. If this charge
reaches a significantly high level, sparks can form that may ignite vapors of
flammable liquids.
IDH number: 548991 Product name: LOCTITE FREKOTE 700NC known as FREKOTE 700-NC RELEASING INT
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Hazardous combustion products: Oxides of carbon. Irritating organic vapours. Acrid smoke and fumes. Collect
contaminated fire extinguishing water separately. This must not be discharged
into drains.
6. ACCIDENTAL RELEASE MEASURES
Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.
Environmental precautions: Do not allow product to enter sewer or waterways. Prevent further leakage or
spillage if safe to do so. Advise authorities if product has entered or may enter
sewers, water sources or extensive land areas. This product is insoluble in
water and will float on surface.
Clean-up methods: Remove all sources of ignition. Ventilate area. Wear suitable protective
clothing, gloves and eye/face protection. Keep upwind of the spilled material
and isolate exposure. Soak up with inert absorbent material (e.g. sand, silica
gel, acid binder, universal binder, sawdust). Store in a partly filled, closed
container until disposal.
7. HANDLING AND STORAGE
Handling: During use and until all vapors are gone: Keep area ventilated – do not
smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical
tools and appliances, and any other sources of ignition. Prevent contact with
eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly
after handling. Make sure containers are properly grounded before use or
transfer of material. For operations where eye or face contact could occur,
provide safety shower and eyewash fountain.
Storage: For safe storage, store at or below 48.8 C (119.8 F)
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROL S / PERSONAL PROTECT ION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.
Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER
Dibutyl ether None None None None
Naphtha, hydrotreated heavy; (petroleum) None None None 196 ppm TWA
Alkanes, C7-10-iso- None None None None
Octane 300 ppm TWA
500 ppm (2,350
mg/m3) PEL
None None
Engineering controls: Use explosion-proof mechanical ventilation and local exhaust to control
contaminants to within their occupational exposure limits during the use of this
product.
Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed
established exposure limits exists.
Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact.
IDH number: 548991 Product name: LOCTITE FREKOTE 700NC known as FREKOTE 700-NC RELEASING INT
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Colorless
Odor: Mild, Solvent
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not available.
Boiling point/range: > 112 C (> 233.6 F) (1,013 hPa)
Melting point/ range: Not determined
Specific gravity: 0.754
Vapor density: Heavier than air.
Flash point: 31 C (87.8 F) Tagliabue closed cup
Flammable/Explosive limits – lower: Not available.
Flammable/Explosive limits – upper: Not available.
Autoignition temperature: > 200 C (> 392 F) (value for solvent)
Evaporation rate: Slower than ether.
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available.
VOC content: 754 g/l of coating
Viscosity: Not available.
Decomposition temperature: Not available.
10. STABILITY AND REACTIVITY
Stability: Risk of ignition.Stable under normal conditions of storage and use.
Hazardous reactions: Will not occur.
Hazardous decomposition
products:
Oxides of carbon. Traces of Ammonia. Hydrocarbons.
Incompatible materials: Strong oxidizing agents. Humid air. Water.
Reactivity: Not available.
Conditions to avoid: Avoid static discharge. Vapors may form explosive mixtures with air. Spray mist may be
flammable at temperatures below the flash point. Keep away from open flames, hot surfaces
and sources of ignition. Fire or intense heat may cause violent rupture of packages. Exposure
to air or moisture over prolonged periods.
11. TOXICOLOGICAL INFORMATION
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
IDH number: 548991 Product name: LOCTITE FREKOTE 700NC known as FREKOTE 700-NC RELEASING INT
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Potential Health Effects/Symptoms
Inhalation: Vapors and mists will irritate nose and throat and possibly eyes. High vapor concentrations
(greater than approximately 1000 ppm) may cause headaches, dizziness, anesthesia,
drowsiness, unconsciousness, and other central nervous system effects, including death.
Skin contact: Causes skin irritation. Solvent action can dry and defat the skin, causing the skin to crack,
leading to dermatitis.
Eye contact: Causes serious eye irritation.
Ingestion: This product may be fatal if it is swallowed. Aspiration may occur during swallowing or vomiting,
resulting in lung damage. Central nervous system depression, including dizziness, drowsiness,
fatigue, nausea, headache, unconsciousness.
Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Dibutyl ether None
Irritant, Central nervous system, Cardiac,
Kidney, Gastrointestinal, Mutagen
Naphtha, hydrotreated heavy; (petroleum) None Irritant
Alkanes, C7-10-iso- None
Central nervous system, Irritant, Lung,
Cardiac
Octane Inhalation LC50 (RAT, 4 h) = 118 mg/l Central nervous system, Irritant, Lung
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
OSHA Carcinogen
(Specifically Regulated)
Dibutyl ether No No No
Naphtha, hydrotreated heavy; (petroleum) No No No
Alkanes, C7-10-iso- No No No
Octane No No No
12. ECOLOGICAL INFORMATION
Ecological information: Not available.
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.
Hazardous waste number: D001: Ignitable.
14. TRANSPORT INFORMATION
The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.
U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: Resin solution
Hazard class or division: 3
Identification number: UN 1866
Packing group: III
International Air Transportation (ICAO/IATA)
Proper shipping name: Resin solution
Hazard class or division: 3
Identification number: UN 1866
Packing group: III
IDH number: 548991 Product name: LOCTITE FREKOTE 700NC known as FREKOTE 700-NC RELEASING INT
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Water Transportation (IMO/IMDG)
Proper shipping name: RESIN SOLUTION (Octane)
Hazard class or division: 3
Identification number: UN 1866
Packing group: III
Marine pollutant: Octane
15. REGULATORY INFORMATI ON
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis
CERCLA/SARA Section 302 EHS: None above reporting de minimis
CERCLA/SARA Section 311/312: Fire, Immediate Health, Delayed Health
CERCLA/SARA Section 313: None above reporting de minimis
CERCLA Reportable quantity: Dibutyl ether (CAS# 142-96-1) 100 lbs. (45.4 kg)
Octane (CAS# 111-65-9) 100 lbs. (45.4 kg)
California Proposition 65: No California Proposition 65 listed chemicals are known to be present.
Canada Regulatory Information
CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the
Domestic Substances List or the Non-Domestic Substances List.
16. OTHER INFORMATION
This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.
Prepared by: Catherine Bimler, Regulatory Affairs Specialist
Issue date: 08/01/2014
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.