SAFETY DATA SHEET
1. Identification
TR-930 Mold ReleaseProduct identifier
None.Other means of identification
Mold release.Recommended use
None known.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 3Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
Causes serious eye irritation. May cause drowsiness or dizziness. May cause respiratory irritation.
Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting// equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear
protective gloves/eye protection/face protection.
Response If swallowed: Immediately call a poison center/doctor/. Do NOT induce vomiting. If on skin (or
hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin
irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a poison
center/doctor// if you feel unwell. In case of fire: Use water fog, alcohol resistant foam, dry
chemical powder, carbon dioxide to extinguish. Collect spillage.
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Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Not
assigned.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Not assigned.
Hazard(s) not otherwise
classified (HNOC)
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
64742-48-9 60-100Naphtha (petroleum),
hydrotreated heavy
CAS number %Chemical name
142-96-1 10 – 30Dibutyl Ether
90622-56-3 1 – 5Alkanes, C7-10-iso-
111-65-9 1 – 5Octane
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Inhalation
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn’t get into the lungs.
Ingestion
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include stinging,
tearing, redness, swelling, and blurred vision. May cause drowsiness and dizziness. May cause
respiratory irritation. Headache. Nausea, vomiting. Swallowing of the liquid, or vomiting as a result,
may result in aspiration into the lungs. Aspiration may cause pulmonary edema and pneumonitis.
Be aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after
exposure.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
General information
5. Fire-fighting measures
Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. This product is a poor conductor of electricity and can become
electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can
occur. To reduce potential for static discharge, use proper bonding and grounding procedures.
This liquid may accumulate static electricity when filling properly grounded containers. Static
electricity accumulation may be significantly increased by the presence of small quantities of water
or other contaminants. Material will float and may ignite on surface of water. During fire, gases
hazardous to health may be formed.
Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to flames with water until well after the fire is out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Flammable liquid and vapor.General fire hazards
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6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Use appropriate containment to avoid environmental
contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other
suitable container for recovery or safe disposal. Local authorities should be advised if significant
spillages cannot be contained.
Personal precautions,
protective equipment and
emergency procedures
Use water spray to reduce vapors or divert vapor cloud drift. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Take precautionary measures against static discharge. Use only
non-sparking tools. Prevent entry into waterways, sewer, basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb spill with vermiculite or other inert material. Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground. Use appropriate containment to avoid environmental
contamination.
Environmental precautions
7. Handling and storage
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Minimize fire risks from flammable and combustible materials (including combustible
dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling
operations that can promote accumulation of static charges include but are not limited to: mixing,
filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container
filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take
precautionary measures against static discharges. All equipment used when handling the product
must be grounded. Use non-sparking tools and explosion-proof equipment. Do not taste or
swallow. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid
prolonged exposure. Wear appropriate personal protective equipment. Wash hands thoroughly
after handling. Avoid release to the environment. Observe good industrial hygiene practices.
For additional information on equipment bonding and grounding, refer to the Canadian Electrical
Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice
2003, “Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents” or National
Fire Protection Association (NFPA) 77, “Recommended Practice on Static Electricity” or National
Fire Protection Association (NFPA) 70, “National Electrical Code”.
Precautions for safe handling
Store locked up. Keep away from heat, sparks and open flame. Keep at temperature not
exceeding 48.8 C. Prevent electrostatic charge build-up by using common bonding and grounding
techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and
equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place
out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place.
Keep in an area equipped with sprinklers. Avoid contact with oxidizing agents. Store away from
incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 2350 mg/m3Octane (CAS 111-65-9)
500 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 300 ppmOctane (CAS 111-65-9)
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US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
Ceiling 1800 mg/m3Octane (CAS 111-65-9)
385 ppm
TWA 350 mg/m3
75 ppm
No biological exposure limits noted for the ingredient(s).Biological limit values
Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Nitrile
gloves are recommended. Other suitable gloves can be recommended by the glove supplier.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing.Other
In case of inadequate ventilation or risk of inhalation of vapors, suitable respiratory equipment with
particulate filter and organic vapor cartridges can be used. If permissible levels are exceeded use
NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. If engineering
controls do not maintain airborne concentrations below recommended exposure limits (where
applicable) or to an acceptable level (in countries where exposure limits have not been
established), an approved respirator must be worn. Check with respiratory protective equipment
suppliers.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Liquid.Physical state
Colorless liquid.Form
Colorless.Color
Mild. Solvent.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot determined.
