SAFETY DATA SHEET
1. Identification
Product identifier
Other means of identification
Product code
Recommended use
TR-500XP One Step Polish
MR500XP
Industrial use polishing compound.
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Company name
Address
Telephone
Emergency telephone
2. Hazard(s) identification
Physical hazards
Health hazards
Category 1
Category 1A
Category 2 (lungs)
TR Industries a Division of Granitize Products Inc.
11022 Vulcan Street
South Gate, CA 90280-0893
United States
(562) 923-5438
CHEMTREC: (800) 424-9300
CHEMTREC International: 00 1-703-527-3887
Flammable liquids
Sensitization, skin
Carcinogenicity (inhalation)
Specific target organ toxicity, repeated
exposure (inhalation)
Category 2Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Not classified.OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Danger
Combustible liquid. May cause an allergic skin reaction. May cause cancer by inhalation. May
cause damage to organs (lungs) through prolonged or repeated exposure by inhalation. Toxic to
aquatic life.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from flames and hot surfaces-No smoking. Do not breathe
mist/vapors. Contaminated work clothing must not be allowed out of the workplace. Avoid
release to the environment. Wear protective gloves/protective clothing/eye protection/face
protection.
If on skin: Wash with plenty of water. If exposed or concerned: Get medical advice/attention. If
skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before
reuse. In case of fire: Use water fog, foam, dry chemical powder, carbon dioxide (CO2) to
extinguish.
Store in a well-ventilated place. Keep cool. Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
None.
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Category 4
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
7732-18-5Water 35 – 65
1317-95-9Microcrystalline silica, Tripoli 15 – 40
8042-47-5White mineral oil 5 – 10
5989-27-5D-Limonene 1 – 5
56-81-5Glycerin 1 – 5
All concentrations are in percent by weight unless otherwise indicated. Components not listed are
either non-hazardous or are below reportable limits.
Composition comments
4. First-aid measures
Move to fresh air. Call a physician if symptoms develop or persist.Inhalation
Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions.
Skin contact
Rinse with water. Get medical attention if irritation develops and persists.Eye contact
Rinse mouth. Get medical attention if symptoms occur.Ingestion
Direct contact with eyes may cause temporary irritation. May cause an allergic skin reaction.
Dermatitis. Rash. Prolonged exposure may cause chronic effects.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.
General information
5. Fire-fighting measures
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
The product is combustible, and heating may generate vapors which may form explosive vapor/air
mixtures. During fire, gases hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to flames with water until well after the fire is out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Combustible liquid.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Do not breathe mist/vapors. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material. Clean surface thoroughly to remove residual
contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
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Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from open flames, hot surfaces and sources of ignition. When using
do not smoke. Do not breathe mist/vapors. Avoid contact with eyes, skin, and clothing. Avoid
prolonged exposure. Persons susceptible to allergic reactions should not handle this product.
Should be handled in closed systems, if possible. Provide adequate ventilation. Wear appropriate
personal protective equipment. Avoid release to the environment. Observe good industrial hygiene
practices.
Precautions for safe handling
Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. Keep
away from heat, sparks and open flame. Store in a cool, dry place out of direct sunlight. Store in
tightly closed container. Store in a well-ventilated place. Store away from incompatible materials
(see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
ValueComponents Type
TWA 0.05 mg/m3Microcrystalline silica,
Tripoli (CAS 1317-95-9)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
FormValueComponents Type
PEL 5 mg/m3 Respirable fraction.Glycerin (CAS 56-81-5)
15 mg/m3 Total dust.
PEL 0.05 mg/m3 Respirable dust.Microcrystalline silica,
Tripoli (CAS 1317-95-9)
PEL 5 mg/m3 Mist.White mineral oil (CAS
8042-47-5)
US. ACGIH Threshold Limit Values
Form
ValueComponents Type
TWA 0.025 mg/m3 Respirable fraction.Microcrystalline silica,
Tripoli (CAS 1317-95-9)
TWA 5 mg/m3 Inhalable fraction.White mineral oil (CAS
8042-47-5)
US. NIOSH: Pocket Guide to Chemical Hazards
Form
ValueComponents Type
TWA 0.05 mg/m3 Respirable dust.Microcrystalline silica,
Tripoli (CAS 1317-95-9)
STEL 10 mg/m3 Mist.White mineral oil (CAS
8042-47-5)
TWA 5 mg/m3 Mist.
US. Workplace Environmental Exposure Level (WEEL) Guides
ValueComponents Type
TWA 165.5 mg/m3D-Limonene (CAS 5989-27-5)
30 ppm
No biological exposure limits noted for the ingredient(s).Biological limit values
Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.Eye/face protection
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Skin protection
Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Nitrile gloves are recommended. Other suitable gloves can be
recommended by the glove supplier.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Check with respiratory protective
equipment suppliers.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Contaminated work clothing should not be allowed out of the workplace.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Liquid.
Semi-Paste.
White.
Characteristic odor.
Not available.
Not available.
Not available.
314.6 – 390.02 F (157 – 198.9 C)
142.0 F (61.1 C)
Not available.
Not applicable.
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
Explosive properties
Oxidizing properties
Percent volatile
10. Stability and reactivity
Reactivity
Not available.
Not available.
4.9 (Air=1)
1.23 (Water=1)
Negligible in water.
Not available.
Not available.
Not available.
Not available.
Not explosive.
Not oxidizing.
20 % v/v
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.Chemical stability
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Hazardous polymerization does not occur.Possibility of hazardous
reactions
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Conditions to avoid
Strong oxidizing agents. Chlorine.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide. Silicon
oxide fumes.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
cancer by inhalation.
