SAFETY DATA SHEET
1. Identification
Product identifier
Other means of identification
Recommended use TR-
955 EZ WIPE II Semi Perm Release
MR 955
Mold Release.
None known.
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufacturer/Supplier Granitize Products, Inc.
11022 Vulcan Street
South Gate, CA 90280-0893 US
Telephone: (562) 923-5438
Emergency CHEMTREC: (800) 424-9300
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 2Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 1Sensitization, skin
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Highly flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May
cause an allergic skin reaction May cause drowsiness or dizziness. May be fatal if swallowed and
enters airways. Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/eye
protection/face protection. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment.
Response In case of fire: Use alcohol resistant foam, dry chemical powder, carbon dioxide to extinguish. If
swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If inhaled:
Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you
feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Collect spillage.
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Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
64741-66-8 60-100Naphtha (petroleum), light
alkylate
CAS number %Chemical name
64742-48-9 10-30Naphtha, hydrotreated heavy;
(petroleum)
Proprietary 0.1-1Silane Derivative
Proprietary 0.1-1Proprietary Resin
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Inhalation
Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions. Wash
contaminated clothing before reuse.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include stinging,
tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Dermatitis.
Rash. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause
pulmonary edema and pneumonitis.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. If you feel unwell, seek medical advice (show the
label where possible). Ensure that medical personnel are aware of the material(s) involved, and
take precautions to protect themselves. Wash contaminated clothing before reuse.
General information
5. Fire-fighting measures
Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. This product is a poor conductor of electricity and can become
electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can
occur. To reduce potential for static discharge, use proper bonding and grounding procedures.
This liquid may accumulate static electricity when filling properly grounded containers. Static
electricity accumulation may be significantly increased by the presence of small quantities of water
or other contaminants. Material will float and may ignite on surface of water. Material may react
with water. During fire, gases hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials. Cool
containers exposed to flames with water until well after the fire is out.
Specific methods
Highly flammable liquid and vapor.General fire hazards
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6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Use appropriate containment to avoid environmental
contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other
suitable container for recovery or safe disposal. Local authorities should be advised if significant
spillages cannot be contained.
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground. Use appropriate containment to avoid environmental
contamination.
Environmental precautions
7. Handling and storage
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Minimize fire risks from flammable and combustible materials (including combustible
dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling
operations that can promote accumulation of static charges include but are not limited to: mixing,
filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container
filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take
precautionary measures against static discharges. All equipment used when handling the product
must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or
vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid prolonged
exposure. Persons susceptible for allergic reactions should not handle this product. Wear
appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release
to the environment. Observe good industrial hygiene practices.
For additional information on equipment bonding and grounding, refer to the Canadian Electrical
Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice
2003, “Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents” or National
Fire Protection Association (NFPA) 77, “Recommended Practice on Static Electricity” or National
Fire Protection Association (NFPA) 70, “National Electrical Code”.
Precautions for safe handling
Store locked up. Avoid contact with oxidizing agents. Keep away from heat, sparks and open
flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques.
Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment.
These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct
sunlight. Store in closed original container at temperatures between 5 C and 25 C. Store in a
well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible
materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents
PEL 400 mg/m3Naphtha, hydrotreated
heavy; (petroleum) (CAS
64742-48-9)
100 ppm
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US. NIOSH: Pocket Guide to Chemical Hazards
ValueTypeComponents
TWA 400 mg/m3Naphtha, hydrotreated
heavy; (petroleum) (CAS
64742-48-9)
100 ppm
No biological exposure limits noted for the ingredient(s).Biological limit values
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Provide easy access to water supply
and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear approved safety glasses or goggles. Wear face shield if there is risk of splashes.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
In case of inadequate ventilation or risk of inhalation of vapors, suitable respiratory equipment with
particulate filter and organic vapor cartridges can be used. If permissible levels are exceeded use
NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants. Contaminated work clothing should not
be allowed out of the workplace.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Liquid.Form
Colorless.Color
Mild solvent.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot determined.
Initial boiling point and boiling
range
> 233.6 F (> 112 C)
Flash point 42.8 F (6.0 C) Tagliabue
Evaporation rate Slower than ether.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
Vapor pressure 2.07 mm Hg
Vapor pressure temp. 68 F (20 C)
Vapor density Heavier than air.
Relative density 0.725 (H20=1)
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Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
VOC (Weight %)
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Slightly soluble in water.
Not available.
Not available.
Not available.
Not available.
99.39%; 6.00lbs./gal ( 719g/l)
The product is stable and non-reactive under normal conditions of use, storage and transport.
Risk of ignition. Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials. Avoid heat, sparks, open flames and other ignition sources.
Protect against direct sunlight. Containers may rupture or explode if exposed to heat. Avoid
temperatures exceeding the flash point. Static discharge may cause ignition at temperatures at or
above flashpoint. Spray mist may be flammable at temperatures below the flash point. Vapors may
form explosive mixture with air.
Strong oxidizing agents. Humid air. Water.
Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.
Hydrocarbons.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be
harmful.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Eye contac
t Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include
stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction.
Dermatitis. Rash. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration
ma
y cause pulmonary edema and pneumonitis.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
May cause an allergic skin reaction.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause drowsiness and dizziness.
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Specific target organ toxicity –
repeated exposure
Not classified.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.
Further information Symptoms may be delayed.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity
No data is available on the degradability of this product. Persistence and degradability
No data available on bioaccumulation.Bioaccumulative potential
This product is slightly water soluble and may disperse in soil.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D001: Waste Flammable material with a flash point <140 F
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN1866UN number
Resin solution, FlammableUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
YesMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
B1, B52, IB3, T2, TP1Special provisions
150Packaging exceptions
173Packaging non bulk
242Packaging bulk
IATA
UN1866UN number
Resin solution, FlammableUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
YesEnvironmental hazards
3LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1866UN number
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RESIN SOLUTION, FLAMMABLEUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
YesMarine pollutant
Environmental hazards
F-E, S -E EmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are listed on or exempt from the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
YesSARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Naphtha, hydrotreated heavy; (petroleum) (CAS 64742-48-9)
US. New Jersey Worker and Community Right-to-Know Act
Naphtha, hydrotreated heavy; (petroleum) (CAS 64742-48-9)
US. Pennsylvania Worker and Community Right-to-Know Law
Naphtha, hydrotreated heavy; (petroleum) (CAS 64742-48-9)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
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International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
17-December-2014Issue date
17-May-2016Revision date
Version # 06
NFPA ratings
02
3
Granitize Products Inc. cannot anticipate all conditions under which this information and its
product, or the products of other manufacturers in combination with its product, may be used. It is
the user s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
Disclaimer
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