Initial boiling point and boiling
range
> 233.6 F (> 112 C)
Boiling point pressure 1013 hPa
Flash point 87.8 F (31.0 C) (Tagliabue Closed Cup)
Evaporation rate Slower than ether.
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
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Vapor pressure Not available.
Vapor density Heavier than air.
Relative density 0.754 (H2O=1)
Solubility(ies)
Solubility (water) Slightly soluble in water.
Solubility (solvents) Soluble in organic solvents.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature > 392 F (> 200 C) (Value for solvent)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
VOC 754 g/l (of coating)
10. Stability and reactivity
The product is stable and non reactive under normal conditions of use, storage and transport.Reactivity
Risk of ignition.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Avoid heat, sparks, open flames and other ignition sources. Static discharge may cause ignition at
temperatures at or above flashpoint. Avoid temperatures exceeding the flash point. Contact with
incompatible materials. Spray mist may be flammable at temperatures below the flash point.
Conditions to avoid
Strong oxidizing agents.Incompatible materials
Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.
Hydrocarbons.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. May cause respiratory irritation. Prolonged inhalation may
be harmful.
Skin contact Causes skin irritation.
Eye contac
t Causes serious eye irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Skin irritation. May cause redness and pain. Severe eye irritation. Symptoms may include
stinging, tearing, redness, swelling, and blurred vision. May cause drowsiness and dizziness. May
cause respiratory irritation. Headache. Nausea, vomiting. Swallowing or vomiting of the liquid may
result in aspiration into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Be
aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after
exposure.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
Dibutyl Ether (CAS 142-96-1)
Oral
Acute
LD50 Rat 3230 – 3920 mg/kg
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
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This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Naphtha (petroleum), hydrotreated heavy
(CAS 64742-48-9)
3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause respiratory irritation. May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
Not classified.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful.
Further information Symptoms may be delayed.
12. Ecological information
Toxic to aquatic life with long lasting effects.Ecotoxicity
Components Test ResultsSpecies
Octane (CAS 111-65-9)
Aquatic
LC50Crustacea 0.38 mg/l, 48 hoursDaphnia magna
No data is available on the degradability of this product.Persistence and degradability
No data available on bioaccumulation.Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Dibutyl Ether (CAS 142-96-1) 3.21
Octane (CAS 111-65-9) 5.18
This product is slightly water soluble and may disperse in soil.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
D001: Waste Flammable material with a flash point <140 F
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN1866UN number
Resin SolutionUN proper shipping name
3Class
Transport hazard class(es)
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-Subsidiary risk
3Label(s)
IIIPacking group
YesMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
B1, B52, IB3, T2, TP1Special provisions
150Packaging exceptions
173Packaging non bulk
242Packaging bulk
IATA
UN1866UN number
Resin Solution, FlammableUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIIPacking group
YesEnvironmental hazards
3LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1866UN number
Resin Solution, FlammableUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIIPacking group
YesMarine pollutant
Environmental hazards
F-E, S-EEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Dibutyl Ether (CAS 142-96-1) Listed.
Octane (CAS 111-65-9) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Toxic Substances Control Act (TSCA)
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
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Flammable (gases, aerosols, liquids, or solids)
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
Aspiration hazard
Hazard not otherwise classified (HNOC)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Dibutyl Ether (CAS 142-96-1)
Octane (CAS 111-65-9)
US. New Jersey Worker and Community Right-to-Know Act
Dibutyl Ether (CAS 142-96-1)
Octane (CAS 111-65-9)
US. Pennsylvania Worker and Community Right-to-Know Law
Dibutyl Ether (CAS 142-96-1)
Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9)
Octane (CAS 111-65-9)
US. Rhode Island RTK
Dibutyl Ether (CAS 142-96-1)
Octane (CAS 111-65-9)
California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material
is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For
more information go to www.P65Warnings.ca.gov.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9)
Octane (CAS 111-65-9)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) NoCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI) YesTaiwan
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
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16. Other information, including date of preparation or last revision
10-April-2014Issue date
24-November-2020Revision date
Version # 04
NFPA ratings
02
3
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
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