Skin contact May cause an allergic skin reaction. May be absorbed through the skin.
Eye contac
t Direct contact with eyes may cause temporary irritation.
Ingestion May cause discomfort if swallowed.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation. May cause an allergic skin reaction.
Dermatitis. Rash. Prolonged exposure may cause chronic effects.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
D-Limonene (CAS 5989-27-5)
Dermal
Acute
LD50 Rabbit > 5000 mg/kg
Oral
LD50 Rat 4400 mg/kg/day
Other
NOAEL Rat 300 mg/kg/day
Glycerin (CAS 56-81-5)
Dermal
Acute
LD50 Rabbit > 18700 mg/kg
Oral
LD50 Rat 27200 mg/kg
White mineral oil (CAS 8042-47-5)
Dermal
Acute
LD50 Rabbit > 2000 mg/kg
Inhalation
LC50 Rat > 5 mg/l
Oral
LD50 Rat > 5000 mg/kg
Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation
Direct contact with eyes may cause temporary irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
May cause an allergic skin reaction.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicit
y May cause cancer.
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IARC Monographs. Overall Evaluation of Carcinogenicity
D-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans.
Microcrystalline silica, Tripoli (CAS 1317-95-9)1 Carcinogenic to humans.
White mineral oil (CAS 8042-47-5) 3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Microcrystalline silica, Tripoli (CAS 1317-95-9)Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Microcrystalline silica, Tripoli (CAS 1317-95-9) Cancer
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
Not classified.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (lungs) through prolonged or repeated exposure by inhalation.
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful. May cause damage to organs through prolonged or
repeated exposure. Prolonged exposure may cause chronic effects.
Further information Symptoms may be delayed.
12. Ecological information
Toxic to aquatic life.Ecotoxicity
Components Test ResultsSpecies
D-Limonene (CAS 5989-27-5)
Aquatic
Acute
EC50Crustacea 0.421 mg/l, 48 HoursDaphnia magna
LC50Fish 0.702 mg/l, 96 HoursFathead minnow (Pimephales promelas)
Chronic
NOECAlgae 4.08 mg/l, 96 HoursGreen algae (Chlamydomonas variabilis)
NOECCrustacea 0.15 mg/l, 21 daysDaphnia magna
Glycerin (CAS 56-81-5)
Aquatic
Acute
EC50Crustacea > 10000 mg/l, 24 HoursDaphnia magna
White mineral oil (CAS 8042-47-5)
Aquatic
Acute
LL50Crustacea 100 mg/lInvertebrates (Invertebrates)
LL50Fish 10 mg/lFish
No data is available on the degradability of this product.Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
D-Limonene (CAS 5989-27-5) 4.232
Glycerin (CAS 56-81-5) -1.76
The product is insoluble or slightly soluble in water. Expected to have low mobility in soil.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
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Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
14. Transport information
DOT
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose in accordance with local regulations. Empty containers or liners may retain some product
residues. This material and its container must be disposed of in a safe manner.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
NA1993UN number
Combustible liquids, n.o.s. (Limonene)UN proper shipping name
– Combustible LiquidClass
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIIPacking group
YesMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
B1, B52, IB3, T4, TP1, TP29Special provisions
150Packaging exceptions
203Packaging non bulk
242Packaging bulk
IATA
UN3082UN number
Environmentally hazardous substance, liquid, n.o.s. (D-Limonene)UN proper shipping name
9Class
Transport hazard class(es)
-Subsidiary risk
9Label(s)
IIIPacking group
YesEnvironmental hazards
9LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN3082UN number
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (D-LIMONENE)UN proper shipping name
9Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
YesMarine pollutant
Environmental hazards
F-A, S-FEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Microcrystalline silica, Tripoli (CAS 1317-95-9) Cancer
lung effects
immune system effects
kidney effects
Toxic Substances Control Act (TSCA) One or more components of the mixture are not on the TSCA 8(b) inventory
or are designated inactive .
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Flammable (gases, aerosols, liquids, or solids)
Respiratory or skin sensitization
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Contains component(s) regulated under the Safe Drinking Water Act.Safe Drinking Water Act
(SDWA)
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
Glycerin (CAS 56-81-5) Other Flavoring Substances with OSHA PEL’s
US state regulations
US. Massachusetts RTK – Substance List
Glycerin (CAS 56-81-5)
Microcrystalline silica, Tripoli (CAS 1317-95-9)
White mineral oil (CAS 8042-47-5)
US. New Jersey Worker and Community Right-to-Know Act
D-Limonene (CAS 5989-27-5)
Glycerin (CAS 56-81-5)
Microcrystalline silica, Tripoli (CAS 1317-95-9)
White mineral oil (CAS 8042-47-5)
US. Pennsylvania Worker and Community Right-to-Know Law
Glycerin (CAS 56-81-5)
Microcrystalline silica, Tripoli (CAS 1317-95-9)
White mineral oil (CAS 8042-47-5)
US. Rhode Island RTK
Glycerin (CAS 56-81-5)
Microcrystalline silica, Tripoli (CAS 1317-95-9)
White mineral oil (CAS 8042-47-5)
California Proposition 65
This product can expose you to Quartz
, which is known to the State of California to cause
cancer. For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 – CRT: Listed date/Carcinogenic substance
Microcrystalline silica, Tripoli (CAS 1317-95-9)Listed: October 1, 1988
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US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
White mineral oil (CAS 8042-47-5)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
NoAustralia Australian Inventory of Industrial Chemicals (AICIS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesTaiwan Taiwan Chemical Substance Inventory (TCSI)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A “Yes” indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
01-May -2025
–
01
NFPA ratings
02
1
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
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